WO2023176391A1 - 耐火シートおよび被覆物品 - Google Patents

耐火シートおよび被覆物品 Download PDF

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Publication number
WO2023176391A1
WO2023176391A1 PCT/JP2023/006970 JP2023006970W WO2023176391A1 WO 2023176391 A1 WO2023176391 A1 WO 2023176391A1 JP 2023006970 W JP2023006970 W JP 2023006970W WO 2023176391 A1 WO2023176391 A1 WO 2023176391A1
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WO
WIPO (PCT)
Prior art keywords
fiber
fibers
fireproof sheet
expandable graphite
mass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2023/006970
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
大 原田
瑛梨香 上村
有希 二ノ宮
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Priority to CN202380026496.7A priority Critical patent/CN118891153A/zh
Priority to JP2023513955A priority patent/JPWO2023176391A1/ja
Priority to EP23770350.9A priority patent/EP4494862A1/en
Priority to US18/843,364 priority patent/US20250198079A1/en
Publication of WO2023176391A1 publication Critical patent/WO2023176391A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
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    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/02—Inorganic materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/02—Synthetic macromolecular fibres
    • D06N2201/0263—Polyamide fibres
    • D06N2201/0272—Aromatic polyamide fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/06—Properties of the materials having thermal properties
    • D06N2209/067—Flame resistant, fire resistant

Definitions

  • the present invention relates to a fire-resistant sheet and a coated article coated with a fire-resistant sheet.
  • flame retardancy is required for the skin material and the material covering the inside of the skin material to ensure safety.
  • automotive interior materials use FMVSS-302 and JIS D1201
  • railway interior materials use the Test Method for Nonmetallic Materials for Railway Vehicles and the 45-degree ethyl alcohol method
  • wall covering materials use JIS A1321
  • Crib-5 is used for some public facilities.
  • Non-melting heat-resistant fibers such as meta-aramid, para-aramid, and flame-resistant yarn are used for the thick felt made of heat-resistant fibers inserted between the upholstery material and the seat cushion. It is disclosed that the basis weight of felt can be reduced by combining thermoplastic fibers with a high LOI value (Patent Document 1).
  • cushion foam is made by mixing commonly used flame retardants such as carbonization accelerators such as salen-type copper complexes, phosphate esters, halogen-containing organic compounds, and inorganic compounds.
  • flame retardants such as carbonization accelerators such as salen-type copper complexes, phosphate esters, halogen-containing organic compounds, and inorganic compounds.
  • methods for imparting excellent flame retardance which are mainly used in the field of building materials, include a method of kneading thermally expandable graphite into a thermoplastic resin to form a molded product (Patent Document 3), and A fireproof sheet (Patent Document 4) has been disclosed that includes a thermally expanding foam layer and a protective layer that protects the foam layer.
  • Patent Document 1 which is a composite of non-melting fibers with a low thermal shrinkage rate at high temperatures and thermoplastic fibers with a high LOI value, can reduce the mass compared to aramid felt, it has not been used in recent years, especially in aircraft. There is room for further weight reduction in terms of weight reduction and space saving in the field, and there is also room for further improvement in terms of durability against wear and tear caused by repeated attachment and detachment and use.
  • Patent Document 3 and Patent Document 4 are difficult to coat along curved surfaces, so they are not suitable as fireproof materials to cover the surface of seat foam. Furthermore, particularly in aircraft seats, if the seat sheet is made by covering the foam with a sheet material that has no air permeability, there is a risk that it will not be able to sufficiently absorb the shock during an emergency landing.
  • an object of the present invention is to provide a fire-resistant sheet and a coated article that can provide a coated article that has excellent durability, high flame retardancy, excellent texture, and good surface quality.
  • the present invention employs the following means.
  • thermoplastic fiber B in the layer including the fiber base layer and the reinforcing layer.
  • non-melting fiber A is a fiber selected from the group of flame-resistant fibers, para-aramid fibers, meta-aramid fibers, and mixtures thereof.
  • the thermoplastic fiber B is anisotropic melt polyester, flame retardant poly(alkylene terephthalate), flame retardant poly(acrylonitrile butadiene styrene), flame retardant polysulfone, poly(ether-ether-ketone), poly (ether-ketone-ketone), polyether sulfone, polyarylate, polyarylene sulfide, polyphenylsulfone, polyetherimide, polyamideimide, and mixtures thereof (1) to ( 7) The fireproof sheet according to any one of 7).
  • the fire-resistant sheet of the present invention and the coated article covered with the fire-resistant sheet have the above-mentioned configuration, and thus have a soft feel, excellent durability, and high flame retardancy. Further, since the fireproof sheet easily follows the shape of the coated article, it has excellent passability in the coating process, and as a result, the coated article has excellent quality. Furthermore, the fire-resistant sheet of the present invention has the advantage that it can be used as a coated article with excellent flame retardancy even if a regular cushion foam is used and coated without using a cushion foam whose rigidity is difficult to adjust. , can provide a coated article with a soft texture.
  • FIG. 2 is an explanatory diagram for explaining a method of assembling a coated article for evaluating the flame retardancy of a coated article used in a combustion test of an aircraft seat cushion, and the combustion test.
  • the present invention uses non-melting fiber A having a high temperature shrinkage rate of 3% or less and a thermal conductivity of 0.060 W/m ⁇ K or less according to ISO 22007-3 (2008), and JIS K7201-2 (2007 It consists of a fiber base material layer containing thermoplastic fiber B having an LOI value of 25 or more according to the Japanese Industrial Standards (2012), and a resin layer containing expandable graphite, and the phase transition temperature of the resin according to JIS K7121 (2012) is , is a fireproof sheet whose temperature is 20°C or more lower than the expansion start temperature of expandable graphite.
