AR074607A1 - Oximeteres e hidrazonas de tiazolilo como agentes fitoprotectores. - Google Patents
Oximeteres e hidrazonas de tiazolilo como agentes fitoprotectores.Info
- Publication number
- AR074607A1 AR074607A1 ARP090104825A ARP090104825A AR074607A1 AR 074607 A1 AR074607 A1 AR 074607A1 AR P090104825 A ARP090104825 A AR P090104825A AR P090104825 A ARP090104825 A AR P090104825A AR 074607 A1 AR074607 A1 AR 074607A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- haloalkyl
- substituents
- cycloalkyl
- phenyl
- Prior art date
Links
- 150000007857 hydrazones Chemical class 0.000 title 1
- 239000003223 protective agent Substances 0.000 title 1
- 125000001424 substituent group Chemical group 0.000 abstract 21
- 125000000217 alkyl group Chemical group 0.000 abstract 16
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 16
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 abstract 14
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 abstract 13
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 13
- 125000006583 (C1-C3) haloalkyl group Chemical group 0.000 abstract 12
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 abstract 12
- 229910052736 halogen Inorganic materials 0.000 abstract 12
- 150000002367 halogens Chemical class 0.000 abstract 12
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 11
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 10
- 125000000232 haloalkynyl group Chemical group 0.000 abstract 10
- 125000004448 alkyl carbonyl group Chemical group 0.000 abstract 9
- 125000000262 haloalkenyl group Chemical group 0.000 abstract 9
- 125000005347 halocycloalkyl group Chemical group 0.000 abstract 9
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 abstract 9
- -1 1-methoxycyclopropyl Chemical group 0.000 abstract 8
- 125000005119 alkyl cycloalkyl group Chemical group 0.000 abstract 8
- 125000001188 haloalkyl group Chemical group 0.000 abstract 8
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 6
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 6
- 125000004414 alkyl thio group Chemical group 0.000 abstract 6
- 125000001316 cycloalkyl alkyl group Chemical group 0.000 abstract 6
- 125000004995 haloalkylthio group Chemical group 0.000 abstract 6
- 125000005196 alkyl carbonyloxy group Chemical group 0.000 abstract 5
- 125000005120 alkyl cycloalkyl alkyl group Chemical group 0.000 abstract 5
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 5
- 229910052739 hydrogen Inorganic materials 0.000 abstract 5
- 239000001257 hydrogen Substances 0.000 abstract 5
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 5
- 125000004768 (C1-C4) alkylsulfinyl group Chemical group 0.000 abstract 4
- 125000004769 (C1-C4) alkylsulfonyl group Chemical group 0.000 abstract 4
- 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 abstract 4
- 125000004771 (C1-C4) haloalkylsulfinyl group Chemical group 0.000 abstract 4
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 abstract 4
- 125000003320 C2-C6 alkenyloxy group Chemical group 0.000 abstract 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 4
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 4
- 125000005133 alkynyloxy group Chemical group 0.000 abstract 4
- 229910052799 carbon Inorganic materials 0.000 abstract 4
- 150000002431 hydrogen Chemical class 0.000 abstract 4
- 229910052757 nitrogen Inorganic materials 0.000 abstract 4
- 125000006700 (C1-C6) alkylthio group Chemical group 0.000 abstract 3
- 125000004737 (C1-C6) haloalkoxy group Chemical group 0.000 abstract 3
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 abstract 3
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 abstract 3
- 125000004441 haloalkylsulfonyl group Chemical group 0.000 abstract 3
