ZA899398B - Yttrium enriched aluminide coating for superalloys - Google Patents
Yttrium enriched aluminide coating for superalloysInfo
- Publication number
- ZA899398B ZA899398B ZA899398A ZA899398A ZA899398B ZA 899398 B ZA899398 B ZA 899398B ZA 899398 A ZA899398 A ZA 899398A ZA 899398 A ZA899398 A ZA 899398A ZA 899398 B ZA899398 B ZA 899398B
- Authority
- ZA
- South Africa
- Prior art keywords
- superalloys
- aluminide coating
- yttrium enriched
- enriched aluminide
- yttrium
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/02—Pretreatment of the material to be coated
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/28—Solid state diffusion of only metal elements or silicon into metallic material surfaces using solids, e.g. powders, pastes
- C23C10/34—Embedding in a powder mixture, i.e. pack cementation
- C23C10/36—Embedding in a powder mixture, i.e. pack cementation only one element being diffused
- C23C10/48—Aluminising
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/12028—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
- Y10T428/12063—Nonparticulate metal component
- Y10T428/1209—Plural particulate metal components
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12736—Al-base component
- Y10T428/1275—Next to Group VIII or IB metal-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12806—Refractory [Group IVB, VB, or VIB] metal-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12806—Refractory [Group IVB, VB, or VIB] metal-base component
- Y10T428/12826—Group VIB metal-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12931—Co-, Fe-, or Ni-base components, alternative to each other
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating By Spraying Or Casting (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/319,593 US4933239A (en) | 1989-03-06 | 1989-03-06 | Aluminide coating for superalloys |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA899398B true ZA899398B (en) | 1990-09-26 |
Family
ID=23242908
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA899398A ZA899398B (en) | 1989-03-06 | 1989-12-08 | Yttrium enriched aluminide coating for superalloys |
Country Status (11)
Country | Link |
---|---|
US (1) | US4933239A (xx) |
EP (1) | EP0386386B1 (xx) |
JP (1) | JP3001161B2 (xx) |
CN (1) | CN1022936C (xx) |
AU (1) | AU626355B2 (xx) |
BR (1) | BR8906389A (xx) |
CA (1) | CA2006892C (xx) |
DE (1) | DE68921194T2 (xx) |
IL (1) | IL92516A (xx) |
NZ (1) | NZ231608A (xx) |
ZA (1) | ZA899398B (xx) |
Families Citing this family (66)
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JPH03268243A (ja) * | 1990-03-16 | 1991-11-28 | Sony Corp | 光ディスク |
US5139824A (en) * | 1990-08-28 | 1992-08-18 | Liburdi Engineering Limited | Method of coating complex substrates |
KR930002869B1 (ko) * | 1990-12-31 | 1993-04-12 | 포항종합제철 주식회사 | 소둔가열로용 방열튜브 및 그 제조방법 |
US5049418A (en) * | 1991-02-19 | 1991-09-17 | Grumman Aerospace Corporation | Barrier coatings for oxidation protection incorporating compatibility layer |
US6010761A (en) * | 1991-03-12 | 2000-01-04 | Sony Corporation | Optical disc |
US5116690A (en) * | 1991-04-01 | 1992-05-26 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Oxidation resistant coating for titanium alloys and titanium alloy matrix composites |
US5161898A (en) * | 1991-07-05 | 1992-11-10 | Camco International Inc. | Aluminide coated bearing elements for roller cutter drill bits |
US5236745A (en) * | 1991-09-13 | 1993-08-17 | General Electric Company | Method for increasing the cyclic spallation life of a thermal barrier coating |
