ZA200700217B - Calcium hypochlorite compositions - Google Patents
Calcium hypochlorite compositions Download PDFInfo
- Publication number
- ZA200700217B ZA200700217B ZA200700217A ZA200700217A ZA200700217B ZA 200700217 B ZA200700217 B ZA 200700217B ZA 200700217 A ZA200700217 A ZA 200700217A ZA 200700217 A ZA200700217 A ZA 200700217A ZA 200700217 B ZA200700217 B ZA 200700217B
- Authority
- ZA
- South Africa
- Prior art keywords
- calcium hypochlorite
- weight
- dodecahydrate
- hydrated
- magnesium sulfate
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 75
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 title claims description 69
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 35
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 29
- 239000000460 chlorine Substances 0.000 claims description 29
- 229910052801 chlorine Inorganic materials 0.000 claims description 29
- WRUGWIBCXHJTDG-UHFFFAOYSA-L magnesium sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Mg+2].[O-]S([O-])(=O)=O WRUGWIBCXHJTDG-UHFFFAOYSA-L 0.000 claims description 23
- 229940061634 magnesium sulfate heptahydrate Drugs 0.000 claims description 23
- ASTWEMOBIXQPPV-UHFFFAOYSA-K trisodium;phosphate;dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[Na+].[O-]P([O-])([O-])=O ASTWEMOBIXQPPV-UHFFFAOYSA-K 0.000 claims description 23
- 150000004687 hexahydrates Chemical class 0.000 claims description 18
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 18
- GNHOJBNSNUXZQA-UHFFFAOYSA-J potassium aluminium sulfate dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GNHOJBNSNUXZQA-UHFFFAOYSA-J 0.000 claims description 16
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 16
- CDMADVZSLOHIFP-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 CDMADVZSLOHIFP-UHFFFAOYSA-N 0.000 claims description 11
- 238000009472 formulation Methods 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 9
- QTNFHDKYXLWNOF-UHFFFAOYSA-K aluminum;potassium;phosphate;dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Al+3].[K+].[O-]P([O-])([O-])=O QTNFHDKYXLWNOF-UHFFFAOYSA-K 0.000 claims 2
- 230000003247 decreasing effect Effects 0.000 claims 1
- 239000000463 material Substances 0.000 description 25
- 238000006243 chemical reaction Methods 0.000 description 24
- 150000003839 salts Chemical class 0.000 description 17
- 239000012530 fluid Substances 0.000 description 12
- 238000012360 testing method Methods 0.000 description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 238000000354 decomposition reaction Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000008187 granular material Substances 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 6
- 229910021538 borax Inorganic materials 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 150000004677 hydrates Chemical class 0.000 description 5
- -1 oxide Chemical compound 0.000 description 5
- 238000011012 sanitization Methods 0.000 description 5
- 230000007704 transition Effects 0.000 description 5
- 235000019801 trisodium phosphate Nutrition 0.000 description 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 235000019504 cigarettes Nutrition 0.000 description 4
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 4
- 229910000397 disodium phosphate Inorganic materials 0.000 description 4
- 235000019800 disodium phosphate Nutrition 0.000 description 4
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000010791 quenching Methods 0.000 description 4
- 230000009257 reactivity Effects 0.000 description 4
- 239000004328 sodium tetraborate Substances 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 3
- 229910017053 inorganic salt Inorganic materials 0.000 description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 3
- 235000019341 magnesium sulphate Nutrition 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 239000011698 potassium fluoride Substances 0.000 description 3