  • the high-temperature shrinkage rate refers to the original length L0 of the fibers used as raw materials for fireproof sheets after being left in standard conditions (20°C, 65% relative humidity) for 12 hours, applying a tension of 0.1 cN/dtex.
  • the fibers were exposed to a dry heat atmosphere at 290°C for 30 minutes without applying any load, cooled sufficiently under standard conditions (20°C, relative humidity 65%), and then exposed to zero
  • the length L1 is measured by applying a tension of .1 cN/dtex, and is a numerical value obtained from L0 and L1 using the following formula.
  • High temperature shrinkage rate [(L0-L1)/L0] x 100 (%)
  • the thermoplastic fibers melt, and the molten thermoplastic fibers spread in a thin film along the surface of the unmelted fibers (aggregate).
  • both fibers will eventually carbonize, but since the high-temperature shrinkage rate of non-melting fibers is less than 3%, it is difficult to shrink near the hot flame contact area, and the low temperature area that is not in contact with the flame is difficult to shrink.
  • the fireproof sheet is less likely to break due to thermal stress generated between the high-temperature part and the high-temperature part, it can block flames for a long time. This achieves excellent flame retardancy as a synthetic leather.
  • the high-temperature shrinkage rate is low, but even if it does not shrink but expands significantly due to heat, it will cause the fireproof sheet to break due to thermal stress, so the high-temperature shrinkage rate should be -5% or more. It is preferable. Among these, it is preferable that the high temperature shrinkage rate is 0 to 2%.
  • Thermal conductivity is a numerical expression of the ease with which heat is conducted. Low thermal conductivity means that when a material is heated from one side, the temperature rises in the unheated part. means to become smaller.
  • the test specimen was felt with a basis weight of 200 g/m 2 and a thickness of 2 mm (density 100 kg/m 3 ) measured using a method based on JIS L1913 (2010), and measured using a method based on ISO 22007-3 (2008). Materials with a thermal conductivity of 0.060 W/m ⁇ K or less are difficult to conduct heat, and when heated from one side using a fireproof sheet, it is difficult to suppress the temperature rise on the other side that is not heated.
  • the thermal conductivity is low, the lower limit for readily available fiber materials is about 0.020 W/m ⁇ K.
  • the LOI value is the volume percentage of the minimum amount of oxygen required to sustain the combustion of a substance in a mixed gas of nitrogen and oxygen, and it can be said that the higher the LOI value, the harder it is to burn. Therefore, thermoplastic fibers with an LOI value of 25 or higher according to JIS K7201-2 (2007) are difficult to burn, and even if they catch fire, the fire will extinguish as soon as the fire source is removed, and the part where the flames have spread will usually be extinguished. A carbonized film is formed, and this carbonized portion can prevent the spread of fire. Although a higher LOI value is preferable, the upper limit of the LOI value of actually available substances is about 65.
  • the ignition temperature is a spontaneous ignition temperature measured by a method based on JIS K7193 (2010).
  • the phase transition indicates the glass transition temperature and melting point in the case of a crystalline material, and the glass transition temperature in the case of an amorphous material, and the melting point is a value measured by a method based on JIS K7121 (2012).
  • the value is the melting peak temperature when heated at 10° C./min under a nitrogen gas stream by differential scanning calorimetry (DSC).
  • the glass transition temperature is a value measured in accordance with JIS K7121 (2012) using differential scanning calorimetry, and is measured on the low temperature side and high temperature side when heated at 10°C/min under a nitrogen gas flow.
  • the temperature at the point where a straight line that is equidistant in the vertical axis direction from the extended straight line of the baseline intersects the curve of the step-like change part of the glass transition (midpoint glass transition temperature). Measurement shall be started at a temperature 30° C. or more lower than the glass transition temperature and continued until the temperature is 30° C. or more higher than the melting point.
  • the lower one is taken as the phase transition temperature.
  • the phase transition temperature is preferably measured using the raw resin, but if it is difficult to measure using the raw resin, it may be the value of the 2nd run of sampling from the fireproof sheet.
  • the phase transition temperature is preferably measured using the raw resin, but if it is difficult to measure using the raw resin, it may be the value of the 2nd run of sampling from the fireproof sheet.
  • non-melting fibers A refer to fibers that do not liquefy and maintain their fiber shape when exposed to flame, preferably those that do not liquefy or ignite at a temperature of 800°C, and that do not liquefy or ignite at a temperature of 1000°C or higher. It is more preferable to use one that does not ignite.
  • non-melting fibers whose high-temperature shrinkage rate falls within the range specified in the present invention include flame-resistant fibers, para-aramid fibers, meta-aramid fibers, and glass fibers, among which flame-resistant fibers, para-aramid fibers, Preferred examples include meta-aramid fibers.
  • the flame-resistant fiber is a fiber that is made from a fiber selected from acrylonitrile-based, pitch-based, cellulose-based, phenol-based fiber, etc. and subjected to flame-resistant treatment. These may be used alone or in combination of two or more. Among these, flame-resistant fibers are preferred, which have a low high-temperature shrinkage rate and which progress carbonization due to the oxygen-blocking effect of the film formed when the thermoplastic fiber B described below comes into contact with the flame, further improving heat resistance at high temperatures. Among various types of flame-resistant fibers, acrylonitrile-based flame-resistant fibers are more preferably used as fibers with low specific gravity, flexibility, and excellent flame retardancy. Obtained by heating and oxidizing.
