ZA200703065B - A foamed isocyanate-based polymer, a mix and process for production thereof - Google Patents
A foamed isocyanate-based polymer, a mix and process for production thereof Download PDFInfo
- Publication number
- ZA200703065B ZA200703065B ZA200703065A ZA200703065A ZA200703065B ZA 200703065 B ZA200703065 B ZA 200703065B ZA 200703065 A ZA200703065 A ZA 200703065A ZA 200703065 A ZA200703065 A ZA 200703065A ZA 200703065 B ZA200703065 B ZA 200703065B
- Authority
- ZA
- South Africa
- Prior art keywords
- isocyanate
- based polymer
- polysaccharide
- derivatized
- polyether polyol
- Prior art date
Links
- 239000012948 isocyanate Substances 0.000 title claims description 207
- 150000002513 isocyanates Chemical class 0.000 title claims description 200
- 229920000642 polymer Polymers 0.000 title claims description 134
- 238000000034 method Methods 0.000 title claims description 99
- 238000004519 manufacturing process Methods 0.000 title claims description 16
- 150000004676 glycans Chemical class 0.000 claims description 196
- 150000003077 polyols Chemical class 0.000 claims description 195
- 229920001282 polysaccharide Polymers 0.000 claims description 195
- 239000005017 polysaccharide Substances 0.000 claims description 195
- 229920005862 polyol Polymers 0.000 claims description 194
- 239000000203 mixture Substances 0.000 claims description 160
- 229920000570 polyether Polymers 0.000 claims description 84
- 239000006260 foam Substances 0.000 claims description 83
- DLRVVLDZNNYCBX-UHFFFAOYSA-N Polydextrose Polymers OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(O)O1 DLRVVLDZNNYCBX-UHFFFAOYSA-N 0.000 claims description 82
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 82
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 70
- 239000011541 reaction mixture Substances 0.000 claims description 48
- 239000004604 Blowing Agent Substances 0.000 claims description 41
- 150000001875 compounds Chemical class 0.000 claims description 40
- 229920001100 Polydextrose Polymers 0.000 claims description 39
- 239000001259 polydextrose Substances 0.000 claims description 39
- 235000013856 polydextrose Nutrition 0.000 claims description 39
- 229940035035 polydextrose Drugs 0.000 claims description 39
- 229920001577 copolymer Polymers 0.000 claims description 37
- 229910052739 hydrogen Inorganic materials 0.000 claims description 33
- 239000001257 hydrogen Substances 0.000 claims description 31
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 30
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Chemical group OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 27
- 239000007788 liquid Substances 0.000 claims description 26
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 25
- -1 polymethylene Polymers 0.000 claims description 25
- 239000003054 catalyst Substances 0.000 claims description 24
- 239000004094 surface-active agent Substances 0.000 claims description 24
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 22
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 21
- 238000006243 chemical reaction Methods 0.000 claims description 19
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 15
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 14
- 238000007373 indentation Methods 0.000 claims description 14
- 229920001451 polypropylene glycol Polymers 0.000 claims description 14
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 13
