WO2024071443A2 - Ester compound and use thereof - Google Patents

Ester compound and use thereof Download PDF

Info

Publication number
WO2024071443A2
WO2024071443A2 PCT/JP2024/002409 JP2024002409W WO2024071443A2 WO 2024071443 A2 WO2024071443 A2 WO 2024071443A2 JP 2024002409 W JP2024002409 W JP 2024002409W WO 2024071443 A2 WO2024071443 A2 WO 2024071443A2
Authority
WO
WIPO (PCT)
Prior art keywords
composition
compound
family
group
compound according
Prior art date
Application number
PCT/JP2024/002409
Other languages
French (fr)
Japanese (ja)
Other versions
WO2024071443A3 (en
Inventor
康 片桐
Original Assignee
住友化学株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 住友化学株式会社 filed Critical 住友化学株式会社
Priority to CN202480001005.8A priority Critical patent/CN118339137A/en
Publication of WO2024071443A2 publication Critical patent/WO2024071443A2/en
Publication of WO2024071443A3 publication Critical patent/WO2024071443A3/en

Links

Definitions

  • Patent Document 1 a compound represented by the formula (A) is disclosed as having excellent insecticidal activity.
  • An ester compound represented by the formula (hereinafter referred to as compound A) is described.
  • the objective of the present invention is to provide a compound that has excellent control effect against harmful arthropods.
  • the present inventors have conducted studies to find a compound having excellent control activity against harmful arthropods, and as a result, have found that a compound represented by the following formula (I) has excellent control activity against harmful arthropods.
  • the present invention is as follows. [1] Formula (I): (hereinafter, referred to as the compound of the present invention). [2] A composition comprising the compound according to [1] and an inert carrier. [3] A method for controlling harmful arthropods, which comprises applying an effective amount of the compound according to [1] to the harmful arthropods or to a habitat of the harmful arthropods.
  • a composition comprising the compound according to [1] and one or more compounds selected from the group consisting of metofluthrin and dimefluthrin.
  • a composition comprising the compound according to [1] or the composition according to [4], and one or more liquid carriers selected from the group consisting of water, alcohols, ketones, aromatic hydrocarbons, aliphatic hydrocarbons, esters, nitriles, ethers, amides, halogenated hydrocarbons, sulfoxides, mineral oils, and vegetable oils.
  • a composition comprising the compound according to [1] or the composition according to [4], and one or more surfactants selected from the group consisting of alkyl sulfate salts, alkyl sulfonate salts, alkylaryl sulfonate salts, alkylaryl ethers, polyoxyethylated alkylaryl ethers, polyethylene glycol ethers, polyhydric alcohol esters, and sugar alcohol derivatives.
  • a composition comprising the compound according to [1] or the composition according to [4] and one or more thickeners selected from the group consisting of casein, gelatin, polysaccharides, lignin derivatives, bentonite, and synthetic water-soluble polymers.
  • a composition comprising the compound according to [1] or the composition according to [4], and one or more antioxidants selected from the group consisting of BHT (2,6-di-t-butyl-4-methylphenol) and BHA (a mixture of 2-t-butyl-4-methoxyphenol and 3-t-butyl-4-methoxyphenol).
  • BHT 2,6-di-t-butyl-4-methylphenol
  • BHA a mixture of 2-t-butyl-4-methoxyphenol and 3-t-butyl-4-methoxyphenol.
  • a composition comprising the compound according to [1] or the composition according to [4] supported on a plant powder.
  • a composition comprising the compound according to [1] or the composition according to [4] and a binder.
  • a composition comprising the compound according to [1] or the composition according to [4] supported on one or more substrates selected from the group consisting of cotton linters and pulp.
  • the present invention makes it possible to control harmful arthropods.
  • Stereoisomers include optical isomers and geometric isomers.
  • the present invention includes each optical isomer, each geometric isomer, and a mixture of isomers in any ratio.
  • the optical isomer of the compound of the present invention includes, for example, a compound represented by the formula (II): and a compound of formula (III):
  • Examples of the compound include those represented by the following formula:
  • optical isomer represented by formula (II) it is preferable to use the optical isomer represented by formula (II) or a mixture of isomers rich in said optical isomer.
  • the geometric isomer of the compound of the present invention includes, for example, the compound represented by formula (IV).
  • optical isomer of the compound represented by formula (IV) for example, the compound represented by formula (V): and compounds of formula (VI): Examples of the compound include those represented by the following formula:
  • the compound of the present invention it is preferable to use a geometric isomer represented by formula (I) or a mixture of isomers rich in said geometric isomer, and it is even more preferable to use a geometric isomer represented by formula (V) or a mixture of isomers rich in said geometric isomer.
  • the embodiments of the compound of the present invention include the following compounds.
  • the composition according to one embodiment of the present invention is a composition containing the compound of the present invention and an inert carrier.
  • the composition is usually prepared by mixing the compound of the present invention with an inert carrier such as a solid carrier or a liquid carrier, and adding a surfactant or other formulation auxiliary as necessary to prepare an emulsion, oil, powder, granule, wettable powder, wettable granule, flowable, dry flowable, microcapsule, etc.
  • the composition generally contains the compound of the present invention in an amount of 0.0001 to 95% by weight based on the total weight of the composition.
  • Solid carriers used in formulation include, for example, fine powders and granules of clays (kaolin clay, diatomaceous earth, bentonite, acid clay, etc.), dry silica, wet silica, talc, ceramics, other inorganic minerals (sericite, quartz, sulfur, activated carbon, calcium carbonate, etc.), chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, ammonium chloride, etc.), and synthetic resins (polyester resins such as polypropylene, polyacrylonitrile, polymethylmethacrylate, polyethylene terephthalate, nylon resins such as nylon-6, nylon-11, nylon-66, polyamide resins, polyvinyl chloride, polyvinylidene chloride, vinyl chloride-propylene copolymers, etc.).
  • clays kaolin clay, diatomaceous earth, bentonite, acid clay, etc.
  • dry silica wet silica
  • Liquid carriers include, for example, water, alcohols (methanol, ethanol, etc.), ketones (acetone, methyl ethyl ketone, etc.), aromatic hydrocarbons (toluene, xylene, etc.), aliphatic hydrocarbons (hexane, cyclohexane, etc.), esters (ethyl acetate, butyl acetate, etc.), nitriles (acetonitrile, etc.), ethers (diisopropyl ether, diethylene glycol dimethyl ether, etc.), amides (N,N-dimethylformamide, etc.), sulfoxides (dimethyl sulfoxide, etc.), and vegetable oils (soybean oil, cottonseed oil, etc.).
  • alcohols methanol, ethanol, etc.
  • ketones acetone, methyl ethyl ketone, etc.
  • aromatic hydrocarbons toluene, xylene, etc
  • Surfactants include, for example, nonionic surfactants such as polyoxyethylene alkyl ether or its salt (polyoxyethylene alkyl ether sulfate ammonium salt), polyoxyethylene alkyl aryl ether or its salt, and polyethylene glycol fatty acid ester, as well as anionic surfactants such as alkyl sulfonates, alkyl benzene sulfonates, and alkyl sulfates.
  • nonionic surfactants such as polyoxyethylene alkyl ether or its salt (polyoxyethylene alkyl ether sulfate ammonium salt), polyoxyethylene alkyl aryl ether or its salt, and polyethylene glycol fatty acid ester, as well as anionic surfactants such as alkyl sulfonates, alkyl benzene sulfonates, and alkyl sulfates.
  • formulation adjuvants include adhesives, dispersants, colorants, and stabilizers, such as casein, gelatin, sugars (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin derivatives, bentonite, synthetic water-soluble polymers (polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acids, etc.), isopropyl acid phosphate, BHT (2,6-di-tert-butyl-4-methylphenol), and BHA (a mixture of 2-tert-butyl-4-methoxyphenol and 3-tert-butyl-4-methoxyphenol).
  • adhesives such as casein, gelatin, sugars (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin derivatives, bentonite, synthetic water-soluble polymers (polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acids, etc.), isopropyl acid phosphate, BHT
  • the compounds of the present invention can control harmful arthropods such as harmful insects and harmful mites. Specific examples include the following.
  • Delphacidae such as the small brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), white-backed planthopper (Sogatella furcifera), corn planthopper (Peregrinus maidis), yellow-eared planthopper (Javesella pellucida), black horned planthopper (Perkinsiella saccharicida), Tagosodes orizicolus, and Stenocranus pacificus.
  • Delphacidae such as the small brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), white-backed planthopper (Sogatella furcifera), corn planthopper (Peregrinus maidis), yellow-eared planthopper (Javesella pellucida), black horned planthopper (Perkinsiella saccharicida), Tagosodes orizicolus, and Stenocranus pacificus.
  • Aphis pomi, snow willow aphid (Aphis spiraecola), green peach aphid (Myzus persicae), strawberry aphid (Brachycaudus helichrysi), radish aphid (Brevicoryne brassicae), rosy apple aphid (Dysaphis plantaginea), false radish aphid (Lipaphis erysimi), tulip long-horn aphid (Macrosiphum euphorbiae), oats Aulacorthum solani, lettuce aphid (Nasonovia ribisnigri), wheat curl aphid (Rhopalosiphum padi), corn aphid (Rhopalosiphum maidis), citrus black aphid (Toxoptera citricida), peach buttercup aphid (Hyalopterus pruni), barnyard millet aphid (Melana
  • the Miridae family such as the long-spined wheat grass bug (Stenodema calcarata) and the rusty whitefly (Lygus lineolaris); Trialeurodes vaporariorum, Bemisia tabaci, the Asian citrus whitefly (Dialeurodes citri), Aleurocanthus spiniferus, Aleurocanthus camelliae, and the Japanese whitefly (Aleurocanthus chinensis).
  • the family Aleyrodidae such as the whitefly (Pealius euryae); the family Coccinellidae, such as the palm scale insect (Abgrallaspis cyanophylli), the red scale insect (Aonidiella aurantii), the pear scale insect (Diaspidiotus perniciosus), the mulberry scale insect (Pseudaulacaspis pentagona), the Yanon scale insect (Unaspis yanonensis), and the false Yanon scale insect (Unaspis citri).
  • the family Coccinellidae such as the palm scale insect (Abgrallaspis cyanophylli), the red scale insect (Aonidiella aurantii), the pear scale insect (Diaspidiotus perniciosus), the mulberry scale insect (Pseudaulacaspis pentagona), the Yanon scale insect (Unaspis yanonensis), and the false
  • Psyllidae including Cacopsylla pyrisuga, Cacopsylla chinensis, Bactericera cockerelli, and Cacopsylla pyricola; Corythucha ciliata, Corythucha marmorata, Stephanitis nashi, and Stephanitis pyrioi des and other Tingidae; Cimicidae such as Cimex lectularius and Cimex hempterus; Cicadidae such as Quesada gigas; Reduviidae such as Triatoma infestans, Triatoma rubrofasciata, Triatoma dimidiata, and Rhodonius prolixus.
  • Lepidoptera Chilo suppressalis, Dark headed stem borer, Chilo polychrysus, White stem borer, Scirpophaga innotata, Scirpophaga incertulas, Rupela albina, Cnaphalocrocis medinalis, Marasmia patnalis, Marasmia exigua, Notarcha derogata, Ostrinia furnacalis, European corn borer, Hellula undalis, Herpetogramma luc Crambidae, such as the Japanese bush moth (Parapediasia teterrellus), the rice case worm (Nymphula depunctalis), the sugar cane borer (Diatraea saccharalis), and the eggplant fruit borer (Leucinodes orbonalis); Pyralidae, such as the corn moth (Elasmopalpus lignosellus), the Indian meal moth (Plodia interpunctella), the two-spotted moth (E
  • Heliothis virescens such as Heliothis virescens, Helicoverpa spp. such as Helicoverpa armigera, corn earworm (Helicoverpa zea), Noctuidae such as Velvet bean caterpillar (Anticarsia gemmatalis), cotton leafworm (Alabama argillacea), hop wine borer (Hydraecia immanis), Pieridae such as Pieris rapae, pear fruit moth (Grapholita molesta), plum fruit moth (Grapholita dimorpha), bean cicada (Coleoptera pedunculidae), Japanese quince (Pyral ...
  • Heliothis virescens such as Helicoverpa armigera, corn earworm (Helicoverpa zea), Noctuidae such as Velvet bean caterpillar (Anticarsia gemmatalis), cotton leafworm (Alabama argillacea), hop wine bore
  • Tortricidae such as the grass moth (Leguminivora glycinivorella), the bean pea moth (Matsumuraeses azukivora), the smaller apple tortrix moth (Adoxophyes orana fasciata), the smaller tea tortrix moth (Adoxophyes honmai), the tea tortrix moth (Homona magnima), the common tortrix moth (Archips fuscocupreanus), the codling moth (Cydia pomonella), the sugar candy moth (Tetramoera schistaceana), the bean shoot borer (Epinotia aporema), the citrus fruit borer (Citripestis sagittiferella), and the European grape wine moth (Lobesia botrana);
  • the Gracilariidae family includes the tea leaf moth (Caloptilia theivora) and the golden leaf moth (Phyllonorycter ringoniella); the Carposini
  • the family Plutellidae includes the long-legged moth (Plutella xylostella); the family Gelechiidae includes the peach leaf moth (Anarsia lineatella), the potato leaf moth (Helcystogramma triannulella), the red cotton moth (Pectinophora gossypiella), the potato tuber moth (Phthorimaea operculella), and the tomato leaf moth (Tuta absolutea); the family Arctiidae includes the fall webworm (Hyphantria cunea); the family Castniidae includes the giant sugarcane borer (Telchin licus); the family Cossidae includes the lesser cotton moth (Cossus insularis); the mugwort geometries (Ascotis selenaria) ), the Geometridae
  • Thysanoptera Thripidae, such as Frankliniella occidentalis, Thrips palmi, Scirtothrips dorsalis, Thrips tabaci, Frankliniella intonsa, Stenchaetothrips biformis, Echinothrips americanus, Scirtothrips perseae; Phlaeothripidae, such as Haplothrips aculeatus.
  • Diptera Anthomyiidae such as Delia platura, Delia antiqua, Pegomyia cunicularia, etc.; Ulidiidae such as Tetanops myopaeformis, etc.; Agromyza oryzae, Liriomyza sativae, Liriomyza trifolii, Chromatomyia horticola, etc.
  • Agromyzidae (Agromyzidae); Chloropidae (Chlorops oryzae), etc.; Bactrocera cucurbitae (Melon fly), Bactrocera dorsalis (Oriental fruit fly), Bactrocera latifrons (Eastern fruit fly), Bactrocera oleae (Olive fruit fly), Bactrocera tryoni (Queensland fruit fly), Ceratitis capitata (Mediterranean fruit fly), Rhagoletis pomonella (Apple maggot), Rhagoletis suzukii (Sugar apple fly), Tephritidae, such as Hacochlaena japonica; Ephydridae, such as Hydrellia griseola, Hydrellia philippina, and Hydrellia sasakii; Drosophilidae, such as Drosophila suzukii and Drosophila melanogaster; Megaselia spiracularis
  • Diabrotica spp. e.g. Western corn rootworm (Diabrotica virgifera virgifera), Southern corn rootworm (Diabrotica undecimpunctata howardi), Northern corn rootworm (Diabrotica barberi), Mexican corn rootworm (Diabrotica virgifera zeae), Banded cucumber beetle (Diabrotica balteata), Cucumber beetle (Diabrotica speciosa), etc.), Bean leaf beetle (Cerotoma trifurcata), Spotted neck leaf beetle (Oulema melanopus), Cucumber leaf beetle (Aulacophora femoralis), Striped flea beetle (Phyllotreta striolat a), cabbage free beetle (Phyllotreta cruciferae), western black free beetle (Phyllotreta pusilla), cabbage stem free beetle (Psylliodes chrys
  • fungus weevils such as Araecerus coffeee Family Anthriibidae; Family Aponidae such as sweet potato weevil (Cylas formicarius); Family Bruchidae such as Brazilian bean weevil (Zabrotes subfasciatus); Family Scolytidae such as pine bark beetle (Tomicus piniperda) and coffee berry borer (Hypothenemus hampei); Family Scolytidae such as potato weevil (Hypothenemus hampei); Bug (Euscepes postfasciatus), Alfalfa weevil (Hypera postica), Maize weevil (Sitophilus zeamais), Rice weevil (Sitophilus oryzae), Granary maize weevil (Sitophilus granarius), Rice weevil (Echinocnemus squameus), Rice water weevil (Lis
  • Aracanthus spp. such as the rust gourd weevil (Scepticus griseus), the brown gourd weevil (Scepticus uniformis), and Aracanthus mourei, and the cotton root borer (Eutinobothrus brasiliensis); Tenebrionidae such as the red flour beetle (Tribolium castaneum), the flat-headed red flour beetle (Tribolium confusum), and the mealworm beetle (Alphitobius diaperinus); Coccinellidae such as the 20-spotted ladybird beetle (Epilachna vigintioctopunctata); Lyctus brunneus, Rhizope rtha dominica; Ptinidae; Cerambycidae; Anoplophora malasiaca, Migdolus fryanus, Aromia bungii; Melanotus okinawensis, Brown-necked wire beet
  • the Dermestidae family including Anthrenus verbasci, Dermestes maculates, and Trogoderma granarium
  • the tobacco beetle Lasioderma serricorne
  • the Japanese cigar beetle Stepgobium paniceum and other Anobiidae
  • Brassicogethes aeneus and other Blossom Beetles Brassicogethes aeneus and other Blossom Beetles.
  • Hymenoptera Tenthredinidae such as Athalia rosae and Athalia japonica; Solenopsis spp. such as Solenopsis invicta and Solenopsis geminata; Atta spp.
  • Atta capiguara and Acro ant myrmex spp.
  • Paraponera clavata Ochetellus glaber
  • Monomorium pharaonis Argentine ant (Linepithema humile)
  • Formica japonica Pristomyrmex punctutus
  • Pheidole noda Pheidole megacephala
  • Camponotus spp. such as the Japanese camponotus (Camponotus japonicus), Camponotus spp., such as the red-breasted camponotus (Camponotus obscuripes)
  • Pogonomyrmex spp. such as Pogonomyrmex occidentalis
  • Wasmania spp. such as Wasmania auropunctata
  • Anoplolepis gracilipa such as Atta capiguara and Acro ant; myrmex spp.), Paraponera clavata, Ochetellus glaber, Monomor
  • Vespidae such as the giant hornet (Vespa mandarinia), the hairy hornet (Vespa simillima), the small hornet (Vespa analis), the red hornet (Vespa velutina), and the Japanese paper wasp (Polistes jokahamae); Siricidae (Wasps) such as the fir wasp (Urocerus gigas); and Bethylidae (Hornets).
  • Vespidae such as the giant hornet (Vespa mandarinia), the hairy hornet (Vespa simillima), the small hornet (Vespa analis), the red hornet (Vespa velutina), and the Japanese paper wasp (Polistes jokahamae); Siricidae (Wasps) such as the fir wasp (Urocerus gigas); and Bethylidae (Hornets).
  • Family Ectobiidae such as the German cockroach (Blattella germanica); Family Blattidae, such as the Siberian cockroach (Periplaneta fuliginosa), the American cockroach (Periplaneta americana), the American cockroach (Periplaneta australiae), the brown cockroach (Periplaneta brunnea), and the Asian cockroach (Blatta orientalis); Family Reticulitermes speratus, Formosan termite (Coptotermes formosanus), Formosan dry wood termite (Incisitermes minor), Formosan termite (Cryptotermes domesticus), Formosan termite (Odontotermes formosanus), and Formosan termite (Neotermes Termites of the family Termitidae, such as Glyptotermes satsumensis, Glyptotermes nakajimai, Glyptotermes fuscus,
  • Order Siphonaptera Family Pulicidae such as the human flea (Pulex irritans), cat flea (Ctenocephalides felis), dog flea (Ctenocephalides canis), rat flea (Xenopsylla cheopis), chicken flea (Echidnophaga gallinacea), etc.; Family Hectopsyllidae such as the sand flea (Tunga penetrans); Family Ceratophyllidae such as the European rat flea (Nosopsyllus fasciatus).
  • Family Pulicidae such as the human flea (Pulex irritans), cat flea (Ctenocephalides felis), dog flea (Ctenocephalides canis), rat flea (Xenopsylla cheopis), chicken flea (Echidnophaga gallinacea), etc.
  • Family Hectopsyllidae such as the sand flea (Tunga penetrans)
  • Psocodae Family Pediculidae such as head lice (Pediculus humanus capitis); Family Pthiridae such as pubic lice (Pthirus pubis); Family Haematopinidae such as cow lice (Haematopinus eurysternus) and pig lice (Haematopinus suis); Family Linognathus vituli, Sheep trunk lice Family Linognathidae, such as body lice (Linognathus ovillus) and cow lice (Solenopotes capillatus); Family Bovicoliidae, such as cow lice (Bovicola bovis), sheep lice (Bovicola ovis), Bovicola breviceps, Damalinia forficula, and Werneckiella spp.; Family Bovicoliidae, such as dog lice (T Family Trichodectidae, such as the cat louse (Felicola subrostratus) and the chicken louse
  • Menoponidae such as the chicken louse (Menopon gallinae), the chicken louse (Menacanthus stramineus), and the Trinoton spp. family Trinoton spp. family Cummingsia spp. family noponidae); Trogiidae, such as Trogium pulsatorium; Liposcelidae or Liposcelididae, such as Liposcelis corrodens, Liposcelis bostrychophila, Liposcelis pearmani, and Liposcelis entomophila.
  • Thysanura Family Lepismatidae, including the Japanese silverfish (Ctenolepisma villosa) and the European silverfish (Lepisma saccharina).
  • Eriophyidae such as Acarus carinatus, Acaphylla theavagrans, Eriophyes chibaensis, Aculus Louendali, Aceria diospyri, Aceria tosichella, Shevtchenkella sp.; Tarsonemidae, such as Polyphagotarsonemus latus; Deutzia purpurea, such as Brevipalpus phoenicis.
  • Order Araneae Family Eutichuridae such as Cheiracanthium japonicum; Family Theridiidae such as Latrodectus hasseltii.
  • Polydesmida Paradoxosomatidae, including Oxidus gracilis, Nedyopus tambanus, etc.
  • Isopoda Family Armadillidiidae, including Armadillidium vulgare.
  • Chilopoda Scutigeridae such as Thereuonema hilgendorfi; Scolopendridae such as Scolopendra subspinipes; Ethopolyidae such as Bothropolys rugosus.
  • the harmful arthropods such as harmful insects and harmful mites may be harmful arthropods such as harmful insects and harmful mites that have reduced sensitivity to insecticides, acaricides, etc., or that have developed resistance to such drugs.
  • composition A is a composition (hereinafter referred to as composition A) containing the compound of the present invention and at least one compound selected from the group consisting of metofluthrin and dimefluthrin.
  • Metofluthrin and dimefluthrin can be used alone or in combination of two types.
  • metofluthrin and dimefluthrin each have one or more stereoisomers, and the metofluthrin and dimefluthrin used in the present invention include stereoisomers and mixtures thereof.
  • the ratio of the compound of the present invention to at least one compound selected from the group consisting of metofluthrin and dimefluthrin is not particularly limited, but may be, in terms of mass ratio (compound of the present invention:at least one compound selected from the group consisting of metofluthrin and dimefluthrin), 100,000:1 to 1:100,000, 50,000:1 to 1:50,000, , 10,000:1 to 1:10,000, 1,000:1 to 1:1000, 500:1 to 1:500, 100:1 to 1:100, 50:1, 20:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:20, 1:50, and the like.
  • composition A containing at least one compound selected from the group consisting of metofluthrin and dimefluthrin is expected to have excellent control effects against harmful arthropods.
  • harmful arthropods that can be controlled by composition A include those mentioned above.
  • the method for controlling harmful arthropods of the present invention is carried out by applying an effective amount of the compound of the present invention or composition A directly to the harmful arthropods and/or to the habitat of the harmful arthropods (plants, soil, inside a house, animals, etc.).
  • Examples of the method for controlling harmful arthropods of the present invention include foliage treatment, soil treatment, root treatment, shower treatment, fumigation treatment, water surface treatment and seed treatment.
  • the application amount is usually 1 to 10,000 g of the compound of the present invention per 10,000 m 2.
  • the compound of the present invention or composition A is formulated as an emulsifiable concentrate, wettable powder, flowable agent or the like, it is usually applied after diluting with water so that the active ingredient concentration becomes 0.01 to 10,000 ppm (for example, 1,000 ppm), and granules, dusts, etc. are usually applied as they are.
  • the application amount is usually 0.01 to 1000 mg of the compound of the present invention per m2 of treatment area when applied on a surface, and usually 0.01 to 500 mg of the compound of the present invention per m3 of treatment space when applied in a space.
  • the compound of the present invention or composition A is formulated as an emulsifiable concentrate, wettable powder, flowable agent, etc., it is usually applied after diluting with water so that the active ingredient concentration is 0.1 to 10000 ppm, and oil solutions, aerosols, fumigants, poison baits, etc. are applied as they are.
  • composition B is usually prepared by mixing the compound of the present invention or composition A with a liquid carrier, a surfactant, etc., and adding formulation auxiliaries such as a thickener, a binder, a dispersant, a stabilizer, and a gas, if necessary, to be used as an oil solution, an emulsion, a wettable powder, a flowable agent (suspension in water, emulsion in water, etc.), a powder, a granule, an aerosol agent (direct spray type, space spray type, metered spray type, one-push type, total spray type, intermittent spray type, etc.), a spray, an electric spray (ultrasonic vibration type, electrostatic spray type, etc.), a heated transpiration agent (incense stick, electric mat, liquid-absorbing wick type heated transpiration agent, etc.), a non-heated transpiration agent (incense stick, electric mat, liquid-absorbing wick type heated transpiration agent, etc.), a non-heated transpiration agent (
  • a formulation that is one embodiment of the present invention is a formulation containing the compound of the present invention or Composition A, which is selected from the group consisting of an oil solution, an emulsion, a flowable agent, an aerosol agent, a heated evaporation agent, a non-heated evaporation agent, a fog agent, and a ULV agent.
  • These preparations usually contain the compound of the present invention or composition A in an amount of 0.0001 to 99% by weight based on the total weight of the preparation.
  • liquid carriers examples include water, alcohols (ethanol, cyclohexanol, benzyl alcohol, propylene glycol, polyethylene glycol, etc.), ketones (acetone, cyclohexanone, methyl ethyl ketone, etc.), aromatic hydrocarbons (benzene, toluene, xylene, ethylbenzene, methylnaphthalene, phenylxylylethane, etc.), aliphatic hydrocarbons (hexane, cyclohexane, etc.), esters (ethyl acetate, butyl acetate, methyl oleate, etc.), nitriles (acetonitrile, isobutyronitrile, etc.), ethers (diisopropyl ether, dioxane, etc.), amides (N,N-dimethylformamide, N,N-dimethylacetamide, etc.), halogenated hydrocarbons (d
  • a composition according to one embodiment of the present invention is a composition containing the compound of the present invention or composition A and one or more liquid carriers selected from the group consisting of water, alcohols, ketones, aromatic hydrocarbons, aliphatic hydrocarbons, esters, nitriles, ethers, amides, halogenated hydrocarbons, sulfoxides, mineral oils, and vegetable oils.
  • a formulation according to one embodiment of the present invention is a formulation containing the composition and selected from the group consisting of oil solutions, emulsions, flowables, aerosols, heat evaporation agents, and ULV agents.
  • surfactant examples include alkyl sulfates, alkyl sulfonates, alkylaryl sulfonates, alkylaryl ethers, polyoxyethylated alkylaryl ethers, polyethylene glycol ethers, polyhydric alcohol esters, and sugar alcohol derivatives.
  • the composition according to one embodiment of the present invention is a composition containing the compound of the present invention or composition A and one or more surfactants selected from the group consisting of alkyl sulfates, alkyl sulfonates, alkylaryl sulfonates, alkylaryl ethers, polyoxyethylated alkylaryl ethers, polyethylene glycol ethers, polyhydric alcohol esters, and sugar alcohol derivatives.
  • the formulation according to one embodiment of the present invention is a formulation containing the composition and selected from the group consisting of emulsions, flowables, and heat-transferables.
  • a composition according to one embodiment of the present invention is a composition containing the compound of the present invention or composition A and one or more thickeners selected from the group consisting of casein, gelatin, polysaccharides, lignin derivatives, bentonite, and synthetic water-soluble polymers.
  • a formulation according to one embodiment of the present invention is a flowable preparation containing the composition.
  • Antioxidants include, for example, BHT (2,6-di-tert-butyl-4-methylphenol) and BHA (a mixture of 2-tert-butyl-4-methoxyphenol and 3-tert-butyl-4-methoxyphenol).
  • a composition which is one embodiment of the present invention is a composition containing the compound of the present invention or composition A and one or more antioxidants selected from the group consisting of BHT and BHA.
  • a formulation which is one embodiment of the present invention is a formulation which contains the composition and is selected from the group consisting of oil solutions, emulsions, flowables, aerosols, heated transpiration agents, non-heated transpiration agents, aerosols, and ULV agents.
  • the composition according to one embodiment of the present invention is a composition in which the compound of the present invention or composition A is supported on a vegetable powder (wood flour, meal powder, etc.).
  • the vegetable powder may be used by mixing the vegetable powder with a binder (tab flour, starch, gluten, etc.).
  • the preparation according to one embodiment of the present invention is a heat-transpirable agent containing the composition.
  • a composition according to another embodiment of the present invention is a composition containing the compound of the present invention or composition A and a binder.
  • a preparation according to one embodiment of the present invention is a heat-transferable agent containing the composition.
  • the composition which is one embodiment of the present invention, is a composition in which the compound of the present invention or composition A is supported on one or more substrates selected from the group consisting of cotton linters and pulp.
  • substrates selected from the group consisting of cotton linters and pulp.
  • Specific examples of the substrate include cotton linters solidified into a plate shape and fibers of a mixture of cotton linters and pulp solidified into a plate shape.
  • the formulation which is one embodiment of the present invention, is a heat-transpirable agent containing the composition.
  • composition according to one embodiment of the present invention is a composition in which the compound of the present invention or composition A is supported on a thermoplastic resin or paper. Also, the preparation according to one embodiment of the present invention is a non-heated evaporative agent containing the composition.
  • the resin examples include polyethylene resins such as low-density polyethylene, linear low-density polyethylene, and high-density polyethylene; ethylene-vinyl ester copolymers such as ethylene-vinyl acetate copolymer; ethylene-methacrylic acid ester copolymers such as ethylene-methyl methacrylate copolymer and ethylene-ethyl methacrylate copolymer; ethylene-acrylic acid ester copolymers such as ethylene-methyl acrylate copolymer and ethylene-ethyl acrylate copolymer; ethylene-vinyl carboxylic acid copolymers such as ethylene-acrylic acid copolymer; ethylene-tetracyclododecene copolymer; polypropylene resins such as propylene polymers and propylene-ethylene copolymers; poly-4-methylpentene-1, polybutene-1, polybutadiene, polystyrene, and acrylonitrile
  • compositions which is another embodiment of the present invention is a composition in which the compound of the present invention or composition A is supported on a thermoplastic resin.
  • a composition which is yet another embodiment of the present invention is a composition in which the compound of the present invention or composition A is supported on paper.
  • Comparative Example 1 instead of the compound 1 of the present invention, compound A described in Japanese Patent No. 3728967 (Patent Document 1) was used as a test compound, and the test was carried out in the same manner as in Test Example 1. The mortality rate (average value of three repetitions) was 7%.
  • the compound of the present invention exhibits excellent control effects against harmful arthropods.