  • meta-aramid fibers generally have a high high-temperature shrinkage rate and do not meet the high-temperature shrinkage rate specified in the present invention, but meta-aramid fibers that are treated to suppress the high-temperature shrinkage rate are within the high-temperature shrinkage rate range of the present invention. If so, it can be preferably used.
  • the non-melting fibers preferably used in the present invention are used alone or in combination with different materials, and the fiber length is preferably within the range of 30 to 120 mm, and preferably within the range of 38 to 70 mm. It is more preferable. If the fiber length is within the range of 38 to 70 mm, it can be made into a nonwoven fabric sheet by the general needle punching method or hydroentangling method, and it is easy to composite it with different materials. Further, the thickness of the single fibers of the non-melting fibers is not particularly limited, but from the viewpoint of passability in the carding process, it is preferable that the single fiber fineness is within the range of 0.1 to 10 dtex. More preferably, it is 0.3 to 8 dtex.
  • thermoplastic fiber B used in the present invention has the above-mentioned LOI value within the range specified by the present invention, and has a melting point lower than the ignition temperature of the non-melting fiber A (if there is no melting point, the melting temperature)
  • Specific examples include anisotropic melt polyester, flame retardant poly(alkylene terephthalate), flame retardant poly(acrylonitrile butadiene styrene), flame retardant polysulfone, poly(ether-ether-ketone), Mention fibers composed of thermoplastic resins selected from the group of poly(ether-ketone-ketone), polyethersulfone, polyarylate, polyarylene sulfide, polyphenylsulfone, polyetherimide, polyamideimide and mixtures thereof be able to.
  • the LOI value is within the range specified by the present invention, combustion in the air is suppressed and the polymer is easily carbonized.
  • the melting point temperature at which it melts if there is no melting point
  • the molten polymer forms a film on the surface of non-melting fiber A and between the fibers, which is further carbonized. This increases the effect of blocking oxygen and suppresses oxidative deterioration of the non-melting fibers A.
  • the carbonized film exhibits excellent flame-retardant properties, making the coating coated with the fireproof sheet of the present invention more effective. The flame retardance of the article as a whole can be maintained.
  • the melting point of the thermoplastic fiber B is preferably 200°C or more lower than the ignition temperature of the non-melting fiber A, more preferably 300°C or more lower.
  • polyphenylene sulfide fibers (hereinafter also referred to as PPS fibers) are most preferred from the viewpoint of high LOI value, melting point range, and easy availability.
  • PPS fibers polyphenylene sulfide fibers
  • the polymer can be preferably used by treating it with a flame retardant as long as the LOI value after treatment is within the range specified by the present invention.
  • thermoplastic fiber B it is preferable to use a fiber containing 15% by mass or more of sulfur atoms. Specifically, polyesters to which PPS and sulfur-based flame retardants have been added may be mentioned. The upper limit is preferably 50% by mass or less from the viewpoint of fiber strength.
  • the sulfur atom ratio here is determined by oxidative decomposition of thermoplastic fibers by heating approximately 10 mg of a sample from room temperature to 800°C at 10°C/min under air flow conditions using a thermogravimetric analyzer. It is determined by quantitatively analyzing the sulfur oxides in the cracked gas using gas chromatography.
  • thermoplastic fiber B used in the present invention is used by the above-mentioned thermoplastic resin alone or in combination with different materials, and the fiber length is preferably within the range of 30 to 120 mm, and preferably within the range of 38 to 70 mm. It is more preferable that there be. If the fiber length is within the range of 38 to 70 mm, it can be made into a nonwoven fabric by the general needle punching method or hydroentangling method, and it is easy to composite it with different materials. Further, the thickness of the single fibers of the thermoplastic fiber B is not particularly limited, but from the viewpoint of passability in the carding process, the single fiber fineness is preferably within the range of 0.1 to 10 dtex. , 0.3 to 8 dtex is more preferable.
  • the PPS fiber preferably used in the present invention is a synthetic fiber made of a polymer whose main structural unit is -(C 6 H 4 -S)-.
  • Representative examples of these PPS polymers include polyphenylene sulfide, polyphenylene sulfide sulfone, polyphenylene sulfide ketone, random copolymers, block copolymers thereof, and mixtures thereof.
  • a particularly preferred PPS polymer is a polyphenylene sulfide containing p-phenylene sulfide units represented by -(C 6 H 4 -S)-, preferably at least 90 mol %, as the main structural unit of the polymer. From the viewpoint of mass, polyphenylene sulfide containing 80% by mass, more preferably 90% by mass or more of p-phenylene sulfide units is desirable.
  • the method for producing the PPS fiber used in the present invention is preferably a method in which the polymer having the above-mentioned phenylene sulfide structural unit is melted above its melting point and spun out from a spinneret to form a fiber.
  • the spun fibers are undrawn PPS fibers as they are. Most of the undrawn PPS fibers have an amorphous structure and have a high elongation at break. On the other hand, since such fibers have poor dimensional stability due to heat, drawn yarns are commercially available which are oriented by hot drawing following spinning to improve the strength and thermal dimensional stability of the fibers.
  • PPS fibers are on the market, such as “Turcon” (registered trademark) (manufactured by Toray Industries, Inc.) and “Procon” (registered trademark) (manufactured by Toyobo Co., Ltd.).
  • the undrawn PPS fibers and the drawn PPS fibers can be used together within the scope of the present invention.
  • drawn fibers and undrawn fibers that meet the scope of the present invention may of course be used in combination.
  • Fibers C other than non-melting fibers A and thermoplastic fibers B may be included in the fiber base layer or reinforcing layer (if it has a reinforcing layer), which will be described later, in order to further add specific performance.
