ZA200505106B - Process for the preparation of linear alpha-olefins from synthesis gas over a cobalt catalyst - Google Patents
Process for the preparation of linear alpha-olefins from synthesis gas over a cobalt catalyst Download PDFInfo
- Publication number
- ZA200505106B ZA200505106B ZA200505106A ZA200505106A ZA200505106B ZA 200505106 B ZA200505106 B ZA 200505106B ZA 200505106 A ZA200505106 A ZA 200505106A ZA 200505106 A ZA200505106 A ZA 200505106A ZA 200505106 B ZA200505106 B ZA 200505106B
- Authority
- ZA
- South Africa
- Prior art keywords
- reactor
- synthesis
- linear alpha
- gas
- hydrocarbon
- Prior art date
Links
- 238000003786 synthesis reaction Methods 0.000 title claims description 252
- 230000015572 biosynthetic process Effects 0.000 title claims description 245
- 239000004711 α-olefin Substances 0.000 title claims description 178
- 238000000034 method Methods 0.000 title claims description 111
- 239000003054 catalyst Substances 0.000 title claims description 87
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims description 48
- 229910017052 cobalt Inorganic materials 0.000 title claims description 46
- 239000010941 cobalt Substances 0.000 title claims description 46
- 238000002360 preparation method Methods 0.000 title description 4
- 239000007789 gas Substances 0.000 claims description 187
- 229930195733 hydrocarbon Natural products 0.000 claims description 183
- 150000002430 hydrocarbons Chemical class 0.000 claims description 183
- 239000004215 Carbon black (E152) Substances 0.000 claims description 124
- 238000006243 chemical reaction Methods 0.000 claims description 84
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 46
- 229910052739 hydrogen Inorganic materials 0.000 claims description 41
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 230000036961 partial effect Effects 0.000 claims description 22
- 239000001257 hydrogen Substances 0.000 claims description 21
- 239000003345 natural gas Substances 0.000 claims description 19
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 16
- 230000003197 catalytic effect Effects 0.000 claims description 16
- 239000000314 lubricant Substances 0.000 claims description 16
- 239000000446 fuel Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 11
- 230000002829 reductive effect Effects 0.000 claims description 9
- 238000009835 boiling Methods 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 230000002194 synthesizing effect Effects 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 description 24
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 19
- 238000002474 experimental method Methods 0.000 description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 11
- 229910052760 oxygen Inorganic materials 0.000 description 11
- 238000000926 separation method Methods 0.000 description 11
- 150000001336 alkenes Chemical class 0.000 description 10
- 239000002002 slurry Substances 0.000 description 9
- 239000003921 oil Substances 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 150000002170 ethers Chemical class 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 239000000376 reactant Substances 0.000 description 7
- 229910052702 rhenium Inorganic materials 0.000 description 7
- 238000004817 gas chromatography Methods 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 238000005194 fractionation Methods 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- GGQQNYXPYWCUHG-RMTFUQJTSA-N (3e,6e)-deca-3,6-diene Chemical compound CCC\C=C\C\C=C\CC GGQQNYXPYWCUHG-RMTFUQJTSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000004587 chromatography analysis Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QSHYGLAZPRJAEZ-UHFFFAOYSA-N 4-(chloromethyl)-2-(2-methylphenyl)-1,3-thiazole Chemical compound CC1=CC=CC=C1C1=NC(CCl)=CS1 QSHYGLAZPRJAEZ-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- QVYYOKWPCQYKEY-UHFFFAOYSA-N [Fe].[Co] Chemical compound [Fe].[Co] QVYYOKWPCQYKEY-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 239000003426 co-catalyst Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- -1 for example Chemical compound 0.000 description 2
- 238000006317 isomerization reaction Methods 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000002336 sorption--desorption measurement Methods 0.000 description 2
