AR044435A1 - Aparato y metodo para producir acidos carboxilicos aromaticos - Google Patents
Aparato y metodo para producir acidos carboxilicos aromaticosInfo
- Publication number
- AR044435A1 AR044435A1 ARP040101793A ARP040101793A AR044435A1 AR 044435 A1 AR044435 A1 AR 044435A1 AR P040101793 A ARP040101793 A AR P040101793A AR P040101793 A ARP040101793 A AR P040101793A AR 044435 A1 AR044435 A1 AR 044435A1
- Authority
- AR
- Argentina
- Prior art keywords
- mixing
- reactor
- mixing element
- aromatic carboxylic
- precursor
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0053—Details of the reactor
- B01J19/006—Baffles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/11—Stirrers characterised by the configuration of the stirrers
- B01F27/19—Stirrers with two or more mixing elements mounted in sequence on the same axis
- B01F27/192—Stirrers with two or more mixing elements mounted in sequence on the same axis with dissimilar elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
- B01F27/81—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis the stirrers having central axial inflow and substantially radial outflow
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
- B01F27/86—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis co-operating with deflectors or baffles fixed to the receptacle
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
- B01F27/91—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with propellers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0053—Details of the reactor
- B01J19/0066—Stirrers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1806—Stationary reactors having moving elements inside resulting in a turbulent flow of the reactants, such as in centrifugal-type reactors, or having a high Reynolds-number
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F2215/00—Auxiliary or complementary information in relation with mixing
- B01F2215/04—Technical information in relation with mixing
- B01F2215/0413—Numerical information
- B01F2215/0418—Geometrical information
- B01F2215/0427—Numerical distance values, e.g. separation, position
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/40—Mixing liquids with liquids; Emulsifying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/50—Mixing liquids with solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
- B01F33/80—Mixing plants; Combinations of mixers
- B01F33/82—Combinations of dissimilar mixers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00245—Avoiding undesirable reactions or side-effects
- B01J2219/00252—Formation of deposits other than coke
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00761—Details of the reactor
- B01J2219/00763—Baffles
- B01J2219/00765—Baffles attached to the reactor wall
- B01J2219/00768—Baffles attached to the reactor wall vertical
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00761—Details of the reactor
- B01J2219/00763—Baffles
- B01J2219/00779—Baffles attached to the stirring means
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
Un reactor para la oxidación de un precursor a un ácido carboxílico aromático o un éster del mismo en una mezcla de reacción en fase líquida. El reactor comprende un recipiente alargado, de uso sustancialmente vertical, que tiene un elemento de mezclado superior y un elemento de mezclado inferior, caracterizado porque el elemento de mezclado superior es un propulsor con bombeo axial y el elemento de mezclado inferior es un propulsor con bombeo radial. También se describe un proceso para producir un ácido carboxílico o un éster del mismo en un reactor del presente. En el uso, la configuración de los elementos de mezclado conduce a tres zonas de mezclado altamente turbulentas. En una realización preferida del proceso del presente el oxidante, desde una entrada, y el solvente, precursor, y catalizador se introducen directamente en una zona de mezclado. Las zonas de mezclado altamente turbulento conducen a una rápida transferencia de materia suprimiendo la formación de subproductos coloreados no deseados, y reduciendo el ensuciamiento del reactor.