Classifications

• • G—PHYSICS
  • G02—OPTICS
  • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
  • G02B5/00—Optical elements other than lenses
  • G02B5/30—Polarising elements
  • G02B5/3016—Polarising elements involving passive liquid crystal elements
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  • C09K19/06—Non-steroidal liquid crystal compounds
  • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
  • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
  • C09K19/20—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers
  • C09K19/2007—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers the chain containing -COO- or -OCO- groups
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  • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
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  • C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
  • C09K19/3001—Cyclohexane rings
  • C09K19/3066—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers
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• • G—PHYSICS
  • G02—OPTICS
  • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
  • G02B5/00—Optical elements other than lenses
  • G02B5/30—Polarising elements
• • G—PHYSICS
  • G02—OPTICS
  • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
  • G02B5/00—Optical elements other than lenses
  • G02B5/30—Polarising elements
  • G02B5/3083—Birefringent or phase retarding elements
• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
  • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
  • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
  • G02F1/1323—Arrangements for providing a switchable viewing angle
• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
  • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
  • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
  • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
  • G02F1/1333—Constructional arrangements; Manufacturing methods
  • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
  • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
  • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
  • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
  • G02F1/1333—Constructional arrangements; Manufacturing methods
  • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
  • G02F1/133528—Polarisers
• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
  • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
  • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
  • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
  • G02F1/1333—Constructional arrangements; Manufacturing methods
  • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
  • G02F1/13363—Birefringent elements, e.g. for optical compensation
• • H—ELECTRICITY
  • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
  • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
  • H05B33/00—Electroluminescent light sources
  • H05B33/02—Details
• • H—ELECTRICITY
  • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
  • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
  • H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
  • H10K59/80—Constructional details
  • H10K59/875—Arrangements for extracting light from the devices
  • H10K59/879—Arrangements for extracting light from the devices comprising refractive means, e.g. lenses
• • H—ELECTRICITY
  • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
  • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
  • H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
  • H10K59/80—Constructional details
  • H10K59/8793—Arrangements for polarized light emission
• • C—CHEMISTRY; METALLURGY
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  • C09K19/00—Liquid crystal materials
  • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
  • C09K2019/0444—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group
  • C09K2019/0448—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group the end chain group being a polymerizable end group, e.g. -Sp-P or acrylate
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  • C09K19/00—Liquid crystal materials
  • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
  • C09K19/06—Non-steroidal liquid crystal compounds
  • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
  • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
  • C09K19/20—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers
  • C09K19/2007—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers the chain containing -COO- or -OCO- groups
  • C09K2019/2042—Ph-Ph-COO-Ph
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  • C09K19/00—Liquid crystal materials
  • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
  • C09K19/06—Non-steroidal liquid crystal compounds
  • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
  • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
  • C09K19/20—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers
  • C09K19/2007—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers the chain containing -COO- or -OCO- groups
  • C09K2019/2064—Ph-Ph-COO-Ph-Ph
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  • C09K19/00—Liquid crystal materials
  • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
  • C09K19/06—Non-steroidal liquid crystal compounds
  • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
  • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
  • C09K19/20—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers
  • C09K19/2007—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers the chain containing -COO- or -OCO- groups
  • C09K2019/2078—Ph-COO-Ph-COO-Ph
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  • C09K19/06—Non-steroidal liquid crystal compounds
  • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
  • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
  • C09K19/20—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers
  • C09K19/2007—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers the chain containing -COO- or -OCO- groups
  • C09K2019/2085—Ph-CH=CH-Ph-COO-Ph
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  • C09K19/06—Non-steroidal liquid crystal compounds
  • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
  • C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
  • C09K19/3001—Cyclohexane rings
  • C09K19/3066—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers
  • C09K19/3068—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers chain containing -COO- or -OCO- groups
  • C09K2019/3075—Cy-COO-Ph

Definitions

• the present invention relates to a light absorption anisotropic layer, an optical film, a viewing angle control system and an image display device.
• Patent Document 1 discloses a polarizer ( A viewing angle control system with a light absorbing anisotropic layer) is disclosed.
• the inventors of the present invention examined the viewing angle control system described in Patent Document 1, and found that the reflection on the window glass (front glass) located above the in-vehicle display was reduced. There is room for improvement in the difference between the transmittance of the anisotropic layer in the front direction and the transmittance in the oblique direction (hereinafter abbreviated as “contrast”). It can be seen that the hue changes greatly from the original color to red, green, and blue, and as a result, the reflected image with suppressed brightness becomes conspicuous again. made it clear.
• the present invention provides a light absorption differential optical system which has high contrast and can suppress hue change with respect to the original image for an image reflected in the surroundings (for example, window glass) when used in a viewing angle control system.
• An object of the present invention is to provide an anisotropic layer, an optical film, a viewing angle control system and an image display device using the same.
• an optically anisotropic layer formed from a liquid crystal composition containing a liquid crystalline compound, a dichroic substance and an alignment agent has a smectic liquid crystalline compound.
• the liquid crystal state of the phase is exhibited, and the content of the dichroic substance is 5.0% by mass or more with respect to the total solid mass of the liquid crystal composition, so that the contrast is high and when used in a viewing angle control system
• the inventors have found that it is possible to suppress the hue change from the original image in the image reflected in the surroundings, and completed the present invention. That is, the inventors have found that the above problems can be solved by the following configuration.
• a light absorption anisotropic layer formed from a liquid crystal composition containing a liquid crystal compound, a dichroic substance, and an alignment agent,
• the liquid crystalline compound is a liquid crystalline compound exhibiting a smectic phase liquid crystal state
• the content of the dichroic substance is 5.0% by mass or more with respect to the total solid mass of the liquid crystal composition
• An anisotropic light absorption layer wherein the angle ⁇ between the central axis of transmittance of the anisotropic light absorption layer and the normal direction of the surface of the anisotropic light absorption layer is 0° or more and 45° or less.
• the dichroic substance is at least one dichroic substance having a maximum absorption wavelength in the wavelength range of 370 to 550 nm, and at least one dichroic substance having a maximum absorption wavelength in the wavelength range of 500 to 700 nm.
• the light absorption anisotropic layer according to any one of [1] to [6] which has a thickness of 4.0 ⁇ m or less.
• the liquid crystalline compound is a liquid crystalline compound exhibiting any one of smectic B phase, E phase, F phase, G phase, H phase, I phase, J phase, K phase and L phase, [ 1] to the light absorption anisotropic layer according to any one of [7].
• the alignment agent is at least one compound selected from the group consisting of nonionic silane compounds and ionic compounds. .
• An optical film comprising a transparent film substrate and the light absorption anisotropic layer according to any one of [1] to [10] provided on the transparent film substrate.
• the optical film of [11] which has an alignment film between the transparent film substrate and the light absorption anisotropic layer.
• a polarizer having an absorption axis in the in-plane direction, and the light absorption anisotropic layer according to any one of [1] to [10] or the optical film according to [11] or [12].
• viewing angle control system [14] having a display element and the viewing angle control system according to [13], An image display device, wherein the viewing angle control system is arranged on at least one major surface of the display element.
• the image display device according to [14], wherein the light absorption anisotropic layer of the viewing angle control system is arranged on the viewing side of the polarizer of the viewing angle control system.
• the contrast is high, and when used in a viewing angle control system, an optical absorption difference that can suppress a hue change with respect to an original image with respect to an image reflected in the surroundings (for example, window glass).
• An anisotropic layer, an optical film, a viewing angle control system and an image display device using the same can be provided.
• a numerical range represented by "-" means a range including the numerical values before and after "-" as lower and upper limits.
• parallel and orthogonal do not mean parallel and orthogonal in a strict sense, respectively, but mean a range of parallel ⁇ 5° and a range of orthogonal ⁇ 5°, respectively.
• both the liquid crystalline composition and the liquid crystalline compound conceptually include those that no longer exhibit liquid crystallinity due to curing or the like.
• each component may use the substance applicable to each component individually by 1 type, or may use 2 or more types together.
• the content of the component refers to the total content of the substances used in combination unless otherwise specified.
• (meth)acrylate” is a notation representing “acrylate” or “methacrylate”
• (meth)acryl is a notation representing "acrylic” or “methacrylic”
• (Meth)acryloyl” is a notation representing “acryloyl” or “methacryloyl”.
• the substituent W used in this specification represents the following groups.
• Examples of the substituent W include a halogen atom, an alkyl group having 1 to 20 carbon atoms, a halogenated alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 1 to 20 carbon atoms, and an alkylcarbonyl group having 1 to 10 carbon atoms.