Landscapes

  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The present invention provides a compound having excellent control efficacy against harmful arthropods. The compound, represented by formula (I), has excellent control efficacy against harmful arthropods.

Description

エステル化合物及びその用途Ester compounds and their uses
　本特許出願は、日本国特許出願２０２３－２１６４７１号（２０２３年１２月２２日出願）に基づくパリ条約上の優先権及びその利益を主張するものであり、その全内容は参照することにより本出願に組み込まれる。
　本発明はエステル化合物及びその用途に関する。 This patent application claims priority under the Paris Convention based on Japanese Patent Application No. 2023-216471 (filed on December 22, 2023), and the benefit thereof, the entire contents of which are incorporated herein by reference.
The present invention relates to an ester compound and its use.
　特許文献１には、優れた殺虫活性を有する化合物として式（Ａ）
Figure JPOXMLDOC01-appb-C000002
 で示されるエステル化合物（以下、化合物Ａと記す）が記載されている。 In Patent Document 1, a compound represented by the formula (A) is disclosed as having excellent insecticidal activity.
Figure JPOXMLDOC01-appb-C000002
 An ester compound represented by the formula (hereinafter referred to as compound A) is described.
特許第３７２８９６７号公報Patent No. 3728967
　本発明は、有害節足動物に対して優れた防除効力を有する化合物を提供することを課題とする。 The objective of the present invention is to provide a compound that has excellent control effect against harmful arthropods.
　本発明者は、有害節足動物に対して優れた防除効力を有する化合物を見出すべく検討した結果、下記式（Ｉ）で示される化合物が、有害節足動物に対して優れた防除効力を有することを見出した。
　本発明は、以下のとおりである。
［１］　式（Ｉ）：
Figure JPOXMLDOC01-appb-C000003
 で示される化合物（以下、本発明化合物と記す）。
［２］　［１］に記載の化合物と、不活性担体とを含有する組成物。
［３］　［１］に記載の化合物の有効量を有害節足動物又は有害節足動物の生息場所に施用することによる、有害節足動物の防除方法。
［４］　［１］に記載の化合物と、メトフルトリン及びジメフルトリンからなる群より選ばれる１以上の化合物とを含有する組成物。
［５］　［１］に記載の化合物又は［４］に記載の組成物と、水、アルコール類、ケトン類、芳香族炭化水素類、脂肪族炭化水素類、エステル類、ニトリル類、エーテル類、アミド類、ハロゲン化炭化水素類、スルホキシド類、鉱物油類及び植物油類からなる群より選ばれる１以上の液体担体とを含有する組成物。
［６］　［１］に記載の化合物又は［４］に記載の組成物と、アルキル硫酸エステル塩、アルキルスルホン酸塩、アルキルアリールスルホン酸塩、アルキルアリールエーテル類、アルキルアリールエーテル類のポリオキシエチレン化物、ポリエチレングリコールエーテル類、多価アルコールエステル類及び糖アルコール誘導体からなる群より選ばれる１以上の界面活性剤とを含有する組成物。
［７］　［１］に記載の化合物又は［４］に記載の組成物と、カゼイン、ゼラチン、多糖類、リグニン誘導体、ベントナイト、及び合成水溶性高分子からなる群より選ばれる１以上の増粘剤とを含有する組成物。
［８］　［１］に記載の化合物又は［４］に記載の組成物と、ＢＨＴ（２，６－ジ－ｔ－ブチル－４－メチルフェノール）及びＢＨＡ（２－ｔ－ブチル－４－メトキシフェノールと３－ｔ－ブチル－４－メトキシフェノールとの混合物）からなる群より選ばれる１以上の酸化防止剤とを含有する組成物。
［９］　［１］に記載の化合物又は［４］に記載の組成物を、植物性粉末に担持させた組成物。
［１０］　［１］に記載の化合物又は［４］に記載の組成物と、結合剤とを含有する組成物。
［１１］　［１］に記載の化合物又は［４］に記載の組成物を、コットンリンター及びパルプからなる群より選ばれる１以上の基材に担持させた組成物。
［１２］　［１］に記載の化合物又は［４］に記載の組成物を、熱可塑性樹脂又は紙に担持させた組成物。
［１３］　［１］に記載の化合物又は［４］に記載の組成物を含有する、油剤、乳剤、フロアブル剤、エアゾール剤、加熱蒸散剤、非加熱蒸散剤、煙霧剤、及びＵＬＶ剤からなる群より選ばれる製剤。 The present inventors have conducted studies to find a compound having excellent control activity against harmful arthropods, and as a result, have found that a compound represented by the following formula (I) has excellent control activity against harmful arthropods.
The present invention is as follows.
[1] Formula (I):
Figure JPOXMLDOC01-appb-C000003
 (hereinafter, referred to as the compound of the present invention).
[2] A composition comprising the compound according to [1] and an inert carrier.
[3] A method for controlling harmful arthropods, which comprises applying an effective amount of the compound according to [1] to the harmful arthropods or to a habitat of the harmful arthropods.
[4] A composition comprising the compound according to [1] and one or more compounds selected from the group consisting of metofluthrin and dimefluthrin.
[5] A composition comprising the compound according to [1] or the composition according to [4], and one or more liquid carriers selected from the group consisting of water, alcohols, ketones, aromatic hydrocarbons, aliphatic hydrocarbons, esters, nitriles, ethers, amides, halogenated hydrocarbons, sulfoxides, mineral oils, and vegetable oils.
[6] A composition comprising the compound according to [1] or the composition according to [4], and one or more surfactants selected from the group consisting of alkyl sulfate salts, alkyl sulfonate salts, alkylaryl sulfonate salts, alkylaryl ethers, polyoxyethylated alkylaryl ethers, polyethylene glycol ethers, polyhydric alcohol esters, and sugar alcohol derivatives.
[7] A composition comprising the compound according to [1] or the composition according to [4] and one or more thickeners selected from the group consisting of casein, gelatin, polysaccharides, lignin derivatives, bentonite, and synthetic water-soluble polymers.
[8] A composition comprising the compound according to [1] or the composition according to [4], and one or more antioxidants selected from the group consisting of BHT (2,6-di-t-butyl-4-methylphenol) and BHA (a mixture of 2-t-butyl-4-methoxyphenol and 3-t-butyl-4-methoxyphenol).
[9] A composition comprising the compound according to [1] or the composition according to [4] supported on a plant powder.
[10] A composition comprising the compound according to [1] or the composition according to [4] and a binder.
[11] A composition comprising the compound according to [1] or the composition according to [4] supported on one or more substrates selected from the group consisting of cotton linters and pulp.
[12] A composition in which the compound according to [1] or the composition according to [4] is supported on a thermoplastic resin or paper.
[13] A preparation containing the compound according to [1] or the composition according to [4], the preparation being selected from the group consisting of an oil solution, an emulsion, a flowable agent, an aerosol agent, a heated evaporation agent, a non-heated evaporation agent, a fog agent, and an ULV agent.
　本発明により、有害節足動物を防除することができる。 The present invention makes it possible to control harmful arthropods.
　本発明化合物には、一つ以上の立体異性体が存在する。立体異性体としては、光学異性体及び幾何異性体が挙げられる。本発明には各光学異性体、各幾何異性体、及び任意の比率の異性体混合物が含まれる。 The compound of the present invention has one or more stereoisomers. Stereoisomers include optical isomers and geometric isomers. The present invention includes each optical isomer, each geometric isomer, and a mixture of isomers in any ratio.
　本発明化合物の光学異性体としては、例えば、式（ＩＩ）：
Figure JPOXMLDOC01-appb-C000004
 で示される化合物及び式（ＩＩＩ）：
Figure JPOXMLDOC01-appb-C000005
 で示される化合物が挙げられる。 The optical isomer of the compound of the present invention includes, for example, a compound represented by the formula (II):
Figure JPOXMLDOC01-appb-C000004
 and a compound of formula (III):
Figure JPOXMLDOC01-appb-C000005
 Examples of the compound include those represented by the following formula:
　本発明化合物として、式（ＩＩ）で示される光学異性体又は該光学異性体を多く含む異性体混合物を使用するのが好ましい。 As the compound of the present invention, it is preferable to use the optical isomer represented by formula (II) or a mixture of isomers rich in said optical isomer.
　本発明化合物の幾何異性体としては、例えば、式（ＩＶ）で示される化合物が挙げられる。
Figure JPOXMLDOC01-appb-C000006
 The geometric isomer of the compound of the present invention includes, for example, the compound represented by formula (IV).
Figure JPOXMLDOC01-appb-C000006
　また、式（ＩＶ）で示される化合物の光学異性体としては、例えば、式（Ｖ）：
Figure JPOXMLDOC01-appb-C000007
 で示される化合物及び式（ＶＩ）：
Figure JPOXMLDOC01-appb-C000008
 で示される化合物が挙げられる。 As the optical isomer of the compound represented by formula (IV), for example, the compound represented by formula (V):
Figure JPOXMLDOC01-appb-C000007
 and compounds of formula (VI):
Figure JPOXMLDOC01-appb-C000008
 Examples of the compound include those represented by the following formula:
　本発明化合物として、式（Ｉ）で示される幾何異性体又は該幾何異性体を多く含む異性体混合物を使用するのが好ましく、式（Ｖ）で示される幾何異性体又は該幾何異性体を多く含む異性体混合物を使用するのがさらに好ましい。 As the compound of the present invention, it is preferable to use a geometric isomer represented by formula (I) or a mixture of isomers rich in said geometric isomer, and it is even more preferable to use a geometric isomer represented by formula (V) or a mixture of isomers rich in said geometric isomer.
　本発明化合物の態様として、以下の化合物が挙げられる。
　式（ＩＩ）で示される化合物。
　式（ＩＩ）で示される化合物と式（ＩＩＩ）で示される化合物とを含む混合物。
　式（ＩＩ）で示される光学異性体を多く含む、光学異性体混合物。
　式（Ｉ）で示される化合物と式（ＩＶ）で示される化合物とを含む混合物。
　式（Ｉ）で示される幾何異性体を多く含む、幾何異性体混合物。
　式（ＩＩ）で示される化合物と式（Ｖ）で示される化合物とを含む混合物。
　式（ＩＩ）で示される幾何異性体を多く含む、幾何異性体混合物。 The embodiments of the compound of the present invention include the following compounds.
A compound represented by formula (II):
A mixture comprising a compound represented by formula (II) and a compound represented by formula (III).
A mixture of optical isomers enriched in the optical isomer represented by formula (II).
A mixture comprising a compound represented by formula (I) and a compound represented by formula (IV).
A mixture of geometric isomers containing an enriched geometric isomer represented by formula (I).
A mixture comprising a compound represented by formula (II) and a compound represented by formula (V).
A mixture of geometric isomers containing an enriched geometric isomer represented by formula (II).
　本発明の１つの実施形態である組成物は、本発明化合物と不活性担体とを含有する組成物である。前記組成物は、通常、本発明化合物と固体担体、液体担体等の不活性担体とを混合し、必要に応じて界面活性剤、その他の製剤用補助剤を添加して、乳剤、油剤、粉剤、粒剤、水和剤、顆粒水和剤、フロアブル剤、ドライフロアブル剤、マイクロカプセル剤等に製剤化される。
　前記組成物は、本発明化合物を通常、組成物の総重量に対して、０．０００１～９５重量％含有する。 The composition according to one embodiment of the present invention is a composition containing the compound of the present invention and an inert carrier. The composition is usually prepared by mixing the compound of the present invention with an inert carrier such as a solid carrier or a liquid carrier, and adding a surfactant or other formulation auxiliary as necessary to prepare an emulsion, oil, powder, granule, wettable powder, wettable granule, flowable, dry flowable, microcapsule, etc.
The composition generally contains the compound of the present invention in an amount of 0.0001 to 95% by weight based on the total weight of the composition.
　製剤化の際に用いられる固体担体としては、例えば粘土類（カオリンクレー、珪藻土、ベントナイト、酸性白土等）、乾式シリカ、湿式シリカ、タルク、セラミック、その他の無機鉱物（セリサイト、石英、硫黄、活性炭、炭酸カルシウム等）、化学肥料（硫安、燐安、硝安、尿素、塩安等）等の微粉末及び粒状物等、並びに合成樹脂（ポリプロピレン、ポリアクリロニトリル、ポリメタクリル酸メチル、ポリエチレンテレフタレート等のポリエステル樹脂、ナイロン－６、ナイロン－１１、ナイロン－６６等のナイロン樹脂、ポリアミド樹脂、ポリ塩化ビニル、ポリ塩化ビニリデン、塩化ビニル－プロピレン共重合体等）が挙げられる。 Solid carriers used in formulation include, for example, fine powders and granules of clays (kaolin clay, diatomaceous earth, bentonite, acid clay, etc.), dry silica, wet silica, talc, ceramics, other inorganic minerals (sericite, quartz, sulfur, activated carbon, calcium carbonate, etc.), chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, ammonium chloride, etc.), and synthetic resins (polyester resins such as polypropylene, polyacrylonitrile, polymethylmethacrylate, polyethylene terephthalate, nylon resins such as nylon-6, nylon-11, nylon-66, polyamide resins, polyvinyl chloride, polyvinylidene chloride, vinyl chloride-propylene copolymers, etc.).
　液体担体としては、例えば水、アルコール類（メタノール、エタノール等）、ケトン類（アセトン、メチルエチルケトン等）、芳香族炭化水素類（トルエン、キシレン等）、脂肪族炭化水素類（ヘキサン、シクロヘキサン等）、エステル類（酢酸エチル、酢酸ブチル等）、ニトリル類（アセトニトリル等）、エーテル類（ジイソプロピルエーテル、ジエチレングリコールジメチルエーテル等）、アミド類（Ｎ，Ｎ－ジメチルホルムアミド等）、スルホキシド類（ジメチルスルホキシド等）、及び植物油（大豆油、綿実油等）が挙げられる。 Liquid carriers include, for example, water, alcohols (methanol, ethanol, etc.), ketones (acetone, methyl ethyl ketone, etc.), aromatic hydrocarbons (toluene, xylene, etc.), aliphatic hydrocarbons (hexane, cyclohexane, etc.), esters (ethyl acetate, butyl acetate, etc.), nitriles (acetonitrile, etc.), ethers (diisopropyl ether, diethylene glycol dimethyl ether, etc.), amides (N,N-dimethylformamide, etc.), sulfoxides (dimethyl sulfoxide, etc.), and vegetable oils (soybean oil, cottonseed oil, etc.).
　界面活性剤としては、例えばポリオキシエチレンアルキルエーテル若しくはその塩（ポリオキシエチレンアルキルエーテルサルフェートアンモニウム塩）、ポリオキシエチレンアルキルアリールエーテル若しくはその塩、ポリエチレングリコール脂肪酸エステル等の非イオン界面活性剤、及びアルキルスルホン酸塩、アルキルベンゼンスルホン酸塩、アルキル硫酸塩等の陰イオン界面活性剤が挙げられる。 Surfactants include, for example, nonionic surfactants such as polyoxyethylene alkyl ether or its salt (polyoxyethylene alkyl ether sulfate ammonium salt), polyoxyethylene alkyl aryl ether or its salt, and polyethylene glycol fatty acid ester, as well as anionic surfactants such as alkyl sulfonates, alkyl benzene sulfonates, and alkyl sulfates.
　その他の製剤用補助剤としては、固着剤、分散剤、着色剤及び安定剤等、具体的には例えばカゼイン、ゼラチン、糖類（でんぷん、アラビアガム、セルロース誘導体、アルギン酸等）、リグニン誘導体、ベントナイト、合成水溶性高分子（ポリビニルアルコール、ポリビニルピロリドン、ポリアクリル酸類等）、酸性リン酸イソプロピル、ＢＨＴ（２，６－ジ－ｔｅｒｔ－ブチル－４－メチルフェノール）、ＢＨＡ（２－ｔｅｒｔ－ブチル－４－メトキシフェノールと３－ｔｅｒｔ－ブチル－４－メトキシフェノールとの混合物）が挙げられる。 Other formulation adjuvants include adhesives, dispersants, colorants, and stabilizers, such as casein, gelatin, sugars (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin derivatives, bentonite, synthetic water-soluble polymers (polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acids, etc.), isopropyl acid phosphate, BHT (2,6-di-tert-butyl-4-methylphenol), and BHA (a mixture of 2-tert-butyl-4-methoxyphenol and 3-tert-butyl-4-methoxyphenol).
　本発明化合物は、有害昆虫、有害ダニ類等の有害節足動物を防除することが出来る。具体的には、例えば、以下のものが挙げられる。 The compounds of the present invention can control harmful arthropods such as harmful insects and harmful mites. Specific examples include the following.
　半翅目(Hemiptera)：ヒメトビウンカ(Laodelphax striatellus)、トビイロウンカ(Nilaparvata lugens)、セジロウンカ(Sogatella furcifera)、トウモロコシウンカ(Peregrinus maidis)、キタウンカ(Javesella pellucida)、クロフツノウンカ(Perkinsiella saccharicida)、Tagosodes orizicolus、Stenocranus pacificus等のウンカ科(Delphacidae)；ツマグロヨコバイ(Nephotettix cincticeps)、タイワンツマグロヨコバイ(Nephotettix virescens)、クロスジツマグロヨコバイ(Nephotettix nigropictus)、イナズマヨコバイ(Recilia dorsalis)、チャノミドリヒメヨコバイ(Empoasca onukii)、ジャガイモヒメヨコバイ(Empoasca fabae)、コーンリーフホッパー(Dalbulus maidis)、シロオオヨコバイ(Cofana spectra)、Amrasca biguttula biguttula等のヨコバイ科(Cicadellidae)；ヨーロピアンスピトルバグ(Philaenus spumarius)等のアワフキムシ科(Aphrophoridae); Mahanarva posticata、Mahanarva fimbriolata等のコガシラアワフキムシ科(Cercopidae)；マメクロアブラムシ(Aphis fabae)、ダイズアブラムシ(Aphis glycines)、ワタアブラムシ(Aphis gossypii)、ヨーロッパリンゴアブラムシ(Aphis pomi)、ユキヤナギアブラムシ(Aphis spiraecola)、モモアカアブラムシ(Myzus persicae)、ムギワラギクオマルアブラムシ(Brachycaudus helichrysi)、ダイコンアブラムシ(Brevicoryne brassicae)、rosy apple aphid(Dysaphis plantaginea)、ニセダイコンアブラムシ(Lipaphis erysimi)、チューリップヒゲナガアブラムシ(Macrosiphum euphorbiae)、ジャガイモヒゲナガアブラムシ(Aulacorthum solani)、レタスヒゲナガアブラムシ(Nasonovia ribisnigri)、ムギクビレアブラムシ(Rhopalosiphum padi)、トウモロコシアブラムシ(Rhopalosiphum maidis)、ミカンクロアブラムシ(Toxoptera citricida)、モモコフキアブラムシ(Hyalopterus pruni)、ヒエノアブラムシ(Melanaphis sacchari)、オカボノクロアブラムシ(Tetraneura nigriabdominalis)、カンシャワタアブラムシ(Ceratovacuna lanigera)、リンゴワタムシ(Eriosoma lanigerum)、イングリッシュグレインエイフィッド（Sitobion avenae）等のアブラムシ科(Aphididae)；ブドウネアブラムシ(Daktulosphaira vitifoliae)、ピーカンフィロキセラ(Phylloxera devastatrix)、ピーカンリーフフィロキセラ (Phylloxera notabilis)、サウザンピーカンリーフフィロキセラ(Phylloxera russelae)等のネアブラムシ科(Phylloxeridae)；ツガカサアブラムシ(Adelges tsugae)、バルサムウーリーアフィッド(Adelges piceae)、ヒメカサアブラムシ(Aphrastasia pectinatae)等のカサアブラムシ科(Adelgidae)；イネクロカメムシ(Scotinophara lurida)、ブラックパディーバグ(Scotinophara coarctata)、アオクサカメムシ(Nezara antennata)、トゲシラホシカメムシ(Eysarcoris aeneus)、オオトゲシラホシカメムシ(Eysarcoris lewisi)、シラホシカメムシ(Eysarcoris ventralis)、ムラサキシラホシカメムシ(Eysarcoris annamita)、クサギカメムシ(Halyomorpha halys)、ミナミアオカメムシ(Nezara viridula)、ブラウンスティンクバグ(Euschistus heros)、レッドバンデッドスティンクバグ(Piezodorus guildinii)、Oebalus pugnax、Dichelops melacanthus、イチモンジカメムシ(Piezodorus hybneri)等のカメムシ科(Pentatomidae)；Scaptocoris castanea等のツチカメムシ科(Cydnidae)；ホソヘリカメムシ(Riptortus clavatus)、クモヘリカメムシ(Leptocorisa chinensis)、ホソクモヘリカメムシ(Leptocorisa acuta)等のホソヘリカメムシ科(Alydidae)；ホソハリカメムシ(Cletus punctiger)、アシビロヘリカメムシ(Leptoglossus australis)等のヘリカメムシ科(Coreidae)；カンシャコバネナガカメムシ(Cavelerius saccharivorus)、コバネヒョウタンナガカメムシ(Togo hemipterus)、アメリカコバネナガカメムシ(Blissus leucopterus)等のナガカメムシ科(Lygaeidae)；アカヒゲホソミドリカスミカメ(Trigonotylus caelestialium)、アカスジカスミカメ(Stenotus rubrovittatus)、フタトゲムギカスミカメ(Stenodema calcarata)、サビイロカスミカメ(Lygus lineolaris)等のカスミカメムシ科(Miridae)；オンシツコナジラミ(Trialeurodes vaporariorum)、タバココナジラミ(Bemisia tabaci)、ミカンコナジラミ(Dialeurodes citri)、ミカントゲコナジラミ(Aleurocanthus spiniferus)、チャトゲコナジラミ(Aleurocanthus camelliae)、ヒサカキワタフキコナジラミ(Pealius euryae)等のコナジラミ科(Aleyrodidae)；シュロマルカイガラムシ(Abgrallaspis cyanophylli)、アカマルカイガラムシ(Aonidiella aurantii)、ナシマルカイガラムシ(Diaspidiotus perniciosus)、クワシロカイガラムシ(Pseudaulacaspis pentagona)、ヤノネカイガラムシ(Unaspis yanonensis)、ニセヤノネカイガラムシ(Unaspis citri)等のマルカイガラムシ科(Diaspididae)；ルビーロウムシ(Ceroplastes rubens)等のカタカイガラムシ科(Coccidae)；イセリアカイガラムシ(Icerya purchasi)、キイロワタフキカイガラムシ(Icerya seychellarum)等のワタフキカイガラムシ科(Margarodidae)；ナスコナガイガラムシ(Phenacoccus solani)、クロテンコナカイガラムシ(Phenacoccus solenopsis)、フジコナカイガラムシ(Planococcus kraunhiae)、クワコナカイガラムシ(Pseudococcus comstocki)、ミカンコナカイガラムシ(Planococcus citri)、ガハニコナカイガラムシ(Pseudococcus calceolariae)、ナガオコナカイガラムシ(Pseudococcus longispinus)、タトルミーリーバグ(Brevennia rehi)等のコナカイガラムシ科(Pseudococcidae)；ミカンキジラミ(Diaphorina citri)、ミカントガリキジラミ(Trioza erytreae)、ナシキジラミ(Cacopsylla pyrisuga)、チュウゴクナシキジラミ(Cacopsylla chinensis)、ジャガイモトガリキジラミ(Bactericera cockerelli)、ピアプシラ(Cacopsylla pyricola)等のキジラミ科(Psyllidae)；プラタナスグンバイ(Corythucha ciliata)、アワダチソウグンバイ(Corythucha marmorata)、ナシグンバイ(Stephanitis nashi)、ツツジグンバイ(Stephanitis pyrioides)等のグンバイムシ科(Tingidae)；トコジラミ(Cimex lectularius)、ネッタイトコジラミ(Cimex hemipterus)等のトコジラミ科(Cimicidae)；Quesada gigas等のセミ科(Cicadidae)；ブラジルサシガメ(Triatoma infestans)、オオサシガメ（Triatoma rubrofasciata）、Triatoma dimidiata、ベネズエラサシガメ(Rhodonius prolixus)等のサシガメ科(Reduviidae)。 