WO2024071443A2 - Composé ester et son utilisation - Google Patents

Composé ester et son utilisation Download PDF

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WO2024071443A2
WO2024071443A2 PCT/JP2024/002409 JP2024002409W WO2024071443A2 WO 2024071443 A2 WO2024071443 A2 WO 2024071443A2 JP 2024002409 W JP2024002409 W JP 2024002409W WO 2024071443 A2 WO2024071443 A2 WO 2024071443A2
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composition
compound
family
group
compound according
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PCT/JP2024/002409
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English (en)
Japanese (ja)
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WO2024071443A3 (fr
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康 片桐
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住友化学株式会社
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Priority to CN202480001005.8A priority Critical patent/CN118339137A/zh
Priority to JP2024522118A priority patent/JP7538380B1/ja
Publication of WO2024071443A2 publication Critical patent/WO2024071443A2/fr
Publication of WO2024071443A3 publication Critical patent/WO2024071443A3/fr

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  • Patent Document 1 a compound represented by the formula (A) is disclosed as having excellent insecticidal activity.
  • An ester compound represented by the formula (hereinafter referred to as compound A) is described.
  • the objective of the present invention is to provide a compound that has excellent control effect against harmful arthropods.
  • the present inventors have conducted studies to find a compound having excellent control activity against harmful arthropods, and as a result, have found that a compound represented by the following formula (I) has excellent control activity against harmful arthropods.
  • the present invention is as follows. [1] Formula (I): (hereinafter, referred to as the compound of the present invention). [2] A composition comprising the compound according to [1] and an inert carrier. [3] A method for controlling harmful arthropods, which comprises applying an effective amount of the compound according to [1] to the harmful arthropods or to a habitat of the harmful arthropods.
  • a composition comprising the compound according to [1] and one or more compounds selected from the group consisting of metofluthrin and dimefluthrin.
  • a composition comprising the compound according to [1] or the composition according to [4], and one or more liquid carriers selected from the group consisting of water, alcohols, ketones, aromatic hydrocarbons, aliphatic hydrocarbons, esters, nitriles, ethers, amides, halogenated hydrocarbons, sulfoxides, mineral oils, and vegetable oils.
  • a composition comprising the compound according to [1] or the composition according to [4], and one or more surfactants selected from the group consisting of alkyl sulfate salts, alkyl sulfonate salts, alkylaryl sulfonate salts, alkylaryl ethers, polyoxyethylated alkylaryl ethers, polyethylene glycol ethers, polyhydric alcohol esters, and sugar alcohol derivatives.
  • a composition comprising the compound according to [1] or the composition according to [4] and one or more thickeners selected from the group consisting of casein, gelatin, polysaccharides, lignin derivatives, bentonite, and synthetic water-soluble polymers.
  • a composition comprising the compound according to [1] or the composition according to [4], and one or more antioxidants selected from the group consisting of BHT (2,6-di-t-butyl-4-methylphenol) and BHA (a mixture of 2-t-butyl-4-methoxyphenol and 3-t-butyl-4-methoxyphenol).
  • BHT 2,6-di-t-butyl-4-methylphenol
  • BHA a mixture of 2-t-butyl-4-methoxyphenol and 3-t-butyl-4-methoxyphenol.
  • a composition comprising the compound according to [1] or the composition according to [4] supported on a plant powder.
  • a composition comprising the compound according to [1] or the composition according to [4] and a binder.
  • a composition comprising the compound according to [1] or the composition according to [4] supported on one or more substrates selected from the group consisting of cotton linters and pulp.
  • the present invention makes it possible to control harmful arthropods.
  • Stereoisomers include optical isomers and geometric isomers.
  • the present invention includes each optical isomer, each geometric isomer, and a mixture of isomers in any ratio.
  • the optical isomer of the compound of the present invention includes, for example, a compound represented by the formula (II): and a compound of formula (III):
  • Examples of the compound include those represented by the following formula:
  • optical isomer represented by formula (II) it is preferable to use the optical isomer represented by formula (II) or a mixture of isomers rich in said optical isomer.
  • the geometric isomer of the compound of the present invention includes, for example, the compound represented by formula (IV).
