AR079666A1 - Carboxamidas 2-(ariloxi biciclicas), composiciones fungicidas y su uso en el control de enfermedades de las plantas. - Google Patents

Carboxamidas 2-(ariloxi biciclicas), composiciones fungicidas y su uso en el control de enfermedades de las plantas.

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Publication number
AR079666A1
AR079666A1 ARP100104831A ARP100104831A AR079666A1 AR 079666 A1 AR079666 A1 AR 079666A1 AR P100104831 A ARP100104831 A AR P100104831A AR P100104831 A ARP100104831 A AR P100104831A AR 079666 A1 AR079666 A1 AR 079666A1
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Argentina
Prior art keywords
alkyl
independently selected
haloalkyl
alkylcarbonyl
alkoxy
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ARP100104831A
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Alvin Donal Crews Jr
Amy X Ding
Chi-Ping Tseng
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Du Pont
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Publication of AR079666A1 publication Critical patent/AR079666A1/es

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    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D217/00Heterocyclic compounds containing isoquinoline or hydrogenated isoquinoline ring systems
    • C07D217/22Heterocyclic compounds containing isoquinoline or hydrogenated isoquinoline ring systems with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the nitrogen-containing ring
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    • C07DHETEROCYCLIC COMPOUNDS
    • C07D215/00Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34Nitriles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04Aryloxy-acetic acids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A01N43/42Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
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    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C235/00Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms
    • C07C235/02Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C235/04Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C235/08Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton the carbon skeleton being acyclic and saturated having the nitrogen atom of at least one of the carboxamide groups bound to an acyclic carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/01Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/24Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the same saturated acyclic carbon skeleton
    • C07C255/29Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the same saturated acyclic carbon skeleton containing cyano groups and acylated amino groups bound to the carbon skeleton
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/49Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/53Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and hydroxy groups bound to the carbon skeleton
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    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C271/00Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C271/06Esters of carbamic acids
    • C07C271/08Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/10Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C271/20Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by nitrogen atoms not being part of nitro or nitroso groups
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/10Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C323/18Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
    • C07C323/21Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton with the sulfur atom of the thio group bound to a carbon atom of a six-membered aromatic ring being part of a condensed ring system
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C327/00Thiocarboxylic acids
    • C07C327/20Esters of monothiocarboxylic acids
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C327/00Thiocarboxylic acids
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    • C07C327/40Amides of thiocarboxylic acids having carbon atoms of thiocarboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C327/42Amides of thiocarboxylic acids having carbon atoms of thiocarboxamide groups bound to hydrogen atoms or to acyclic carbon atoms to hydrogen atoms or to carbon atoms of a saturated carbon skeleton
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    • C07DHETEROCYCLIC COMPOUNDS
    • C07D215/00Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
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    • C07D215/16Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D215/20Oxygen atoms
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    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/30Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/32Esters thereof
    • C07F9/3205Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/3211Esters of acyclic saturated acids which can have further substituents on alkyl
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    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
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    • C07F9/60Quinoline or hydrogenated quinoline ring systems
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    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
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    • C07C2601/14The ring being saturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Quinoline Compounds (AREA)
  • Other In-Based Heterocyclic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)