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/443,542 US7153480B2 (en) | 2003-05-22 | 2003-05-22 | Apparatus for and method of producing aromatic carboxylic acids |
Publications (1)
Publication Number | Publication Date |
---|---|
AR044435A1 true AR044435A1 (es) | 2005-09-14 |
Family
ID=33450441
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP040101793A AR044435A1 (es) | 2003-05-22 | 2004-05-24 | Aparato y metodo para producir acidos carboxilicos aromaticos |
Country Status (15)
Country | Link |
---|---|
US (1) | US7153480B2 (es) |
EP (1) | EP1635942B1 (es) |
KR (1) | KR101137641B1 (es) |
CN (1) | CN100376321C (es) |
AR (1) | AR044435A1 (es) |
AT (1) | ATE411102T1 (es) |
BR (1) | BRPI0411146B1 (es) |
CA (1) | CA2525898C (es) |
DE (1) | DE602004017173D1 (es) |
ES (1) | ES2314420T3 (es) |
MX (1) | MXPA05012598A (es) |
MY (1) | MY135637A (es) |
TW (1) | TWI331991B (es) |
WO (1) | WO2004105935A1 (es) |
ZA (1) | ZA200509228B (es) |
Families Citing this family (50)
Publication number | Priority date | Publication date | Assignee | Title |
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US7273950B2 (en) * | 2003-06-13 | 2007-09-25 | Tereftalatos Mexicanos, S.A. De C.V. | Process and apparatus for the efficient oxidation of alkyl aromatic compounds |
JP2005104941A (ja) * | 2003-10-02 | 2005-04-21 | Nippon Shokubai Co Ltd | 芳香族カルボニル化合物の製造方法及び芳香族カルボニル化合物製造用触媒 |
US7507857B2 (en) | 2004-09-02 | 2009-03-24 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7381836B2 (en) | 2004-09-02 | 2008-06-03 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7589231B2 (en) | 2004-09-02 | 2009-09-15 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7572936B2 (en) | 2004-09-02 | 2009-08-11 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7582793B2 (en) | 2004-09-02 | 2009-09-01 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7910769B2 (en) | 2004-09-02 | 2011-03-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7504535B2 (en) | 2004-09-02 | 2009-03-17 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7683210B2 (en) * | 2004-09-02 | 2010-03-23 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7741515B2 (en) * | 2004-09-02 | 2010-06-22 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7692036B2 (en) | 2004-11-29 | 2010-04-06 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7692037B2 (en) | 2004-09-02 | 2010-04-06 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7568361B2 (en) | 2004-09-02 | 2009-08-04 | Eastman Chemical Company | Optimized liquid-phase oxidation |
US7884232B2 (en) * | 2005-06-16 | 2011-02-08 | Eastman Chemical Company | Optimized liquid-phase oxidation |
ES1061700Y (es) * | 2005-11-29 | 2006-07-01 | Valver Air Speed S L | Maquina dosificadora y mezcladora de productos liquidos en general |
US20070155987A1 (en) * | 2006-01-04 | 2007-07-05 | O'meadhra Ruairi S | Oxidative digestion with optimized agitation |
US20070208194A1 (en) * | 2006-03-01 | 2007-09-06 | Woodruff Thomas E | Oxidation system with sidedraw secondary reactor |
US7816556B2 (en) * | 2006-03-01 | 2010-10-19 | Eastman Chemical Company | Polycarboxylic acid production system employing enhanced multistage oxidative digestion |
US7420082B2 (en) * | 2006-03-01 | 2008-09-02 | Eastman Chemical Company | Polycarboxylic acid production system employing hot liquor removal downstream of oxidative digestion |
