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  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/182—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing using pre-adducts of epoxy compounds with curing agents
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  • C07D—HETEROCYCLIC COMPOUNDS
  • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
  • C07D405/14—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings
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  • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
  • C07D303/02—Compounds containing oxirane rings
  • C07D303/34—Compounds containing oxirane rings with hydrocarbon radicals, substituted by sulphur, selenium or tellurium atoms
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  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
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  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/02—Polycondensates containing more than one epoxy group per molecule
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  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/02—Polycondensates containing more than one epoxy group per molecule
  • C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
  • C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
  • C08G59/063—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with epihalohydrins
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  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/14—Polycondensates modified by chemical after-treatment
  • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
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  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/14—Polycondensates modified by chemical after-treatment
  • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
  • C08G59/1477—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing nitrogen
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  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
  • C08G59/22—Di-epoxy compounds
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  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
  • C08G59/22—Di-epoxy compounds
  • C08G59/24—Di-epoxy compounds carbocyclic
  • C08G59/245—Di-epoxy compounds carbocyclic aromatic
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  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
  • C08G59/22—Di-epoxy compounds
  • C08G59/26—Di-epoxy compounds heterocyclic
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  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
  • C08G59/22—Di-epoxy compounds
  • C08G59/30—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen
  • C08G59/302—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen containing sulfur
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  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
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  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
  • C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
  • C08G59/4014—Nitrogen containing compounds
  • C08G59/4042—Imines; Imides
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  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
  • C08G59/62—Alcohols or phenols
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  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
  • C08G59/62—Alcohols or phenols
  • C08G59/621—Phenols

Definitions

• the present invention relates to a glycidyl ether group-containing compound having a specific structure, a curable resin composition containing the same, a cured product, and a laminate containing a layer consisting of the cured product.
• Cured products obtained from epoxy resins have excellent heat resistance, mechanical strength, electrical properties, adhesive properties, etc., and are indispensable materials in various fields such as electricity and electronics, paints, and adhesives.
• thermosetting resins such as epoxy resins have low long-term reliability.
• cured products of epoxy resins deteriorate due to oxidation, cracks may occur.
• thermosetting resins such as epoxy resins cannot be dissolved in solvents (insoluble) or even at high temperatures (infusible), making them easy to recycle and reuse. Since the cured product becomes waste after use, it is a challenge to reduce waste and reduce the burden on the environment.
• microcapsule particles containing the first thermosetting resin and the second thermosetting resin precursor can be used.
• discloses a method of creating a self-repairable sealing material for example, see Patent Document 2.
• Patent Document 1 the adhesive after disassembly is discarded, and although the base material that is the adhesive is recyclable, there is a problem that the recyclability as a whole is insufficient. Furthermore, although the technology disclosed in Patent Document 2 has self-repair properties to a certain extent, it is not a solution from the viewpoint of reuse, and the problem of waste when it is no longer needed remains. In addition, since it is necessary to ensure the molecular mobility of the raw materials involved in the reversible bond, there is a problem that the raw materials used are limited to gel-like substances with poor mechanical strength. The current situation is that improvements are required.
• the object of the present invention is to provide a compound that is a curable resin but can easily achieve repairability and remoldability in a cured product, a curable resin composition using the same, and a curable resin composition thereof. It's about providing things.
• the present invention includes the following aspects.
• a glycidyl ether group-containing compound in which a structural unit A having one or more glycidyl ether groups and a structural unit B different from the above-mentioned A are connected by ABA, and the above-mentioned structural unit A and the above-mentioned A glycidyl ether group-containing compound characterized in that structural unit B is bonded to the structural unit B through a reversible bond having a dissociation temperature of 120°C or higher.
• the reversible bond has a dissociation temperature of 120° C. or higher, an addition type structure by Diels-Alder reaction, a disulfide bond, an ester bond, a boronate ester bond, a hemiaminal bond, an imine bond, an acylhydrazone bond, an olefin metathesis reaction,
• the glycidyl ether group-containing compound of [2] above which has either an alkoxyamine skeleton or an amide bond.
• the structural unit B further has the same reversible bond as the reversible bond with a dissociation temperature of 120° C. or higher, which is the connection site between the structural unit A and the structural unit B, [1] to [6] ]
• the glycidyl ether group-containing compound according to any one of the above.
• [Ar in formula (2) each independently has a structure containing an aromatic ring that is unsubstituted or has a substituent, and the anthracene-derived structure in formulas (1-1) and (1-2) has a halogen having an atom, an alkoxy group, an aralkyloxy group, an aryloxy group, a nitro group, an amido group, an alkyloxycarbonyl group, an aryloxycarbonyl group, a cyano group, an alkyl group, a cycloalkyl group, an aralkyl group, or an aryl group as a substituent. You can leave it there.
• G is a glycidyl group or a 2-methylglycidyl group.
• m ⁇ a is an integer of 1 to 10
• n is an average value of the number of repetitions of 0 to 10.
• Z 1 is the following formula (3)
• Z 2 is the following formula (4)
• Z 3 is the following formula (5)
• Z 4 is any of the structures represented by the following formula (6) or (7)
• Each of the plurality of molecules in one molecule may be the same or different.
• the aromatic ring in formula (3) may be substituted or unsubstituted, and * represents a bonding point.
• G is the same as above, and -OG on the naphthalene ring in the formula indicates that it may be bonded at any position.
• Ar is each independently a structure having an aromatic ring that is unsubstituted or has a substituent
• R 1 and R 2 are each independently a hydrogen atom, a methyl group or an ethyl group
• R is a hydrogen atom or a methyl group
• R' is a divalent hydrocarbon group having 2 to 12 carbon atoms
• n1 is an integer from 2 to 16
• n2 is an average value of repeating units from 2 to 30
• k1 is the average number of repetitions and ranges from 0.5 to 10
• p1 and p2 are each independently 0 to 5
• X is a structural unit represented by the following formula (4-1)
• Y is a structural unit represented by the following formula (4-2)
• n3 and n5 are the average values of the repeating numbers, each from 0.5 to 10, n4 is an integer from 1 to 16, and R '' each independently represents a hydrogen atom, a methyl or ethyl group.
• the curable resin composition as described in [10] above, wherein the compound (I) that is reactive with the glycidyl ether group-containing compound is a hydroxyl group-containing compound having a reversible bond.
• the curable resin composition as described in [11] above, wherein the hydroxyl group-containing compound having a reversible bond is a hydroxyl group-containing compound represented by the following general formula.
• [Ar in formula (9) each independently has a structure containing an aromatic ring that is unsubstituted or has a substituent, and the anthracene-derived structure in formulas (8-1) and (8-2) has a halogen having an atom, an alkoxy group, an aralkyloxy group, an aryloxy group, a nitro group, an amido group, an alkyloxycarbonyl group, an aryloxycarbonyl group, a cyano group, an alkyl group, a cycloalkyl group, an aralkyl group, or an aryl group as a substituent. You can leave it there.
• m ⁇ a is an integer of 1 to 10
• n is an average value of the number of repetitions of 0 to 10.
• Z 5 is the following formula (10)
• Z 2 is the following formula (11)
• Z 3 is the following formula (12)
• Z 4 is any of the structures represented by the following formula (13) or (14)
• Each of the plurality of molecules in one molecule may be the same or different.
• the aromatic ring in formula (10) may be substituted or unsubstituted, and * represents a bonding point.
• the hydroxyl group on the naphthalene ring in the formula may be bonded to any position.
• Ar is the same as above, Ar is each independently a structure having an aromatic ring that is unsubstituted or has a substituent, R 1 and R 2 are each independently a hydrogen atom, a methyl group or an ethyl group, R is a hydrogen atom or a methyl group, R' is a divalent hydrocarbon group having 2 to 12 carbon atoms, n1 is an integer from 2 to 16, n2 is an average value of repeating units from 2 to 30, k1 is the average number of repetitions and ranges from 0.5 to 10, p1 and p2 are each independently 0 to 5, X is a structural unit represented by the following formula (11-1), Y is a structural unit represented by the following formula (11-2),
• n3 and n5 are the average values of the number of repetitions, each from 0.5 to 10, n4 is an integer from 1 to 16, and R '' each independently represents hydrogen. Atom, methyl group or ethyl group.
• the above [9] to [12] contains an epoxy resin having an epoxy equivalent of 100 to 10,000 g/eq, other than the glycidyl ether group-containing compound described in any one of [1] to [8] above.
• the curable resin composition according to [14] The curable resin composition according to [13] above, wherein the epoxy resin is represented by the following formula (15) and has an epoxy equivalent of 500 to 10,000 g/eq.
• each Ar is independently a structure having an aromatic ring that is unsubstituted or has a substituent
• X' is a structural unit represented by the following formula (15-1)
• Y' is a structural unit represented by the following formula (15-2)
• R 1 and R 2 are each independently a hydrogen atom, a methyl group or an ethyl group
• R' is a divalent hydrocarbon group having 2 to 12 carbon atoms
• R 3 , R 4 , R 7 and R 8 are each independently a hydroxyl group, a glycidyl ether group or a 2-methylglycidyl ether group
• R 5 , R 6 , R 9 and R 10 are each independently a hydrogen atom or a methyl group
• n 1 is an integer from 4 to 16
• n 2 is an average value of repeating units, and is 2 to 30.
• R 11 and R 12 are each independently a glycidyl ether group or a 2-methylglycidyl ether group
• R 13 and R 14 are each independently a hydroxyl group, a glycidyl ether group or a 2-methylglycidyl ether group
• R 15 and R 16 are hydrogen atoms or methyl groups
• m3, m4, p1, p2, q are repeated average values
• m3 and m4 are each independently from 0 to 25
• m3+m4 ⁇ 1 p1 and p2 are each independently 0 to 5
• q is 0.5 to 5.
• the bond between the structural unit X' represented by the formula (15-1) and the structural unit Y' represented by the formula (15-2) may be random or block,
• the total number of structural units X and Y present in one molecule is m3 and m4, respectively.
• a curable resin composition wherein the concentration of reversible bonds is 0.10 mmol/g or more based on the total mass of curable components in the curable resin composition. thing.
• a curable resin composition wherein the curable resin composition according to any one of [9] to [15] above is a self-healing composition or a composition for remolding material.
• a cured product obtained by curing the curable resin composition according to any one of [9] to [16] above.
• a laminate comprising a base material and a layer containing the cured product according to [17].
• the glycidyl ether group-containing compound represented by the above formulas (1-1) and (1-2) is converted into a conjugated diene represented by the following general formulas (1-1)' and (1-2)'.
• n, Z 2 and Z 3 are the same as above.
• a glycidyl ether group-containing compound as one embodiment of the present invention has a glycidyl ether group formed by connecting a structural unit A having one or more glycidyl ether groups and a structural unit B different from the above A with ABA.
• the structural unit A and the structural unit B are bonded together through a reversible bond having a dissociation temperature of 120° C. or higher.
• the glycidyl ether group in the present invention does not mean only a glycidyl ether group without a substituent, but also includes a glycidyl ether group having a substituent on a carbon atom.
• the glycidyl ether group-containing compound is incorporated into the crosslinked structure by a curing reaction based on the glycidyl ether group.
• the structural unit B since it has reversibility even after becoming a cured product, the structural unit B in particular can exist apart from the crosslinked structure, so it has high molecular mobility even in the cured product. For this reason, when the cured product is subjected to impact and cracks or is crushed, the reversible bond is likely to be broken, but on the other hand, the reversible bond can be used even in low temperature ranges including room temperature. , the bond can be reversibly reshaped and can exhibit functions such as repairability and remoldability.
• the structural unit B exists apart from the crosslinked structure, it exhibits particularly high molecular mobility and exhibits low-temperature repairability and low-temperature remolding. For example, even if a cured product made using the glycidyl ether group-containing compound of the present invention is crushed, the cured product can be repaired based on reversible bonds by placing it at a low temperature including room temperature or in a heated state. It is easy, and it is also possible to re-shape the cured product after pulverizing it.
• the reversible bond having a dissociation temperature of 120° C. or higher may be a covalent bond type or a non-covalent bond type, and a covalent bond type is preferable from the viewpoint of durability of the cured product.
• non-covalent bond systems are preferable from the viewpoint of shortening the repair time and remolding time after pulverization of the cured product.
• the covalent bond system is not particularly limited, but includes, for example, an addition type structure by Diels-Alder reaction, a disulfide bond, an ester bond, a boronic acid ester bond, a hemiaminal bond, an imine bond, an acylhydrazone bond, an olefin metathesis reaction, and an alkoxyamine.
• Examples include a skeleton and an amide bond.
• anthracene type reversible bond consisting of an anthracene structure and maleimide structure
• addition type structure by Diels-Alder reaction and disulfide bond sandwiched between aromatic rings are recommended. preferable.
• the non-covalent bond system is not particularly limited, but includes, for example, van der Waals forces, ionic bonds, cyclodextrin inclusion bonds, and hydrogen bonds such as ureidopyrimidinone units and polyether thiourea.
• anthracene-type addition type structure by the Diels-Alder reaction into a compound
• a method using anthracene having a reactive functional group on the ring and maleimide having a reactive functional group is available. This is preferable because it is simple.
• a specific reversible bond partial structure can be represented by the chemical formula below. Introducing a reversible bond into a compound by bonding with other structural units based on the R moiety in the formula below in the maleimide-derived structure or various reactive functional groups on the ring of the anthracene-derived structure. I can do it.
• the Diels-Alder reaction a conjugated diene and a parent diene undergo an addition reaction to form a 6-membered ring. Since the Diels-Alder reaction is an equilibrium reaction, the Retro-Diels-Alder reaction occurs at a predetermined temperature and dissociation (dissociation and crosslinking) occurs. At this time, if the temperature at which the Retro-Diels-Alder reaction occurs (dissociation temperature) is low, decrosslinking will occur in the high temperature range, resulting in a decrease in crosslink density of the cured product and a decrease in mechanical strength.
