WO2024056308A1 - Compositions de matériau de revêtement par électrodéposition comprenant une suspension de pigment et des particules composites contenant un catalyseur contenant du métal - Google Patents

Compositions de matériau de revêtement par électrodéposition comprenant une suspension de pigment et des particules composites contenant un catalyseur contenant du métal Download PDF

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Publication number
WO2024056308A1
WO2024056308A1 PCT/EP2023/072642 EP2023072642W WO2024056308A1 WO 2024056308 A1 WO2024056308 A1 WO 2024056308A1 EP 2023072642 W EP2023072642 W EP 2023072642W WO 2024056308 A1 WO2024056308 A1 WO 2024056308A1
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Prior art keywords
electrodeposition coating
coating material
meth
material composition
pigment
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PCT/EP2023/072642
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English (en)
Inventor
Hubert Baumgart
Susanne Piontek
Sebastian FLAMME
Jörg Exner
Natalja OTT-ARENS
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Basf Coatings Gmbh
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Publication of WO2024056308A1 publication Critical patent/WO2024056308A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols

Definitions

  • Electrodeposition coating material compositions comprising pigment slurry and composite particles containing metal-containing catalyst
  • the present invention relates to an aqueous cathodically depositable electrodeposition coating material composition (also called aqueous electrocoat material) comprising at least one binder dispersion (I) comprising at least one cathodically depositable polymer (a) and at least one crosslinking agent (b) as well as at least one pigment slurry (II) comprising at least one pigment and/or filler (c), wherein the composition also comprises at least one kind of composite particles (p) comprising at least one metal-containing catalyst (pc) and at least one (meth)acrylate-based polymer (mp), wherein the polymer (mp) is preferably prepared in the presence of the metal-containing catalyst (pc).
  • aqueous cathodically depositable electrodeposition coating material composition also called aqueous electrocoat material
  • the composition also comprises at least one kind of composite particles (p) comprising at least one metal-containing catalyst (pc) and at least one (meth)acrylate-based polymer (mp), wherein the polymer (mp
  • the present invention also relates to a method for at least partially coating an electrically conductive substrate by cathodic electrodeposition coating comprising at least steps (1 ) to (5) including the step (1 ) of immersing of the substrate at least partially into an electrodeposition coating bath, which comprises the inventive electrodeposition coating material composition.
  • the present invention relates to an electrically conductive substrate, which is at least partially coated with a baked inventive electrodeposition coating material composition and/or which is obtainable by the inventive method.
  • Electrodeposition coating (electrocoat) materials are coating materials which comprise polymers as binders including crosslinkers, pigments and/or fillers, and, frequently, additives. In general, there are anodically and cathodically depositable electrocoat materials.
  • Anodic electrodeposition coating compositions comprising inter alia metal effect pigments are, e.g., disclosed in WO 2006/117189 A1. However, cathodically depositable materials have the greatest importance in industrial coating and particularly in automotive finishing.
  • the substrates to be coated are immersed into an electrocoating bath and connected as the cathode.
  • the bath has an anode as the counter electrode.
  • the particles of the electrocoating material are stabilized with a positive charge and deposit on the cathode to form a coating film.
  • the coated substrate is removed from the electrocoating bath, rinsed with water and the coating film is baked, i.e., thermally cured.
  • chemical reaction and thus crosslinking of binder polymers and crosslinking agents occur, as for example the crosslinking of hydroxyl and/or amino groups with isocyanates.
  • electrodeposition coating compositions normally contain a respective catalyst, in particular a metal-containing catalyst like tin- or bismuth- containing catalysts.
  • Cathodically depositable electrocoat materials are known in the prior art, for example in EP 1 041 125 A1 , DE 197 03 869 A1 and in WO 91 /09917 A2.
  • a major challenge in this regard is an effective incorporation of the curing catalyst into the electrocoat material, namely incorporation of the catalyst in a way that it is indeed available for facilitating the curing reaction, i.e. chemical reaction between crosslinker and binder polymer via respective functional groups.
  • metal-containing catalysts in particular bismuth-containing catalysts.
  • bismuth-containing catalysts have gained more and more focus in recent times as showing in principle good curing efficiency and lower toxicity compared to, for example, tin compounds
  • a remaining challenge is the low (if at all existing) water solubility of these solid compounds (when mentioning solid and waterinsoluble constituents, it is meant that these constituents are solid constituents at room temperature and also are insoluble in water).
  • the low water solubility or even insolubility does not fit to the aqueous character of an aqueous electrocoat material.
  • the non-dissolved and thus solid catalyst as such is not effectively available for facilitating the curing reaction.
  • Electrocoat materials also comprise pigments and, in most cases, also fillers. These pigments and fillers again are solid and water-insoluble constituents meaning again that they also and consequently remain as solids in the composition.
  • pigments and fillers are normally applied in from and as part of pigment pastes.
  • the pigments and/or fillers i.e. the solid and water-insoluble constituents
  • the grinding resin in particular, thereby has the effect of an emulsifier I dispersing agent and facilitates, together with the grinding process (which leads to crushing and thus minimizing particles sizes of the solid constituents), an effective and homogeneous incorporation of the solid constituents.
  • pigment slurries are generally applicable in coating compositions.
  • Pigment slurries like pigment pastes, are, per definition, intermediate products comprising pigments (and/or fillers).
  • intermediate products comprising pigments (and/or fillers).
  • production of pigment slurries comprise standard mixing processes conducted in standard mixing equipment like dissolvers.
  • potent and tailored additives like wetting agents or dispersants are applied during the mixing processes.
  • a first subject-matter of the present invention is an aqueous cathodically depositable electrodeposition coating material composition comprising
  • At least one binder dispersion comprising at least one cathodically depositable polymer (a) and at least one crosslinking agent (b),
  • a further subject-matter of the present invention is a method for at least partially coating an electrically conductive substrate by cathodic electrodeposition coating comprising at least steps (1 ) to (5), namely
  • a further subject-matter of the present invention is an electrically conductive substrate, which is at least partially coated with a baked inventive electrodeposition coating material composition and/or which is obtainable by the inventive method.
  • the inventive electrodeposition coating material composition shows effective curing performance after having been applied to a respective substrate and thus allows for production of appropriately electrocoated substrates. Therefore, the metal-containing catalyst is incorporated in a form of catalytic activity, even if the application of pigment pastes may be avoided.
  • the cathodically depositable aqueous electrodeposition coating material composition of the invention (also named hereinafter inventive electrodeposition coating material composition or inventive composition) comprises at least one binder dispersion (I) comprising at least one cathodically depositable polymer (a) (also named component (a)) and at least one crosslinking agents (b) (also named component (b)) as well as at least one pigment slurry (II) comprising at least one pigment and/or filler.
  • inventive composition also comprises water.
  • the terms “electrodeposition coating material composition” and “electrodeposition coating composition” used herein are interchangeable.
  • the cathodically depositable aqueous electrodeposition coating material composition of the invention is suitable for at least partially coating an electrically conductive substrate with an electrodeposition coating composition, meaning that it is suitable for an at least partial application to the substrate surface of an electrically conductive substrate and whose application leads to an electrodeposition coating film onto the surface of the substrate
  • the cathodically depositable electrodeposition coating material composition of the invention is aqueous.
  • aqueous in connection with the electrodeposition coating material composition of the invention is understood preferably for the purposes of the present invention to mean that water, as solvent and/or as diluent, is present as the main constituent of all solvents and/or diluents present in the electrodeposition coating material composition, preferably in an amount of at least 35 wt.-%, based on the total weight of the electrodeposition coating composition of the invention.
  • Organic solvents may be present additionally in smaller proportions, preferably in an amount of ⁇ 20 wt.-%.
  • the electrodeposition coating composition of the invention preferably includes a water fraction of at least 40 wt.-%, more preferably of at least 50 wt.-%, still more preferably of at least 60 wt.-%, yet more preferably of at least 65 wt.-%, in particular of at least 70 wt.-%, most preferably of at least 75 wt.-%, based in each case on the total weight of the electrodeposition coating composition.
  • the electrodeposition coating composition of the invention preferably includes a fraction of organic solvents that is ⁇ 10 wt.-%, more preferably in a range of from 0 to ⁇ 10 wt.-%, very preferably in a range of from 0 to ⁇ 7.5 wt.-% or of from 0 to ⁇ 5 wt.- % or of from 0 to 2 wt.-%, based in each case on the total weight of the electrodeposition coating composition.
  • organic solvents examples include heterocyclic, aliphatic, or aromatic hydrocarbons, mono- or polyhydric alcohols, especially methanol and/or ethanol, ethers, esters, ketones, and amides, such as, for example, N-methylpyrrolidone, N-ethylpyrrolidone, dimethylformamide, toluene, xylene, butanol, ethylene glycol, propylene glycol and butyl glycol ethers and also their acetates, butyl diglycol, diethylene glycol dimethyl ether, cyclohexanone, methyl ethyl ketone, methyl isobutyl ketone, acetone, isophorone, or mixtures thereof.
  • Prominent examples of such organic solvents are, for example, ethylene glycol ethers like butyl glycol or propylene glycol ethers like butoxy propanol or phenoxy propanol.