• an alkyloxycarbonyl group having 1 to 10 carbon atoms an alkylcarbonyloxy group having 1 to 10 carbon atoms, an alkylamino group having 1 to 10 carbon atoms, an alkylaminocarbonyl group, an alkoxy group having 1 to 20 carbon atoms, and 1 carbon atom ⁇ 20 alkenyl groups, alkynyl groups having 1 to 20 carbon atoms, aryl groups having 1 to 20 carbon atoms, heterocyclic groups (also referred to as heterocyclic groups), cyano groups, hydroxy groups, nitro groups, carboxy groups, aryloxy group, silyloxy group, heterocyclic oxy group, acyloxy group, carbamoyloxy group, alkoxycarbonyloxy group, aryloxycarbonyloxy group, amino group (including anilino group), ammonio group, acylamino group, aminocarbonylamino group, alkoxycarbonylamino group, aryloxycarbonylamino group,
• LW represents a single bond or a divalent linking group
• SPW represents a divalent spacer group
• Q represents Q1 or Q2 in formula (A-1) below
• * represents a binding position.
• the divalent linking group represented by LW includes —O—, —(CH 2 ) g —, —(CF 2 ) g —, —Si(CH 3 ) 2 —, and —(Si(CH 3 ) 2 O).
• the divalent spacer group represented by SPW includes a linear, branched or cyclic alkylene group having 1 to 50 carbon atoms, or a heterocyclic group having 1 to 20 carbon atoms.
• the hydrogen atom of the alkylene group and the hydrogen atom of the heterocyclic group are a halogen atom, a cyano group, -Z H , -OH, -OZ H , -COOH, -C(O)Z H , -C(O) OZ H , -OC(O)Z H , -OC(O)OZ H , -NZ H Z H ', -NZ H C(O) Z H ', -NZ H C(O) OZ H ', -C (O) NZHZH ', -OC (O) NZHZH ', -NZHC (O) NZH'OZH '', -SH , -SZH , -C (S) ZH , —C(O)SZ H , —SC(O)Z H (hereinafter also abbreviated as “SP-H”).
• Z H and Z H ' are alkyl groups having 1 to 10 carbon atoms, halogenated alkyl groups, -L-CL (L represents a single bond or a divalent linking group. Specific examples of the divalent linking group is the same as LW and SPW described above.
• CL represents a crosslinkable group, and includes groups represented by Q1 or Q2 in formula (A-1) described below, and formulas (P-1) to A polymerizable group represented by (P-30) is preferable.).
• the light absorption anisotropic layer of the present invention is a light absorption anisotropic layer formed from a liquid crystal composition containing a liquid crystal compound, a dichroic substance, and an alignment agent.
• the liquid crystalline compound is a liquid crystalline compound exhibiting a smectic liquid crystal state.
• the content of the dichroic substance is 5.0% by mass or more with respect to the total solid mass of the liquid crystal composition.
• the anisotropic light absorption layer of the present invention has an angle ⁇ between the transmittance central axis of the anisotropic light absorption layer and the normal direction of the surface of the anisotropic light absorption layer (hereinafter referred to as "transmittance central axis Also abbreviated as “angle ⁇ ”) is 0° or more and 45° or less.
• the central axis of transmittance means the highest transmittance when the transmittance is measured by changing the tilt angle (polar angle) and the tilt direction (azimuth angle) with respect to the normal direction of the light absorption anisotropic layer surface. means the direction of the rate.
• AxoScan OPMF-1 manufactured by Optoscience is used to actually measure the Mueller matrix at a wavelength of 550 nm.
• the azimuth angle at which the transmittance central axis is tilted is first searched, and then the plane ( In the plane including the transmittance central axis and perpendicular to the layer surface), the wavelength A Mueller matrix at 550 nm is actually measured to derive the transmittance of the light absorption anisotropic layer.
• the direction with the highest transmittance is taken as the center axis of transmittance.
• the transmittance central axis means the direction of the absorption axis of the dichroic substance contained in the light absorption anisotropic layer (molecular long axis direction).
• the liquid crystalline compound exhibits a liquid crystal state of a smectic phase, and a dichroic a light absorption anisotropic layer in which the content of the optical substance is 5.0% by mass or more relative to the total solid mass of the liquid crystal composition, and the transmittance center axis angle ⁇ is 0° or more and 45° or less.
• the contrast is high, and when it is used in a viewing angle control system, it is possible to suppress the change in hue with respect to the original image with respect to the image reflected in the surroundings.
• the transmittance center axis angle ⁇ is adjusted by orienting the liquid crystalline compound and the dichroic substance using an alignment agent. It is believed that the light absorption anisotropic layer of the present invention has a high content of the dichroic substance, so that sufficient absorption is exhibited and the contrast is increased.
• the light absorption anisotropic layer of the present invention uses a liquid crystalline compound exhibiting a smectic phase liquid crystal state, thereby increasing the contrast and suppressing the change in hue of the image reflected in the surroundings with respect to the original image. It is thought that
• the transmittance central axis angle ⁇ is preferably 0° or more and less than 45°, more preferably 0° or more and 35° or less, and even more preferably 0° or more and less than 35°. .
• the light absorption anisotropic layer of the present invention is formed from a liquid crystal composition containing a liquid crystal compound, a dichroic substance and an alignment agent.
• a liquid crystalline compound exhibiting a smectic phase liquid crystal state is used as the liquid crystalline compound. It is preferably a light absorption anisotropic layer.
• the liquid crystal composition may contain a solvent, a polymerization initiator, a polymerizable compound, an interface improver, and other additives. Each component will be described below.
• the liquid crystal composition contains a liquid crystalline compound.
• a liquid crystalline compound exhibiting a smectic phase liquid crystal state (hereinafter also abbreviated as “smectic liquid crystalline compound”) is used as the liquid crystalline compound.
• the smectic phase includes, for example, a smectic A phase, a smectic C phase, and the like. phase, smectic I phase, smectic J phase, smectic K phase, smectic L phase, etc.).
• a nematic phase may be developed.
• the liquid crystalline compound is a smectic B-phase, E-phase, F-phase, G-phase, H-phase, I-phase, J-phase, K-phase or L-phase liquid crystal for the reason of higher contrast. It is preferably a liquid crystalline compound that exhibits a state.
• a compound represented by the following formula (A-1) is preferable.
• Formula (A-1) Q1-V1-SP1-X1-(Ma-La)na-X2-SP2-V2-Q2
• Q1 and Q2 each independently represent a polymerizable group.
• V1, V2, X1 and X2 each independently represent a single bond or a divalent linking group.
• SP1 and SP2 each independently represent a divalent spacer group.
• Ma represents an aromatic ring, an aliphatic ring or a hetero ring which may have a substituent. However, multiple Ma may be the same or different.
• La represents a single bond or a divalent linking group. However, multiple La's may be the same or different.
• na represents an integer of 2-10.
• the polymerizable group represented by Q1 and Q2 is preferably a radically polymerizable group (radical polymerizable group) or a cationically polymerizable group (cationically polymerizable group).
• a known radically polymerizable group can be used as the radically polymerizable group, and an acryloyloxy group or a methacryloyloxy group is preferable. It is known that an acryloyloxy group tends to have a high polymerization rate, and an acryloyloxy group is preferred from the viewpoint of improving productivity, but a methacryloyloxy group can also be used as the polymerizable group.
• a known cationic polymerizable group can be used, and examples thereof include an alicyclic ether group, a cyclic acetal group, a cyclic lactone group, a cyclic thioether group, a spiroorthoester group and a vinyloxy group.
• an alicyclic ether group or a vinyloxy group is preferable, and an epoxy group, an oxetanyl group or a vinyloxy group is more preferable.
• Examples of preferred polymerizable groups include polymerizable groups represented by the following formulas (P-1) to (P-30).
• R P is a hydrogen atom, a halogen atom, a linear, branched or cyclic alkylene group having 1 to 10 carbon atoms, a halogen having 1 to 20 carbon atoms alkyl group, alkoxy group having 1 to 20 carbon atoms, alkenyl group having 1 to 20 carbon atoms, alkynyl group having 1 to 20 carbon atoms, aryl group having 1 to 20 carbon atoms, heterocyclic group (also referred to as heterocyclic group) , cyano group, hydroxy group, nitro group, carboxy group, aryloxy group, silyloxy group, heterocyclic oxy group, acyloxy group, carbamoyloxy group, alkoxycarbonyloxy group, aryloxycarbonyloxy group, amino group (including anilino group) ), ammonio group, acylamino group, aminocarbonylamino group, alkoxycarbonylamino group, alkoxycarbonylamino group
• the radically polymerizable group includes a vinyl group represented by the above formula (P-1), a butadiene group represented by the above formula (P-2), and a ( A meth)acryl group, a (meth)acrylamide group represented by the above formula (P-5), a vinyl acetate group represented by the above formula (P-6), and a fumaric acid represented by the above formula (P-7) an ester group, a styryl group represented by the above formula (P-8), a vinylpyrrolidone group represented by the above formula (P-9), a maleic anhydride represented by the above formula (P-11), or the above A maleimide group represented by the formula (P-12) is preferable, and the cationically polymerizable group includes a vinyl ether group represented by the above formula (P-18), an epoxy group represented by the above formula (P-19), Alternatively, an oxetanyl group represented by the above formula (P-20) is preferred.
