ZA200305278B - Process for making and using a low beverage soluble iron content adsorbent and composition made thereby. - Google Patents
Process for making and using a low beverage soluble iron content adsorbent and composition made thereby. Download PDFInfo
- Publication number
- ZA200305278B ZA200305278B ZA200305278A ZA200305278A ZA200305278B ZA 200305278 B ZA200305278 B ZA 200305278B ZA 200305278 A ZA200305278 A ZA 200305278A ZA 200305278 A ZA200305278 A ZA 200305278A ZA 200305278 B ZA200305278 B ZA 200305278B
- Authority
- ZA
- South Africa
- Prior art keywords
- sodium
- acid
- silicate
- silica gel
- polyphosphate
- Prior art date
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims description 87
- 239000003463 adsorbent Substances 0.000 title claims description 62
- 238000000034 method Methods 0.000 title claims description 54
- 230000008569 process Effects 0.000 title claims description 46
- 229910052742 iron Inorganic materials 0.000 title claims description 43
- 235000013361 beverage Nutrition 0.000 title claims description 42
- 239000000203 mixture Substances 0.000 title claims description 36
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 73
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 45
- 239000002253 acid Substances 0.000 claims description 40
- 239000000741 silica gel Substances 0.000 claims description 36
- 229910002027 silica gel Inorganic materials 0.000 claims description 36
- 229920000388 Polyphosphate Polymers 0.000 claims description 33
- 239000001205 polyphosphate Substances 0.000 claims description 33
- 235000011176 polyphosphates Nutrition 0.000 claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- 239000004115 Sodium Silicate Substances 0.000 claims description 28
- 239000003352 sequestering agent Substances 0.000 claims description 28
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 28
- 239000000017 hydrogel Substances 0.000 claims description 25
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 22
- 239000004111 Potassium silicate Substances 0.000 claims description 20
- 229910052913 potassium silicate Inorganic materials 0.000 claims description 20
- 235000019353 potassium silicate Nutrition 0.000 claims description 20
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 19
- 239000000377 silicon dioxide Substances 0.000 claims description 17
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 13
- 239000002243 precursor Substances 0.000 claims description 12
- 239000000376 reactant Substances 0.000 claims description 11
- 238000005406 washing Methods 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 6
- 238000003801 milling Methods 0.000 claims description 6
- 239000011707 mineral Substances 0.000 claims description 6
- 229910052700 potassium Inorganic materials 0.000 claims description 6
- 230000014759 maintenance of location Effects 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000002250 absorbent Substances 0.000 claims 1
- 230000002745 absorbent Effects 0.000 claims 1
- 239000000243 solution Substances 0.000 description 24
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 21
- 235000013405 beer Nutrition 0.000 description 19
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 14
- 239000000499 gel Substances 0.000 description 14
- 239000011148 porous material Substances 0.000 description 10
- 238000001179 sorption measurement Methods 0.000 description 8
- 238000001914 filtration Methods 0.000 description 6
- 239000000356 contaminant Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000002459 porosimetry Methods 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000010335 hydrothermal treatment Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 239000005909 Kieselgur Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 235000015107 ale Nutrition 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000010923 batch production Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000004445 quantitative analysis Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- GXCLVBGFBYZDAG-UHFFFAOYSA-N N-[2-(1H-indol-3-yl)ethyl]-N-methylprop-2-en-1-amine Chemical compound CN(CCC1=CNC2=C1C=CC=C2)CC=C GXCLVBGFBYZDAG-UHFFFAOYSA-N 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000013124 brewing process Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229940006199 ferric cation Drugs 0.000 description 1