  • the solids content of the electrodeposition coating material composition of the invention is preferably in a range of from 5 to 35 wt.-%, more preferably of from 7.5 to 30 wt.-%, very preferably of from 10 to 27.5 wt.-%, more particularly of from 12.5 to 25 wt.-%, most preferably of from 15 to 22.5 wt.-% or of from 15 to 20 wt.-%, based in each case on the total weight of the electrodeposition coating composition.
  • the solids content in other words the nonvolatile fraction, is determined in accordance with the method described hereinafter.
  • the electrodeposition coating material composition of the invention preferably has a pH in the range of from 2.0 to 10.0, more preferably in the range of from 2.5 to 9.5 or in the range of from 2.5 to 9.0, very preferably in the range of from 3.0 to 8.5 or in the range of from 3.0 to 8.0, more particularly in the range of from 2.5 to 7.5 or in the range of from 3.5 to 7.0, especially preferably in the range of from 4.0 to 6.5, most preferably in the range of from 3.5 to 6.5 or of from 5.0 to 6.0.
  • the electrodeposition coating material of the composition includes component (a) preferably in an amount in a range of from 15 to 85 wt.-%, more preferably of from 20 to 80 wt.-%, very preferably of from 25 to 77.5 wt.-%, more particularly of from 30 to 75 wt.-% or of from 35 to 75 wt.-%, most preferably of from 40 to 70 wt.-% or of from 45 to 70 wt.-% or of from 50 to 70 wt.-%, based in each case on the total solids content of the electrodeposition coating composition.
  • the electrodeposition coating material composition of the invention includes component (a) preferably in an amount in a range of from 1 to 80 wt.-%, more preferably of from 2.5 to 75 wt.-%, very preferably of from 5 to 70 wt.-%, more particularly of from 7.5 to 65 wt.-%, most preferably of from 8 to 60 wt.-% or of from 10 to 50 wt.-%, based in each case on the total weight of the electrodeposition coating material composition respectively the coating bath.
  • the electrodeposition coating material composition of the invention additionally includes at least one crosslinking agent component (b), said component (b) is preferably present in an amount in the range of from 5 to 45 wt.-%, more preferably of from 6 to 42.5 wt.-%, very preferably of from 7 to 40 wt.-%, more particularly of from 8 to 37.5 wt.-% or of from 9 to 35 wt.-%, most preferably of from 10 to 35 wt.-%, especially preferably of from 15 to 35 wt.-%, based in each case on the total solids content of the electrodeposition coating composition.
  • the electrodeposition coating composition of the invention includes at least one crosslinking agent component (b), said component (b) is preferably present in an amount in a range of from 0.5 to 30 wt.-%, more preferably of from 1 to 25 wt.-%, very preferably of from 1.5 to 20 wt.-%, more particularly of from 2 to 17.5 wt.-%, most preferably of from 2.5 to 15 wt.-%, especially preferably of from 3 to 10 wt.-%, based in each case on the total weight of the electrodeposition coating material composition, respectively the coating bath.
  • the relative weight ratio of components (a) and (b) to one another in the electrodeposition coating material composition is preferably in a range of from 5:1 to 1.1 :1 , more preferably in a range of from 4.5:1 to 1.1 :1 , very preferably in a range of from 4:1 to 1.2:1 , more particularly in a range of from 3:1 to 1.5:1.
  • the inventive composition comprises at least one, preferably exactly one, binder dispersion (I).
  • binder dispersion As known to the person skilled in the art, electrodeposition coating compositions regularly contain such a binder dispersion, i.e. an aqueous dispersion comprising at least one polymer as binder. Also, the inventive composition contains at least one pigment slurry (II).
  • Component (a) is at least one cathodically depositable polymer, which preferably functions as at least one binder in the inventive electrodeposition coating material composition.
  • Any polymer is suitable as binder and thus as component (a) as long as it is cathodically depositable.
  • Preferred are poly(meth)acrylates, (meth)acrylate copolymers, and epoxide polymers.
  • component (a) of the electrodeposition coating composition of the invention comprises and/or is at least one epoxide-amine adduct.
  • An epoxide-amine adduct for the purposes of the present invention is a reaction product of at least one epoxy resin and at least one amine.
  • Epoxy-amine adducts are hydroxyl functional, meaning that component (a) preferably is hydroxyl functional.
  • Epoxy resins used are more particularly those based on bisphenol A and/or derivatives thereof.
  • Amines reacted with the epoxy resins are primary and/or secondary amines or salts thereof and/or salts of tertiary amines.
  • the at least one epoxide-amine adduct used as component (a) is preferably a cationic, epoxide-based and amine-modified resin.
  • the preparation of such cationic, amine-modified, epoxide-based resins is known and is described for example in DE 35 18 732, DE 35 18 770, EP 0 004 090, EP 0 012 463, EP 0 961 797 B1 , and EP 0 505 445 B1.
  • Cationic, epoxide-based, amine-modified resins are understood preferably to be reaction products of at least one polyepoxide having preferably two or more, e.g., three, epoxide groups, and at least one amine, preferably at least one primary and/or secondary amine.
  • Particularly preferred polyepoxides are polyglycidyl ethers of polyphenols that are prepared from polyphenols and epihalohydrins. Polyphenols used may in particular be bisphenol A and/or bisphenol F.
  • polyepoxides are polyglycidyl ethers of polyhydric alcohols, such as, for example, of ethylene glycol, diethylene glycol, triethylene glycol, propylene 1 ,2-glycol, propylene 1 ,4-glycol, 1 ,5-pentanediol, 1 ,2,6-hexanetriol, glycerol, and 2,2-bis(4- hydroxycyclohexyl)propane.
  • the polyepoxide used may also be a modified polyepoxide. Modified polyepoxides are understood to be those polyepoxides in which some of the reactive functional groups have been reacted with at least one modifying compound.
  • modifying compounds are as follows: i) compounds containing carboxyl groups, such as saturated or unsaturated monocarboxylic acids (e.g., benzoic acid, linseed oil fatty acid, 2-ethylhexanoic acid, Versatic acid), aliphatic, cycloaliphatic and/or aromatic dicarboxylic acids of various chain lengths (e.g., adipic acid, sebacic acid, isophthalic acid, or dimeric fatty acids), hydroxyalkyl carboxylic acids (e.g., lactic acid, dimethylolpropionoic acid), and carboxyl-containing polyesters, or ii) compounds containing amino groups, such as diethylamine or ethylhexylamine or diamines with secondary amino groups, e.g., N,N'-dialkylalkylenediamines, such as dimethylethylenediamine, N,N'-dialkyl-polyoxyalkyleneamines, such as N
  • amines which can be used for preparing component (a) are mono- and dialkylamines, such as methylamine, ethylamine, propylamine, butylamine, dimethylamine, diethylamine, dipropylamine, methylbutylamine, alkanolamines, such as methylethanolamine or diethanolamine, dialkylaminoalkylamines, such as dimethylaminoethylamine, diethylaminopropylamine, or dimethylaminopropylamine, for example.
  • mono- and dialkylamines such as methylamine, ethylamine, propylamine, butylamine, dimethylamine, diethylamine, dipropylamine, methylbutylamine
  • alkanolamines such as methylethanolamine or diethanolamine
  • dialkylaminoalkylamines such as dimethylaminoethylamine, diethylaminopropylamine, or dimethylaminopropy
  • the amines which can be used may also include other functional groups as well, provided they do not disrupt the reaction of the amine with the epoxide group of the optionally modified polyepoxide and also do not lead to gelling of the reaction mixture. Secondary amines are preferably used.
  • the charges that are needed for dilutability with water and for electrical deposition may be generated by protonation with water-soluble acids (e.g., boric acid, formic acid, acetic acid, lactic acid, alkylsulfonic acids (e.g. methanesulfonic acid)); preferably acetic acid and/or formic acid).
  • a further way of introducing cationic groups into the optionally modified polyepoxide is to react epoxide groups of the polyepoxide with amine salts.
  • the epoxide-amine adduct which can be used as component (a) is preferably a reaction product of an epoxy resin based on bisphenol A and primary and/or secondary amines or salts thereof and/or the salt of a tertiary amine.
  • At least one crosslinking agent is present in the electrodeposition coating material composition as component (b), which preferably is selected from the group consisting of blocked polyisocyanates, free polyisocyanates, amino resins, and mixtures thereof. Said component (b) is different from component (a).
  • Blocked polyisocyanates is known to the skilled person.
  • Blocked polyisocyanates which can be utilized are polyisocyanates having at least two isocyanate groups (diisocyanates in case of precisely two isocyanate groups), but preferably having more than two, such as, for example, 3 to 5 isocyanate groups, wherein the isocyanate groups have been reacted, so that the blocked polyisocyanate formed is stable in particular with respect to hydroxyl groups and amino groups such as primary and/or secondary amino groups at room temperature, i.e., at a temperature of 18 to 23°C, but at elevated temperatures, as for example at > 80°C, > 110°C, > 130°C, > 140°C, > 150°C, > 160°C, > 170°C, or > 180°, reacts with conversion and with formation of urethane and/or urea bonds, respectively.