- 239000000194 fatty acid Substances 0.000 claims description 12
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 claims description 12
- 229920005830 Polyurethane Foam Polymers 0.000 claims description 11
- 239000011496 polyurethane foam Substances 0.000 claims description 11
- 239000000654 additive Substances 0.000 claims description 10
- 150000004665 fatty acids Chemical class 0.000 claims description 10
- 230000009975 flexible effect Effects 0.000 claims description 10
- 239000003431 cross linking reagent Substances 0.000 claims description 9
- 229920000768 polyamine Polymers 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 8
- 229930195729 fatty acid Natural products 0.000 claims description 8
- 150000002894 organic compounds Chemical class 0.000 claims description 8
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 claims description 7
- 239000001569 carbon dioxide Substances 0.000 claims description 7
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 7
- 150000001735 carboxylic acids Chemical class 0.000 claims description 7
- 125000005442 diisocyanate group Chemical group 0.000 claims description 7
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 6
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- VZDIRINETBAVAV-UHFFFAOYSA-N 2,4-diisocyanato-1-methylcyclohexane Chemical compound CC1CCC(N=C=O)CC1N=C=O VZDIRINETBAVAV-UHFFFAOYSA-N 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 5
- 239000005056 polyisocyanate Substances 0.000 claims description 5
- 229920001228 polyisocyanate Polymers 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 150000003512 tertiary amines Chemical class 0.000 claims description 4
- MTZUIIAIAKMWLI-UHFFFAOYSA-N 1,2-diisocyanatobenzene Chemical class O=C=NC1=CC=CC=C1N=C=O MTZUIIAIAKMWLI-UHFFFAOYSA-N 0.000 claims description 3
- VGHSXKTVMPXHNG-UHFFFAOYSA-N 1,3-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC(N=C=O)=C1 VGHSXKTVMPXHNG-UHFFFAOYSA-N 0.000 claims description 3
- OHLKMGYGBHFODF-UHFFFAOYSA-N 1,4-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=C(CN=C=O)C=C1 OHLKMGYGBHFODF-UHFFFAOYSA-N 0.000 claims description 3
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 claims description 3
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 claims description 3
- FWWWRCRHNMOYQY-UHFFFAOYSA-N 1,5-diisocyanato-2,4-dimethylbenzene Chemical compound CC1=CC(C)=C(N=C=O)C=C1N=C=O FWWWRCRHNMOYQY-UHFFFAOYSA-N 0.000 claims description 3
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 claims description 3
- DKJBREHOVWISMR-UHFFFAOYSA-N 1-chloro-2,3-diisocyanatobenzene Chemical class ClC1=CC=CC(N=C=O)=C1N=C=O DKJBREHOVWISMR-UHFFFAOYSA-N 0.000 claims description 3
- ICLCCFKUSALICQ-UHFFFAOYSA-N 1-isocyanato-4-(4-isocyanato-3-methylphenyl)-2-methylbenzene Chemical compound C1=C(N=C=O)C(C)=CC(C=2C=C(C)C(N=C=O)=CC=2)=C1 ICLCCFKUSALICQ-UHFFFAOYSA-N 0.000 claims description 3
- DTZHXCBUWSTOPO-UHFFFAOYSA-N 1-isocyanato-4-[(4-isocyanato-3-methylphenyl)methyl]-2-methylbenzene Chemical compound C1=C(N=C=O)C(C)=CC(CC=2C=C(C)C(N=C=O)=CC=2)=C1 DTZHXCBUWSTOPO-UHFFFAOYSA-N 0.000 claims description 3
- VOUDXMXYROJCKN-UHFFFAOYSA-N 2,4-diisocyanato-1,3,5-triazine Chemical compound O=C=NC1=NC=NC(N=C=O)=N1 VOUDXMXYROJCKN-UHFFFAOYSA-N 0.000 claims description 3
- QZWKEPYTBWZJJA-UHFFFAOYSA-N 3,3'-Dimethoxybenzidine-4,4'-diisocyanate Chemical compound C1=C(N=C=O)C(OC)=CC(C=2C=C(OC)C(N=C=O)=CC=2)=C1 QZWKEPYTBWZJJA-UHFFFAOYSA-N 0.000 claims description 3