  • Fibers C other than non-melting fibers A and thermoplastic fibers B may be included in the fiber base layer or reinforcing layer (if it has a reinforcing layer), which will be described later, in order to further add specific performance.
  • vinylon fibers, modified polyester fibers, nylon fibers, etc. may be used to improve the wettability of the fiber base material layer. By changing the wettability, it is possible to improve process passability when forming a resin layer containing expandable graphite on a fiber base layer.
  • the blending ratio of fiber C is not particularly limited as long as it does not impair the effects of the present invention, but fibers other than non-melting fiber A and thermoplastic fiber B may be added to the layer consisting of the fiber base layer and the reinforcing layer (if it has a reinforcing layer).
  • the blending rate of C is preferably 20% by mass or less, more preferably 15% by mass or less.
  • the lower limit when using fiber C may be 0% by mass since it is an optional component.
  • the thickness of the single fibers of the fibers C other than the thermoplastic fibers B is not particularly limited, but from the viewpoint of passability in the carding process, the fineness of the single fibers is within the range of 0.1 to 10 dtex. It is preferable to have a certain dtex, and more preferably 0.3 to 8 dtex.
  • the resin layer containing expandable graphite refers to a layer containing expandable graphite, a resin supporting it, and a flame retardant other than expandable graphite as an optional component.
  • Expandable graphite is graphite that expands when heated, and is also called expanded graphite. Expandable graphite has a substance such as sulfuric acid introduced between the graphite layers, and when heated, this substance gasifies and expands. It is desirable to use expandable graphite that has been neutralized so that it does not react with phosphorus compounds or the like.
  • the preferred expansion ratio of the expandable graphite in the present invention is preferably 2 to 400 times, more preferably 5 to 350 times.
  • the expansion ratio refers to the rate of change in volume before and after heating when a fixed volume of expandable graphite is heated in a thermal oven set at a predetermined temperature for 30 minutes.
  • the area of 20 expansible graphite particles is calculated using an optical microscope image magnified approximately 30 times, and the area change rate before and after heating is used to judge the area.
  • Expandable graphite is commercially available from, for example, Ito Graphite Industries Co., Ltd. or Fuji Graphite Industries Co., Ltd.
  • the expansion start temperature of the expandable graphite in the present invention is preferably 120 to 300°C, more preferably 150 to 250°C.
  • the resin forming the resin layer is available in the form of an aqueous emulsion, so the efficiency of the fixing process can be improved by setting the expansion start temperature to 100° C. or higher.
  • the expandable graphite expands to form a heat insulating layer, and then the thermoplastic fiber B carbonizes to form a heat insulating layer in stages, so the expansion start temperature is below the melting point of the thermoplastic fiber B.
  • the expansion start temperature refers to the lowest heating temperature at which expansion can be visually confirmed when a certain volume of expandable graphite is heated for 30 minutes in a thermal oven set at various temperatures.
  • the particle size of the expandable graphite in the present invention is such that it passes through a sieve with a nominal opening of 150 ⁇ m and does not pass through a sieve with a nominal opening of 75 ⁇ m in the nominal opening of the sieve mesh in accordance with JIS Z8801-1 (2019). It is preferable that the particles are contained in an amount of 50% by mass or more based on the total mass of the expandable graphite.
  • the particle size was determined by measuring a sufficient amount of expandable graphite sample using a sieve mesh that complies with JIS Z8801-1 (2019), and measuring the nominal mesh size according to the "dry, manual sieving" method described in JIS Z8815 (1994). Judgment is made based on the mass ratio when separated by sieve mesh.
  • the specific method when the particle size is 1 mm or less is as follows.
  • (a) Stack the sieve with large openings on top of the receiver.
  • (b) Place the charge sample into the top sieve and close the lid.
  • (c) Support the stacked sieves at an angle of about 20 degrees with one hand or with your arm bent, and tap the sieve frame with one hand at a rate of about 120 times per minute. During this time, place the sieve horizontally, rotate it 90 degrees, and tap the sieve frame firmly once or twice at a rate of 4 times per minute.
  • (d) If fine powder is attached to the back side of the sieve screen, gently remove it from the back side of the sieve with an appropriate brush and place the fine powder under the sieve.
  • expandable graphite the larger the particle size, the higher the expansion rate and the better the insulation properties, but if the particle size is too large, the ability to support the expandable graphite will decrease, and the expandable graphite will easily fall off from the resin layer due to friction. .
  • expandable graphite In order to achieve both thermal insulation and abrasion resistance with expandable graphite, expandable graphite must pass through a sieve with a nominal opening of 150 ⁇ m in accordance with JIS Z8801-1 (2019), and It is preferable that particles that do not pass through a sieve having a nominal opening of 75 ⁇ m are contained in an amount of 50% by mass or more based on the total mass of the expandable graphite.
  • the resin supporting the expandable graphite is not limited as long as it is a thermoplastic resin having a phase transition temperature that is 20°C or more lower than the expansion start temperature of the expandable graphite, and polyethylene (PE) resin or polypropylene (PP) can be used.
  • PE polyethylene
  • PP polypropylene
  • Polyolefin resins such as resins and ethylene vinyl acetate (EVA) resins, polystyrene (PS) resins, acrylonitrile butadiene styrene (ABS) resins, acrylic resins, polyvinyl chloride (PVC) resins, thermoplastic elastomers (especially olefin thermoplastics) elastomer) etc.