- 239000011029 spinel Substances 0.000 description 2
- 229910052596 spinel Inorganic materials 0.000 description 2
- 238000000629 steam reforming Methods 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 238000012935 Averaging Methods 0.000 description 1
- 239000008037 PVC plasticizer Substances 0.000 description 1
- 239000012494 Quartz wool Substances 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000002453 autothermal reforming Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000001193 catalytic steam reforming Methods 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- MZZUATUOLXMCEY-UHFFFAOYSA-N cobalt manganese Chemical compound [Mn].[Co] MZZUATUOLXMCEY-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000006257 total synthesis reaction Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/043—Catalysts; their physical properties characterised by the composition
- C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0455—Reaction conditions
- C07C1/046—Numerical values of parameters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0485—Set-up of reactors or accessories; Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
- C07C27/04—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by reduction of oxygen-containing compounds
- C07C27/06—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by reduction of oxygen-containing compounds by hydrogenation of oxides of carbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Lubricants (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/330,860 US6787576B2 (en) | 2002-12-27 | 2002-12-27 | Linear alpha olefins from natural gas-derived synthesis gas over a nonshifting cobalt catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200505106B true ZA200505106B (en) | 2006-11-29 |
Family
ID=32654607
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200505106A ZA200505106B (en) | 2002-12-27 | 2005-06-23 | Process for the preparation of linear alpha-olefins from synthesis gas over a cobalt catalyst |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6787576B2 (ja) |
| EP (1) | EP1575883A1 (ja) |
| JP (1) | JP2006512393A (ja) |
| KR (1) | KR20050088481A (ja) |
| CN (1) | CN1732137A (ja) |
| AR (1) | AR042466A1 (ja) |
| AU (1) | AU2003295625B2 (ja) |
| BR (1) | BR0316839A (ja) |
| CA (1) | CA2507722A1 (ja) |
| MY (1) | MY127796A (ja) |
| NO (1) | NO20053633L (ja) |
| TW (1) | TWI296614B (ja) |
| WO (1) | WO2004060836A1 (ja) |
| ZA (1) | ZA200505106B (ja) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7914764B2 (en) * | 2003-02-28 | 2011-03-29 | Exxonmobil Research And Engineering Company | Hydrogen manufacture using pressure swing reforming |
| US7361619B2 (en) * | 2003-04-11 | 2008-04-22 | Exxonmobil Research And Engineering Company | Fischer-Tropsch catalyst production |
| US7875402B2 (en) * | 2005-02-23 | 2011-01-25 | Exxonmobil Research And Engineering Company | Proton conducting solid oxide fuel cell systems having temperature swing reforming |
| US7799314B2 (en) * | 2005-09-09 | 2010-09-21 | Exxonmobil Research And Engineering Company | Hydrogen production and use in an internal combustion engine system |
| DE102005056784A1 (de) * | 2005-11-28 | 2007-05-31 | Basf Ag | Verfahren zur Herstellung von Olefinen aus Synthesegas in einer Reaktionskolonne |
| US7815873B2 (en) * | 2006-12-15 | 2010-10-19 | Exxonmobil Research And Engineering Company | Controlled combustion for regenerative reactors with mixer/flow distributor |
| WO2011054738A1 (de) | 2009-11-06 | 2011-05-12 | Basf Se | Eisenhaltiger heterogenkatalysator und verfahren zur herstellung von olefinen durch umsetzung von kohlenmonoxid mit wasserstoff |
| CN102711991B (zh) | 2009-11-06 | 2015-01-21 | 巴斯夫欧洲公司 | 含铁和锰的非均相催化剂和通过一氧化碳与氢气反应而制备烯烃的方法 |
| CN102665899B (zh) * | 2009-11-06 | 2015-08-12 | 巴斯夫欧洲公司 | 含铁和铜的多相催化剂和通过用氢气转化一氧化碳制备烯烃的方法 |
| CN105473495A (zh) | 2013-07-31 | 2016-04-06 | 沙特基础工业公司 | 通过基于费-托的合成产生烯烃的方法 |
| EP3027716A2 (en) | 2013-07-31 | 2016-06-08 | Saudi Basic Industries Corporation | A process for the production of olefins through fischer-tropsch based synthesis |
| CN104560191B (zh) * | 2013-10-28 | 2017-03-22 | 中国石油化工股份有限公司 | 低黏度润滑油基础油的制备方法 |
| US10745624B2 (en) * | 2015-05-08 | 2020-08-18 | Sabic Global Technologies B.V. | Systems and methods related to syngas to olefin production |