Abstract

También se describen composiciones que contienen los compuestos de la formula (1) y métodos para controlar enfermedades de las plantas causadas por un patogeno fungico; el método comprende aplicar una cantidad eficaz de un compuesto o una composicion de la solicitud. Reivindicacion 1: Un compuesto seleccionado de la formula (1), N-oxidos y sus sales, en donde Q es O o S; Z1 y Z2 son cada uno independientemente CR9 o N; R1 es alquilo C1-2, alquenilo C2-4, alquinilo C2-4, haloalquilo C1-4, haloalquenilo C2-4, haloalquinilo C2-4, halocicloalquilo C3-4, cicloalquilalquilo C4-5, alcoxialquilo C2-4, alquiltioalquilo C2-4, alquilsulfinilalquilo C2-4, alquilsulfonilalquilo C2-4, cianoalquilo C2-4, alquilcarbonilo C2-6, alcoxicarbonilo C2-6, alcoxi C1-4 o haloalcoxi C1-4; R2 es hidrogeno, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, haloalquilo C1-6, haloalquenilo C2-6, haloalquinilo C2-6, cicloalquilo C3-6, halocicloalquilo C3-6, cianoalquilo C2-6, alcoxialquilo C2-6, alcoxialcoxialquilo o benciloxi C3-8(alquilo C2-3); R3 es alquilo C1-8, alquenilo C2-8 o alquinilo C2-8, cada uno se sustituye, opcionalmente, con sustituyentes seleccionados independientemente de halogeno, hidroxi, ciano, nitro, amino, C(=O)OH, C(=O)NH2, C(=O)R10, C(=O)OR11, C(=O)NR12R13, OC(=O)R10, SC(=O)R10, OC(=O)OR11, OC(=O)NR12R13, N(R12)C(=O)R10, N(R12)C(=O)OR11, N(R12)C(=O)NR12R13, OSO2R14, OSO2NR12R13, NR12SO2R14, NR12SO2NR12R13, OR15, NR12R13, S(O)nR14, SO2NR12R13, P(=O)(R17)2, OP(=O)(R17)2, Si(R18)3, C(=NNR12R13)R19, N=CR19NR12R13, CH=NR21 y -CH[O(CH2)]; o R3 es NR12R13; o R3 es un anillo carboxílico saturado de 3-, 4-, 5- o 6- miembros opcionalmente sustituido con hasta 5 sustituyentes seleccionados independientemente de R20; o un anillo heterocíclico de 3-, 4-, 5- o 6- miembros que contiene miembros anulares seleccionados de átomos de carbono y hasta 4 heteroátomos seleccionados de hasta 2 oxígenos, hasta 2 azufres y hasta 3 átomos de nitrogeno, en donde hasta 3 miembros anulares del átomo de carbono se seleccionan independientemente de C(=O) y C(=S), y los miembros anulares del átomo de azufre se seleccionan independientemente de S(=O)p(=NR16)q, el anillo heterocíclico opcionalmente sustituido con hasta 5 sustituyentes seleccionados independientemente de R20 en los miembros anulares del átomo de carbono y R20a en los miembros anulares del átomo de nitrogeno; R4, R5, R7 y R8 se seleccionan independientemente de hidrogeno, halogeno, ciano, amino, nitro, -CHO, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, haloalquilo C1-6, haloalquenilo C2-6, haloalquinilo C2-6, cicloalquilo C3-6, halocicloalquilo C3-6, alquilcicloalquilo C4-8, cicloalquilalquilo C4-8, cicloalquenilo C3-6, alcoxialquilo C2-6, alquiltioalquilo C2-6, alquilcarbonilo C2-6, haloalquilcarbonilo C2-6, alcoxicarbonilo C2-6, alquilaminocarbonilo C2-6, dialquilaminocarbonilo C3-8, cianoalquilo C2-6, alcoxi C1-6, haloalcoxi C1-6, alcoxialcoxi C2-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6, haloalquilsulfonilo C1-6, trialquilsililo C3-9, alquilamino C1-6, dialquilamino C2-6, haloalquilamino C2-6, halodialquilamino C2-6 y alquilcarbonilamino C2-6; R6 es halogeno, ciano, amino, nitro, -CHO, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, haloalquilo C1-6, haloalquenilo C2-6, haloalquinilo C2-6, cicloalquilo C3-6 halocicloalquilo C3-6, alquilcicloalquilo C4-8, cicloalquilalquilo C4-8, cicloalquenilo C3-6, alcoxialquilo C2-6, alquiltioalquilo C2-6, alquilcarbonilo C2-6, haloalquilcarbonilo C2-6, alcoxicarbonilo C2-6, alquilaminocarbonilo C2-6, dialquilaminocarbonilo