• the divalent spacer group represented by SP1 and SP2 is, for example, a linear, branched or cyclic alkylene group having 1 to 50 carbon atoms, or a heterocyclic ring having 1 to 20 carbon atoms. and the like.
• the hydrogen atoms of the above alkylene groups and heterocyclic groups are halogen atoms, cyano groups, -Z H , -OH, -OZ H , -COOH, -C(O)Z H , -C(O)OZ H , -OC(O)ZH, -OC (O) OZH , -NZHZH ', -NZHC (O) ZH ', -NZHC (O) OZH ', -C (O) NZHZH ', -OC(O) NZHZH ', -NZHC (O) NZH'OZH '', -SH , -SZH , -C (S) ZH , -C (O )SZ H , —SC(O)Z H , wherein Z H , Z H ′ and Z′′ are each independently an alkyl group having 1 to 10 carbon atoms, an alky
• MA represents an optionally substituted aromatic ring, aliphatic ring or heterocyclic ring, preferably a 4- to 15-membered ring.
• MA may be monocyclic or condensed, and multiple MAs may be the same or different.
• Aromatic rings represented by MA include phenylene group, naphthylene group, fluorene-diyl group, anthracene-diyl group and tetracene-diyl group. A phenylene group and a naphthylene group are preferred.
• Aliphatic rings represented by MA include a cyclopentylene group and a cyclohexylene group, and the carbon atoms are -O-, -Si(CH 3 ) 2 -, -N(Z)-, -C( O)—, (Z independently represents hydrogen, an alkyl group having 1 to 4 carbon atoms, a cycloalkyl group, an aryl group, a cyano group, or a halogen atom.), —S—, —C(S) —, —S(O)—, and —SO 2 —, optionally substituted by a group consisting of two or more of these groups.
• Atoms other than carbon constituting the heterocyclic ring represented by MA include a nitrogen atom, a sulfur atom and an oxygen atom.
• the heterocycle has more than one non-carbon ring-constituting atom, these may be the same or different.
• heterocycles include pyridylene group (pyridine-diyl group), pyridazine-diyl group, imidazole-diyl group, thienylene (thiophene-diyl group), quinolylene group (quinoline-diyl group), isoquinolylene group (isoquinoline -diyl group), oxazole-diyl group, thiazole-diyl group, oxadiazole-diyl group, benzothiazole-diyl group, benzothiadiazole-diyl group, phthalimido-diyl group, thienothiazole-diyl group, thiazolothiazole-diyl group groups, thienothiophene-diyl groups, and thienooxazole-diyl groups, structures (II-1) to (II-4) below, and the like.
• D 1 represents -S-, -O-, or NR 11 -
• R 11 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms.
• Y 1 represents an aromatic hydrocarbon group having 6 to 12 carbon atoms or an aromatic heterocyclic group having 3 to 12 carbon atoms.
• Z 1 , Z 2 and Z 3 are each independently a hydrogen atom, an aliphatic hydrocarbon group having 1 to 20 carbon atoms, an alicyclic hydrocarbon group having 3 to 20 carbon atoms, or a monovalent C 6 to 20 represents an aromatic hydrocarbon group, a halogen atom, a cyano group, a nitro group, —NR 12 R 13 , or SR 12 .
• Z 1 and Z 2 may combine with each other to form an aromatic ring or an aromatic heterocyclic ring
• R 12 and R 13 each independently represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms. show.
• a 1 and A 2 each independently represents a group selected from the group consisting of -O-, -NR 21 - (R 21 represents a hydrogen atom or a substituent), -S- and -CO-.
• E represents a hydrogen atom or a nonmetallic atom of Groups 14-16 to which a substituent may be attached.
• Ax represents an organic group having 2 to 30 carbon atoms and having at least one aromatic ring selected from the group consisting of an aromatic hydrocarbon ring and an aromatic heterocyclic ring;
• Ay is a hydrogen atom, an optionally substituted alkyl group having 1 to 6 carbon atoms, or at least one aromatic ring selected from the group consisting of an aromatic hydrocarbon ring and an aromatic heterocyclic ring; represents an organic group having 2 to 30 carbon atoms, the aromatic ring of Ax and Ay may have a substituent, and Ax and Ay may combine to form a ring.
• D2 represents a hydrogen atom or an optionally substituted alkyl group having 1 to 6 carbon atoms.
• Y 1 when Y 1 is an aromatic hydrocarbon group having 6 to 12 carbon atoms, it may be monocyclic or polycyclic. When Y 1 is an aromatic heterocyclic group having 3 to 12 carbon atoms, it may be monocyclic or polycyclic.
• a 1 and A 2 represent —NR 21 —, the substituents of R 21 can be referred to, for example, paragraphs 0035 to 0045 of JP-A-2008-107767. , the contents of which are incorporated herein.
• R' represents a substituent, and as the substituent, for example, descriptions in paragraphs [0035] to [0045] of JP-A-2008-107767 can be referred to, and a nitrogen atom is preferable.
• examples of substituents that the aromatic ring, aliphatic ring or hetero ring may have include a halogen atom, an alkyl group having 1 to 20 carbon atoms, an alkyl group having 1 to 20 carbon atoms, 20 halogenated alkyl group, cycloalkyl group having 1 to 20 carbon atoms, alkoxy group having 1 to 20 carbon atoms, alkenyl group having 1 to 20 carbon atoms, alkynyl group having 1 to 20 carbon atoms, alkynyl group having 1 to 20 carbon atoms, Aryl group, heterocyclic group (also referred to as heterocyclic group), cyano group, hydroxy group, nitro group, carboxy group, aryloxy group, silyloxy group, heterocyclicoxy group, acyloxy group, carbamoyloxy group, alkoxycarbonyloxy group , aryloxycarbonyloxy group, amino group (including anilino group), ammonio group,
• na represents an integer of 2-10, more preferably an integer of 2-8.
• Examples of smectic liquid crystalline compounds include paragraphs [0033] to [0039] of JP-A-2008-19240, paragraphs [0037]-[0041] of JP-A-2008-214269, and JP-A-2006-215437. and the compounds described in paragraphs [0033] to [0040] and structures shown below, but are not limited thereto.
• the content of the smectic liquid crystalline compound is preferably 50 to 99% by mass, more preferably 60 to 95% by mass, based on the total solid mass of the liquid crystal composition.
• the liquid crystal composition further contains a dichroic substance.
• a dichroic substance means a dye that absorbs differently depending on the direction.
• the dichroic substance may or may not exhibit liquid crystallinity.
• the dichroic substance is not particularly limited, and includes visible light absorbing substances (dichroic dyes), luminescent substances (fluorescent substances, phosphorescent substances), ultraviolet absorbing substances, infrared absorbing substances, nonlinear optical substances, carbon nanotubes, and inorganic Substances (for example, quantum rods) and the like can be mentioned, and conventionally known dichroic substances (dichroic dyes) can be used.
• Techniques for orienting a dichroic substance in a desired direction can refer to techniques for producing polarizers using dichroic substances, techniques for producing guest-host liquid crystal cells, and the like.
• the technique used in the manufacturing method of the device can also be used for manufacturing the light absorption anisotropic layer of the present invention.
• a guest dichroic substance and a rod-like liquid crystalline compound as a host liquid crystal are mixed, the host liquid crystal is oriented, and the liquid crystal molecules of the liquid crystal are mixed.
• the light absorption anisotropic layer of the present invention can be produced by orienting the molecules of the dichroic portion substance along the orientation and fixing the orientation state.
• the orientation of the dichroic substance can be fixed by proceeding with the polymerization of the host liquid crystal, dichroic substance, and optional polymerizable component.
• two or more dichroic substances may be used in combination, preferably three or more dichroic substances.
• the contrast becomes higher, and when used in a viewing angle control system, the hue change with respect to the original image is further suppressed with respect to the image reflected in the surroundings.
• At least one dichroic substance having a maximum absorption wavelength in the wavelength range of 370 to 550 nm and at least one dichroic substance having a maximum absorption wavelength in the wavelength range of 500 to 700 nm It is preferable to use together.
• at least one dichroic substance having a maximum absorption wavelength in the range of 560 to 700 nm for example, the formula (1) described after paragraph [0043] of International Publication No.
• Examples of at least one dichroic substance having a maximum absorption wavelength in the wavelength range of 455 nm or more and less than 560 nm include the compounds represented by, for example, International Publication No. 2019/189345, paragraph [0054] and subsequent descriptions Compounds represented by formula (2) are included.