  • optical isomer of the compound represented by formula (IV) for example, the compound represented by formula (V): and compounds of formula (VI): Examples of the compound include those represented by the following formula:
  • the compound of the present invention it is preferable to use a geometric isomer represented by formula (I) or a mixture of isomers rich in said geometric isomer, and it is even more preferable to use a geometric isomer represented by formula (V) or a mixture of isomers rich in said geometric isomer.
  • the embodiments of the compound of the present invention include the following compounds.
  • the composition according to one embodiment of the present invention is a composition containing the compound of the present invention and an inert carrier.
  • the composition is usually prepared by mixing the compound of the present invention with an inert carrier such as a solid carrier or a liquid carrier, and adding a surfactant or other formulation auxiliary as necessary to prepare an emulsion, oil, powder, granule, wettable powder, wettable granule, flowable, dry flowable, microcapsule, etc.
  • the composition generally contains the compound of the present invention in an amount of 0.0001 to 95% by weight based on the total weight of the composition.
  • Solid carriers used in formulation include, for example, fine powders and granules of clays (kaolin clay, diatomaceous earth, bentonite, acid clay, etc.), dry silica, wet silica, talc, ceramics, other inorganic minerals (sericite, quartz, sulfur, activated carbon, calcium carbonate, etc.), chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, ammonium chloride, etc.), and synthetic resins (polyester resins such as polypropylene, polyacrylonitrile, polymethylmethacrylate, polyethylene terephthalate, nylon resins such as nylon-6, nylon-11, nylon-66, polyamide resins, polyvinyl chloride, polyvinylidene chloride, vinyl chloride-propylene copolymers, etc.).
  • clays kaolin clay, diatomaceous earth, bentonite, acid clay, etc.
  • dry silica wet silica
  • Liquid carriers include, for example, water, alcohols (methanol, ethanol, etc.), ketones (acetone, methyl ethyl ketone, etc.), aromatic hydrocarbons (toluene, xylene, etc.), aliphatic hydrocarbons (hexane, cyclohexane, etc.), esters (ethyl acetate, butyl acetate, etc.), nitriles (acetonitrile, etc.), ethers (diisopropyl ether, diethylene glycol dimethyl ether, etc.), amides (N,N-dimethylformamide, etc.), sulfoxides (dimethyl sulfoxide, etc.), and vegetable oils (soybean oil, cottonseed oil, etc.).
  • alcohols methanol, ethanol, etc.
  • ketones acetone, methyl ethyl ketone, etc.
  • aromatic hydrocarbons toluene, xylene, etc
  • Surfactants include, for example, nonionic surfactants such as polyoxyethylene alkyl ether or its salt (polyoxyethylene alkyl ether sulfate ammonium salt), polyoxyethylene alkyl aryl ether or its salt, and polyethylene glycol fatty acid ester, as well as anionic surfactants such as alkyl sulfonates, alkyl benzene sulfonates, and alkyl sulfates.
  • nonionic surfactants such as polyoxyethylene alkyl ether or its salt (polyoxyethylene alkyl ether sulfate ammonium salt), polyoxyethylene alkyl aryl ether or its salt, and polyethylene glycol fatty acid ester, as well as anionic surfactants such as alkyl sulfonates, alkyl benzene sulfonates, and alkyl sulfates.
  • formulation adjuvants include adhesives, dispersants, colorants, and stabilizers, such as casein, gelatin, sugars (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin derivatives, bentonite, synthetic water-soluble polymers (polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acids, etc.), isopropyl acid phosphate, BHT (2,6-di-tert-butyl-4-methylphenol), and BHA (a mixture of 2-tert-butyl-4-methoxyphenol and 3-tert-butyl-4-methoxyphenol).
  • adhesives such as casein, gelatin, sugars (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin derivatives, bentonite, synthetic water-soluble polymers (polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acids, etc.), isopropyl acid phosphate, BHT
  • the compounds of the present invention can control harmful arthropods such as harmful insects and harmful mites. Specific examples include the following.
  • Delphacidae such as the small brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), white-backed planthopper (Sogatella furcifera), corn planthopper (Peregrinus maidis), yellow-eared planthopper (Javesella pellucida), black horned planthopper (Perkinsiella saccharicida), Tagosodes orizicolus, and Stenocranus pacificus.
  • Delphacidae such as the small brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), white-backed planthopper (Sogatella furcifera), corn planthopper (Peregrinus maidis), yellow-eared planthopper (Javesella pellucida), black horned planthopper (Perkinsiella saccharicida), Tagosodes orizicolus, and Stenocranus pacificus.