JP2949605B2 (ja) * | 1991-09-20 | 1999-09-20 | 株式会社日立製作所 | 合金被覆ガスタービン翼及びその製造方法 |
US5221354A (en) * | 1991-11-04 | 1993-06-22 | General Electric Company | Apparatus and method for gas phase coating of hollow articles |
US5264245A (en) * | 1991-12-04 | 1993-11-23 | Howmet Corporation | CVD method for forming uniform coatings |
US5261963A (en) * | 1991-12-04 | 1993-11-16 | Howmet Corporation | CVD apparatus comprising exhaust gas condensation means |
US5334263A (en) * | 1991-12-05 | 1994-08-02 | General Electric Company | Substrate stabilization of diffusion aluminide coated nickel-based superalloys |
GB9210683D0 (en) * | 1992-05-19 | 1992-07-08 | Rolls Royce Plc | Multiplex aluminide-silicide coating |
US5268045A (en) * | 1992-05-29 | 1993-12-07 | John F. Wolpert | Method for providing metallurgically bonded thermally sprayed coatings |
DE4226272C1 (de) * | 1992-08-08 | 1994-02-10 | Mtu Muenchen Gmbh | Verfahren zur Behandlung von MCrAlZ-Schichten und mit dem Verfahren hergestellte Bauteile |
US5500252A (en) * | 1992-09-05 | 1996-03-19 | Rolls-Royce Plc | High temperature corrosion resistant composite coatings |
US5650235A (en) * | 1994-02-28 | 1997-07-22 | Sermatech International, Inc. | Platinum enriched, silicon-modified corrosion resistant aluminide coating |
US5660886A (en) * | 1995-04-24 | 1997-08-26 | Mc Donnell Douglas Corp | Method for forming in situ diffusion barrier while diffusing aluminum through nickel-boron |
US6022632A (en) * | 1996-10-18 | 2000-02-08 | United Technologies | Low activity localized aluminide coating |
US6458473B1 (en) | 1997-01-21 | 2002-10-01 | General Electric Company | Diffusion aluminide bond coat for a thermal barrier coating system and method therefor |
US6284390B1 (en) | 1998-06-12 | 2001-09-04 | United Technologies Corporation | Thermal barrier coating system utilizing localized bond coat and article having the same |
WO2000009777A1 (en) | 1998-08-17 | 2000-02-24 | Coltec Industries Inc. | Vapor phase co-deposition coating for superalloy applications |
EP1033417A1 (de) * | 1999-03-04 | 2000-09-06 | Siemens Aktiengesellschaft | Verfahren und Einrichtung zur Beschichtung eines Erzeugnisses, insbesondere eines Hochtemperaturbauteils einer Gasturbine |
US6435830B1 (en) * | 1999-12-20 | 2002-08-20 | United Technologies Corporation | Article having corrosion resistant coating |
SG98436A1 (en) * | 1999-12-21 | 2003-09-19 | United Technologies Corp | Method of forming an active-element containing aluminide as stand alone coating and as bond coat and coated article |
US6472018B1 (en) | 2000-02-23 | 2002-10-29 | Howmet Research Corporation | Thermal barrier coating method |
US6346134B1 (en) * | 2000-03-27 | 2002-02-12 | Sulzer Metco (Us) Inc. | Superalloy HVOF powders with improved high temperature oxidation, corrosion and creep resistance |
FR2813318B1 (fr) | 2000-08-28 | 2003-04-25 | Snecma Moteurs | Formation d'un revetement aluminiure incorporant un element reactif, sur un substrat metallique |
US6635362B2 (en) | 2001-02-16 | 2003-10-21 | Xiaoci Maggie Zheng | High temperature coatings for gas turbines |
US8252376B2 (en) * | 2001-04-27 | 2012-08-28 | Siemens Aktiengesellschaft | Method for restoring the microstructure of a textured article and for refurbishing a gas turbine blade or vane |
US6560870B2 (en) * | 2001-05-08 | 2003-05-13 | General Electric Company | Method for applying diffusion aluminide coating on a selective area of a turbine engine component |