• the content of the dichroic substance is 5.0% by mass or more with respect to the total solid mass of the liquid crystal composition.
• it is preferably 8.0% by mass or more, more preferably 10.0% by mass or more, based on the total solid mass of the liquid crystal composition.
• it is more preferably 10 to 50% by mass.
• the total amount of the plurality of dichroic substances is preferably within the above range.
• the content of the dichroic substance is preferably 2 to 100 parts by mass, more preferably 4 to 50 parts by mass, with respect to 1 part by mass of the alignment agent described later, for the reason that the contrast is higher. preferable.
• the liquid crystal composition further contains an alignment agent.
• an alignment agent for example, [ 0153] to [0170] paragraphs, etc., and these may be used singly or in combination of two or more.
• the aligning agent is preferably an onium compound represented by the following formula (B1) because the contrast is higher.
• ring A represents a quaternary ammonium ion consisting of a nitrogen-containing heterocyclic ring.
• X represents an anion.
• L 1 represents a divalent linking group.
• L2 represents a single bond or a divalent linking group.
• Y 1 represents a divalent linking group having a 5- or 6-membered ring as a partial structure.
• Z represents a divalent linking group having an alkylene group having 2 to 20 carbon atoms as a partial structure.
• P 1 and P 2 each independently represent a monovalent substituent having a polymerizable ethylenically unsaturated bond.
• Ring A represents a quaternary ammonium ion consisting of a nitrogen-containing heterocycle.
• ring A include pyridine ring, picoline ring, 2,2′-bipyridyl ring, 4,4′-bipyridyl ring, 1,10-phenanthroline ring, quinoline ring, oxazole ring, thiazole ring, imidazole ring and pyrazine ring. , a triazole ring, a tetrazole ring, and the like, preferably a quaternary imidazolium ion and a quaternary pyridinium ion.
• X represents an anion.
• X include halogen anions (e.g., fluorine ion, chloride ion, bromide ion, iodine ion, etc.), sulfonate ions (e.g., methanesulfonate ion, trifluoromethanesulfonate ion, methylsulfate ion, vinylsulfonate ion, , allylsulfonate ion, p-toluenesulfonate ion, p-chlorobenzenesulfonate ion, p-vinylbenzenesulfonate ion, 1,3-benzenedisulfonate ion, 1,5-naphthalenedisulfonate ion, 2,6- naphthalenedisulfonate ion, etc.), sulfate ion, carbonate ion, nitrate ion
• Halogen anions, sulfonate ions and hydroxide ions are preferred. Chloride ion, bromide ion, iodide ion, methanesulfonate ion, vinylsulfonate ion, p-toluenesulfonate ion and p-vinylbenzenesulfonate ion are particularly preferred.
• L 1 represents a divalent linking group.
• L 1 include an alkylene group, —O—, —S—, —CO—, —SO 2 —, and —NRa—, where Ra is an alkyl group having 1 to 5 carbon atoms or a hydrogen atom. ), an alkenylene group, an alkynylene group, or a divalent linking group having 1 to 20 carbon atoms in combination with an arylene group.
• L 1 is preferably -AL-, -O-AL-, -CO-O-AL-, -O-CO-AL- having 1 to 10 carbon atoms, and -AL having 1 to 10 carbon atoms -, -O-AL- are more preferred, and -AL- and -O-AL- having 1 to 5 carbon atoms are most preferred.
• AL represents an alkylene group.
• L2 represents a single bond or a divalent linking group.
• L 2 include an alkylene group, —O—, —S—, —CO—, —SO 2 —, and —NRa—, where Ra is an alkyl group having 1 to 5 carbon atoms or a hydrogen atom.
• AL represents an alkylene group.
• L2 is preferably a single bond, -AL-, -O-AL-, -NRa-AL-O- having 1 to 10 carbon atoms, and a single bond, -AL-, - having 1 to 5 carbon atoms.
• O-AL- and -NRa-AL-O- are more preferable, and -O-AL- and -NRa-AL-O- having a single bond and 1 to 5 carbon atoms are most preferable.
• Y 1 represents a divalent linking group having a 5- or 6-membered ring as a partial structure.
• Examples of Y 1 include a cyclohexyl ring, an aromatic ring or a heterocyclic ring.
• aromatic rings include benzene ring, indene ring, naphthalene ring, fluorene ring, phenanthrene ring, anthracene ring, biphenyl ring and pyrene ring, with benzene ring, biphenyl ring and naphthalene ring being particularly preferred.
• the heteroatom constituting the heterocyclic ring is preferably a nitrogen atom, an oxygen atom and a sulfur atom.
• the heterocycle is a 6-membered ring.
• the divalent linking group represented by Y 1 and having a 5- or 6-membered ring as a partial structure may further have a substituent (for example, the substituent W described above).
• the divalent linking group represented by Y 1 is preferably a divalent linking group having two or more 5- or 6-membered rings, and preferably has a structure in which two or more rings are linked by a linking group. More preferred.
• Z has an alkylene group having 2 to 20 carbon atoms as a partial structure, and represents a divalent linking group consisting of a combination of -O-, -S-, -CO-, and -SO2-, and the alkylene group is It may have a substituent.
• the divalent linking group include an alkyleneoxy group and a polyalkyleneoxy group.
• the number of carbon atoms in the alkylene group represented by Z is preferably 2 to 16, still more preferably 2 to 12, and particularly preferably 2 to 8.
• P1 and P2 each independently represent a monovalent substituent having a polymerizable ethylenically unsaturated group.
• Examples of the monovalent substituent having a polymerizable ethylenically unsaturated group include the following formulas (M-1) to (M-8). That is, the monovalent substituent having a polymerizable ethylenically unsaturated group may be a substituent consisting only of an ethenyl group, such as (M-8).
• R represents a hydrogen atom or an alkyl group, preferably a hydrogen atom or a methyl group.
• R represents a hydrogen atom or an alkyl group, preferably a hydrogen atom or a methyl group.
• (M-1) to (M-8), (M-1), (M-2) and (M-8) are preferred, and (M-1) or (M-8) are more preferred.
• (M-1) is particularly preferable as P1.
• P2 is preferably (M-1) or (M-8), and in compounds in which ring A is a quaternary imidazolium ion, P2 is (M-8) or (M-1).
• P2 is (M ⁇ 1).
• Examples of the onium compound represented by the above formula (B1) include onium salts described in paragraphs 0052 to 0058 of JP-A-2012-208397, and onium described in paragraphs 0024 to 0055 of JP-A-2008-026730. salts, and onium salts described in JP-A-2002-37777.
• the aligning agent is preferably a boronic acid compound represented by the following formula (B2) because the contrast is higher.
• R 1 and R 2 are each independently a hydrogen atom, an optionally substituted aliphatic hydrocarbon group, an optionally substituted aryl group, or a substituted represents a heterocyclic group which may have a group.
• R 3 represents a substituent.
• Aliphatic hydrocarbon groups represented by one aspect of R 1 and R 2 include substituted or unsubstituted straight-chain or branched alkyl groups having 1 to 20 carbon atoms (e.g., methyl group, ethyl group, iso-propyl group, etc.) ), substituted or unsubstituted cyclic alkyl groups having 3 to 20 carbon atoms (eg, cyclohexyl group), and alkenyl groups having 2 to 20 carbon atoms (eg, vinyl group).
• substituted or unsubstituted straight-chain or branched alkyl groups having 1 to 20 carbon atoms e.g., methyl group, ethyl group, iso-propyl group, etc.
• substituted or unsubstituted cyclic alkyl groups having 3 to 20 carbon atoms eg, cyclohexyl group
• alkenyl groups having 2 to 20 carbon atoms eg, vinyl group
• the aryl group represented by one aspect of R 1 and R 2 includes a substituted or unsubstituted phenyl group having 6 to 20 carbon atoms (eg, phenyl group, tolyl group, etc.), a substituted or unsubstituted phenyl group having 10 to 20 carbon atoms, A substituted naphthyl group and the like can be mentioned.
• the heterocyclic group represented by one embodiment of R 1 and R 2 includes, for example, a substituted or unsubstituted 5- or 6-membered Examples include a membered ring group, and specific examples include a pyridyl group, an imidazolyl group, a furyl group, a piperidyl group, a morpholino group and the like.
• R 1 and R 2 may be linked together to form a ring, for example, the isopropyl groups of R 1 and R 2 are linked to give 4,4,5,5-tetramethyl-1,3,2 - may form a dioxaborolane ring.
• R 1 and R 2 are preferably a hydrogen atom, a linear or branched alkyl group having 1 to 3 carbon atoms, or a ring formed by linking them, more preferably a hydrogen atom.
• the substituent represented by R 3 is preferably a substituent containing a functional group capable of bonding with a (meth)acryl group.