  • Isocyanates used preferably are (hetero)aliphatic, (hetero)cycloaliphatic, (hetero)aromatic or (hetero)aliphatic- (hetero)aromatic isocyanates.
  • Preferred polyisocyanates are those containing 2 to 36, especially 6 to 15, carbon atoms.
  • Preferred examples are ethylene 1 ,2-ethylene diisocyanate, tetramethylene 1 ,4-diisocyanate, hexamethylene 1 ,6-diisocyanate (HDI), 2,2,4(2,4,4)-tri-methylhexamethylene 1 ,6-diisocyanate (TMDI), diphenylmethane diisocyanate (MDI), 1 ,9-diisocyanato-5-methylnonane, 1 ,8- diisocyanato-2,4-dimethyloctane, dodecane 1 ,12-diisocyanate, co,co'-di- isocyanatodipropyl ether, cyclobutene 1 ,3-diisocyanate, cyclohexane 1 ,3- and 1 ,4- diisocyanate, 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate (isophorone
  • Polyisocyanates of higher isocyanate functionality may also be used. Examples thereof are trimerized hexamethylene diisocyanate and trimerized isophorone diisocyanate, more particularly the corresponding isocyanurates. It is also possible, furthermore, to utilize mixtures of polyisocyanates.
  • any desired suitable aliphatic, cycloaliphatic, or aromatic alkyl monoalcohols examples thereof are aliphatic alcohols, such as methyl, ethyl, chloroethyl, propyl, butyl, amyl, hexyl, heptyl, octyl, nonyl, 3,3,5-trimethylhexyl, decyl, and lauryl alcohol; cycloaliphatic alcohols, such as cyclopentanol and cyclohexanol; aromatic alkyl alcohols, such as phenylcarbinol and methylphenylcarbinol.
  • aliphatic alcohols such as methyl, ethyl, chloroethyl, propyl, butyl, amyl, hexyl, heptyl, octyl, nonyl, 3,3,5-trimethylhexyl, decyl, and lauryl alcohol
  • suitable diols such as ethanediol, 1 ,2-propanediol, 1 ,3-propanediol and/or polyols may also be used for blocking of the polyisocyanates.
  • suitable blocking agents are hydroxylamines, such as ethanolamine, oximes, such as methyl ethyl ketone oxime, acetone oxime, and cyclohexanone oxime, and amines, such as dibutylamine and diisopropylamine.
  • Tris(alkoxycarbonylamino)-1 ,3,5-triazine are likewise known to the skilled person.
  • the use of tris(alkoxycarbonylamino)-1 ,3,5-triazines as crosslinking agents in coating material compositions is known.
  • DE 197 12 940 A1 describes the use of such crosslinking agents in basecoat materials.
  • U.S. patent No. 5,084,541 describes the preparation of corresponding compounds which can be used as component (c).
  • Such triazines are for the purposes of the present invention to be encompassed by the term “blocked polyisocyanates”.
  • Amino resins are likewise known to the skilled person.
  • Amino resins used are preferably melamine resins, more particularly melamineformaldehyde resins, which are likewise known to the skilled person. Preference, however, is given to using no amino resins such as melamine-formaldehyde resins as crosslinking agents (b).
  • the electrodeposition coating material composition of the invention therefore preferably comprises no amino resins such as melamineformaldehyde resins.
  • the electrodeposition coating material composition of the invention is used preferably as a one-component (1 K) coating composition.
  • the electrodeposition coating composition of the invention preferably contains no free polyisocyanates.
  • At least one component (b) of the inventive composition is selected from blocked polyisocyanates.
  • Preferred blocked polyisocyanates have an NCO content of, for example, 200 to 300 g/eq, more preferably, 225 to 275 g/eq (whereby g/eq means gram of component per mol of NCO in the component).
  • the molar ratio of hydroxyl groups of component (a) and the NCO groups of component (b), preferably, is from 1 .5 to 3.5, preferably from 2.0 to 3.0.
  • the electrodeposition coating material composition of the invention comprise at least one pigment and/or at least one filler (c).
  • pigment is known to the skilled person, from DIN 55943 (date: October 2001 ), for example.
  • a “pigment” in the sense of the present invention refers preferably to a component in powder or flake form which is substantially, preferably entirely, insoluble in the medium surrounding them, such as the electrodeposition coating material composition of the invention, for example.
  • Pigments are preferably colorants and/or substances which can be used as pigment on account of their magnetic, electrical and/or electromagnetic properties.
  • Pigments differ from “fillers” preferably in their refractive index, which for pigments is > 1 .7.
  • filler is known to the skilled person, from DIN 55943 (date: October 2001 ), for example.
  • Fills for the purposes of the present invention preferably are components, which are substantially, preferably entirely, insoluble in the application medium, such as the electrodeposition coating material composition of the invention, for example, and which are used in particular for increasing the volume.
  • Fillers in the sense of the present invention preferably differ from “pigments” in their refractive index, which for fillers is ⁇ 1.7.
  • any customary pigment known to the skilled person may be used.
  • suitable pigments are inorganic and organic coloring pigments.
  • suitable inorganic coloring pigments are white pigments such as titanium dioxide, zinc white, zinc sulfide or lithopone; black pigments such as carbon black, iron manganese black or spinel black; chromatic pigments such as chromium oxide, chromium oxide hydrate green, cobalt green or ultramarine green, cobalt blue, ultramarine blue or manganese blue, ultramarine violet or cobalt violet and manganese violet, red iron oxide, cadmium sulfoselenide, molybdate red or ultramarine red; brown iron oxide, mixed brown, spinel phases and corundum phases or chromium orange; or yellow iron oxide, nickel titanium yellow, chromium titanium yellow, cadmium sulfide, cadmium zinc sulfide, chromium yellow or bismuth vanadate.
  • inorganic coloring pigments are silicon dioxide, aluminum oxide, aluminum oxide hydrate, especially boehmit, titanium dioxide, zirconium oxide, cerium oxide, and mixtures thereof.
  • suitable organic coloring pigments are monoazo pigments, disazo pigments, anthraquinone pigments, benzimidazole pigments, quinoacridone pigments, quinophthalone pigments, diketopyrrolopyrrol pigments, dioxazine pigments, indanthrone pigments, isoindoline pigments, isoindolinone pigments, azomethine pigments, thioindigo pigments metal complex pigments, perinone pigments, perylene pigments, phthalocyanine pigments or aniline black.
  • any customary filler known to the skilled person may be used.
  • suitable fillers are kaolin, dolomite, calcite, chalk, calcium sulfate, barium sulfate, graphite, silicates such as magnesium silicates, especially corresponding phyllosilicates such as hectorite, bentonite, montmorillonite, talc and/or mica, silicas, especially fumed silicas, hydroxides such as aluminum hydroxide or magnesium hydroxide.
  • kaolin commercial products like ASP 200 (non-calcined kaolin, Fa. BASF) or KaMin 2000C (calcined kaolin, Fa. KaMin) may be mentioned (with a preference on ASP 200).
  • organic fillers such as textile fibers, cellulose fibers, polyethylene fibers or polymer powders may be applied.
  • fabrics such as textile fibers, cellulose fibers, polyethylene fibers or polymer powders may be applied.
  • the pigment plus filler content is preferably in the range of from 0.1 to 20.0 wt.-%, more preferably of from 0.1 to 15.0 wt.-%, very preferably of from 0.1 to 10.0 wt.-%, especially preferably of from 0.1 to 5.0 wt.-%, and more particularly of from 0.1 to 3.5 wt.-%.
  • At least one pigment and/or filler is incorporated in the form of at least one pigment slurry (II) into the electrodeposition coating material composition.
  • at least 60 % by weight, more preferably at least 75 % by weight or at least 90 % by weight of pigments and fillers of the electrocoat material are applied in form of at least one slurry (II).
  • Sometimes, even all applied pigments and fillers are applied in form of at least one pigment slurry (II). Therefore, while it is possible to include pigments and/or fillers also in other form like in form of a pigment slurry, the application of all or at least a major part of pigments and fillers in that form is preferred.
  • one pigment slurry (II) comprises both one or more pigments and/or fillers.
  • Pigment slurry is a term known to the person skilled in the art and having a well-recognized meaning and scope.
  • a milling (or grinding) step means that respective constituents are brought into contact in milling equipment under high shear forces with high energy input further involving the use of milling media, i.e. milling beads like zirconium oxide or glass beads.
  • production of pigment slurries includes dispersing and/or mixing processes conducted in dispersing and/or mixing equipment like, for example, dissolvers or inline dispersers.
  • pigment slurries in order to facilitate incorporation of pigments and fillers in an appropriate form (i.e. well-dispersed) rely on dispersants (including wetting agents and emulsifiers), i.e. customary known dispersant additives facilitating pigment and/or filler incorporation in finely dispersed form.
  • dispersants including wetting agents and emulsifiers
  • customary known dispersant additives facilitating pigment and/or filler incorporation in finely dispersed form.
  • pigment slurries do not include typical grinding resins (like it is customary for pigment pastes) or at least do not comprise such grinding resins in any significant or major portion. Therefore, the binder resins content of a pigment slurry, compared to a pigment paste, generally is lower.