US7501537B2 (en) * | 2006-03-01 | 2009-03-10 | Eastman Chemical Company | Polycarboxylic acid production system employing oxidative digestion with reduced or eliminated upstream liquor exchange |
US7772424B2 (en) * | 2006-03-01 | 2010-08-10 | Eastman Chemical Company | Polycarboxylic acid production system employing enhanced evaporative concentration downstream of oxidative digestion |
US7755172B2 (en) * | 2006-06-21 | 2010-07-13 | The Regents Of The University Of California | Opto-electronic and electronic devices using N-face or M-plane GaN substrate prepared with ammonothermal growth |
US20110144384A1 (en) * | 2006-09-22 | 2011-06-16 | Luciano Piras | Liquid-gas phase reactor system |
WO2009082677A1 (en) | 2007-12-21 | 2009-07-02 | Philadelphia Gear Corporation | Method and apparatus for mixing |
KR100988684B1 (ko) * | 2008-04-16 | 2010-10-18 | 삼남석유화학 주식회사 | 조테레프탈산 제조를 위한 산화 반응기 |
GB0808200D0 (en) | 2008-05-06 | 2008-06-11 | Invista Technologies Srl | Power recovery |
EP2437874B1 (en) * | 2009-06-05 | 2015-05-06 | F.Hoffmann-La Roche Ag | Device for cultivating cells |
WO2011009625A1 (en) * | 2009-07-24 | 2011-01-27 | F. Hoffmann-La Roche Ag | Stirrer system |
KR101159409B1 (ko) * | 2009-10-16 | 2012-06-28 | 삼남석유화학 주식회사 | 방향족 카르복실산 제조용 산화 반응기 및 이를 이용한 방향족 카르복실산의 제조 방법 |
KR101044404B1 (ko) | 2011-02-18 | 2011-06-27 | 김유학 | 멀티샤프트를 이용한 급속 혼화조 교반기 |
CN103143286A (zh) * | 2011-12-06 | 2013-06-12 | 沈阳铝镁设计研究院有限公司 | 一种能提高混合效果减少沉淀的多层搅拌桨结构 |
US9333468B2 (en) | 2012-09-24 | 2016-05-10 | Abengoa Bioenergy New Technologies, Llc | Soak vessels and methods for impregnating biomass with liquid |
US9115214B2 (en) | 2012-09-24 | 2015-08-25 | Abengoa Bioenergy New Technologies, Llc | Methods for controlling pretreatment of biomass |
WO2014094793A1 (en) * | 2012-12-19 | 2014-06-26 | Flsmidth A/S | Apparatus and method for solvent extraction processing |
JP2015054272A (ja) * | 2013-09-11 | 2015-03-23 | 住友金属鉱山株式会社 | 攪拌装置 |
JP5597315B1 (ja) * | 2014-03-12 | 2014-10-01 | ヤマテック株式会社 | 攪拌装置 |
CN104437221A (zh) * | 2014-11-25 | 2015-03-25 | 潘春圃 | 双叶轮的搅拌机 |
JP6848507B2 (ja) * | 2017-02-17 | 2021-03-24 | 住友金属鉱山株式会社 | 加圧反応装置、及びそれを用いた有価金属の浸出処理方法 |
CA3088865A1 (en) * | 2018-01-17 | 2019-07-25 | Outotec (Finland) Oy | Reactor for gas-liquid mass transfer |
KR102256402B1 (ko) * | 2018-10-15 | 2021-05-25 | 한화솔루션 주식회사 | 회분식 반응기 |
KR20200078221A (ko) * | 2018-12-21 | 2020-07-01 | 한화솔루션 주식회사 | 회분식 반응기 |
EP3962638A4 (en) * | 2019-05-03 | 2023-01-11 | Philadelphia Mixing Solutions, LLC | REACTION MIXER |
WO2020264545A1 (en) * | 2019-06-24 | 2020-12-30 | Siemens Healthcare Diagnostics Inc. | Methods and apparatus for rotary mixing of laboratory samples |
CN110963528B (zh) * | 2019-12-20 | 2022-06-28 | 大连博融新材料有限公司 | 一种球形高密度偏钒酸铵、其制备方法及用途 |
CN111589398A (zh) * | 2020-05-26 | 2020-08-28 | 义乌申翊塑胶制品有限公司 | 一种用于泳镜生产的抗菌性材料制备的反应釜装置 |
CN114247333A (zh) * | 2020-09-24 | 2022-03-29 | 天华化工机械及自动化研究设计院有限公司 | 混合进料缓冲罐 |
WO2022093232A1 (en) | 2020-10-29 | 2022-05-05 | Mercury Clean Up, LLC | Mercury collecton system |
CN113546536B (zh) * | 2021-07-28 | 2022-09-06 | 吉林隆源农业服务有限公司 | 一种防沉积的高塔复合肥生产用料浆环流式乳化装置 |
CN113731339B (zh) * | 2021-11-08 | 2022-03-11 | 东营威联化学有限公司 | 一种对二甲苯氧化结晶装置 |
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CA1225634A (en) * | 1984-07-30 | 1987-08-18 | Adam J. Bennett | Apparatus for dispersing a particulate material in a liquid |
SE461444B (sv) * | 1985-11-21 | 1990-02-19 | Boerje Skaanberg | Impellerapparat foer omroerning av vaetska under dispergering av gas daeri |
US5099064A (en) * | 1985-12-30 | 1992-03-24 | Amoco Corporation | Method for increasing conversion efficiency for oxidation of an alkyl aromatic compound to an aromatic carboxylic acid |
