AR056250A1 - Metodos para la preparacion de alquenil alcanoatos - Google Patents
Metodos para la preparacion de alquenil alcanoatosInfo
- Publication number
- AR056250A1 AR056250A1 ARP040104282A ARP040104282A AR056250A1 AR 056250 A1 AR056250 A1 AR 056250A1 AR P040104282 A ARP040104282 A AR P040104282A AR P040104282 A ARP040104282 A AR P040104282A AR 056250 A1 AR056250 A1 AR 056250A1
- Authority
- AR
- Argentina
- Prior art keywords
- catalyst
- palladium
- gold
- methods
- corresponds
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 8
- 239000003054 catalyst Substances 0.000 abstract 8
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract 4
- 239000010931 gold Substances 0.000 abstract 4
- 229910052737 gold Inorganic materials 0.000 abstract 4
- 229910052763 palladium Inorganic materials 0.000 abstract 4
- 239000012041 precatalyst Substances 0.000 abstract 4
- 239000000463 material Substances 0.000 abstract 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/51—Spheres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0072—Preparation of particles, e.g. dispersion of droplets in an oil bath
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0248—Coatings comprising impregnated particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La presente se refiere a al menos cuatro aspectos diferentes relacionados con la estructura de catalizadores, métodos para preparar esos catalizadores y métodos para usar esos catalizadores para preparar alquenil alcanoatos. Por separado o juntos en combinacion, los diversos aspectos de la presente apuntan a mejorar la produccion de alquenil alcanoatos y VA en particular, incluyendo la reduccion de subproductos y la eficiencia de produccion mejorada. Un primer aspecto de la presente corresponde a un catalizador o pre-catalizador unico de paladio/oro (calcinato opcionalmente) que incluye rodio u otro metal. Un segundo aspecto de la presente corresponde a un catalizador o pre-catalizador de paladio/oro basado en un material soporte en capas donde una capa del material soporte está sustancialmente libre de componentes catalíticos. Un tercer aspecto corresponde a un catalizador o pre-catalizador de paladio/oro sobre un material soporte que contiene zirconia. Un cuatro aspecto corresponde a un catalizador o pre-catalizador de paladio/oro que se produce a partir de componentes catalíticos sustancialmente libres de cloruro.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US53093603P | 2003-12-19 | 2003-12-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
AR056250A1 true AR056250A1 (es) | 2007-10-03 |
Family
ID=34748748
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP040104282A AR056250A1 (es) | 2003-12-19 | 2004-11-19 | Metodos para la preparacion de alquenil alcanoatos |
Country Status (15)
Country | Link |
---|---|
EP (1) | EP1694437A1 (es) |
JP (1) | JP4772694B2 (es) |
KR (1) | KR100890655B1 (es) |
CN (1) | CN100569364C (es) |
AR (1) | AR056250A1 (es) |
AU (1) | AU2004311900B2 (es) |
BR (1) | BRPI0416406A (es) |
CA (1) | CA2547318C (es) |
NO (1) | NO20062528L (es) |
NZ (1) | NZ547073A (es) |
PL (1) | PL380018A1 (es) |
RU (1) | RU2380154C2 (es) |
UA (1) | UA94208C2 (es) |
WO (1) | WO2005065821A1 (es) |
ZA (1) | ZA200604363B (es) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PL382741A1 (pl) * | 2004-12-20 | 2007-12-10 | Celanese International Corporation | Zmodyfikowane materiały podłoża dla katalizatorów |
DE102007025362A1 (de) | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025444A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025443A1 (de) * | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025442B4 (de) | 2007-05-31 | 2023-03-02 | Clariant International Ltd. | Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator |
DE102007025223A1 (de) | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
CN101428238B (zh) * | 2007-11-07 | 2011-02-09 | 中国石油化工股份有限公司上海石油化工研究院 | 热稳定性的层状复合载体 |
DE102008059341A1 (de) * | 2008-11-30 | 2010-06-10 | Süd-Chemie AG | Katalysatorträger, Verfahren zu seiner Herstellung sowie Verwendung |
JP2011121048A (ja) * | 2009-12-09 | 2011-06-23 | Rohm & Haas Co | 固体触媒物質をブレンドし、管状構造物に装填する方法 |
DE102011101459A1 (de) * | 2011-05-13 | 2012-11-15 | Süd-Chemie AG | Verfahren zur Herstellung eines metallhaltigen Schalenkatalysators ohne Zwischenkalzinierung |
DE102012008714A1 (de) * | 2012-05-03 | 2013-11-07 | Clariant Produkte (Deutschland) Gmbh | Vorimprägnierung von Schalenkatalysatoren mit einem Acetat |
