ZA200405429B - Hydrometallurgical processing of manganese containing material. - Google Patents
Hydrometallurgical processing of manganese containing material. Download PDFInfo
- Publication number
- ZA200405429B ZA200405429B ZA200405429A ZA200405429A ZA200405429B ZA 200405429 B ZA200405429 B ZA 200405429B ZA 200405429 A ZA200405429 A ZA 200405429A ZA 200405429 A ZA200405429 A ZA 200405429A ZA 200405429 B ZA200405429 B ZA 200405429B
- Authority
- ZA
- South Africa
- Prior art keywords
- process according
- leach
- manganese
- less
- manganese dioxide
- Prior art date
Links
- 239000011572 manganese Substances 0.000 title claims description 32
- 229910052748 manganese Inorganic materials 0.000 title claims description 28
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims description 27
- 239000000463 material Substances 0.000 title claims description 15
- 238000012545 processing Methods 0.000 title claims description 9
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 92
- 239000000243 solution Substances 0.000 claims description 56
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 54
- 238000000034 method Methods 0.000 claims description 45
- 230000008569 process Effects 0.000 claims description 45
- 235000010269 sulphur dioxide Nutrition 0.000 claims description 27
- 239000004291 sulphur dioxide Substances 0.000 claims description 27
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 22
- 229940075933 dithionate Drugs 0.000 claims description 20
- 239000002002 slurry Substances 0.000 claims description 19
- 150000002500 ions Chemical class 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 15
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 235000007079 manganese sulphate Nutrition 0.000 claims description 12
- 239000011702 manganese sulphate Substances 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 11
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 10
- 238000005363 electrowinning Methods 0.000 claims description 8
- 239000003929 acidic solution Substances 0.000 claims description 6
- 238000004090 dissolution Methods 0.000 claims description 6
- 229910021607 Silver chloride Inorganic materials 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 239000003792 electrolyte Substances 0.000 claims description 5
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims description 5
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 230000033116 oxidation-reduction process Effects 0.000 claims description 4
- 235000011149 sulphuric acid Nutrition 0.000 claims description 4
- 239000001117 sulphuric acid Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 239000007789 gas Substances 0.000 description 9
- 238000002386 leaching Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 229910017358 Fe2(SO4) Inorganic materials 0.000 description 1
- 229910001021 Ferroalloy Inorganic materials 0.000 description 1
- 229910000616 Ferromanganese Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- BPKGOZPBGXJDEP-UHFFFAOYSA-N [C].[Zn] Chemical compound [C].[Zn] BPKGOZPBGXJDEP-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- RMGVZKRVHHSUIM-UHFFFAOYSA-N dithionic acid Chemical compound OS(=O)(=O)S(O)(=O)=O RMGVZKRVHHSUIM-UHFFFAOYSA-N 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 1
- 239000012633 leachable Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- OKVGBKABWITJQA-UHFFFAOYSA-L manganese dithionate Chemical compound [Mn+2].[O-]S(=O)(=O)S([O-])(=O)=O OKVGBKABWITJQA-UHFFFAOYSA-L 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910000357 manganese(II) sulfate Inorganic materials 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000011085 pressure filtration Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/21—Manganese oxides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B47/00—Obtaining manganese
- C22B47/0018—Treating ocean floor nodules
- C22B47/0045—Treating ocean floor nodules by wet processes
- C22B47/0054—Treating ocean floor nodules by wet processes leaching processes
- C22B47/0063—Treating ocean floor nodules by wet processes leaching processes with acids or salt solutions
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B47/00—Obtaining manganese
- C22B47/0018—Treating ocean floor nodules