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 3
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Substances ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000004806 packaging method and process Methods 0.000 claims description 2
- 238000009877 rendering Methods 0.000 claims 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 2
- 229920006389 polyphenyl polymer Polymers 0.000 claims 2
- NPURPEXKKDAKIH-UHFFFAOYSA-N iodoimino(oxo)methane Chemical compound IN=C=O NPURPEXKKDAKIH-UHFFFAOYSA-N 0.000 claims 1
- 150000004804 polysaccharides Polymers 0.000 claims 1
- 125000005628 tolylene group Chemical group 0.000 claims 1
- 239000000047 product Substances 0.000 description 33
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- 238000009472 formulation Methods 0.000 description 17
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- 239000004814 polyurethane Substances 0.000 description 17
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 15
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- 239000008103 glucose Substances 0.000 description 13
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- 239000000945 filler Substances 0.000 description 12
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- 150000003254 radicals Chemical class 0.000 description 7
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 6
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 5
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Classifications
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/40—High-molecular-weight compounds
- C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
- C08G18/6484—Polysaccharides and derivatives thereof
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
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- C08B37/0009—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid alpha-D-Glucans, e.g. polydextrose, alternan, glycogen; (alpha-1,4)(alpha-1,6)-D-Glucans; (alpha-1,3)(alpha-1,4)-D-Glucans, e.g. isolichenan or nigeran; (alpha-1,4)-D-Glucans; (alpha-1,3)-D-Glucans, e.g. pseudonigeran; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4081—Mixtures of compounds of group C08G18/64 with other macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
- C08G18/632—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyethers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/82—Post-polymerisation treatment
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Biochemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US61895804P | 2004-10-15 | 2004-10-15 |
Publications (1)
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ZA200703065B true ZA200703065B (en) | 2008-06-25 |
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ZA200703065A ZA200703065B (en) | 2004-10-15 | 2007-04-13 | A foamed isocyanate-based polymer, a mix and process for production thereof |
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US (1) | US20060122286A1 (ja) |
EP (1) | EP1817357A1 (ja) |
JP (1) | JP2008517086A (ja) |
KR (1) | KR20070100879A (ja) |
CN (1) | CN101080430A (ja) |
AU (1) | AU2005293571A1 (ja) |
CA (1) | CA2584201C (ja) |
MY (1) | MY141043A (ja) |
TW (1) | TW200621825A (ja) |
WO (1) | WO2006040333A1 (ja) |
