ZA785891B - Hydrocarbon synthesis from co and h2 using ru supported on group vb metal oxides - Google Patents

Hydrocarbon synthesis from co and h2 using ru supported on group vb metal oxides

Info

Publication number
ZA785891B
ZA785891B ZA00785891A ZA785891A ZA785891B ZA 785891 B ZA785891 B ZA 785891B ZA 00785891 A ZA00785891 A ZA 00785891A ZA 785891 A ZA785891 A ZA 785891A ZA 785891 B ZA785891 B ZA 785891B
Authority
ZA
South Africa
Prior art keywords
supported
group
metal oxides
hydrocarbon synthesis
hydrocarbon
Prior art date
Application number
ZA00785891A
Other languages
English (en)
Inventor
S Tauster
M Vannice
Original Assignee
Exxon Research Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research Engineering Co filed Critical Exxon Research Engineering Co
Publication of ZA785891B publication Critical patent/ZA785891B/xx

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/648—Vanadium, niobium or tantalum or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/18—Carbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20—Vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20—Vanadium, niobium or tantalum
    • C07C2523/22—Vanadium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56—Platinum group metals
    • C07C2523/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tatalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/648—Vanadium, niobium or tantalum

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
ZA00785891A 1977-10-19 1978-10-19 Hydrocarbon synthesis from co and h2 using ru supported on group vb metal oxides ZA785891B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/843,497 US4171320A (en) 1977-10-19 1977-10-19 Hydrocarbon synthesis from CO and H2 using Ru supported on group VB metal oxides

Publications (1)

Publication Number Publication Date
ZA785891B true ZA785891B (en) 1979-09-26

Family

ID=25290175

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA00785891A ZA785891B (en) 1977-10-19 1978-10-19 Hydrocarbon synthesis from co and h2 using ru supported on group vb metal oxides

Country Status (8)

Country Link
US (1) US4171320A (xx)
JP (1) JPS5470205A (xx)
AU (1) AU526136B2 (xx)
CA (1) CA1089496A (xx)
DE (1) DE2845294A1 (xx)
FR (1) FR2406618A1 (xx)
GB (1) GB2006261B (xx)
ZA (1) ZA785891B (xx)

