ZA200303030B - Method for the isomerisation of allyl alcohols. - Google Patents

Method for the isomerisation of allyl alcohols. Download PDF

Info

Publication number
ZA200303030B
ZA200303030B ZA200303030A ZA200303030A ZA200303030B ZA 200303030 B ZA200303030 B ZA 200303030B ZA 200303030 A ZA200303030 A ZA 200303030A ZA 200303030 A ZA200303030 A ZA 200303030A ZA 200303030 B ZA200303030 B ZA 200303030B
Authority
ZA
South Africa
Prior art keywords
formula
mixtures
alcohols
complex
iii
Prior art date
Application number
ZA200303030A
Other languages
English (en)
Inventor
Klaus Ebel
Frank Haese
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of ZA200303030B publication Critical patent/ZA200303030B/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/56—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by isomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213—Complexes without C-metal linkages
    • B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Pyridine Compounds (AREA)
ZA200303030A 2000-09-20 2003-04-17 Method for the isomerisation of allyl alcohols. ZA200303030B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10046865A DE10046865A1 (de) 2000-09-20 2000-09-20 Verfahren zur Isomerisierung von Allylalkoholen

Publications (1)

Publication Number Publication Date
ZA200303030B true ZA200303030B (en) 2004-04-19

Family

ID=7657152

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA200303030A ZA200303030B (en) 2000-09-20 2003-04-17 Method for the isomerisation of allyl alcohols.

Country Status (14)

Country Link
US (1) US6989468B2 (es)
EP (1) EP1322583B1 (es)
JP (1) JP4377128B2 (es)
CN (1) CN1211331C (es)
AR (1) AR030752A1 (es)
AT (1) ATE315547T1 (es)
AU (1) AU2001291871A1 (es)
BR (1) BR0113916A (es)
DE (2) DE10046865A1 (es)
ES (1) ES2255569T3 (es)
IL (1) IL154519A0 (es)
MX (1) MXPA03001577A (es)
WO (1) WO2002024617A1 (es)
ZA (1) ZA200303030B (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10160146A1 (de) 2001-12-07 2003-06-18 Basf Ag Verfahren zur Isomerisierung von Allylalkoholen
DE10160147A1 (de) * 2001-12-07 2003-06-18 Basf Ag Verfahren zur Isomerisierung von Allylalkoholen
DE102004009311A1 (de) * 2004-02-26 2005-09-08 Basf Ag Verfahren zur Herstellung eines Propargylalkohols und eines Allylalkohols
CN101605748B (zh) * 2007-02-09 2013-04-03 帝斯曼知识产权资产管理有限公司 戊-1-烯-3-醇的异构化工艺
JP5801727B2 (ja) * 2012-01-16 2015-10-28 株式会社日本触媒 ペルオキソ錯体
EP2657216B1 (de) 2012-04-27 2014-06-25 Symrise AG Verfahren zum Umsetzen von Farnesol zu Nerolidol in Gegenwart von alpha-Bisabolol
CN105218312B (zh) * 2015-11-03 2017-04-26 山东新和成药业有限公司 一种烯丙基醇经异构化法连续制备芳樟醇的方法
CN105541544A (zh) * 2015-12-16 2016-05-04 绍兴明业化纤有限公司 一种3-甲基-3-丁烯-1-醇的生产方法
CN105967978B (zh) * 2016-07-15 2018-04-24 西南化工研究设计院有限公司 含水甲基丁烯醇异构化合成异戊烯醇
CN108892602A (zh) * 2018-09-18 2018-11-27 杭州更蓝生物科技有限公司 一种制备芳樟醇的方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2516698A1 (de) * 1974-04-22 1975-10-30 Kuraray Co Neue wolframverbindungen
JPS5826730B2 (ja) * 1976-04-22 1983-06-04 株式会社クラレ シトロネロ−ルの分離方法
EP0860415B1 (de) 1997-02-25 2002-12-04 Basf Aktiengesellschaft Verfahren zur Isomerisierung von Allylalkoholen

Also Published As

Publication number Publication date
IL154519A0 (en) 2003-09-17
MXPA03001577A (es) 2003-06-04
DE50108693D1 (de) 2006-04-06
US6989468B2 (en) 2006-01-24
ES2255569T3 (es) 2006-07-01
JP2004509157A (ja) 2004-03-25
AU2001291871A1 (en) 2002-04-02
BR0113916A (pt) 2003-07-22
US20040097765A1 (en) 2004-05-20
CN1211331C (zh) 2005-07-20
JP4377128B2 (ja) 2009-12-02
WO2002024617A1 (de) 2002-03-28
DE10046865A1 (de) 2002-03-28
ATE315547T1 (de) 2006-02-15
EP1322583B1 (de) 2006-01-11
CN1461291A (zh) 2003-12-10
EP1322583A1 (de) 2003-07-02
AR030752A1 (es) 2003-09-03

Similar Documents

Publication Publication Date Title
JP2008538352A (ja) Ｒｕ／二座配位子の錯体を用いたエステルの水素化
US6989468B2 (en) Method for the isomerization of allyl alcohols
US4673757A (en) Process for selective hydrogenation of C-C double bonds in the presence of reducible, nitrogen-containing groups and new ruthenium complex compounds
CN106905125A (zh) 一种钴催化的酮α‑烷基化合成酮类衍生物的方法
CN110423190A (zh) 一种铁配合物催化酮α-烷基化的方法
JP7362609B2 (ja) 四座ｐｎｎｐ配位子ルテニウム錯体でのカルボニルの水素化
US7132576B2 (en) Method for isomerizing allyl alcohols
US6566564B1 (en) Method for isomersing allyl acohols
Guo et al. Stereoselective synthesis of conjugated polyenones from diynones
Ohtsuka et al. Convenient preparation of optically pure 1, 3-diaryl-1, 3-propanediols
CN114516796A (zh) 一种制备5-氧代己酸酯的方法
CN111087343B (zh) 一种羟基吡啶配体及其制备方法和催化应用
CN109438402B (zh) 一类苯并呋喃酮类衍生物及其合成方法
CN113583046A (zh) 双齿膦配体及其制备方法、应用
CN117586188A (zh) 一种手性n-咪唑啉类卡宾及其制备方法与应用
CN102698808B (zh) 一种复合型催化剂及其清洁催化氧化环己烯合成己二酸的用途
CN114656501A (zh) 2,2′-联吡啶骨架双膦配体及其制备方法、应用
JPH0416457B2 (es)