ZA200204491B - A thermally stable, high surface area, modified mesoporous aluminophosphate. - Google Patents
A thermally stable, high surface area, modified mesoporous aluminophosphate.Info
- Publication number
- ZA200204491B ZA200204491B ZA200204491A ZA200204491A ZA200204491B ZA 200204491 B ZA200204491 B ZA 200204491B ZA 200204491 A ZA200204491 A ZA 200204491A ZA 200204491 A ZA200204491 A ZA 200204491A ZA 200204491 B ZA200204491 B ZA 200204491B
- Authority
- ZA
- South Africa
- Prior art keywords
- mesoporous aluminophosphate
- surface area
- aluminophosphate
- mesoporous
- inorganic
- Prior art date
Links
- 239000000463 material Substances 0.000 abstract 5
- 239000011148 porous material Substances 0.000 abstract 4
- 229910052684 Cerium Inorganic materials 0.000 abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 abstract 2
- 229910017052 cobalt Inorganic materials 0.000 abstract 2
- 239000010941 cobalt Substances 0.000 abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 2
- 229910052746 lanthanum Inorganic materials 0.000 abstract 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 abstract 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- 229910052720 vanadium Inorganic materials 0.000 abstract 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- 229910052726 zirconium Inorganic materials 0.000 abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000004523 catalytic cracking Methods 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/54—Phosphates, e.g. APO or SAPO compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
- B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
- B01J27/1804—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
- B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/187—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/30—Alpo and sapo
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/468,451 US6447741B1 (en) | 1999-12-21 | 1999-12-21 | Thermally stable, high surface area, modified mesoporous aluminophosphate material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200204491B true ZA200204491B (en) | 2004-01-28 |
Family
ID=23859867
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200204491A ZA200204491B (en) | 1999-12-21 | 2002-06-05 | A thermally stable, high surface area, modified mesoporous aluminophosphate. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US6447741B1 (xx) |
| EP (1) | EP1244520B1 (xx) |
| JP (1) | JP4870890B2 (xx) |
| KR (1) | KR100783987B1 (xx) |
| CN (1) | CN1169622C (xx) |
| AT (1) | ATE297806T1 (xx) |
| AU (1) | AU2588001A (xx) |
| BR (1) | BR0016414A (xx) |
| CA (1) | CA2392803C (xx) |
| DE (1) | DE60020882T2 (xx) |
| MX (1) | MXPA02006201A (xx) |
| WO (1) | WO2001045840A1 (xx) |
| ZA (1) | ZA200204491B (xx) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2359825C (en) * | 2000-10-26 | 2008-09-23 | Quanjie Liu | A mesoporous aluminum based molecular sieve and a process for the preparation of the same |
| US20040064008A1 (en) * | 2002-09-30 | 2004-04-01 | Torsten Maurer | Molecular sieve catalyst composition |
| US7763359B2 (en) * | 2004-08-30 | 2010-07-27 | Bunge Fertilizantes S.A. | Aluminum phosphate, polyphosphate and metaphosphate particles and their use as pigments in paints and method of making same |
| BRPI0403713B1 (pt) * | 2004-08-30 | 2021-01-12 | Universidade Estadual De Campinas - Unicamp | processo de fabricação de um pigmento branco baseado na síntese de partículas ocas de ortofosfato ou polifosfato de alumínio |
| CN1312037C (zh) * | 2004-10-14 | 2007-04-25 | 中国科学院大连化学物理研究所 | 一种中孔mzpa－8材料及其制备方法 |
| JP5208762B2 (ja) * | 2005-12-22 | 2013-06-12 | アルベマール・ネーザーランズ・ベーブイ | 新規クラッキング触媒組成物を使用するｆｃｃ法 |
| KR100979580B1 (ko) | 2008-02-05 | 2010-09-01 | 에스케이에너지 주식회사 | 경질올레핀 생산용 탄화수소 접촉 분해 촉매 및 그제조방법 |
| US9023145B2 (en) | 2008-02-12 | 2015-05-05 | Bunge Amorphic Solutions Llc | Aluminum phosphate or polyphosphate compositions |
| AR075381A1 (es) * | 2009-02-10 | 2011-03-30 | Unicamp | Uso de particulas de fosfato, polifosfato y metafosfato, de aluminio en aplicaciones de recubrimiento de papeles. |
| KR101816706B1 (ko) * | 2010-03-17 | 2018-02-21 | 삼성전자주식회사 | 다공성 산화물 촉매 및 그의 제조방법 |