  • EVA ethylene vinyl acetate
  • PS polystyrene
  • ABS acrylonitrile butadiene styrene
  • acrylic resins polyvinyl chloride (PVC) resins
  • PVC polyvinyl chloride
  • thermosetting resin such as epoxy resin or melamine resin may be added in order to improve the coating strength of the resin layer and prevent the expansible graphite from falling off. Since there is a concern that the ratio of the thermosetting resin to the thermoplastic resin is 20% by mass or less, it is preferable that the ratio of the thermosetting resin to the thermoplastic resin is 20% by mass or less.
  • the resin layer containing expandable graphite may contain other components as necessary.
  • a flame retardant such as red phosphorus, a phosphorus compound such as a phosphate ester, a metal phosphate, or an ammonium polyphosphate
  • flame retardancy can be increased and the fireproof insulation effect can be improved.
  • ammonium polyphosphate particularly suitable is the addition of ammonium polyphosphate.
  • Water-containing inorganic substances such as aluminum hydroxide and magnesium hydroxide may be added as flame retardants other than those mentioned above, and a dehydration reaction occurs during heating, and the heat-absorbing action of the generated water can improve fireproof and heat-insulating performance.
  • the mass ratio of resin and expandable graphite is preferably in the range of 1:0.5 to 1:2. If the resin ratio is too large, the expandable graphite will be buried in the resin, and the insulation effect due to expansion will be reduced. On the other hand, if the ratio of the resin is too small, the supporting force of the expandable graphite will be weak, and the expandable graphite will easily fall off due to friction or the like.
  • the basis weight of the resin layer containing expandable graphite is not particularly limited, but in order to obtain sufficient fire resistance, it is preferably 10 g/m 2 or more, more preferably 20 g/m 2 or more, and even more preferably 30 g /m 2 or more, and the upper limit may be set according to the lightweight effect and fire resistance that can be obtained.
  • the upper limit is preferably 150 g/m 2 or less from the viewpoint of the texture of the fireproof sheet and the lightweight effect obtained.
  • the fiber base material layer in the present invention includes the non-melting fibers A, thermoplastic fibers B, and fibers C as optional components.
  • the fiber base layer may be a woven fabric, a knitted fabric, or a nonwoven fabric sheet, but a nonwoven fabric sheet is preferable because it is flexible and can be easily covered with an aircraft seat cushion foam.
  • the basis weight of the fiber base material layer is preferably 50 g/m 2 or more, more preferably 100 g/m 2 or more, even more preferably 150 g/m 2 or more, and preferably 450 g/m 2 or less, and 400 g/m 2 or less. More preferably, it is 350 g/m 2 or less. When the basis weight of the fiber base layer is within the above range, a cushion foam-covered article for aircraft seats that has excellent mechanical properties and is lightweight can be obtained.
  • the thickness of the nonwoven fabric sheet of the fiber base layer is measured by a method based on JIS L1913 (2010), and is preferably 0.4 mm or more.
  • the thickness of the nonwoven fabric sheet is at least the above lower limit, it is possible to obtain excellent mechanical properties as a fiber base material layer, and also to obtain excellent flame retardancy, as well as a resin layer containing expandable graphite, which will be described later.
  • the resin layer does not penetrate to the back side of the fiber base layer, resulting in an excellent texture of the fireproof sheet.
  • the upper limit is preferably 4 mm or less in terms of coverage on cushion foam and the like.
  • the structure of the nonwoven fabric sheet is not limited as long as it is within the range specified by the present invention, but it is preferable that the density of the nonwoven fabric sheet is greater than 50 kg/m 3 and less than 200 kg/m 3 , and preferably 55 to 200 kg/m 3 . 180 kg/m 3 is more preferable, and even more preferably 70 to 160 kg/m 3 . If the density is too low, when a resin layer containing expandable graphite is formed on the fiber base layer, the resin will soak into the fiber base layer too much and the texture of the fireproof sheet will become too hard. On the other hand, if the density is too high, the fiber base layer itself becomes too hard and the texture of the fireproof sheet becomes hard. The density is calculated by dividing the mass of a 30 cm square sample by the thickness measured by a method based on JIS L1913 (2010).
  • the number of crimps of the fibers is 7/2.54 cm or more; It is preferable that the number is 12 pieces/2.54 cm or more.
  • the crimp number in the present invention is measured in accordance with JIS L1015 (2010). It is preferable to measure the crimp number in the state of raw cotton, but if this is difficult, it may be measured using a sample obtained by disassembling the fiber base layer.
  • the short fibers of the fibers C have the same length in order to obtain a more uniform nonwoven fabric sheet.
  • the same length does not have to be strictly the same, and there may be a difference of about ⁇ 5% with respect to the length of the non-melting fiber A.
  • the fiber length of the non-melting fiber and the fiber length of the thermoplastic fiber B or fiber C when using the fiber C is preferably within the range of 30 to 120 mm, and preferably within the range of 38 to 70 mm. It is more preferable that it be within.
  • the method for forming the nonwoven fabric sheet of the present invention is not particularly limited, but examples include a needle punch method and a hydroentangling method.
  • a reinforcing layer may be included between the fiber base layer and the resin layer containing expandable graphite.
  • a reinforcing layer may be combined to improve passage through the processing process. Good too.
  • the reinforcing layer include sheets and films made of fibers. In the case of a sheet made of fibers, the constituting fibers may be short fibers or long fibers, or the sheet may be formed by direct spinning.
  • the fiber length is preferably within the range of 30 to 120 mm, more preferably within the range of 38 to 51 mm. If the fiber length is within the range of 38 to 51 mm, it is easy to make a spun yarn using a general spinning process, and the resulting spun yarn can be woven or knitted using a standard method to create a woven or knitted fabric. It can be made with a reinforcing layer.
