AR070172A1 - Compuestos de organofosfina sulfonada y su uso en procesos de hidroformilacion - Google Patents
Compuestos de organofosfina sulfonada y su uso en procesos de hidroformilacionInfo
- Publication number
- AR070172A1 AR070172A1 ARP090100115A ARP090100115A AR070172A1 AR 070172 A1 AR070172 A1 AR 070172A1 AR P090100115 A ARP090100115 A AR P090100115A AR P090100115 A ARP090100115 A AR P090100115A AR 070172 A1 AR070172 A1 AR 070172A1
- Authority
- AR
- Argentina
- Prior art keywords
- ligand
- transition metal
- composition
- carbon
- attached
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 4
- 239000003446 ligand Substances 0.000 abstract 7
- 229910052799 carbon Inorganic materials 0.000 abstract 4
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 125000004437 phosphorous atom Chemical group 0.000 abstract 3
- 229910052698 phosphorus Inorganic materials 0.000 abstract 3
- 229910052723 transition metal Inorganic materials 0.000 abstract 3
- 150000003624 transition metals Chemical class 0.000 abstract 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 2
- 125000002723 alicyclic group Chemical group 0.000 abstract 2
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- -1 alkyl radicals Chemical class 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 239000012018 catalyst precursor Substances 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 238000007037 hydroformylation reaction Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 230000007704 transition Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5004—Acyclic saturated phosphines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5018—Cycloaliphatic phosphines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
El compuesto es util como ligando en catalizadores complejos de metal de transicion-ligando, que son capaces de catalizar la hidroformilacion de un compuesto olefínicamente insaturado, con monoxido de carbono e hidrogeno, para formar uno o más correspondientes productos aldehído. El ligando es incapaz de realizar intercambio alquilo-arilo, lo cual produce un uso reducido del ligando y una mejor recuperacion y reciclamiento del ligando y del metal de transicion, por ejemplo rodio, en composicion con los ligandos de la técnica anterior. Reivindicacion 1: Una composicion que comprende una clase de compuestos de triorganofosfina sulfonada, representados por la formula (1) en donde R1 y R2 cada uno individualmente representa un radical hidrocarbilo monovalente o hidrocarbilo sustituido, que se selecciona del grupo que consiste de radicales alquilo, aralquilo y alicíclicos; en donde R3 representa un radical alquileno bivalente o polivalente o alicíclico bivalente o polivalente, que está enlazado al átomo de fosforo y a uno o más sustituyentes sulfonato; además en donde R3 no contiene ninguna porcion arilo; en donde M representa un cation monovalente, y n es un numero entero que representa un numero total de sustituyentes sulfonato; y además en donde en cada uno de R1, R2 y R3, el átomo de carbono unido al átomo de fosforo o un átomo de carbono directamente unido al átomo de carbono unido al átomo de fosforo, adicionalmente está unido a cuando menos otros 2 átomos de carbono. Reivindicacion 8: Una nueva composicion de catalizador complejo o precursor de catalizador complejo, que comprende un metal de transicion del Grupo 8, 9 o 10 enlazado a cuando menos un ligando representado por la composicion de cualquiera de las reivindicaciones 1 a 7, en donde el metal de transicion opcionalmente está enlazado además a monoxido de carbono, hidrogeno, o a ambos.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US2107008P | 2008-01-15 | 2008-01-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
AR070172A1 true AR070172A1 (es) | 2010-03-17 |
Family
ID=40524946
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP090100115A AR070172A1 (es) | 2008-01-15 | 2009-01-14 | Compuestos de organofosfina sulfonada y su uso en procesos de hidroformilacion |
Country Status (5)
Country | Link |
---|---|
US (1) | US8394978B2 (es) |
EP (1) | EP2231682B1 (es) |
AR (1) | AR070172A1 (es) |
BR (1) | BRPI0905699A2 (es) |
WO (1) | WO2009091671A1 (es) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102627667B (zh) * | 2012-03-20 | 2015-07-22 | 河南省科学院化学研究所有限公司 | 一种生产三环己基膦的方法 |
CN104558029B (zh) * | 2014-12-19 | 2016-07-06 | 河南省科学院化学研究所有限公司 | 一种合成双(二环己基膦)烷烃的方法 |
EP3281973A1 (en) * | 2016-08-11 | 2018-02-14 | Borealis AG | Polypropylene composition with flame retardant activity |
CN113289695B (zh) * | 2021-06-21 | 2022-07-12 | 万华化学集团股份有限公司 | 一种氢甲酰化催化剂的回收方法 |
Family Cites Families (33)
Publication number | Priority date | Publication date | Assignee | Title |
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US2900393A (en) | 1956-12-11 | 1959-08-18 | Rohm & Haas | Preparation of 3-methyl 1,3-propane sultone |
US3527809A (en) | 1967-08-03 | 1970-09-08 | Union Carbide Corp | Hydroformylation process |