- 229940045203 ferrous cation Drugs 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 239000008131 herbal destillate Substances 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- -1 iron Chemical class 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 235000020004 porter Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 235000015106 stout Nutrition 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000014101 wine Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12H—PASTEURISATION, STERILISATION, PRESERVATION, PURIFICATION, CLARIFICATION OR AGEING OF ALCOHOLIC BEVERAGES; METHODS FOR ALTERING THE ALCOHOL CONTENT OF FERMENTED SOLUTIONS OR ALCOHOLIC BEVERAGES
- C12H1/00—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages
- C12H1/02—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material
- C12H1/04—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material with the aid of ion-exchange material or inert clarification material, e.g. adsorption material
- C12H1/0408—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material with the aid of ion-exchange material or inert clarification material, e.g. adsorption material with the aid of inorganic added material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/46—Materials comprising a mixture of inorganic and organic materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Food Science & Technology (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Distillation Of Fermentation Liquor, Processing Of Alcohols, Vinegar And Beer (AREA)
- Silicon Compounds (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/760,353 US6555151B2 (en) | 2001-01-12 | 2001-01-12 | Process for making and using a low beverage soluble iron content adsorbent and composition made thereby |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200305278B true ZA200305278B (en) | 2004-10-20 |
Family
ID=25058843
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200305278A ZA200305278B (en) | 2001-01-12 | 2003-07-08 | Process for making and using a low beverage soluble iron content adsorbent and composition made thereby. |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US6555151B2 (https=) |
| EP (1) | EP1385620A2 (https=) |
| JP (2) | JP2004530533A (https=) |
| KR (1) | KR20030077574A (https=) |
| CN (1) | CN1284620C (https=) |
| AU (1) | AU2002234246A1 (https=) |
| BR (1) | BR0206382A (https=) |
| CA (1) | CA2433658A1 (https=) |
| MX (1) | MXPA03006304A (https=) |
| WO (1) | WO2002055190A2 (https=) |
| ZA (1) | ZA200305278B (https=) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2857599B1 (fr) * | 2003-07-16 | 2006-02-24 | Realdyme | Procede biologique de detoxication d'un milieu liquide alimentaire et milieu liquide alimentaire detoxifie obtenu selon ce procede |
| US7229655B2 (en) * | 2003-12-30 | 2007-06-12 | Pq Corporation | Composition of, and process for using, silica xerogel for beer stabilization |
| WO2008024952A2 (en) * | 2006-08-25 | 2008-02-28 | World Minerals, Inc. | Processes for reducing beer soluble iron in diatomaceous earth products, diatomaceous earth products and compositions thereof, and methods of use |
| CN102239125A (zh) * | 2008-09-26 | 2011-11-09 | 世界矿物公司 | 含有降低的可溶性金属水平的硅藻土产品、在硅藻土产品中降低可溶性金属水平的工艺及其使用方法 |
| US20110180470A1 (en) * | 2010-01-27 | 2011-07-28 | James Jeffrey Harris | Aqueous iron removal process and apparatus |
| US9005687B2 (en) * | 2010-03-15 | 2015-04-14 | Millercoors Llc | Methods for reducing soluble metal ions in diatomaceous earth filter aids |
| RU2015114330A (ru) | 2012-09-17 | 2016-11-10 | У.Р. Грейс Энд Ко.-Конн. | Хроматографические среды и устройства |
| CN103788989B (zh) * | 2012-10-29 | 2015-11-25 | 中国石油化工股份有限公司 | 一种蒸汽裂解方法 |
| JP6914189B2 (ja) | 2014-05-02 | 2021-08-04 | ダブリュー・アール・グレース・アンド・カンパニー−コーンＷ Ｒ Ｇｒａｃｅ ＆ Ｃｏ−Ｃｏｎｎ | 官能化担体材料並びに官能化担体材料を作製及び使用する方法 |
| CN107921407B (zh) | 2015-06-05 | 2022-07-05 | 格雷斯公司 | 生物处理吸附澄清剂及其制备和使用方法 |