| US8524630B2 (en) | 2010-10-08 | 2013-09-03 | Exxonmobil Research And Engineering Company | Mesoporous aluminas stabilized with rare earth and phosphorous |
| US9371454B2 (en) | 2010-10-15 | 2016-06-21 | Bunge Amorphic Solutions Llc | Coating compositions with anticorrosion properties |
| US9005355B2 (en) | 2010-10-15 | 2015-04-14 | Bunge Amorphic Solutions Llc | Coating compositions with anticorrosion properties |
| US9155311B2 (en) | 2013-03-15 | 2015-10-13 | Bunge Amorphic Solutions Llc | Antimicrobial chemical compositions |
| US9611147B2 (en) | 2012-04-16 | 2017-04-04 | Bunge Amorphic Solutions Llc | Aluminum phosphates, compositions comprising aluminum phosphate, and methods for making the same |
| US9078445B2 (en) | 2012-04-16 | 2015-07-14 | Bunge Amorphic Solutions Llc | Antimicrobial chemical compositions |
| KR101937872B1 (ko) * | 2016-09-07 | 2019-01-11 | 에쓰대시오일 주식회사 | 프로판 암모산화 반응용 촉매, 이의 제조방법 및 이를 이용한 아크릴로니트릴의 제조방법 |
| JP7101003B2 (ja) * | 2018-03-22 | 2022-07-14 | 日揮触媒化成株式会社 | 活性マトリックスおよびその製造方法、ならびに（残油）流動接触分解触媒 |
| CN111092213B (zh) * | 2019-12-31 | 2023-01-31 | 河南电池研究院有限公司 | 一种锂离子电池复合正极材料及其制备方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4158621A (en) | 1978-07-21 | 1979-06-19 | Gulf Research & Development Company | Process for increasing gasoline yield and quality during catalytic cracking of high metals content charge stocks using an alumina-aluminum phosphate-silica-zeolite catalyst |
| US4179358A (en) | 1978-11-08 | 1979-12-18 | Gulf Research And Development Company | Fluid cracking catalyst process using a zeolite dispersed in a magnesia-alumina-aluminum phosphate matrix |
| US4845069A (en) * | 1983-09-29 | 1989-07-04 | The Dow Chemical Company | Porous amorphous metallo phosphates process for preparing porous amorphous metallo phosphates |
| US4743572A (en) | 1986-12-05 | 1988-05-10 | Mobil Oil Corporation | Magnesia-alumina-aluminum phosphate catalyst and catalyst product thereof |
| US4767733A (en) | 1987-05-18 | 1988-08-30 | Mobil Oil Corporation | Amorphous refractory composition |
| US4919787A (en) | 1987-12-28 | 1990-04-24 | Mobil Oil Corporation | Metal passivating agents |
| JP3403402B2 (ja) * | 1990-01-25 | 2003-05-06 | モービル・オイル・コーポレイション | 合成多孔質結晶性物質、それの合成および用途 |
| US5264203A (en) | 1990-01-25 | 1993-11-23 | Mobil Oil Corporation | Synthetic mesoporous crystalline materials |
-
1999
- 1999-12-21 US US09/468,451 patent/US6447741B1/en not_active Expired - Lifetime
-
2000
- 2000-12-20 BR BR0016414-3A patent/BR0016414A/pt not_active Application Discontinuation
- 2000-12-20 DE DE60020882T patent/DE60020882T2/de not_active Expired - Lifetime
- 2000-12-20 AT AT00989370T patent/ATE297806T1/de not_active IP Right Cessation
- 2000-12-20 MX MXPA02006201A patent/MXPA02006201A/es active IP Right Grant
- 2000-12-20 AU AU25880/01A patent/AU2588001A/en not_active Abandoned
- 2000-12-20 WO PCT/US2000/034842 patent/WO2001045840A1/en active IP Right Grant
- 2000-12-20 CN CNB008165289A patent/CN1169622C/zh not_active Expired - Fee Related
- 2000-12-20 EP EP00989370A patent/EP1244520B1/en not_active Expired - Lifetime
- 2000-12-20 JP JP2001546776A patent/JP4870890B2/ja not_active Expired - Fee Related
- 2000-12-20 KR KR1020027007928A patent/KR100783987B1/ko not_active IP Right Cessation
- 2000-12-20 CA CA002392803A patent/CA2392803C/en not_active Expired - Fee Related
-
2002
- 2002-06-05 ZA ZA200204491A patent/ZA200204491B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP1244520B1 (en) | 2005-06-15 |
| WO2001045840A1 (en) | 2001-06-28 |
| CA2392803A1 (en) | 2001-06-28 |
| BR0016414A (pt) | 2002-08-20 |
| KR100783987B1 (ko) | 2007-12-07 |
| AU2588001A (en) | 2001-07-03 |
| JP2003517995A (ja) | 2003-06-03 |
| MXPA02006201A (es) | 2002-12-09 |
| DE60020882D1 (de) | 2005-07-21 |
| US6447741B1 (en) | 2002-09-10 |
| CA2392803C (en) | 2009-12-22 |
| KR20020092354A (ko) | 2002-12-11 |
| EP1244520A1 (en) | 2002-10-02 |
| CN1169622C (zh) | 2004-10-06 |
| ATE297806T1 (de) | 2005-07-15 |
| CN1402651A (zh) | 2003-03-12 |
| DE60020882T2 (de) | 2006-05-11 |
| JP4870890B2 (ja) | 2012-02-08 |
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