US4148830A (en) | 1975-03-07 | 1979-04-10 | Union Carbide Corporation | Hydroformylation of olefins |
US4247486A (en) | 1977-03-11 | 1981-01-27 | Union Carbide Corporation | Cyclic hydroformylation process |
US4283304A (en) | 1979-05-21 | 1981-08-11 | Union Carbide Corporation | Process for removing triorganophosphine from a liquid composition |
DE3235030A1 (de) | 1982-09-22 | 1984-03-22 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von sulfonierten arylphosphinen |
US4625068A (en) | 1985-03-20 | 1986-11-25 | Exxon Chemical Patents Inc. | Rhodium catalyzed hydroformylation of internal olefins |
US4642388A (en) | 1985-08-30 | 1987-02-10 | Exxon Chemical Patents Inc. | Rhodium catalyzed hydroformylation of alpha-substituted alpha-olefins |
US4689437A (en) * | 1986-07-21 | 1987-08-25 | Union Carbide Corporation | Oligomerization to alpha-olefins |
US4822915A (en) | 1986-07-21 | 1989-04-18 | Union Carbide Corporation | Phosphine and sulfonate bearing ligands |
US4716138A (en) | 1986-07-21 | 1987-12-29 | Union Carbide Corporation | Oligomerization to alpha-olefins |
US4731486A (en) * | 1986-11-18 | 1988-03-15 | Union Carbide Corporation | Hydroformylation using low volatile phosphine ligands |
US5180854A (en) | 1988-07-14 | 1993-01-19 | Union Carbide Chemicals & Plastics Technology Corporation | Process for catalyst aldehyde product separation |
KR950000633B1 (ko) * | 1988-07-14 | 1995-01-26 | 유니온 카바이드 케미칼즈 앤드 플라스틱스 캄파니 인코포레이티드 | 알콜 및 알데하이드의 제조방법 |
US5300617A (en) | 1993-01-21 | 1994-04-05 | Exxon Chemical Patents Inc. | Potassium para-diphenyl phosphino benzene sulfonate ligand |
TW248563B (es) | 1993-06-29 | 1995-06-01 | Hoechst Ag | |
DE4325816A1 (de) | 1993-07-31 | 1995-02-02 | Hoechst Ag | Sekundäre und tertiäre Phosphane und Verfahren zu ihrer Herstellung |
DE4427836A1 (de) | 1994-08-05 | 1996-02-08 | Hoechst Ag | Verbindungen aus der Reihe der Phosphane, Verfahren zu ihrer Herstellung sowie ihre Verwendung |
US5756855A (en) | 1994-08-19 | 1998-05-26 | Union Carbide Chemicals & Plastics Technology Corporation | Stabilization of phosphite ligands in hydroformylation process |
DE4435189A1 (de) | 1994-09-30 | 1996-04-04 | Hoechst Ag | Neue sulfonierte Phosphine, Verfahren zu ihrer Herstellung und ihre Verwendung als Bestandteil von Katalysatorsystemen |
EP0805139B1 (en) | 1995-09-26 | 2000-04-26 | Kuraray Co., Ltd. | Hydroformylation method |
US5760286A (en) | 1997-04-02 | 1998-06-02 | Uop Llc | Preparation of tertiary phosphine sulfonic acids |
DE19740672A1 (de) | 1997-09-16 | 1999-03-18 | Hoechst Ag | Verfahren zur Herstellung von Aldehyden durch Hydroformylierung |
DE19756945C2 (de) | 1997-12-22 | 2000-08-03 | Celanese Chem Europe Gmbh | Nichtwäßrige ionogene Ligandflüssigkeiten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatorbestandteil |
US5932772A (en) | 1998-02-02 | 1999-08-03 | Union Carbide Chemicals & Plastics Technology Corporation | Separation processes |
US5952530A (en) | 1998-02-02 | 1999-09-14 | Union Carbide Chemicals & Plastics Technology Corporation | Separation processes |
FR2787786B1 (fr) | 1998-12-23 | 2001-02-02 | Rhone Poulenc Fibres | Procede de preparation de composes organophosphores sulfones hydrosolubles et la realisation de reactions organiques avec catalyse biphasique |
DE19918284C1 (de) | 1999-04-22 | 2000-12-14 | Celanese Chem Europe Gmbh | Verfahren zur Herstellung von sulfonierten Arylphosphinen |
CA2424225C (en) | 2003-03-31 | 2008-08-05 | Cytec Canada Inc. | Tertiary phosphines and their methods of preparation |
US7615658B2 (en) | 2003-04-25 | 2009-11-10 | Dow Global Technologies, Inc. | Aldehyde and alcohol compositions derived from seed oils |
WO2007035540A2 (en) | 2005-09-15 | 2007-03-29 | Dow Global Technologies Inc. | Process for the monosulfonation of aromatic phosphines, and zwitterionic product derived therefrom |
CA2652016C (en) * | 2006-05-15 | 2015-02-03 | Dow Global Technologies Inc. | Hydroformylation process and product separation with improved recovery of rhodium |
EP1894938A1 (en) * | 2006-08-31 | 2008-03-05 | Evonik Degussa GmbH | New cyclopentadienyl, indenyl or fluorenyl substituted phosphine compounds and their use in catalytic reactions |
-
2009
- 2009-01-09 BR BRPI0905699-8A patent/BRPI0905699A2/pt not_active Application Discontinuation
- 2009-01-09 EP EP09701652.1A patent/EP2231682B1/en active Active
- 2009-01-09 US US12/812,985 patent/US8394978B2/en active Active
- 2009-01-09 WO PCT/US2009/030560 patent/WO2009091671A1/en active Application Filing
- 2009-01-14 AR ARP090100115A patent/AR070172A1/es not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
EP2231682A1 (en) | 2010-09-29 |
US8394978B2 (en) | 2013-03-12 |
US20110054205A1 (en) | 2011-03-03 |
WO2009091671A1 (en) | 2009-07-23 |
BRPI0905699A2 (pt) | 2015-07-14 |
EP2231682B1 (en) | 2016-01-06 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG | Grant, registration | ||
FD | Application declared void or lapsed, e.g., due to non-payment of fee |