Hemiptera: Delphacidae, such as the small brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), white-backed planthopper (Sogatella furcifera), corn planthopper (Peregrinus maidis), yellow-eared planthopper (Javesella pellucida), black horned planthopper (Perkinsiella saccharicida), Tagosodes orizicolus, and Stenocranus pacificus. dae); green rice leafhopper (Nephotettix cincticeps), Taiwan green rice leafhopper (Nephotettix virescens), black-striped green rice leafhopper (Nephotettix nigropictus), lightning leafhopper (Recilia dorsalis), tea green leafhopper (Empoasca onukii), potato leafhopper (Empoasca fabae), corn leafhopper (Dalbulus maidis), white giant leafhopper (Cofana spectrum), Amras Cicadellidae (Cicadellidae), such as ca biguttula biguttula; Aphrophoridae (Aphrophoridae), such as European spittlebug (Philaenus spumaris); Cercopidae (Cercopidae), such as Mahanarva posticata and Mahanarva fimbriolata; Bean aphid (Aphis fabae), soybean aphid (Aphis glycines), cotton aphid (Aphis gossypii), European apple aphid (Aphis spp.), etc. Aphis pomi, snow willow aphid (Aphis spiraecola), green peach aphid (Myzus persicae), strawberry aphid (Brachycaudus helichrysi), radish aphid (Brevicoryne brassicae), rosy apple aphid (Dysaphis plantaginea), false radish aphid (Lipaphis erysimi), tulip long-horn aphid (Macrosiphum euphorbiae), oats Aulacorthum solani, lettuce aphid (Nasonovia ribisnigri), wheat curl aphid (Rhopalosiphum padi), corn aphid (Rhopalosiphum maidis), citrus black aphid (Toxoptera citricida), peach buttercup aphid (Hyalopterus pruni), barnyard millet aphid (Melanaphis sacchari), and Japanese black aphid (Tetraneura nigriabd) ominalis, candy cotton aphid (Ceratovacuna lanigera), apple aphid (Eriosoma lanigerum), English grain aphid (Sitobion avenae); grapevine aphid (Daktulosphaira vitifoliae), pecan phylloxera (Phylloxera devastatrix), pecan leaf phylloxera (Phylloxera notabilis), southern pecan leaf phylloxera (P Phylloxeridae, such as hylloxera russelae; Adelgidae, such as Adelges tsugae, Adelges piceae, Aphrastasia pectinatae; Scotinophara lurida, black paddy bug, Nezara antennata, spiny star bug Stink bug (Eysarcoris aeneus), large spurred spotted bug (Eysarcoris lewisi), white spotted bug (Eysarcoris ventralis), purple spotted bug (Eysarcoris annamita), brown stink bug (Halyomorpha halys), southern green stink bug (Nezara viridula), brown stink bug (Euschistus heros), red banded stink bug (Piezodorus guildinii), Oebalus pugna x, Dichelops melacanthus, Piezodorus hybneri and other members of the Pentatomidae family; Scaptocoris castanea and other members of the Cydnidae family; Riptortus clavatus, Leptocorisa chinensis, Leptocorisa acuta and other members of the Alydidae family; Cletus punctiger, Coreidae, such as the foot-striped long-horned bug (Leptoglossus australis); Lygaeidae, such as the rice-winged long-horned bug (Cavelerius saccharivorus), the rice-winged long-horned bug (Togo hemipterus), and the American long-horned bug (Blissus leucopterus); Trigonotylus caelestialium, Stenotus rubrovittatus, and other long-horned bugs. s), the Miridae family, such as the long-spined wheat grass bug (Stenodema calcarata) and the rusty whitefly (Lygus lineolaris); Trialeurodes vaporariorum, Bemisia tabaci, the Asian citrus whitefly (Dialeurodes citri), Aleurocanthus spiniferus, Aleurocanthus camelliae, and the Japanese whitefly (Aleurocanthus chinensis). The family Aleyrodidae, such as the whitefly (Pealius euryae); the family Coccinellidae, such as the palm scale insect (Abgrallaspis cyanophylli), the red scale insect (Aonidiella aurantii), the pear scale insect (Diaspidiotus perniciosus), the mulberry scale insect (Pseudaulacaspis pentagona), the Yanon scale insect (Unaspis yanonensis), and the false Yanon scale insect (Unaspis citri). Diaspididae; Coccidae, such as Ceroplastes rubens; Margarodidae, such as Icerya purchasi and Icerya seychellarum; Phenacoccus solani, Phenacoccus solenopsis, Planococcus kraunhiae, Mealybugs (Pseudococcidae) such as mulberry mealybug (Pseudococcus comstocki), citrus mealybug (Planococcus citri), Japanese quill mealybug (Pseudococcus calceolariae), long-legged mealybug (Pseudococcus longispinus), and tuttlemea leaf bug (Brevennia rehi); citrus psyllid (Diaphorina citri), Asian citrus psyllid (Trioza erytreae), and pear psyllid (Pseudococcus erytreae). Psyllidae, including Cacopsylla pyrisuga, Cacopsylla chinensis, Bactericera cockerelli, and Cacopsylla pyricola; Corythucha ciliata, Corythucha marmorata, Stephanitis nashi, and Stephanitis pyrioi des and other Tingidae; Cimicidae such as Cimex lectularius and Cimex hempterus; Cicadidae such as Quesada gigas; Reduviidae such as Triatoma infestans, Triatoma rubrofasciata, Triatoma dimidiata, and Rhodonius prolixus.
　鱗翅目(Lepidoptera)：ニカメイガ(Chilo suppressalis)、ダークヘディドステムボーラー(Chilo polychrysus)、ホワイトステムボーラー(Scirpophaga innotata)、イッテンオオメイガ(Scirpophaga incertulas)、Rupela albina、コブノメイガ(Cnaphalocrocis medinalis)、Marasmia patnalis、イネハカジノメイガ(Marasmia exigua)、ワタノメイガ(Notarcha derogata)、アワノメイガ(Ostrinia furnacalis)、ヨーロピアンコーンボーラー(Ostrinia nubilalis)、ハイマダラノメイガ(Hellula undalis)、モンキクロノメイガ(Herpetogramma luctuosale)、シバツトガ(Parapediasia teterrellus)、ライスケースワーム(Nymphula depunctalis)、シュガーケーンボーラー(Diatraea saccharalis)、エッグプラントフルーツボーラー（Leucinodes orbonalis）等のツトガ科(Crambidae)；モロコシマダラメイガ(Elasmopalpus lignosellus)、ノシメマダラメイガ(Plodia interpunctella)、フタモンマダラノメイガ(Euzophera batangensis)、スジマダラメイガ(Cadra cautella)等のメイガ科(Pyralidae)；ハスモンヨトウ(Spodoptera litura)、シロイチモジヨトウ(Spodoptera exigua)、アワヨトウ(Mythimna separata)、ヨトウガ(Mamestra brassicae)、イネヨトウ(Sesamia inferens)、シロナヨトウ(Spodoptera mauritia)、フタオビコヤガ(Naranga aenescens)、ツマジロクサヨトウ(Spodoptera frugiperda)、アフリカシロナヨトウ(Spodoptera exempta)、Spodoptera cosmioides、セミトロピカルアーミーワーム（Spodoptera eridania）、タマナヤガ(Agrotis ipsilon)、カブラヤガ(Agrotis segetum)、タマナギンウワバ(Autographa nigrisigna)、イネキンウワバ(Plusia festucae)、Soybean looper(Chrysodeixis includens)、トリコプルシア属(Trichoplusia spp.)、ニセアメリカタバコガ(Heliothis virescens)等のヘリオティス属(Heliothis spp.)、オオタバコガ(Helicoverpa armigera)、コーンイヤワーム(Helicoverpa zea)等のヘリコベルパ属(Helicoverpa spp.)、ベルベットビーンキャタピラー(Anticarsia gemmatalis)、コットンリーフワーム(Alabama argillacea)、ホップワインボーラー(Hydraecia immanis)等のヤガ科(Noctuidae)；モンシロチョウ(Pieris rapae)等のシロチョウ科(Pieridae)；ナシヒメシンクイ(Grapholita molesta)、スモモヒメシンクイ(Grapholita dimorpha)、マメシンクイガ(Leguminivora glycinivorella)、アズキサヤムシガ(Matsumuraeses azukivora)、リンゴコカクモンハマキ(Adoxophyes orana fasciata)、チャノコカクモンハマキ(Adoxophyes honmai)、チャハマキ(Homona magnanima)、ミダレカクモンハマキ(Archips fuscocupreanus)、コドリングモス(Cydia pomonella)、カンシャシンクイハマキ(Tetramoera schistaceana)、ビーンシュートボーラ(Epinotia aporema)、シトラスフルーツボーラー(Citripestis sagittiferella)、ヨーロピアングレープワインモス（Lobesia botrana）等のハマキガ科(Tortricidae)；チャノホソガ(Caloptilia theivora)、キンモンホソガ(Phyllonorycter ringoniella)等のホソガ科(Gracillariidae)；モモシンクイガ(Carposina sasakii)等のシンクイガ科(Carposinidae)；コーヒーリーフマイナー(Leucoptera coffeella)、モモハモグリガ(Lyonetia clerkella)、ギンモンハモグリガ(Lyonetia prunifoliella)等のハモグリガ科(Lyonetiidae)；マイマイガ(Lymantria dispar)等のリマントリア属(Lymantria spp.)、チャドクガ(Euproctis pseudoconspersa)等のユープロクティス属(Euproctis spp.)等のドクガ科(Lymantriidae)；コナガ(Plutella xylostella)等のコナガ科(Plutellidae)；モモキバガ(Anarsia lineatella)、イモキバガ(Helcystogramma triannulella)、ワタアカミムシガ(Pectinophora gossypiella)、ジャガイモガ(Phthorimaea operculella)、トマトキバガ(Tuta absoluta)等のキバガ科(Gelechiidae)；アメリカシロヒトリ(Hyphantria cunea)等のヒトリガ科(Arctiidae)；ジャイアントシュガーケーンボーラー(Telchin licus)等のカストニアガ科(Castniidae)；ヒメボクトウ（Cossus insularis）等のボクトウガ科（Cossidae）；ヨモギエダシャク(Ascotis selenaria)等のシャクガ科(Geometridae)；ヒロヘリアオイラガ(Parasa lepida)等のイラガ科(Limacodidae)；カキノヘタムシガ(Stathmopoda masinissa)等のニセマイコガ科(Stathmopodidae)；クロメンガタスズメ(Acherontia lachesis)等のスズメガ科(Sphingidae)；キクビスカシバ(Nokona feralis)、コスカシバ(Synanthedon hector)、ヒメコスカシバ(Synanthedon tenuis)等のスカシバガ科(Sesiidae)；イネツトムシ(Parnara guttata)等のセセリチョウ科(Hesperiidae)；イガ(Tinea translucens)、コイガ(Tineola bisselliella)等のヒロズコガ科(Tineidae)。 Lepidoptera: Chilo suppressalis, Dark headed stem borer, Chilo polychrysus, White stem borer, Scirpophaga innotata, Scirpophaga incertulas, Rupela albina, Cnaphalocrocis medinalis, Marasmia patnalis, Marasmia exigua, Notarcha derogata, Ostrinia furnacalis, European corn borer, Hellula undalis, Herpetogramma luc Crambidae, such as the Japanese bush moth (Parapediasia teterrellus), the rice case worm (Nymphula depunctalis), the sugar cane borer (Diatraea saccharalis), and the eggplant fruit borer (Leucinodes orbonalis); Pyralidae, such as the corn moth (Elasmopalpus lignosellus), the Indian meal moth (Plodia interpunctella), the two-spotted moth (Euzophera batangensis), and the striped moth (Cadra cautella); Spodoptera litura, Spodoptera exigua, and the armyworm moth (Mythimna s eparata, armyworm moth (Mamestra brassicae), rice armyworm moth (Sesamia inferens), armyworm moth (Spodoptera mauritia), two-banded cutworm moth (Naranga aenescens), armyworm moth (Spodoptera frugiperda), African armyworm moth (Spodoptera exempta), Spodoptera cosmioides, semi-tropical armyworm (Spodoptera eridania), cutworm moth (Agrotis ipsilon), turnip cutworm moth (Agrotis segetum), silver looper moth (Autographa nigrisigna), rice yellow looper moth (Plusia festucae), soybean looper (Chrysodeixis includens), trichoppers Trichoplusia spp., Heliothis spp. such as Heliothis virescens, Helicoverpa spp. such as Helicoverpa armigera, corn earworm (Helicoverpa zea), Noctuidae such as Velvet bean caterpillar (Anticarsia gemmatalis), cotton leafworm (Alabama argillacea), hop wine borer (Hydraecia immanis), Pieridae such as Pieris rapae, pear fruit moth (Grapholita molesta), plum fruit moth (Grapholita dimorpha), bean cicada (Coleoptera pedunculidae), Japanese quince (Pyral ... Tortricidae, such as the grass moth (Leguminivora glycinivorella), the bean pea moth (Matsumuraeses azukivora), the smaller apple tortrix moth (Adoxophyes orana fasciata), the smaller tea tortrix moth (Adoxophyes honmai), the tea tortrix moth (Homona magnima), the common tortrix moth (Archips fuscocupreanus), the codling moth (Cydia pomonella), the sugar candy moth (Tetramoera schistaceana), the bean shoot borer (Epinotia aporema), the citrus fruit borer (Citripestis sagittiferella), and the European grape wine moth (Lobesia botrana); The Gracilariidae family includes the tea leaf moth (Caloptilia theivora) and the golden leaf moth (Phyllonorycter ringoniella); the Carposinidae family includes the peach fruit moth (Carposina sasakii); the Lyonetiidae family includes the coffee leaf miner (Leucoptera coffee), the peach leafminer (Lyonetia clerkella), and the silver leafminer (Lyonetia prunifoliella); the Lymantriidae family includes the gypsy moth (Lymantria dispar), and the Euproctis spp. including the brown tussock moth (Euproctis pseudoconspersa); The family Plutellidae includes the long-legged moth (Plutella xylostella); the family Gelechiidae includes the peach leaf moth (Anarsia lineatella), the potato leaf moth (Helcystogramma triannulella), the red cotton moth (Pectinophora gossypiella), the potato tuber moth (Phthorimaea operculella), and the tomato leaf moth (Tuta absoluta); the family Arctiidae includes the fall webworm (Hyphantria cunea); the family Castniidae includes the giant sugarcane borer (Telchin licus); the family Cossidae includes the lesser cotton moth (Cossus insularis); the mugwort geometries (Ascotis selenaria) ), the Geometridae family; the Limacodidae family; the Stathmopodidae family; the Persimmon leaf moth (Stathmopoda masinissa), the Sphingidae family; the Sesiidae family; the Japanese bush moth (Nokona feralis), the Synanthedon hector, the Synanthedon tenuis, the Hesperiidae family; the Rice beetle (Parnara guttata), the Tineidae family; the Tinea translucens, the Bush moth (Tineola bisselliella), and the like.
　総翅目(Thysanoptera)：ミカンキイロアザミウマ(Frankliniella occidentalis)、ミナミキイロアザミウマ(Thrips palmi)、チャノキイロアザミウマ(Scirtothrips dorsalis)、ネギアザミウマ(Thrips tabaci)、ヒラズハナアザミウマ(Frankliniella intonsa)、イネアザミウマ(Stenchaetothrips biformis)、モトジロアザミウマ(Echinothrips americanus)、アボカドスリプス（Scirtothrips perseae）等のアザミウマ科(Thripidae)；イネクダアザミウマ(Haplothrips aculeatus)等のクダアザミウマ科(Phlaeothripidae)。 Thysanoptera: Thripidae, such as Frankliniella occidentalis, Thrips palmi, Scirtothrips dorsalis, Thrips tabaci, Frankliniella intonsa, Stenchaetothrips biformis, Echinothrips americanus, Scirtothrips perseae; Phlaeothripidae, such as Haplothrips aculeatus.