  • long fibers it may be used as raw silk, or it may be woven or knitted to form a reinforcing layer after undergoing various commonly known thread processing.
  • a direct spinning type it can be made into a non-woven sheet using a spunbond method or a melt blow method to form a reinforcing layer.
  • the material constituting the reinforcing layer is preferably a reinforcing layer made of PPS fibers, for example, since excellent fire resistance can be obtained by including the above-mentioned non-melting fibers A or thermoplastic fibers B.
  • fibers C other than the non-melting fibers A and the thermoplastic fibers B may be included in the reinforcing layer and the fiber base layer as long as the desired fire resistance and reinforcing effect can be obtained.
  • examples of the fiber C-1 suitably used for the reinforcing layer include polyester, polypropylene, cotton, and wool.
  • examples of the fiber C-2 suitably used in the fiber base layer include polyester, nylon, acrylic, vinylon, and the like.
  • the proportion of other fibers C in the combined layer of the fiber base layer and the reinforcing layer is preferably 20% by mass or less. .
  • the basis weight of the reinforcing layer is not particularly limited and can be selected according to the desired reinforcing effect, but when a reinforcing layer is included, the basis weight of the reinforcing layer is preferably 10 to 300 g/m 2 , more preferably 15 -280 g/m 2 , more preferably 20-250 g/m 2 .
  • the basis weight of the reinforcing layer is within the above range, a cushion foam-covered article for aircraft seats that has excellent mechanical properties and is lightweight can be obtained.
  • the reinforcing layer and the fiber base layer may be bonded by mechanical action such as a needle punch method or hydroentangling method, by heat bonding such as a thermal calendar, or by bonding using an adhesive. Good too.
  • the fiber base layer alone or the fiber base layer combined with a reinforcing layer may be heat set using a tenter or calendered. You may do so. Of course, you can use the raw material as is.
  • the setting temperature is preferably a temperature at which the effect of suppressing high temperature shrinkage can be obtained, preferably 160 to 240°C, more preferably 190 to 230°C. Calendering is used to adjust the thickness of the fiber base layer, that is, the density.
  • the density is too low, and when forming a resin layer containing expandable graphite on the fiber base layer, the resin layer soaks into the fiber base layer too much and the texture of the fireproof sheet becomes too hard.
  • calendering may be performed. As long as a nonwoven fabric sheet having physical properties within the range specified by the present invention is obtained, the speed, pressure, and temperature of the calender are not limited.
  • the mixing ratio is preferably 15% by mass or more, more preferably 20% by mass or more.
  • the upper limit is preferably 85% by mass or less from the viewpoint of productivity and strength of the fiber base material and reinforcing layer, more preferably 70% by mass or less, even more preferably 60% by mass or less, and even more preferably 50% by mass or less. It is particularly preferable that it is less than % by mass.
  • thermoplastic fibers B in the fiber sheet are too low, the thermoplastic fibers will not spread sufficiently into a film between the non-melting fibers of the aggregate, so the content of thermoplastic fibers B should be 10% by mass or more. It is preferably at least 15% by mass, more preferably at least 20% by mass, particularly preferably at least 30% by mass. If the blending ratio of thermoplastic fiber B becomes too high, the carbonized part tends to become brittle during flame contact, and holes tend to form in the fiber base layer. Therefore, the upper limit is preferably 85% by mass or less, and 80% by mass. % or less is more preferable.
  • the fabric weight of the fiber sheet is preferably the fabric weight of the fiber base layer, or, if a reinforcing layer is included, the fabric weight of the fiber base layer plus the fabric weight of the reinforcing layer.
  • the basis weight of the fiber sheet is determined from the basis weight of the fiber base layer as described above. A sufficient effect can be achieved even if the basis weight of the reinforcing layer is lower than the total basis weight.
  • the basis weight of the fiber sheet is set to 450 g/m 2 or less, especially 400 g/m 2 or less, particularly 350 g/m 2 or less, the weight of the fiber sheet can be reduced. It is preferable.
  • the lower limit is preferably 50 g/m 2 or more, particularly 100 g/m 2 or more, particularly 150 g/m 2 or more. In this case, the division of basis weight between the fiber base layer and the reinforcing layer in the fiber sheet can be appropriately selected depending on the application.
  • the basis weight of the reinforcing layer is increased, and when emphasis is placed on softness and conformability to the shape of the covered object, the basis weight of the fiber base material layer is increased. is preferred.
  • the fireproof sheet of the present invention is produced by forming a resin layer containing expandable graphite on a fiber sheet which is usually a fiber base layer or a fiber base layer combined with a reinforcing layer.
  • a resin layer is provided on the fiber base material layer to which the reinforcing layer is combined, the resin layer is formed on the reinforcing layer side to create a structure in which the reinforcing layer is provided between the fiber base material layer and the resin layer. It is preferable.
  • the method for forming the resin layer is not particularly limited, and a resin solution containing expandable graphite emulsified and dispersed in water or a solvent is prepared, and the resin solution is applied to the fibers including a fiber base layer and an optional reinforcing layer. It is coated or dipped onto a sheet and then dried.
  • the coating method include a gravure coating method and a knife coating method.
  • the immersion method involves dipping the fiber sheet in a coating solution, and then squeezing out excess coating solution using a mangle or the like.
  • a viscosity modifier may be used in combination as appropriate. Further, in order to achieve the desired coating amount, the coating may be applied multiple times.
  • a commonly used dryer such as a tenter is used, but if drying is performed at a temperature below the expansion start temperature of expandable graphite, or at a temperature above the expansion start temperature, the drying time may be shortened. It is preferable to adjust the conditions appropriately so as to achieve the desired time.