- 235000003270 potassium fluoride Nutrition 0.000 description 3
- 238000010079 rubber tapping Methods 0.000 description 3
- 239000001488 sodium phosphate Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 235000017899 Spathodea campanulata Nutrition 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229940037003 alum Drugs 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 2
- 229910001863 barium hydroxide Inorganic materials 0.000 description 2
- KQHXBDOEECKORE-UHFFFAOYSA-L beryllium sulfate Chemical compound [Be+2].[O-]S([O-])(=O)=O KQHXBDOEECKORE-UHFFFAOYSA-L 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 150000001642 boronic acid derivatives Chemical class 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 239000000383 hazardous chemical Substances 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Chemical compound [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 description 2
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 2
- 229960002337 magnesium chloride Drugs 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002455 scale inhibitor Substances 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 229940048086 sodium pyrophosphate Drugs 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- PHIQPXBZDGYJOG-UHFFFAOYSA-N sodium silicate nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-][Si]([O-])=O PHIQPXBZDGYJOG-UHFFFAOYSA-N 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 description 2
- 229910001866 strontium hydroxide Inorganic materials 0.000 description 2
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Chemical compound [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 description 2
- 230000009182 swimming Effects 0.000 description 2
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- GHPYJLCQYMAXGG-WCCKRBBISA-N (2R)-2-amino-3-(2-boronoethylsulfanyl)propanoic acid hydrochloride Chemical compound Cl.N[C@@H](CSCCB(O)O)C(O)=O GHPYJLCQYMAXGG-WCCKRBBISA-N 0.000 description 1
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- SZHQPBJEOCHCKM-UHFFFAOYSA-N 2-phosphonobutane-1,2,4-tricarboxylic acid Chemical compound OC(=O)CCC(P(O)(O)=O)(C(O)=O)CC(O)=O SZHQPBJEOCHCKM-UHFFFAOYSA-N 0.000 description 1
- ZMYKITJYWFYRFJ-UHFFFAOYSA-N 4-oxo-4-(2-phenylethylamino)butanoic acid Chemical class OC(=O)CCC(=O)NCCC1=CC=CC=C1 ZMYKITJYWFYRFJ-UHFFFAOYSA-N 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- UNMYWSMUMWPJLR-UHFFFAOYSA-L Calcium iodide Chemical compound [Ca+2].[I-].[I-] UNMYWSMUMWPJLR-UHFFFAOYSA-L 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 239000001692 EU approved anti-caking agent Substances 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 208000013016 Hypoglycemia Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- OEAYUPMWQVSQSQ-UHFFFAOYSA-L O.O.O.O.O.O.P(=O)(O)([O-])[O-].[K+].[K+] Chemical compound O.O.O.O.O.O.P(=O)(O)([O-])[O-].[K+].[K+] OEAYUPMWQVSQSQ-UHFFFAOYSA-L 0.000 description 1
- DMHWOVJCMTWFMF-UHFFFAOYSA-N O.[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] Chemical class O.[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] DMHWOVJCMTWFMF-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241000036848 Porzana carolina Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000002353 algacidal effect Effects 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- QAFATHSWTJYDJP-UHFFFAOYSA-J aluminum;rubidium(1+);disulfate Chemical compound [Al+3].[Rb+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O QAFATHSWTJYDJP-UHFFFAOYSA-J 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 239000004067 bulking agent Substances 0.000 description 1
- 229910001622 calcium bromide Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- WGEFECGEFUFIQW-UHFFFAOYSA-L calcium dibromide Chemical compound [Ca+2].[Br-].[Br-] WGEFECGEFUFIQW-UHFFFAOYSA-L 0.000 description 1