　双翅目(Diptera)：タネバエ(Delia platura)、タマネギバエ(Delia antiqua)、テンサイモグリハナバエ(Pegomya cunicularia)等のハナバエ科(Anthomyiidae)；シュガービートルートマゴット(Tetanops myopaeformis)等のハネフリバエ科(Ulidiidae)；イネハモグリバエ(Agromyza oryzae)、トマトハモグリバエ(Liriomyza sativae)、マメハモグリバエ(Liriomyza trifolii)、ナモグリバエ(Chromatomyia horticola)等のハモグリバエ科(Agromyzidae)；イネキモグリバエ(Chlorops oryzae)等のキモグリバエ科(Chloropidae)；ウリミバエ(Bactrocera cucurbitae)、ミカンコミバエ(Bactrocera dorsalis)、ナスミバエ(Bactrocera latifrons)、オリーブミバエ(Bactrocera oleae)、クインスランドミバエ(Bactrocera tryoni)、チチュウカイミバエ(Ceratitis capitata)、アップルマゴット(Rhagoletis pomonella)、オウトウハマダラミバエ(Rhacochlaena japonica)等のミバエ科(Tephritidae)；イネヒメハモグリバエ(Hydrellia griseola)、トウヨウイネクキミギワバエ(Hydrellia philippina)、イネクキミギワバエ(Hydrellia sasakii)等のミギワバエ科(Ephydridae)；オウトウショウジョウバエ(Drosophila suzukii)、キイロショウジョウバエ（Drosophila melanogaster）等のショウジョウバエ科(Drosophilidae)；オオキモンノミバエ(Megaselia spiracularis)等のノミバエ科(Phoridae)；オオチョウバエ(Clogmia albipunctata)等のチョウバエ科(Psychodidae)；チビクロバネキノコバエ(Bradysia difformis)、ネギネクロバネキノコバエ(Bradysia odoriphaga)等のクロバネキノコバエ科(Sciaridae)；ヘシアンバエ(Mayetiola destructor)、イネノシントメタマバエ(Orseolia oryzae)等のタマバエ科(Cecidomyiidae)；Diopsis macrophthalma等のシュモクバエ科(Diopsidae)；Glossina palpalis、Glossina morsitans等のツェツェバエ科 (Glossinidae)；アシマダラブユ（Simulium japonicum）、Simulium damnosum等のブユ科(Simuliidae)；サシチョウバエ亜科(Phlebotominae)；キリウジガガンボ(Tipula aino)、コモンクレーンフライ(Tipula oleracea)、ヨーロピアンクレーンフライ(Tipula paludosa)等のガガンボ科(Tipulidae)；アカイエカ(Culex pipiens pallens)、コガタアカイエカ(Culex tritaeniorhynchus)、チカイエカ(Culex pipiens f. molestus)、ネッタイイエカ(Culex quinquefasciatus)、トビイロイエカ(Culex pipiens pipiens)、ニセシロハシイエカ(Culex vishnui)、ヒトスジシマカ(Aedes albopictus)、ネッタイシマカ(Aedes aegypti)、シナハマダラカ(Anopheles sinensis)、ガンビエハマダラカ(Anopheles gambiae)、ステフェンスハマダラカ(Anopheles stephensi)、Anopheles coluzzii、Anopheles albimanus、Anopheles sundaicus、Anopheles arabiensis、Anopheles funestus、Anopheles darlingi、Anopheles farauti、Anopheles minimus等のカ科(Culicidae)；キアシオオブユ(Prosimulium yezoensis)、ツメ卜ゲブユ(Simulium ornatum)等のブユ科(Simulidae)；ウシアブ(Tabanus trigonus)等のアブ科(Tabanidae)；イエバエ(Musca domestica)、オオイエバエ(Muscina stabulans)、サシバエ(Stomoxys calcitrans)、ノサシバエ(Haematobia irritans)等のイエバエ科(Muscidae)；クロバエ科(Calliphoridae)；ニクバエ科(Sarcophagidae)；オオユスリカ(Chironomus plumosus)、セスジユスリカ(Chironomus yoshimatsui)、ハイイロユスリカ(Glyptotendipes tokunagai)等のユスリカ科(Chironomidae)；ヒメイエバエ科(Fannidae)。 Diptera: Anthomyiidae such as Delia platura, Delia antiqua, Pegomyia cunicularia, etc.; Ulidiidae such as Tetanops myopaeformis, etc.; Agromyza oryzae, Liriomyza sativae, Liriomyza trifolii, Chromatomyia horticola, etc. Agromyzidae (Agromyzidae); Chloropidae (Chlorops oryzae), etc.; Bactrocera cucurbitae (Melon fly), Bactrocera dorsalis (Oriental fruit fly), Bactrocera latifrons (Eastern fruit fly), Bactrocera oleae (Olive fruit fly), Bactrocera tryoni (Queensland fruit fly), Ceratitis capitata (Mediterranean fruit fly), Rhagoletis pomonella (Apple maggot), Rhagoletis suzukii (Sugar apple fly), Tephritidae, such as Hacochlaena japonica; Ephydridae, such as Hydrellia griseola, Hydrellia philippina, and Hydrellia sasakii; Drosophilidae, such as Drosophila suzukii and Drosophila melanogaster; Megaselia spiracularis ), Psychodidae, such as Clogmia albipunctata, Sciaridae, such as Bradysia difformis and Bradysia odoriphaga, Cecidomyiidae, such as Mayetiola destructor and Orseolia oryzae, Diopsidae, such as Diopsis macrophthalma, Glos Family Glossinidae, such as Glossina sina palpalis and Glossina morsitans; Family Simuliidae, such as Simulium japonicum and Simulium damnosum; Subfamily Phlebotominae; Family Tipulidae, such as Tipula aino, Tipula oleracea, and European crane fly; Family Culex pipiens pallens, Culex tritaeniorhynchus, Culex pipiens pallens ... x tritaeniorhynchus, Culex pipiens f. molestus, Culex quinquefasciatus, Culex pipiens pipiens, Culex vishnui, Aedes albopictus, Aedes aegypti, Anopheles sinensis, Anopheles gambiae, Anopheles stephensi, Anop Culicidae (Anopheles heles coluzzii, Anopheles albimanus, Anopheles sundaicus, Anopheles arabiensis, Anopheles funestus, Anopheles darlingi, Anopheles farauti, Anopheles minimus, etc.); Simulidae (Prosimulium yezoensis, Simulium ornatum, etc.); Tabanidae (Tabanus trigonus, etc.); Musc Family Muscidae, such as Musca domestica, Muscina stabulans, Stomoxys calcitrans, and Haematobia irritans; Family Calliphoridae; Family Sarcophagidae; Family Chironomidae, such as Chironomus plumosus, Chironomus yoshimatsui, and Glyptotendipes tokunagai; Family Fannidae.
　鞘翅目(Coleoptera)：ダイアブロティカ属(Diabrotica spp.、例えば、ウエスタンコーンルートワーム(Diabrotica virgifera virgifera)、サザンコーンルートワーム(Diabrotica undecimpunctata howardi)、ノーザンコーンルートワーム(Diabrotica barberi)、メキシカンコーンルートワーム(Diabrotica virgifera zeae)、バンデッドキューカンバービートル(Diabrotica balteata)、キューカビットビートル(Diabrotica speciosa)等）、ビーンリーフビートル(Cerotoma trifurcata)、クビアカクビホソハムシ(Oulema melanopus)、ウリハムシ(Aulacophora femoralis)、キスジノミハムシ(Phyllotreta striolata)、キャベッジフリービートル(Phyllotreta cruciferae)、ウエスタンブラックフリービートル(Phyllotreta pusilla)、キャベッジステムフリービートル(Psylliodes chrysocephala)、ホップフリービートル(Psylliodes punctulata)、コロラドハムシ(Leptinotarsa decemlineata)、イネドロオイムシ(Oulema oryzae)、グレープコラスピス(Colaspis brunnea)、コーンフリービートル(Chaetocnema pulicaria)、サツマイモヒサゴトビハムシ(Chaetocnema confinis)、ポテトフリービートル(Epitrix cucumeris)、イネトゲハムシ(Dicladispa armigera)、サザンコーンリーフビートル(Myochrous denticollis)、ヨツモンカメノコハムシ(Laccoptera quadrimaculata)、タバコノミハムシ(Epitrix hirtipennis)、ダイコンサルハムシ(Phaedon brassicae)、フタスジヒメハムシ(Medythia nigrobilineata)等のハムシ科(Chrysomelidae)；シードコーンビートル(Stenolophus lecontei)、スレンダーシードコーンビートル(Clivina impressifrons)等のオサムシ科(Carabidae)；ドウガネブイブイ(Anomala cuprea)、ヒメコガネ(Anomala rufocuprea)、アオドウガネ(Anomala albopilosa)、マメコガネ(Popillia japonica)、ナガチャコガネ(Heptophylla picea)、ヨーロピアンチェーファー(Rhizotrogus majalis)、クロマルコガネ(Tomarus gibbosus)、クロコガネ属(Holotrichia spp.)、ジューン・ビートル(Phyllophaga crinita)等のフィロファガ属(Phyllophaga spp.)、Diloboderus abderus等のディロボデルス属(Diloboderus spp.)等のコガネムシ科(Scarabaeidae)；ワタミヒゲナガゾウムシ(Araecerus coffeae)等のヒゲナガゾウムシ科（Anthriibidae);アリモドキゾウムシ(Cylas formicarius)等のホソクチゾウムシ科(Aponidae)；ブラジルマメゾウムシ(Zabrotes subfasciatus)等のマメゾウムシ科(Bruchidae)；マツノキクイムシ(Tomicus piniperda)、コーヒーベリーボーラー(Hypothenemus hampei)等のキクイムシ科(Scolytidae)；イモゾウムシ(Euscepes postfasciatus)、アルファルファタコゾウムシ(Ｈypera postica)、コクゾウムシ(Sitophilus zeamais)、ココクゾウムシ(Sitophilus oryzae)、グラナリアコクゾウムシ(Sitophilus granarius)、イネゾウムシ(Echinocnemus squameus)、イネミズゾウムシ(Lissorhoptrus oryzophilus)、シロスジオサゾウムシ(Rhabdoscelus lineaticollis)、ワタミハナゾウムシ(Anthonomus grandis)、シバオサゾウムシ(Sphenophorus venatus)、サザンコーンビルバグ(Sphenophorus callosus)、ソイビーンストークウィービル(Sternechus subsignatus)、シュガーケーンウィービル(Sphenophorus levis)、サビヒョウタンゾウムシ(Scepticus griseus)、トビイロヒョウタンゾウムシ(Scepticus uniformis)、Aracanthus mourei等のAracanthus属(Aracanthus spp.)、コットンルートボーラー (Eutinobothrus brasiliensis)等のゾウムシ科(Curculionidae)；コクヌストモドキ(Tribolium castaneum)、ヒラタコクヌストモドキ(Tribolium confusum)、ガイマイゴミムシダマシ(Alphitobius diaperinus)等のゴミムシダマシ科(Tenebrionidae)；ニジュウヤホシテントウ(Epilachna vigintioctopunctata)等のテントウムシ科(Coccinellidae)；ヒラタキクイムシ(Lyctus brunneus)、コナナガシンクイ(Rhizopertha dominica)等のナガシンクイムシ科(Bostrychidae)；ヒョウホンムシ科(Ptinidae)；ゴマダラカミキリ(Anoplophora malasiaca)、Migdolus fryanus、クビアカツヤカミキリ（Aromia bungii）等のカミキリムシ科(Cerambycidae)；オキナワカンシャクシコメツキ(Melanotus okinawensis)、トビイロムナボソコメツキ(Agriotes fuscicollis)、クシコメツキ(Melanotus legatus)、アシブトコメツキ属(Anchastus spp.)、コノデルス属(Conoderus spp.)、クテニセラ属(Ctenicera spp.)、リモニウス属(Limonius spp.)、アエオルス属(Aeolus spp.)等のコメツキムシ科(Elateridae)；アオバアリガタハネカクシ(Paederus fuscipes)等のハネカクシ科(Staphylinidae)；ヒメマルカツオブシムシ(Anthrenus verbasci)、ハラジロカツオブシムシ(Dermestes maculates)、ヒメアカカツオブシムシ(Trogoderma granarium)等のカツオブシムシ科(Dermestidae)；タバコシバンムシ(Lasioderma serricorne)、ジンサンシバンムシ(Stegobium paniceum)等のシバンムシ科(Anobiidae)；アカチビヒラタムシ(Cryptolestes ferrugineus)等のチビヒラタムシ科(Laemophloeidae)；ノコギリヒラタムシ(Oryzaephilus surinamensis)等のホソヒラタムシ科(Silvanidae)、ブロッサムビートル（Brassicogethes aeneus）等のケシキスイムシ科（Nitidulidae）。 Coleoptera: Diabrotica spp. (e.g. Western corn rootworm (Diabrotica virgifera virgifera), Southern corn rootworm (Diabrotica undecimpunctata howardi), Northern corn rootworm (Diabrotica barberi), Mexican corn rootworm (Diabrotica virgifera zeae), Banded cucumber beetle (Diabrotica balteata), Cucumber beetle (Diabrotica speciosa), etc.), Bean leaf beetle (Cerotoma trifurcata), Spotted neck leaf beetle (Oulema melanopus), Cucumber leaf beetle (Aulacophora femoralis), Striped flea beetle (Phyllotreta striolat a), cabbage free beetle (Phyllotreta cruciferae), western black free beetle (Phyllotreta pusilla), cabbage stem free beetle (Psylliodes chrysocephala), hop free beetle (Psylliodes punctulata), Colorado potato beetle (Leptinotarsa decemlineata), rice leaf beetle (Oulema oryzae), grape colaspis (Colaspis brunnea), corn free beetle (Chaetocnema pulicaria), sweet potato leaf beetle (Chaetocnema confinis), potato free beetle (Epitrix cucumeris), rice thorn beetle (Dicladispa armigera), southern corn leaf beetle (Myochrous denticollis), four-legged turtle The Chrysomelidae family includes the saw beetle (Laccoptera quadrimaculata), the tobacco flea beetle (Epitrix hirtipennis), the Chinese radish beetle (Phaedon brassicae), and the two-striped beetle (Medythia nigrobilineata); the Carabidae family includes the seed corn beetle (Stenolophus lecontei) and the slender seed corn beetle (Clivina impressifrons); the cuprea beetle (Anomala cuprea), the dung beetle (Anomala rufocuprea), the green beetle (Anomala albopilosa), the Japanese beetle (Popillia japonica), the long-legged beetle (Heptophylla picea), the European chafer (Rhizotrogus majalis), the black chafer (Tom arus gibbosus, Phyllophaga spp. such as the black scarab beetle (Holotrichia spp.), Phyllophaga spp. such as the June beetle (Phyllophaga crinita), Scarabaeidae such as Diloboderus spp. such as Diloboderus abderus; fungus weevils such as Araecerus coffeee Family Anthriibidae; Family Aponidae such as sweet potato weevil (Cylas formicarius); Family Bruchidae such as Brazilian bean weevil (Zabrotes subfasciatus); Family Scolytidae such as pine bark beetle (Tomicus piniperda) and coffee berry borer (Hypothenemus hampei); Family Scolytidae such as potato weevil (Hypothenemus hampei); Bug (Euscepes postfasciatus), Alfalfa weevil (Hypera postica), Maize weevil (Sitophilus zeamais), Rice weevil (Sitophilus oryzae), Granary maize weevil (Sitophilus granarius), Rice weevil (Echinocnemus squameus), Rice water weevil (Lissorhoptrus oryzophilus), White grain weevil (Rhabdoscelus lineaticollis), Boll weevil (Anthonomus grandis), Grass banded weevil (Sphenophorus venatus), Southern cornbill bug (Sphenophorus callosus), Soybean stalk weevil (Sternechus subsignatus), Sugar cane weevil (Sphenophorus levii). is, Aracanthus spp. such as the rust gourd weevil (Scepticus griseus), the brown gourd weevil (Scepticus uniformis), and Aracanthus mourei, and the cotton root borer (Eutinobothrus brasiliensis); Tenebrionidae such as the red flour beetle (Tribolium castaneum), the flat-headed red flour beetle (Tribolium confusum), and the mealworm beetle (Alphitobius diaperinus); Coccinellidae such as the 20-spotted ladybird beetle (Epilachna vigintioctopunctata); Lyctus brunneus, Rhizope rtha dominica; Ptinidae; Cerambycidae; Anoplophora malasiaca, Migdolus fryanus, Aromia bungii; Melanotus okinawensis, Brown-necked wire beetle; Elateridae, including Agriotes fuscicollis, Melanotus legatus, Anchastus spp., Conoderus spp., Ctenicera spp., Limonius spp., Aeolus spp., and other genera; Paederus spp. fuscipes; the Dermestidae family, including Anthrenus verbasci, Dermestes maculates, and Trogoderma granarium; the tobacco beetle (Lasioderma serricorne), the Japanese cigar beetle (Stegobium paniceum and other Anobiidae; Cryptolestes ferrugineus and other Laemophloeidae; Oryzaephilus surinamensis and other Silvanidae; and Brassicogethes aeneus and other Blossom Beetles.
　直翅目(Orthoptera)：トノサマバッタ(Locusta migratoria)、モロッコトビバッタ(Dociostaurus maroccanus)、オーストラリアトビバッタ(Chortoicetes terminifera)、アカトビバッタ(Nomadacris septemfasciata)、ブラウンローカスト(Locustana pardalina)、ツリーローカスト(Anacridium melanorhodon)、イタリアンローカスト(Calliptamus italicus)、ディファレンシャルグラスホッパー(Melanoplus differentialis)、ツーストライプドグラスホッパー(Melanoplus bivittatus)、マイグレトリーグラスホッパー(Melanoplus sanguinipes)、レッドレッグドグラスホッパー(Melanoplus femurrubrum)、クリアウィングドグラスホッパー(Camnula pellucida)、サバクワタリバッタ(Schistocerca gregaria)、イエローウィングドローカスト(Gastrimargus musicus)、スパースローテッドローカスト(Austracris guttulosa)、コバネイナゴ(Oxya yezoensis)、ハネナガイナゴ(Oxya japonica)、タイワンツチイナゴ(Patanga succincta)等のバッタ科(Acrididae)；ケラ(Gryllotalpa orientalis)等のケラ科(Gryllotalpidae)；ヨーロッパイエコオロギ(Acheta domestica)、エンマコオロギ(Teleogryllus emma)等のコオロギ科(Gryllidae)；モルモンクリケット(Anabrus simplex)等のキリギリス科(Tettigoniidae)。 Orthoptera: Migratory grasshopper (Locusta migratoria), Moroccan grasshopper (Dociostaurus maroccanus), Australian grasshopper (Chortoicetes terminifera), Red grasshopper (Nomadacris septemfasciata), Brown locust (Locustana pardalina), Tree locust (Anacridium melanorhodon), Italian locust (Calliptamus italicus), Differential grasshopper (Melanoplus differentialis), Two-striped grasshopper (Melanoplus bivittatus), Migratory grasshopper (Melanoplus sanguinipes), Red-legged grasshopper (Melanoplus femurrubru) m), Clearwing Grasshopper (Camnula pellucida), Desert Locust (Schistocerca gregaria), Yellowwing Locust (Gastrimargus musicus), Sparse-throated Locust (Austracris guttulosa), Oriental Locust (Oxya yezoensis), Long-winged Locust (Oxya japonica), Formosan Ground Locust (Patanga succincta), and other grasshoppers (Acrididae); mole crickets (Gryllotalpidae) such as the mole cricket (Gryllotalpa orientalis); crickets (Gryllidae) such as the European house cricket (Acheta domestica) and the field cricket (Teleogryllus emma); and katydids (Tettigoniidae) such as the Mormon cricket (Anabrus simplex).
　膜翅目(Hymenoptera)：カブラハバチ(Athalia rosae)、ニホンカブラバチ(Athalia japonica)等のハバチ科(Tenthredinidae)；ヒアリ(Solenopsis invicta)、アカカミアリ(Solenopsis geminata)等のトフシアリ属(Solenopsis spp.)、ブラウンリーフカッティングアント(Atta capiguara)等のハキリアリ属(Atta spp.)、ヒメハキリアリ属(Acromyrmex spp.)、サシハリアリ(Paraponera clavata)、ルリアリ(Ochetellus glaber)、イエヒメアリ(Monomorium pharaonis)、アルゼンチンアリ(Linepithema humile)、クロヤマアリ(Formica japonica)、アミメアリ(Pristomyrmex punctutus)、オオズアリ(Pheidole noda)、ツヤオオズアリ(Pheidole megacephala)、クロオオアリ(Camponotus japonicus)、ムネアカオオアリ(Camponotus obscuripes)等のオオアリ属(Camponotus spp.)、オキシデンタリスシュウカクアリ(Pogonomyrmex occidentalis)等のシュウカクアリ属(Pogonomyrmex spp.)、コカミアリ(Wasmania auropunctata)等のコカミアリ属(Wasmania spp.)、アシナガキアリ(Anoplolepis gracilipes)等のアリ科(Formicidae)；オオスズメバチ(Vespa mandarinia)、ケブカスズメバチ(Vespa simillima)、コガタスズメバチ(Vespa analis)、ツマアカスズメバチ(Vespa velutina)、セグロアシナガバチ(Polistes jokahamae)等のスズメバチ科(Vespidae)；モミノオオキバチ(Urocerus gigas)等のキバチ科(Siricidae)；アリガタバチ科(Bethylidae)。 Hymenoptera: Tenthredinidae such as Athalia rosae and Athalia japonica; Solenopsis spp. such as Solenopsis invicta and Solenopsis geminata; Atta spp. such as Atta capiguara and Acro ant; myrmex spp.), Paraponera clavata, Ochetellus glaber, Monomorium pharaonis, Argentine ant (Linepithema humile), Formica japonica, Pristomyrmex punctutus, Pheidole noda, Pheidole megacephala, Camponotus spp., such as the Japanese camponotus (Camponotus japonicus), Camponotus spp., such as the red-breasted camponotus (Camponotus obscuripes), Pogonomyrmex spp., such as Pogonomyrmex occidentalis, Wasmania spp., such as Wasmania auropunctata, and Anoplolepis gracilipa. es); Vespidae (Hornets) such as the giant hornet (Vespa mandarinia), the hairy hornet (Vespa simillima), the small hornet (Vespa analis), the red hornet (Vespa velutina), and the Japanese paper wasp (Polistes jokahamae); Siricidae (Wasps) such as the fir wasp (Urocerus gigas); and Bethylidae (Hornets).
　ゴキブリ目(Blattodea)：チャバネゴキブリ(Blattella germanica)等のチャバネゴキブリ科(Ectobiidae)；クロゴキブリ(Periplaneta fuliginosa)、ワモンゴキブリ(Periplaneta americana)、コワモンゴキブリ（Periplaneta australasiae）、トビイロゴキブリ(Periplaneta brunnea)、トウヨウゴキブリ(Blatta orientalis)等のゴキブリ科(Blattidae)；ヤマトシロアリ(Reticulitermes speratus)、イエシロアリ(Coptotermes formosanus)、アメリカカンザイシロアリ(Incisitermes minor)、ダイコクシロアリ(Cryptotermes domesticus)、タイワンシロアリ(Odontotermes formosanus)、コウシュンシロアリ(Neotermes koshunensis)、サツマシロアリ(Glyptotermes satsumensis)、ナカジマシロアリ(Glyptotermes nakajimai)、カタンシロアリ(Glyptotermes fuscus)、オオシロアリ(Hodotermopsis sjostedti)、コウシュウイエシロアリ(Coptotermes guangzhouensis)、アマミシロアリ(Reticulitermes amamianus)、ミヤタケシロアリ(Reticulitermes miyatakei)、カンモンシロアリ(Reticulitermes kanmonensis)、タカサゴシロアリ(Nasutitermes takasagoensis)、ニトベシロアリ(Pericapritermes nitobei)、ムシャシロアリ(Sinocapritermes mushae)、Cornitermes cumulans等のシロアリ科(Termitidae)。 　Order Blattodea: Family Ectobiidae, such as the German cockroach (Blattella germanica); Family Blattidae, such as the Siberian cockroach (Periplaneta fuliginosa), the American cockroach (Periplaneta americana), the American cockroach (Periplaneta australiae), the brown cockroach (Periplaneta brunnea), and the Asian cockroach (Blatta orientalis); Family Reticulitermes speratus, Formosan termite (Coptotermes formosanus), Formosan dry wood termite (Incisitermes minor), Formosan termite (Cryptotermes domesticus), Formosan termite (Odontotermes formosanus), and Formosan termite (Neotermes Termites of the family Termitidae, such as Glyptotermes satsumensis, Glyptotermes nakajimai, Glyptotermes fuscus, Hodotermopsis sjostedti, Coptotermes guangzhouensis, Reticulitermes amamianus, Reticulitermes miyatakei, Reticulitermes kanmonensis, Nasutitermes takasagoensis, Pericapritermes nitobei, Sinocapritermes mushae, and Cornitermes cumulans.