JP3700766B2 (ja) * | 2001-05-15 | 2005-09-28 | 株式会社東北テクノアーチ | 熱遮蔽皮膜被覆部材並びに溶射用粉体 |
EP1298230A1 (de) * | 2001-10-01 | 2003-04-02 | Siemens Aktiengesellschaft | Verfahren zur Entfernung von Schichtbereichen eines Bauteils aus Metall |
US6942929B2 (en) | 2002-01-08 | 2005-09-13 | Nianci Han | Process chamber having component with yttrium-aluminum coating |
US7371467B2 (en) * | 2002-01-08 | 2008-05-13 | Applied Materials, Inc. | Process chamber component having electroplated yttrium containing coating |
US6855212B2 (en) * | 2002-02-15 | 2005-02-15 | Honeywell International Inc. | Elevated temperature oxidation protection coatings for titanium alloys and methods of preparing the same |
US6746783B2 (en) * | 2002-06-27 | 2004-06-08 | General Electric Company | High-temperature articles and method for making |
US7297247B2 (en) * | 2003-05-06 | 2007-11-20 | Applied Materials, Inc. | Electroformed sputtering target |
ATE329067T1 (de) * | 2003-06-26 | 2006-06-15 | Alstom Technology Ltd | Verfahren für das auftragen eines mehrschichtigen systems |
US7153586B2 (en) * | 2003-08-01 | 2006-12-26 | Vapor Technologies, Inc. | Article with scandium compound decorative coating |
US6935187B1 (en) * | 2004-03-03 | 2005-08-30 | General Electric Company | Test method for assessing thermal mechanical fatigue performance of a test material |
US20070026205A1 (en) | 2005-08-01 | 2007-02-01 | Vapor Technologies Inc. | Article having patterned decorative coating |
DE102005053531A1 (de) * | 2005-11-08 | 2007-05-10 | Man Turbo Ag | Wärmedämmende Schutzschicht für ein Bauteil innerhalb des Heißgasbereiches einer Gasturbine |
US20100136240A1 (en) * | 2007-05-07 | 2010-06-03 | O'connell Matthew James | Process for Forming an Outward Grown Aluminide Coating |
CN101310971B (zh) * | 2007-05-25 | 2012-01-04 | 中国科学院金属研究所 | 一种MCrAlY加复合梯度涂层及制备工艺 |
EP2098606A1 (en) * | 2008-03-04 | 2009-09-09 | Siemens Aktiengesellschaft | A MCrAlY alloy, methods to produce a MCrAlY layer and a honeycomb seal |
DE102008019296A1 (de) * | 2008-04-16 | 2009-10-22 | Rolls-Royce Deutschland Ltd & Co Kg | Verfahren zur Herstellung eines Feuerschutzes für aus Titan bestehende Bauteilkörper einer Fluggasturbine und Bauteilkörper aus Titan für eine Fluggasturbine |
EP2174740A1 (en) * | 2008-10-08 | 2010-04-14 | Siemens Aktiengesellschaft | Honeycomb seal and method to produce it |
EP2239351B1 (en) * | 2009-04-09 | 2013-03-13 | Siemens Aktiengesellschaft | Introduction of at least one of the elements of hafnium, lanthanum and yttrium into a superalloy component |
EP2239346A1 (en) * | 2009-04-09 | 2010-10-13 | Siemens Aktiengesellschaft | Slurry composition for aluminising a superalloy component |
US20110300405A1 (en) * | 2010-06-03 | 2011-12-08 | General Electric Company | Oxidation resistant components and related methods |
WO2012033160A1 (ja) * | 2010-09-09 | 2012-03-15 | 独立行政法人物質・材料研究機構 | 耐酸化特性に優れた高温用合金材料およびその製造方法 |
CN101942635B (zh) * | 2010-09-09 | 2011-11-30 | 西北工业大学 | 一种铝钇镁共渗粉末包覆渗剂及其制备和包覆方法 |
US8367160B2 (en) * | 2010-11-05 | 2013-02-05 | United Technologies Corporation | Coating method for reactive metal |
US20120189778A1 (en) * | 2011-01-26 | 2012-07-26 | Riewe Curtis H | Coating method using ionic liquid |
CN102776512B (zh) * | 2012-08-10 | 2014-07-23 | 苏州市涵信塑业有限公司 | 一种梯度热障涂层的制备方法 |
CN103060747B (zh) * | 2012-12-13 | 2014-10-15 | 北京航空航天大学 | 一种采用包埋渗工艺在Ni基高温合金上制备Y改性CoAlNi涂层的方法 |
CN103305844B (zh) * | 2013-05-07 | 2015-09-09 | 南京航空航天大学 | 一种钛合金表面抗高温氧化和耐磨损的复合涂层的制备方法 |