• dissociation temperature the temperature at which the Retro-Diels-Alder reaction occurs
• the Diels-Alder reaction unit consisting of an anthracene structure and a maleimide structure has a high dissociation temperature of 250° C. or higher, does not dissociate at least about 200° C. and maintains a crosslinked structure, and has excellent thermal stability. Therefore, reduction in crosslink density of the cured product can be suppressed, and good mechanical strength can be maintained.
• the C-C bond of the Diels-Alder reaction unit has a lower bond energy than a normal covalent bond, so the Diels-Alder The C—C bond of the reaction unit will be preferentially cleaved.
• the equilibrium of the C-C bond in the Diels-Alder reaction unit shifts in the direction of bonding, so it forms an adduct (Diels-Alder reaction unit) again, which can be used to repair scratches or It is thought that remolding becomes possible.
• Examples of the compound containing the disulfide bond include the compounds shown below.
• a site other than the disulfide bond site such as a hydroxyl group, an amino group, or a vinyl group
• this disulfide bond site when the cured product is broken by an external force, the disulfide bond will be preferentially broken, but below the dissociation temperature, the equilibrium will shift in the direction of bonding. By doing so, SS bonds are formed again, making it possible to repair and reshape the damage.
• Examples of the compound containing the alkoxyamine skeleton include the compounds shown below. Similarly to the above, by bonding to another compound via the terminal vinyl group (methacryloyl group), it becomes possible to incorporate a reversible bond into the glycidyl ether group-containing compound.
• structural unit B also has a plurality of reversible bonds of the same type as the reversible bond between AB.
• the molecular weight of the structural unit B is a certain value or more, and for example, it is preferable that the average molecular weight (Mw) is 28 or more.
• Mw average molecular weight
• the molecular weight between the reversible bonds is preferably 28 or more.
• a crosslinkable functional group similar to the glycidyl ether group in structural unit A may be present in structural unit B, but from the viewpoint of more easily exerting the effects of the present invention, crosslinkable (curable) It is preferable not to have a functional group.
• the glycidyl ether group-containing compound of the present invention when used, for example, as a structural adhesive, there is an aspect that the cured product can exhibit more flexibility or conformability to the base material. Therefore, it is preferable to have an alkylene chain or an alkylene ether chain, and in this case, the alkylene chain more preferably has 2 to 30 carbon atoms, most preferably 4 to 16 carbon atoms.
• the alkylene ether chain is not particularly limited, but it is preferably an alkylene ether chain having 2 to 12 carbon atoms, and preferably has an average repeating number of 2 to 30.
• the glycidyl ether group in the structural unit A may be any type as long as it can easily react with other functional groups, but from the viewpoint of availability of raw materials and curability, A glycidyl ether group having no substituents is preferred.
• the number of glycidyl ether groups in the structural unit A is not particularly limited, but may be selected from the viewpoint of industrial availability of raw materials, ease of adjustment of crosslinking density when cured, etc. From this point of view, the range is preferably from 1 to 3, and more preferably from 1 to 2.
• the average molecular weight (Mw) of the glycidyl ether group-containing compound is not particularly limited, but from the viewpoint of achieving both mechanical strength, flexibility, and repair/remoldability when made into a cured product, It is preferably 500 or more, and preferably 50,000 or less.
• the molecular weight per reversible bond should be in the range of 300 to 10,000 to improve the remoldability of the cured product. More preferable from this point of view.
• a glycidyl ether group-containing compound as one embodiment of the present invention is a compound represented by the following general formula.
• Ar in formula (2) each independently has a structure containing an aromatic ring that is unsubstituted or has a substituent, and the anthracene-derived structure in formulas (1-1) and (1-2) has a halogen atom. , an alkoxy group, an aralkyloxy group, an aryloxy group, a nitro group, an amide group, an alkyloxycarbonyl group, an aryloxycarbonyl group, a cyano group, an alkyl group, a cycloalkyl group, an aralkyl group, or an aryl group as a substituent. It's okay.
• G is a glycidyl group or a 2-methylglycidyl group.
• m ⁇ a is an integer of 1 to 10
• n is an average value of the number of repetitions of 0 to 10.
• Z 1 is the following formula (3)
• Z 2 is the following formula (4)
• Z 3 is the following formula (5)
• Z 4 is any of the structures represented by the following formula (6) or (7)
• Each of the plurality of molecules in one molecule may be the same or different.
• the aromatic ring in formula (3) may be substituted or unsubstituted, and * represents a bonding point.
• G is the same as above, and -OG on the naphthalene ring in the formula indicates that it may be bonded at any position.
• Ar is each independently a structure having an aromatic ring that is unsubstituted or has a substituent
• R 1 and R 2 are each independently a hydrogen atom, a methyl group or an ethyl group
• R is a hydrogen atom or a methyl group
• R' is a divalent hydrocarbon group having 2 to 12 carbon atoms
• n1 is an integer from 2 to 16
• n2 is an average value of repeating units from 2 to 30
• k1 is the average number of repetitions and ranges from 0.5 to 10
• p1 and p2 are each independently 0 to 5
• X is a structural unit represented by the following formula (4-1)
• Y is a structural unit represented by the following formula (4-2)
• n3 and n5 are the average values of the repeating numbers, each from 0.5 to 10, n4 is an integer from 1 to 16, and R '' each independently represents a hydrogen atom, a methyl or ethyl group.
• the general formulas (1-1) and (1-2) have a reversible bond formed by anthracene and maleimide within the molecule and at the end.
• One or more Z1 which is any structure represented by the above general formula (3), is added to the terminal maleimide structure in general formula (1-1) and the terminal anthracene structure in general formula (1-2).
• This glycidyl ether group or 2-methylglycidyl ether group contributes to the curing reaction in the curable resin composition described below.
• m-a is the number of Z1 in the anthracene-derived structure, and is an integer from 1 to 10, but from the viewpoint of ease of obtaining industrial raw materials, ease of control of curing reaction, etc., it is in the range of 1 to 4. It is preferably 1 or 2, and more preferably 1 or 2.
• the general formula (2) has a disulfide bond in the molecule, and the molecular terminal has a structure containing an aromatic ring having one or more Z1, which is any structure represented by the general formula (3). It has become.
• This glycidyl ether group or 2-methylglycidyl ether group contributes to the curing reaction in the curable resin composition described below.
• Z1 in the formula is a structural unit having a glycidyl ether group or a 2-methylglycidyl ether group, represented by the general formula (3) above, and among these, from the viewpoint of raw material availability and reactivity, Those having the following structural formula are preferred.
• G is a glycidyl ether group or a 2-methylglycidyl ether group.
• the site connecting the maleimide-derived structure is Z3
• the site connecting the anthracene-derived structure is Z2
• the oxygen atom is Z4, and each has one of the structures represented by the general formulas (4), (5), (6), and (7).
• n is the average value of the number of repetitions, and is in the range of 0 to 10, preferably in the range of 0 to 5.
• Ar in these structural formulas is an aromatic ring that may have a substituent, and is not particularly limited.
• the aromatic ring include a benzene ring, a naphthalene ring, an anthracene ring, a phenanthrene ring, and a fluorene ring.
• the substituent include a halogen atom, an alkoxy group, an aralkyloxy group, an aryloxy group, a nitro group, an amide group, an alkyloxycarbonyl group, an aryloxycarbonyl group, a cyano group, an alkyl group, a cycloalkyl group, an aralkyl group, Examples include aryl groups.
• the substituent on Ar is preferably one that does not cause a curing reaction when used as a later curable resin composition because the effects of the present invention are more likely to be exhibited.
• Ar has any structure represented by the following structural formula.
• the repeating unit n 1 is an integer from 2 to 16.
• n 1 is 4 or more, the deformation mode when cured is likely to be elastic deformation. Further, by setting n 1 to 16 or less, reduction in crosslink density can be suppressed. It is preferably 4 to 15, more preferably 6 to 12.
• R 1 and R 2 are each independently a hydrogen atom, a methyl group, or an ethyl group, and each R is independently a hydrogen atom or a methyl group. Among these, hydrogen atoms are preferred.
• n 2 is an average value of repeating units of 2 to 30. This range is preferable since the viscosity of the glycidyl ether group-containing compound and the crosslinking density of the obtained cured product are well balanced. It is preferably 2-25, more preferably 4-20.
• R' is a divalent hydrocarbon group having 2 to 12 carbon atoms. Within this range, the adhesive strength is improved and the deformation mode of the cured product tends to be elastic deformation. Preferably, R' is a divalent hydrocarbon group having 2 to 6 carbon atoms.
• the divalent hydrocarbon group is not particularly limited, and includes linear or branched alkylene groups, alkenylene groups, alkynylene groups, cycloalkylene groups, arylene groups, aralkylene groups (2 having an alkylene group and an arylene group). valence groups), etc.
• Examples of the alkylene group include a methylene group, an ethylene group, a propylene group, a butylene group, a pentylene group, a hexylene group, a trimethylene group, a tetramethylene group, a pentamethylene group, a hexamethylene group, and the like.
• Examples of the alkenylene group include vinylene group, 1-methylvinylene group, propenylene group, butenylene group, and pentenylene group.
• Examples of the alkynylene group include ethynylene group, propynylene group, butynylene group, pentynylene group, hexynylene group, and the like.
• Examples of the cycloalkylene group include a cyclopropylene group, a cyclobutylene group, a cyclopentylene group, and a cyclohexylene group.
• Examples of the arylene group include a phenylene group, tolylene group, xylylene group, and naphthylene group.
• ethylene group, propylene group, and tetramethylene group are preferable from the viewpoint of easy availability of raw materials, viscosity of the resulting glycidyl ether group-containing compound, and balance of flexibility when cured.
• each R is independently a hydrogen atom or a methyl group. Among these, hydrogen atoms are preferred.
• m1 and m2 are the repeating average values of the structural unit X and structural unit Y, respectively, and each independently ranges from 0 to 25, and m1+m2 ⁇ 1.
• m1 and m2 each range from 0.5 to 10.
• k1 in the general formula (4) is the average number of repetitions, and is in the range of 0.5 to 5, preferably in the range of 0.5 to 2.
• n3 and n5 are average values of the number of repetitions, each of which is from 0.5 to 10, n4 is an integer from 1 to 16, and R '' is each independently A hydrogen atom, a methyl group, or an ethyl group.
• n3 is in the range of 0.5 to 10
• n5 is in the range of 2 to 3, from the viewpoint of raw material availability, mechanical properties of the obtained cured product, etc.
• n4 is preferably an integer of 1 to 8
• R '' is preferably a hydrogen atom.
• R 1 , R 2 , R', n1, and n2 are the same as above, and preferred ones are also the same as above.
• Examples of the glycidyl ether group-containing compound of the present invention include, but are not limited to, those represented below.
• the method for producing the glycidyl ether group-containing compound which is an embodiment of the present invention, is not particularly limited, and may be produced stepwise using known reactions depending on the desired structure. It can also be obtained by appropriately combining commercially available products. Typical synthesis methods will be described below.
• the above general formulas (1-1) and (1-2) have a Diels-Alder reaction unit, which is an addition reaction unit formed by a Diels-Alder reaction consisting of an anthracene structure and a maleimide structure, in the molecule as a reversible bond. and by using a maleimide compound having the structure of Z1 in the general formula (1-1) and using an anthracene compound having the structure of Z1 in the general formula (1-2). I can do it.
• the so-called Diels-Alder reaction in which a conjugated diene such as an anthracene structure and a parent diene such as a maleimide structure form a six-membered ring is an equilibrium reaction, and at a higher temperature than the temperature at which the addition reaction proceeds, It is widely known that the retro-Diels-Alder reaction proceeds, which is a reverse reaction in which the addition reaction moiety dissociates and returns to the original conjugated diene and parent diene.
• the maleimide compound having a hydroxyl group which is a precursor of the maleimide compound having the structure of Z1
• any of the compounds listed in the following formula can be mentioned.
• hydroxyphenylmaleimide is preferred in terms of curability
• monohydroxyphenylmaleimide is particularly preferred in terms of balance between reactivity, physical properties of cured product, and repairability and remoldability.
• monohydroxyphenylmaleimides parahydroxyphenylmaleimide is particularly preferred from the viewpoint of heat resistance.
• the hydroxyl group in the compound can be converted into a glycidyl ether group, for example, by a known method as described in Examples.
• anthracene compound having a hydroxyl group which is a precursor of the anthracene compound having the structure of Z1
• any of the compounds listed in the following formula can be mentioned.
• 9-(4-hydroxybenzyl)-10-(4-hydroxyphenyl)anthracene and hydroxyanthracene are preferable because of their good curability
• 9-(4-hydroxybenzyl)-10-(4- Hydroxyphenyl)anthracene and monohydroxyanthracene are particularly preferred in view of the balance between reactivity, physical properties of cured products, and repairability and remolding properties.
• the hydroxyl group in the compound can be converted into a glycidyl ether group, for example, by a known method as described in Examples.
• the structures of the above maleimide compound and anthracene compound each independently include a hydrogen atom, a halogen atom, an alkoxy group, an aralkyloxy group, an aryloxy group, a nitro group, an amide group, an alkyloxycarbonyl group, and an aryloxycarbonyl group. , a cyano group, an alkyl group, a cycloalkyl group, an aralkyl group, or an aryl group as a substituent.
• an alkoxy group, an aralkyloxy group, an aryloxy group, a carboxy group, an alkyloxycarbonyl group, an aryloxycarbonyl group, an alkyl group, a cycloalkyl group, an aralkyl group, and an aryl group. also include those in which various substituents are further bonded to the carbon atoms they have.
• a known method may be used for the Diels-Alder reaction.
• a conjugated diene compound and a parent diene compound are mixed in equimolar amounts, or in some cases in excess of one component, melted by heating or dissolved in a solvent, stirred for 1 to 24 hours at a temperature of room temperature to 200°C, and then purified as is. It can be obtained by filtration or solvent distillation without any purification, or it can be obtained by commonly used isolation and purification methods such as recrystallization, reprecipitation, and chromatography.