  • Aphis pomi, snow willow aphid (Aphis spiraecola), green peach aphid (Myzus persicae), strawberry aphid (Brachycaudus helichrysi), radish aphid (Brevicoryne brassicae), rosy apple aphid (Dysaphis plantaginea), false radish aphid (Lipaphis erysimi), tulip long-horn aphid (Macrosiphum euphorbiae), oats Aulacorthum solani, lettuce aphid (Nasonovia ribisnigri), wheat curl aphid (Rhopalosiphum padi), corn aphid (Rhopalosiphum maidis), citrus black aphid (Toxoptera citricida), peach buttercup aphid (Hyalopterus pruni), barnyard millet aphid (Melana
  • the Miridae family such as the long-spined wheat grass bug (Stenodema calcarata) and the rusty whitefly (Lygus lineolaris); Trialeurodes vaporariorum, Bemisia tabaci, the Asian citrus whitefly (Dialeurodes citri), Aleurocanthus spiniferus, Aleurocanthus camelliae, and the Japanese whitefly (Aleurocanthus chinensis).
  • the family Aleyrodidae such as the whitefly (Pealius euryae); the family Coccinellidae, such as the palm scale insect (Abgrallaspis cyanophylli), the red scale insect (Aonidiella aurantii), the pear scale insect (Diaspidiotus perniciosus), the mulberry scale insect (Pseudaulacaspis pentagona), the Yanon scale insect (Unaspis yanonensis), and the false Yanon scale insect (Unaspis citri).
  • the family Coccinellidae such as the palm scale insect (Abgrallaspis cyanophylli), the red scale insect (Aonidiella aurantii), the pear scale insect (Diaspidiotus perniciosus), the mulberry scale insect (Pseudaulacaspis pentagona), the Yanon scale insect (Unaspis yanonensis), and the false
  • Psyllidae including Cacopsylla pyrisuga, Cacopsylla chinensis, Bactericera cockerelli, and Cacopsylla pyricola; Corythucha ciliata, Corythucha marmorata, Stephanitis nashi, and Stephanitis pyrioi des and other Tingidae; Cimicidae such as Cimex lectularius and Cimex hempterus; Cicadidae such as Quesada gigas; Reduviidae such as Triatoma infestans, Triatoma rubrofasciata, Triatoma dimidiata, and Rhodonius prolixus.
  • Lepidoptera Chilo suppressalis, Dark headed stem borer, Chilo polychrysus, White stem borer, Scirpophaga innotata, Scirpophaga incertulas, Rupela albina, Cnaphalocrocis medinalis, Marasmia patnalis, Marasmia exigua, Notarcha derogata, Ostrinia furnacalis, European corn borer, Hellula undalis, Herpetogramma luc Crambidae, such as the Japanese bush moth (Parapediasia teterrellus), the rice case worm (Nymphula depunctalis), the sugar cane borer (Diatraea saccharalis), and the eggplant fruit borer (Leucinodes orbonalis); Pyralidae, such as the corn moth (Elasmopalpus lignosellus), the Indian meal moth (Plodia interpunctella), the two-spotted moth (E
  • Heliothis virescens such as Heliothis virescens, Helicoverpa spp. such as Helicoverpa armigera, corn earworm (Helicoverpa zea), Noctuidae such as Velvet bean caterpillar (Anticarsia gemmatalis), cotton leafworm (Alabama argillacea), hop wine borer (Hydraecia immanis), Pieridae such as Pieris rapae, pear fruit moth (Grapholita molesta), plum fruit moth (Grapholita dimorpha), bean cicada (Coleoptera pedunculidae), Japanese quince (Pyral ...