• functional groups capable of bonding with (meth)acrylic groups include vinyl groups, acrylate groups, methacrylate groups, acrylamide groups, styryl groups, vinyl ketone groups, butadiene groups, vinyl ether groups, oxiranyl groups, aziridinyl groups, and oxetane groups.
• a vinyl group, an acrylate group, a methacrylate group, a styryl group, an oxiranyl group or an oxetane group is preferred, and a vinyl group, an acrylate group, an acrylamide group or a styryl group is more preferred.
• R 3 is preferably a substituted or unsubstituted aliphatic hydrocarbon group, aryl group or heterocyclic group having a functional group capable of bonding with a (meth)acryl group.
• the aliphatic hydrocarbon group includes a substituted or unsubstituted straight-chain or branched alkyl group having 1 to 30 carbon atoms (e.g., methyl group, ethyl group, iso-propyl group, n-propyl group, butyl group, pentyl group , hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, tridecyl group, hexadecyl group, octadecyl group, eicosyl group, isopropyl group, isobutyl group, sec-butyl group, tert-butyl group, isopentyl
• the aryl group includes a substituted or unsubstituted phenyl group having 6 to 50 carbon atoms (e.g., phenyl group, tolyl group, styryl group, 4-benzoyloxyphenyl group, 4-phenoxycarbonylphenyl group, 4-biphenyl group, 4 -(4-octyloxybenzoyloxy)phenoxycarbonylphenyl group, etc.), substituted or unsubstituted naphthyl group having 10 to 50 carbon atoms, etc. (eg, unsubstituted naphthyl group, etc.).
• phenyl group e.g., phenyl group, tolyl group, styryl group, 4-benzoyloxyphenyl group, 4-phenoxycarbonylphenyl group, 4-biphenyl group, 4 -(4-octyloxybenzoyloxy)phenoxycarbonylphenyl group, etc.
• the heterocyclic group is, for example, a substituted or unsubstituted 5- or 6-membered ring group containing at least one heteroatom (e.g., nitrogen atom, oxygen atom, sulfur atom, etc.), such as pyrrole, furan, Thiophene, pyrazole, imidazole, triazole, oxazole, isoxazole, oxadiazole, thiazole, thiadiazole, indole, carbazole, benzofuran, dibenzofuran, thianaphthene, dibenzothiophene, indazole benzimidazole, anthranil, benzisoxazole, benzoxazole, benzothiazole, Groups such as purine, pyridine, pyridazine, pyrimidine, pyrazine, triazine, quinoline, acridine, isoquinoline, phthalazine, quinazoline, quinoxa
• Examples of the boronic acid compound represented by formula (B2) include boronic acid compounds represented by general formula (I) described in paragraphs 0023 to 0032 of JP-A-2008-225281. As the compound represented by the above formula (B2), compounds exemplified below are also preferable.
• Examples of the alignment agent include at least one compound selected from the group consisting of nonionic silane compounds and ionic compounds, in addition to the compound represented by formula (B1) or (B2).
• the ionic compound does not include the compound represented by the formula (B1).
• nonionic silane compounds include those described in paragraphs [0035] to [0039] of JP-A-2020-181150.
• ionic compounds include those described in paragraphs [0017] to [0029] of JP-A-2020-181150.
• the content of the aligning agent is preferably 0.1 to 10 parts by mass, more preferably 0.2 to 8 parts by mass, with respect to the total of 100 parts by mass of the liquid crystal compound and the dichroic substance contained in the liquid crystal composition. Parts by mass are more preferred.
• the liquid crystal composition preferably contains a solvent.
• solvents include ketones (eg, acetone, 2-butanone, methyl isobutyl ketone, cyclopentanone, cyclohexanone, acetylacetone, etc.), ethers (eg, dioxane, tetrahydrofuran, tetrahydropyran, dioxolane, tetrahydrofurfuryl alcohol, cyclopentyl methyl ether, dibutyl ether, etc.), aliphatic hydrocarbons (e.g., hexane, etc.), alicyclic hydrocarbons (e.g., cyclohexane, etc.), aromatic hydrocarbons (e.g., benzene, toluene, xylene, tetralin, trimethylbenzene, etc.), halogenated carbons (e.g., dichloromethane,
• solvents e.g., methyl cellosolve, ethyl cellosolve, and 1,2-dimethoxyethane
• cellosolve acetates sulfoxides (e.g., dimethyl sulfoxide, etc.), amides (e.g., dimethylformamide , and dimethylacetamide, N-methylpyrrolidone, N-ethylpyrrolidone, 1,3-dimethyl-2-imidazolidinone, etc.), and organic compounds such as heterocyclic compounds (e.g., pyridine, 2,6-lutidine, etc.).
• Solvents as well as water may be mentioned. These solvents may be used singly or in combination of two or more.
• the content of the solvent is preferably 60 to 99.5% by mass, more preferably 70 to 99% by mass, relative to the total mass (100% by mass) of the liquid crystal composition. more preferably 75 to 98% by mass.
• the liquid crystal composition may contain a polymerization initiator.
• the polymerization initiator is not particularly limited, it is preferably a compound having photosensitivity, that is, a photopolymerization initiator.
• Various compounds can be used as the photopolymerization initiator without any particular limitation. Examples of photoinitiators include ⁇ -carbonyl compounds (US Pat. Nos. 2,367,661 and 2,367,670), acyloin ethers (US Pat. No. 2,448,828), ⁇ -hydrocarbon-substituted aromatic acyloins, compounds (US Pat. No. 2,722,512), polynuclear quinone compounds (US Pat. Nos.
• photopolymerization initiators and BASF Irgacure-184, Irgacure-907, Irgacure-369, Irgacure-651, Irgacure-819, Irgacure-OXE-01 and Irgacure- OXE-02 and the like.
• the content of the polymerization initiator is preferably 0.01 to 30% by mass, more preferably 0.1 to 15% by mass, based on the total solid mass of the liquid crystal composition. more preferred.
• the liquid crystal composition may contain a polymerizable compound.
• Polymerizable compounds include compounds containing acrylates (eg, (meth)acrylate monomers, etc.).
• the content of the polymerizable compound is preferably 0.5 to 50% by mass, and 1.0 to 40% by mass, based on the total solid mass of the liquid crystal composition. more preferred.
• the liquid crystal composition may contain an interface modifier.
• the interface improver is not particularly limited, and a polymer interface improver and a low molecular weight interface improver can be used, and the compounds described in paragraphs [0253] to [0293] of JP-A-2011-237513 can be used. can be done.
• As the interface improver fluorine (meth)acrylate polymers described in [0018] to [0043] of JP-A-2007-272185 can also be used.
• the content of the interface modifier is preferably 0.005 to 15% by mass, more preferably 0.01 to 5% by mass, based on the total solid mass of the liquid crystal composition. Preferably, 0.015 to 3% by mass is more preferable.
• the total amount of the plurality of surface improvers is preferably within the above range.
• the method for forming the anisotropic light absorption layer of the present invention is not particularly limited, and the liquid crystal composition described above (hereinafter also referred to as “composition for forming an anisotropic light absorption layer”) is applied to form a coating film. (hereinafter also referred to as “coating film forming step”) and the process of orienting the liquid crystalline component and dichroic substance contained in the coating film (hereinafter also referred to as “alignment step”) in this order. and a method comprising:
• the liquid crystalline component is a component containing not only the liquid crystalline compound described above but also a dichroic substance having liquid crystallinity when the dichroic substance described above has liquid crystallinity.
• the coating film forming step is a step of applying a composition for forming a light absorption anisotropic layer to form a coating film.
• a composition for forming a light absorption anisotropic layer containing the above-mentioned solvent, or by using a liquid such as a melt by heating the composition for forming a light absorption anisotropic layer, It becomes easy to apply the composition for forming a light-absorbing anisotropic layer.
• Specific examples of the coating method of the composition for forming a light-absorbing anisotropic layer include roll coating, gravure printing, spin coating, wire bar coating, extrusion coating, direct gravure coating, and reverse coating. Known methods such as a gravure coating method, a die coating method, a spray method, and an inkjet method can be used.
• the alignment step is a step of orienting the liquid crystalline component contained in the coating film. Thereby, a light absorption anisotropic layer is obtained.
• the orientation step may include drying. Components such as the solvent can be removed from the coating film by the drying treatment.
• the drying treatment may be performed by a method of leaving the coating film at room temperature for a predetermined time (for example, natural drying), or by a method of heating and/or blowing air.
• the liquid crystalline component contained in the composition for forming a light-absorbing anisotropic layer may be oriented by the above coating film forming step or drying treatment.
• the coating film is dried to remove the solvent from the coating film, thereby obtaining the anisotropic light absorption.
• a coating film (that is, a light absorption anisotropic layer) is obtained.
