AR037104A1 - Proceso para la fabricacion de acidos policarboxilicos utilizando agentes reductores que contienen fosforo - Google Patents

Proceso para la fabricacion de acidos policarboxilicos utilizando agentes reductores que contienen fosforo

Info

Publication number
AR037104A1
AR037104A1 ARP020103912A ARP020103912A AR037104A1 AR 037104 A1 AR037104 A1 AR 037104A1 AR P020103912 A ARP020103912 A AR P020103912A AR P020103912 A ARP020103912 A AR P020103912A AR 037104 A1 AR037104 A1 AR 037104A1
Authority
AR
Argentina
Prior art keywords
carboxylic acid
phosphorus
reducing agent
group
reaction mixture
Prior art date
Application number
ARP020103912A
Other languages
English (en)
Inventor
Mark Robert Sivik
Robb Richard Gardner
William Michael Scheper
Original Assignee
Procter & Gamble
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter & Gamble filed Critical Procter & Gamble
Publication of AR037104A1 publication Critical patent/AR037104A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04—Acids, Metal salts or ammonium salts thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

Un método para la producción de ácidos policarboxílicos que comprenden los pasos de: a) mezclar un agente reductor que contiene fósforo con por lo menos un monómero de ácido carboxílico para formar una mezcla de reacción;b) anadir un equivalente de base a la mezcla de reacción para proveer una mezcla de reacción parcialmente neutralizada; y c) anadir un generador de radical libre a la mezcla de reacción parcialmente neutralizada bajo condiciones de polimerización para formar una solución que contiene polímero de fosfo/ácido carboxílico. Dicho generador de radical libre se selecciona del grupo que consiste de sodio, persulfato de amonio, peróxido de hidrógeno, dihidrocloruro de 2,2'-azobis(2-metilpropionamidina), y mezclas de éstos. Dicho agente reductor que contiene fósforo se selecciona del grupo que consiste de ácido hipofosforoso y sus sales de metales alcalinos, ácido fosforoso, y sus sales de metales alcalinos, y mezclas de éstos. La relación molar de monómero de ácido carboxílico a agente reductor que contiene fósforo es 1:4 a 4:1. Dicho monómero de ácido carboxílico se selecciona del grupo que consiste de ácido maleico y otros de acuerdo con la memoria. Producto obtenido mediante dicho proceso.
ARP020103912A 2001-10-18 2002-10-17 Proceso para la fabricacion de acidos policarboxilicos utilizando agentes reductores que contienen fosforo AR037104A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US33035101P 2001-10-18 2001-10-18

Publications (1)

Publication Number Publication Date
AR037104A1 true AR037104A1 (es) 2004-10-20

Family

ID=23289375

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP020103912A AR037104A1 (es) 2001-10-18 2002-10-17 Proceso para la fabricacion de acidos policarboxilicos utilizando agentes reductores que contienen fosforo

Country Status (8)

Country Link
US (1) US7169742B2 (es)
EP (1) EP1448626B1 (es)
JP (1) JP2005506360A (es)
AR (1) AR037104A1 (es)
AT (1) ATE394432T1 (es)
DE (1) DE60226481D1 (es)
EG (1) EG23160A (es)
WO (1) WO2003033552A1 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009006356A1 (en) * 2007-07-02 2009-01-08 Yin Wang Polymeric composition for cellulosic materials binding and modification
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CN109467332B (zh) * 2018-11-07 2021-06-08 天津市鑫永强混凝土外加剂有限公司 一种聚羧酸减水剂及其制备方法

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Also Published As

Publication number Publication date
ATE394432T1 (de) 2008-05-15
US7169742B2 (en) 2007-01-30
EP1448626A1 (en) 2004-08-25
WO2003033552A1 (en) 2003-04-24
US20030074741A1 (en) 2003-04-24
EP1448626B1 (en) 2008-05-07
DE60226481D1 (de) 2008-06-19
EG23160A (en) 2004-05-31
JP2005506360A (ja) 2005-03-03

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