  • Heliothis virescens such as Helicoverpa armigera, corn earworm (Helicoverpa zea), Noctuidae such as Velvet bean caterpillar (Anticarsia gemmatalis), cotton leafworm (Alabama argillacea), hop wine bore
  • Tortricidae such as the grass moth (Leguminivora glycinivorella), the bean pea moth (Matsumuraeses azukivora), the smaller apple tortrix moth (Adoxophyes orana fasciata), the smaller tea tortrix moth (Adoxophyes honmai), the tea tortrix moth (Homona magnima), the common tortrix moth (Archips fuscocupreanus), the codling moth (Cydia pomonella), the sugar candy moth (Tetramoera schistaceana), the bean shoot borer (Epinotia aporema), the citrus fruit borer (Citripestis sagittiferella), and the European grape wine moth (Lobesia botrana);
  • the Gracilariidae family includes the tea leaf moth (Caloptilia theivora) and the golden leaf moth (Phyllonorycter ringoniella); the Carposini
  • the family Plutellidae includes the long-legged moth (Plutella xylostella); the family Gelechiidae includes the peach leaf moth (Anarsia lineatella), the potato leaf moth (Helcystogramma triannulella), the red cotton moth (Pectinophora gossypiella), the potato tuber moth (Phthorimaea operculella), and the tomato leaf moth (Tuta absolutea); the family Arctiidae includes the fall webworm (Hyphantria cunea); the family Castniidae includes the giant sugarcane borer (Telchin licus); the family Cossidae includes the lesser cotton moth (Cossus insularis); the mugwort geometries (Ascotis selenaria) ), the Geometridae
  • Thysanoptera Thripidae, such as Frankliniella occidentalis, Thrips palmi, Scirtothrips dorsalis, Thrips tabaci, Frankliniella intonsa, Stenchaetothrips biformis, Echinothrips americanus, Scirtothrips perseae; Phlaeothripidae, such as Haplothrips aculeatus.
  • Diptera Anthomyiidae such as Delia platura, Delia antiqua, Pegomyia cunicularia, etc.; Ulidiidae such as Tetanops myopaeformis, etc.; Agromyza oryzae, Liriomyza sativae, Liriomyza trifolii, Chromatomyia horticola, etc.
  • Agromyzidae (Agromyzidae); Chloropidae (Chlorops oryzae), etc.; Bactrocera cucurbitae (Melon fly), Bactrocera dorsalis (Oriental fruit fly), Bactrocera latifrons (Eastern fruit fly), Bactrocera oleae (Olive fruit fly), Bactrocera tryoni (Queensland fruit fly), Ceratitis capitata (Mediterranean fruit fly), Rhagoletis pomonella (Apple maggot), Rhagoletis suzukii (Sugar apple fly), Tephritidae, such as Hacochlaena japonica; Ephydridae, such as Hydrellia griseola, Hydrellia philippina, and Hydrellia sasakii; Drosophilidae, such as Drosophila suzukii and Drosophila melanogaster; Megaselia spiracularis
  • Diabrotica spp. e.g. Western corn rootworm (Diabrotica virgifera virgifera), Southern corn rootworm (Diabrotica undecimpunctata howardi), Northern corn rootworm (Diabrotica barberi), Mexican corn rootworm (Diabrotica virgifera zeae), Banded cucumber beetle (Diabrotica balteata), Cucumber beetle (Diabrotica speciosa), etc.), Bean leaf beetle (Cerotoma trifurcata), Spotted neck leaf beetle (Oulema melanopus), Cucumber leaf beetle (Aulacophora femoralis), Striped flea beetle (Phyllotreta striolat a), cabbage free beetle (Phyllotreta cruciferae), western black free beetle (Phyllotreta pusilla), cabbage stem free beetle (Psylliodes chrys
  • fungus weevils such as Araecerus coffeee Family Anthriibidae; Family Aponidae such as sweet potato weevil (Cylas formicarius); Family Bruchidae such as Brazilian bean weevil (Zabrotes subfasciatus); Family Scolytidae such as pine bark beetle (Tomicus piniperda) and coffee berry borer (Hypothenemus hampei); Family Scolytidae such as potato weevil (Hypothenemus hampei); Bug (Euscepes postfasciatus), Alfalfa weevil (Hypera postica), Maize weevil (Sitophilus zeamais), Rice weevil (Sitophilus oryzae), Granary maize weevil (Sitophilus granarius), Rice weevil (Echinocnemus squameus), Rice water weevil (Lis
  • Aracanthus spp. such as the rust gourd weevil (Scepticus griseus), the brown gourd weevil (Scepticus uniformis), and Aracanthus mourei, and the cotton root borer (Eutinobothrus brasiliensis); Tenebrionidae such as the red flour beetle (Tribolium castaneum), the flat-headed red flour beetle (Tribolium confusum), and the mealworm beetle (Alphitobius diaperinus); Coccinellidae such as the 20-spotted ladybird beetle (Epilachna vigintioctopunctata); Lyctus brunneus, Rhizope rtha dominica; Ptinidae; Cerambycidae; Anoplophora malasiaca, Migdolus fryanus, Aromia bungii; Melanotus okinawensis, Brown-necked wire beet
  • the Dermestidae family including Anthrenus verbasci, Dermestes maculates, and Trogoderma granarium
  • the tobacco beetle Lasioderma serricorne
  • the Japanese cigar beetle Stepgobium paniceum and other Anobiidae
  • Brassicogethes aeneus and other Blossom Beetles Brassicogethes aeneus and other Blossom Beetles.