• Sites other than reversible binding can be synthesized by known methods. For example, after a diglycidyl ether or aliphatic divinyl ether of an aliphatic dihydroxy compound is reacted with an aromatic hydroxy compound to obtain a compound having a hydroxy group at the terminal, chloromethylanthracene, glycidyloxyanthracene, etc.
• the compound represented by the general formula (1-1) is further reacted with a maleimide compound having a glycidyl ether group according to the above to introduce an anthracene structure at the terminal. You can get it.
• a compound represented by the general formula (1-1) can be obtained by carrying out a Diels-Alder reaction with a maleimide compound having a glycidyl ether group.
• an aromatic dihydroxy compound and a dihalogenated alkyl compound or a dihalogenated aralkyl compound are reacted to obtain a compound having a halogenated alkyl group at the end, and then the terminal is reacted with hydroxymethylanthracene or the like.
• the compound represented by the general formula (1-1) can be obtained by introducing an anthracene structure and further performing a Diels-Alder reaction with a maleimide compound having a glycidyl ether group as described above.
• the diglycidyl ether of the aliphatic dihydroxy compound is not particularly limited, and includes, for example, 1,11-undecanediol diglycidyl ether, 1,12-dodecanediol diglycidyl ether, 1,13-tridecanediol, 1,14-tetradecanediol diglycidyl ether, 1,15-pentadecanediol diglycidyl ether, 1,16-hexadecanediol diglycidyl ether, 2-methyl-1,11-undecanediol diglycidyl ether, 3-methyl-1, Examples include 11-undecanediol diglycidyl ether and 2,6,10-trimethyl-1,11-undecanediol diglycidyl ether, which may be used alone or in combination of two or more.
• 1,12-dodecanediol diglycidyl ether, 1,13-tridecanediol, and 1,14-tetradecanediol diglycidyl ether are most preferably used.
• the aliphatic divinyl ether is not particularly limited, and examples thereof include polyethylene glycol divinyl ether, polypropylene glycol divinyl ether, polytetramethylene glycol divinyl ether, 1,3-butylene glycol divinyl ether, and 1,4-butane divinyl ether.
• divinyl ethers of linear alkylene groups such as all divinyl ether, 1,6-hexanediol divinyl ether, 1,9-nonanediol divinyl ether, 1,10-decanediol divinyl ether, and neopentyl glycol divinyl ether
• Divinyl ether of alkylene group 1,4-cyclohexanediol divinyl ether, 1,4-cyclohexanedimethanol divinyl ether, tricyclodecanediol divinyl ether, tricyclodecane dimethanol divinyl ether, pentacyclopentadecane dimethanol divinyl ether, penta Divinyl ether containing a cycloalkane structure such as cyclopentadecane diol divinyl ether, bisphenol A divinyl ether, bisphenol F divinyl ether, hydroquinone divinyl ether, etc.
• divinyl ethers having a polyether structure or a linear alkylene chain having 9 to 10 carbon atoms are preferred from the viewpoint of an excellent balance between flexibility and toughness of the resulting cured product, such as polyethylene glycol divinyl ether, polypropylene glycol divinyl ether, Most preferably, polytetramethylene glycol divinyl ether, 1,12-dodecanediol diglycidyl ether, 1,13-tridecanediol, 1,14-tetradecanediol diglycidyl ether are used.
• the aromatic hydroxy compound is not particularly limited, and includes, for example, hydroquinone, resorcinol, dihydroxybenzenes such as catechol, pyrogallol, 1,2,4-trihydroxybenzene, 1,3,5-trihydroxy Trihydroxybenzenes such as benzene, triphenylmethane type phenols such as 4,4',4"-trihydroxytriphenylmethane, 1,6-dihydroxynaphthalene, 2,7-dihydroxynaphthalene, 1,4-dihydroxynaphthalene , 1,5-dihydroxynaphthalene, 2,3-dihydroxynaphthalene, and 2,6-dihydroxynaphthalene.
• hydroquinone resorcinol
• dihydroxybenzenes such as catechol, pyrogallol
• 1,2,4-trihydroxybenzene 1,3,5-trihydroxy Trihydroxybenzenes
• Trihydroxybenzenes such as benzene
• 1,1'-binaphthalene-2,2',7,7'-tetraol 1,1'-binaphthalene-2,2',7,7'-tetraol, tetrafunctional phenols such as 1,1'-oxybis(2,7-naphthalenediol), bis(4-hydroxyphenyl) ) methane, 2,2-bis(4-hydroxyphenyl)propane, 2,2-bis(3-methyl-4-hydroxyphenyl)propane, 1,1-bis(4-hydroxyphenyl)cyclohexane, and 1,1 - Bisphenols such as bis(4-hydroxyphenyl)-1-phenylethane and bis(4-hydroxyphenyl)sulfone, 2,2'-biphenol, 4,4'-biphenol, (1,1'-biphenyl) -3,4-diol, 3,3'-dimethyl-(1,1'-biphenyl)-4,4'-diol, 3-methyl-
• Alicyclic structure-containing phenols such as biphenols, polyadducts of phenol and dicyclopentadiene, and polyadducts of phenol and terpene compounds, bis(2-hydroxy-1-naphthyl)methane, and bis( Examples include naphthols such as 2-hydroxy-1-naphthyl propane, so-called Zylock type phenolic resins which are condensation reaction products of phenol and phenylene dimethyl chloride or biphenylene dimethyl chloride, and can be used alone or in combination of two or more. May be used.
• bifunctional phenol compounds having a structure in which the aromatic nucleus of each of the above compounds is substituted with a methyl group, t-butyl group, or a halogen atom as a substituent may also be mentioned.
• the alicyclic structure-containing phenols and the Zylock type phenol resins may contain not only bifunctional components but also trifunctional or higher functional components, but they may be used as they are, or they may be used as they are in columns, etc. Only the bifunctional components may be extracted and used after a purification step.
• bisphenols are preferable because they have an excellent balance between flexibility and toughness when made into a cured product, and bis(4-hydroxyphenyl)methane, 2,2- Bis(4-hydroxyphenyl)propane is preferred. Furthermore, when moisture resistance of the cured product is important, it is preferable to use phenols containing an alicyclic structure.
• the reaction ratio of the diglycidyl ether of the aliphatic dihydroxy compound and the aromatic hydroxy compound is preferably such that the former/latter is in the range of 1/1.01 to 1/5.0 (molar ratio). From the viewpoint of achieving a well-balanced combination of flexibility and heat resistance of the obtained cured product, it is preferable that (a1)/(a2) is 1/1.02 to 1/3.0 (molar ratio).
• the reaction between the diglycidyl ether of the aliphatic dihydroxy compound and the aromatic hydroxy compound is preferably carried out in the presence of a catalyst.
• a catalyst can be used as the catalyst, including alkali (earth) metal hydroxides such as sodium hydroxide, potassium hydroxide, lithium hydroxide, and calcium hydroxide; alkali metals such as sodium carbonate and potassium carbonate; Carbonates, phosphorus compounds such as triphenylphosphine, DMP-30, DMAP, chlorides such as tetramethylammonium, tetraethylammonium, tetrabutylammonium, benzyltributylammonium, bromide, iodide, tetramethylphosphonium, tetraethylphosphonium, tetrabutylphosphonium , chlorides such as benzyltributylphosphonium, quaternary ammonium salts such as bromide and iodide,
• Tertiary amines such as octane, imidazoles such as 2-ethyl-4-methylimidazole and 2-phenylimidazole, and the like.
• Two or more types of these catalysts may be used in combination.
• sodium hydroxide, potassium hydroxide, triphenylphosphine, and DMP-30 are preferred because the reaction proceeds quickly and they are highly effective in reducing the amount of impurities.
• the amount of these catalysts to be used is not particularly limited, but it is preferably used in an amount of 0.0001 to 0.01 mol per 1 mol of the phenolic hydroxyl group of the aromatic hydroxy compound.
• the form of these catalysts is not particularly limited either, and they may be used in the form of an aqueous solution or in the form of a solid.
• the reaction between the diglycidyl ether of the aliphatic dihydroxy compound and the aromatic hydroxy compound can be carried out in the absence of a solvent or in the presence of an organic solvent.
• organic solvents that can be used include methyl cellosolve, ethyl cellosolve, toluene, xylene, methyl isobutyl ketone, dimethyl sulfoxide, propyl alcohol, butyl alcohol, and the like.
• the amount of organic solvent used is usually 50 to 300% by weight, preferably 100 to 250% by weight based on the total weight of the raw materials charged. These organic solvents can be used alone or in combination. In order to carry out the reaction quickly, it is preferable to use no solvent, and on the other hand, it is preferable to use dimethyl sulfoxide in terms of reducing impurities in the final product.
• the reaction temperature when carrying out the above reaction is usually 50 to 180°C, and the reaction time is usually 1 to 10 hours. From the viewpoint of reducing impurities in the final product, the reaction temperature is preferably 100 to 160°C.
• an antioxidant or a reducing agent may be added to suppress it.
• Antioxidants are not particularly limited, but examples include hindered phenol compounds such as 2,6-dialkylphenol derivatives, divalent sulfur compounds, and phosphite compounds containing trivalent phosphorus atoms. Can be done.
• the reducing agent is not particularly limited, but includes, for example, hypophosphorous acid, phosphorous acid, thiosulfuric acid, sulfite, hydrosulfite, or salts thereof.
• neutralization or washing with water may be carried out until the pH value of the reaction mixture becomes 3 to 7, preferably 5 to 7.
• Neutralization treatment and water washing treatment may be carried out according to conventional methods.
• an acidic substance such as hydrochloric acid, monobasic sodium hydrogen phosphate, p-toluenesulfonic acid, or oxalic acid can be used as a neutralizing agent.
• the solvent is distilled off under reduced pressure and heating to concentrate the product to obtain a compound.
• the reaction ratio of the aliphatic divinyl ether and the aromatic hydroxy compound is preferably in the range of 1/1.01 to 1/5.0 (mole ratio) of the former/latter, and the resulting curing From the viewpoint of achieving a good balance between flexibility and heat resistance of the product, it is preferable that (a1)/(a2) is 1/1.02 to 1/3.0 (molar ratio).
• Catalysts that can be used here include inorganic acids such as sulfuric acid, hydrochloric acid, nitric acid, phosphoric acid, toluenesulfonic acid, methanesulfonic acid, xylene sulfonic acid, trifluoromethanesulfonic acid, oxalic acid, formic acid, trichloroacetic acid, trifluoroacetic acid.
• inorganic acids such as sulfuric acid, hydrochloric acid, nitric acid, phosphoric acid, toluenesulfonic acid, methanesulfonic acid, xylene sulfonic acid, trifluoromethanesulfonic acid, oxalic acid, formic acid, trichloroacetic acid, trifluoroacetic acid.
• Examples include organic acids such as aluminum chloride, iron chloride, tin chloride, gallium chloride, titanium chloride, aluminum bromide, gallium bromide, Lewis acids such as boron trifluoride ether complex, and trifluoroboronphenol complex.
• the amount of catalyst used is usually in the range of 10 ppm to 1% by weight based on the weight of the divinyl ether compound. At this time, it is preferable to select the type and amount used so as not to cause a nucleation reaction of the vinyl group to the aromatic ring.
• the reaction between the aliphatic divinyl ether and the aromatic hydroxy compound can be carried out in the absence of a solvent or in the presence of an organic solvent.
• organic solvents such as benzene, toluene, and xylene
• ketone organic solvents such as acetone, methyl ethyl ketone, methyl isobutyl ketone, and cyclohexanone
• alcohol organic solvents such as methanol, ethanol, and isopropyl alcohol-normal butanol.
• the amount of organic solvent used is usually 50 to 300% by weight, preferably 100 to 250% by weight based on the total weight of the raw materials charged. These organic solvents can be used alone or in combination.
• the reaction temperature when carrying out the above reaction is usually 50 to 150°C, and the reaction time is usually 0.5 to 10 hours. At this time, in order to prevent self-polymerization of the vinyl ether group, it is preferable to carry out the reaction under an oxygen atmosphere.
• the thus obtained compound having a hydroxyl group at the end is reacted with chloromethylanthracene or the like.
• sodium hydroxide, potassium hydroxide, potassium carbonate, etc. can be used as a catalyst, and toluene, acetone, methyl ethyl ketone (MEK), methyl isobutyl ketone, acetonitrile, dimethyl formamide, etc. can be used as a solvent.
• the reaction temperature is room temperature to 200°C, and the reaction time is 1 to 24 hours.
• the catalyst can be removed by filtration, etc., and the target compound can be obtained by extraction, solvent removal, etc.
• the Diels-Alder reaction for this compound is as described above.
• the aliphatic hydroxy compound is not particularly limited and includes, for example, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, 1,7-heptanediol, 1,8 -Octanediol, 1,9-nonanediol, 1,10-decanediol, 1,11-undecanediol, 1,12-dodecanediol, 1,13-tridecanediol, 1,14-tetradecanediol, 1,15 -Pentadecanediol, 1,16-hexadecanediol, 2-methyl-1,11-undecanediol, 3-methyl-1,11-undecanediol, 2,6,10-trimethyl-1,11-undecanediol, polyethylene glycol , polypropylene glycol, polytetramethylene glycol, polypent
• dihydroxy compounds with a polyether structure or a linear alkylene chain having 12 to 14 carbon atoms in view of the excellent balance between flexibility and heat resistance of the resulting cured product, and polyethylene glycol, polypropylene glycol, Most preferably, polytetramethylene glycol, 1,12-dodecanediol, 1,13-tridecanediol, 1,14-tetradecanediol are used.
• the dihalogenated alkyl compound is not particularly limited and includes, for example, 1,4-dichlorobutane, 1,5-dichloropentane, 1,6-dichlorohexane, 1,7-dichloroheptane, 1,8- Dichlorooctane, 1,9-dichlorononane, 1,10-dichlorodecane, 1,11-dichloroundecane, 1,12-dichlorododecane, 1,4-dibromobutane, 1,5-dibromopentane, 1,6- Dibromohexane, 1,7-dibromoheptane, 1,8-dibromooctane, 1,9-dibromononane, 1,10-dibromodecane, 1,11-dibromoundecane, 1,12-dibromododecane, etc. They may be used alone or in combination of two or more.