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- 229920006395 saturated elastomer Chemical group 0.000 abstract 3
- 229910052717 sulfur Inorganic materials 0.000 abstract 3
- 241000233866 Fungi Species 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 125000003545 alkoxy group Chemical group 0.000 abstract 2
- 125000004453 alkoxycarbonyl group Chemical group 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000000000 cycloalkoxy group Chemical group 0.000 abstract 2
- 125000004438 haloalkoxy group Chemical group 0.000 abstract 2
- 125000004692 haloalkylcarbonyl group Chemical group 0.000 abstract 2
- 125000001072 heteroaryl group Chemical group 0.000 abstract 2
- 125000005842 heteroatom Chemical group 0.000 abstract 2
- 125000000623 heterocyclic group Chemical group 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 2
- 125000004043 oxo group Chemical group O=* 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 230000003032 phytopathogenic effect Effects 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 239000011593 sulfur Substances 0.000 abstract 2
- 125000004454 (C1-C6) alkoxycarbonyl group Chemical group 0.000 abstract 1
- 125000004738 (C1-C6) alkyl sulfinyl group Chemical group 0.000 abstract 1
- 125000004916 (C1-C6) alkylcarbonyl group Chemical group 0.000 abstract 1
- 125000004739 (C1-C6) alkylsulfonyl group Chemical group 0.000 abstract 1
- 125000004749 (C1-C6) haloalkylsulfinyl group Chemical group 0.000 abstract 1
- 125000004741 (C1-C6) haloalkylsulfonyl group Chemical group 0.000 abstract 1
- 125000006376 (C3-C10) cycloalkyl group Chemical group 0.000 abstract 1
- 125000006570 (C5-C6) heteroaryl group Chemical group 0.000 abstract 1
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 125000005083 alkoxyalkoxy group Chemical group 0.000 abstract 1
- 125000005130 alkyl carbonyl thio group Chemical group 0.000 abstract 1
- 125000000392 cycloalkenyl group Chemical group 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 125000005366 cycloalkylthio group Chemical group 0.000 abstract 1
- 125000004994 halo alkoxy alkyl group Chemical group 0.000 abstract 1
- 125000006769 halocycloalkoxy group Chemical group 0.000 abstract 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 abstract 1
- 125000001624 naphthyl group Chemical group 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P3/00—Drugs for disorders of the metabolism
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing three or more hetero rings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Pharmacology & Pharmacy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Diabetes (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Hematology (AREA)
- Animal Behavior & Ethology (AREA)
- Obesity (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Medicinal Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Plural Heterocyclic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08171392 | 2008-12-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR074607A1 true AR074607A1 (es) | 2011-01-26 |
Family
ID=41664742
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP090104825A AR074607A1 (es) | 2008-12-11 | 2009-12-11 | Oximeteres e hidrazonas de tiazolilo como agentes fitoprotectores. |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US8697878B2 (OSRAM) |
| EP (1) | EP2376487B1 (OSRAM) |
| JP (1) | JP2012511525A (OSRAM) |
| CN (1) | CN102292334A (OSRAM) |
| AR (1) | AR074607A1 (OSRAM) |
| BR (1) | BRPI0923366A2 (OSRAM) |
| MX (1) | MX2011006042A (OSRAM) |
| WO (1) | WO2010066353A1 (OSRAM) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012511525A (ja) | 2008-12-11 | 2012-05-24 | バイエル・クロップサイエンス・アーゲー | 植物保護剤としてのチアゾリルオキシムエーテルおよびヒドラゾン |
