AR045588A1 - Procedimiento para la preparacion de bisepoxidos y ditioles para ser usados en el tratamiento de pieles - Google Patents
Procedimiento para la preparacion de bisepoxidos y ditioles para ser usados en el tratamiento de pielesInfo
- Publication number
- AR045588A1 AR045588A1 ARP040103182A ARP040103182A AR045588A1 AR 045588 A1 AR045588 A1 AR 045588A1 AR P040103182 A ARP040103182 A AR P040103182A AR P040103182 A ARP040103182 A AR P040103182A AR 045588 A1 AR045588 A1 AR 045588A1
- Authority
- AR
- Argentina
- Prior art keywords
- dithiol
- bisepoxides
- preparation
- treatment
- moles
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D407/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00
- C07D407/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00 containing two hetero rings
- C07D407/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/10—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton
- C07C323/11—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
- C07C323/12—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Procedimiento para la preparación de bisepóxidos, caracterizado porque se hace reaccionar un dieno conjugado de la fórmula general (1), en donde: R1 es seleccionado entre hidrógeno y alquilo C1-12, sustituido o no sustituido con uno o más grupos S-H- u O-H, en presencia de un catalizador, que se puede obtener poniendo en contacto, por lo menos un compuesto de manganeso, elegido entre A2MnX4, AMnX3, MnY, MnX2 y MnX3 con por lo menos un ligando L de la fórmula general (2), definiéndose las variables como sigue: X es igual o diferente y seleccionado entre aniones monovalentes; Y un anión bivalente; A seleccionado entre un metal alcalino y amonio, que puede ser alquilado; R2 son diferentes o preferentemente iguales o seleccionados entre alquilo C1-20; y por lo menos un coligando, derivado de ácidos monocarboxílicos, ácidos carboxílicos bi- o polivalentes o diaminas, con por lo menos un peróxido, usándose hasta 4 equivalentes de peróxido por equivalente de un doble enlace C-C. Obteniéndose así, mezclas de ditiol que contienen de 55 a 65 moles % de evitro ditiol y 35 a 45 moles % treo-ditiol utilizadas para el tratamiento de pieles de animales muertos para eliminar sustancias córneas de las mismas.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10343252A DE10343252A1 (de) | 2003-09-17 | 2003-09-17 | Verfahren zur Herstellung von Bisepoxiden und Dithiolen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR045588A1 true AR045588A1 (es) | 2005-11-02 |
Family
ID=34352937
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP040103182A AR045588A1 (es) | 2003-09-17 | 2004-09-06 | Procedimiento para la preparacion de bisepoxidos y ditioles para ser usados en el tratamiento de pieles |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US7527652B2 (es) |
| EP (2) | EP1801099B1 (es) |
| CN (2) | CN100364967C (es) |
| AR (1) | AR045588A1 (es) |
| AT (2) | ATE501116T1 (es) |
| BR (1) | BRPI0414391A (es) |
| DE (3) | DE10343252A1 (es) |
| ES (2) | ES2361627T3 (es) |
| WO (1) | WO2005033070A2 (es) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PT2402087E (pt) | 2005-05-27 | 2013-07-22 | Catexel Ltd | Sais pré-formados de catalisador de metal de transição |
| EP2149569A1 (en) | 2008-08-01 | 2010-02-03 | Hexion Specialty Chemicals Research Belgium S.A. | Process for the manufacture of a 1,2-Epoxide |
| EP2149570A1 (en) * | 2008-08-01 | 2010-02-03 | Hexion Specialty Chemicals Research Belgium S.A. | Process for the manufacture of epichlorohydrin using hydrogen peroxide and a manganese komplex |
| EP2273006A1 (en) | 2009-06-17 | 2011-01-12 | Unilever PLC | Bleaching of substrates |