• the dihalogenated aralkyl compound is not particularly limited and includes, for example, dichloroxylene, dichloromethylbiphenyl, dibromoxylene, dibromomethylbiphenyl, etc., and may be used alone or in combination of two or more types.
• the reaction ratio of the aromatic dihydroxy compound and the dihalogenated alkyl compound or dihalogenated aralkyl compound is preferably such that the former/latter is in the range of 1/1.01 to 1/5.0 (molar ratio). From the viewpoint of achieving a well-balanced combination of flexibility and heat resistance of the obtained cured product, it is preferable that (a1)/(a2) is 1/1.02 to 1/3.0 (molar ratio).
• the reaction between the aromatic dihydroxy compound and the dihalogenated alkyl compound or dihalogenated aralkyl compound is preferably carried out in the presence of a catalyst.
• a catalyst can be used as the catalyst, including alkali (earth) metal hydroxides such as sodium hydroxide, potassium hydroxide, lithium hydroxide, and calcium hydroxide; alkali metals such as sodium carbonate and potassium carbonate; Examples include carbonates. Two or more types of these catalysts may be used in combination. Among these, sodium hydroxide, potassium hydroxide, and potassium carbonate are preferred because the reaction proceeds quickly and the effect of reducing the amount of impurities is high.
• the amount of these catalysts used is not particularly limited, but it is preferably used in an amount of 0.0001 to 10 mol per 1 mol of the phenolic hydroxyl group of the aromatic hydroxy compound.
• the form of these catalysts is not particularly limited either, and they may be used in the form of an aqueous solution or in the form of a solid.
• the reaction between the aromatic dihydroxy compound and the dihalogenated alkyl compound or dihalogenated aralkyl compound can be carried out in the absence of a solvent or in the presence of an organic solvent.
• organic solvents examples include toluene, acetone, methyl ethyl ketone (MEK), methyl isobutyl ketone, acetonitrile, and dimethylformamide.
• the amount of organic solvent used is usually 50 to 300% by weight, preferably 100 to 1000% by weight based on the total weight of the raw materials charged. These organic solvents can be used alone or in combination.
• the reaction temperature when carrying out the above reaction is usually room temperature to 150°C, and the reaction time is usually 1 to 24 hours. From the viewpoint of reducing impurities in the final product, the reaction temperature is preferably room temperature to 100°C.
• the thus obtained compound having a halogenated alkyl group at the end is reacted with hydroxymethylanthracene or the like.
• sodium hydroxide, potassium hydroxide, potassium carbonate, etc. can be used as a catalyst, and toluene, acetone, methyl ethyl ketone (MEK), methyl isobutyl ketone, acetonitrile, dimethyl formamide, etc. can be used as a solvent.
• the reaction temperature is room temperature to 200°C, and the reaction time is 1 to 24 hours. Thereafter, the catalyst can be removed by filtration, etc., and the target compound can be obtained by extraction, solvent removal, etc.
• the Diels-Alder reaction for this compound is as described above.
• the conjugated diene intermediate or parent diene intermediate before performing the Diels-Alder reaction can be represented by the following general formulas (1-1)' and (1-2)'.
• n, Z 2 and Z 3 are the same as above. ]
• the method for producing the compound having a disulfide bond as a reversible bond represented by the general formula (3) is not particularly limited.
• a known method may be used for the compound having a disulfide bond.
• compounds having thiol groups are oxidatively bonded.
• the oxidizing agent iodine, hydrogen peroxide, etc. are generally used. It can be obtained by heating and melting or dissolving in a solvent, stirring at a temperature of room temperature to 200°C for 1 to 24 hours, and then filtering or distilling off the solvent without purification, or by recrystallization, reprecipitation, chromatography, etc. It can also be obtained by commonly used isolation and purification methods. After obtaining a hydroxyl group-containing compound as a precursor, a known method can be used to convert it into a glycidyl ether group.
• the glycidyl ether group-containing compound of the present invention can be made into a curable resin composition by using the glycidyl ether group-containing compound and a reactive compound (I) in combination.
• the curable resin composition can be suitably used for various electrical and electronic components such as adhesives, paints, photoresists, printed wiring boards, and semiconductor sealing materials.
• Examples of the compound (I) that is reactive with the glycidyl ether group-containing compound include various known compounds such as amine compounds, acid anhydrides, amide compounds, phenolic hydroxyl group-containing compounds, carboxylic acid compounds, and thiol compounds. curing agents for epoxy resins.
• the curing agent can be appropriately selected depending on the physical properties of the desired cured product, but it is particularly preferable to use a hydroxyl group-containing compound from the viewpoint of mechanical strength, adhesion to the substrate, etc.
• amine compounds examples include trimethylenediamine, ethylenediamine, N,N,N',N'-tetramethylethylenediamine, pentamethyldiethylenetriamine, triethylenediamine, dipropylenediamine, and N,N,N',N'-tetramethyldiamine.
• Aromatic amine compounds such as o-phenylenediamine, m-phenylenediamine, p-phenylenediamine, diaminodiphenylmethane, diaminodiphenylsulfone, pyridine, picoline;
• Epoxy compound addition polyamine Michael addition polyamine, Mannich addition polyamine, thiourea addition polyamine, ketone-blocked polyamine, dicyandiamide, guanidine, organic acid hydrazide, diaminomaleonitrile, amine imide, boron trifluoride-piperidine complex, boron trifluoride-mono Examples include modified amine compounds such as ethylamine complexes.
• the acid anhydrides include phthalic anhydride, trimellitic anhydride, pyromellitic anhydride, maleic anhydride, polypropylene glycol maleic anhydride, tetrahydrophthalic anhydride, methyltetrahydrophthalic anhydride, methylnadic anhydride, and hexahydrophthalic anhydride. acids, methylhexahydrophthalic anhydride, and the like.
• the phenolic hydroxyl group-containing compound includes bis(4-hydroxyphenyl)methane, 2,2-bis(4-hydroxyphenyl)propane, 2,2-bis(3-methyl-4-hydroxyphenyl)propane, Bisphenols such as 1,1-bis(4-hydroxyphenyl)cyclohexane, 1,1-bis(4-hydroxyphenyl)-1-phenylethane, and bis(4-hydroxyphenyl)sulfone, phenol novolac resin, cresol Novolak resin, aromatic hydrocarbon formaldehyde resin modified phenolic resin, dicyclopentadiene phenol addition type resin, phenol aralkyl resin (Zyrock resin), naphthol aralkyl resin, trimethylolmethane resin, tetraphenylolethane resin, naphthol novolac resin, naphthol- Phenol co-condensed novolak resin, naphthol-cresol co-condensed novolac resin, bipheny
• the amide compounds include dicyandiamide and polyamide amine.
• the polyamide amine includes, for example, aliphatic dicarboxylic acids such as succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, and azelaic acid, carboxylic acid compounds such as fatty acids and dimer acids, and aliphatic polyamines and polyoxyalkylenes. Examples include those obtained by reacting polyamines having chains.
• carboxylic acid compound examples include carboxylic acid polymers such as carboxylic acid-terminated polyester, polyacrylic acid, and maleic acid-modified polypropylene glycol.
• the thiol compound preferably contains two or more thiol groups in two molecules.
• amine compounds particularly dicyandiamide
• solid type phenolic compounds are preferred from the viewpoint of heat resistance of cured products.
• aliphatic amines and thiol compounds are preferred from the viewpoint of low temperature curing.
• the compound (I) that is reactive with the glycidyl ether group-containing compound is preferably a hydroxyl group-containing compound having a reversible bond.
• the hydroxyl group-containing compound having the reversible bond is composed of a structural unit A' having one or more hydroxyl groups and a structural unit B' different from the above A' connected by A'-B'-A', and the above-mentioned Examples include hydroxyl group-containing compounds in which the structural unit A' and the structural unit B' are bonded through a reversible bond.
• the dissociation temperature of the reversible bond is preferably 120° C. or higher, from the viewpoint of further achieving the effects of the present invention.
• reversible bond examples include those similar to the reversible bond in the glycidyl ether group-containing compound in the present invention.
• Examples of the hydroxyl group-containing compound having the reversible bond include those represented by the following formula. Among these, compounds represented by the following formulas (8-1), (8-2), and (9) are preferably used from the viewpoint of the dissociation temperature of reversible bonds.
• [Ar in formula (9) is each independently a structure containing an aromatic ring that is unsubstituted or has a substituent, and is anthracene-derived structure in formula (8-1) (8-2), -3)
• Furan-derived structures in (8-4) include halogen atoms, alkoxy groups, aralkyloxy groups, aryloxy groups, nitro groups, amide groups, alkyloxycarbonyl groups, aryloxycarbonyl groups, cyano groups, and alkyl groups. , a cycloalkyl group, an aralkyl group, or an aryl group as a substituent.
• n is an average value of the number of repetitions of 0 to 10.
• Z 5 is the following formula (10)
• Z 2 is the following formula (11)
• Z 3 is the following formula (12)
• Z 4 is any of the structures represented by the following formula (13) or (14)
• Each of the plurality of molecules in one molecule may be the same or different.
• the aromatic ring in formula (10) may be substituted or unsubstituted, and * represents a bonding point.
• the hydroxyl group on the naphthalene ring in the formula may be bonded to any position.
• Ar is each independently a structure having an aromatic ring that is unsubstituted or has a substituent
• R 1 and R 2 are each independently a hydrogen atom, a methyl group or an ethyl group
• R is a hydrogen atom or a methyl group
• R' is a divalent hydrocarbon group having 2 to 12 carbon atoms
• n1 is an integer from 2 to 16
• n2 is an average value of repeating units from 2 to 30
• k1 is the average number of repetitions and ranges from 0.5 to 10
• p1 and p2 are each independently 0 to 5
• X is a structural unit represented by the following formula (11-1)
• Y is a structural unit represented by the following formula (11-2)
• n3 and n5 are the average values of the number of repetitions, each from 0.5 to 10, n4 is an integer from 1 to 16, and R '' each independently represents hydrogen. Atom, methyl group or ethyl group.
• Examples of the above-mentioned hydroxyl group-containing compound having a reversible bond include those represented by the following structural formula.
• hydroxyl group-containing compounds correspond to intermediates (precursors) of the glycidyl ether group-containing compounds of the present invention, commercially available hydroxyl group-containing maleimide, furan, anthracene, etc. It can be obtained by using raw materials.
• the other epoxy resins include bisphenol A epoxy resin, bisphenol F epoxy resin, bisphenol S epoxy resin, bisphenol AD epoxy resin, polyhydroxybenzene epoxy resin, polyhydroxynaphthalene epoxy resin, and biphenyl epoxy resin.
• Resin liquid epoxy resin such as tetramethylbiphenyl epoxy resin, brominated epoxy resin such as brominated phenol novolak epoxy resin, solid bisphenol A epoxy resin, phenol novolac epoxy resin, cresol novolak epoxy resin, triphenylmethane type epoxy resin, tetraphenylethane type epoxy resin, dicyclopentadiene-phenol addition reaction type epoxy resin, phenol aralkyl type epoxy resin, phenylene ether type epoxy resin, naphthylene ether type epoxy resin, naphthol novolak type epoxy resin, naphthol aralkyl type epoxy resin Epoxy resins, naphthol-phenol co-condensed novolac type epoxy resins, naphthol-cresol co-condensed novolac type epoxy
• an epoxy resin having an epoxy equivalent of 100 to 10,000 g/eq in combination from the viewpoint of achieving an excellent balance between curability and crosslinking density of the resulting cured product. It is preferable to use an epoxy resin which is
• each Ar is independently a structure having an aromatic ring that is unsubstituted or has a substituent
• X' is a structural unit represented by the following formula (15-1)
• Y' is a structural unit represented by the following formula (15-2)
• R 1 and R 2 are each independently a hydrogen atom, a methyl group or an ethyl group
• R' is a divalent hydrocarbon group having 2 to 12 carbon atoms
• R 3 , R 4 , R 7 and R 8 are each independently a hydroxyl group, a glycidyl ether group or a 2-methylglycidyl ether group
• R 5 , R 6 , R 9 and R 10 are each independently a hydrogen atom or a methyl group
• n 1 is an integer from 4 to 16
• n 2 is an average value of repeating units, and is 2 to 30.
• R 11 and R 12 are each independently a glycidyl ether group or a 2-methylglycidyl ether group
• R 13 and R 14 are each independently a hydroxyl group, a glycidyl ether group or a 2-methylglycidyl ether group
• R 15 and R 16 are hydrogen atoms or methyl groups
• m3, m4, p1, p2, q are repeated average values
• m3 and m4 are each independently from 0 to 25
• m3+m4 ⁇ 1 p1 and p2 are each independently 0 to 5
• q is 0.5 to 5.
• the bond between the structural unit X' represented by the formula (15-1) and the structural unit Y' represented by the formula (15-2) may be random or block,
• the total number of structural units X and Y present in one molecule is m3 and m4, respectively.
• the epoxy resin represented by the general formula (15) may be used alone in combination to form a curable resin composition, but it is also possible to impart even more flexibility to the cured product and easily exhibit easy dismantling properties. In view of this, it is also preferable to use an epoxy resin having an epoxy equivalent of 100 to 300 g/eq.
• the above-mentioned epoxy resin that can be used in combination may have an epoxy equivalent in the range of 100 to 300 g/eq, and its structure is not limited.
• bisphenol A type epoxy resin bisphenol F type epoxy resin, bisphenol S type epoxy resin, bisphenol AD type epoxy resin, polyhydroxybenzene type epoxy resin, polyhydroxynaphthalene type epoxy resin, biphenyl type epoxy resin, tetramethylbiphenyl type epoxy resin.