• the transition temperature of the liquid crystalline component contained in the coating film to the liquid crystal phase is preferably 10 to 250°C, more preferably 25 to 190°C, from the standpoint of production suitability.
• the transition temperature is 10° C. or higher, cooling treatment or the like for lowering the temperature to the temperature range where the liquid crystal phase is exhibited is not required, which is preferable.
• the transition temperature is 250° C. or less, a high temperature is not required even when the isotropic liquid state is converted to an isotropic liquid state at a temperature higher than the temperature range in which the liquid crystal phase is once exhibited, which wastes thermal energy and reduces substrate damage. This is preferable because it can reduce deformation, deterioration, and the like.
• the orientation step preferably includes heat treatment.
• the liquid crystalline component contained in the coating film can be oriented, so that the coating film after the heat treatment can be suitably used as the light absorption anisotropic layer.
• the heat treatment is preferably from 10 to 250° C., more preferably from 25 to 190° C., from the standpoint of suitability for production.
• the heating time is preferably 1 to 300 seconds, more preferably 1 to 60 seconds.
• the orientation step may have a cooling treatment performed after the heat treatment.
• the cooling process is a process of cooling the coated film after heating to about room temperature (20 to 25° C.). Thereby, the orientation of the liquid crystalline component contained in the coating film can be fixed.
• the cooling means is not particularly limited, and a known method can be used.
• a light absorption anisotropic layer can be obtained by the above steps. In this embodiment, drying treatment, heat treatment, and the like are mentioned as methods for orienting the liquid crystalline component contained in the coating film.
• the method for forming the anisotropic light absorption layer may include a step of curing the anisotropic light absorption layer (hereinafter also referred to as a “curing step”) after the alignment step.
• the curing step is carried out by heating and/or light irradiation (exposure), for example, when the light absorption anisotropic layer has a crosslinkable group (polymerizable group).
• the curing step is preferably carried out by light irradiation.
• Various light sources such as infrared light, visible light, and ultraviolet light can be used as the light source for curing, but ultraviolet light is preferred.
• ultraviolet rays may be irradiated while being heated during curing, or ultraviolet rays may be irradiated through a filter that transmits only specific wavelengths.
• the heating temperature during exposure is preferably 25 to 140° C., depending on the transition temperature of the liquid crystalline component contained in the liquid crystal film to the liquid crystal phase.
• the exposure may be performed in a nitrogen atmosphere.
• radical polymerization it is preferable to perform exposure in a nitrogen atmosphere because inhibition of polymerization by oxygen is reduced.
• the thickness of the light absorption anisotropic layer of the present invention is preferably 1.5 ⁇ m or more, and preferably 4.0 ⁇ m or less, for the reason of suppressing hue change with respect to the original image with respect to the image reflected in the surroundings. preferable.
• the light absorption anisotropic layer of the present invention can be a light absorption anisotropic layer having a region A and a region B in the plane and having different central axes of transmittance in each region. If the light-emitting pixel is controlled by patterning the liquid crystal for each pixel, it becomes possible to switch the center of the narrow field of view.
• the light absorption anisotropic layer of the present invention has a region C and a region D in the plane, and the region C and the region D include the transmittance center axis and the normal line of the light absorption anisotropic layer surface.
• It can be an anisotropic light absorption layer having different transmittances in a plane inclined by 30° from the transmittance central axis in the normal direction.
• the transmittance of the region C tilted 30° in the normal direction from the transmittance central axis is 50% or less
• the transmittance of the region D tilted 30° in the normal direction from the transmittance central axis is 80% or more.
• the viewing angle dependency for each display position as a display device, it is possible to design the display device with excellent design. Furthermore, by controlling the light-emitting pixels by patterning the liquid crystal for each pixel, it is possible to switch between a narrow viewing angle and a wide viewing angle.
• the method for forming the patterned light absorption anisotropic layer having two or more different regions in the plane is not limited, and various known methods such as those described in WO2019/176918 can be used. Available.
• a method of forming a pattern by changing the irradiation angle of ultraviolet light with which the photo-alignment film is irradiated a method of controlling the thickness of the patterned light absorption anisotropic layer in the plane, a method of controlling the thickness of the patterned light absorption anisotropic layer, Examples thereof include a method of unevenly distributing a dichroic dye compound and a method of post-processing an optically uniform patterned light absorption anisotropic layer.
• Methods for controlling the thickness of the patterned anisotropic light absorption layer in-plane include a method using lithography, a method using imprinting, and a method of forming a patterned light absorption anisotropic layer on a base material having an uneven structure. and the like.
• a method for unevenly distributing the dichroic dye compound in the patterned light absorption anisotropic layer there is a method of extracting the dichroic dye by immersion in a solvent (bleaching).
• a method of post-processing the optically uniform patterned light absorption anisotropic layer there is a method of cutting a part of the flat light absorption anisotropic layer by laser processing or the like.
• optical film has a transparent film substrate and the light absorption anisotropic layer of the present invention provided on the transparent film substrate. Each member constituting the optical film of the present invention will be described below.
• transparent film substrate a known transparent resin film, transparent resin plate, transparent resin sheet, or the like can be used, and there is no particular limitation.
• transparent resin films include cellulose acylate films (e.g., cellulose triacetate film (refractive index: 1.48), cellulose diacetate film, cellulose acetate butyrate film, cellulose acetate propionate film), polyethylene terephthalate film, and polyethersulfone.
• Films, polyacrylic resin films, polyurethane resin films, polyester films, polycarbonate films, polysulfone films, polyether films, polymethylpentene films, polyetherketone films, (meth)acrylonitrile films, and the like can be used.
• cellulose acylate film which is highly transparent, has little optical birefringence, is easy to manufacture, and is generally used as a protective film for polarizing plates, is preferable, and cellulose triacetate (also called triacetyl cellulose (TAC)) is preferable. .) films are particularly preferred.
• the thickness of the transparent film substrate is usually 20 ⁇ m to 100 ⁇ m. In the present invention, it is particularly preferred that the transparent film substrate is a cellulose ester film and has a thickness of 20 to 70 ⁇ m.
• the anisotropic light absorption layer of the optical film of the present invention is the anisotropic light absorption layer of the present invention described above, the description thereof will be omitted.
• the optical film of the present invention preferably has an alignment film between the transparent film substrate and the light absorption anisotropic layer.
• an alignment film made of polyvinyl alcohol or polyimide is preferable.
• the thickness of the alignment film is preferably 0.01 to 10 ⁇ m, more preferably 0.01 to 1 ⁇ m.
• the optical film of the present invention preferably has a barrier layer together with the transparent film substrate and the light absorption anisotropic layer.
• the barrier layer is also called a gas blocking layer (oxygen blocking layer), and has a function of protecting the polarizing element of the present invention from gases such as oxygen in the atmosphere, moisture, or compounds contained in adjacent layers. have.
• the optical film of the present invention preferably has a refractive index adjusting layer from the viewpoint of suppressing the influence of internal reflection caused by the high refractive index of the light absorption anisotropic layer.
• the refractive index adjustment layer is a layer arranged so as to be in contact with the light absorption anisotropic layer, and has an in-plane average refractive index of 1.55 or more and 1.70 or less at a wavelength of 550 nm. It is preferably a refractive index adjustment layer for performing so-called index matching.
• the viewing angle control system of the present invention has a polarizer having an absorption axis in the in-plane direction, and the light absorption anisotropic layer of the present invention or the optical film of the present invention described above.
• the polarizer of the viewing angle control system of the present invention is not particularly limited as long as it has an in-plane absorption axis and a function of converting light into specific linearly polarized light, and conventionally known polarizers are used. can do.
• As the polarizer an iodine-based polarizer, a dye-based polarizer using a dichroic dye, a polyene-based polarizer, or the like is used.
• Iodine-based polarizers and dye-based polarizers include coating-type polarizers and stretching-type polarizers, both of which can be applied.
• a polarizer in which a dichroic organic dye is oriented by utilizing the orientation of a liquid crystalline compound is preferable.
• Polarizers made by stretching are preferred.
• a method of obtaining a polarizer by stretching and dyeing a laminated film in which a polyvinyl alcohol layer is formed on a substrate there are disclosed in Japanese Patent Nos. 5048120, 5143918, 5048120, and No. 4,691,205, Japanese Patent No. 4,751,481, and Japanese Patent No. 4,751,486 can be mentioned, and known techniques relating to these polarizers can also be preferably used.
• polyvinyl alcohol-based resins (polymers containing —CH 2 —CHOH— as repeating units, particularly polyvinyl alcohol and ethylene-vinyl alcohol copolymers are selected from the group consisting of polyvinyl alcohol-based resins, which are readily available and excellent in the degree of polarization. It is preferable that the polarizer includes at least one
• the thickness of the polarizer is not particularly limited in the present invention, it is preferably 3 ⁇ m to 60 ⁇ m, more preferably 5 ⁇ m to 20 ⁇ m, even more preferably 5 ⁇ m to 10 ⁇ m.