- 229910001640 calcium iodide Inorganic materials 0.000 description 1
- 229940046413 calcium iodide Drugs 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000012691 depolymerization reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical class O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 231100000092 inhalation hazard Toxicity 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229940059936 lithium bromide Drugs 0.000 description 1
- PEXNRZDEKZDXPZ-UHFFFAOYSA-N lithium selenidolithium Chemical compound [Li][Se][Li] PEXNRZDEKZDXPZ-UHFFFAOYSA-N 0.000 description 1
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 description 1
- 229910001623 magnesium bromide Inorganic materials 0.000 description 1
- 229940050906 magnesium chloride hexahydrate Drugs 0.000 description 1
- DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 description 1
- LFCFXZHKDRJMNS-UHFFFAOYSA-L magnesium;sulfate;hydrate Chemical class O.[Mg+2].[O-]S([O-])(=O)=O LFCFXZHKDRJMNS-UHFFFAOYSA-L 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920001444 polymaleic acid Chemical class 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000003346 selenoethers Chemical class 0.000 description 1
- 229940096017 silver fluoride Drugs 0.000 description 1
- REYHXKZHIMGNSE-UHFFFAOYSA-M silver monofluoride Chemical compound [F-].[Ag+] REYHXKZHIMGNSE-UHFFFAOYSA-M 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- YJPVTCSBVRMESK-UHFFFAOYSA-L strontium bromide Chemical compound [Br-].[Br-].[Sr+2] YJPVTCSBVRMESK-UHFFFAOYSA-L 0.000 description 1
- 229910001625 strontium bromide Inorganic materials 0.000 description 1
- 229940074155 strontium bromide Drugs 0.000 description 1
- 229910001631 strontium chloride Inorganic materials 0.000 description 1
- AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 1
- KRIJWFBRWPCESA-UHFFFAOYSA-L strontium iodide Chemical compound [Sr+2].[I-].[I-] KRIJWFBRWPCESA-UHFFFAOYSA-L 0.000 description 1
- 229910001643 strontium iodide Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- YNIRKEZIDLCCMC-UHFFFAOYSA-K trisodium;phosphate;hydrate Chemical class [OH-].[Na+].[Na+].[Na+].OP([O-])([O-])=O YNIRKEZIDLCCMC-UHFFFAOYSA-K 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/04—Hypochlorous acid
- C01B11/06—Hypochlorites
- C01B11/064—Hypochlorites of alkaline-earth metals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/02—Inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Agronomy & Crop Science (AREA)
- Materials Engineering (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/872,202 US7045077B2 (en) | 2004-06-18 | 2004-06-18 | Calcium hypochlorite compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200700217B true ZA200700217B (en) | 2008-05-28 |
Family
ID=35479680
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200700217A ZA200700217B (en) | 2004-06-18 | 2004-07-09 | Calcium hypochlorite compositions |
Country Status (10)
| Country | Link |
|---|---|
| US (4) | US7045077B2 (de) |
| EP (1) | EP1781567B1 (de) |
| CN (2) | CN101048341B (de) |
| AU (1) | AU2004321724B2 (de) |
| CA (1) | CA2570980C (de) |
| ES (1) | ES2441207T3 (de) |
| HK (1) | HK1151787A1 (de) |
| NZ (1) | NZ552081A (de) |
| WO (1) | WO2006009554A1 (de) |
| ZA (1) | ZA200700217B (de) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6776926B2 (en) * | 2001-08-09 | 2004-08-17 | United States Filter Corporation | Calcium hypochlorite of reduced reactivity |
| CA2520857C (en) * | 2003-04-02 | 2011-09-20 | Arch Chemicals, Inc. | Calcium hypochlorite blended tablets |
| US6984398B2 (en) * | 2003-04-02 | 2006-01-10 | Arch Chemicals, Inc. | Calcium hypochlorite blended tablets |
| US7410938B2 (en) * | 2004-02-24 | 2008-08-12 | Arch Chemicals, Inc. | Calcium hypochlorite/scale inhibitor/residue disperser triblend |