  • Binder resins content per definition, is the portion of the solids content which is not pigment and/or fillers. Therefore, this portion of the solids content is made up by organic non-volatile constituents, in particular organic-based additives like in particular the above-mentioned dispersant additives.
  • the solids content is determined as described in the examples. The same applies for the pigment and filler content.
  • the binder resin solids content results as the difference from solids content and binder resins solids.
  • the pigment slurry (II) preferably has a binder resins content of not more than 10.0 %, based on the total weight of the pigment slurry. More preferably, the binder resins content is not more than 5.0 % or even not more than 2.5 %. Preferred ranges are from 0.5 to 10 %, preferably 0.75 to 5.0 % or even 1 .0 to 2.5 %.
  • the solids content of the pigment slurry (II) preferably is from 50 to 85 %, preferably from 60 to 80 %, in each case based on the total weight of the total weight of the pigment slurry.
  • the pigment and filler (pigment + filler) content of the pigment slurry (II) preferably is from 45 to 80 %, preferably 57.5 to 77.5 %.
  • the pigment and filler content is determined via calculation (applied quantities).
  • the pigment slurry (II) is an aqueous component.
  • aqueous in connection with the pigment slurry (II) is understood for the purposes of the present invention to mean that water, as solvent and/or as diluent, is present as the main constituent of all solvents and/or diluents present in the slurry, preferably in an amount of at least 15 wt.-%, based on the total weight of the slurry.
  • Organic solvents may be present additionally in smaller proportions, preferably in an amount of ⁇ 7.5 wt.-%, based on the total weight of the slurry.
  • the ratio of amounts of water and organic solvents is from 2:1 to 20:1 , preferably from 3:1 to 10:1.
  • a pigment slurry (II) may also contain further constituents like, for example, further customary additives like defoamers or neutralizing agents.
  • the inventive composition contains at least one binder dispersion (I).
  • the binder dispersion (I) contains at least one component (a) and at least one component (b).
  • the binder dispersion (I) regularly contains further optional components (d) mentioned below.
  • further organic cosolvents may be part of the binder dispersion (I).
  • the electrodeposition coating material composition of the invention may comprise one or more commonly employed further additives as one or more optional components (d).
  • Component (d) is different from any of components (a) to (c) and also from the below described composite particles (p).
  • these additives are selected from the group consisting of dispersants (including wetting agents and emulsifiers), surface-active compounds such as surfactants, flow control assistants, solubilizers, defoamers, rheological assistants, antioxidants, stabilizers, preferably heat stabilizers, process stabilizers, and UV and/or light stabilizers, flexibilizers, plasticizers, and mixtures of the aforesaid additives.
  • the additive content may vary very widely according to intended use.
  • the additive content is preferably in the range of from 0.1 to 20.0 wt.-%, more preferably of from 0.1 to 15.0 wt.-%, very preferably of from 0.1 to 10.0 wt.-%, especially preferably of from 0.1 to 5.0 wt.-%, and more particularly of from 0.1 to 2.5 wt.-%.
  • the composition of the invention comprises as essential component at least one kind of composite particles (p).
  • at least one kind of composite particles is comprised.
  • the composite particles (p) comprise at least one metal-containing catalyst (pc), preferably exactly one metal-comprising catalyst (pc).
  • the metal-containing catalyst (pc) is a metal-containing catalyst for catalyzing chemical reaction of the cathodically depositable polymer (a) and the crosslinking agent component (b).
  • the metal-containing catalyst (pc) in particular is selected from a tin- or bismuth- containing catalyst. Even more preferably, the catalyst (pc) is a bismuth-containing catalyst, in particular a bismuth(lll)-containing catalyst.
  • a bismuth-containing catalyst such as, for example, bismuth(lll) oxide, basic bismuth(lll) oxide, bismuth(lll) hydroxide, bismuth(lll) carbonate, bismuth(lll) nitrate, bismuth(lll) subnitrate (basic bismuth(lll) nitrate), bismuth(lll) salicylate and/or bismuth(lll) subsalicylate (basic bismuth(lll) salicylate), bismuth(lll) carboxylates like in particular bismuth(lll) neodecanoate, and also mixtures thereof.
  • water-insoluble catalysts preferably water-insoluble bismuth-containing catalysts.
  • Preferred more particularly are bismuth(lll) carboxylates, more preferably bismuth(lll) neodecanoate.
  • the electrodeposition coating material composition of the invention preferably includes at least one bismuth(lll)-containing catalyst in an amount such that the bismuth(lll) content, calculated as bismuth metal, based on the total weight of the electrodeposition coating material of the invention, is in a range from 10 ppm to 20,000 ppm, preferably 100 to 15,000 ppm, more preferably 500 to 10,000 ppm and particularly preferred 1000 to 5000 ppm.
  • the amount of bismuth, calculated as metal may be determined by means of inductively coupled plasma-atomic emission spectrometry (ICP-OES) in accordance with DIN EN ISO 11885 (date: September 2009). Accordingly, the amount of composite particles (p) is preferably chosen as corresponding to the above specified amounts of bismuth, calculated as metal.
  • the composite particles (p) comprise at least one (meth)acrylate-based polymer (mp), preferably exactly one such polymer (mp).
  • (Meth)acrylate-based polymers are known to the person skilled in the art. Such polymers comprise, in reacted form, acrylate-based and/or methacrylate-based monomers like, for example, (meth)acrylic acid and esters, nitriles, or amides of (meth)acrylic acid.
  • (meth)acrylate-based polymers may also contain, in reacted form, further olefinically unsaturated monomers like vinylic olefinically unsaturated monomers, alpha-beta unsaturated carboxylic acids, and allyl compounds. Accordingly, while a significant part of monomers, i.e.
  • polymers may also comprise the prementioned further olefinically unsaturated monomers.
  • olefinically unsaturated monomers may be monoolefinically or polyolefinically unsaturated. Production of these polymers include, for example, radical polymerization of the mentioned olefinically unsaturated monomers.
  • the (meth)acrylate-based monoolefinically unsaturated monomers may be, for example, (meth)acrylic acid and esters, nitriles, or amides of (meth)acrylic acid.
  • Esters of (meth)acrylic acid are, in particular, those having a radical R which is not olefinically unsaturated.
  • the radical R may be aliphatic or aromatic.
  • the radical R is preferably aliphatic.
  • the radical R may be, for example, an alkyl radical, or may contain heteroatoms. Examples of radicals R which contain heteroatoms are ethers. Preference is given to using at least, but not necessarily exclusively, monomers in which the radical R is an alkyl radical.
  • R is an alkyl radical, it may be a linear, branched, or cyclic alkyl radical. In all three cases, the radicals in question may be unsubstituted or else substituted by functional groups.
  • the alkyl radical preferably has 1 to 24, more preferably 1 to 10, carbon atoms.
  • Monounsaturated esters of (meth)acrylic acid with an unsubstituted alkyl radical that are suitable with particular preference are methyl (meth)acrylate, ethyl (meth)acrylate, propyl (meth)acrylate, isopropyl (meth)acrylate, n-butyl (meth)acrylate, isobutyl (meth)acrylate, tert-butyl (meth)acrylate, amyl (meth)acrylate, hexyl (meth)acrylate, ethylhexyl (meth)acrylate, propylheptyl (meth)acrylate, 3,3,5- trimethylhexyl (meth)acrylate, stearyl (meth)acrylate, lauryl (meth)acrylate, cycloalkyl (meth)acrylates, such as cyclopentyl (meth)acrylate, isobornyl (meth)acrylate, and also cyclohexy
  • Suitable monounsaturated esters of (meth)acrylic acid with a substituted alkyl radical may be substituted by one or more hydroxyl groups, phosphoric ester groups or amino groups like primary, secondary or tertiary amino groups.
  • Monounsaturated esters of (meth)acrylic acid with an alkyl radical substituted by one or more hydroxyl groups are 2-hydroxy-ethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 3-hydroxypropyl (meth)acrylate, 3-hydroxybutyl (meth)acrylate and 4- hydroxybutyl (meth)acrylate, with 2-hydroxyethyl (meth)acrylate being especially preferred.
  • Monounsaturated esters of (meth)acrylic acid with phosphoric ester groups are, for example, the phosphoric ester of polypropylene glycol monomethacrylate, such as the commercially available Sipomer PAM 200 from Rhodia.
  • Monosaturated esters of (meth)acrylic acid with amino groups are, for example, dimethylaminoethyl (meth)acrylate, diethylaminoethyl (meth)acrylate, dimethylaminopropyl (meth)acrylate, diethylaminopropyl (meth)acrylate, 2-(tert- butylamino)ethyl (meth)acrylate, 2-aminoethyl (meth)acrylate hydrochloride, 2-N- morpholinoethyl (meth)acrylate, 2-(diisopropylamino)ethyl (meth)acrylate or 3- (diisopropylamino)propyl (meth)acrylate.