• the angle ⁇ formed by the direction ⁇ 1 obtained by orthogonally projecting the transmittance center of the light absorption anisotropic layer onto the film surface and the absorption axis ⁇ 2 of the polarizer is 45° to 90°. is preferred, 80° to 90° is more preferred, and 88° to 90° is even more preferred. The closer the angle is to 90°, the more illuminance contrast can be provided between the direction in which the image display device is easy to see and the direction in which it is difficult to see.
• the light absorption anisotropic layer and the polarizer may be laminated via an adhesive layer or an adhesive layer described later, or the alignment film and the polarizer may be laminated on the polarizer.
• the light absorption anisotropic layer may be directly coated and laminated.
• the adhesive layer is preferably a transparent and optically isotropic adhesive similar to that used in ordinary image display devices, and a pressure sensitive adhesive is usually used.
• a cross-linking agent e.g., isocyanate-based cross-linking agent, epoxy-based cross-linking agent, etc.
• tackifier Agents e.g., rosin derivative resins, polyterpene resins, petroleum resins, oil-soluble phenolic resins, etc.
• plasticizers fillers, antioxidants, surfactants, ultraviolet absorbers, light stabilizers, antioxidants, etc. Additives may be added.
• the thickness of the adhesive layer is usually 20-500 ⁇ m, preferably 20-250 ⁇ m. If the thickness is less than 20 ⁇ m, the necessary adhesive strength and reworkability may not be obtained, and if the thickness exceeds 500 ⁇ m, the adhesive may protrude or ooze out from the peripheral edges of the image display device.
• a base material, conductive particles, and, if necessary, a coating liquid containing thermally expandable particles, additives, solvents, etc. is directly applied onto the protective member support 110 and peeled off.
• a method of pressure bonding through a liner in which a coating liquid is applied to a suitable release liner (release paper, etc.) to form a thermally expandable adhesive layer, which is pressure-transferred (transferred) onto the protective member support 110. It can be carried out by an appropriate method such as a method of
• the protective member for example, a configuration in which conductive particles are added to the configuration of the heat-peelable pressure-sensitive adhesive sheet described in Japanese Patent Application Laid-Open No. 2003-292916 can be applied.
• a commercial product such as "Riva Alpha” manufactured by Nitto Denko Co., Ltd., in which conductive particles are dispersed on the surface of the adhesive layer, may be used.
• the adhesive develops adhesiveness through drying and reaction after bonding.
• Polyvinyl alcohol-based adhesive (PVA-based adhesive) develops adhesiveness when dried, making it possible to bond materials together.
• curable adhesives that exhibit adhesiveness through reaction include active energy ray curable adhesives such as (meth)acrylate adhesives and cationic polymerization curable adhesives.
• (Meth)acrylate means acrylate and/or methacrylate.
• the curable component in the (meth)acrylate adhesive includes, for example, a compound having a (meth)acryloyl group and a compound having a vinyl group. Compounds having an epoxy group or an oxetanyl group can also be used as cationic polymerization curing adhesives.
• the compound having an epoxy group is not particularly limited as long as it has at least two epoxy groups in the molecule, and various commonly known curable epoxy compounds can be used.
• Preferred epoxy compounds include compounds having at least two epoxy groups and at least one aromatic ring in the molecule (aromatic epoxy compounds), and compounds having at least two epoxy groups in the molecule, at least one of which Examples include compounds (alicyclic epoxy compounds) formed between two adjacent carbon atoms constituting an alicyclic ring.
• an ultraviolet curable adhesive that is cured by ultraviolet irradiation is preferably used.
• Each layer of the adhesive layer and adhesive layer is treated with an ultraviolet absorber such as a salicylate compound, a benzophenol compound, a benzotriazole compound, a cyanoacrylate compound, a nickel complex compound, etc. to improve the UV absorption ability. It may be something that is held.
• an ultraviolet absorber such as a salicylate compound, a benzophenol compound, a benzotriazole compound, a cyanoacrylate compound, a nickel complex compound, etc.
• the attachment of the adhesive layer and adhesive layer can be performed by an appropriate method.
• a base polymer or a composition thereof is dissolved or dispersed in a suitable solvent such as toluene or ethyl acetate alone or in a mixture to prepare a pressure-sensitive adhesive solution of about 10 to 40% by weight
• a suitable solvent such as toluene or ethyl acetate alone or in a mixture to prepare a pressure-sensitive adhesive solution of about 10 to 40% by weight
• Examples include a method in which it is directly attached on a film by an appropriate spreading method such as a casting method or a coating method, or a method in which an adhesive layer is formed on a separator according to the above and transferred.
• the adhesive layer and adhesive layer can also be provided on one side or both sides of the film as superimposed layers of different compositions or types.
• the front and back sides of the film may have adhesive layers with different compositions, types, thicknesses, and the like.
• the viewing angle control system of the present invention can use the above-described light absorption anisotropic layer in combination with an optically anisotropic film or a polarization rotator in order to control the angular dependence of the viewing angle.
• an optically anisotropic resin film made of a polymer containing carbonate, cycloolefin, cellulose acylate, methyl methacrylate, styrene, maleic anhydride, or the like, as the transparent substrate film.
• An image display device of the present invention is an image display device having a display element and the above-described viewing angle control system of the present invention, wherein the viewing angle control system is arranged on at least one main surface of the display element. Further, the image display device of the present invention is an image display device in which the light absorption anisotropic layer of the viewing angle control system is arranged on the viewing side relative to the polarizer of the viewing angle control system, that is, from the viewing side , a light absorption anisotropic layer, a polarizer and a display element in this order.
• the display element used in the image display device of the present invention is not particularly limited, and examples thereof include liquid crystal cells, organic electroluminescence (hereinafter abbreviated as "EL") display panels, and plasma display panels. Among these, a liquid crystal cell or an organic EL display panel is preferable. That is, the display device of the present invention is preferably a liquid crystal display device using a liquid crystal cell as a display element, or an organic EL display device using an organic EL display panel as a display element.
• Some image display devices are thin and can be formed into a curved surface. Since the optically anisotropic absorbing film used in the present invention is thin and easily bendable, it can be suitably applied to an image display device having a curved display surface.
• Some image display devices have a pixel density exceeding 250 ppi and are capable of high-definition display.
• the optically anisotropic absorbing film used in the present invention can be suitably applied to such a high-definition image display device without causing moire.
• a liquid crystal display device preferably includes an optical film having a polarizer and a liquid crystal cell.
• the optical film of the present invention is disposed on the front side polarizing plate or the rear side polarizing plate. In these configurations, it is possible to control the viewing angle so that light is shielded in the vertical direction or the horizontal direction.
• the optical film of the present invention may be arranged on both the front-side polarizing plate and the rear-side polarizing plate. With such a configuration, it is possible to control the viewing angle so that light is blocked in all directions and light is transmitted only in the front direction.
• a plurality of optical films of the present invention may be laminated via retardation layers.
• transmission performance and light shielding performance can be controlled.
• a polarizer, an optical film, a ⁇ /2 wavelength plate (the axis angle is an angle shifted by 45° with respect to the orientation direction of the polarizer), and an optical film light is blocked in all directions, and the front direction It is possible to control the viewing angle through which only light is transmitted.
• a positive A plate, a negative A plate, a positive C plate, a negative C plate, a B plate, an O plate, or the like can be used as the retardation layer.
• the thickness of the retardation layer is preferably thin as long as it does not impair the optical properties, mechanical properties, and manufacturability. 70 ⁇ m is more preferable, and 1 to 30 ⁇ m is even more preferable.
• the liquid crystal cell constituting the liquid crystal display device will be described in detail below.
• Liquid crystal cells used in liquid crystal display devices are preferably in VA (Vertical Alignment) mode, OCB (Optically Compensated Bend) mode, IPS (In-Plane-Switching) mode, or TN (Twisted Nematic) mode. It is not limited to these.
• VA Vertical Alignment
• OCB Optically Compensated Bend
• IPS In-Plane-Switching
• TN Transmission Nematic
• the rod-like liquid crystal molecules are substantially horizontally aligned when no voltage is applied, and are twisted at an angle of 60 to 120°.
• TN mode liquid crystal cells are most commonly used as color TFT liquid crystal display devices, and are described in many documents.
• VA mode liquid crystal cell rod-like liquid crystal molecules are aligned substantially vertically when no voltage is applied.
• VA mode liquid crystal cells include (1) a narrowly defined VA mode liquid crystal cell in which rod-like liquid crystalline molecules are aligned substantially vertically when no voltage is applied and substantially horizontally aligned when voltage is applied (Japanese Unexamined Patent Application Publication No. 2-2002). 176625), and (2) a liquid crystal cell in which the VA mode is multi-domained (MVA mode) for widening the viewing angle (SID97, Digest of tech. Papers (preliminary collection) 28 (1997) 845).