  • the surface to be coated when applying a resin layer containing expandable graphite is not particularly limited, but if it has a reinforcing layer, coating it on the surface of the reinforcing layer will allow it to penetrate into the fiber base material layer. Excessive resin seepage can be suppressed and the texture of the fireproof sheet can be maintained. Moreover, by unevenly distributing a resin layer containing expandable graphite on one side of the fireproof sheet, the density of expandable graphite increases, and the resulting heat insulation effect improves.
  • the resin layer containing expandable graphite firmly adheres to a portion of the fiber base material layer, improving durability against abrasion and allowing "Velcro (registered trademark)" tape to be applied to items such as cushion foam covered with a fire-resistant sheet. It is possible to prevent the fireproof sheet from fraying or breaking at the "Velcro (registered trademark)" tape portion when attaching and detaching items by attaching hook-and-loop fasteners.
  • the thickness of the obtained fireproof sheet is preferably 0.4 to 4.0 mm, preferably 0.5 to 3 It is more preferably 0.5 mm, and even more preferably 0.6 to 3.0 mm. If the thickness is thinner than the above range, the abrasion durability may be poor, and the entire coated article such as a sheet may have insufficient fire resistance when integrated with an article such as a seat cushion material. On the other hand, if the thickness is thicker than the above range, the texture will be hard.
  • the basis weight of the fireproof sheet is preferably 460 g/m 2 or less, more preferably 60 to 400 g/m 2 from the viewpoint of flame retardant performance, abrasion durability, texture, and weight reduction of coated articles such as sheets. It is more preferably 80 to 350 g/m 2 , particularly preferably 100 to 300 g/m 2 .
  • the basis weight is at least the lower limit of the above range, the coated article has excellent abrasion durability and the entire coated article such as a sheet when integrated with an article such as a seat cushion material has excellent flame retardancy.
  • the basis weight is below the upper limit of the above range, the merit of reducing the weight of the entire coated article such as a sheet is extremely large.
  • the mass ratio of the resin layer containing expandable graphite to the mass of the entire fireproof sheet is preferably 5 to 75%, more preferably 5 to 60%, and 8 to 55%. %, particularly preferably 10 to 50%. Since the resin layer containing expandable graphite of the present invention exhibits excellent heat insulation and flame retardant properties and contributes to reducing the weight of the fireproof sheet, the mass proportion of the resin layer containing expandable graphite is equal to or higher than the above lower limit. The flame retardance of the fire-resistant sheet alone or as a coated article such as a sheet is sufficiently excellent.
  • the mass ratio of the resin layer containing expandable graphite is below the above upper limit, the relative mass of the fiber base layer is sufficiently large, and the fireproof sheet has morphological stability when exposed to high-temperature flame. It is preferable because it has sufficiently excellent flame retardancy when made into coated articles such as sheets. Since the mass of the fiber base material layer can be suppressed in order to provide the fireproof sheet with morphological stability when exposed to high-temperature flames, the advantage of weight reduction can be effectively exhibited.
  • the air permeability at 125 Pa is preferably 5 to 400 cc/(cm 2 ⁇ s), and preferably 10 to 300 cc/(cm 2 ⁇ s). It is more preferably 20 to 200 cc/(cm 2 ⁇ s), even more preferably 40 to 150 cc/(cm 2 ⁇ s). If the air permeability is less than 5 cc/(cm 2 ⁇ s), when a seat sheet is made by covering the foam with a sheet material, it will be difficult to absorb shock, and the seating comfort will be poor at the moment of sitting. On the other hand, if the air permeability is greater than 400 cc/(cm 2 ⁇ s), there is a concern that flames may escape through the gaps between the heat-resistant sheets and the flame retardancy of the coating may deteriorate.
  • the thus obtained fire-resistant sheet of the present invention has excellent flame retardancy and also has excellent physical properties such as texture and abrasion durability.
  • the flame-retardant performance can be applied not only to the fire-resistant sheet alone but also to cushion foam, etc. When coated on an article, etc., the effect is exerted on the entire coated article. Therefore, in addition to being used directly to decorate ceilings and walls, it can also be used as a covering material for covering seat cushion materials and the like. Among these, it is especially suitable for use as covering materials for seat cushions installed in automobiles, trains, and ships that require high flame retardancy, and as covering materials for chairs and sofas in high-rise buildings and public facilities. can.
  • the fabric weight (g/m 2 ) is obtained by subtracting the fabric weight of the fiber base layer and the fabric weight of the reinforcing layer from the above-mentioned fabric weight of the fireproof sheet.
  • the thickness of fiber base layer and fireproof sheet was measured in accordance with JIS L1913 (2010). If the measurement sample is a fireproof sheet and it is difficult to measure the fiber base layer alone, the entire thickness of the fireproof sheet in the cross section of the sample is within the imaging range of a scanning electron microscope (SEM). The image is taken at a magnification of about 50 to 90% (specifically about 30 to 200 times), and the thickness of the fiber base layer is read on a scale at five arbitrary points in the cross-sectional photograph. The average value may be used as the thickness of the fiber base layer.
  • SEM scanning electron microscope
  • FIG. 1 is an explanatory diagram illustrating a method for assembling a coated article for evaluating the flame retardance of a coated article used in a combustion test of an aircraft seat cushion, and the combustion test.
  • Flexible urethane foam commercially available from Fuji Rubber Sangyo Co., Ltd. was cut into 450 mm x 500 mm for the seat and 450 mm x 630 mm for the back, which were used as urethane foam (seat) 1 and urethane foam (back) 2, respectively.