| EP2516426B1 (de) | 2009-12-21 | 2015-09-16 | Bayer CropScience AG | Bis(difluormethyl)pyrazole als fungizide |
| EP2563786B1 (de) | 2010-04-28 | 2016-11-02 | Bayer Intellectual Property GmbH | Ketoheteroarylpiperidin und -piperazin Derivate als Fungizide |
| CN102933577B (zh) * | 2010-05-20 | 2014-08-06 | 纳幕尔杜邦公司 | 杀真菌的肟和腙 |
| CN103025723A (zh) | 2010-05-27 | 2013-04-03 | 拜尔农作物科学股份公司 | 作为杀真菌剂的吡啶基羧酸衍生物 |
| US20140005224A1 (en) | 2010-10-27 | 2014-01-02 | Bayer Intellectual Property Gmbh | Heteroaryl piperidine and heteroaryl piperazine derivatives as fungicides |
| MX352307B (es) | 2011-02-01 | 2017-11-17 | Bayer Ip Gmbh | Derivados de heteroarilpiperidina y -piperazina como fungicidas. |
| GEP20156399B (en) * | 2011-06-30 | 2015-11-10 | Syngenta Participations Ag | Microbiocidal heterocycles |
| CN103827112A (zh) | 2011-09-15 | 2014-05-28 | 拜耳知识产权有限责任公司 | 作为杀真菌剂的哌啶吡唑 |
| CA2861020C (en) | 2012-02-02 | 2018-07-17 | Actelion Pharmaceuticals Ltd | 4-(benzoimidazol-2-yl)-thiazole compounds and related aza derivatives and their use as cxcr3 receptor modulators |
| DK2819518T3 (en) * | 2012-02-27 | 2017-12-11 | Bayer Ip Gmbh | COMBINATIONS OF ACTIVE COMPOUNDS CONTAINING A THIAZOYLISOXAZOLINE AND A FUNGICIDE |
| KR102140620B1 (ko) | 2012-08-30 | 2020-08-03 | 바이엘 크롭사이언스 악티엔게젤샤프트 | 3,5-비스(할로알킬)-피라졸-4-카복실산 유도체의 탈카복실화 방법 |
| CN102960341B (zh) * | 2012-11-15 | 2013-11-27 | 郭红甫 | 一种用于缓解除草剂药害的农药组合物 |
| ES2671323T3 (es) | 2013-07-22 | 2018-06-06 | Idorsia Pharmaceuticals Ltd | Derivados 1¿(piperazin¿1¿il)¿2¿([1,2,4]triazol¿1¿il)¿etanona |
| AR099789A1 (es) | 2014-03-24 | 2016-08-17 | Actelion Pharmaceuticals Ltd | Derivados de 8-(piperazin-1-il)-1,2,3,4-tetrahidro-isoquinolina |
| WO2016024350A1 (ja) | 2014-08-13 | 2016-02-18 | 株式会社エス・ディー・エス バイオテック | 縮合11員環化合物及びそれらを含有する農園芸用殺菌剤 |
| WO2016094307A1 (en) | 2014-12-08 | 2016-06-16 | The Research Foundation For The State University Of New York | Anti-fungals targeting the synthesis of fungal shingolipids |
| CN104650061B (zh) * | 2014-12-17 | 2018-01-19 | 南开大学 | 一类噻唑醛肟醚类化合物及其制备方法和用途 |
| CN104650059B (zh) * | 2014-12-17 | 2018-06-22 | 南开大学 | 一类噻唑酮肟醚类衍生物及其制备方法和用途 |
| CN107619408B (zh) * | 2014-12-17 | 2020-08-18 | 南开大学 | 一类氨基噻唑羧酸衍生物及其制备方法和用途 |
| CN104650060B (zh) * | 2014-12-17 | 2018-04-03 | 南开大学 | 一类哌啶噻唑衍生物及其制备方法和用途 |
| PL3245203T3 (pl) | 2015-01-15 | 2019-05-31 | Idorsia Pharmaceuticals Ltd | Pochodne hydroksyalkilopiperazyny jako modulatory receptora cxcr3 |
| AR103399A1 (es) | 2015-01-15 | 2017-05-10 | Actelion Pharmaceuticals Ltd | Derivados de (r)-2-metil-piperazina como moduladores del receptor cxcr3 |
| CN108602765B (zh) | 2016-02-08 | 2022-05-03 | 高文有限公司 | 1,2-苯二甲醇化合物的制造方法 |
| WO2017138069A1 (ja) | 2016-02-08 | 2017-08-17 | 株式会社エス・ディー・エス バイオテック | 殺菌性組成物 |
| WO2018232298A1 (en) | 2017-06-16 | 2018-12-20 | The Research Foundation For The State University Of New York | Anti-fungals compounds targeting the synthesis of fungal sphingolipids |
| CN109456317A (zh) * | 2017-09-06 | 2019-03-12 | 华中师范大学 | 含环丙基的化合物及其制备方法和应用以及杀菌剂 |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4272417A (en) | 1979-05-22 | 1981-06-09 | Cargill, Incorporated | Stable protective seed coating |
| US4245432A (en) | 1979-07-25 | 1981-01-20 | Eastman Kodak Company | Seed coatings |
| US4675398A (en) * | 1985-08-16 | 1987-06-23 | E. R. Squibb & Sons, Inc. | Copper-mediated oximation reaction |
| US4808430A (en) | 1987-02-27 | 1989-02-28 | Yazaki Corporation | Method of applying gel coating to plant seeds |
| US6576455B1 (en) | 1995-04-20 | 2003-06-10 | Basf Corporation | Structure-based designed herbicide resistant products |
| US5876739A (en) | 1996-06-13 | 1999-03-02 | Novartis Ag | Insecticidal seed coating |