| EP2343288A1 (en) | 2009-11-27 | 2011-07-13 | Momentive Specialty Chemicals Research Belgium S.A. | Process for the manufacture of propylene oxide |
| EP2354131A1 (en) | 2010-02-02 | 2011-08-10 | Momentive Specialty Chemicals Research Belgium | Process for the manufacture of a 1,2-epoxide and a device for carrying out said process |
| WO2011106906A1 (en) | 2010-03-03 | 2011-09-09 | Unilever Plc | Preparation of bleaching catalysts |
| EP2377614A1 (en) * | 2010-04-16 | 2011-10-19 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Bleaching of substrates |
| CN101979428B (zh) * | 2010-10-09 | 2012-09-19 | 天津工业大学 | 一种动物毛发溶解剂及角蛋白溶液的制备方法和用途 |
| BR112014005435B1 (pt) | 2011-09-08 | 2019-11-12 | Catexel Ltd | método de preparação de um pó e pó |
| CN105294397B (zh) * | 2015-11-30 | 2017-07-11 | 金陵科技学院 | 一种多元醇的合成方法 |
| CN105399651B (zh) * | 2015-12-03 | 2017-08-04 | 黄河三角洲京博化工研究院有限公司 | 一种连续合成硫代二甘醇的方法 |
| CN111100096B (zh) * | 2019-12-30 | 2021-09-14 | 新乡医学院 | 用于合成二硫代赤藓醇的中间化合物及其应用和二硫代赤藓醇的合成方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2131630A1 (de) * | 1970-06-29 | 1972-01-05 | Avon Prod Inc | Mittel zur Entfernung von Hornsubstanzen,insbesondere Haaren |
| US3766275A (en) * | 1971-03-15 | 1973-10-16 | Avon Prod Inc | Process for preparing a dithiol butanediol |
| US3775484A (en) | 1972-07-21 | 1973-11-27 | Avon Prod Inc | Process for preparing metal salts of dithiolbutanediols |
| US5329024A (en) | 1993-03-30 | 1994-07-12 | National Starch And Chemical Investment Holding Corporation | Epoxidation of olefins via certain manganese complexes |
| WO2002069921A1 (en) * | 2001-03-07 | 2002-09-12 | Unilever Plc | Hair colouring compositions |
-
2003
- 2003-09-17 DE DE10343252A patent/DE10343252A1/de not_active Withdrawn
-
2004
- 2004-09-06 AR ARP040103182A patent/AR045588A1/es unknown
- 2004-09-10 US US10/571,772 patent/US7527652B2/en not_active Expired - Fee Related
- 2004-09-10 CN CNB2004800269900A patent/CN100364967C/zh not_active Expired - Fee Related
- 2004-09-10 AT AT07104119T patent/ATE501116T1/de active
- 2004-09-10 BR BRPI0414391-4A patent/BRPI0414391A/pt not_active IP Right Cessation
- 2004-09-10 CN CN2007101047819A patent/CN101037407B/zh not_active Expired - Fee Related
- 2004-09-10 WO PCT/EP2004/010123 patent/WO2005033070A2/de active IP Right Grant
- 2004-09-10 ES ES07104119T patent/ES2361627T3/es active Active
- 2004-09-10 EP EP07104119A patent/EP1801099B1/de not_active Not-in-force
- 2004-09-10 ES ES04765052T patent/ES2308225T3/es active Active
- 2004-09-10 AT AT04765052T patent/ATE399764T1/de not_active IP Right Cessation
- 2004-09-10 DE DE502004012296T patent/DE502004012296D1/de active Active
- 2004-09-10 EP EP04765052A patent/EP1663964B1/de not_active Not-in-force
- 2004-09-10 DE DE502004007508T patent/DE502004007508D1/de active Active
-
2009
- 2009-02-12 US US12/369,825 patent/US20090149666A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| WO2005033070A2 (de) | 2005-04-14 |
| ES2308225T3 (es) | 2008-12-01 |
| EP1663964A2 (de) | 2006-06-07 |
| WO2005033070A3 (de) | 2005-06-23 |
| DE502004007508D1 (de) | 2008-08-14 |
| US20060277687A1 (en) | 2006-12-14 |
| ES2361627T3 (es) | 2011-06-20 |
| DE10343252A1 (de) | 2005-04-21 |
| CN1852892A (zh) | 2006-10-25 |
| CN101037407A (zh) | 2007-09-19 |
| EP1801099B1 (de) | 2011-03-09 |
| CN101037407B (zh) | 2010-09-15 |
| EP1801099A1 (de) | 2007-06-27 |
| BRPI0414391A (pt) | 2006-11-21 |
| CN100364967C (zh) | 2008-01-30 |
| US20090149666A1 (en) | 2009-06-11 |
| US7527652B2 (en) | 2009-05-05 |
| DE502004012296D1 (de) | 2011-04-21 |
| ATE501116T1 (de) | 2011-03-15 |
| ATE399764T1 (de) | 2008-07-15 |
| EP1663964B1 (de) | 2008-07-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FB | Suspension of granting procedure |