  • Amides of (meth)acrylic acid are those known to the person skilled in the art, for example (meth)acrylamide, N,N-dimethyl (meth)acrylamide, N,N- diethyl(meth)acrylamide, N-propyl(meth)acrylamide, N-isopropyl(meth)acrylamide, N- butyl(meth)acrylamide, N-tert-butyl(meth)acrylamide, N-ethyl(meth)acrylamide, N- propyl(meth)acrylamide, N-butyl(meth)acrylamide, N-phenyl(meth)acrylamide, N-(1- naphthyl)-N-phenyl(meth)acrylamide, N-(triphenylmethyl)methacrylamide N-[3-
  • (meth)acrylamide hydrochloride N-(2-aminoethyl)-(meth)acrylamide hydrochloride, diacetone (meth)acrylamide, N-(hydroxymethyl)-(meth)acrylamide, N-(hydroxyethyl)-
  • Vinylic monounsaturated monomers may be monomers having a radical R' on the vinyl group that is not olefinically unsaturated.
  • the radical R‘ may be aliphatic or aromatic, with aromatic radicals being preferred.
  • the radical R‘ may be a hydrocarbon radical or may contain heteroatoms.
  • Examples of radicals R‘ which contain heteroatoms are ethers, esters, amides, nitriles, and heterocycles.
  • the radical R‘ is preferably a hydrocarbon radical. Where R‘ is a hydrocarbon radical, it may be unsubstituted or substituted by heteroatoms, with unsubstituted radicals being preferred.
  • the radical R‘ is preferably an aromatic hydrocarbon radical.
  • Preferred vinylic olefinically unsaturated monomers are vinylaromatic hydrocarbons, especially vinyltoluene, alpha-methylstyrene, and especially styrene.
  • olefinically unsaturated monomers are preferred, such as acrylonitrile, methacrylonitrile, acrylamide, methacrylamide, N,N- dimethylacrylamide, N-[3-(dimethylamino)-propyl]-methacrylamide, vinyl acetate, vinyl propionate, vinyl chloride, N-vinylpyrrolidone, N-vinylcaprolactame, N- vinylformamide, N-vinylimidazole, and N-vinyl-2-methylimidazoline.
  • Suitable polyolefinically unsaturated monomers encompass esters of (meth)acrylic acid with an olefinically unsaturated radical R”, and allyl ethers of mono- or polyhydric alcohols.
  • the radical R“ may be an allyl radical or a (meth)acryloyl radical. or
  • Preferred polyolefinically unsaturated monomers include ethylene glycol di(meth)acrylate, 1 ,2-propylene glycol di(meth)acrylate, 2,2-propylene glycol di(meth)acrylate, butane-1 ,4-diol di(meth)acrylate, neopentyl glycol di(meth)acrylate, 3-methylpentanediol di(meth)acrylate, diethylene glycol di(meth)acrylate, triethylene glycol di(meth)acrylate, tetraethylene glycol di(meth)acrylate, dipropylene glycol di(meth)acrylate, tripropylene glycol di(meth)acrylate, polyethylene glycol di(meth)acrylate, hexanediol di(meth)acrylate, and allyl (meth)acrylate.
  • Polyolefinically unsaturated compounds additionally include acrylic and methacrylic esters of alcohols having more than two OH groups, such as, for example, trimethylolpropane tri(meth)acrylate or glycerol tri(meth)acrylate, but also trimethylolpropane di(meth)acrylate monoallyl ether, trimethylolpropane (meth)acrylate-diallyl ether, pentaerythritol tri(meth)acrylate monoallyl ether, pentaerythritol di(meth)acrylate diallyl ether, pentaerythritol (meth)acrylate triallyl ether, triallylsucrose, and pentaallylsucrose.
  • acrylic and methacrylic esters of alcohols having more than two OH groups such as, for example, trimethylolpropane tri(meth)acrylate or glycerol tri(meth)acrylate, but also trimethylolpropane
  • the (meth)acrylate-based polymer comprises a monomer mixture consisting of (a) 40 to 98 % by weight, preferably 50 to 88 % by weight, of C1-C10- alkyl esters of (meth)acrylic acid, (b) 2 to 45 % by weight, preferably 5 to 30 % by weight of polyolefinically unsaturated monomers, in particular diolefinically unsaturated monomers and (c) 0 to 20 % by weight, preferably 2 to 10 % by weight of monoolefinically unsaturated monomers which differ from monomers (a).
  • polymer composed of a monomer mixture consisting of is equivalent to the term “applied for manufacture (i.e., polymerization) of the polymer”.
  • the (meth)acrylate-based polymer is composed of the beforementioned monomer mixture.
  • At least one monomer (c) is selected from monomers having at least one, preferably one amino group.
  • monomers (c) are selected from at least one monomer having at least one amino group, preferably one amino group (i.e. monomers (c) are composed of only monomers having at least one, preferably one amino group).
  • Reason is that such monomers may be protonated and thus transferred into a cationic state, meaning that the composite particles, within a cationic electrodeposition process, may be driven to the to-be-coated substrate in order to facilitate actual deposition (similar as occurring with above-described component(a)).
  • the (meth)acrylate-based polymer is prepared in the presence of the metal-containing catalyst. This in-situ production provides very well for formation of actual composite particles, i.e. particles being hybrids of both the (meth)acrylate- based polymer and the catalyst.
  • the principle of production of the composite particles is preferably based on production from the above-specified monomers and the catalyst together with preferably a free-radical initiator in a reaction medium for polymerizing the monomers.
  • production takes place in an oil-in-water emulsion in which the monomers and the preferably water-insoluble catalyst plus potentially an organic solvent for solubilizing the catalyst (for example n-butyl acetate) take the form of the disperse phase in the aqueous dispersion medium, whereby preferably dispersants are included to enhance the formation of the dispersive character and to avoid aggregation and coagulation of the formed particles.
  • the composite particles will be available in form of an aqueous dispersion (or emulsion), i.e. in form of particles being present in an aqueous medium. It is preferred that the composite particles (p) are present, after production, in form of an aqueous dispersion as this allows direct application within the inventive electrocoat material.
  • the aqueous phase usually contains at least one dispersant in order to stabilize the droplets of the o/w emulsion during its production.
  • Dispersants suitable for stabilizing oil/water emulsions are common knowledge and are mentioned for example in EP 2794085 and EP 3007815 (therein also named protective colloids), the teaching of which is expressly incorporated by reference.
  • Typical dispersants include polysaccharides, polyvinyl alcohols, polymers bearing sulfonate groups, polymers bearing carboxylate groups, polyvinylpyrolidone, copolymers of vinylpyrrolidone and inorganic pickering stabilizers.
  • Suitable dispersants are typically water-soluble organic polymers.
  • Inorganic pickering systems such as colloidal silica and colloidal clay minerals may also be used as dispersants for this purpose.
  • the pickering stabilizers also referred to as pickering systems, may be used as such or in combination with the water-soluble organic polymers.
  • Dispersants of the group of polysaccharides include, for example, cellulose derivatives such as hydroxyethyl cellulose, methyl hydroxyethyl cellulose, methyl cellulose and carboxymethyl cellulose, methyl hydroxypropyl cellulose, lignin sulfonates and also mixtures of the above.
  • partially hydrolysed polyvinyl acetates also termed partially hydrolysed polyvinyl alcohols (PVAs) with particularly having a degree of hydrolysis of 70% to 99.9%, in particular 75 to 99%, more particular 80 to 95%.
  • PVA copolymers as described in WO 2015/165836, are also suitable.
  • the PVA may be in particular a carboxy-modified anionic PVA.
  • Such a carboxy-modified PVA preferably has a proportion of carboxyl groups of 1 to 6 mol%.
  • a carboxy-modified PVA is used as a dispersant, whose 4% by weight aqueous solution preferably has a viscosity in the range of 20.0 to 30.0 mPa*s at 20°C.
  • a group of partially hydrolysed polyvinyl alcohols particular preference is given to those having a degree of hydrolysis of 70% to 99.9%, in particular 75 to 99%, more particular 80 to 95% and especially 85 to 95%.
  • An especially preferred dispersant is a carboxy modified anionic PVA having 1 to 6 mol-% of carboxyl groups, based on the amount of repeating units and a degree of hydrolysis of in the range of 75 to 99%, in particular 80 to 95% and especially 85% to 95%.
  • those are preferred, whose 4% by weight aqueous solution has a viscosity of 20.0 to 30.0 mPa*s at 20°C.
  • dispersants are salts polymers bearing sulfonate groups.
  • Such polymers include homo and copolymers of ethylenically unsaturated sulfonic acids, such as 2-acrylamide-2-methylpropane sulfonic acid, optionally with one or more water-soluble monomers, such as acrylamide or methacrylamide and the salts thereof.
  • They also include the salts of lignin based sulfonic acids, also termed lignin sulfonates or lignosulfonates.
  • Suitable lignin sulfonates may comprise, for example, sodium lignosulfonate, calcium lignosulfonate, ammonium lignosulfonate, magnesium lignosulfonate, potassium lignosulfonate, or sulfomethylated lignosulfonate.
  • the aforementioned salts are in particular the sodium salts or the ammonium salts of the polymers bearing sulfonate groups.