| CN106582698B (zh) * | 2015-10-20 | 2019-05-21 | 中国石油化工股份有限公司 | 一种负载型催化剂及其制备方法和应用以及由合成气制备α-烯烃的方法 |
| WO2017093859A1 (en) * | 2015-12-02 | 2017-06-08 | Sabic Global Technologies B.V. | A two-step process of co2 assisted oxidative conversion of methane to syngas and methane assisted conversion of syngas to hydrocarbons |
| CN109534939B (zh) * | 2018-11-12 | 2021-03-23 | 陕西师范大学 | 一种Co基催化剂催化合成气直接一步高选择性制α-烯烃的方法 |
| KR102653716B1 (ko) * | 2020-03-03 | 2024-04-03 | 한국화학연구원 | 이산화탄소가 포함된 합성가스로부터 선형 알파 올레핀을 제조하기 위한 촉매 및 이를 이용한 선형 알파 올레핀의 제조방법 |
| US11578016B1 (en) | 2021-08-12 | 2023-02-14 | Saudi Arabian Oil Company | Olefin production via dry reforming and olefin synthesis in a vessel |
| US11787759B2 (en) | 2021-08-12 | 2023-10-17 | Saudi Arabian Oil Company | Dimethyl ether production via dry reforming and dimethyl ether synthesis in a vessel |
| US11718575B2 (en) | 2021-08-12 | 2023-08-08 | Saudi Arabian Oil Company | Methanol production via dry reforming and methanol synthesis in a vessel |
| US11617981B1 (en) | 2022-01-03 | 2023-04-04 | Saudi Arabian Oil Company | Method for capturing CO2 with assisted vapor compression |
Family Cites Families (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4048250A (en) * | 1975-04-08 | 1977-09-13 | Mobil Oil Corporation | Conversion of natural gas to gasoline and LPG |
| US4279830A (en) * | 1977-08-22 | 1981-07-21 | Mobil Oil Corporation | Conversion of synthesis gas to hydrocarbon mixtures utilizing dual reactors |
| NL7712952A (en) | 1977-11-24 | 1979-05-28 | Shell Int Research | Ethylene prodn. from carbon mon:oxide and hydrogen - by catalytic reaction of the feed stream and pyrolysis of the gaseous reaction prod. |
| US4418155A (en) * | 1980-03-24 | 1983-11-29 | Mobil Oil Corporation | Conversion of synthesis gas to hydrocarbons enriched in linear alpha-olefins |
| DE3130988A1 (de) * | 1981-08-05 | 1983-02-24 | Schering Ag, 1000 Berlin Und 4619 Bergkamen | Katalysator und verfahren zur herstellung von olefinen - insbesondere linearen (alpha)-olefinen - aus synthesegas |
| CA1196617A (en) * | 1982-07-14 | 1985-11-12 | George E. Morris | Catalyst composition, method for its production and its use in the production of hydrocarbons from synthesis gas |
| US4544674A (en) * | 1983-12-14 | 1985-10-01 | Exxon Research And Engineering Co. | Cobalt-promoted fischer-tropsch catalysts |
| US4584323A (en) * | 1983-12-14 | 1986-04-22 | Exxon Research And Engineering Co. | Fischer-Tropsch hydrocarbon synthesis with copper promoted iron/cobalt spinel catalyst |
| US4532229A (en) * | 1983-12-14 | 1985-07-30 | Exxon Research And Engineering Co. | Process for preparing a Fe-Co catalyst slurry system for alpha olefin production |
| US5118715A (en) * | 1983-12-20 | 1992-06-02 | Exxon Research And Engineering Company | Selective fixed-bed fischer-tropsch synthesis with high surface area Cu and K promoted, iron/manganese spinels |
| NL8401253A (nl) * | 1984-04-18 | 1985-11-18 | Shell Int Research | Werkwijze voor de bereiding van koolwaterstoffen. |
| US4579986A (en) * | 1984-04-18 | 1986-04-01 | Shell Oil Company | Process for the preparation of hydrocarbons |
| US4579830A (en) * | 1984-06-27 | 1986-04-01 | Union Carbide Corporation | Enhanced catalyst for converting synthesis gas to liquid motor fuels |
| JPS6118433A (ja) | 1984-07-04 | 1986-01-27 | Toyota Central Res & Dev Lab Inc | 炭化水素合成用触媒 |
| GB2169614A (en) | 1984-12-31 | 1986-07-16 | Mobil Oil Corp | Producing alpha-olefins and their conversion into lubricants |
| US4639431A (en) * | 1985-07-11 | 1987-01-27 | Exxon Research And Engineering Company | Catalysts in Fischer-Tropsch process for producing olefins |
| US6319960B1 (en) | 1986-10-03 | 2001-11-20 | Exxon Research & Engineering Company | Method for hydrocarbon synthesis reactions |
| US5545674A (en) * | 1987-05-07 | 1996-08-13 | Exxon Research And Engineering Company | Surface supported cobalt catalysts, process utilizing these catalysts for the preparation of hydrocarbons from synthesis gas and process for the preparation of said catalysts |
| US4874732A (en) * | 1987-07-13 | 1989-10-17 | Uop | Cobalt Fischer-Tropsch catalysts having improved selectivity |
| US4801573A (en) * | 1987-10-23 | 1989-01-31 | 501 Den Norske Stats Oljeslenskap A.S. | Catalyst for production of hydrocarbons |