  • Hymenoptera Tenthredinidae such as Athalia rosae and Athalia japonica; Solenopsis spp. such as Solenopsis invicta and Solenopsis geminata; Atta spp.
  • Atta capiguara and Acro ant myrmex spp.
  • Paraponera clavata Ochetellus glaber
  • Monomorium pharaonis Argentine ant (Linepithema humile)
  • Formica japonica Pristomyrmex punctutus
  • Pheidole noda Pheidole megacephala
  • Camponotus spp. such as the Japanese camponotus (Camponotus japonicus), Camponotus spp., such as the red-breasted camponotus (Camponotus obscuripes)
  • Pogonomyrmex spp. such as Pogonomyrmex occidentalis
  • Wasmania spp. such as Wasmania auropunctata
  • Anoplolepis gracilipa such as Atta capiguara and Acro ant; myrmex spp.), Paraponera clavata, Ochetellus glaber, Monomor
  • Vespidae such as the giant hornet (Vespa mandarinia), the hairy hornet (Vespa simillima), the small hornet (Vespa analis), the red hornet (Vespa velutina), and the Japanese paper wasp (Polistes jokahamae); Siricidae (Wasps) such as the fir wasp (Urocerus gigas); and Bethylidae (Hornets).
  • Vespidae such as the giant hornet (Vespa mandarinia), the hairy hornet (Vespa simillima), the small hornet (Vespa analis), the red hornet (Vespa velutina), and the Japanese paper wasp (Polistes jokahamae); Siricidae (Wasps) such as the fir wasp (Urocerus gigas); and Bethylidae (Hornets).
  • Family Ectobiidae such as the German cockroach (Blattella germanica); Family Blattidae, such as the Siberian cockroach (Periplaneta fuliginosa), the American cockroach (Periplaneta americana), the American cockroach (Periplaneta australiae), the brown cockroach (Periplaneta brunnea), and the Asian cockroach (Blatta orientalis); Family Reticulitermes speratus, Formosan termite (Coptotermes formosanus), Formosan dry wood termite (Incisitermes minor), Formosan termite (Cryptotermes domesticus), Formosan termite (Odontotermes formosanus), and Formosan termite (Neotermes Termites of the family Termitidae, such as Glyptotermes satsumensis, Glyptotermes nakajimai, Glyptotermes fuscus,
  • Order Siphonaptera Family Pulicidae such as the human flea (Pulex irritans), cat flea (Ctenocephalides felis), dog flea (Ctenocephalides canis), rat flea (Xenopsylla cheopis), chicken flea (Echidnophaga gallinacea), etc.; Family Hectopsyllidae such as the sand flea (Tunga penetrans); Family Ceratophyllidae such as the European rat flea (Nosopsyllus fasciatus).
  • Family Pulicidae such as the human flea (Pulex irritans), cat flea (Ctenocephalides felis), dog flea (Ctenocephalides canis), rat flea (Xenopsylla cheopis), chicken flea (Echidnophaga gallinacea), etc.
  • Family Hectopsyllidae such as the sand flea (Tunga penetrans)
  • Psocodae Family Pediculidae such as head lice (Pediculus humanus capitis); Family Pthiridae such as pubic lice (Pthirus pubis); Family Haematopinidae such as cow lice (Haematopinus eurysternus) and pig lice (Haematopinus suis); Family Linognathus vituli, Sheep trunk lice Family Linognathidae, such as body lice (Linognathus ovillus) and cow lice (Solenopotes capillatus); Family Bovicoliidae, such as cow lice (Bovicola bovis), sheep lice (Bovicola ovis), Bovicola breviceps, Damalinia forficula, and Werneckiella spp.; Family Bovicoliidae, such as dog lice (T Family Trichodectidae, such as the cat louse (Felicola subrostratus) and the chicken louse
  • Menoponidae such as the chicken louse (Menopon gallinae), the chicken louse (Menacanthus stramineus), and the Trinoton spp. family Trinoton spp. family Cummingsia spp. family noponidae); Trogiidae, such as Trogium pulsatorium; Liposcelidae or Liposcelididae, such as Liposcelis corrodens, Liposcelis bostrychophila, Liposcelis pearmani, and Liposcelis entomophila.