ZA (1) | ZA200703065B (ja) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9284401B2 (en) * | 2006-11-13 | 2016-03-15 | Bayer Materialscience Llc | Process for the preparation of polyether-ester polyols |
JP2010512439A (ja) * | 2006-12-11 | 2010-04-22 | ビーエーエスエフ ソシエタス・ヨーロピア | 高弾性ポリウレタンフォーム |
DE102007039501A1 (de) * | 2007-08-21 | 2009-02-26 | Evonik Röhm Gmbh | Neues polymerisierbares Isocyanat und Polymere, enthaltend dieses Isocyanat |
JP5170421B2 (ja) * | 2008-06-27 | 2013-03-27 | 三菱瓦斯化学株式会社 | 水発泡硬質ポリウレタンフォームの製造方法 |
US8735460B2 (en) * | 2009-01-09 | 2014-05-27 | DuPont Nutrition BioScience ApS | Foamed isocyanate-based polymer, a mix and process for production thereof |
CN102341420B (zh) * | 2009-01-12 | 2014-03-19 | 巴斯夫欧洲公司 | 高弹性柔性聚氨酯泡沫体 |
KR20140007822A (ko) | 2010-12-20 | 2014-01-20 | 바이엘 인텔렉쳐 프로퍼티 게엠베하 | 폴리에테르 에스테르 폴리올의 제조 방법 |
CN103797039A (zh) * | 2011-07-19 | 2014-05-14 | 约翰逊控制技术公司 | 泡沫材料增强的结构构件 |
US10138392B2 (en) | 2013-03-29 | 2018-11-27 | The Chemours Company Fc, Llc | Non-fluorinated urethane based coatings |
US9260605B2 (en) | 2013-03-29 | 2016-02-16 | The Chemours Company Fc, Llc | Urethane based extenders for surface effect compositions |
EP3155164B1 (en) | 2014-06-12 | 2021-03-17 | The Chemours Company FC, LLC | Wax and urethane based extender blends for surface effect compositions |
US9938431B2 (en) | 2014-09-26 | 2018-04-10 | The Chemours Company Fc, Llc | Use of non-fluorinated or partially fluorinated urethanes in coatings |
US10138594B2 (en) | 2014-09-26 | 2018-11-27 | The Chemours Company Fc, Llc | Partially fluorinated urethane based coatings |
EP3197932A1 (en) | 2014-09-26 | 2017-08-02 | The Chemours Company FC, LLC | Non-fluorinated and partially fluorinated polymers |
WO2016048684A1 (en) | 2014-09-26 | 2016-03-31 | The Chemours Company Fc, Llc | Method of imparting water repellency with non-fluorinated laundry treatment compositions |
KR20220165837A (ko) | 2014-09-26 | 2022-12-15 | 더 케무어스 컴퍼니 에프씨, 엘엘씨 | 비-플루오르화 우레탄계 코팅 |
CN107001553B (zh) | 2014-09-26 | 2020-10-27 | 科慕埃弗西有限公司 | 磺化氟化、非氟化或部分氟化的氨基甲酸酯 |
WO2018000095A1 (en) * | 2016-06-29 | 2018-01-04 | Proprietect L.P. | Foamed isocyanate-based polymer |
KR102486203B1 (ko) * | 2016-07-22 | 2023-01-11 | 뉴트리션 앤드 바이오사이언시스 유에스에이 4, 인크. | 다당류를 포함하는 폴리우레탄 중합체 |
CN107814897A (zh) * | 2017-10-24 | 2018-03-20 | 合肥华凌股份有限公司 | 聚氨酯泡沫组合物、聚氨酯泡沫、制备聚氨酯泡沫的方法以及制冷设备 |
CN110283352A (zh) * | 2019-05-29 | 2019-09-27 | 佳化化学科技发展(上海)有限公司 | 一种聚氨酯软泡海绵及其制备方法 |
WO2024208715A1 (en) | 2023-04-05 | 2024-10-10 | Basf Se | Uv light stabilizers |
Family Cites Families (74)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2436967A (en) * | 1942-04-01 | 1948-03-02 | Corn Prod Refining Co | Polymerization of sugars |
US2461139A (en) * | 1945-01-08 | 1949-02-08 | Nat Starch Products Inc | Starch ester derivatives and method of making same |
US2719179A (en) * | 1951-01-25 | 1955-09-27 | Mora Peter Tibor | Branched-chain carbohydrate polymers and their preparation |
US3318868A (en) * | 1965-06-21 | 1967-05-09 | Nat Starch Chem Corp | Process for the continuous acylation of amylose |
US3766165A (en) * | 1966-08-17 | 1973-10-16 | Pfizer | Polysaccharides and their preparation |
US4035235A (en) * | 1973-03-12 | 1977-07-12 | Anheuser-Busch, Incorporated | Method of making lipophilic starch derivatives |
US3932532A (en) * | 1973-06-01 | 1976-01-13 | Ici United States Inc. | Ethers of polyglycerol |
US3956202A (en) | 1973-11-14 | 1976-05-11 | Kohkoku Chemical Industry Co. Ltd. | Process for preparing low smoke-generating rigid polyurethane foam |