| CA1340441C (en) * | 1988-04-25 | 1999-03-16 | Chang Jung Kim | Water addition for increased co/h2 hydrocarbon synthesis activity over catalysts comprising rhenium promoted cobalt on titania |
| JPH0269423A (ja) * | 1988-08-29 | 1990-03-08 | Exxon Res & Eng Co | 金属コバルト上に於けるｃｏとｈ↓２とからの接触炭化水素合成 |
| US5100856A (en) * | 1990-10-01 | 1992-03-31 | Exxon Research And Engineering Company | Iron-zinc based catalysts for the conversion of synthesis gas to alpha-olefins |
| US5210060A (en) * | 1991-07-30 | 1993-05-11 | Amoco Corporation | Catalyst for converting synthesis gas to paraffin wax |
| US5248701A (en) * | 1991-08-05 | 1993-09-28 | Exxon Research And Engineering Company | Substituted cobalt catalysts for Fischer-Tropsch synthesis |
| US5877378A (en) | 1995-06-14 | 1999-03-02 | Amoco Corporation | Process for selective utilization of alpha-olefins in mixtures containing non-alpha-olefins |
| EG21174A (en) * | 1996-04-16 | 2000-12-31 | Procter & Gamble | Surfactant manufacture |
| US5863856A (en) | 1997-04-22 | 1999-01-26 | Exxon Research And Engineering Company | Preparation of high activity catalysts the catalysts and their use |
| US5856261A (en) | 1997-04-22 | 1999-01-05 | Exxon Research And Engineering Company | Preparation of high activity catalysts; the catalysts and their use |
| US6090742A (en) | 1997-04-22 | 2000-07-18 | Exxon Research And Engineering Company | Process for the preparation of high activity hydrocarbon synthesis catalysts; and catalyst compositions |
| US5856260A (en) | 1997-04-22 | 1999-01-05 | Exxon Research And Engineering Company | Preparation of high activity catalysts; the catalysts and their use |
| US5883138A (en) | 1997-04-25 | 1999-03-16 | Exxon Research And Engineering Company | Rapid injection catalytic partial oxidation process and apparatus for producing synthesis gas (law 562) |
| US6043288A (en) * | 1998-02-13 | 2000-03-28 | Exxon Research And Engineering Co. | Gas conversion using synthesis gas produced hydrogen for catalyst rejuvenation and hydrocarbon conversion |
| DE19825295B4 (de) | 1998-06-05 | 2006-10-26 | Linde Ag | Verfahren zur Gewinnung von hochreinen Alpha--Olefinen und Vorrichtung zu dessen Durchführung |
| DE19833941B4 (de) | 1998-07-28 | 2006-11-02 | Linde Ag | Verfahren und Destillationsvorrichtung zur Gewinnung von 1-Okten |
| GC0000088A (en) | 1999-02-15 | 2004-06-30 | Shell Int Research | Process for the preparation of hydrocarbons from carbon monoxide and hydrogen. |
| US6355593B1 (en) | 2000-09-01 | 2002-03-12 | Exxonmobil Research And Engineering Company | Fischer-Tropsch catalyst enhancement |
-
2002
- 2002-12-27 US US10/330,860 patent/US6787576B2/en not_active Expired - Lifetime
-
2003
- 2003-11-18 BR BR0316839-5A patent/BR0316839A/pt not_active IP Right Cessation
- 2003-11-18 AU AU2003295625A patent/AU2003295625B2/en not_active Ceased
- 2003-11-18 KR KR1020057012151A patent/KR20050088481A/ko not_active Application Discontinuation
- 2003-11-18 CN CNA2003801077903A patent/CN1732137A/zh active Pending
- 2003-11-18 WO PCT/US2003/036896 patent/WO2004060836A1/en active Application Filing
- 2003-11-18 CA CA002507722A patent/CA2507722A1/en not_active Abandoned
- 2003-11-18 JP JP2004565018A patent/JP2006512393A/ja active Pending
- 2003-11-18 EP EP03786824A patent/EP1575883A1/en not_active Withdrawn
- 2003-11-19 TW TW092132447A patent/TWI296614B/zh not_active IP Right Cessation
- 2003-12-04 MY MYPI20034646A patent/MY127796A/en unknown
- 2003-12-15 AR ARP030104628A patent/AR042466A1/es unknown
-
2005
- 2005-06-23 ZA ZA200505106A patent/ZA200505106B/en unknown
- 2005-07-26 NO NO20053633A patent/NO20053633L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| TW200422284A (en) | 2004-11-01 |
| AR042466A1 (es) | 2005-06-22 |
| JP2006512393A (ja) | 2006-04-13 |
| AU2003295625A1 (en) | 2004-07-29 |
| NO20053633D0 (no) | 2005-07-26 |
| TWI296614B (en) | 2008-05-11 |
| US20040127582A1 (en) | 2004-07-01 |
| BR0316839A (pt) | 2005-10-18 |
| US6787576B2 (en) | 2004-09-07 |
| WO2004060836A1 (en) | 2004-07-22 |
| AU2003295625B2 (en) | 2009-11-26 |
| CN1732137A (zh) | 2006-02-08 |
| KR20050088481A (ko) | 2005-09-06 |
| EP1575883A1 (en) | 2005-09-21 |
| CA2507722A1 (en) | 2004-07-22 |
| MY127796A (en) | 2006-12-29 |
| NO20053633L (no) | 2005-08-31 |
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