| IT201800004721A1 (it) * | 2018-04-19 | 2019-10-19 | Dispositivo per la stabilizzazione del vino ed altre bevande vegetali e relativo procedimento di stabilizzazione. | |
| CN111747419B (zh) * | 2020-07-08 | 2023-08-22 | 青岛美高集团有限公司 | 一种降低硅胶中重金属含量的方法 |
| US12435295B1 (en) | 2021-11-15 | 2025-10-07 | Sciessent Llc | Water-based anti-odor fabric treatment compositions |
| GB202305914D0 (en) | 2023-04-21 | 2023-06-07 | Pq Silicas Uk Ltd | Clarifying agents |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1215928A (en) | 1967-04-28 | 1970-12-16 | Unilever Ltd | A process for reducing haze in beer |
| CH510115A (de) * | 1968-11-22 | 1971-07-15 | Brauerei Ind Ag F | Verfahren zur Herstellung eines Adsorptionsmittels |
| US3800031A (en) * | 1972-04-06 | 1974-03-26 | Grace W R & Co | Process for preparing silica hydrogel |
| US3846337A (en) * | 1972-07-20 | 1974-11-05 | Union Oil Co | Phosphate-silica-aluminosilicate compositions of improved crushing strength and methods of preparing the same |
| US4134857A (en) | 1977-02-07 | 1979-01-16 | Johns-Manville Corporation | Use of tannic or gallic acid to produce low beverage soluble iron content filter aid |
| FR2471949A1 (fr) | 1979-12-20 | 1981-06-26 | Rhone Poulenc Ind | Procede de fabrication de silices precipitees fines |
| US4508742A (en) | 1983-05-06 | 1985-04-02 | Pq Corporation | Treating beer to prevent chill haze and metal contamination |
| US4758440A (en) * | 1986-02-03 | 1988-07-19 | Heem Peter V D | Process for chillproofing a malt beverage and silica product for chillproofing |
| US4847235A (en) * | 1986-02-03 | 1989-07-11 | Scm Glidco Organics Corp. | Silica product |
| US5215733A (en) * | 1986-04-25 | 1993-06-01 | Unilever Patent Holdings B.V. | Manufacture of silica gels using shear to reduce the particle size prior to washing with a hydrocyclone |
| GB8707526D0 (en) | 1987-03-30 | 1987-05-07 | Unilever Plc | Amorphous silicas |
| US4847532A (en) * | 1988-05-27 | 1989-07-11 | Tektronix, Inc. | Tensed shadow mask assembly for cathode-ray tube |
| JPH038710A (ja) * | 1989-06-05 | 1991-01-16 | Jgc Corp | 瀘過性の良い微粉末シリカゲルの製造法 |
| US5641532A (en) * | 1995-12-15 | 1997-06-24 | The Procter & Gamble Company | Beverages having stable flavor/cloud emulsions in the presence of polyphosphate-containing preservative systems by including gellan gum |
| WO2000066705A2 (en) | 1999-05-03 | 2000-11-09 | Pq Holding, Inc. | Process and composition for reducing chill haze in beverages |
| RU2160777C1 (ru) * | 2000-02-16 | 2000-12-20 | Открытое акционерное общество "Воскресенские минеральные удобрения" | Способ осветления пива |
-
2001
- 2001-01-12 US US09/760,353 patent/US6555151B2/en not_active Expired - Lifetime
-
2002
- 2002-01-14 CN CNB02803659XA patent/CN1284620C/zh not_active Expired - Fee Related
- 2002-01-14 MX MXPA03006304A patent/MXPA03006304A/es active IP Right Grant
- 2002-01-14 KR KR10-2003-7009304A patent/KR20030077574A/ko not_active Withdrawn
- 2002-01-14 WO PCT/US2002/001005 patent/WO2002055190A2/en not_active Ceased
- 2002-01-14 AU AU2002234246A patent/AU2002234246A1/en not_active Abandoned
- 2002-01-14 BR BR0206382-4A patent/BR0206382A/pt not_active IP Right Cessation
- 2002-01-14 EP EP02701048A patent/EP1385620A2/en not_active Withdrawn
- 2002-01-14 CA CA002433658A patent/CA2433658A1/en not_active Abandoned
- 2002-01-14 JP JP2002555914A patent/JP2004530533A/ja active Pending
-
2003
- 2003-03-17 US US10/390,361 patent/US20030170361A1/en not_active Abandoned
- 2003-07-08 ZA ZA200305278A patent/ZA200305278B/en unknown
-
2007
- 2007-09-18 JP JP2007241602A patent/JP2008080332A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA03006304A (es) | 2003-09-16 |
| WO2002055190A2 (en) | 2002-07-18 |
| JP2004530533A (ja) | 2004-10-07 |
| US6555151B2 (en) | 2003-04-29 |
| KR20030077574A (ko) | 2003-10-01 |
| AU2002234246A1 (en) | 2002-07-24 |
| CN1284620C (zh) | 2006-11-15 |
| CA2433658A1 (en) | 2002-07-18 |
| US20030170361A1 (en) | 2003-09-11 |
| WO2002055190A3 (en) | 2003-11-13 |
| CN1503693A (zh) | 2004-06-09 |
| US20020094364A1 (en) | 2002-07-18 |
| BR0206382A (pt) | 2004-02-03 |
| EP1385620A2 (en) | 2004-02-04 |
| JP2008080332A (ja) | 2008-04-10 |
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