　ノミ目(Siphonaptera): ヒトノミ(Pulex irritans)、ネコノミ(Ctenocephalides felis)、イヌノミ(Ctenocephalides canis)、ケオプスネズミノミ(Xenopsylla cheopis) 、ニワトリノミ(Echidnophaga gallinacea)等のヒトノミ科（Pulicidae）；スナノミ(Tunga penetrans)等のスナノミ科（Hectopsyllidae）；ヨーロッパネズミノミ(Nosopsyllus fasciatus)等のナガノミ科（Ceratophyllidae）。 　Order Siphonaptera: Family Pulicidae such as the human flea (Pulex irritans), cat flea (Ctenocephalides felis), dog flea (Ctenocephalides canis), rat flea (Xenopsylla cheopis), chicken flea (Echidnophaga gallinacea), etc.; Family Hectopsyllidae such as the sand flea (Tunga penetrans); Family Ceratophyllidae such as the European rat flea (Nosopsyllus fasciatus).
　咀顎目(Psocodae)：アタマジラミ(Pediculus humanus capitis)等のヒトジラミ科（Pediculidae）；ケジラミ(Pthirus pubis)等のケジラミ科（Pthiridae）；ウシジラミ(Haematopinus eurysternus)、ブタジラミ(Haematopinus suis)等のケモノジラミ科（Haematopinidae）；ウシホソジラミ(Linognathus vituli)、ヒツジ体幹寄生ホソジラミ(Linognathus ovillus)、ケブカウシジラミ(Solenopotes capillatus)等のケモノホソジラミ科（Linognathidae）；ウシハジラミ(Bovicola bovis)、ヒツジジラミ(Bovicola ovis)、Bovicola breviceps、Damalinia forficula、ウェルネッキエラ属(Werneckiella spp.)等のボビコラ科（Bovicoliidae）；イヌハジラミ(Trichodectes canis)、ネコハジラミ(Felicola subrostratus)等のケモノハジラミ科（Trichodectidae）；ニワトリハジラミ(Menopon gallinae)、ニワトリオオハジラミ(Menacanthus stramineus)、トリノトン属(Trinoton spp.)等のタンカクハジラミ科（Menoponidae）；クミングシア属(Cummingsia spp.)等のケモノタンカクハジラミ科（Trimenoponidae）；コナチャタテ(Trogium pulsatorium)等のコチャタテ科(Trogiidae)；ウスグロチャタテ(Liposcelis corrodens)、ヒラタチャタテ(Liposcelis bostrychophila)、ソウメンチャタテ(Liposcelis pearmani)、カツブシチャタテ(Liposcelis entomophila)等のコナチャタテ科(Liposcelidae又はLiposcelididae )。 　Psocodae: Family Pediculidae such as head lice (Pediculus humanus capitis); Family Pthiridae such as pubic lice (Pthirus pubis); Family Haematopinidae such as cow lice (Haematopinus eurysternus) and pig lice (Haematopinus suis); Family Linognathus vituli, Sheep trunk lice Family Linognathidae, such as body lice (Linognathus ovillus) and cow lice (Solenopotes capillatus); Family Bovicoliidae, such as cow lice (Bovicola bovis), sheep lice (Bovicola ovis), Bovicola breviceps, Damalinia forficula, and Werneckiella spp.; Family Bovicoliidae, such as dog lice (T Family Trichodectidae, such as the cat louse (Felicola subrostratus) and the chicken louse (Menopon gallinae), the chicken louse (Menacanthus stramineus), and the Trinoton spp. family Menoponidae, such as the chicken louse (Menopon gallinae), the chicken louse (Menacanthus stramineus), and the Trinoton spp. family Trinoton spp. family Cummingsia spp. family noponidae); Trogiidae, such as Trogium pulsatorium; Liposcelidae or Liposcelididae, such as Liposcelis corrodens, Liposcelis bostrychophila, Liposcelis pearmani, and Liposcelis entomophila.
　シミ目(Thysanura):ヤマトシミ(Ctenolepisma villosa)、セイヨウシミ(Lepisma saccharina)等のシミ科(Lepismatidae)。 　Order Thysanura: Family Lepismatidae, including the Japanese silverfish (Ctenolepisma villosa) and the European silverfish (Lepisma saccharina).
　ダニ目(Acari)：ナミハダニ(Tetranychus urticae)、カンザワハダニ(Tetranychus kanzawai)、ミツユビナミハダニ(Tetranychus evansi)、ミカンハダニ(Panonychus citri)、リンゴハダニ(Panonychus ulmi)、オリゴニカス属(Oligonychus spp.)等のハダニ科(Tetranychidae)；ミカンサビダニ(Aculops pelekassi)、リュウキュウミカンサビダニ(Phyllocoptruta citri)、トマトサビダニ(Aculops lycopersici)、チャノサビダニ(Calacarus carinatus)、チャノナガサビダニ(Acaphylla theavagrans)、ニセナシサビダニ(Eriophyes chibaensis)、リンゴサビダニ(Aculus schlechtendali)、カキサビダニ(Aceria diospyri)、Aceria tosichella、シソサビダニ(Shevtchenkella sp.)等のフシダニ科(Eriophyidae)；チャノホコリダニ(Polyphagotarsonemus latus)等のホコリダニ科(Tarsonemidae)；ミナミヒメハダニ(Brevipalpus phoenicis)等のヒメハダニ科(Tenuipalpidae)；ケナガハダニ科(Tuckerellidae)；フタトゲチマダニ(Haemaphysalis longicornis)、キチマダニ(Haemaphysalis flava)、ヤマトマダニ(Haemaphysalis japonica)、ツリガネチマダニ(Haemaphysalis campanulata)、アメリカイヌカクマダニ(Dermacentor variabilis)、タイワンカクマダニ(Dermacentor taiwanensis)、ロッキーマウンテンウッドチック(Dermacentor andersoni)、アミメカクマダニ（Dermacentor reticulatus）、ヤマトマダニ(Ixodes ovatus)、シュルツマダニ(Ixodes persulcatus)、ブラックレッグドチック(Ixodes scapularis)、西部クロアシマダニ(Ixodes pacificus)、Ixodes holocyclus、Ixodes ricinus、ローンスターチック(Amblyomma americanum)、ガルフコーストチック(Amblyomma maculatum)、オウシマダニ(Rhipicephalus　microplus)、キャトルチック(Rhipicephalus annulatus)、クリイロコイタマダニ(Rhipicephalus sanguineus)、Rhipicephalus appendiculatus、Rhipicephalus decoloratus等のマダニ科（Ixodidae）；ナガヒメダニ(Argas persicus)、Ornithodoros hermsi、Ornithodoros turicata等のヒメダニ科(Argasidae)；ケナガコナダニ(Tyrophagus putrescentiae)、ホウレンソウケナガコナダニ(Tyrophagus similis)等のコナダニ科(Acaridae)；コナヒョウヒダニ(Dermatophagoides farinae)、ヤケヒョウヒダニ(Dermatophagoides pteronyssinus)等のチリダニ科(Pyroglyphidae)；ホソツメダニ(Cheyletus eruditus)、クワガタツメダニ(Cheyletus malaccensis)、ミナミツメダニ(Chelacaropsis moorei)、イヌツメダニ(Cheyletiella yasguri)等のツメダニ科(Cheyletidae)；ヒツジキュウセンヒゼンダニ(Psoroptes ovis)、ウマキュウセンヒゼンダニ(Psoroptes equi)、Knemidocoptes mutans、ミミヒゼンダニ(Otodectes cynotis)、ショクヒヒゼンダニ属(Chorioptes spp.)等のキュウセン科(Psoroptidae)；ネコショウセンコウヒゼンダニ(Notoedres cati)、ネズミショウセンコウヒゼンダニ(Notoedres muris)、センコウヒゼンダニ(Sarcoptes scabiei)等のヒゼンダニ科(Sarcoptidae)；ウサギズツキダニ(Listrophorus gibbus)等のズツキダニ科(Listrophoridae)；ワクモ(Dermanyssus gallinae)等のサシダニ科(Dermanyssidae)；トリサシダニ(Ornithonyssus sylviarum)、イエダニ(Ornithonyssus bacoti)等のオオサシダニ科(Macronyssidae)；ミツバチヘギイタダニ(Varroa jacobsoni)等のヘギイタダニ科(Varroidae)；イヌニキビダニ(Demodex canis)、ネコニキビダニ(Demodex cati)等のニキビダニ科(Demodicidae)；アカツツガムシ(Leptotrombidium akamushi)、フトゲツツガムシ(Leptotrombidium pallidum)、タテツツガムシ(Leptotrombidium scutellare)等のツツガムシ科(Trombiculidae)。 　Acari: Tetranychus urticae, Tetranychus kanzawai, Tetranychus evansi, Panonychus citri, Panonychus ulmi, Oligonychus spp., etc.; Aculops pelekassi, Phyllocoptruta citri, Aculops lycopersici, Calaminella spp., etc. Eriophyidae, such as Acarus carinatus, Acaphylla theavagrans, Eriophyes chibaensis, Aculus schlechtendali, Aceria diospyri, Aceria tosichella, Shevtchenkella sp.; Tarsonemidae, such as Polyphagotarsonemus latus; Deutzia purpurea, such as Brevipalpus phoenicis. (Tenuipalpidae); Tuckerellidae; Haemaphysalis longicornis, Haemaphysalis flava, Haemaphysalis japonica, Haemaphysalis campanulata, Dermacentor variabilis, Dermacentor taiwanensis, Dermacentor andersoni, Dermacentor reticulatus), Ixodes ovatus, Ixodes persulcatus, Black-legged tick (Ixodes scapularis), Western black-legged tick (Ixodes pacificus), Ixodes holocyclus, Ixodes ricinus, Lone Star tick (Amblyomma americanum), Gulf Coast tick (Amblyomma maculatum), Bullfinch tick (Rhipicephalus microplus), Cattle tick (Rhipicephalus annulatus), Brown dog tick (Rhi Ixodidae, such as Rhipicephalus appendiculatus, Rhipicephalus decoloratus; Argasidae, such as Argas persicus, Ornithodoros hermsi, Ornithodoros turicata; Acaridae, such as Tyrophagus putrescentiae and Tyrophagus similis; Dermatophagoides farinae, burnt mites, Pyroglyphidae family, such as Dermatophagoides pteronyssinus; Cheyletidae family, such as Cheyletus eruditus, Cheyletus malaccensis, Chelacaropsis moorei, and Cheyletiella yasguri; Psoroptes ovis, Psoroptes equi, Knemidocoptes mutans, and Otodectes cy Psoroptidae such as Notoedres notis and Chorioptes spp.; Sarcoptidae such as Notoedres cati, Notoedres muris and Sarcoptes scabiei; Listrophoridae such as Listrophorus gibbus; Demanyssidae such as Dermanyssus gallinae; Ornithonyssus sylvia rum), and the Macronyssidae family, such as the house mite (Ornithonyssus bacoti); the Varroidae family, such as the Varroa jacobsoni mite; the Demodex canis family, such as the Demodex cati mite; the Trombiculidae family, such as the Leptotrombidium akamushi, Leptotrombidium pallidum, and Leptotrombidium scutellare mite.
　クモ目(Araneae)：カバキコマチグモ(Cheiracanthium japonicum)等のコマチグモ科(Eutichuridae)；セアカゴケグモ(Latrodectus hasseltii)等のヒメグモ科(Theridiidae)。
　オビヤスデ目(Polydesmida)：ヤケヤスデ(Oxidus gracilis)、アカヤスデ(Nedyopus tambanus)等のヤケヤスデ科(Paradoxosomatidae)。
　等脚目(Isopoda)：オカダンゴムシ(Armadillidium vulgare)等のオカダンゴムシ科(Armadillidiidae)。
　唇脚綱(Chilopoda)：ゲジ(Thereuonema hilgendorfi)等のゲジ科(Scutigeridae)；トビズムカデ(Scolopendra subspinipes)等のオオムカデ科(Scolopendridae)；イッスンムカデ(Bothropolys rugosus)等のイッスンムカデ科(Ethopolyidae)。 Order Araneae: Family Eutichuridae such as Cheiracanthium japonicum; Family Theridiidae such as Latrodectus hasseltii.
Polydesmida: Paradoxosomatidae, including Oxidus gracilis, Nedyopus tambanus, etc.
Isopoda: Family Armadillidiidae, including Armadillidium vulgare.
Chilopoda: Scutigeridae such as Thereuonema hilgendorfi; Scolopendridae such as Scolopendra subspinipes; Ethopolyidae such as Bothropolys rugosus.
　有害昆虫、有害ダニ類等の有害節足動物は、殺虫剤、殺ダニ剤等に薬剤感受性の低下した、又は薬剤抵抗性の発達した有害昆虫、有害ダニ類等の有害節足動物であってもよい。 The harmful arthropods such as harmful insects and harmful mites may be harmful arthropods such as harmful insects and harmful mites that have reduced sensitivity to insecticides, acaricides, etc., or that have developed resistance to such drugs.
　本発明の１つの実施形態である組成物は、本発明化合物と、メトフルトリン（metofluthrin）及びジメフルトリン（dimefluthrin）からなる群より選ばれる少なくとも１つの化合物とを含有する組成物（以下、組成物Ａと記す）である。メトフルトリン及びジメフルトリンは、一種のみで、又は、二種を組み合わせて、使用できる。また、メトフルトリン及びジメフルトリンには、それぞれ一つ以上の立体異性体が存在するが、本発明で使用されるメトフルトリン及びジメフルトリンには、立体異性体及びその混合物が含まれる。
　組成物Ａにおいて、本発明化合物と、メトフルトリン及びジメフルトリンからなる群より選ばれる少なくとも１つの化合物との比は、特に限定されるものではないが、質量比（本発明化合物：メトフルトリン及びジメフルトリンからなる群より選ばれる少なくとも１つの化合物）で、１０００００：１～１：１０００００、５００００：１～１：５００００、１００００：１～１：１００００、１０００：１～１：１０００、５００：１～１：５００、１００：１～１：１００、５０：１、２０：１、１０：１、９：１、８：１、７：１、６：１、５：１、４：１、３：１、２：１、１：１、１：２、１：３、１：４、１：５、１：６、１：７、１：８、１：９、１：１０、１：２０、１：５０等が挙げられる。 A composition according to one embodiment of the present invention is a composition (hereinafter referred to as composition A) containing the compound of the present invention and at least one compound selected from the group consisting of metofluthrin and dimefluthrin. Metofluthrin and dimefluthrin can be used alone or in combination of two types. In addition, metofluthrin and dimefluthrin each have one or more stereoisomers, and the metofluthrin and dimefluthrin used in the present invention include stereoisomers and mixtures thereof.
In composition A, the ratio of the compound of the present invention to at least one compound selected from the group consisting of metofluthrin and dimefluthrin is not particularly limited, but may be, in terms of mass ratio (compound of the present invention:at least one compound selected from the group consisting of metofluthrin and dimefluthrin), 100,000:1 to 1:100,000, 50,000:1 to 1:50,000, , 10,000:1 to 1:10,000, 1,000:1 to 1:1000, 500:1 to 1:500, 100:1 to 1:100, 50:1, 20:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:20, 1:50, and the like.
　メトフルトリン及びジメフルトリンは、それぞれ、有害昆虫、有害ダニ類等の有害節足動物に対し優れた防除効果を発揮することが知られている。そのため、メトフルトリン及びジメフルトリンからなる群より選ばれる少なくとも１つの化合物を含有する組成物Ａは、有害節足動物に対し優れた防除効果を発揮することが期待できる。組成物Ａにより防除することのできる有害節足動物としては、例えば、前記のものが挙げられる。 Metofluthrin and dimefluthrin are known to have excellent control effects against harmful arthropods such as harmful insects and harmful mites. Therefore, composition A containing at least one compound selected from the group consisting of metofluthrin and dimefluthrin is expected to have excellent control effects against harmful arthropods. Examples of harmful arthropods that can be controlled by composition A include those mentioned above.
　本発明の有害節足動物防除方法としては、本発明化合物又は組成物Ａの有効量を、有害節足動物に直接、及び／又は、有害節足動物の生息場所（植物、土壌、家屋内、動物等）に施用することにより行われる。本発明の有害節足動物の防除方法としては、例えば、茎葉処理、土壌処理、根部処理、シャワー処理、燻煙処理、水面処理及び種子処理が挙げられる。 The method for controlling harmful arthropods of the present invention is carried out by applying an effective amount of the compound of the present invention or composition A directly to the harmful arthropods and/or to the habitat of the harmful arthropods (plants, soil, inside a house, animals, etc.). Examples of the method for controlling harmful arthropods of the present invention include foliage treatment, soil treatment, root treatment, shower treatment, fumigation treatment, water surface treatment and seed treatment.
　本発明化合物又は組成物Ａを農業分野の有害節足動物防除に用いる場合、その施用量は、１００００ｍ2あたりの本発明化合物の量で通常１～１００００ｇである。本発明化合物又は組成物Ａが乳剤、水和剤、フロアブル剤等に製剤化されている場合は、通常、有効成分濃度が０．０１～１００００ｐｐｍ（例えば１０００ｐｐｍ）となるように水で希釈して施用し、粒剤、粉剤等は、通常、そのまま施用する。 When the compound of the present invention or composition A is used for controlling harmful arthropods in the agricultural field, the application amount is usually 1 to 10,000 g of the compound of the present invention per 10,000 m 2. When the compound of the present invention or composition A is formulated as an emulsifiable concentrate, wettable powder, flowable agent or the like, it is usually applied after diluting with water so that the active ingredient concentration becomes 0.01 to 10,000 ppm (for example, 1,000 ppm), and granules, dusts, etc. are usually applied as they are.
　本発明化合物又は組成物Ａを家屋内に生息する有害節足動物の防除に用いる場合、その施用量は、面上に処理する場合は処理面積１ｍ2あたりの本発明化合物の量で、通常、０．０１～１０００ｍｇであり、空間に処理する場合は処理空間１ｍ3あたりの本発明化合物の量で、通常、０．０１～５００ｍｇである。本発明化合物又は組成物Ａが乳剤、水和剤、フロアブル剤等に製剤化されている場合は、通常、有効成分濃度が０．１～１００００ｐｐｍとなるように水で希釈して施用し、油剤、エアゾール剤、燻煙剤、毒餌剤等はそのまま施用する。 When the compound of the present invention or composition A is used for controlling harmful arthropods living in houses, the application amount is usually 0.01 to 1000 mg of the compound of the present invention per m2 of treatment area when applied on a surface, and usually 0.01 to 500 mg of the compound of the present invention per m3 of treatment space when applied in a space. When the compound of the present invention or composition A is formulated as an emulsifiable concentrate, wettable powder, flowable agent, etc., it is usually applied after diluting with water so that the active ingredient concentration is 0.1 to 10000 ppm, and oil solutions, aerosols, fumigants, poison baits, etc. are applied as they are.
　本発明化合物又は組成物Ａは、通常、さらに不活性担体を含有する組成物（以下、組成物Ｂと記す）として使用する。組成物Ｂは、通常、本発明化合物又は組成物Ａと液体担体、界面活性剤等とを混合し、必要により、増粘剤、結合剤、分散剤、安定剤、ガス等の製剤用補助剤を添加して、油剤、乳剤、水和剤、フロアブル剤（水中懸濁剤、水中乳濁剤等）、粉剤、粒剤、エアゾール剤（直撃噴霧型、空間噴霧型、定量噴霧型、ワンプッシュ型、全量噴霧型、間欠噴霧型等）、スプレー剤、電気式噴霧剤（超音波振動式、静電噴霧式等）、加熱蒸散剤（線香、電気マット、吸液芯型加熱蒸散剤等）、非加熱蒸散剤（樹脂蒸散剤、含浸紙蒸散剤、ネット製剤等）、煙霧剤（フォギング等）、ＵＬＶ（Ultra Low Volume）剤等に用いることができる。
　本発明の１つの実施形態である製剤は、本発明化合物又は組成物Ａを含有する、油剤、乳剤、フロアブル剤、エアゾール剤、加熱蒸散剤、非加熱蒸散剤、煙霧剤、及びＵＬＶ剤からなる群より選ばれる製剤である。
　これらの製剤には本発明化合物又は組成物Ａが、製剤の総重量に対して、重量比で通常０．０００１～９９％含有される。 The compound of the present invention or composition A is usually used as a composition further containing an inert carrier (hereinafter referred to as composition B). Composition B is usually prepared by mixing the compound of the present invention or composition A with a liquid carrier, a surfactant, etc., and adding formulation auxiliaries such as a thickener, a binder, a dispersant, a stabilizer, and a gas, if necessary, to be used as an oil solution, an emulsion, a wettable powder, a flowable agent (suspension in water, emulsion in water, etc.), a powder, a granule, an aerosol agent (direct spray type, space spray type, metered spray type, one-push type, total spray type, intermittent spray type, etc.), a spray, an electric spray (ultrasonic vibration type, electrostatic spray type, etc.), a heated transpiration agent (incense stick, electric mat, liquid-absorbing wick type heated transpiration agent, etc.), a non-heated transpiration agent (resin transpiration agent, impregnated paper transpiration agent, net preparation, etc.), a fog agent (fogging, etc.), ULV (Ultra Low Volume) agent, etc.