US3973049A (en) * | 1974-03-14 | 1976-08-03 | General Foods Corporation | Method of mixing flavors and fixed composition comprising derivatized synthetic polysaccharides |
US4086279A (en) * | 1975-02-07 | 1978-04-25 | Basf Wyandotte Corporation | Nonionic surfactants |
US4011389A (en) * | 1975-03-21 | 1977-03-08 | Basf Wyandotte Corporation | Glycoside polyethers |
US4197372A (en) | 1978-01-16 | 1980-04-08 | Krause Milling Company | Semi-flexible polyurethane foams containing amylaceous material and process for preparing same |
US4458034A (en) | 1978-05-12 | 1984-07-03 | Wm. T. Burnett & Co., Inc. | Flame retardant, char-forming, flexible polyurethane foams |
US4223129A (en) * | 1978-09-01 | 1980-09-16 | A. E. Staley Manufacturing Company | Continuous process for making alkyl aldosides from starch or other carbohydrates |
US4237182A (en) | 1978-11-02 | 1980-12-02 | W. R. Grace & Co. | Method of sealing interior mine surface with a fire retardant hydrophilic polyurethane foam and resulting product |
US4296213A (en) * | 1979-10-17 | 1981-10-20 | Texaco Inc. | Polyurethane foams using a polyurea polymer polyol |
USRE31757E (en) | 1980-06-25 | 1984-12-04 | Patrick J. Crehan | Composition and a method for controlling reaction pressures during the foaming process resulting in an easily flame retarded foam-in place insulation |
US4374209A (en) | 1980-10-01 | 1983-02-15 | Interchem International S.A. | Polymer-modified polyols useful in polyurethane manufacture |
DE3113387A1 (de) | 1981-04-02 | 1982-11-18 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von flammwidrigen harnstoff- und urethangruppen aufweisenden leichtschaumstoffen |
US4404295A (en) | 1981-05-13 | 1983-09-13 | Witco Chemical Corporation | Polyester resins for polyurethane foams |
US4400475A (en) | 1981-12-08 | 1983-08-23 | Patrick James Crehan | Polyurethane foams and processes for preparation |
US4417998A (en) | 1982-11-23 | 1983-11-29 | Patrick James Crehan | Polyurethane foams and processes for preparation |
US4518772A (en) * | 1983-06-23 | 1985-05-21 | The Proctor & Gamble Company | Synthesis of higher polyol fatty acid polyesters using high soap:polyol ratios |
US4517360A (en) * | 1983-06-23 | 1985-05-14 | The Procter & Gamble Company | Synthesis of higher polyol fatty acid polyesters using carbonate catalysts |
US4518778A (en) * | 1983-07-14 | 1985-05-21 | Texaco Inc. | Polymer polyols from alkylene oxide adducts of alkanolamines |
US4520139A (en) | 1984-07-26 | 1985-05-28 | Patrick James Crehan | Pectin and related carbohydrates for the preparation of polyurethane foams |
AT382381B (de) * | 1984-10-02 | 1987-02-25 | Oesterr Zuckerfab Evidenz | Verfahren zur herstellung neuer grenzfl|chenaktiver kohlenhydrat-derivate |
US4622233A (en) * | 1984-12-06 | 1986-11-11 | Pfizer Inc. | Preparation and use of a highly purified polydextrose |
ATE43612T1 (de) * | 1985-05-08 | 1989-06-15 | Akzo Nv | Verfahren zur herstellung eines esters von staerke und einer monocarbonsaeure und zusammensetzung auf basis von so hergestellter staerke. |
US4654375A (en) | 1986-04-03 | 1987-03-31 | Sealed Air Corporation | Fire-retardant polyurethane foam and method and resin for preparing the same |
US4948596A (en) * | 1987-04-29 | 1990-08-14 | Warner-Lambert Company | Method of purifying polydextrose and composition containing same |
