ZA869080B - Process for the preparation of l-homoalanin-4-yl(methyl)-phosphinic acid and its alkyl esters - Google Patents
Process for the preparation of l-homoalanin-4-yl(methyl)-phosphinic acid and its alkyl estersInfo
- Publication number
- ZA869080B ZA869080B ZA869080A ZA869080A ZA869080B ZA 869080 B ZA869080 B ZA 869080B ZA 869080 A ZA869080 A ZA 869080A ZA 869080 A ZA869080 A ZA 869080A ZA 869080 B ZA869080 B ZA 869080B
- Authority
- ZA
- South Africa
- Prior art keywords
- methyl
- phosphinic acid
- homoalanin
- preparation
- alkyl esters
- Prior art date
Links
- IAJOBQBIJHVGMQ-BYPYZUCNSA-N glufosinate-P Chemical compound CP(O)(=O)CC[C@H](N)C(O)=O IAJOBQBIJHVGMQ-BYPYZUCNSA-N 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 125000005907 alkyl ester group Chemical group 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 238000003776 cleavage reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- -1 phosphinic acid ester Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 230000007017 scission Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/32—Esters thereof
- C07F9/3205—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/3211—Esters of acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/301—Acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
- C07F9/6509—Six-membered rings
- C07F9/650952—Six-membered rings having the nitrogen atoms in the positions 1 and 4
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853542645 DE3542645A1 (de) | 1985-12-03 | 1985-12-03 | Verfahren zur herstellung von l-homoalanin-4-yl(methyl)-phosphinsaeure sowie ihrer alkylester |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA869080B true ZA869080B (en) | 1987-07-29 |
Family
ID=6287439
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA869080A ZA869080B (en) | 1985-12-03 | 1986-12-02 | Process for the preparation of l-homoalanin-4-yl(methyl)-phosphinic acid and its alkyl esters |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4777279A (xx) |
| EP (1) | EP0224880B1 (xx) |
| JP (1) | JPS62132891A (xx) |
| AT (1) | ATE44382T1 (xx) |
| DE (2) | DE3542645A1 (xx) |
| DK (1) | DK579586A (xx) |
| ES (1) | ES2009768B3 (xx) |
| GR (1) | GR3000098T3 (xx) |
| IL (1) | IL80819A0 (xx) |
| ZA (1) | ZA869080B (xx) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2615777B2 (ja) * | 1987-05-26 | 1997-06-04 | 日産化学工業株式会社 | ホスフィニルアミノ酸誘導体の製造方法 |
| DE3817956A1 (de) * | 1988-05-27 | 1989-12-07 | Hoechst Ag | Verfahren zur herstellung phosphorhaltiger l-aminosaeuren sowie ihrer ester und n-derivate |
| TW353663B (en) * | 1991-04-06 | 1999-03-01 | Hoechst Ag | Process for the preparation of phosphorus-containing L-amino acids, their derivatives and intermediates for this process |
| IL104056A (en) * | 1991-12-13 | 1997-02-18 | Hoechst Ag | Process for the preparation of L-phosphinothricin and its derivatives |
| DE4407197A1 (de) * | 1994-03-04 | 1995-09-07 | Hoechst Schering Agrevo Gmbh | Verfahren zur Herstellung von /L/-Homoalanin-4-yl-(methyl)phosphinsäure und deren Salze durch Racematspaltung |
| ES2391468T3 (es) * | 2005-03-29 | 2012-11-27 | Meiji Seika Pharma Co., Ltd. | Procedimiento para la producción de ácido L-2-amino-4-(hidroximetilfosfinil)butanoico |
| AU2007292167B2 (en) * | 2006-09-04 | 2012-11-22 | Meiji Seika Pharma Co., Ltd. | Process for production of optically active aminophosphinylbutanoic acid |
| CN101516898B (zh) * | 2006-09-20 | 2013-07-10 | 明治制果株式会社 | 含有磷的α-氨基酸的制造方法及其制造中间体 |
| TWI546311B (zh) | 2011-09-30 | 2016-08-21 | 明治製菓藥業股份有限公司 | 固殺草ｐ游離酸之製造方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59219297A (ja) * | 1983-05-27 | 1984-12-10 | Meiji Seika Kaisha Ltd | 光学活性な〔（３−アミノ−３−カルボキシ）プロピル−１〕−ホスフイン酸誘導体の製造法 |
| DE3319850C2 (de) * | 1983-06-01 | 1985-05-09 | Hoechst Ag, 6230 Frankfurt | Verfahren zur Herstellung von phosphorhaltigen Cyanhydrinderivaten |
| DE3525267A1 (de) * | 1984-09-08 | 1986-03-20 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von weitgehend reinen enantiomeren von (3-amino-3-carboxy-propyl)-alkyl-phosphinsaeurederivaten, neue pyrazinderivate und ihre verwendung als herbizide und bioregulatoren |
-
1985
- 1985-12-03 DE DE19853542645 patent/DE3542645A1/de not_active Withdrawn
-
1986
- 1986-11-27 EP EP86116508A patent/EP0224880B1/de not_active Expired
- 1986-11-27 DE DE8686116508T patent/DE3664212D1/de not_active Expired
- 1986-11-27 ES ES86116508T patent/ES2009768B3/es not_active Expired
- 1986-11-27 AT AT86116508T patent/ATE44382T1/de not_active IP Right Cessation
- 1986-12-01 US US06/936,335 patent/US4777279A/en not_active Expired - Fee Related
- 1986-12-01 IL IL80819A patent/IL80819A0/xx unknown
- 1986-12-02 ZA ZA869080A patent/ZA869080B/xx unknown
- 1986-12-02 DK DK579586A patent/DK579586A/da not_active Application Discontinuation
- 1986-12-02 JP JP61286097A patent/JPS62132891A/ja active Pending
-
1989
- 1989-07-06 GR GR89400093T patent/GR3000098T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DK579586D0 (da) | 1986-12-02 |
| DE3542645A1 (de) | 1987-06-04 |
| DK579586A (da) | 1987-06-04 |
| EP0224880A1 (de) | 1987-06-10 |
| US4777279A (en) | 1988-10-11 |
| DE3664212D1 (en) | 1989-08-10 |
| GR3000098T3 (en) | 1990-11-29 |
| ES2009768B3 (es) | 1989-10-16 |
| ATE44382T1 (de) | 1989-07-15 |
| EP0224880B1 (de) | 1989-07-05 |
| IL80819A0 (en) | 1987-03-31 |
| JPS62132891A (ja) | 1987-06-16 |
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