  • Thysanura Family Lepismatidae, including the Japanese silverfish (Ctenolepisma villosa) and the European silverfish (Lepisma saccharina).
  • Eriophyidae such as Acarus carinatus, Acaphylla theavagrans, Eriophyes chibaensis, Aculus Louendali, Aceria diospyri, Aceria tosichella, Shevtchenkella sp.; Tarsonemidae, such as Polyphagotarsonemus latus; Deutzia purpurea, such as Brevipalpus phoenicis.
  • Order Araneae Family Eutichuridae such as Cheiracanthium japonicum; Family Theridiidae such as Latrodectus hasseltii.
  • Polydesmida Paradoxosomatidae, including Oxidus gracilis, Nedyopus tambanus, etc.
  • Isopoda Family Armadillidiidae, including Armadillidium vulgare.
  • Chilopoda Scutigeridae such as Thereuonema hilgendorfi; Scolopendridae such as Scolopendra subspinipes; Ethopolyidae such as Bothropolys rugosus.
  • the harmful arthropods such as harmful insects and harmful mites may be harmful arthropods such as harmful insects and harmful mites that have reduced sensitivity to insecticides, acaricides, etc., or that have developed resistance to such drugs.
  • composition A is a composition (hereinafter referred to as composition A) containing the compound of the present invention and at least one compound selected from the group consisting of metofluthrin and dimefluthrin.
  • Metofluthrin and dimefluthrin can be used alone or in combination of two types.
  • metofluthrin and dimefluthrin each have one or more stereoisomers, and the metofluthrin and dimefluthrin used in the present invention include stereoisomers and mixtures thereof.
  • the ratio of the compound of the present invention to at least one compound selected from the group consisting of metofluthrin and dimefluthrin is not particularly limited, but may be, in terms of mass ratio (compound of the present invention:at least one compound selected from the group consisting of metofluthrin and dimefluthrin), 100,000:1 to 1:100,000, 50,000:1 to 1:50,000, , 10,000:1 to 1:10,000, 1,000:1 to 1:1000, 500:1 to 1:500, 100:1 to 1:100, 50:1, 20:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:20, 1:50, and the like.
  • composition A containing at least one compound selected from the group consisting of metofluthrin and dimefluthrin is expected to have excellent control effects against harmful arthropods.
  • harmful arthropods that can be controlled by composition A include those mentioned above.
  • the method for controlling harmful arthropods of the present invention is carried out by applying an effective amount of the compound of the present invention or composition A directly to the harmful arthropods and/or to the habitat of the harmful arthropods (plants, soil, inside a house, animals, etc.).
  • Examples of the method for controlling harmful arthropods of the present invention include foliage treatment, soil treatment, root treatment, shower treatment, fumigation treatment, water surface treatment and seed treatment.
  • the application amount is usually 1 to 10,000 g of the compound of the present invention per 10,000 m 2.
  • the compound of the present invention or composition A is formulated as an emulsifiable concentrate, wettable powder, flowable agent or the like, it is usually applied after diluting with water so that the active ingredient concentration becomes 0.01 to 10,000 ppm (for example, 1,000 ppm), and granules, dusts, etc. are usually applied as they are.
  • the application amount is usually 0.01 to 1000 mg of the compound of the present invention per m2 of treatment area when applied on a surface, and usually 0.01 to 500 mg of the compound of the present invention per m3 of treatment space when applied in a space.
  • the compound of the present invention or composition A is formulated as an emulsifiable concentrate, wettable powder, flowable agent, etc., it is usually applied after diluting with water so that the active ingredient concentration is 0.1 to 10000 ppm, and oil solutions, aerosols, fumigants, poison baits, etc. are applied as they are.