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ZA783466B (en) * 1978-06-16 1981-07-29 Johnson Matthey Co Ltd Hydrocarbon synthesis
GB2086255B (en) * 1980-05-12 1984-03-21 Commw Scient Ind Res Org Hydrocarbon conversion catalysts with improved regeneration characteristics
DE3035404C2 (de) * 1980-09-19 1982-09-23 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur Herstellung ungesättigter Kohlenwasserstoffe
FR2499552A1 (fr) 1981-02-11 1982-08-13 Inst Francais Du Petrole Procede de synthese catalytique d'hydrocarbures, et en particulier de methane, a partir d'hydrogene et de monoxyde de carbone
DE3227327A1 (de) * 1981-07-28 1983-02-17 Institut Français du Pétrole, 92502 Rueil-Malmaison, Hauts-de-Seine Verfahren zur herstellung von methan durch katalytische reduktion von kohlenoxiden in waessriger phase
US4585798A (en) * 1981-10-13 1986-04-29 Gulf Research & Development Company Synthesis gas conversion using ruthenium-promoted cobalt catalyst
US4390639A (en) * 1981-12-21 1983-06-28 The Standard Oil Company Upgrading synthesis gas
US4496666A (en) * 1981-12-21 1985-01-29 The Standard Oil Company Upgrading synthesis gas
US4377643A (en) * 1981-12-21 1983-03-22 The Standard Oil Company Upgrading synthesis gas
US4444901A (en) * 1981-12-21 1984-04-24 The Standard Oil Company Catalyst for upgrading synthesis gas
US4478955A (en) * 1981-12-21 1984-10-23 The Standard Oil Company Upgrading synthesis gas
US4476247A (en) * 1981-12-21 1984-10-09 The Standard Oil Company Synthesis gas catalyst
US4477595A (en) * 1982-03-31 1984-10-16 Exxon Research And Engineering Co. Liquid hydrocarbon synthesis using supported ruthenium catalysts
GB2119277B (en) * 1982-05-03 1985-11-20 Air Prod & Chem Olefin synthesis catalysts
JPS5910527A (ja) * 1982-07-09 1984-01-20 Res Assoc Petroleum Alternat Dev<Rapad> 炭化水素類の製造法
DE3319254A1 (de) * 1983-05-27 1984-11-29 Bergwerksverband Gmbh, 4300 Essen Verfahren zur herstellung von katalysatoren fuer die erzeugung von ungesaettigten kohlenwasserstoffen aus kohlenmonoxid-wasserstoff-gemischen
DE3320388A1 (de) * 1983-06-06 1984-12-06 Süd-Chemie AG, 8000 München Katalysator zur selektiven hydrierung von mehrfach ungesaettigten organischen verbindungen
GB8334155D0 (en) * 1983-12-22 1984-02-01 Ici Plc Catalytic composition
US4748145A (en) * 1983-12-30 1988-05-31 The Dow Chemical Company Catalysts having alkoxide-modified supports and method of increasing the catalytic activity of a catalytic metal
US4559364A (en) * 1983-12-30 1985-12-17 The Dow Chemical Company Catalysts having alkoxide-modified supports
US4647592A (en) * 1984-01-05 1987-03-03 Exxon Research & Engineering Company Start-up with ruthenium catalysts
US4711871A (en) * 1984-06-29 1987-12-08 Exxon Research And Engineering Company Catalysts comprising ruthenium on titania surface modified with group Va oxide of vanadium, niobium or tantalum
US4670475A (en) * 1984-06-29 1987-06-02 Exxon Research And Engineering Company Improved cobalt catalysts, and use thereof for Fischer-Tropsch synthesis
US4861747A (en) * 1984-06-29 1989-08-29 Exxon Research And Engineering Company Catalysts comprising ruthenium on titania surface modified with group VA oxide of vanadium, niobium or tantalum
CA1250565A (en) * 1984-08-10 1989-02-28 Michael A. Richard Method for preparing dual colloid catalyst compositions
US4642302A (en) * 1984-09-28 1987-02-10 The Dow Chemical Company Catalysts having alkoxide-modified supports and method of increasing the catalytic activity of a catalytic metal
US4666881A (en) * 1985-05-31 1987-05-19 The Dow Chemical Company Methanation catalyst
US4609679A (en) * 1985-05-31 1986-09-02 The Dow Chemical Company Process for producing methane from hydrogen and carbon monoxide
JPS62109888A (ja) * 1985-11-06 1987-05-21 Res Assoc Petroleum Alternat Dev<Rapad> 炭化水素の製造法
US4714692A (en) * 1986-04-03 1987-12-22 Uop Inc. Microemulsion impregnated catalyst composite and use thereof in a synthesis gas conversion process
US4861802A (en) * 1988-02-17 1989-08-29 E. I. Du Pont De Nemours And Company Preparation of low molecular weight olefinic hydrocarbons using a perovskite catalyst
GB8814229D0 (en) * 1988-06-15 1988-07-20 Johnson Matthey Plc Improved catalyst
US5145876A (en) * 1988-06-15 1992-09-08 Johnson Matthey Public Limited Company Catalyst for use in a Fischer-Tropsch process
US4945116A (en) * 1988-12-29 1990-07-31 Uop Fischer-Tropsch synthesis process employing a moderated ruthenium catalyst
US5652193A (en) * 1989-03-29 1997-07-29 Exxon Research And Engineering Company Method for hydrocarbon synthesis reactions
DE19734974A1 (de) * 1997-08-13 1999-02-25 Hoechst Ag Verfahren zur Herstellung von porös geträgerten Metall-Nanopartikel-haltigen Katalysatoren, insbesondere für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat
US6169120B1 (en) 1999-09-17 2001-01-02 Syntroleum Corporation Extended catalyst life two stage hydrocarbon synthesis process
US6239184B1 (en) 1999-09-22 2001-05-29 Syntroleum Corporation Extended catalyst life Fischer-Tropsch process
US6331573B1 (en) 2000-02-29 2001-12-18 Chevron U.S.A. Inc. Increased liquid sensitivity during fischer-tropsch synthesis by olefin incorporation
US6392109B1 (en) 2000-02-29 2002-05-21 Chevron U.S.A. Inc. Synthesis of alkybenzenes and synlubes from Fischer-Tropsch products
US6369286B1 (en) 2000-03-02 2002-04-09 Chevron U.S.A. Inc. Conversion of syngas from Fischer-Tropsch products via olefin metathesis
EP1276829A2 (en) 2000-04-03 2003-01-22 Chevron U.S.A. Inc. Improved conversion of syngas to distillate fuels
US6455595B1 (en) 2000-07-24 2002-09-24 Chevron U.S.A. Inc. Methods for optimizing fischer-tropsch synthesis
US6472441B1 (en) 2000-07-24 2002-10-29 Chevron U.S.A. Inc. Methods for optimizing Fischer-Tropsch synthesis of hydrocarbons in the distillate fuel and/or lube base oil ranges
US6908543B1 (en) 2000-10-23 2005-06-21 Chevron U.S.A. Inc. Method for retarding fouling of feed heaters in refinery processing
US7452844B2 (en) * 2001-05-08 2008-11-18 Süd-Chemie Inc High surface area, small crystallite size catalyst for Fischer-Tropsch synthesis
FR2826596B1 (fr) * 2001-06-28 2004-08-13 Toulouse Inst Nat Polytech Compositon catalytique pour la fabrication selective de nanotubes de carbone ordonne en lit fluidise, et son procede de fabrication
AU2003248772A1 (en) * 2002-06-28 2004-01-19 Conocophillips Company Oxidized metal catalysts and process for producing synthesis gas
US7045554B2 (en) * 2003-09-03 2006-05-16 Conocophillips Company Method for improved Fischer-Tropsch catalyst stability and higher stable syngas conversion
US8445550B2 (en) * 2010-11-23 2013-05-21 Chevron U.S.A. Inc. Ruthenium hybrid fischer-tropsch catalyst, and methods for preparation and use thereof
CN102477020A (zh) * 2010-11-29 2012-05-30 中国科学院大连化学物理研究所 一种催化碳水化合物制备5-羟甲基糠醛的方法
CN114570360B (zh) * 2022-03-18 2023-12-08 中国科学院上海高等研究院 一种Ru基催化剂及其制备方法、应用
CN117904673B (zh) * 2024-03-19 2024-05-24 四川大学 一种电催化剂及其制备和应用