A formulation that is one embodiment of the present invention is a formulation containing the compound of the present invention or Composition A, which is selected from the group consisting of an oil solution, an emulsion, a flowable agent, an aerosol agent, a heated evaporation agent, a non-heated evaporation agent, a fog agent, and a ULV agent.
These preparations usually contain the compound of the present invention or composition A in an amount of 0.0001 to 99% by weight based on the total weight of the preparation.
　液体担体としては、例えば、水、アルコール類（エタノール、シクロヘキサノール、ベンジルアルコール、プロピレングリコール、ポリエチレングリコール等）、ケトン類（アセトン、シクロヘキサノン、メチルエチルケトン等）、芳香族炭化水素類（ベンゼン、トルエン、キシレン、エチルベンゼン、メチルナフタレン、フェニルキシリルエタン等）、脂肪族炭化水素類（ヘキサン、シクロヘキサン等）、エステル類（酢酸エチル、酢酸ブチル、オレイン酸メチル等）、ニトリル類（アセトニトリル、イソブチロニトリル等）、エーテル類（ジイソプロピルエーテル、ジオキサン等）、アミド類（Ｎ，Ｎ－ジメチルホルムアミド、Ｎ，Ｎ－ジメチルアセトアミド等）、ハロゲン化炭化水素類（ジクロロメタン、トリクロロメタン、四塩化炭素等）、スルホキシド類（ジメチルスルホキシド等）、ラクタム類（Ｎ－メチルピロリドン、Ｎ－オクチルピロリドン等）、脂肪酸類（オレイン酸等）、鉱物油類（ケロシン、灯油、軽油等）、及び植物油類（大豆油、綿実油等）が挙げられる。
　本発明の１つの実施形態である組成物は、本発明化合物又は組成物Ａと、水、アルコール類、ケトン類、芳香族炭化水素類、脂肪族炭化水素類、エステル類、ニトリル類、エーテル類、アミド類、ハロゲン化炭化水素類、スルホキシド類、鉱物油類、及び植物油類からなる群より選ばれる１以上の液体担体とを含有する組成物である。また、本発明の１つの実施形態である製剤は、当該組成物を含有する、油剤、乳剤、フロアブル剤、エアゾール剤、加熱蒸散剤、及びＵＬＶ剤からなる群より選ばれる製剤である。 Examples of liquid carriers include water, alcohols (ethanol, cyclohexanol, benzyl alcohol, propylene glycol, polyethylene glycol, etc.), ketones (acetone, cyclohexanone, methyl ethyl ketone, etc.), aromatic hydrocarbons (benzene, toluene, xylene, ethylbenzene, methylnaphthalene, phenylxylylethane, etc.), aliphatic hydrocarbons (hexane, cyclohexane, etc.), esters (ethyl acetate, butyl acetate, methyl oleate, etc.), nitriles (acetonitrile, isobutyronitrile, etc.), ethers (diisopropyl ether, dioxane, etc.), amides (N,N-dimethylformamide, N,N-dimethylacetamide, etc.), halogenated hydrocarbons (dichloromethane, trichloromethane, carbon tetrachloride, etc.), sulfoxides (dimethyl sulfoxide, etc.), lactams (N-methylpyrrolidone, N-octylpyrrolidone, etc.), fatty acids (oleic acid, etc.), mineral oils (kerosene, kerosene, diesel, etc.), and vegetable oils (soybean oil, cottonseed oil, etc.).
A composition according to one embodiment of the present invention is a composition containing the compound of the present invention or composition A and one or more liquid carriers selected from the group consisting of water, alcohols, ketones, aromatic hydrocarbons, aliphatic hydrocarbons, esters, nitriles, ethers, amides, halogenated hydrocarbons, sulfoxides, mineral oils, and vegetable oils. A formulation according to one embodiment of the present invention is a formulation containing the composition and selected from the group consisting of oil solutions, emulsions, flowables, aerosols, heat evaporation agents, and ULV agents.
　界面活性剤としては、例えば、アルキル硫酸エステル塩、アルキルスルホン酸塩、アルキルアリールスルホン酸塩、アルキルアリールエーテル類、アルキルアリールエーテル類のポリオキシエチレン化物、ポリエチレングリコールエーテル類、多価アルコールエステル類、及び糖アルコール誘導体が挙げられる。
　本発明の１つの実施形態である組成物は、本発明化合物又は組成物Ａと、アルキル硫酸エステル塩、アルキルスルホン酸塩、アルキルアリールスルホン酸塩、アルキルアリールエーテル類、アルキルアリールエーテル類のポリオキシエチレン化物、ポリエチレングリコールエーテル類、多価アルコールエステル類、及び糖アルコール誘導体からなる群より選ばれる１以上の界面活性剤とを含有する組成物である。また、本発明の１つの実施形態である製剤は、当該組成物を含有する、乳剤、フロアブル剤、及び加熱蒸散剤からなる群より選ばれる製剤である。 Examples of the surfactant include alkyl sulfates, alkyl sulfonates, alkylaryl sulfonates, alkylaryl ethers, polyoxyethylated alkylaryl ethers, polyethylene glycol ethers, polyhydric alcohol esters, and sugar alcohol derivatives.
The composition according to one embodiment of the present invention is a composition containing the compound of the present invention or composition A and one or more surfactants selected from the group consisting of alkyl sulfates, alkyl sulfonates, alkylaryl sulfonates, alkylaryl ethers, polyoxyethylated alkylaryl ethers, polyethylene glycol ethers, polyhydric alcohol esters, and sugar alcohol derivatives. Also, the formulation according to one embodiment of the present invention is a formulation containing the composition and selected from the group consisting of emulsions, flowables, and heat-transferables.
　増粘剤としては、例えば、カゼイン、ゼラチン、多糖類（デンプン、アラビアガム、セルロース誘導体、アルギン酸等）、リグニン誘導体、ベントナイト、及び合成水溶性高分子（ポリビニルアルコール、ポリビニルピロリドン、ポリアクリル酸類等）が挙げられる。
　本発明の１つの実施形態である組成物は、本発明化合物又は組成物Ａと、カゼイン、ゼラチン、多糖類、リグニン誘導体、ベントナイト、及び合成水溶性高分子からなる群より選ばれる１以上の増粘剤とを含有する組成物である。また、本発明の１つの実施形態である製剤は、当該組成物を含有する、フロアブル剤である。 Examples of thickeners include casein, gelatin, polysaccharides (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin derivatives, bentonite, and synthetic water-soluble polymers (polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acids, etc.).
A composition according to one embodiment of the present invention is a composition containing the compound of the present invention or composition A and one or more thickeners selected from the group consisting of casein, gelatin, polysaccharides, lignin derivatives, bentonite, and synthetic water-soluble polymers. A formulation according to one embodiment of the present invention is a flowable preparation containing the composition.
　酸化防止剤としては、例えば、ＢＨＴ（２，６－ジ－ｔｅｒｔ－ブチル－４－メチルフェノール）及びＢＨＡ（２－ｔｅｒｔ－ブチル－４－メトキシフェノールと３－ｔｅｒｔ－ブチル－４－メトキシフェノールとの混合物）が挙げられる。
　本発明の１つの実施形態である組成物は、本発明化合物又は組成物Ａと、ＢＨＴ及びＢＨＡからなる群より選ばれる１以上の酸化防止剤とを含有する組成物である。また、本発明の１つの実施形態である製剤は、当該組成物を含有する、油剤、乳剤、フロアブル剤、エアゾール剤、加熱蒸散剤、非加熱蒸散剤、煙霧剤、及びＵＬＶ剤からなる群より選ばれる製剤である。 Antioxidants include, for example, BHT (2,6-di-tert-butyl-4-methylphenol) and BHA (a mixture of 2-tert-butyl-4-methoxyphenol and 3-tert-butyl-4-methoxyphenol).
A composition which is one embodiment of the present invention is a composition containing the compound of the present invention or composition A and one or more antioxidants selected from the group consisting of BHT and BHA. Also, a formulation which is one embodiment of the present invention is a formulation which contains the composition and is selected from the group consisting of oil solutions, emulsions, flowables, aerosols, heated transpiration agents, non-heated transpiration agents, aerosols, and ULV agents.
　本発明の１つの実施形態である組成物は、本発明化合物又は組成物Ａを、植物性粉末（木粉、粕粉等）に担持させた組成物である。植物性粉末は、前記植物性粉末と結合剤（タブ粉、スターチ、グルテン等）とを混合して用いてもよい。また、本発明の１つの実施形態である製剤は、当該組成物を含有する、加熱蒸散剤である。
　本発明のまた別の実施形態である組成物は、本発明化合物又は組成物Ａと、結合剤とを含有する組成物である。また、本発明の１つの実施形態である製剤は、当該組成物を含有する、加熱蒸散剤である。 The composition according to one embodiment of the present invention is a composition in which the compound of the present invention or composition A is supported on a vegetable powder (wood flour, meal powder, etc.). The vegetable powder may be used by mixing the vegetable powder with a binder (tab flour, starch, gluten, etc.). The preparation according to one embodiment of the present invention is a heat-transpirable agent containing the composition.
A composition according to another embodiment of the present invention is a composition containing the compound of the present invention or composition A and a binder. A preparation according to one embodiment of the present invention is a heat-transferable agent containing the composition.
　本発明の１つの実施形態である組成物は、本発明化合物又は組成物Ａを、コットンリンター及びパルプからなる群より選ばれる１以上の基材に担持させた組成物である。前記基材は、具体的には、例えば、コットンリンターを板状に固めたもの及びコットンリンターとパルプとの混合物の繊維を板状に固めたものが挙げられる。また、本発明の１つの実施形態である製剤は、当該組成物を含有する、加熱蒸散剤である。 The composition, which is one embodiment of the present invention, is a composition in which the compound of the present invention or composition A is supported on one or more substrates selected from the group consisting of cotton linters and pulp. Specific examples of the substrate include cotton linters solidified into a plate shape and fibers of a mixture of cotton linters and pulp solidified into a plate shape. In addition, the formulation, which is one embodiment of the present invention, is a heat-transpirable agent containing the composition.
　本発明の１つの実施形態である組成物は、本発明化合物又は組成物Ａを、熱可塑性樹脂又は紙に担持させた組成物である。また、本発明の１つの実施形態である製剤は、当該組成物を含有する、非加熱蒸散剤である。
　前記樹脂としては、例えば、低密度ポリエチレン、直鎖状低密度ポリエチレン、高密度ポリエチレン等のポリエチレン樹脂；エチレン－酢酸ビニル共重合体等のエチレン－ビニルエステル共重合体；エチレン－メタクリル酸メチル共重合体、エチレン－メタクリル酸エチル共重合体等のエチレン－メタクリル酸エステル共重合体；エチレン－アクリル酸メチル共重合体、エチレン－アクリル酸エチル共重合体等のエチレン－アクリル酸エステル共重合体；エチレン－アクリル酸共重合体等のエチレン－ビニルカルボン酸共重合体；エチレン－テトラシクロドデセン共重合体；プロピレン重合体、プロピレン－エチレン共重合体のポリプロピレン樹脂；ポリ－４－メチルペンテン－１、ポリブテン－１、ポリブタジエン、ポリスチレン、アクリロニトリル－スチレン樹脂；アクリロニトリル－ブタジエン－スチレン樹脂、スチレン－共役ジエン共重合体、スチレン－共役ジエンブロック共重合体水素添加物等のスチレン系エラストマー；フッ素樹脂；ポリメタクリル酸メチル等のアクリル酸樹脂；ナイロン６、ナイロン６６等のポリアミド樹脂；ポリエチレンテレフタレート、ポリエチレンナフタレート、ポリブチレンテレフタレート、ポリシクロへキシレンジメチレンテレフタレート等のポリエステル樹脂；ポリカーボネート、ポリアセタール、ポリアクリルサルフォン、ポリアリレート、ヒドロキシ安息香酸ポリエステル、ポリエーテルイミド、ポリエステルカーボネート、ポリフェニレンエーテル樹脂、ポリ塩化ビニル、ポリ塩化ビニリデン、ポリウレタンが挙げられ、これらの樹脂は、単独で用いても２種以上の混合物として用いてもよい。これらの樹脂には、必要により、フタル酸エステル類（フタル酸ジメチル、フタル酸ジオクチル等）、アジピン酸エステル類、ステアリン酸等の可塑剤が添加されていてもよい。
　前記紙としては、例えば、濾紙及び和紙が挙げられる。
　本発明の別の実施形態である組成物は、本発明化合物又は組成物Ａを、熱可塑性樹脂に担持させた組成物である。
　本発明のまた別の実施形態である組成物は、本発明化合物又は組成物Ａを、紙に担持させた組成物である。 The composition according to one embodiment of the present invention is a composition in which the compound of the present invention or composition A is supported on a thermoplastic resin or paper. Also, the preparation according to one embodiment of the present invention is a non-heated evaporative agent containing the composition.
Examples of the resin include polyethylene resins such as low-density polyethylene, linear low-density polyethylene, and high-density polyethylene; ethylene-vinyl ester copolymers such as ethylene-vinyl acetate copolymer; ethylene-methacrylic acid ester copolymers such as ethylene-methyl methacrylate copolymer and ethylene-ethyl methacrylate copolymer; ethylene-acrylic acid ester copolymers such as ethylene-methyl acrylate copolymer and ethylene-ethyl acrylate copolymer; ethylene-vinyl carboxylic acid copolymers such as ethylene-acrylic acid copolymer; ethylene-tetracyclododecene copolymer; polypropylene resins such as propylene polymers and propylene-ethylene copolymers; poly-4-methylpentene-1, polybutene-1, polybutadiene, polystyrene, and acrylonitrile-styrene resins; acrylonitrile-styrene resins such as ethylene-vinyl carboxylic acid copolymers; Examples of the resin include styrene-based elastomers such as styrene-conjugated diene copolymers and hydrogenated styrene-conjugated diene block copolymers; fluororesins; acrylic resins such as polymethyl methacrylate; polyamide resins such as nylon 6 and nylon 66; polyester resins such as polyethylene terephthalate, polyethylene naphthalate, polybutylene terephthalate, and polycyclohexylene dimethylene terephthalate; polycarbonate, polyacetal, polyacrylsulfone, polyarylate, hydroxybenzoic acid polyester, polyetherimide, polyester carbonate, polyphenylene ether resin, polyvinyl chloride, polyvinylidene chloride, and polyurethane. These resins may be used alone or in combination of two or more. If necessary, plasticizers such as phthalates (dimethyl phthalate, dioctyl phthalate, and the like), adipic acid esters, and stearic acid may be added to these resins.
Examples of the paper include filter paper and Japanese paper.
The composition which is another embodiment of the present invention is a composition in which the compound of the present invention or composition A is supported on a thermoplastic resin.
A composition which is yet another embodiment of the present invention is a composition in which the compound of the present invention or composition A is supported on paper.
　以下、本発明を製造例及び試験例等によりさらに詳しく説明するが、本発明はこれらの例のみに限定されるものではない。 The present invention will be explained in more detail below with reference to production examples and test examples, but the present invention is not limited to these examples.
　まず、本発明化合物の製造例を示す。 First, we will show an example of how to prepare the compound of the present invention.
製造例１
　特開２００４－２６９５０７号公報の製造例１に記載の方法で製造した４－メトキシメチル－２，３，５，６－テトラフルオロベンジル　（１Ｒ）－トランス－３－（１－プロペニル）－２，２－ジメチルシクロプロパンカルボキシレート１．１０ｇ、クロロホルム１０ｍＬ、及びメタノール１．３６ｍＬの混合物に、四塩化チタン（１．０Ｍ　トルエン溶液）１５．３ｍＬを加え、室温で１時間撹拌した。得られた混合物に飽和炭酸水素ナトリウム水溶液を加え、ｔｅｒｔ－ブチルメチルエーテルで抽出した。得られた有機層を無水硫酸マグネシウムで乾燥し、減圧下で濃縮した。得られた残渣をシリカゲルカラムクロマトグラフィー（ヘキサン：酢酸エチル＝１０：１）に付し、下式（ＩＩ）で示される化合物（本発明化合物１と記す）を１．１２ｇ得た。
Figure JPOXMLDOC01-appb-C000009
 Production Example 1
To a mixture of 1.10 g of 4-methoxymethyl-2,3,5,6-tetrafluorobenzyl (1R)-trans-3-(1-propenyl)-2,2-dimethylcyclopropanecarboxylate (1.10 g) produced by the method described in Production Example 1 of JP-A-2004-269507, 10 mL of chloroform, and 1.36 mL of methanol, 15.3 mL of titanium tetrachloride (1.0 M toluene solution) was added and stirred at room temperature for 1 hour. A saturated aqueous solution of sodium bicarbonate was added to the resulting mixture, and the mixture was extracted with tert-butyl methyl ether. The resulting organic layer was dried over anhydrous magnesium sulfate and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography (hexane:ethyl acetate=10:1) to obtain 1.12 g of a compound represented by the following formula (II) (referred to as compound 1 of the present invention).
Figure JPOXMLDOC01-appb-C000009
　本発明化合物１の1Ｈ－ＮＭＲデータを以下に示す。
1H-NMR（CDCl3）δ：5.69 (1H, dt), 5.52 (1H, dt), 5.25 (2H, s), 4.59 (2H, s), 3.40 (3H, s), 3.33 (1H, d), 2.11-2.03 (2H, m), 1.64 (3H, s), 1.59 (3H, s), 0.99 (3H, t). The 1 H-NMR data of the compound 1 of the present invention is shown below.
1H -NMR ( CDCl3 ) δ: 5.69 (1H, dt), 5.52 (1H, dt), 5.25 (2H, s), 4.59 (2H, s), 3.40 (3H, s), 3.33 (1H, d), 2.11-2.03 (2H, m), 1.64 (3H, s), 1.59 (3H, s), 0.99 (3H, t).
　次に、本発明化合物の有害節足動物に対する効力を試験例により示す。 Next, the efficacy of the compound of the present invention against harmful arthropods is shown by test examples.
試験例１
　供試化合物が１２．５ｐｐｍとなるように調製したアセトン溶液を内容量２０ｍＬの容器に注ぎ、供試化合物が０．６３ｍｇ／ｍ2となるように容器の内面に均一にコーティングし、その後７６時間乾燥させた。
　該容器にイエヒメアリ雌成虫１０頭を入れ、蓋を閉めた。１時間経過後にイエヒメアリの状態を調査し、死虫率を求めた。死虫率は下式により計算した。
　　　死虫率（％）＝（死虫数／供試虫数）×１００
　試験は３反復行い、その死虫率の平均値を求めた。
　その結果、本発明化合物１を供試化合物として用いた場合の死中率（３反復の平均値）は６７％であった。 Test Example 1
An acetone solution prepared so that the test compound was 12.5 ppm was poured into a 20 mL container, and the test compound was uniformly coated on the inner surface of the container so that the test compound was 0.63 mg/m 2 , and then dried for 76 hours.
Ten adult females of the house ant were placed in the container, and the lid was closed. After one hour, the condition of the house ant was examined and the mortality rate was calculated by the following formula.
Mortality rate (%) = (number of dead insects/number of test insects) x 100
The test was repeated three times, and the average mortality rate was calculated.
As a result, when the compound 1 of the present invention was used as the test compound, the mortality rate (average value of three repetitions) was 67%.
比較例１
　本発明化合物１に代えて、特許第３７２８９６７号公報（特許文献１）に記載の化合物Ａを供試化合物として用い、試験例１と同様に試験を行ったところ、死中率（３反復の平均値）は７％であった。 Comparative Example 1
Instead of the compound 1 of the present invention, compound A described in Japanese Patent No. 3728967 (Patent Document 1) was used as a test compound, and the test was carried out in the same manner as in Test Example 1. The mortality rate (average value of three repetitions) was 7%.
　本発明化合物は、有害節足動物に対して優れた防除効果を示す。 The compound of the present invention exhibits excellent control effects against harmful arthropods.