  • such polymers are homo- or copolymers of monoethylenically unsaturated carboxylic acids, such as acrylic acid, methacrylic acid, maleic acid, fumaric acid or itaconic acid.
  • carboxylic acids such as acrylic acid, methacrylic acid, maleic acid, fumaric acid or itaconic acid.
  • the polymers bearing carboxyl groups are typically used in their partially or completely neutralized form, where the carboxyl groups are converted in the anionic carboxylate form.
  • the counterions are selected from sodium and ammonium.
  • the above-described production method conducted in oil-in-water emulsion is expected to facilitate the formation of capsules, i.e. particles having a shell or wall essentially comprising the resulting (meth)acrylate-based polymer (mp) enclosing the preferably water-insoluble catalyst (pc) which furthermore preferably is solubilized in an organic solvent.
  • the composite particles preferably have particle sizes (d5o(volume-based) measured by laser diffraction) in the range from 0.2 to 10 pm, preferably from 0.5 to 5 pm, in particular from 0.5 to 3 pm (dso).
  • the given particle sizes relate to the particle sizes as measured in the form in which the particles are present after manufacture, i.e. therefore preferably in form of an aqueous dispersion (or emulsion).
  • the weight ratio (w/w) of the metal-containing catalyst to the (meth)acrylate-based polymer preferably is from 98:2 to 20:80, more preferably from 97:3 to 50:50 and most preferably 95:5 to 60:40. Calculation of the weight ratio is done by consideration of the overall weight of monomers applied for production of the polymer and the weight of applied metal catalyst. Also, preferably, the weight ratio (w/w) of metal in the metal containing catalyst (i.e. calculated as metal) to the (meth)acrylate-based polymer is from 90:10 to 5:95, more preferably 85:15 to 15:85 and most preferably 80:20 to 20:80.
  • the composite particles (p) may be introduced into the inventive composition by versatile means.
  • the composite particles (and the aqueous dispersion (emulsion) of the particles, respectively) may be applied as is in the production of the composition as individual recipe constituent.
  • the particles (and aqueous dispersion (emulsion) of the particles, respectively) may be part of, for example, the binder dispersion (I).
  • the present invention also relates to a method of production of composite particles (p) comprising at least one metal-containing catalyst (pc) and at least one (meth)acrylate polymer (mp), wherein the polymer (mp) is prepared in the presence of the metal-containing catalyst (pc), whereby the method comprises the steps of
  • step (1 ) (2) polymerizing the monomers in the oil-in-water emulsion of step (1 ) by means of an initiator.
  • the oil-in-water emulsion of step (1 ) comprises at least one protective colloid.
  • the present invention relates to composite particles (p) prepared according to the above-defined method.
  • the present invention also relates to a method of manufacturing a cathodically depositable electrodeposition coating material composition comprising
  • At least one component comprises at least one kind of composite particles (p) comprising at least one metal-containing catalyst (pc) and at least one (meth)acrylate-based polymer (mp), wherein the polymer (mp) is prepared in the presence of the metal-containing catalyst (pc).
  • any and all essential and also preferred features and embodiments mentioned above in the context of the inventive composition likewise apply for the kit of parts and method of manufacturing.
  • a further subject of the present invention is a method for at least partially coating an electrically conductive substrate by cathodic electrodeposition coating comprising at least steps (1 ) to (5), namely
  • the above-mentioned method comprises, between step (4) and (5), a step (4.1 ) of rinsing the coated substrate, for example with DI water.
  • This step serves the cleaning of the substrate, i.e. removal of residual coating material not being well deposited on the substrate.
  • the method of the invention is particularly suitable for the electrodeposition coating of automotive vehicle bodies or parts thereof including respective metallic substrates.
  • the preferred substrates are automotive vehicle bodies or parts thereof.
  • Such substrates are metallic automotive component parts like, for example, transverse control arms, spring-loaded control arms or dampers.
  • Such component parts may be cast iron parts or may also be produced by other established methods known in the art.
  • substrates are metallic automotive bodies, for example automotive bodies that were partly stamped to cut out specific parts or form specific geometries and thus also comprise comparably many edges.
  • electrically conductive substrate used in accordance with the invention are all electrically conductive substrates used customarily and known to the skilled person.
  • the electrically conductive substrates used in accordance with the invention are preferably metallic substrates, more preferably selected from the group consisting of steel, preferably steel selected from the group consisting of bare steel, cold rolled steel (CRS), hot rolled steel, galvanized steel such as hot dip galvanized steel (HDG), alloy galvanized steel (such as, for example, Galvalume, Galvannealed or Galfan) and aluminized steel, aluminum and magnesium, and also Zn/Mg alloys and Zn/Ni alloys.
  • Particularly suitable substrates are parts of vehicle bodies or complete bodies of automobiles for production.
  • step (1 ) of the inventive method Before the respective electrically conductive substrate is used in step (1 ) of the inventive method, it is preferably cleaned and/or degreased.
  • the electrically conductive substrate used in accordance with the invention is preferably a pretreated substrate, for example pretreated with at least one metal phosphate such as zinc phosphate.
  • a pretreatment of this kind by means of phosphating which takes place normally after the substrate has been cleaned and before the substrate is electrodeposition-coated in step (1 ), is in particular a pretreatment step that is customary in the automobile industry.
  • Pretreatment methods other than phosphating are, however, also possible, for example a thin film pretreatment based on zirconium oxide or typical silanes.
  • the electrodeposition coating material composition of the invention is deposited cathodically on the region of the substrate immersed into the bath in step (1 ).
  • the substrate is connected as the cathode, and an electrical voltage is applied between the substrate and at least one counterelectrode, which is located in the deposition bath or is present separately from it, for example by way of an anion exchange membrane which is permeable for anions.
  • the counterelectrode functions, accordingly, as an anode.
  • a firmly adhering coating film is deposited on the cathode, i.e., on the immersed part of the substrate.
  • the voltage applied here is preferably in a range from 50 to 500 volts.
  • the electrodeposition coating bath preferably has a bath temperature in a range from 20 to 45°C.
  • the baking temperature in step (5) is preferably in a range from 100 to 210°C, more preferably from 120 to 205°C, very preferably from 120 to 200°C, more particularly from 125 to 195°C or from 125°C to 190°C, most preferably from 130 to 185°C or from 140 to 180°C.
  • one or more further coating layers can be applied onto the baked coating film obtained after step (5).
  • a primer and/or filler can be applied, followed by a basecoat and a clearcoat.
  • the inventive method preferably comprises at least one further step (6), namely
  • a further subject of the present invention is an electrically conductive substrate which is coated at least partially with a baked electrodeposition coating material of the invention.
  • the baked coating material corresponds to the baked coating film obtained after step (5) of the inventive method.
  • a baked electrodeposition coating layer produced from an inventive electrodeposition coating material composition is a subject of the present invention.
  • the nonvolatile fraction (the solids or solids content) is determined in accordance with DIN EN ISO 3251 (date: June 2019). This involves weighing out 1 g of sample into an aluminum dish which has been dried beforehand and drying the dish with sample in a drying cabinet at 180°C for 30 minutes, cooling it in a desiccator, and then reweighing. The residue, relative to the total amount of sample employed, corresponds to the nonvolatile fraction (in % or wt.-%)
  • the glass transition temperature T g is determined with differential scanning calorimetry (DSC) according to DIN 53765:1994-03 using a heating rate of 10 K/min.
  • the pH value was determined according to DIN 55659-1 (Jan 2012).
  • the film thicknesses are determined according to DIN EN ISO 2808 (date: May 2007), method 12A, using Dualscope FM40 instrument from Fischer.
  • the determination of the acetone resistance is performed on test panels (GB 6800/OC Chemetall) that were ED-coated and cured according to the above mentioned 5 step procedure.
  • the coated panels are rubbed with a hammer-like tool which has a weight of 1 kg and a head containing a cotton wool immersed in acetone.
  • the hammer-like tool and with it the wool with acetone is pushed and pulled over the coating surface without any additional pressure, one time in each direction is counted as 1 double rub.
  • 200 double rubs are evaluated as excellent acetone resistance (i.e. excellent curing performance), meaning that 200 double rubs are the maximum number of double rubs conducted in the test.
  • the number of double rubs given below in the result section corresponds to the number at which a delamination of cured coating material is observed (or, in case of a result of 200 in acetone resistance, no such delamination occurs).
  • binder resins content (non-volatile fraction) - (pigment and filler content))
  • aqueous solution of a commercially available polyvinyl alcohol (10 wt.-%) were mixed to give a mixture 1.
  • a mixture 2 of Bismuth neodecanoate catalyst, optionally an organic solvent, and the monomer(s) to be used for preparing the (meth)acrylate-based polymer was prepared.
  • Mixture 2 was then emulsified in mixture 1 using, for example, a silent crusher (rotor stator dispersion tool) for 5 min at 18.000 rpm to result in an oil-in-water emulsion.
  • Temperature was maintained below 35 °C during the emulsification step using an ice bath.