• a liquid crystal cell in a mode in which rod-like liquid crystalline molecules are substantially vertically aligned when no voltage is applied and twisted multi-domain alignment is performed when voltage is applied (Proceedings of the Japan Liquid Crystal Forum 58-59 (1998)) and (4) Survival mode liquid crystal cells (presented at LCD International 98).
• any of PVA (Patterned Vertical Alignment) type, optical alignment type, and PSA (Polymer-Sustained Alignment) type may be used. Details of these modes are described in detail in JP-A-2006-215326 and JP-A-2008-538819.
• the liquid crystal compound In the IPS mode liquid crystal cell, the liquid crystal compound is oriented substantially parallel to the substrate, and the liquid crystal molecules respond planarly by applying an electric field parallel to the substrate surface. That is, the liquid crystalline compound is oriented in the plane in the state where no electric field is applied.
• a black display is obtained when no electric field is applied, and the absorption axes of the pair of upper and lower polarizing plates are perpendicular to each other.
• a method of using an optical compensatory sheet to reduce leakage light during black display in an oblique direction and improve the viewing angle is disclosed in Japanese Patent Application Laid-Open Nos. 10-54982, 11-202323 and 9-292522. JP-A-11-133408, JP-A-11-305217 and JP-A-10-307291.
• An organic EL display device which is an example of the display device of the present invention, includes, for example, an optical film having the above-described polarizer, a ⁇ /4 plate, and an organic EL display panel in this order from the viewing side. are preferably mentioned. Also, in the same manner as in the liquid crystal display device described above, a plurality of optical films of the present invention may be laminated via retardation layers and arranged on an organic EL display panel. By controlling the retardation value and the optical axis direction, transmission performance and light shielding performance can be controlled.
• the organic EL display panel is a display panel configured using an organic EL element in which an organic light-emitting layer (organic electroluminescence layer) is sandwiched between electrodes (between a cathode and an anode).
• organic light-emitting layer organic electroluminescence layer
• the configuration of the organic EL display panel is not particularly limited, and a known configuration is adopted.
• Example 1 ⁇ Formation of Alignment Film 1>
• the surface of a cellulose acylate film 1 (TAC substrate having a thickness of 40 ⁇ m; TG40, manufactured by Fuji Film Co., Ltd.), which is a transparent film substrate, was saponified with an alkaline solution, and the following alignment film forming coating solution 1 was applied thereon with a wire bar. applied.
• the cellulose acylate film 1 on which the coating film was formed was dried with hot air at 60° C. for 60 seconds and further with hot air at 100° C. for 120 seconds to form an alignment film 1, thereby obtaining a TAC film with an alignment film.
• the thickness of the alignment film 1 was 0.5 ⁇ m. Further, the prepared TAC film with an alignment film was used after rubbing the alignment film surface.
• ⁇ Preparation of light absorption anisotropic layer> The following composition P1 for forming a light absorption anisotropic layer was applied on the alignment film of the TAC film with the alignment film thus produced by using a wire bar to form a coating layer P1. Next, the coating layer P1 was heated at 120°C for 30 seconds and cooled to 100°C. Then, an anisotropic light absorption layer P1 was formed on the alignment layer 1 by irradiating for 10 seconds under irradiation conditions of an illuminance of 200 mW/cm 2 using an LED lamp (center wavelength of 365 nm). The thickness of the light absorption anisotropic layer P1 was 3.0 ⁇ m.
• composition P1 for forming light absorption anisotropic layer ⁇ ⁇ 90 parts by mass of liquid crystalline compound L1 below ⁇ 10 parts by mass of liquid crystalline compound L2 below ⁇ 3 parts by mass of dichroic substance Y1 below ⁇ 2 parts by mass of dichroic substance O1 below ⁇ 4 parts by mass of dichroic substance C1 below ⁇ Polymerization Initiator I1 IRGACUREOXE-02 (manufactured by BASF) 3 parts by mass Interface improver F1 below 0.1 parts by mass Vertical alignment agent F2 below 1 part by mass Cyclopentanone (CPO) 500 parts by mass Tetrahydrofuran (THF) 500 parts by mass- ⁇
• the following barrier layer-forming coating solution was applied on the prepared light absorption anisotropic layer P1 with a wire bar to form a coating film, which was dried at 80° C. for 5 minutes. Then, the dried coating film is irradiated with an LED lamp (center wavelength 365 nm) in an environment with an oxygen concentration of 100 ppm and a temperature of 60 ° C. for 2 seconds at an illuminance of 150 mW / cm 2 .
• a barrier layer 1 was formed on the absorption anisotropic layer P1. The thickness of the barrier layer 1 was 1.0 ⁇ m.
• an optical film P1 having a transparent film substrate, an alignment film, an anisotropic light absorption layer and a barrier layer was obtained.
• a polarizing plate 1 having a polarizer thickness of 8 ⁇ m and one surface of which is exposed was prepared in the same manner as the polarizing plate 02 with a single-sided protective film described in WO 2015/166991.
• the exposed surface of the polarizer of the polarizing plate 1 and the surface of the optical film P1 prepared above are subjected to corona treatment, and the polarizer and the barrier layer 1 of the optical film P1 are bonded using the following PVA adhesive 1, A laminate A1 was produced.
• Adhesive Sheet 1 An acrylate-based polymer was prepared according to the following procedure. 95 parts by mass of butyl acrylate and 5 parts by mass of acrylic acid were polymerized by a solution polymerization method in a reaction vessel equipped with a cooling tube, a nitrogen inlet tube, a thermometer and a stirring device to obtain an average molecular weight of 2,000,000 and a molecular weight distribution (Mw/ An acrylate polymer A1 having Mn) of 3.0 was obtained.
• This composition was applied to a separate film surface-treated with a silicone release agent using a die coater and dried for 1 minute at 90° C. to obtain an acrylate pressure-sensitive adhesive sheet.
• the obtained acrylate pressure-sensitive adhesive sheet had a thickness of 25 ⁇ m and a storage elastic modulus of 0.1 MPa.
• the manufactured image display device B1 with anti-reflection system displayed a white image (R256, G256, B256) on the entire surface in order to evaluate the reflection image on the window glass.
• an acrylic plate was placed in front of the reflection image evaluation device, and the hue of the image reflected on the surface was evaluated for color (reddish, greenish, bluish) by sensory evaluation.
• the direction in which the reflected image is observed is an oblique direction at an angle of about 30° to a straight line extending from the center of the image display device toward the front of the acrylic plate, and is evaluated according to the following criteria. did.
• Table 1 The results are shown in Table 1 below.
• A The change in hue of the reflected image is small, and the reflected image is not disturbing.
• B The hue change of the reflected image is observed, but the reflected image is not disturbing, and is at an acceptable level.
• C A change in hue of the reflected image is observed, and the reflected image is somewhat disturbing.
• D A change in hue of the reflected image is clearly observed, and the reflected image is disturbing.
• Examples 2 to 8 and Comparative Examples 1 to 3 In the same manner as in Example 1, except that the composition P1 for forming a light-absorbing anisotropic layer was changed to the composition shown in Table 1 below, and the coating conditions (polymerization temperature) shown in Table 1 below were changed.
• the light absorption anisotropic layers, optical films, laminates, and image display devices with anti-reflection systems of Examples 2 to 8 and Comparative Examples 1 to 3 were produced and evaluated in the same manner as in Example 1.
• the transmittance central axis angle ⁇ of each of the light absorption anisotropic layers produced in Examples 2 to 8 and Comparative Examples 1 to 3 was 0°.
• the item of coating conditions shows the state of the liquid crystal phase of the liquid crystal compound at the polymerization temperature. It was confirmed that only the nematic phase was exhibited.
• a liquid crystalline compound exhibiting a smectic phase liquid crystal state is used, the content of the dichroic substance is 5.0% by mass or more with respect to the total solid mass of the liquid crystal composition, and an alignment agent is included. It was found that the use of the liquid crystal composition increased the contrast and reduced the change in color of the reflected image from that of the original image (Examples 1 to 8). In particular, from the comparison between Example 1 and Example 2, it was found that the use of a liquid crystalline compound exhibiting a high-order smectic phase resulted in a higher contrast.
• Example 2 and Example 3 the content of the dichroic substance was 10.0 mass with respect to the total solid mass of the liquid crystal composition. % or more, the reflected image has a smaller change in color than the original image.
• the contrast was higher when the alignment agent was the compound represented by the above formula (B1) or (B2).
• the comparison between Example 2 and Example 7 it was found that when two or more dichroic substances were used in combination, the contrast became higher and the color change of the reflected image was smaller than that of the original image. Do you get it.

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