Claims (13)

  1. 　式（Ｉ）：
    Figure JPOXMLDOC01-appb-C000001
     で示される化合物。     Formula (I):
    Figure JPOXMLDOC01-appb-C000001
     A compound represented by the formula:
  2. 　請求項１に記載の化合物と、不活性担体とを含有する組成物。 A composition comprising the compound of claim 1 and an inert carrier.
  3. 　請求項１に記載の化合物の有効量を有害節足動物又は有害節足動物の生息場所に施用することによる、有害節足動物の防除方法。 A method for controlling harmful arthropods by applying an effective amount of the compound described in claim 1 to the harmful arthropods or to the habitat of the harmful arthropods.
  4. 　請求項１に記載の化合物と、メトフルトリン及びジメフルトリンからなる群より選ばれる１以上の化合物とを含有する組成物。 A composition containing the compound according to claim 1 and one or more compounds selected from the group consisting of metofluthrin and dimefluthrin.
  5. 　請求項１に記載の化合物又は請求項４に記載の組成物と、水、アルコール類、ケトン類、芳香族炭化水素類、脂肪族炭化水素類、エステル類、ニトリル類、エーテル類、アミド類、ハロゲン化炭化水素類、スルホキシド類、鉱物油類、及び植物油類からなる群より選ばれる１以上の液体担体とを含有する組成物。 A composition comprising the compound according to claim 1 or the composition according to claim 4 and one or more liquid carriers selected from the group consisting of water, alcohols, ketones, aromatic hydrocarbons, aliphatic hydrocarbons, esters, nitriles, ethers, amides, halogenated hydrocarbons, sulfoxides, mineral oils, and vegetable oils.
  6. 　請求項１に記載の化合物又は請求項４に記載の組成物と、アルキル硫酸エステル塩、アルキルスルホン酸塩、アルキルアリールスルホン酸塩、アルキルアリールエーテル類、アルキルアリールエーテル類のポリオキシエチレン化物、ポリエチレングリコールエーテル類、多価アルコールエステル類、及び糖アルコール誘導体からなる群より選ばれる１以上の界面活性剤とを含有する組成物。 A composition comprising the compound according to claim 1 or the composition according to claim 4 and one or more surfactants selected from the group consisting of alkyl sulfate ester salts, alkyl sulfonate salts, alkylaryl sulfonate salts, alkylaryl ethers, polyoxyethylated alkylaryl ethers, polyethylene glycol ethers, polyhydric alcohol esters, and sugar alcohol derivatives.
  7. 　請求項１に記載の化合物又は請求項４に記載の組成物と、カゼイン、ゼラチン、多糖類、リグニン誘導体、ベントナイト、及び合成水溶性高分子からなる群より選ばれる１以上の増粘剤とを含有する組成物。 A composition comprising the compound according to claim 1 or the composition according to claim 4 and one or more thickeners selected from the group consisting of casein, gelatin, polysaccharides, lignin derivatives, bentonite, and synthetic water-soluble polymers.
  8. 　請求項１に記載の化合物又は請求項４に記載の組成物と、ＢＨＴ（２，６－ジ－ｔ－ブチル－４－メチルフェノール）及びＢＨＡ（２－ｔ－ブチル－４－メトキシフェノールと３－ｔ－ブチル－４－メトキシフェノールとの混合物）からなる群より選ばれる１以上の酸化防止剤とを含有する組成物。 A composition containing the compound according to claim 1 or the composition according to claim 4 and one or more antioxidants selected from the group consisting of BHT (2,6-di-t-butyl-4-methylphenol) and BHA (a mixture of 2-t-butyl-4-methoxyphenol and 3-t-butyl-4-methoxyphenol).
  9. 　請求項１に記載の化合物又は請求項４に記載の組成物を、植物性粉末に担持させた組成物。 A composition in which the compound described in claim 1 or the composition described in claim 4 is supported on a plant powder.
  10. 　請求項１に記載の化合物又は請求項４に記載の組成物と、結合剤とを含有する組成物。 A composition comprising the compound according to claim 1 or the composition according to claim 4 and a binder.
  11. 　請求項１に記載の化合物又は請求項４に記載の組成物を、コットンリンター及びパルプからなる群より選ばれる１以上の基材に担持させた組成物。 A composition in which the compound according to claim 1 or the composition according to claim 4 is supported on one or more substrates selected from the group consisting of cotton linters and pulp.
  12. 　請求項１に記載の化合物又は請求項４に記載の組成物を、熱可塑性樹脂又は紙に担持させた組成物。 A composition in which the compound according to claim 1 or the composition according to claim 4 is supported on a thermoplastic resin or paper.
  13. 　請求項１に記載の化合物又は請求項４に記載の組成物を含有する、油剤、乳剤、フロアブル剤、エアゾール剤、加熱蒸散剤、非加熱蒸散剤、煙霧剤、及びＵＬＶ剤からなる群より選ばれる製剤。 A preparation containing the compound according to claim 1 or the composition according to claim 4, the preparation being selected from the group consisting of an oil solution, an emulsion, a flowable agent, an aerosol, a heated vaporization agent, a non-heated vaporization agent, a fog agent, and an ULV agent.
PCT/JP2024/002409 2023-12-22 2024-01-26 Ester compound and use thereof WO2024071443A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202480001005.8A CN118339137A (en) 2023-12-22 2024-01-26 Ester compound and use thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2023216471 2023-12-22
JP2023-216471 2023-12-22