| RO121119B1 (ro) * | 1997-12-10 | 2006-12-29 | Dainippon Ink And Chemicals, Inc. | Derivaţi de oximă şi chimicale pentru agricultură, incluzând aceşti derivaţi |
| US6503904B2 (en) | 1998-11-16 | 2003-01-07 | Syngenta Crop Protection, Inc. | Pesticidal composition for seed treatment |
| US6660690B2 (en) | 2000-10-06 | 2003-12-09 | Monsanto Technology, L.L.C. | Seed treatment with combinations of insecticides |
| US20020134012A1 (en) | 2001-03-21 | 2002-09-26 | Monsanto Technology, L.L.C. | Method of controlling the release of agricultural active ingredients from treated plant seeds |
| TW200738701A (en) * | 2005-07-26 | 2007-10-16 | Du Pont | Fungicidal carboxamides |
| EA200800622A1 (ru) | 2005-08-24 | 2008-08-29 | Пайонир Хай-Бред Интернэшнл, Инк. | Композиции, обеспечивающие толерантность к нескольким гербицидам, и способы их применения |
| KR101156893B1 (ko) | 2005-08-31 | 2012-06-21 | 몬산토 테크놀로지 엘엘씨 | 살충 단백질을 암호화하는 뉴클레오티드 서열들 |
| RU2008112198A (ru) | 2005-09-29 | 2009-10-10 | Санофи-Авентис (Fr) | Производные фенил-1,2,4-оксадиазолона, способы их получения и их применение в качестве фармацевтических средств |
| JP2007137852A (ja) * | 2005-11-22 | 2007-06-07 | Hokko Chem Ind Co Ltd | アジン誘導体および農園芸用殺菌剤 |
| BRPI0619730A2 (pt) * | 2005-12-12 | 2011-10-11 | Genelabs Tech Inc | compostos antivirais de n-(anel aromático de 5 membros)-amido |
| US8653115B2 (en) | 2006-06-13 | 2014-02-18 | Shanghai Institute Of Materia Medica, Chinese Academy Of Sciences | Heterocyclic non-nucleoside compounds, their preparation, pharmaceutical composition and their use as antiviral agents |
| WO2008006873A1 (en) * | 2006-07-13 | 2008-01-17 | Bayer Cropscience Sa | Fungicide hydroximoyl-tetrazole derivatives |
| WO2008013622A2 (en) | 2006-07-27 | 2008-01-31 | E. I. Du Pont De Nemours And Company | Fungicidal azocyclic amides |
| WO2008091594A2 (en) | 2007-01-24 | 2008-07-31 | E. I. Du Pont De Nemours And Company | Fungicidal mixtures |
| WO2008091580A2 (en) * | 2007-01-25 | 2008-07-31 | E. I. Du Pont De Nemours And Company | Fungicidal amides |
| TWI428091B (zh) | 2007-10-23 | 2014-03-01 | Du Pont | 殺真菌劑混合物 |
| JP5529044B2 (ja) | 2008-01-25 | 2014-06-25 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 殺菌性複素環化合物 |
| JP5535941B2 (ja) | 2008-01-25 | 2014-07-02 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 殺菌性アミド |
| WO2009132785A1 (de) | 2008-04-30 | 2009-11-05 | Bayer Cropscience Aktiengesellschaft | Thiazol-4-carbonsäureester und thioester als pflanzenschutzmittel |
| JP2012511525A (ja) | 2008-12-11 | 2012-05-24 | バイエル・クロップサイエンス・アーゲー | 植物保護剤としてのチアゾリルオキシムエーテルおよびヒドラゾン |
-
2009
- 2009-11-28 JP JP2011539923A patent/JP2012511525A/ja active Pending
- 2009-11-28 CN CN2009801553875A patent/CN102292334A/zh active Pending
- 2009-11-28 BR BRPI0923366A patent/BRPI0923366A2/pt not_active IP Right Cessation
- 2009-11-28 EP EP09759910.4A patent/EP2376487B1/de not_active Not-in-force
- 2009-11-28 WO PCT/EP2009/008492 patent/WO2010066353A1/de not_active Ceased
- 2009-11-28 MX MX2011006042A patent/MX2011006042A/es not_active Application Discontinuation
- 2009-12-10 US US12/654,124 patent/US8697878B2/en not_active Expired - Fee Related
- 2009-12-11 AR ARP090104825A patent/AR074607A1/es not_active Application Discontinuation
-
2014
- 2014-02-28 US US14/194,134 patent/US9215875B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP2376487B1 (de) | 2016-01-06 |
| US9215875B2 (en) | 2015-12-22 |
| CN102292334A (zh) | 2011-12-21 |
| MX2011006042A (es) | 2011-07-04 |
| US20100190828A1 (en) | 2010-07-29 |
| BRPI0923366A2 (pt) | 2019-09-24 |
| WO2010066353A1 (de) | 2010-06-17 |
| EP2376487A1 (de) | 2011-10-19 |
| US8697878B2 (en) | 2014-04-15 |
| JP2012511525A (ja) | 2012-05-24 |
| US20140296289A1 (en) | 2014-10-02 |
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