| US7045077B2 (en) * | 2004-06-18 | 2006-05-16 | Biolab, Inc. | Calcium hypochlorite compositions |
| US7820198B2 (en) * | 2004-10-19 | 2010-10-26 | Arch Chemicals, Inc. | Pool chemical tablet |
| JP5318567B2 (ja) | 2005-05-12 | 2013-10-16 | ダウ グローバル テクノロジーズ エルエルシー | 光沢の少ない熱成形押出しシート材 |
| US8252200B2 (en) * | 2005-12-01 | 2012-08-28 | Arch Chemicals, Inc. | Coated calcium hypochlorite composition |
| US7431863B2 (en) * | 2006-03-08 | 2008-10-07 | Ppg Industries Ohio, Inc. | Calcium hypochlorite composition |
| US8492419B2 (en) * | 2006-04-26 | 2013-07-23 | Bromine Compounds Ltd. | Multifunctional solid formulations for water conditioning |
| US7625496B2 (en) * | 2006-11-03 | 2009-12-01 | Chemtura Corporation | Solid composition for treating water |
| US7927510B2 (en) * | 2007-04-20 | 2011-04-19 | Arch Chemicals, Inc. | Calcium hypochlorite compositions comprising zinc salts and lime |
| US8372291B2 (en) * | 2007-04-20 | 2013-02-12 | Arch Chemicals, Inc. | Calcium hypochlorite compositions comprising zinc salts and lime |
| SK287106B6 (sk) * | 2007-07-17 | 2009-12-07 | Imrich Bell�R | Roztok na zisťovanie ovulačného obdobia v skúmavke z moču u žien |
| DE102008017379B4 (de) * | 2008-04-05 | 2013-08-29 | Cealin Chemische Fabrik Gmbh | Wässrige Lösung zur Oxidation, Entkeimung und Desodorierung sowie Verfahren zur Herstellung dieser Lösung |
| US8257748B2 (en) * | 2009-09-01 | 2012-09-04 | Ppg Industries Ohio, Inc. | Calcium hypochlorite compositions |
| CA2787586C (en) * | 2010-01-21 | 2017-02-28 | The University Of South Dakota | Polymeric systems for delivering hypohalide salts |
| US20110256242A1 (en) * | 2010-04-16 | 2011-10-20 | Walls John E | Pool water sanitizer and method |
| US20120301555A1 (en) * | 2010-04-16 | 2012-11-29 | Walls John E | Pool Water Sanitizer And Method |
| GB201315098D0 (en) * | 2013-08-23 | 2013-10-09 | Sunamp Ltd | Strontium Bromide Phase Change Material |
| CN103947691B (zh) * | 2014-04-18 | 2016-04-27 | 安徽省中日农业环保科技有限公司 | 一种过氧化氢/聚硅硫酸铝复合蓝藻处理剂及其制作方法 |
| CN103936103B (zh) * | 2014-04-18 | 2015-02-25 | 芜湖凯奥尔环保科技有限公司 | 一种铝灰/硫磺复合蓝藻处理剂及其制作方法 |
| CN103936102B (zh) * | 2014-04-18 | 2015-03-25 | 芜湖凯奥尔环保科技有限公司 | 一种聚合铝/艾叶复合粉状蓝藻处理剂及其制作方法 |
| CN103936101B (zh) * | 2014-04-18 | 2015-02-25 | 芜湖凯奥尔环保科技有限公司 | 一种辣木铁氧石复合型蓝藻处理剂及其制作方法 |
| CN103947694B (zh) * | 2014-04-18 | 2016-04-13 | 安徽省中日农业环保科技有限公司 | 一种蓝藻抑制剂组合物及其制作方法 |
| GB2532070B (en) | 2014-11-07 | 2018-05-09 | Xanadox Tech Limited | Improvements relating to hypochlorous acid solutions |
| GB201816380D0 (en) * | 2018-10-08 | 2018-11-28 | Sunamp Ltd | Group II metal nitrate based compositions for use as phase change materials |
| USD875911S1 (en) | 2019-01-09 | 2020-02-18 | Paul V. Bennett, III | Liquid animal deterrent diffuser |
| WO2021062467A1 (en) * | 2019-09-30 | 2021-04-08 | Bonds Chemicals Pty Ltd | Hypochlorite compositions, methods of manufacture and uses thereof |
| JP2023513757A (ja) * | 2020-02-14 | 2023-04-03 | コリディオン，インコーポレイテッド | 洗浄、消毒、滅菌、および／または処置のための組成物、キット、方法、および使用 |
| CN111979534A (zh) * | 2020-07-14 | 2020-11-24 | 中国科学院海洋研究所 | 基于液滴自弹跳效应的超疏水表面的制备方法及应用 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3036013A (en) * | 1959-02-16 | 1962-05-22 | Olin Mathieson | Coated calcium hypochlorite and process for making same |
| US3560396A (en) * | 1967-07-28 | 1971-02-02 | Olin Corp | Calcium hypochlorite compositions containing spray-dried sodium nitrate |
| US3544267A (en) * | 1968-09-04 | 1970-12-01 | Pennwalt Corp | Calcium hypochlorite product and process for producing same |
| US3669894A (en) * | 1970-09-02 | 1972-06-13 | Olin Corp | Preparation of high test calcium hypochlorite |
| US3793216A (en) * | 1971-12-06 | 1974-02-19 | Pennwalt Corp | Calcium hypochlorite composition |
| US3895099A (en) * | 1972-05-30 | 1975-07-15 | Olin Corp | Process for manufacture of calcium hydrochlorite |