• Liquid epoxy resins such as resins, brominated epoxy resins such as brominated phenol novolac type epoxy resins, solid bisphenol A type epoxy resins, phenol novolac type epoxy resins, cresol novolac type epoxy resins, triphenylmethane type epoxy resins, tetraphenylethane type epoxy resin, dicyclopentadiene-phenol addition reaction type epoxy resin, phenol aralkyl type epoxy resin, phenylene ether type epoxy resin, naphthylene ether type epoxy resin, naphthol novolak type epoxy resin, naphthol aralkyl type epoxy resin, naphthol-phenol type epoxy resin
• bisphenol A type epoxy resin bisphenol F type epoxy resin, bisphenol S type epoxy resin, bisphenol AD type epoxy resin, polyhydroxybenzene type epoxy resin, polyhydroxynaphthalene type epoxy resin, biphenyl type epoxy resin, tetramethylbiphenyl.
• liquid epoxy resins such as type epoxy resins, it is preferable to use epoxy resins having an epoxy equivalent of 100 to 300 g/eq.
• the resins it is particularly preferable to use an epoxy resin having an epoxy equivalent of 100 to 300 g/eq.
• the ratio of the epoxy resin represented by the general formula (15) and the epoxy resin having an epoxy equivalent of 100 to 300 g/eq is not particularly limited, but from the viewpoint of easy phase separation in the cured product,
• the mass ratio of the former to the latter is 97:3 to 3:97, preferably 10:90 to 90:10, particularly preferably 80:20 to 20:80.
• Phase separation in the cured product creates a sea-island structure, which achieves both adhesion and stress relaxation ability of the cured product, exhibits particularly high adhesive strength over a wide temperature range, and is suitable for molding before and after heat curing of the resin composition. It has the effect of reducing the shrinkage rate.
• the concentration of reversible bonds in the curable resin composition of the present invention is preferably 0.10 mmol/g or more based on the total mass of curable components in the curable resin composition. According to such a configuration, both the repairability and the remoldability of the cured product obtained from the curable resin composition become even better.
• the concentration of the aforementioned reversible bond is more preferably 0.10 to 3.00 mmol/g, even more preferably 0.15 to 2.00 mmol/g.
• the glycidyl ether group-containing compound of the present invention has a plurality of reversible bonds, or when the above-mentioned hydroxyl group-containing compound having a reversible bond is used as a curing agent alone or in combination with another curing agent.
• the total concentration of the reversible bonds is preferably 0.10 mmol/g or more, and 0.10 to 3.00 mmol/g based on the total mass of the curable components in the curable resin composition. More preferably, it is 0.15 to 2.00 mmol/g, and even more preferably 0.15 to 2.00 mmol/g.
• the concentration of the reversible bond can be appropriately selected depending on the glass transition temperature defined by the tan ⁇ peak top of the desired cured product measured by a dynamic viscoelastic analyzer (DMA). For example, when using the glass transition temperature as a guideline, if the glass transition temperature of the cured product is around room temperature, sufficient repairability and remoldability functions are likely to be exhibited even at the low concentration side of the preferred range. On the other hand, if the glass transition temperature of the desired cured product exceeds 100° C., the function will be more likely to be exhibited at the higher concentration side of the preferred range.
• DMA dynamic viscoelastic analyzer
• the ratio of the total glycidyl ether groups to the total active groups capable of reacting with the glycidyl ether groups in the curable resin composition of the present invention is not particularly limited, but the resulting cured product From the viewpoint of good mechanical properties, etc., the amount of active groups capable of reacting with glycidyl ether groups is preferably 0.4 to 1.5 equivalents per total equivalent of glycidyl ether groups in the resin composition. .
• the curable resin composition may contain a curing accelerator.
• a curing accelerator Various types of curing accelerators can be used, and examples thereof include urea compounds, phosphorus compounds, tertiary amines, imidazole, imidazolines, organic acid metal salts, Lewis acids, and amine complex salts.
• urea compounds particularly 3-(3,4-dichlorophenyl)-1,1-dimethylurea (DCMU) are preferred because of their excellent workability and low-temperature curability.
• DCMU 3-(3,4-dichlorophenyl)-1,1-dimethylurea
• triphenylphosphine is used as a phosphorus compound, and 1,8-diazabicyclo-[ 5.4.0]-undecene is preferred.
• Examples of the phosphorus compound include alkyl phosphines such as ethylphosphine and butylphosphine, primary phosphines such as phenylphosphine; dialkylphosphines such as dimethylphosphine and dipropylphosphine; secondary phosphines such as diphenylphosphine and methylethylphosphine; trimethyl Examples include tertiary phosphines such as phosphine, triethylphosphine, and triphenylphosphine.
• alkyl phosphines such as ethylphosphine and butylphosphine
• primary phosphines such as phenylphosphine
• dialkylphosphines such as dimethylphosphine and dipropylphosphine
• secondary phosphines such as diphenylphosphine and methylethy
• imidazole examples include imidazole, 1-methylimidazole, 2-methylimidazole, 3-methylimidazole, 4-methylimidazole, 5-methylimidazole, 1-ethylimidazole, 2-ethylimidazole, 3-ethylimidazole, 4 -ethylimidazole, 5-ethylimidazole, 1-n-propylimidazole, 2-n-propylimidazole, 1-isopropylimidazole, 2-isopropylimidazole, 1-n-butylimidazole, 2-n-butylimidazole, 1-isobutyl Imidazole, 2-isobutylimidazole, 2-undecyl-1H-imidazole, 2-heptadecyl-1H-imidazole, 1,2-dimethylimidazole, 1,3-dimethylimidazole, 2,4-dimethylimidazole, 2-ethyl
• imidazoline compound examples include 2-methylimidazoline and 2-phenylimidazoline.
• urea compounds examples include p-chlorophenyl-N,N-dimethylurea, 3-phenyl-1,1-dimethylurea, 3-(3,4-dichlorophenyl)-N,N-dimethylurea, N-( Examples include 3-chloro-4-methylphenyl)-N',N'-dimethylurea.
• curable resin composition of the present invention may be used in combination with other thermosetting resins or thermoplastic resins as long as the effects of the present invention are not impaired.
• thermosetting resins examples include cyanate ester resins, resins having a benzoxazine structure, active ester resins, vinylbenzyl compounds, acrylic compounds, and copolymers of styrene and maleic anhydride.
• the amount used is not particularly limited as long as it does not impede the effects of the present invention, but within the range of 1 to 50 parts by mass based on 100 parts by mass of the curable resin composition. It is preferable that there be.
• cyanate ester resin examples include bisphenol A type cyanate ester resin, bisphenol F type cyanate ester resin, bisphenol E type cyanate ester resin, bisphenol S type cyanate ester resin, bisphenol sulfide type cyanate ester resin, and phenylene ether type cyanate ester resin.
• naphthylene ether type cyanate ester resin biphenyl type cyanate ester resin, tetramethylbiphenyl type cyanate ester resin, polyhydroxynaphthalene type cyanate ester resin, phenol novolak type cyanate ester resin, cresol novolak type cyanate ester resin, triphenylmethane type cyanate Ester resin, tetraphenylethane type cyanate ester resin, dicyclopentadiene-phenol addition reaction type cyanate ester resin, phenol aralkyl type cyanate ester resin, naphthol novolak type cyanate ester resin, naphthol aralkyl type cyanate ester resin, naphthol-phenol condensed novolak Examples include a naphthol-cresol cocondensed novolac type cyanate ester resin, an aromatic hydrocarbon formaldehyde resin-modified phenol resin type cyanate ester resin, a biphenyl-cresol
• cyanate ester resins bisphenol A type cyanate ester resins, bisphenol F type cyanate ester resins, bisphenol E type cyanate ester resins, and polyhydroxynaphthalene type cyanate ester resins are preferred in that they yield cured products with particularly excellent heat resistance. It is preferable to use a naphthylene ether type cyanate ester resin, or a novolac type cyanate ester resin, and a dicyclopentadiene-phenol addition reaction type cyanate ester resin is preferable in that a cured product having excellent dielectric properties can be obtained.
• the resin having a benzoxazine structure there are no particular restrictions on the resin having a benzoxazine structure, but for example, the reaction product of bisphenol F, formalin, and aniline (F-a type benzoxazine resin), the reaction product of diaminodiphenylmethane, formalin, and phenol (P- d-type benzoxazine resin), reaction product of bisphenol A, formalin and aniline, reaction product of dihydroxydiphenyl ether, formalin and aniline, reaction product of diaminodiphenyl ether, formalin and phenol, dicyclopentadiene-phenol addition type resin and formalin and aniline, a reaction product of phenolphthalein, formalin and aniline, and a reaction product of diphenyl sulfide, formalin and aniline.
• F-a type benzoxazine resin the reaction product of bisphenol F, formalin, and aniline
• P- d-type benzoxazine resin the reaction product of bis
• the active ester resin is not particularly limited, but generally contains ester groups with high reactivity such as phenol esters, thiophenol esters, N-hydroxyamine esters, and esters of heterocyclic hydroxy compounds in one molecule. Compounds having two or more are preferably used.
• the active ester resin is preferably one obtained by a condensation reaction between a carboxylic acid compound and/or a thiocarboxylic acid compound and a hydroxy compound and/or a thiol compound.
• active ester resins obtained from a carboxylic acid compound or its halide and a hydroxy compound are preferred, and active ester resins obtained from a carboxylic acid compound or its halide and a phenol compound and/or a naphthol compound are preferred. More preferred.
• the carboxylic acid compound include benzoic acid, acetic acid, succinic acid, maleic acid, itaconic acid, phthalic acid, isophthalic acid, terephthalic acid, pyromellitic acid, and halides thereof.
• Phenol compounds or naphthol compounds include hydroquinone, resorcinol, bisphenol A, bisphenol F, bisphenol S, dihydroxydiphenyl ether, phenolphthalein, methylated bisphenol A, methylated bisphenol F, methylated bisphenol S, phenol, o-cresol, m -Cresol, p-cresol, catechol, ⁇ -naphthol, ⁇ -naphthol, 1,5-dihydroxynaphthalene, 1,6-dihydroxynaphthalene, 2,6-dihydroxynaphthalene, dihydroxybenzophenone, trihydroxybenzophenone, tetrahydroxybenzophenone, phloroglucin , benzenetriol, dicyclopentadiene-phenol addition type resin, etc.
• active ester resins include active ester resins containing a dicyclopentadiene-phenol addition structure, active ester resins containing a naphthalene structure, active ester resins that are acetylated phenol novolacs, and active ester resins that are benzoylated phenol novolacs. Ester resins are preferred, and among them, active ester resins containing a dicyclopentadiene-phenol addition structure and active ester resins containing a naphthalene structure are more preferred since they are excellent in improving peel strength.
• novolac resins addition polymerized resins of alicyclic diene compounds such as dicyclopentadiene and phenol compounds, modified novolac resins of phenolic hydroxyl group-containing compounds and alkoxy group-containing aromatic compounds, phenolic aralkyl resins (Zyrock resins) ), naphthol aralkyl resin, trimethylolmethane resin, tetraphenylolethane resin, biphenyl-modified phenol resin, biphenyl-modified naphthol resin, aminotriazine-modified phenol resin, and various vinyl polymers may be used in combination.
• the various novolak resins are made by combining phenolic hydroxyl group-containing compounds such as phenol, phenylphenol, resorcinol, biphenyl, bisphenols such as bisphenol A and bisphenol F, naphthol, and dihydroxynaphthalene, and aldehyde compounds with an acid catalyst.
• phenolic hydroxyl group-containing compounds such as phenol, phenylphenol, resorcinol, biphenyl, bisphenols such as bisphenol A and bisphenol F, naphthol, and dihydroxynaphthalene
• aldehyde compounds with an acid catalyst.
• examples include polymers obtained by reacting under certain conditions.
• the various vinyl polymers include polyhydroxystyrene, polystyrene, polyvinylnaphthalene, polyvinylanthracene, polyvinylcarbazole, polyindene, polyacenaphthylene, polynorbornene, polycyclodecene, polytetracyclododecene, polynortricyclene, poly( Examples include homopolymers of vinyl compounds such as meth)acrylates and copolymers thereof.
• Thermoplastic resin refers to a resin that can be melt-molded by heating. Specific examples include polyethylene resin, polypropylene resin, polystyrene resin, rubber-modified polystyrene resin, acrylonitrile-butadiene-styrene (ABS) resin, acrylonitrile-styrene (AS) resin, polymethyl methacrylate resin, acrylic resin, polyvinyl chloride resin, Polyvinylidene chloride resin, polyethylene terephthalate resin, ethylene vinyl alcohol resin, cellulose acetate resin, ionomer resin, polyacrylonitrile resin, polyamide resin, polyacetal resin, polybutylene terephthalate resin, polylactic acid resin, polyphenylene ether resin, modified polyphenylene ether resin, polycarbonate Resin, polysulfone resin, polyphenylene sulfide resin, polyetherimide resin, polyethersulfone resin, polyarylate resin, thermoplastic polyimide resin, polyamideimide resin
• the blending ratio of the glycidyl ether group-containing compound of the present invention and the other resins can be set arbitrarily depending on the application, but the repairability and remolding properties of the present invention can be set as desired.
• the proportion of other resins is preferably 0.5 to 100 parts by mass based on 100 parts by mass of the glycidyl ether group-containing compound of the present invention.
• a non-halogen flame retardant containing substantially no halogen atoms may be blended.
• non-halogen flame retardants examples include phosphorus flame retardants, nitrogen flame retardants, silicone flame retardants, inorganic flame retardants, organic metal salt flame retardants, etc., and there are no restrictions on their use. It is also possible to use a single flame retardant, a plurality of flame retardants of the same type, or a combination of flame retardants of different types.
• the phosphorus flame retardant can be either inorganic or organic.
• inorganic compounds include ammonium phosphates such as red phosphorus, monoammonium phosphate, diammonium phosphate, triammonium phosphate, and ammonium polyphosphate, and inorganic nitrogen-containing phosphorus compounds such as phosphoric acid amide. .
• the red phosphorus is subjected to a surface treatment for the purpose of preventing hydrolysis, etc.