  • the emulsion was then transferred to a glass reactor equipped with an anchor stirrer and a water-condenser and stirred at 130 rpm. Nitrogen gas was flown in the reactor over the whole polymerization. Radical initiator (thermal initiator) was then added to the media and the temperature was raised: Starting from 20 °C, 75 °C is reached over 60 minutes (linear rate). Then, the temperature was raised to 85 °C within 60 min (linear rate) and held for 60 min. Afterwards, the system was cooled down to room temperature (20 °C) over 60 min (linear rate). At the beginning of the cooling, initiators (redox initiator partners) were added over 50 minutes to the media to decrease the residual monomer content.
  • Radical initiator thermal initiator
  • Monomers applied were as follows: MMA: methyl methacrylate, tBMA: te/Y-butyl methacrylate, DMAPMA: Dimethylaminopropyl methacrylamide, nBA: n-butyl acrylate, BDDA: 1 ,4-butanediol diacrylate.
  • n-butyl acetate (BA) was applied as optional organic solvent.
  • Vit C L(+)-ascorbic acid
  • tBHP tert- Butylhydroperoxid
  • Composite particles were prepared from (i) MMA/tBMA/DMAPMA/BDDA utilized in a 60/25/5/10 wt.-% ratio and (ii) 75/25 wt.-%-mixture of K-Kat XK 651 (King Industries) as active catalyst and BA as solvent.
  • the targeted ratio of metal-containing catalyst and polymer was 90/10 wt.-%.
  • An overall active content of 32.15 wt% in the final dispersion was targeted.
  • an aqueous solution was prepared by diluting 270.0 g of 10 wt.-% aqueous solution of Mowiol 40-88 in 271.64 g of demineralized water and 2.16 g of 2.5 wt.-% aqueous solution of sodium nitrite. Then, the oil phase was obtained by mixing 364.5 g of K-Kat XK 651 , 121.5 g of BA, 32.4 g of MMA, 13.5 g of tBMA, 2.7 g of DMAPMA and 5.4 g of BDDA.
  • the oil phase was emulsified in the water phase using a laboratory dissolver equipped with a 5 cm diameter dissolver disk for 40 min at 3.500 rpm. Temperature of the emulsion was maintained below 35 °C during the emulsification step using an ice bath. The glass reactor was then equipped with an anchor stirrer and a water-condenser and stirred at 130 rpm. Nitrogen gas was flown in the reactor over the whole polymerization. 3.24 g of tert-butyl peroxyneodecanoate was added as thermal initiator to the dispersion and the temperature was raised: Starting from 20 °C, 75 °C was reached over 60 minutes (linear rate).
  • the temperature was raised to 85 °C within 60 min (linear rate) and held for 60 min. Afterwards, the system was cooled down to room temperature (20 °C) within 60 min (linear rate). At the beginning of the cooling, 15.66 g of 10 wt.- % aqueous solution tBHP was added within 3 min while 30.94 g of 10 wt.-% aqueous solution Vit C was added consecutively over 50 minutes to the media to decrease the residual monomer content.
  • Composite particles were prepared from (i) MMA/DMAPMA/BDDA utilized in an 80/5/15 wt.-% ratio and (ii) K-Kat XK 651 (King Industries) as active catalyst.
  • the targeted ratio of metal-containing catalyst and polymer was 90/10 wt.-%.
  • An overall active content of 35.75 wt% in the final dispersion was targeted.
  • an aqueous solution was prepared by diluting 405 g of 10 wt.-% aqueous solution of Mowiol 40-88 in 160.95 g of demineralized water and 4.32 g of 2.5 wt.-% aqueous solution of sodium nitrite. 0.03 g of Tego Foamex 3062 defoamer was added. Then, the oil phase was obtained by mixing 486 g of K-Kat XK 651 , 43.2 g of MMA, 2.7 g of DMAPMA and 8.1 g of BDDA.
  • the oil phase was emulsified in the water phase using a laboratory dissolver equipped with a 5 cm diameter dissolver disk for 40 min at 3.500 rpm. Temperature of the emulsion was maintained below 35 °C during the emulsification step using an ice bath. The glass reactor was then equipped with an anchor stirrer and a water-condenser and stirred at 130 rpm. 100 g demineralized water was added. Nitrogen gas was flown in the reactor over the whole polymerization. 3.24 g of tert-butyl peroxyneodecanoate was added as thermal initiator to the dispersion and the temperature was raised: Starting from 20 °C, 75 °C was reached over 60 minutes (linear rate).
  • Composite particles were prepared from (i) MMA/DMAPMA/BDDA utilized in an 80/5/15 wt.-% ratio and (ii) K-Kat XK 651 (King Industries) as active catalyst.
  • the targeted ratio of metal-containing catalyst and polymer was 90/10 wt.-%.
  • An overall active content of 35.73 wt% in the final dispersion was targeted.
  • an aqueous solution was prepared by diluting 899.10 g of 10 wt.-% aqueous solution of Mowiol 40-88 in 357.31 g of demineralized water and 9.59 g of 2.5 wt.-% aqueous solution of sodium nitrite. 0.30 g of Silicon SRE-PFL defoamer was finally added. Then, the oil phase was obtained by mixing 1078.92 g of K-Kat XK 651 , 95.9 g of MMA, 5.99 g of DMAPMA and 17.98 g of BDDA.
  • the oil phase was emulsified in the water phase using a laboratory dissolver equipped with a 5 cm diameter dissolver disk for 40 min at 3.500 rpm. Temperature of the emulsion was maintained below 35 °C during the emulsification step using an ice bath. The glass reactor was then equipped with an anchor stirrer and a water-condenser and stirred at 130 rpm. 444 g of demineralized water was added. Nitrogen gas was flown in the reactor over the whole polymerization.
  • tert-butyl peroxyneodecanoate was added as thermal initiator to the dispersion and the temperature was raised: Starting from 20 °C, 75 °C was reached over 60 minutes (linear rate). Then, the temperature was raised to 85 °C within 60 min (linear rate) and held for 60 min. Afterwards, the system was cooled down to room temperature (20 °C) within 60 min (linear rate). At the beginning of the cooling, 68.69 g of 10 wt.-% aq solution Vit C was added within 3 min while 34.77 g of 10 wt.-% aq solution tBHP was added consecutively over 50 minutes to the media to decrease the residual monomer content.
  • Table 1 shows different composite particles prepared according to the general procedure outlined under 1.1.
  • a standard pigment paste P1 customary used in the preparation of aqueous cathodically depositable electrodeposition coating material compositions is prepared by (i) mixing respective constituents in a dissolver and (ii) milling the mixture from (i) using a standard mill under customary conditions at a temperature not exceeding 35°C.
  • Pigment paste P1 comprises a grinding resin (solids content 40 %).
  • paste P1 comprises bismuth(lll) subnitrate as a catalyst, carbon black as a black pigment and titanium dioxide as white pigment and also kaolin as a filler.
  • water and additives customary for aqueous cathodically depositable electrodeposition coating material compositions were applied. The amount of bismuth(lll), calculated as bismuth metal, was 4.38 %, based on the total weight of the pigment paste P1 .
  • a pigment slurry (II) is produced as follows. At first, 107 parts by weight (pbw) of water, 38 pbw of butyl di glycol as well as a defoamer, a dispersant additive and a neutralizing agent are weighted in a dissolver and then homogenized. The total mixture, at this stage, has a sum of 188 pbw. Then, 700 pbw of titanium dioxide white pigment was added under slow stirring. Afterwards, the mixture is dissolved at high speed to achieve a homogeneous state. Then, 112 pbw of water is added, the resulting mixture is again dissolved at medium speed and then filtered.
  • the pigment slurry (II) has a pigment and filler content of 70 %.
  • the slurry does not contain a customary grinding resin.
  • the binder resins content is well below 5 %.
  • the constituents of the binder dispersion are added in an individual order, whereby different mixing (dissolving) steps and dispersing stages took place.
  • the solids content of the binder dispersions is 38 %.
  • electrodeposition coating material compositions were prepared. While the comparative system (C1 ) was prepared from pigment paste P1 and the binder dispersion (I), the inventive composition (E1 ) was prepared from pigment slurry (II), binder dispersion (I) and also composite particles according to Example 8 above.
  • Coating films obtained from the electrodeposition coating material compositions (C1 ) and (E1 ) are deposited on cathodically connected test panels under customary conditions and baked at a substrate temperature of 175°C for 15 minutes afterwards, to obtain a coating layer thickness of approximately 20-22 Micrometer.
  • test panels cold-rolled steel substrates which were pretreated with a phosphatizing composition (spray applied zinc manganese phosphatizing composition) were used (Gardobond® GB26S 6800 OC)).
  • composition (C1 ) and with composition (E1 ) showed an excellent acetone resistance (200 double rubs, each).
  • the examples show that the inventive aqueous cathodically depositable electrodeposition coating material composition containing a pigment slurry shows an excellent curing performance which also is comparable with the performance of a standard composition relying on a pigment paste.