  • composition B is usually prepared by mixing the compound of the present invention or composition A with a liquid carrier, a surfactant, etc., and adding formulation auxiliaries such as a thickener, a binder, a dispersant, a stabilizer, and a gas, if necessary, to be used as an oil solution, an emulsion, a wettable powder, a flowable agent (suspension in water, emulsion in water, etc.), a powder, a granule, an aerosol agent (direct spray type, space spray type, metered spray type, one-push type, total spray type, intermittent spray type, etc.), a spray, an electric spray (ultrasonic vibration type, electrostatic spray type, etc.), a heated transpiration agent (incense stick, electric mat, liquid-absorbing wick type heated transpiration agent, etc.), a non-heated transpiration agent (incense stick, electric mat, liquid-absorbing wick type heated transpiration agent, etc.), a non-heated transpiration agent (
  • a formulation that is one embodiment of the present invention is a formulation containing the compound of the present invention or Composition A, which is selected from the group consisting of an oil solution, an emulsion, a flowable agent, an aerosol agent, a heated evaporation agent, a non-heated evaporation agent, a fog agent, and a ULV agent.
  • These preparations usually contain the compound of the present invention or composition A in an amount of 0.0001 to 99% by weight based on the total weight of the preparation.
  • liquid carriers examples include water, alcohols (ethanol, cyclohexanol, benzyl alcohol, propylene glycol, polyethylene glycol, etc.), ketones (acetone, cyclohexanone, methyl ethyl ketone, etc.), aromatic hydrocarbons (benzene, toluene, xylene, ethylbenzene, methylnaphthalene, phenylxylylethane, etc.), aliphatic hydrocarbons (hexane, cyclohexane, etc.), esters (ethyl acetate, butyl acetate, methyl oleate, etc.), nitriles (acetonitrile, isobutyronitrile, etc.), ethers (diisopropyl ether, dioxane, etc.), amides (N,N-dimethylformamide, N,N-dimethylacetamide, etc.), halogenated hydrocarbons (d
  • a composition according to one embodiment of the present invention is a composition containing the compound of the present invention or composition A and one or more liquid carriers selected from the group consisting of water, alcohols, ketones, aromatic hydrocarbons, aliphatic hydrocarbons, esters, nitriles, ethers, amides, halogenated hydrocarbons, sulfoxides, mineral oils, and vegetable oils.
  • a formulation according to one embodiment of the present invention is a formulation containing the composition and selected from the group consisting of oil solutions, emulsions, flowables, aerosols, heat evaporation agents, and ULV agents.
  • surfactant examples include alkyl sulfates, alkyl sulfonates, alkylaryl sulfonates, alkylaryl ethers, polyoxyethylated alkylaryl ethers, polyethylene glycol ethers, polyhydric alcohol esters, and sugar alcohol derivatives.
  • the composition according to one embodiment of the present invention is a composition containing the compound of the present invention or composition A and one or more surfactants selected from the group consisting of alkyl sulfates, alkyl sulfonates, alkylaryl sulfonates, alkylaryl ethers, polyoxyethylated alkylaryl ethers, polyethylene glycol ethers, polyhydric alcohol esters, and sugar alcohol derivatives.
  • the formulation according to one embodiment of the present invention is a formulation containing the composition and selected from the group consisting of emulsions, flowables, and heat-transferables.
  • a composition according to one embodiment of the present invention is a composition containing the compound of the present invention or composition A and one or more thickeners selected from the group consisting of casein, gelatin, polysaccharides, lignin derivatives, bentonite, and synthetic water-soluble polymers.
  • a formulation according to one embodiment of the present invention is a flowable preparation containing the composition.
  • Antioxidants include, for example, BHT (2,6-di-tert-butyl-4-methylphenol) and BHA (a mixture of 2-tert-butyl-4-methoxyphenol and 3-tert-butyl-4-methoxyphenol).
  • a composition which is one embodiment of the present invention is a composition containing the compound of the present invention or composition A and one or more antioxidants selected from the group consisting of BHT and BHA.
  • a formulation which is one embodiment of the present invention is a formulation which contains the composition and is selected from the group consisting of oil solutions, emulsions, flowables, aerosols, heated transpiration agents, non-heated transpiration agents, aerosols, and ULV agents.
  • the composition according to one embodiment of the present invention is a composition in which the compound of the present invention or composition A is supported on a vegetable powder (wood flour, meal powder, etc.).
  • the vegetable powder may be used by mixing the vegetable powder with a binder (tab flour, starch, gluten, etc.).
  • the preparation according to one embodiment of the present invention is a heat-transpirable agent containing the composition.