US9957629B2 (en) | 2014-08-27 | 2018-05-01 | Praxair S.T. Technology, Inc. | Electroplated coatings |
EP3470543A1 (en) * | 2017-10-12 | 2019-04-17 | General Electric Company | Coated component and method of preparing a coated component |
CN107620061B (zh) * | 2017-10-30 | 2019-11-05 | 江苏大学 | 一种高温抗氧化钴基涂层材料及其制备方法 |
US11092019B2 (en) * | 2018-10-12 | 2021-08-17 | General Electric Company | Coated component and method of preparing a coated component |
CN113774313B (zh) * | 2021-08-20 | 2022-09-27 | 华北电力大学 | 受热面具有铝增强型熔覆复合涂层的水冷壁及其制备方法 |
DE102021127344A1 (de) * | 2021-10-21 | 2023-04-27 | MTU Aero Engines AG | Verfahren zum Beschichten eines Bauteils eines Flugtriebwerks mit einer Verschleißschutzschicht und Bauteil für ein Flugtriebwerk mit wenigstens einer Verschleißschutzschicht |
US11821337B1 (en) | 2022-08-05 | 2023-11-21 | Rtx Corporation | Internal aluminide coating for vanes and blades and method of manufacture |
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US30995A (en) * | 1860-12-18 | Device eok | ||
US32121A (en) * | 1861-04-23 | Francis comtesse | ||
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US4152223A (en) * | 1977-07-13 | 1979-05-01 | United Technologies Corporation | Plasma sprayed MCrAlY coating and coating method |
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US4123594A (en) * | 1977-09-22 | 1978-10-31 | General Electric Company | Metallic coated article of improved environmental resistance |
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GB2009251B (en) * | 1977-12-01 | 1982-08-18 | Rolls Royce | Coated metal part and the method of applying coating |
DE3067748D1 (en) * | 1979-07-30 | 1984-06-14 | Secr Defence Brit | A method of forming a corrosion resistant coating on a metal article |
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FR2503829B1 (fr) * | 1981-04-08 | 1985-09-13 | Creusot Loire | Raccords de canalisation d'eau chaude proteges par un revetement de fer-aluminium |
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-
1989
- 1989-03-06 US US07/319,593 patent/US4933239A/en not_active Expired - Lifetime
- 1989-12-01 NZ NZ23160889A patent/NZ231608A/xx unknown
- 1989-12-01 IL IL9251689A patent/IL92516A/en not_active IP Right Cessation
- 1989-12-05 AU AU45903/89A patent/AU626355B2/en not_active Ceased
- 1989-12-08 EP EP89630218A patent/EP0386386B1/en not_active Expired - Lifetime
- 1989-12-08 ZA ZA899398A patent/ZA899398B/xx unknown
- 1989-12-08 DE DE68921194T patent/DE68921194T2/de not_active Expired - Fee Related
- 1989-12-09 CN CN89109243A patent/CN1022936C/zh not_active Expired - Fee Related
- 1989-12-11 BR BR8906389A patent/BR8906389A/pt not_active IP Right Cessation
- 1989-12-29 JP JP34503289A patent/JP3001161B2/ja not_active Expired - Fee Related
- 1989-12-29 CA CA 2006892 patent/CA2006892C/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
IL92516A (en) | 1994-11-28 |
EP0386386B1 (en) | 1995-02-15 |
CA2006892C (en) | 1999-12-07 |
AU4590389A (en) | 1990-09-06 |
BR8906389A (pt) | 1990-08-21 |
JPH0344484A (ja) | 1991-02-26 |
AU626355B2 (en) | 1992-07-30 |
JP3001161B2 (ja) | 2000-01-24 |
CN1045425A (zh) | 1990-09-19 |
IL92516A0 (en) | 1990-08-31 |
CA2006892A1 (en) | 1990-09-06 |
CN1022936C (zh) | 1993-12-01 |
NZ231608A (en) | 1993-02-25 |
DE68921194D1 (de) | 1995-03-23 |
EP0386386A1 (en) | 1990-09-12 |
US4933239A (en) | 1990-06-12 |
DE68921194T2 (de) | 1995-06-14 |
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