C3-8, cianoalquilo C2-6, alcoxi C1-6, haloalcoxi C1-6, alcoxialcoxi C2-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6, haloalquilsulfonilo C1-6, alquilamino C1-6, dialquilamino C2-6, haloalquilamino C2-6, halodialquilamino C2-6 o alquilcarbonilamino C2-6; cada R9 se selecciona independientemente de hidrogeno, halogeno, ciano, amino, nitro, -CHO, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, haloalquilo C1-6, haloalquenilo C2-6, haloalquinilo C2-6, cicloalquilo C3-6, halocicloalquilo C3-6, alquilcicloalquilo C4-8, cicloalquilalquilo C4-8, cicloalquenilo C3-6, alcoxialquilo C2-6, alquiltioalquilo C2-6, alquilcarbonilo C2-6, alcoxicarbonilo C2-6, alquilaminocarbonilo C2-6, dialquilaminocarbonilo C3-8, cianoalquilo C2-6, alcoxi C1-6, haloalcoxi C1-6, alcoxialcoxi C2-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6, haloalquilsulfonilo C1-6, trialquilsililo C3-9, alquilamino C1-6, dialquilamino C2-6, haloalquilamino C2-6, halodialquilamino C2-6 y alquilcarbonilamino C2-6; cada R10 se selecciona independientemente de hidrogeno, alquilo C1-6, haloalquilo C1-6, cicloalquilo C3-6 y halocicloalquilo C3-6; cada R11 se selecciona independientemente de alquilo C1-6, haloalquilo C1-6, cicloalquilo C3-6 y halocicloalquilo C3-6; cada R12 se selecciona independientemente de hidrogeno, CHO, alquilo C1-6, haloalquilo C1-6 y alquilcarbonilo C2-6; cada R13 se selecciona independientemente de CHO, alquilo C1-6, haloalquilo C1-6 y alquilcarbonilo C2-6; cada R14 es independientemente alquilo C1-6 o haloalquilo C1-6; cada R15 se selecciona independientemente de CHO, alquilo C1-6, haloalquilo C1-6 y alcoxialquilo C2-6; cada R16 y R19 es independientemente hidrogeno o alquilo C1-3; cada R17 es independientemente alquilo C1-6 o alcoxi C1-6; cada R18 es independientemente alquilo C1-6; cada R20 se selecciona independientemente de halogeno, ciano, alquilo C1-6, haloalquilo C1-6, alquilcarbonilo C2-6, alcoxi C1-6, haloalcoxi C1-6 y alquiltio C1-6; cada R20a se selecciona independientemente de ciano, alquilo C1-6, haloalquilo C1-6 y alquilcarbonilo C2-6; cada R21 es un anillo heterocíclico insaturado de 5 miembros que contiene 2 - 4 átomos de carbono y 1 - 3 átomos de nitrogeno como miembros anulares, en donde el anillo heterocíclico se selecciona, opcionalmente, con hasta 2 sustituyentes seleccionados independientemente de R20 en los miembros anulares del átomo de carbono y R20a en los miembros anulares del átomo de nitrogeno; cada n es independientemente 0, 1 o 2; y p y q son independientemente 0, 1 o 2 en cada instancia de S(=O)p(NR16)q, siempre que la suma de p y q es 0, 1 o 2; siempre que el compuesto de la formula (1) es distinto a 2-[(7-metoxi-2-naftalenil)oxi]-N-(2-propen-1-il)-propanamida.
ARP100104831A 2009-12-22 2010-12-21 Carboxamidas 2-(ariloxi biciclicas), composiciones fungicidas y su uso en el control de enfermedades de las plantas. AR079666A1 (es)

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EP (1) EP2516385A2 (es)
JP (1) JP2013515084A (es)
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CN (1) CN102844296A (es)
AR (1) AR079666A1 (es)
AU (1) AU2010341457A1 (es)
BR (1) BR112012015297A2 (es)
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WO2013063243A1 (en) * 2011-10-25 2013-05-02 New York University Small molecule malarial aldolase-trap enhancers and glideosome inhibitors
JP2017160124A (ja) * 2014-07-24 2017-09-14 日本曹達株式会社 アリールオキシ化合物および有害生物防除剤
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UY33147A (es) 2011-07-29
US20120283216A1 (en) 2012-11-08
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