  • a composition according to another embodiment of the present invention is a composition containing the compound of the present invention or composition A and a binder.
  • a preparation according to one embodiment of the present invention is a heat-transferable agent containing the composition.
  • the composition which is one embodiment of the present invention, is a composition in which the compound of the present invention or composition A is supported on one or more substrates selected from the group consisting of cotton linters and pulp.
  • substrates selected from the group consisting of cotton linters and pulp.
  • Specific examples of the substrate include cotton linters solidified into a plate shape and fibers of a mixture of cotton linters and pulp solidified into a plate shape.
  • the formulation which is one embodiment of the present invention, is a heat-transpirable agent containing the composition.
  • composition according to one embodiment of the present invention is a composition in which the compound of the present invention or composition A is supported on a thermoplastic resin or paper. Also, the preparation according to one embodiment of the present invention is a non-heated evaporative agent containing the composition.
  • the resin examples include polyethylene resins such as low-density polyethylene, linear low-density polyethylene, and high-density polyethylene; ethylene-vinyl ester copolymers such as ethylene-vinyl acetate copolymer; ethylene-methacrylic acid ester copolymers such as ethylene-methyl methacrylate copolymer and ethylene-ethyl methacrylate copolymer; ethylene-acrylic acid ester copolymers such as ethylene-methyl acrylate copolymer and ethylene-ethyl acrylate copolymer; ethylene-vinyl carboxylic acid copolymers such as ethylene-acrylic acid copolymer; ethylene-tetracyclododecene copolymer; polypropylene resins such as propylene polymers and propylene-ethylene copolymers; poly-4-methylpentene-1, polybutene-1, polybutadiene, polystyrene, and acrylonitrile
  • compositions which is another embodiment of the present invention is a composition in which the compound of the present invention or composition A is supported on a thermoplastic resin.
  • a composition which is yet another embodiment of the present invention is a composition in which the compound of the present invention or composition A is supported on paper.
  • Comparative Example 1 instead of the compound 1 of the present invention, compound A described in Japanese Patent No. 3728967 (Patent Document 1) was used as a test compound, and the test was carried out in the same manner as in Test Example 1. The mortality rate (average value of three repetitions) was 7%.
  • the compound of the present invention exhibits excellent control effects against harmful arthropods.

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  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La présente invention concerne un composé ayant une excellente efficacité de lutte contre les arthropodes nuisibles. Le composé, représenté par la formule (I), présente une excellente efficacité de lutte contre les arthropodes nuisibles.
PCT/JP2024/002409 2023-12-22 2024-01-26 Composé ester et son utilisation WO2024071443A2 (fr)

Priority Applications (2)

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CN202480001005.8A CN118339137A (zh) 2023-12-22 2024-01-26 酯化合物及其用途
JP2024522118A JP7538380B1 (ja) 2023-12-22 2024-01-26 エステル化合物及びその用途

Applications Claiming Priority (2)

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JP2023-216471 2023-12-22
JP2023216471 2023-12-22

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WO2024071443A2 true WO2024071443A2 (fr) 2024-04-04
WO2024071443A3 WO2024071443A3 (fr) 2024-06-06

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JP (1) JP7538380B1 (fr)
CN (1) CN118339137A (fr)
WO (1) WO2024071443A2 (fr)

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EG11383A (en) * 1972-07-11 1979-03-31 Sumitomo Chemical Co Novel composition for controlling nixious insects and process for preparing thereof
JPS564522B2 (fr) * 1972-07-11 1981-01-30
JP3728967B2 (ja) * 1998-02-26 2005-12-21 住友化学株式会社 エステル化合物
JP4289331B2 (ja) * 1998-02-26 2009-07-01 住友化学株式会社 有害生物防除剤
JP4926425B2 (ja) 2005-08-05 2012-05-09 Ｊｘ日鉱日石エネルギー株式会社 Ｅｔｂｅ含有ガソリン組成物及びその製造方法
JP2007039412A (ja) * 2005-08-05 2007-02-15 Dainippon Jochugiku Co Ltd 殺虫・防虫剤又は害虫の摂食阻害剤

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WO2024071443A3 (fr) 2024-06-06
CN118339137A (zh) 2024-07-12
JP7538380B1 (ja) 2024-08-21
JPWO2024071443A1 (fr) 2024-04-04

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