  • the inventive composition contains the catalyst not in form of a pigment paste, but still in a way of catalytic activity, meaning that the application of pigment pastes may be avoided or at least significantly reduced.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
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Abstract

La présente invention concerne une composition aqueuse de matériau de revêtement par électrodéposition pouvant être déposée par voie cathodique comprenant (I) au moins une dispersion de liant comprenant au moins un polymère pouvant être déposé par voie cathodique (a) et au moins un agent de réticulation (b), (II) au moins une suspension de pigment contenant au moins un pigment et/ou une charge (c), la composition comprenant également au moins un type de particules composites (p) comprenant au moins un catalyseur contenant un métal (pc) et au moins un polymère de (méth)acrylate (mp).
PCT/EP2023/072642 2022-09-15 2023-08-17 Compositions de matériau de revêtement par électrodéposition comprenant une suspension de pigment et des particules composites contenant un catalyseur contenant du métal WO2024056308A1 (fr)

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Citations (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0004090A2 (fr) 1978-03-13 1979-09-19 Herberts Gesellschaft mit beschränkter Haftung Composition d'enduction aqueuse déposable par électrophorèse
EP0012463A1 (fr) 1978-12-11 1980-06-25 Shell Internationale Researchmaatschappij B.V. Compositions de liants résineux thermodurcissables, leur préparation et leur utilisation comme matériaux de revêtement
DE3518770A1 (de) 1985-05-24 1986-11-27 BASF Lacke + Farben AG, 4400 Münster Wasserverduennbare bindemittel fuer kationische elektrotauchlacke und verfahren zu ihrer herstellung
DE3518732A1 (de) 1985-05-24 1986-11-27 BASF Lacke + Farben AG, 4400 Münster Wasserverduennbare bindemittel fuer kationische elektrotauchlacke und verfahren zu ihrer herstellung
WO1991009917A2 (fr) 1989-12-23 1991-07-11 Basf Lacke + Farben Aktiengesellschaft Procede pour revetir des substrats electroconducteurs, vernis aqueux, produit d'addition amine-epoxy et emploi de ce dernier comme resine de friction pour la fabrication de pates pigmentaires
US5084541A (en) 1988-12-19 1992-01-28 American Cyanamid Company Triazine crosslinking agents and curable compositions
WO1993000402A1 (fr) * 1991-06-27 1993-01-07 Basf Corporation Composition pour peinture par electrophorese contenant une dispersion d'un pigment solide
DE19703869A1 (de) 1997-02-03 1998-08-06 Basf Coatings Ag Wäßrige Bindemitteldispersion für kationische Elektrotauchlacke
DE19712940A1 (de) 1997-03-27 1998-10-01 Basf Coatings Ag Wäßriges Beschichtungsmittel
EP1041125A1 (fr) 1997-12-12 2000-10-04 Kansai Paint Co., Ltd. Composition de peinture pour electrodeposition cationique
US20030000837A1 (en) * 2001-05-15 2003-01-02 Kaylo Alan J. Biodegradation-resistant electrodepositable coating compositions and methods related thereto
DE10139171A1 (de) 2001-08-16 2003-02-27 Basf Ag Verwendung von Mikrokapseln in Gipskartonplatten
WO2006117189A1 (fr) 2005-05-02 2006-11-09 Eckart Gmbh & Co. Kg Peinture par electrolyse anodique, sa production et son utilisation, utilisation de pigments metalliques en forme de pastilles et objet revetu
EP1743925A1 (fr) * 2005-07-16 2007-01-17 Cytec Surface Specialties Austria GmbH Liants diluables dans l'eau pour revêtements par électrodéposition cathodique
US20080254284A1 (en) * 2007-04-13 2008-10-16 Valspar Sourcing, Inc. Epoxy-based electroplating composition
US20100167089A1 (en) * 2008-12-29 2010-07-01 Basf Corporation Metal containing integrated electrocoat for better corrosion resistance
WO2011004006A2 (fr) 2009-07-10 2011-01-13 Basf Se Microcapsules comprenant des monomères polyvinyle comme agents réticulants
WO2012110443A1 (fr) 2011-02-16 2012-08-23 Basf Se Microcapsules à composition de paraffine comme coeur de capsule
EP2794085A2 (fr) 2011-12-19 2014-10-29 Basf Se Dispersion de microcapsules contenant des microcapsules à noyau hydrophile
WO2015165836A1 (fr) 2014-04-29 2015-11-05 Basf Se Procédé de production de microcapsules
US20150361227A1 (en) 2013-02-25 2015-12-17 Basf Se Particulate microcapsule composition
EP3007815A1 (fr) 2013-06-14 2016-04-20 Basf Se Procédé de production d'une dispersion de microcapsules contenant des microcapsules dotées d'un noyau hydrophile
WO2021198866A1 (fr) * 2020-03-31 2021-10-07 Kansai Nerolac Paints Limited Composition bleue de revêtement par électrodéposition cathodique (ced)

Patent Citations (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0004090A2 (fr) 1978-03-13 1979-09-19 Herberts Gesellschaft mit beschränkter Haftung Composition d'enduction aqueuse déposable par électrophorèse
EP0012463A1 (fr) 1978-12-11 1980-06-25 Shell Internationale Researchmaatschappij B.V. Compositions de liants résineux thermodurcissables, leur préparation et leur utilisation comme matériaux de revêtement
DE3518770A1 (de) 1985-05-24 1986-11-27 BASF Lacke + Farben AG, 4400 Münster Wasserverduennbare bindemittel fuer kationische elektrotauchlacke und verfahren zu ihrer herstellung
DE3518732A1 (de) 1985-05-24 1986-11-27 BASF Lacke + Farben AG, 4400 Münster Wasserverduennbare bindemittel fuer kationische elektrotauchlacke und verfahren zu ihrer herstellung
US5084541A (en) 1988-12-19 1992-01-28 American Cyanamid Company Triazine crosslinking agents and curable compositions
EP0505445B1 (fr) 1989-12-23 1994-11-17 BASF Lacke + Farben AG Procede pour revetir des substrats electroconducteurs, vernis aqueux, produit d'addition amine-epoxy et emploi de ce dernier comme resine de friction pour la fabrication de pates pigmentaires
WO1991009917A2 (fr) 1989-12-23 1991-07-11 Basf Lacke + Farben Aktiengesellschaft Procede pour revetir des substrats electroconducteurs, vernis aqueux, produit d'addition amine-epoxy et emploi de ce dernier comme resine de friction pour la fabrication de pates pigmentaires
WO1993000402A1 (fr) * 1991-06-27 1993-01-07 Basf Corporation Composition pour peinture par electrophorese contenant une dispersion d'un pigment solide
DE19703869A1 (de) 1997-02-03 1998-08-06 Basf Coatings Ag Wäßrige Bindemitteldispersion für kationische Elektrotauchlacke
EP0961797B1 (fr) 1997-02-03 2003-04-09 BASF Coatings Aktiengesellschaft Dispersion aqueuse de liant pour peinture pour trempage electrophoretique
DE19712940A1 (de) 1997-03-27 1998-10-01 Basf Coatings Ag Wäßriges Beschichtungsmittel
EP1041125A1 (fr) 1997-12-12 2000-10-04 Kansai Paint Co., Ltd. Composition de peinture pour electrodeposition cationique
US20030000837A1 (en) * 2001-05-15 2003-01-02 Kaylo Alan J. Biodegradation-resistant electrodepositable coating compositions and methods related thereto
DE10139171A1 (de) 2001-08-16 2003-02-27 Basf Ag Verwendung von Mikrokapseln in Gipskartonplatten
WO2006117189A1 (fr) 2005-05-02 2006-11-09 Eckart Gmbh & Co. Kg Peinture par electrolyse anodique, sa production et son utilisation, utilisation de pigments metalliques en forme de pastilles et objet revetu
EP1743925A1 (fr) * 2005-07-16 2007-01-17 Cytec Surface Specialties Austria GmbH Liants diluables dans l'eau pour revêtements par électrodéposition cathodique
US20080254284A1 (en) * 2007-04-13 2008-10-16 Valspar Sourcing, Inc. Epoxy-based electroplating composition
US20100167089A1 (en) * 2008-12-29 2010-07-01 Basf Corporation Metal containing integrated electrocoat for better corrosion resistance
WO2011004006A2 (fr) 2009-07-10 2011-01-13 Basf Se Microcapsules comprenant des monomères polyvinyle comme agents réticulants
WO2012110443A1 (fr) 2011-02-16 2012-08-23 Basf Se Microcapsules à composition de paraffine comme coeur de capsule
EP2794085A2 (fr) 2011-12-19 2014-10-29 Basf Se Dispersion de microcapsules contenant des microcapsules à noyau hydrophile
US20150361227A1 (en) 2013-02-25 2015-12-17 Basf Se Particulate microcapsule composition
EP3007815A1 (fr) 2013-06-14 2016-04-20 Basf Se Procédé de production d'une dispersion de microcapsules contenant des microcapsules dotées d'un noyau hydrophile
WO2015165836A1 (fr) 2014-04-29 2015-11-05 Basf Se Procédé de production de microcapsules
WO2021198866A1 (fr) * 2020-03-31 2021-10-07 Kansai Nerolac Paints Limited Composition bleue de revêtement par électrodéposition cathodique (ced)

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
GEORG THIEME VERLAG, ROMPP LEXIKON LACKE UND DRUCKFARBEN, 1998, pages 250

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