• surface treatment methods include, for example, (i) magnesium hydroxide, aluminum hydroxide, zinc hydroxide, water A method of coating with an inorganic compound such as titanium oxide, bismuth oxide, bismuth hydroxide, bismuth nitrate, or a mixture thereof; (ii) an inorganic compound such as magnesium hydroxide, aluminum hydroxide, zinc hydroxide, titanium hydroxide; (iii) a method of coating with a mixture of thermosetting resins such as phenolic resin; (iii) a method of coating with a mixture of thermosetting resins such as phenolic resin; Examples include a method of double coating with resin.
• organic phosphorus compounds examples include general-purpose organic phosphorus compounds such as phosphoric acid ester compounds, phosphonic acid compounds, phosphinic acid compounds, phosphine oxide compounds, phosphorane compounds, organic nitrogen-containing phosphorus compounds, and 9,10-dihydrophosphorus compounds.
• the blending amount of these phosphorus-based flame retardants is appropriately selected depending on the type of phosphorus-based flame retardant, other components of the resin composition, and the desired degree of flame retardancy.
• red phosphorus is used as a non-halogen flame retardant, it is blended in the range of 0.1 parts by mass to 2.0 parts by mass in 100 parts by mass of the resin composition containing all other fillers and additives.
• organic phosphorus compound is used, it is preferably blended in a range of 0.1 parts by mass to 10.0 parts by mass, and preferably blended in a range of 0.5 parts by mass to 6.0 parts by mass. It is more preferable to do so.
• hydrotalcite, magnesium hydroxide, boron compounds, zirconium oxide, black dye, calcium carbonate, zeolite, zinc molybdate, activated carbon, etc. may be used in combination with the phosphorus-based flame retardant. good.
• nitrogen-based flame retardant examples include triazine compounds, cyanuric acid compounds, isocyanuric acid compounds, phenothiazine, etc., with triazine compounds, cyanuric acid compounds, and isocyanuric acid compounds being preferred.
• the triazine compounds include, for example, melamine, acetoguanamine, benzoguanamine, melon, melam, succinoguanamine, ethylene dimelamine, melamine polyphosphate, triguanamine, and also (1) guanylmelamine sulfate, melem sulfate, melam sulfate.
• sulfuric acid aminotriazine compounds such as (2) cocondensates of phenols such as phenol, cresol, xylenol, butylphenol, nonylphenol, and melamines such as melamine, benzoguanamine, acetoguanamine, and formguanamine, and formaldehyde; (3) the above-mentioned (2) A mixture of the co-condensate and a phenol resin such as a phenol-formaldehyde condensate; (4) a mixture of the above-mentioned (2) and (3) further modified with tung oil, isomerized linseed oil, etc., and the like.
• cyanuric acid compound examples include cyanuric acid, melamine cyanurate, and the like.
• the blending amount of the nitrogen-based flame retardant is appropriately selected depending on the type of the nitrogen-based flame retardant, other components of the resin composition, and the desired degree of flame retardancy. It is preferably blended in the range of 0.05 to 10 parts by mass, and preferably blended in the range of 0.1 to 5 parts by mass in 100 parts by mass of the resin composition containing all other fillers and additives. It is more preferable to do so.
• metal hydroxides, molybdenum compounds, etc. may be used in combination.
• the silicone flame retardant can be used without particular limitation as long as it is an organic compound containing a silicon atom, and examples include silicone oil, silicone rubber, and silicone resin.
• the amount of the silicone flame retardant to be blended is appropriately selected depending on the type of silicone flame retardant, other components of the resin composition, and the desired degree of flame retardancy. It is preferable to blend the filler and other fillers and additives in an amount of 0.05 to 20 parts by mass in 100 parts by mass of the resin composition.
• a molybdenum compound, alumina, etc. may be used in combination.
• inorganic flame retardant examples include metal hydroxides, metal oxides, metal carbonate compounds, metal powders, boron compounds, and low-melting glass.
• metal hydroxide examples include aluminum hydroxide, magnesium hydroxide, dolomite, hydrotalcite, calcium hydroxide, barium hydroxide, and zirconium hydroxide.
• the metal oxides include, for example, zinc molybdate, molybdenum trioxide, zinc stannate, tin oxide, aluminum oxide, iron oxide, titanium oxide, manganese oxide, zirconium oxide, zinc oxide, molybdenum oxide, cobalt oxide, bismuth oxide, Examples include chromium oxide, nickel oxide, copper oxide, and tungsten oxide.
• metal carbonate compounds examples include zinc carbonate, magnesium carbonate, calcium carbonate, barium carbonate, basic magnesium carbonate, aluminum carbonate, iron carbonate, cobalt carbonate, titanium carbonate, and the like.
• metal powder examples include aluminum, iron, titanium, manganese, zinc, molybdenum, cobalt, bismuth, chromium, nickel, copper, tungsten, and tin.
• Examples of the boron compound include zinc borate, zinc metaborate, barium metaborate, boric acid, and borax.
• low melting point glass examples include Sheeply (BOXI BROWN), hydrated glass SiO 2 -MgO-H 2 O, PbO-B 2 O 3- based, ZnO-P 2 O 5 -MgO-based, P 2 O 5 Glassy compounds such as -B 2 O 3 -PbO-MgO series, P-Sn-O-F series, PbO-V 2 O 5 -TeO 2 series, Al 2 O 3 -H 2 O series, lead borosilicate series, etc. can be mentioned.
• the amount of the inorganic flame retardant to be blended is appropriately selected depending on the type of the inorganic flame retardant, other components of the resin composition, and the desired degree of flame retardancy. It is preferably blended in the range of 0.05 parts by mass to 20 parts by mass, and preferably in the range of 0.5 parts by mass to 15 parts by mass, in 100 parts by mass of the resin composition containing all other fillers and additives. It is more preferable to mix it with
• the organic metal salt flame retardant is, for example, ferrocene, an acetylacetonate metal complex, an organic metal carbonyl compound, an organic cobalt salt compound, an organic sulfonic acid metal salt, a metal atom and an aromatic compound or a heterocyclic compound having an ionic bond or an arrangement. Examples include compounds with position bonding.
• the amount of the organic metal salt flame retardant to be blended is appropriately selected depending on the type of the organic metal salt flame retardant, other components of the resin composition, and the desired degree of flame retardancy. It is preferably blended in an amount of 0.005 parts by mass to 10 parts by mass in 100 parts by mass of the resin composition containing all the halogenated flame retardants and other fillers and additives.
• the curable resin composition of the present invention may contain a filler.
• fillers include inorganic fillers and organic fillers.
• examples of the inorganic filler include inorganic fine particles.
• Examples of inorganic fine particles with excellent heat resistance include alumina, magnesia, titania, zirconia, silica (quartz, fumed silica, precipitated silica, silicic anhydride, fused silica, crystalline silica, ultrafine amorphous powder)
• Examples of materials with excellent thermal conductivity include boron nitride, aluminum nitride, alumina oxide, titanium oxide, magnesium oxide, zinc oxide, silicon oxide, diamond, etc.
• materials with excellent conductivity include single metals or alloys ( For example, metal fillers and/or metal-coated fillers using iron, copper, magnesium, aluminum, gold, silver, platinum, zinc, manganese, stainless steel, etc.
• Examples of materials with excellent barrier properties include mica, clay, kaolin, Minerals such as talc, zeolite, wollastonite, smectite, potassium titanate, magnesium sulfate, sepiolite, zonolite, aluminum borate, calcium carbonate
• silica fine particles such as powdered silica and colloidal silica
• known silica fine particles such as powdered silica and colloidal silica
• powdered silica fine particles include Aerosil 50 and 200 manufactured by Nippon Aerosil Co., Ltd., Sildex H31, H32, H51, H52, H121, and H122 manufactured by Asahi Glass Co., Ltd., and E220A manufactured by Nippon Silica Kogyo Co., Ltd. , E220, SYLYSIA470 manufactured by Fuji Silysia Co., Ltd., and SG flake manufactured by Nippon Sheet Glass Co., Ltd., and the like.
• colloidal silica includes, for example, methanol silica sol manufactured by Nissan Chemical Industries, Ltd., IPA-ST, MEK-ST, NBA-ST, XBA-ST, DMAC-ST, ST-UP, ST-OUP, Examples include ST-20, ST-40, ST-C, ST-N, ST-O, ST-50, ST-OL, and the like.
• silica fine particles may be used; for example, the silica fine particles may be surface-treated with a reactive silane coupling agent having a hydrophobic group, or modified with a compound having a (meth)acryloyl group.
• a reactive silane coupling agent having a hydrophobic group or modified with a compound having a (meth)acryloyl group.
• Examples of commercially available powdered silica modified with a compound having a (meth)acryloyl group include Aerosil RM50 and R711 manufactured by Nippon Aerosil Co., Ltd.; commercially available colloidal silica modified with a compound having a (meth)acryloyl group include: Examples include MIBK-SD manufactured by Nissan Chemical Industries, Ltd.
• the shape of the silica fine particles is not particularly limited, and spherical, hollow, porous, rod-like, plate-like, fibrous, or irregularly shaped particles can be used. Further, the primary particle diameter is preferably in the range of 5 to 200 nm.
• titanium oxide fine particles not only extender pigments but also ultraviolet light-responsive photocatalysts can be used, such as anatase-type titanium oxide, rutile-type titanium oxide, brookite-type titanium oxide, etc. Furthermore, particles designed to respond to visible light by doping a different element into the crystal structure of titanium oxide can also be used.
• the element to be doped into titanium oxide anion elements such as nitrogen, sulfur, carbon, fluorine, and phosphorus, and cation elements such as chromium, iron, cobalt, and manganese are suitably used.
• a powder, a sol or a slurry dispersed in an organic solvent or water can be used.
• Examples of commercially available powdered titanium oxide fine particles include Aerosil P-25 manufactured by Nippon Aerosil Co., Ltd. and ATM-100 manufactured by Teika Co., Ltd. Furthermore, examples of commercially available titanium oxide fine particles in the form of slurry include TKD-701 manufactured by Teika Corporation.
• the curable resin composition of the present invention may further contain a fibrous matrix.
• the fibrous substrate is not particularly limited, but it is preferably one used for fiber reinforced resins, including inorganic fibers and organic fibers.
• Inorganic fibers include inorganic fibers such as carbon fiber, glass fiber, boron fiber, alumina fiber, and silicon carbide fiber, as well as carbon fiber, activated carbon fiber, graphite fiber, tungsten carbide fiber, silicon carbide fiber (silicon carbide fiber), and ceramics.
• Examples include fibers, natural fibers, mineral fibers such as basalt, boron nitride fibers, boron carbide fibers, and metal fibers.
• the metal fibers include aluminum fibers, copper fibers, brass fibers, stainless steel fibers, and steel fibers.
• Organic fibers include synthetic fibers made of resin materials such as polybenzazole, aramid, PBO (polyparaphenylenebenzoxazole), polyphenylene sulfide, polyester, acrylic, polyamide, polyolefin, polyvinyl alcohol, polyarylate, cellulose, pulp, Examples include natural fibers such as cotton, wool, and silk, and regenerated fibers such as proteins, polypeptides, and alginic acid.
• resin materials such as polybenzazole, aramid, PBO (polyparaphenylenebenzoxazole), polyphenylene sulfide, polyester, acrylic, polyamide, polyolefin, polyvinyl alcohol, polyarylate, cellulose, pulp, Examples include natural fibers such as cotton, wool, and silk, and regenerated fibers such as proteins, polypeptides, and alginic acid.
• carbon fibers and glass fibers are preferred because they have a wide range of industrial applications. Among these, only one type may be used, or a plurality of types may be used simultaneously.
• the fibrous substrate may be an aggregate of fibers, and the fibers may be continuous or discontinuous, and may be woven or nonwoven. Further, it may be a fiber bundle in which the fibers are aligned in one direction, or it may be in the form of a sheet in which the fiber bundles are arranged. Alternatively, the fiber aggregate may have a three-dimensional shape with a thickness.
• a dispersion medium may be used in the curable resin composition of the present invention for the purpose of adjusting the solid content and viscosity of the resin composition.
• the dispersion medium may be any liquid medium that does not impair the effects of the present invention, and includes various organic solvents, liquid organic polymers, and the like.
• organic solvent examples include ketones such as acetone, methyl ethyl ketone (MEK), and methyl isobutyl ketone (MIBK), cyclic ethers such as tetrahydrofuran (THF), and dioxolane, and esters such as methyl acetate, ethyl acetate, and butyl acetate.
• ketones such as acetone, methyl ethyl ketone (MEK), and methyl isobutyl ketone (MIBK)
• cyclic ethers such as tetrahydrofuran (THF)
• dioxolane examples of the organic solvent
• esters such as methyl acetate, ethyl acetate, and butyl acetate.
• aromatics such as toluene and xylene
• alcohols such as carbitol, cellosolve, methanol, isopropanol, butanol, and propylene glycol monomethyl ether.
• the liquid organic polymer is a liquid organic polymer that does not directly contribute to the curing reaction, such as acrylic polymer (Floren WK-20: Kyoeisha), amine salt of specially modified phosphoric acid ester (HIPLAAD ED-251: Kusumoto Kasei), modified Examples include acrylic block copolymers (DISPERBYK2000; BYK Chemie).
• the resin composition of the present invention may contain other ingredients.
• catalysts polymerization initiators, inorganic pigments, organic pigments, extender pigments, clay minerals, waxes, surfactants, stabilizers, flow regulators, coupling agents, dyes, leveling agents, rheology control agents, ultraviolet absorbers, Examples include antioxidants, flame retardants, plasticizers, and reactive diluents.
• a cured product can be obtained by curing the resin composition of the present invention.
• curing may be performed at room temperature or by heating.
• thermal curing it may be cured by one heating process or may be cured through a multi-step heating process.
• the curable resin composition of the present invention can also be cured with active energy rays.
• a photocationic polymerization initiator may be used as the polymerization initiator.
• the active energy ray visible light, ultraviolet rays, X-rays, electron beams, etc. can be used.
• photocationic polymerization initiator examples include aryl-sulfonium salts, aryl-iodonium salts, etc. Specifically, arylsulfonium hexafluorophosphate, arylsulfonium hexafluoroantimonate, arylsulfonium tetrakis(pentafluoro)borate , tri(alkylphenyl)sulfonium hexafluorophosphate, etc. can be used.