US4950743A (en) * | 1987-07-29 | 1990-08-21 | Henkel Kommanditgesellschaft Auf Aktien | Process for preparation of alkylglycosides |
US4965354A (en) * | 1988-02-26 | 1990-10-23 | Taito Company, Ltd. | Process for producing a condensed polysaccharide |
US4956458A (en) * | 1988-05-13 | 1990-09-11 | Warner-Lambert Company | Purification of polydextrose by reverse osmosis |
US5667593A (en) * | 1989-01-26 | 1997-09-16 | Cultor Ltd. | Modified polydextrose and process therefor |
US5051500A (en) * | 1989-08-11 | 1991-09-24 | A. E. Staley Manufacturing Company | Method of preparing a randomly-bonded polysaccharide |
NL8902243A (nl) * | 1989-09-07 | 1991-04-02 | Suiker Unie | Laag-calorische polydextrose-derivaten. |
US5378491A (en) * | 1990-02-20 | 1995-01-03 | A. E. Staley Manufacturing Co. | Method of preparing a starch hydrolysate, an aqueous starch hydrolysate dispersion, method of preparing a food containing a starch hydrolysate, and a food formulation containing a starch hydrolysate |
US5091015A (en) * | 1990-05-22 | 1992-02-25 | Warner-Lambert Company | Polydextrose compositions |
KR0180015B1 (ko) * | 1990-09-11 | 1999-04-01 | 제이코버스 코넬리스 레이서 | 이지방 케톤 및 베타-케토에스테르의 양이 감소된 고도로 에스테르화된 폴리올 지방산 폴리에스테르의 개선된 제조방법 |
KR100226394B1 (ko) * | 1991-02-20 | 1999-10-15 | 디. 제이. 우드, 스피겔 알렌 제이 | 환원된 폴리덱스트로즈 |
SE9200564L (sv) * | 1992-02-26 | 1993-03-15 | Perstorp Ab | Dendritisk makromolekyl av polyestertyp, foerfarande foer framstaellning daerav samt anvaendning daerav |
FR2688800B1 (fr) * | 1992-03-19 | 1995-06-16 | Roquette Freres | Procede de preparation de polysaccharides peu digestibles, eventuellement hydrogenes. |
FR2697023B1 (fr) * | 1992-10-16 | 1994-12-30 | Roquette Freres | Polymère soluble hypocalorique du glucose et procédé de préparation de ce polymère . |
US5292778A (en) | 1992-11-20 | 1994-03-08 | Woodbridge Foam Corporation | Polymer-modified polyol dispersions and processes for production and use thereof |
US5360845A (en) * | 1992-12-23 | 1994-11-01 | National Starch And Chemical Investment Holding Corporation | Starch ester based hot melt adhesive |
AU691805B2 (en) * | 1993-04-07 | 1998-05-28 | Valtion Teknillinen Tutkimuskeskus | Applications and methods for the preparation of fatty acid esters of polysaccharides |
FR2712891B1 (fr) * | 1993-11-22 | 1996-02-02 | Roquette Freres | Procédé de purification d'un polymère soluble hypocalorique du glucose et produit ainsi obtenu. |
US5585506A (en) * | 1994-07-22 | 1996-12-17 | Lonza Inc. | One phase production of polyglycerol esters |
FR2726829B1 (fr) * | 1994-11-10 | 1997-01-17 | Roquette Freres | Composition de polyols, son procede de preparation et ses applications |
US5681948A (en) * | 1995-03-06 | 1997-10-28 | Kraft Foods, Inc. | Two-stage method for preparing polyol fatty acid polyesters |
JP3019191B2 (ja) * | 1995-04-05 | 2000-03-13 | 千葉製粉株式会社 | 新規デキストリン脂肪酸エステル及びその用途 |
WO1997003120A1 (en) * | 1995-07-12 | 1997-01-30 | Valtion Teknillinen Tutkimuskeskus | Thermoplasticized starch component and process for the preparation thereof |
US5672699A (en) * | 1995-09-06 | 1997-09-30 | National Starch And Chemical Investment Holding Corporation | Process for preparation of hydrophobic starch derivatives |
US5767257A (en) * | 1996-07-19 | 1998-06-16 | The Procter & Gamble Company | Methods for producing polyol fatty acid polyesters using atmospheric or superatmospheric pressure |