TWI510293B (zh) * | 2012-09-19 | 2015-12-01 | Clariant Int Ltd | 用於製造烯基羧酸酯之銅促進殼催化劑,及用於製造該銅促進殼催化劑之方法。 |
EP3325144A4 (en) | 2015-07-22 | 2019-01-16 | BASF Corporation | HIGH GEOMETRIC SURFACE CATALYSTS FOR THE MANUFACTURE OF VINYL ACETATE MONOMER |
CN105478154B (zh) * | 2015-12-14 | 2019-09-03 | 中石化南京催化剂有限公司 | 一种用于高活性流体床催化剂 |
KR102309341B1 (ko) * | 2017-11-30 | 2021-10-05 | 롯데케미칼 주식회사 | 열적 안정성이 향상된 코어-쉘 구조의 촉매담체 및 이의 제조방법 |
EP4201523A1 (de) | 2021-12-21 | 2023-06-28 | Clariant International Ltd | Schalenkatalysator zur herstellung von alkenylcarbonsäureestern mit verbesserter pd-verteilung |
EP4201519A1 (de) | 2021-12-21 | 2023-06-28 | Clariant International Ltd | Schalenkatalysator zur herstellung von alkenylcarbonsäureestern mit verbesserter pd- und au-verteilung |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2469204A1 (fr) * | 1979-11-12 | 1981-05-22 | Inst Francais Du Petrole | Nouveaux catalyseurs de dealkylation, a la vapeur d'eau, d'hydrocarbures aromatiques |
DE19501891C1 (de) * | 1995-01-23 | 1996-09-26 | Degussa | Verfahren zur Herstellung eines Trägerkatalysators und seine Verwendung für die Produktion von Vinylacetat |
IN188013B (es) * | 1995-05-23 | 2002-08-10 | Hoechst Celanese Corp | |
US5705679A (en) * | 1996-04-02 | 1998-01-06 | Nicolau; Ioan | Honeycomb catalyst for vinyl acetate synthesis |
DE19613791C2 (de) * | 1996-04-04 | 2002-01-31 | Celanese Chem Europe Gmbh | Katalysator, Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Vinylacetat |
SA97180048B1 (ar) * | 1996-05-24 | 2005-12-21 | هوكست سيلانس كوربوريشن | محفز بلاديوم - ذهب palladium gold ثنائي المعدن متغاير الخواص heterogeneous bimetallic vinyl acetate لإنتاج أسيتات فينيل |
CN1292726A (zh) * | 1998-02-05 | 2001-04-25 | 恩格尔哈德公司 | 减缓pd-Au醋酸乙烯催化剂的老化 |
ID26891A (id) * | 1998-06-02 | 2001-02-15 | Celanese Internasional Corp | Katalis vinil asetat yang terdiri dari palladium logam dan emas yang dibuat dengan potasium aurat |
DE19827844A1 (de) * | 1998-06-23 | 1999-12-30 | Aventis Res & Tech Gmbh & Co | Verfahren zur Herstellung von Schalenkatalysatoren durch CVD-Beschichtung |
JP2000024518A (ja) * | 1998-07-10 | 2000-01-25 | Tokyo Roki Co Ltd | 触媒装置の製造方法 |
US6358882B1 (en) * | 1998-12-08 | 2002-03-19 | The Standard Oil Company | Fluid bed vinyl acetate catalyst |
DE19914066A1 (de) * | 1999-03-27 | 2000-10-05 | Celanese Chem Europe Gmbh | Katalysatoren für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat, Verfahren zu ihrer Herstellung und ihre Verwendung |
US6303537B1 (en) * | 1999-11-17 | 2001-10-16 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication |
-
2004
- 2004-11-19 CA CA2547318A patent/CA2547318C/en not_active Expired - Fee Related
- 2004-11-19 RU RU2006119178/04A patent/RU2380154C2/ru not_active IP Right Cessation
- 2004-11-19 ZA ZA200604363A patent/ZA200604363B/en unknown
- 2004-11-19 BR BRPI0416406-7A patent/BRPI0416406A/pt not_active Application Discontinuation
- 2004-11-19 CN CNB2004800372009A patent/CN100569364C/zh not_active Expired - Fee Related
- 2004-11-19 PL PL380018A patent/PL380018A1/pl not_active IP Right Cessation
- 2004-11-19 UA UAA200606851A patent/UA94208C2/ru unknown
- 2004-11-19 EP EP04811517A patent/EP1694437A1/en not_active Withdrawn
- 2004-11-19 WO PCT/US2004/038814 patent/WO2005065821A1/en not_active Application Discontinuation
- 2004-11-19 JP JP2006545663A patent/JP4772694B2/ja not_active Expired - Fee Related
- 2004-11-19 KR KR1020067010646A patent/KR100890655B1/ko not_active IP Right Cessation
- 2004-11-19 AR ARP040104282A patent/AR056250A1/es active IP Right Grant
- 2004-11-19 NZ NZ547073A patent/NZ547073A/en not_active IP Right Cessation
- 2004-11-19 AU AU2004311900A patent/AU2004311900B2/en not_active Ceased
-
2006
- 2006-06-01 NO NO20062528A patent/NO20062528L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
CN1929916A (zh) | 2007-03-14 |
EP1694437A1 (en) | 2006-08-30 |
NZ547073A (en) | 2010-05-28 |
NO20062528L (no) | 2006-07-03 |
CA2547318A1 (en) | 2005-07-21 |
ZA200604363B (en) | 2007-10-31 |
RU2380154C2 (ru) | 2010-01-27 |
BRPI0416406A (pt) | 2007-01-09 |
JP4772694B2 (ja) | 2011-09-14 |
KR100890655B1 (ko) | 2009-03-26 |
PL380018A1 (pl) | 2006-12-11 |
CN100569364C (zh) | 2009-12-16 |
KR20060100454A (ko) | 2006-09-20 |
AU2004311900A1 (en) | 2005-07-21 |
JP2007514540A (ja) | 2007-06-07 |
AU2004311900B2 (en) | 2008-10-02 |
RU2006119178A (ru) | 2007-12-20 |
UA94208C2 (ru) | 2011-04-26 |
WO2005065821A1 (en) | 2005-07-21 |
CA2547318C (en) | 2010-11-02 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG | Grant, registration |