• the photocationic polymerization initiators may be used alone or in combination of two or more.
• the curable resin composition of the present invention can be prepared by uniformly mixing the above-mentioned components, and the method is not particularly limited.
• it can be prepared by uniformly mixing using a pot mill, ball mill, bead mill, roll mill, homogenizer, super mill, homodisper, all-purpose mixer, Banbury mixer, kneader, or the like.
• the curable resin composition of the present invention comprises the above-described glycidyl ether group-containing compound of the present invention and a compound (I) that is reactive with the glycidyl ether group-containing compound, and if necessary, the above-mentioned curing agent that can be used in combination.
• the filler, fibrous matrix, dispersion medium, and resin other than the various compounds described above are dissolved in a dispersion medium such as the organic solvent described above. After dissolution, a curable resin composition can be obtained by distilling off the solvent and drying under reduced pressure using a vacuum oven or the like. Further, the curable resin composition of the present invention may be in a state in which the above-mentioned constituent materials are uniformly mixed.
• each constituent material can be adjusted as appropriate depending on the desired properties of the cured product, such as mechanical strength, heat resistance, repairability, and remoldability. Further, in preparing the curable resin composition, there are no particular limitations on the order in which the specific constituent materials are mixed.
• the cured product of the present invention is obtained by curing the compound (I) that is reactive with the glycidyl ether group-containing compound using the glycidyl ether group-containing compound of the present invention.
• a known method can be appropriately selected and employed depending on the properties of the compound (I) that is reactive with the glycidyl ether group-containing compound used.
• the cured product of the present invention is cured with the glycidyl ether group-containing compound of the present invention as described above, it is possible to maintain good mechanical strength by developing an appropriate crosslink density. Furthermore, when the cured product of the present invention is scratched or subjected to mechanical energy such as an external force, the reversible bond is broken, but the equilibrium shifts in the bonding direction, so that an adduct is formed again, which can be used to repair scratches or It is thought that remolding becomes possible.
• the structure of the obtained cured product can be confirmed by infrared absorption (IR) spectroscopy using Fourier transform infrared spectroscopy (FT-IR), elemental analysis, X-ray scattering, etc.
• IR infrared absorption
• FT-IR Fourier transform infrared spectroscopy
• elemental analysis X-ray scattering, etc.
• the cured product that is an embodiment of the present invention can be obtained by using the glycidyl ether group-containing compound of the present invention as a component of a curable resin composition.
• the glycidyl ether group-containing compound is formed during the curing process. It is also possible to produce a cured product while (synthesizing in situ).
• a compound represented by the formula (1-1)', maleimide having a glycidyl ether group, and a compound (I) having reactivity with the glycidyl ether group-containing compound are used as essential raw materials.
• a glycidyl ether group-containing compound represented by the above formula (1-1) can be obtained in the course of the curing reaction, and as the curing reaction progresses, a cured product can be obtained.
• the maleimide having a glycidyl ether group that can be used at this time is the same as described above.
• the curable resin composition of the present invention and the cured product produced from the curable resin composition have excellent both heat resistance and repairability, and have remoldability, and are useful for the following uses. .
• the cured resin of the present invention can be laminated with a base material to form a laminate.
• the base material for the laminate may be an inorganic material such as metal or glass, or an organic material such as plastic or wood, depending on the purpose, and may be in the form of a laminate, such as a flat plate, sheet, or tertiary It may have an original structure or may be three-dimensional. It may have any shape depending on the purpose, such as having curvature on the entire surface or in part. Furthermore, there are no restrictions on the hardness, thickness, etc. of the base material. Alternatively, it may be a multilayer laminate in which the first base material, a layer made of a cured product of the curable resin composition of the present invention, and the second base material are laminated in this order.
• the curable resin composition of this embodiment has excellent adhesive properties, it can be suitably used as an adhesive for bonding a first base material and a second base material. Further, the cured resin of the present invention may be used as a base material, and the cured product of the present invention may be further laminated.
• the cured resin of the present invention can relieve stress, it can be particularly suitably used for bonding different materials.
• the base material is a metal and/or metal oxide and the second base material is a laminate of different materials such as a plastic layer, the adhesive strength will be improved due to the stress relaxation ability of the cured product of the present invention. maintained.
• the layer containing the cured product may be formed by direct coating or molding on the base material, or may be formed by laminating already molded products.
• direct coating there are no particular limitations on the coating method, including spray method, spin coating method, dip method, roll coating method, blade coating method, doctor roll method, doctor blade method, curtain coating method, slit coating method, Examples include screen printing method, inkjet method, and the like.
• direct molding examples include in-mold molding, insert molding, vacuum molding, extrusion lamination molding, press molding, and the like.
• uncured or semi-cured composition layers may be laminated and then cured, or a layer containing a completely cured composition may be laminated on the base material. It's okay.
• the cured product of the present invention may be laminated by coating and curing a precursor that can serve as a base material, or if the precursor that can serve as a base material or the composition of the present invention is uncured or semi-cured. It may be hardened after adhering in this state.
• the precursor that can serve as the base material and examples include various curable resin compositions.
• the cured product obtained using the curable resin composition of the present invention has particularly high adhesion to metals and/or metal oxides, so it can be used particularly well as a primer for metals.
• metals include copper, aluminum, gold, silver, iron, platinum, chromium, nickel, tin, titanium, zinc, various alloys, and composite materials of these metals
• metal oxides include single oxides and materials of these metals. /or composite oxides. In particular, it has excellent adhesive strength to iron, copper, and aluminum, so it can be used satisfactorily as an adhesive for iron, copper, and aluminum.
• the curable resin composition of the present invention can be suitably used as an adhesive for structural members in the fields of automobiles, trains, civil engineering and construction, electronics, aircraft, and space industries. Even when the adhesive is used to bond different materials, such as between metal and non-metal, it can maintain high adhesion without being affected by changes in temperature environment, and is unlikely to peel off.
• the adhesive can also be used for general office use, medical use, carbon fiber, storage battery cells, modules, and cases, as well as adhesive for joining optical parts and bonding optical discs. adhesives for semiconductors such as adhesives for mounting printed wiring boards, die bonding adhesives, underfills, underfills for BGA reinforcement, anisotropic conductive films, anisotropic conductive pastes, etc. It can be used as an agent.
• the curable resin composition of the present invention has a fibrous matrix and the fibrous matrix is a reinforcing fiber
• the curable resin composition containing the fibrous matrix can be used as a fiber-reinforced resin.
• the method for incorporating the fibrous matrix into the composition is not particularly limited as long as it does not impair the effects of the present invention, and methods such as kneading, coating, impregnating, injecting, and pressing the fibrous matrix and the composition may be used. The method can be selected depending on the form of the fiber and the use of the fiber-reinforced resin.
• the method for molding the fiber reinforced resin is not particularly limited. If a plate-shaped product is to be manufactured, extrusion molding is generally used, but flat pressing is also possible. In addition, extrusion molding, blow molding, compression molding, vacuum molding, injection molding, and the like can be used. If a film-shaped product is to be manufactured, a solution casting method can be used in addition to the melt extrusion method, and when using the melt molding method, there are blown film molding, cast molding, extrusion lamination molding, calendar molding, and sheet molding. , fiber molding, blow molding, injection molding, rotational molding, coating molding, etc. Further, in the case of a resin that is cured by active energy rays, a cured product can be produced using various curing methods using active energy rays.
• thermosetting resin is the main component of the matrix resin
• thermosetting resin is the main component of the matrix resin
• thermosetting resin there is a molding method in which the molding material is made into prepreg and heated under pressure in a press or autoclave.
• RTM Resin Transfer Molding
• examples include VaRTM (Vacuum Assist Resin Transfer Molding) molding, lamination molding, hand lay-up molding, and the like.
• the curable resin composition of the present invention has good heat resistance and repairability as well as remoldability, so it can be used in large cases, motor housings, and inside cases. It can be used as a casting material and a molding material for gears, pulleys, etc. These may be cured products of resin alone or fiber-reinforced cured products such as glass chips.
• the fiber-reinforced resin can form an uncured or semi-cured prepreg. After distributing the product in the prepreg state, final curing may be performed to form a cured product. When forming a laminate, it is preferable to form a prepreg, laminate other layers, and then perform final curing, since it is possible to form a laminate in which each layer is in close contact with each other.
• the mass ratio of the composition and the fibrous substrate used at this time is not particularly limited, but it is usually preferable to prepare the prepreg so that the resin content is 20 to 60% by mass.
• the cured product of the present invention has good heat resistance and repairability, and has remoldability, and can be used as a heat-resistant material and an electronic material.
• it can be suitably used for semiconductor sealing materials, circuit boards, build-up films, build-up substrates, adhesives, and resist materials.
• It can also be suitably used as a matrix resin for fiber-reinforced resins, and is particularly suitable as a highly heat-resistant prepreg.
• the heat-resistant components and electronic components thus obtained can be suitably used for various purposes, such as industrial mechanical parts, general mechanical parts, automobile/railway/vehicle parts, space/aviation related parts, electronic/electrical parts, etc. Examples include, but are not limited to, building materials, containers/packaging members, household goods, sports/leisure goods, wind power generation casing members, etc.
• the adhesive of the present invention can be suitably used as an adhesive for structural members in the fields of automobiles, trains, civil engineering, architecture, electronics, aircraft, and the space industry. Even when the adhesive of the present invention is used to bond dissimilar materials, such as between metal and non-metal, it can maintain high adhesion without being affected by changes in temperature environment, and does not cause peeling or the like. hard.
• the adhesive of the present invention can also be used as an adhesive for general office, medical, carbon fiber, storage battery cells, modules, and cases, and as an adhesive for bonding optical parts and optical discs.
• Mounting adhesives for bonding adhesives for mounting, adhesives for mounting printed wiring boards, die bonding adhesives, semiconductor adhesives such as underfill, underfill for reinforcing BGA, anisotropic conductive films, anisotropic conductive pastes, etc. Examples include adhesives for
• the resin composition and compounding agents such as a curing accelerator and an inorganic filler are mixed in an extruder, a kneader, etc. as necessary. Examples include a method of sufficiently melting and mixing using a roller, roller, etc. until the mixture becomes uniform.
• fused silica is usually used as the inorganic filler, but when used as a highly thermally conductive semiconductor encapsulant for power transistors and power ICs, crystalline silica, alumina, nitride, etc., which have higher thermal conductivity than fused silica, It is preferable to use highly filled silicon or the like, or use fused silica, crystalline silica, alumina, silicon nitride, or the like.
• the filling rate is preferably 30 to 95% by mass of the inorganic filler per 100 parts by mass of the curable resin composition. In order to reduce the amount, the amount is more preferably 70 parts by mass or more, and even more preferably 80 parts by mass or more.
• the semiconductor encapsulating material is molded using a casting, transfer molding machine, injection molding machine, etc., and then heated at 50 to 250°C. A method of heating for 2 to 10 hours is mentioned.
• Printed circuit board A method for obtaining a printed circuit board from the composition of the present invention is to laminate the prepregs described above by a conventional method, overlay copper foil as appropriate, and then under a pressure of 1 to 10 MPa at 170 to 300°C for 10 minutes to A method of heat-pressing for 3 hours may be mentioned.
• a method for manufacturing a flexible board from the crosslinkable resin composition of the present invention includes a method comprising the following three steps.
• the first step is a step of applying a crosslinkable resin composition containing a resin component, an organic solvent, etc. to an electrically insulating film using a coating machine such as a reverse roll coater or a comma coater.
• a coating machine such as a reverse roll coater or a comma coater.
• the electrically insulating film coated with the crosslinkable resin composition is heated at 60 to 170°C for 1 to 15 minutes using a heating machine, and the solvent is evaporated from the electrically insulating film.
• the third step is to B-stage the composition, and the third step is to heat the adhesive with metal foil using a heating roll or the like on the electrically insulating film in which the crosslinkable resin composition has been B-staged.
• This is a step of crimping (the crimping pressure is preferably 2 to 200 N/cm, and the crimping temperature is preferably 40 to 200°C). If sufficient adhesion performance is obtained by going through the above three steps, you can finish the process here, but if complete adhesion performance is required, an additional 1 to 24 hours at 100 to 200°C is required. It is preferable to post-cure with.
• the thickness of the resin composition layer after final curing is preferably in the range of 5 to 100 ⁇ m.
• a method for obtaining a buildup substrate from the composition of the present invention includes, for example, the following steps. First, the above-mentioned composition containing rubber, filler, etc. as appropriate is applied to a circuit board on which a circuit is formed using a spray coating method, a curtain coating method, etc., and then cured (step 1). After that, after drilling a predetermined through-hole section as necessary, the surface is treated with a roughening agent, and the surface is washed with hot water to form unevenness, and the process of plating metal such as copper (process 2). A step (step 3) of repeatedly repeating such operations as desired to alternately build up and form a resin insulating layer and a conductor layer of a predetermined circuit pattern.
• the through-hole portions are formed after the outermost resin insulating layer is formed.
• the build-up board of the present invention is produced by heat-pressing a resin-coated copper foil obtained by semi-curing the resin composition on the copper foil at 170 to 300°C onto a wiring board on which a circuit is formed. It is also possible to fabricate a build-up board by omitting the steps of forming a chemical surface and plating.
• a method for obtaining a build-up film from the composition of the present invention is to apply the above-mentioned composition onto the surface of the support film (Y) as a base material, and then apply an organic solvent by heating or blowing hot air. It can be manufactured by drying to form the layer (X) of the composition.
• organic solvent used here examples include ketones such as acetone, methyl ethyl ketone, and cyclohexanone, acetic acid esters such as ethyl acetate, butyl acetate, cellosolve acetate, propylene glycol monomethyl ether acetate, and carbitol acetate, cellosolve, butyl carbitol, and the like. It is preferable to use carbitols, aromatic hydrocarbons such as toluene and xylene, dimethylformamide, dimethylacetamide, N-methylpyrrolidone, etc., and it is preferable to use them in a proportion such that the nonvolatile content is 30 to 60% by mass. preferable.