Publications (2)

Publication Number Publication Date
WO2024071443A2 true WO2024071443A2 (en) 2024-04-04
WO2024071443A3 WO2024071443A3 (en) 2024-06-06

Family

ID=90479206

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2024/002409 WO2024071443A2 (en) 2023-12-22 2024-01-26 Ester compound and use thereof

Country Status (2)

Country Link
CN (1) CN118339137A (en)
WO (1) WO2024071443A2 (en)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS564522B2 (en) * 1972-07-11 1981-01-30
JP2007039412A (en) * 2005-08-05 2007-02-15 Dainippon Jochugiku Co Ltd Insecticide/insect repellent or ingestion inhibiting agent for vermin

Also Published As

Publication number Publication date
WO2024071443A3 (en) 2024-06-06
CN118339137A (en) 2024-07-12

Similar Documents

Publication Publication Date Title
WO2019131575A1 (en) Heterocyclic compounds and noxious arthropod control agent containing same
WO2020158889A1 (en) Heterocyclic compound and harmful arthropod control composition containing same
EP4089096A1 (en) Heterocyclic compound and harmful arthropod-controlling composition including same
US11490619B2 (en) Alkyne compound and arthropod pest control composition containing same
EP3928607A1 (en) Heterocyclic compound and harmful arthropod-controlling composition containing same
EP3604300B1 (en) Fused heterocyclic compound and composition containing same
CN108349973A (en) Condensed heterocyclic compouds
JP6816763B2 (en) Heterocyclic compound
WO2024071443A2 (en) Ester compound and use thereof
US11905240B2 (en) Cyclopropyl ethylene compound and arthropod pest control composition containing same
EP3689872B1 (en) Heterocyclic compound and harmful arthropod controlling agent containing same
WO2019124568A2 (en) Pest control composition and pest control method
JP2018162264A (en) Paddy rice pest control composition and pest control method using the same
BR112020019804A2 (en) HETEROCYCLIC COMPOUND AND ARTHROPOD FEVER CONTROL COMPOSITION CONTAINING THE SAME
WO2017188078A1 (en) Heterocyclic compound
WO2024085224A1 (en) Crystal of 2-(5-cyclopropyl-3-(ethylsulfonyl)pyridin-2-yl)-5-((trifluoromethyl)sulfonyl)benzo[d]oxazole
EP3928834A1 (en) Ether compound and harmful arthropod-controlling composition containing same
JP2023166287A (en) Agrochemical spray liquid for low-volume spraying and use thereof
WO2024147306A1 (en) Amide compound and harmful arthropod control composition containing same
WO2019017313A1 (en) Urea compound and harmful arthropods control agent containing same