CN1230963A (zh) * | 1996-08-08 | 1999-10-06 | 普罗克特和甘保尔公司 | 多元醇多酯的合成 |
FI107386B (fi) * | 1996-12-31 | 2001-07-31 | Valtion Teknillinen | Menetelmä tärkkelysesterien valmistamiseksi |
US6475552B1 (en) * | 1997-03-19 | 2002-11-05 | Danisco Finland Oy | Polymerization of mono and disaccharides using low levels of polycarboxylic acids |
DE19717968A1 (de) * | 1997-04-28 | 1998-10-29 | Henkel Kgaa | Verfahren zur Herstellung von Kohlenhydratpartialestern |
JP3051833B2 (ja) * | 1997-05-23 | 2000-06-12 | 花王株式会社 | アルキルグリコシドの製造方法 |
US5945519A (en) * | 1997-06-17 | 1999-08-31 | Th Goldschmidt Ag | Process for the preparation of sucrose fatty acid esters |
US5977348A (en) * | 1997-07-25 | 1999-11-02 | National Starch And Chemical Investment Holding Corporation | Polysaccharide modification in densified fluid |
US6121440A (en) * | 1998-01-29 | 2000-09-19 | The Procter & Gamble Company | Process for synthesis of polyol fatty acid polyesters |
JP2939586B1 (ja) * | 1998-11-25 | 1999-08-25 | 日本コーンスターチ株式会社 | 澱粉エステル |
US6037466A (en) * | 1998-12-31 | 2000-03-14 | National Starch And Chemical Investment Holding Corporation | Method for preparing hydrophobic starch derivatives |
US6100391A (en) * | 1999-01-04 | 2000-08-08 | Henkel Corporation | Method for making an alkyl glycoside |
US6620952B1 (en) * | 1999-01-28 | 2003-09-16 | The Procter & Gamble Co. | Synthesis of polyol fatty acid polyesters |
US6204369B1 (en) * | 1999-06-08 | 2001-03-20 | Henkel Corporation | Process for the preparation of alykl polyglycosides |
JP4651786B2 (ja) * | 2000-07-21 | 2011-03-16 | フジカーボン株式会社 | バイオマス由来のポリオール及び生分解性ポリウレタン |
US6423756B1 (en) * | 2000-11-10 | 2002-07-23 | Crompton Corporation | Process to improve polyurethane foam performance |
US6458861B1 (en) * | 2001-01-18 | 2002-10-01 | Bayer Antwerp N.V. | Carbon dioxide blown low density, flexible microcellular elastomers suitable for preparing shoe components |
US6455512B1 (en) * | 2001-03-05 | 2002-09-24 | Tic Gums, Inc. | Water-soluble esterified hydrocolloids |
WO2002083739A2 (en) * | 2001-04-10 | 2002-10-24 | Danisco Usa, Inc. | Polymerization of mono and disaccharides with monocarboxylic acids and lactones |
US20030083394A1 (en) * | 2001-06-07 | 2003-05-01 | Clatty Jan L. | Polyurethane foams having improved heat sag and a process for their production |
-
2005
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- 2005-10-13 KR KR1020077011061A patent/KR20070100879A/ko not_active Application Discontinuation
- 2005-10-13 AU AU2005293571A patent/AU2005293571A1/en not_active Abandoned
- 2005-10-13 JP JP2007536174A patent/JP2008517086A/ja active Pending
- 2005-10-13 CA CA2584201A patent/CA2584201C/en not_active Expired - Fee Related
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- 2005-10-14 TW TW094136041A patent/TW200621825A/zh unknown
- 2005-10-14 US US11/251,190 patent/US20060122286A1/en not_active Abandoned
- 2005-10-14 MY MYPI20054857A patent/MY141043A/en unknown
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MY141043A (en) | 2010-02-25 |
EP1817357A1 (en) | 2007-08-15 |
AU2005293571A1 (en) | 2006-04-20 |
CA2584201A1 (en) | 2006-04-20 |
CA2584201C (en) | 2014-12-23 |
CN101080430A (zh) | 2007-11-28 |
US20060122286A1 (en) | 2006-06-08 |
TW200621825A (en) | 2006-07-01 |
JP2008517086A (ja) | 2008-05-22 |
KR20070100879A (ko) | 2007-10-12 |
WO2006040333A1 (en) | 2006-04-20 |
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