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US2553398A (en) * 1946-02-07 1951-05-15 Texas Co Method of effecting catalytic conversion
US2616914A (en) * 1946-05-11 1952-11-04 Hydrocarbon Research Inc Process for catalytic conversion
US2583611A (en) * 1946-07-13 1952-01-29 Hydrocarbon Research Inc Method for the synthesis of hydrocarbons in the presence of a solid adsorbent
AU7576774A (en) * 1973-12-14 1976-05-27 Exxon Research Engineering Co Catalytic formation of hydrocarbons from co, h2 mixtures
US4042614A (en) * 1976-04-05 1977-08-16 Exxon Research And Engineering Co. Hydrocarbon synthesis from CO and H2 using Ru supported on a titanium oxide
DE2712909A1 (de) * 1976-04-05 1977-10-13 Exxon Research Engineering Co Verfahren zur synthese von kohlenwasserstoffen

Also Published As

Publication number Publication date
CA1089496A (en) 1980-11-11
JPS5470205A (en) 1979-06-05
AU4081078A (en) 1980-04-24
US4171320A (en) 1979-10-16
FR2406618A1 (fr) 1979-05-18
GB2006261B (en) 1982-03-17
FR2406618B1 (xx) 1984-02-03
AU526136B2 (en) 1982-12-16
GB2006261A (en) 1979-05-02
DE2845294A1 (de) 1979-04-26

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