- C22B47/0045—Treating ocean floor nodules by wet processes
- C22B47/0081—Treatment or purification of solutions, e.g. obtained by leaching
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Ocean & Marine Engineering (AREA)
- Inorganic Chemistry (AREA)
- Oceanography (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2002952042A AU2002952042A0 (en) | 2002-10-10 | 2002-10-10 | Hydrometallurgical processing of manganese containing materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200405429B true ZA200405429B (en) | 2005-06-20 |
Family
ID=28047615
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200405429A ZA200405429B (en) | 2002-10-10 | 2004-07-08 | Hydrometallurgical processing of manganese containing material. |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US7951282B2 (zh) |
| CN (1) | CN100336919C (zh) |
| AU (1) | AU2002952042A0 (zh) |
| WO (1) | WO2004033738A1 (zh) |
| ZA (1) | ZA200405429B (zh) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2004260809B2 (en) * | 2003-07-30 | 2008-11-20 | Auvex Resources Pty Ltd | Improved hydrometallurgical processing of manganese containing materials |
| AU2003903992A0 (en) * | 2003-07-30 | 2003-08-14 | Hitec Energy Limited | Improved hydrometallurgical processing of manganese containing materials |
| BRPI0418064B1 (pt) * | 2004-05-25 | 2013-07-30 | processo para a obtenção de manganês eletrolítico a partir de resíduos da fabricação de ferro-ligas | |
| EP2212263B1 (en) * | 2007-09-26 | 2015-05-27 | Hitec Energy Limited | A micronutrient fertiliser and method for producing same |
| FR2946332B1 (fr) * | 2009-06-05 | 2011-10-21 | Kimpe Sarl | Procede de fabrication d'oxyde de manganese |
| WO2011085438A1 (en) * | 2010-01-13 | 2011-07-21 | Galaxy Resources Limited | Process for the production of electrolytic manganese dioxide |
| WO2012024294A1 (en) * | 2010-08-18 | 2012-02-23 | American Manganese Inc. | Processing of manganous sulphate/dithionate liquors |
| CN103261121B (zh) * | 2010-12-08 | 2016-05-04 | 美萨矿物有限公司 | 改进的微量营养素肥料及其生产方法 |
| JP5740540B2 (ja) * | 2012-01-31 | 2015-06-24 | ディープグリーン エンジニアリング プライヴェート リミテッド | マンガン含有原料の処理 |
| CN102634819B (zh) * | 2012-04-10 | 2015-05-13 | 四川大学 | 二氧化硫浸出氧化锰制取电解锰/电解二氧化锰的方法 |
| CN103572055A (zh) * | 2013-11-07 | 2014-02-12 | 广西桂柳化工有限责任公司 | 一种电解二氧化锰用硫酸锰的制备方法 |
| CN108165742A (zh) * | 2018-02-11 | 2018-06-15 | 乐昌市绿叶环保科技有限公司 | 软锰矿浸出液中降低连二硫酸锰含量的方法 |
| PE20230020A1 (es) * | 2020-05-07 | 2023-01-09 | Befesa Zinc Metal LLC | Un metodo, un sistema y un aparato para preparar sulfato de manganeso |
| CN114505306A (zh) * | 2021-12-30 | 2022-05-17 | 云锡文山锌铟冶炼有限公司 | 清洗二氧化硫还原浸出釜内结垢的方法 |
| WO2023148644A1 (en) * | 2022-02-04 | 2023-08-10 | Tata Steel Limited | A method for recovering manganese from manganese ore |
| CN115522053B (zh) * | 2022-08-23 | 2023-07-25 | 郴州金铖环保科技有限公司 | 一种从黑钨矿浸出渣回收锡、钨、锰的方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3301777A (en) * | 1963-04-01 | 1967-01-31 | American Potash & Chem Corp | Anode for the electrowinning of manganese |
| US3438878A (en) * | 1966-10-27 | 1969-04-15 | Union Carbide Canada Ltd | Simultaneous refining of zinc and manganese dioxide |
| DE3211658A1 (de) * | 1982-03-30 | 1983-10-06 | Grillo Werke Ag | Verfahren zum aufschluss von manganerzen mittels schwefeldioxid |
| WO1998014623A1 (en) * | 1996-10-02 | 1998-04-09 | International Curator Resources Limited | Hydrometallurgical extraction of copper, zinc and cobalt from ores containing manganese dioxide |
| US5932086A (en) * | 1997-09-18 | 1999-08-03 | Elkem Metals Company, L.P. | Process for making manganese |
-
2002
- 2002-10-10 AU AU2002952042A patent/AU2002952042A0/en not_active Abandoned
-
2003
- 2003-10-01 WO PCT/AU2003/001295 patent/WO2004033738A1/en not_active Application Discontinuation
- 2003-10-01 US US10/501,277 patent/US7951282B2/en active Active
- 2003-10-01 CN CNB2003801006965A patent/CN100336919C/zh not_active Expired - Lifetime
-
2004
- 2004-07-08 ZA ZA200405429A patent/ZA200405429B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2004033738A1 (en) | 2004-04-22 |
| US20050103163A1 (en) | 2005-05-19 |
| CN1692169A (zh) | 2005-11-02 |
| CN100336919C (zh) | 2007-09-12 |
| US7951282B2 (en) | 2011-05-31 |
| AU2002952042A0 (en) | 2002-10-31 |
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