| US4053429A (en) * | 1973-10-27 | 1977-10-11 | Nippon Soda Company, Limited | Safety-calcium hypochlorite composition |
| US4048351A (en) * | 1974-11-06 | 1977-09-13 | Olin Corporation | Granular calcium hypochlorite coated with a low melting inorganic salt by spray graining |
| US4146676A (en) * | 1975-03-12 | 1979-03-27 | Olin Corporation | Granular calcium hypochlorite coated with a low melting inorganic salt by spray graining |
| AU536179B2 (en) * | 1979-05-29 | 1984-04-19 | Toyo Soda Manufacturing Co. Ltd. | Calcium hypochlorite |
| US4747978A (en) * | 1986-08-07 | 1988-05-31 | Ppg Industries, Inc. | Calcium hypochlorite compositions |
| JPH01122903A (ja) * | 1987-11-06 | 1989-05-16 | Tosoh Corp | 次亜塩素酸カルシウム粒状物およびその製造方法 |
| US4973419A (en) * | 1988-12-30 | 1990-11-27 | Lever Brothers Company, Division Of Conopco, Inc. | Hydrated alkali metal phosphate and silicated salt compositions |
| KR0152969B1 (ko) * | 1989-05-18 | 1998-10-15 | 브루스 이. 버딕 | 개선된 차아염소산칼슘 생성물 |
| US5112521A (en) * | 1989-10-10 | 1992-05-12 | Olin Corporation | Calcium hypochlorite compositions containing phosphonobutane polycarboxylic acid salts |
| US5676844A (en) * | 1996-02-28 | 1997-10-14 | Girvan; Don H. | Method of treating water |
| DK0969964T4 (da) | 1997-09-04 | 2011-05-09 | Claude Q C Hayes | Varmekontrolanordning |
| WO1999061376A1 (en) | 1998-05-22 | 1999-12-02 | Ppg Industries Ohio, Inc. | Calcium hypochlorite composition |
| US6638446B1 (en) * | 2002-10-15 | 2003-10-28 | Arch Chemicals, Inc. | Lower reactivity blends of calcium hypochlorite and magnesium sulfate |
| CA2520857C (en) * | 2003-04-02 | 2011-09-20 | Arch Chemicals, Inc. | Calcium hypochlorite blended tablets |
| US6984398B2 (en) * | 2003-04-02 | 2006-01-10 | Arch Chemicals, Inc. | Calcium hypochlorite blended tablets |
| US7045077B2 (en) * | 2004-06-18 | 2006-05-16 | Biolab, Inc. | Calcium hypochlorite compositions |
| US8252200B2 (en) * | 2005-12-01 | 2012-08-28 | Arch Chemicals, Inc. | Coated calcium hypochlorite composition |
-
2004
- 2004-06-18 US US10/872,202 patent/US7045077B2/en active Active
- 2004-07-09 EP EP04777735.4A patent/EP1781567B1/de active Active
- 2004-07-09 ES ES04777735.4T patent/ES2441207T3/es active Active
- 2004-07-09 NZ NZ552081A patent/NZ552081A/en unknown
- 2004-07-09 WO PCT/US2004/021838 patent/WO2006009554A1/en active Application Filing
- 2004-07-09 CA CA2570980A patent/CA2570980C/en active Active
- 2004-07-09 CN CN2004800433642A patent/CN101048341B/zh not_active Expired - Fee Related
- 2004-07-09 CN CN2010101112542A patent/CN101913567B/zh not_active Expired - Fee Related
- 2004-07-09 AU AU2004321724A patent/AU2004321724B2/en active Active
- 2004-07-09 ZA ZA200700217A patent/ZA200700217B/en unknown
-
2006
- 2006-01-27 US US11/341,548 patent/US20060128584A1/en not_active Abandoned
-
2007
- 2007-06-04 US US11/757,722 patent/US7364669B2/en active Active
-
2008
- 2008-03-17 US US12/049,913 patent/US7695639B2/en active Active
-
2011
- 2011-06-10 HK HK11105897.0A patent/HK1151787A1/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2006009554A1 (en) | 2006-01-26 |
| CA2570980A1 (en) | 2006-01-26 |
| US7364669B2 (en) | 2008-04-29 |
| US20050279971A1 (en) | 2005-12-22 |
| US20070224108A1 (en) | 2007-09-27 |
| US20090008603A1 (en) | 2009-01-08 |
| CN101048341A (zh) | 2007-10-03 |
| US20060128584A1 (en) | 2006-06-15 |
| EP1781567B1 (de) | 2013-10-02 |
| CN101048341B (zh) | 2010-04-28 |
| EP1781567A1 (de) | 2007-05-09 |
| AU2004321724B2 (en) | 2010-09-02 |
| US7045077B2 (en) | 2006-05-16 |
| CN101913567B (zh) | 2012-04-25 |
| EP1781567A4 (de) | 2011-06-22 |
| NZ552081A (en) | 2009-11-27 |
| CA2570980C (en) | 2014-01-28 |
| HK1151787A1 (en) | 2012-02-10 |
| US7695639B2 (en) | 2010-04-13 |
| CN101913567A (zh) | 2010-12-15 |
| ES2441207T3 (es) | 2014-02-03 |
| AU2004321724A1 (en) | 2006-01-26 |
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