• ketones such as acetone, methyl ethyl ketone, and cyclohexanone
• acetic acid esters such as ethyl acetate, butyl acetate, cellosolve acetate, propylene glyco
• the thickness of the layer (X) to be formed is usually greater than or equal to the thickness of the conductor layer. Since the thickness of a conductor layer included in a circuit board is usually in the range of 5 to 70 ⁇ m, the thickness of the resin composition layer is preferably in the range of 10 to 100 ⁇ m.
• the layer (X) of the said composition in this invention may be protected with the protective film mentioned later. By protecting with a protective film, it is possible to prevent dust and the like from adhering to the surface of the resin composition layer and from scratching it.
• the support film and protective film described above are made of polyolefins such as polyethylene, polypropylene, and polyvinyl chloride, polyesters such as polyethylene terephthalate (hereinafter sometimes abbreviated as "PET"), polyethylene naphthalate, polycarbonate, polyimide, and even release materials. Examples include paper patterns and metal foils such as copper foil and aluminum foil. Note that the support film and the protective film may be subjected to a release treatment in addition to a matte treatment and a corona treatment.
• the thickness of the support film is not particularly limited, but is usually 10 to 150 ⁇ m, preferably 25 to 50 ⁇ m. Further, the thickness of the protective film is preferably 1 to 40 ⁇ m.
• the support film (Y) described above is peeled off after being laminated onto the circuit board or after forming an insulating layer by heating and curing. If the support film (Y) is peeled off after the curable resin composition layer constituting the build-up film is cured by heating, it is possible to prevent dust and the like from adhering during the curing process. When peeling is performed after curing, the support film is usually subjected to a release treatment in advance.
• a multilayer printed circuit board can be manufactured using the build-up film obtained as described above.
• the layer (X) is protected by a protective film, after peeling off these layers, the layer (X) is laminated on one or both sides of the circuit board so as to be in direct contact with the circuit board, for example, by a vacuum laminating method.
• the lamination method may be a batch method or a continuous method using rolls.
• the build-up film and the circuit board may be heated (preheated) before lamination.
• the pressure bonding temperature (laminate temperature) is 70 to 140°C, and the pressure bonding is 1 to 11 kgf/cm2 (9.8 ⁇ 10 4 to 107.9 ⁇ 10 4 N/m 2 ). It is preferable to laminate under reduced air pressure of 20 mmHg (26.7 hPa) or less.
• Conductive Paste A method for obtaining a conductive paste from the composition of the present invention includes, for example, a method of dispersing conductive particles in the composition.
• the above-mentioned conductive paste can be made into a paste resin composition for circuit connection or an anisotropic conductive adhesive depending on the type of conductive particles used.
• GPC “HLC-8320GPC” manufactured by Tosoh Corporation Column: Tosoh Corporation "TSK-GEL G2000HXL” + “TSK-GEL G3000HXL” + “TSK-GEL G4000HXL” Detector: RI (differential refractometer) Measurement conditions: 40°C Mobile phase: Tetrahydrofuran Flow rate: 1ml/min Standard: "PStQuick A", "PStQuick B", “PStQuick E”, "PStQuick F” manufactured by Tosoh Corporation
• the epoxy equivalent of the synthesized epoxy resin was measured in accordance with JIS K7236, and the epoxy equivalent (g/eq) was calculated.
• Examples of methods for calculating the number of repeating units include GPC molecular weight measurement and calculation from the results of various appropriate instrumental analyzes such as FD-MS and NMR.
• Synthesis example 1 A flask equipped with a thermometer and a stirrer was charged with 151 g (1.0 mol) of 4-hydroxyacetanilide, 300 g of acetone, and 166 g (1.2 mol) of potassium carbonate, and the temperature was raised to the reflux temperature. Thereafter, 144 g (1.2 mol) of allyl bromide was added dropwise, and the reaction was further continued for 7 hours. After cooling to room temperature, potassium carbonate was removed by filtration, and acetone and excess allyl bromide in the filtrate were distilled off under reduced pressure using an evaporator.
• the obtained solid was dissolved in 222 g of ethanol, 417 g (4.0 mol) of a 35% aqueous hydrochloric acid solution was added dropwise, and the mixture was reacted at 60 to 65° C. for 12 hours. After cooling to room temperature, the mixture was neutralized with 880 g (4.4 mol) of 20% aqueous sodium hydroxide solution, and liquid separation was performed three times with 373 g of ethyl acetate. After dehydrating the organic layer over sodium sulfate, ethyl acetate was distilled off under reduced pressure using an evaporator to obtain 113 g (0.76 mol, yield 76%) of 4-allyloxyaniline.
• Synthesis example 2 In a flask equipped with a thermometer and a stirrer, 445 g (0.5 mol) of diglycidyl ether of polytetramethylene glycol ("Denacol EX-991L" manufactured by Nagase ChemteX: epoxy equivalent 445 g/eq) and bisphenol A (hydroxyl equivalent After adding 76 g (0.33 mol) of 114 g/eq) and raising the temperature to 140° C. over 30 minutes, 2.6 g of 4% aqueous sodium hydroxide solution was added. Thereafter, the temperature was raised to 150°C over 30 minutes, and the reaction was further carried out at 150°C for 7 hours.
• diglycidyl ether of polytetramethylene glycol (“Denacol EX-991L” manufactured by Nagase ChemteX: epoxy equivalent 445 g/eq) and bisphenol A (hydroxyl equivalent
• Synthesis example 3 In a flask equipped with a thermometer, dropping funnel, cooling tube, and stirrer, 38.8 g (0.20 mol) of 9-anthrone was added to 180 ml of dimethylacetamide while immersed in an ice water bath under a nitrogen atmosphere to form a slurry. 110 g (0.22 mol) of 8.09% aqueous sodium hydroxide solution was added. Then, 27.7 g (0.20 mol) of epibromohydrin dissolved in 40 ml of dimethylacetamide was added dropwise.
• Example 2 12.5 g (0.05 mol) of 9-(2-glycidyloxy)anthracene obtained in Synthesis Example 3 and 1,6'-bismaleimide-(2 , 2,4-trimethyl)hexane (BMI-THM manufactured by Daiwa Chemical Industries, Ltd.) 6.6 g (0.02 mol), 62.5 g of methyl isobutyl ketone, and 62.5 g of toluene were charged, and after purging with nitrogen, the mixture was heated at 100°C. The reaction was allowed to proceed for 7 hours. Thereafter, the precipitate was removed by filtration, and the organic solvent in the filtrate was distilled off under reduced pressure at 50°C. Subsequently, drying was performed under reduced pressure at 80° C.
• BMI-THM 1,6'-bismaleimide-(2 , 2,4-trimethyl)hexane
• Example 3 6.6 g (0.02 mol) of 1,6'-bismaleimide-(2,2,4-trimethyl)hexane (BMI-THM, manufactured by Daiwa Kasei Kogyo Co., Ltd.) was mixed with 4,4'-diphenylmethane bismaleimide (manufactured by Daiwa Kasei Co., Ltd., BMI-THM). The reaction was carried out in the same manner as in Example 2, except that 7.4 g (0.02 mol) of BMI-1000 (manufactured by Kogyo Co., Ltd.) was used, and 34.3 g of Diels-Alder reaction product (D-3) was obtained.
• BMI-THM 1,6'-bismaleimide-(2,2,4-trimethyl)hexane
• BMI-THM 4,4'-diphenylmethane bismaleimide
• the epoxy equivalent of the obtained Diels-Alder reaction product (D-3) was 495 g/eq.
• Example 4 In a flask equipped with a thermometer, a stirrer, and a cooling tube, 26.4 g (0.1 mol) of the anthracene modified product (A-3) obtained in Synthesis Example 4, 1,6'-bismaleimide-(2, 15.9 g (0.05 mol) of 2,4-trimethyl)hexane (BMI-THM manufactured by Daiwa Kasei Kogyo Co., Ltd.) and 169.4 g of methyl isobutyl ketone were charged, and after purging with nitrogen, the mixture was reacted at 110° C. for 7 hours.
• BMI-THM 2,4-trimethyl)hexane
• Synthesis example 5 According to a previous report (Polymer, 82, 319 (2016)), a disulfide bond-containing epoxy resin (S-1) having the following structure was synthesized.
• Synthesis example 6 In a flask equipped with a thermometer and a stirrer, 445 g (0.5 mol) of diglycidyl ether of polytetramethylene glycol ("Denacol EX-991L" manufactured by Nagase ChemteX: epoxy equivalent 445 g/eq) and 4,4'- 190 g (0.76 mol) of dihydroxydiphenyl disulfide (hydroxyl equivalent: 125 g/eq) was added, the temperature was raised to 140° C. over 30 minutes, and then 3.2 g of a 4% aqueous sodium hydroxide solution was added. Thereafter, the temperature was raised to 150°C over 30 minutes, and the reaction was further carried out at 150°C for 5 hours.
• diglycidyl ether of polytetramethylene glycol (“Denacol EX-991L" manufactured by Nagase ChemteX: epoxy equivalent 445 g/eq)
• a neutralizing amount of sodium phosphate was added to obtain 635 g of a hydroxy compound (S-2) represented by the following formula.
• the hydroxyl equivalent of this hydroxy compound (S-2) calculated by GPC was 750 g/eq, the average value of n 1 was 10.6, and the average value of m 1 was 1.09.
• Example 5 In a flask equipped with a thermometer, dropping funnel, condenser, and stirrer, while purging with nitrogen gas, 37.5 g (0.025 mol) of the hydroxy compound (S-2) obtained in Synthesis Example 6, 750 mL of DMF, and carbonic acid were added. 69 g (0.5 mol) of potassium and 69 g (0.5 mol) of epibromohydrin were added and dissolved. After raising the temperature to 60°C, stirring was continued for 20 hours. The mixture was cooled to room temperature, potassium carbonate was removed by filtration, and 1000 g each of water and chloroform were added to perform three liquid separations.
• Synthesis example 7 In a flask equipped with a thermometer and a stirrer, 210 g (0.5 mol) of diglycidyl ether of 1,12-dodecanediol (manufactured by Yokkaichi Gosei Co., Ltd.: epoxy equivalent 210 g/eq) and 4,4'-dihydroxydiphenyl disulfide were added. (hydroxyl equivalent: 125 g/eq) (145 g (0.58 mol)) was added, the temperature was raised to 140° C. over 30 minutes, and then 3.6 g of a 4% aqueous sodium hydroxide solution was added.
• Example 6 In a flask equipped with a thermometer, a dropping funnel, a cooling tube, and a stirrer, while purging with nitrogen gas, 53.8 g (0.025 mol) of the hydroxy compound (S-4) obtained in Synthesis Example 7, 750 mL of DMF, and carbonic acid were added. 69 g (0.5 mol) of potassium and 69 g (0.5 mol) of epibromohydrin were added and dissolved. After raising the temperature to 60°C, stirring was continued for 20 hours. The mixture was cooled to room temperature, potassium carbonate was removed by filtration, and 1000 g each of water and chloroform were added to perform three liquid separations.
• an epoxy compound (S-5) represented by the following structural formula.
• Synthesis example 8 In a flask equipped with a thermometer and a stirrer, 445 g (0.5 mol) of diglycidyl ether of polytetramethylene glycol ("Denacol EX-991L" manufactured by Nagase ChemteX: epoxy equivalent 445 g/eq) and bisphenol A (hydroxyl equivalent After adding 171 g (0.75 mol) of 114 g/eq) and raising the temperature to 140° C. over 30 minutes, 3.1 g of 4% aqueous sodium hydroxide solution was added. Thereafter, the temperature was raised to 150°C over 30 minutes, and the reaction was further carried out at 150°C for 16 hours.
• a neutralizing amount of sodium phosphate was added to obtain 616 g of a hydroxy compound represented by the following formula (Ph-1).
• the hydroxy compound was of the PTMG ( polytetramethylene ether glycol) type ( BPA : It was confirmed that it contained a hydroxy compound of bisphenol A).
• the hydroxyl equivalent of this hydroxy compound (Ph-1) calculated by GPC was 1080 g/eq, the average value of n 1 was 10.6, and the average value of m 1 was 0.76.
• Synthesis example 9 In a flask equipped with a thermometer, dropping funnel, cooling tube, and stirrer, while purging with nitrogen gas, 200 g of the hydroxy compound Ph-1 obtained in Synthesis Example 5, 437 g (4.72 mol) of epichlorohydrin, and n-butanol were added. 118g was added and dissolved. After raising the temperature to 65° C., the pressure was reduced to an azeotropic pressure, and 6.66 g (0.08 mol) of a 49% aqueous sodium hydroxide solution was added dropwise over 5 hours. Next, stirring was continued for 0.5 hour under the same conditions.
• Ep-1 epoxy resin
• composition and cured product Using each compound according to Table 1 and Table 2 (numbers in the table are based on mass), mixer ("Awatori Rentaro ARV-200" manufactured by Thinky Co., Ltd.) The mixture was uniformly mixed to obtain a curable resin composition.
• This curable resin composition was sandwiched between aluminum mirror plates ("JIS H 4000 A1050P” manufactured by Engineering Test Service Co., Ltd.) using a silicone tube as a spacer, and heated and cured under predetermined conditions to obtain a cured product with a thickness of 0.7 mm. I got it.
• ⁇ Repair test> The produced cured product was cut with a razor, the resulting fractured surfaces were brought into contact, and then aged at 150° C. for 24 hours in a dryer. After taking it out from the dryer, the presence or absence of bonding between the cross sections of the cured product was visually confirmed. The judgment criteria are as follows. A: Even after joining and bending the cured product by 90 degrees, the joint does not separate. B: When the cured product is joined and bent, the joint does not separate. C: Not bonded.
• EPICLON850-S BPA type liquid epoxy resin, epoxy equivalent 188g/eq
• DICY dicyandiamide
• DCMU 3-(3,4-dichlorophenyl)-1,1-dimethylurea

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