ZA200603283B - The use of a source of chromium with a precipitated catalyst in a fischer-tropsch reaction - Google Patents
The use of a source of chromium with a precipitated catalyst in a fischer-tropsch reaction Download PDFInfo
- Publication number
- ZA200603283B ZA200603283B ZA200603283A ZA200603283A ZA200603283B ZA 200603283 B ZA200603283 B ZA 200603283B ZA 200603283 A ZA200603283 A ZA 200603283A ZA 200603283 A ZA200603283 A ZA 200603283A ZA 200603283 B ZA200603283 B ZA 200603283B
- Authority
- ZA
- South Africa
- Prior art keywords
- catalyst
- iron
- fischer
- chromium
- precipitated
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims description 58
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 title claims description 15
- 239000011651 chromium Substances 0.000 title claims description 15
- 229910052804 chromium Inorganic materials 0.000 title claims description 15
- 238000006243 chemical reaction Methods 0.000 title claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 93
- 238000000034 method Methods 0.000 claims description 48
- 229910052742 iron Inorganic materials 0.000 claims description 44
- 229930195733 hydrocarbon Natural products 0.000 claims description 14
- 150000002430 hydrocarbons Chemical class 0.000 claims description 14
- 239000012071 phase Substances 0.000 claims description 9
- 239000000376 reactant Substances 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 4
- 238000001556 precipitation Methods 0.000 claims 3
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims 2
- 230000003247 decreasing effect Effects 0.000 claims 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical group O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims 2
- 230000000694 effects Effects 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 claims 2
- 150000007524 organic acids Chemical class 0.000 claims 2
- 230000001376 precipitating effect Effects 0.000 claims 2
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 239000007790 solid phase Substances 0.000 claims 1
- 239000000047 product Substances 0.000 description 13
- 239000012535 impurity Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/862—Iron and chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/612—Surface area less than 10 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/009—Preparation by separation, e.g. by filtration, decantation, screening
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ZA200603283A ZA200603283B (en) | 2003-11-20 | 2006-04-25 | The use of a source of chromium with a precipitated catalyst in a fischer-tropsch reaction |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ZA200309038 | 2003-11-20 | ||
| ZA200603283A ZA200603283B (en) | 2003-11-20 | 2006-04-25 | The use of a source of chromium with a precipitated catalyst in a fischer-tropsch reaction |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200603283B true ZA200603283B (en) | 2007-10-31 |
Family
ID=34620871
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200603283A ZA200603283B (en) | 2003-11-20 | 2006-04-25 | The use of a source of chromium with a precipitated catalyst in a fischer-tropsch reaction |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7598295B2 (zh) |
| CN (1) | CN101278032A (zh) |
| AU (1) | AU2004291739B2 (zh) |
| CA (1) | CA2546011A1 (zh) |
| RU (1) | RU2392296C2 (zh) |
| UA (1) | UA93346C2 (zh) |
| WO (1) | WO2005049765A1 (zh) |
| ZA (1) | ZA200603283B (zh) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10086365B2 (en) * | 2007-08-30 | 2018-10-02 | Res Usa, Llc | Strengthened iron catalyst for slurry reactors |
| WO2010101636A2 (en) * | 2009-03-02 | 2010-09-10 | Sud-Chemie Inc. | Promoted zirconium oxide catalyst support |
| WO2014209664A1 (en) | 2013-06-27 | 2014-12-31 | Clariant Corporation | Manganese oxide-stabilized zirconia catalyst support materials |
| JP2023176739A (ja) * | 2022-05-31 | 2023-12-13 | Ykk株式会社 | 炭化水素合成触媒及びその製造方法、並びに炭化水素の合成方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB473932A (en) * | 1935-11-30 | 1937-10-22 | Ig Farbenindustrie Ag | Improvements in the manufacture and production of valuable hydrocarbons and their derivatives containing oxygen from carbon monoxide and hydrogen |
| GB631457A (en) | 1946-08-06 | 1949-11-03 | Standard Oil Dev Co | An improved process for the catalytic synthesis of hydrocarbons |
| US4139550A (en) * | 1976-09-10 | 1979-02-13 | Suntech, Inc. | Aromatics from synthesis gas |
| US4290924A (en) * | 1979-06-04 | 1981-09-22 | Conoco, Inc. | Catalyst composition useful for preparing 2,6-xylenol |
| US4436834A (en) * | 1981-09-03 | 1984-03-13 | Exxon Research And Engineering Co. | Iron-thallium catalysts for use in CO hydrogenation and process of preparing the catalysts |
| US4686313A (en) * | 1984-12-31 | 1987-08-11 | Mobil Oil Corporation | Low nitrogen iron-containing Fischer-Tropsch catalyst and conversion of synthesis gas therewith |
| US6756411B2 (en) * | 1995-06-29 | 2004-06-29 | Sasol Technology (Proprietary) Limited | Process for producing oxygenated products |
| US20040106517A1 (en) * | 2000-05-23 | 2004-06-03 | Dlamini Thulani Humphrey | Chemicals from synthesis gas |
| WO2003087265A1 (en) * | 2002-04-16 | 2003-10-23 | Sasol Technology (Proprietary) Limited | Hydrocarbon synthesis process using an alkali promoted iron catalyst |
| EP1658354B1 (en) * | 2003-08-22 | 2008-12-17 | Sasol Technology (Proprietary) Limited | Process for synthesising hydrocarbons |
-
2004
- 2004-11-18 WO PCT/IB2004/052471 patent/WO2005049765A1/en active Application Filing
- 2004-11-18 CN CNA2004800342179A patent/CN101278032A/zh active Pending
- 2004-11-18 RU RU2006117098/04A patent/RU2392296C2/ru not_active IP Right Cessation
- 2004-11-18 AU AU2004291739A patent/AU2004291739B2/en not_active Ceased
- 2004-11-18 CA CA002546011A patent/CA2546011A1/en not_active Abandoned
- 2004-11-18 UA UAA200605717A patent/UA93346C2/ru unknown
- 2004-11-18 US US10/580,022 patent/US7598295B2/en not_active Expired - Fee Related
-
2006
- 2006-04-25 ZA ZA200603283A patent/ZA200603283B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US7598295B2 (en) | 2009-10-06 |
| RU2392296C2 (ru) | 2010-06-20 |
| US20070191498A1 (en) | 2007-08-16 |
| AU2004291739A1 (en) | 2005-06-02 |
| UA93346C2 (ru) | 2011-02-10 |
| CN101278032A (zh) | 2008-10-01 |
| RU2006117098A (ru) | 2007-12-10 |
| CA2546011A1 (en) | 2005-06-02 |
| AU2004291739B2 (en) | 2010-02-11 |
| WO2005049765A1 (en) | 2005-06-02 |
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