US5198156A (en) * | 1986-02-17 | 1993-03-30 | Imperial Chemical Industries Plc | Agitators |
US5211924A (en) * | 1988-02-29 | 1993-05-18 | Amoco Corporation | Method and apparatus for increasing conversion efficiency and reducing power costs for oxidation of an aromatic alkyl to an aromatic carboxylic acid |
US5102630A (en) * | 1988-03-17 | 1992-04-07 | Amoco Corporation | Apparatus for increasing yield and product quality while reducing power costs in oxidation of an aromatic alkyl to an aromatic carboxylic acid |
US4935539A (en) * | 1988-03-17 | 1990-06-19 | Amoco Corporation | Method for increasing yield and product quality while reducing power costs in oxidation of an aromatic alkyl hydrocarbon to an aromatic carboxylic acid |
FR2680983B1 (fr) * | 1991-09-10 | 1993-10-29 | Institut Francais Petrole | Dispositif melangeur continu, procede et utilisation dans une installation de pompage d'un fluide de forte viscosite. |
US5371283A (en) * | 1993-12-22 | 1994-12-06 | Praxair Technology, Inc. | Terephthalic acid production |
CA2149058C (en) * | 1994-05-11 | 1998-07-28 | Jeffrey Paul Kingsley | Enhanced oxidation of organic chemicals |
SE503898C2 (sv) * | 1994-10-25 | 1996-09-30 | Tetra Laval Holdings & Finance | Blandare för blandning av vätskor eller suspensioner samt förfarande för blandning |
US5696285A (en) | 1995-12-29 | 1997-12-09 | Praxair Technology, Inc. | Production of terephthalic acid with excellent optical properties through the use of pure or nearly pure oxygen as the oxidant in p-xylene oxidation |
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US7273950B2 (en) * | 2003-06-13 | 2007-09-25 | Tereftalatos Mexicanos, S.A. De C.V. | Process and apparatus for the efficient oxidation of alkyl aromatic compounds |
-
2003
- 2003-05-22 US US10/443,542 patent/US7153480B2/en not_active Expired - Lifetime
-
2004
- 2004-05-20 AT AT04753071T patent/ATE411102T1/de not_active IP Right Cessation
- 2004-05-20 ZA ZA200509228A patent/ZA200509228B/en unknown
- 2004-05-20 WO PCT/US2004/016180 patent/WO2004105935A1/en active Search and Examination
- 2004-05-20 KR KR1020057022229A patent/KR101137641B1/ko active IP Right Grant
- 2004-05-20 ES ES04753071T patent/ES2314420T3/es not_active Expired - Lifetime
- 2004-05-20 DE DE602004017173T patent/DE602004017173D1/de not_active Expired - Lifetime
- 2004-05-20 BR BRPI0411146A patent/BRPI0411146B1/pt not_active IP Right Cessation
- 2004-05-20 CA CA2525898A patent/CA2525898C/en not_active Expired - Fee Related
- 2004-05-20 MX MXPA05012598A patent/MXPA05012598A/es active IP Right Grant
- 2004-05-20 EP EP04753071A patent/EP1635942B1/en not_active Expired - Lifetime
- 2004-05-20 CN CNB2004800205858A patent/CN100376321C/zh not_active Expired - Lifetime
- 2004-05-21 MY MYPI20041978A patent/MY135637A/en unknown
- 2004-05-21 TW TW093114546A patent/TWI331991B/zh not_active IP Right Cessation
- 2004-05-24 AR ARP040101793A patent/AR044435A1/es active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
BRPI0411146A (pt) | 2006-07-11 |
EP1635942A1 (en) | 2006-03-22 |
KR20060024380A (ko) | 2006-03-16 |
ZA200509228B (en) | 2007-03-28 |
WO2004105935A1 (en) | 2004-12-09 |
MY135637A (en) | 2008-05-30 |
EP1635942B1 (en) | 2008-10-15 |
TW200510293A (en) | 2005-03-16 |
CA2525898A1 (en) | 2004-12-09 |
US7153480B2 (en) | 2006-12-26 |
ES2314420T3 (es) | 2009-03-16 |
MXPA05012598A (es) | 2006-02-08 |
CN1822900A (zh) | 2006-08-23 |
US20040234435A1 (en) | 2004-11-25 |
TWI331991B (en) | 2010-10-21 |
ATE411102T1 (de) | 2008-10-15 |
CA2525898C (en) | 2012-11-06 |
BRPI0411146B1 (pt) | 2016-07-26 |
KR101137641B1 (ko) | 2012-04-19 |
DE602004017173D1 (de) | 2008-11-27 |
CN100376321C (zh) | 2008-03-26 |
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