  • a skin material (seat surface) 4 and a skin material (back surface) 5 are prepared by attaching "Velcro (registered trademark)" tape 3 made of polyphenylene sulfide to the fireproof sheet of the present invention by sewing with meta-aramid thread.
  • the urethane foam (seat surface) 1 and the urethane foam (back surface) 2 are covered with the skin material (seat surface) 4 and the skin material (back surface) 5, respectively, and fixed to an L-shaped frame (not shown).
  • Assemble 7. measure the mass of the sample before the test.
  • the burner temperature must be within the range of 1000 ⁇ 20°C between the lowest and highest temperatures measured at 5 points in the width direction at the base of the burner opening. do. After heating, remove the burner from the sample and leave it for 5 minutes. After standing for 5 minutes, measure the sample mass. The flame that ignited the sample after being left for 5 minutes is completely extinguished, and the combustion length of the front and rear sides of the back cushion and the bottom and top of the seat cushion are all 17 inches (432 mm) or less, and , If the sample mass reduction rate after the test is 10.0% or less, it is passed, and among these, the mass reduction rate is 6.0% or less, A, and the mass reduction rate is greater than 6.0% and 10.0% or less.
  • Non-melting fiber A-1 Oxidized polyacrylic nitrile fiber (“ZOLTEK” (registered trademark) OX) manufactured by Zoltek of 2.2 dtex (length 50 mm, high temperature shrinkage rate 1.6%, thermal conductivity 0.033 W/m ⁇ K (200 g) /m 2 , a needle punch felt of 2 mm thickness was prepared and measured). The number of crimps was 12 (pieces/25 mm), and the crimp rate was 12%).
  • ARAWIN registered trademark
  • the proportion of sulfur atoms in the fiber was 26.2% by mass.
  • PET polyethylene terephthalate
  • ⁇ Reinforcement layer 1> (spinning)
  • the drawn yarns of PPS fibers were mixed by a spreader, further mixed by a mixing and batting machine, and then passed through a carding machine to form a sliver.
  • the mass of the obtained sliver was 30.23 g/5.46 m.
  • the sliver was drawn using a drawing machine with the total draft set to 8 times to obtain a sliver of 28.03 g/5.46 m.
  • the yarn was twisted to 0.55 T/2.54 cm using a roving machine and stretched 7.4 times to obtain a roving of 323.20 g/5.46 m.
  • the yarn was twisted to 16.4 T/2.54 cm using a spinning machine, stretched to a total draft of 30 times, and twisted to obtain a spun yarn with a cotton count of 20.
  • the spun yarn of No. 20 is used as the weft yarn of the scrim.
  • the obtained spun yarn was twisted with a double twister at 64.7 T/2.54 cm to obtain a 20 count double yarn. Use the 20th twin thread to thread the warp of the scrim.
  • the obtained spun yarn was woven in a plain weave with a warp of 113 yarns/10 cm and a weft of 98 yarns/10 cm using a rapier loom to obtain a scrim of 109 g/m 2 .
  • ⁇ Reinforcement layer 2> A 100% PET spunbond nonwoven fabric, "Acstar” (registered trademark) manufactured by Toray Industries, Inc., product number M1025-5T, having a basis weight of 25 g/m 2 and a thickness of 0.07 mm was used.
  • Expanded graphite EXP-50S160 manufactured by Fuji Graphite Industries Co., Ltd. was used.
  • the expansion start temperature measured for a single expandable graphite particle is 160°C, and the expansion magnification is 285 times.
  • the nominal particle size includes 75% or more of particles that do not pass through a sieve with a nominal opening of 300 ⁇ m (equivalent to 50 mesh).
  • the proportion of particles that passed through a sieve with a nominal opening of 150 ⁇ m and did not pass through a sieve with a nominal opening of 75 ⁇ m was 12.5% by mass.
  • Expanded graphite EXP-80S manufactured by Fuji Graphite Industries Co., Ltd. was used.
  • the expansion start temperature measured for a single expandable graphite particle is 200°C, and the expansion magnification is 180 times.
  • the nominal particle size includes 75% or more of particles that do not pass through a sieve with a nominal opening of 180 ⁇ m (equivalent to 80 mesh).
  • the proportion of particles that passed through a sieve with a nominal opening of 150 ⁇ m but did not pass through a sieve with a nominal opening of 75 ⁇ m was 4.5% by mass.
  • Expanded graphite EXP-50S300 manufactured by Fuji Graphite Industries Co., Ltd. was used.
  • the expansion start temperature measured for a single expandable graphite particle is 300°C, and the expansion magnification is 164 times.
  • the nominal particle size includes 75% or more of particles that do not pass through a sieve with a nominal opening of 300 ⁇ m (equivalent to 50 mesh).
  • the proportion of particles that passed through a sieve with a nominal opening of 150 ⁇ m but did not pass through a sieve with a nominal opening of 75 ⁇ m was 3.5% by mass.
  • Expanded graphite EXP-200S manufactured by Fuji Graphite Industries Co., Ltd. was used.
  • the expansion start temperature measured for a single expandable graphite particle is 200°C, and the expansion magnification is 35 times.
  • the nominal particle size includes 60% or more of particles that pass through a sieve with a nominal opening of 75 ⁇ m (equivalent to 200 mesh).
  • the proportion of particles that passed through a sieve with a nominal opening of 150 ⁇ m and did not pass through a sieve with a nominal opening of 75 ⁇ m was 27.8% by mass.
  • Expanded graphite 9510045 manufactured by Ito Graphite Industries Co., Ltd. was used.
  • the expansion start temperature measured for a single expandable graphite particle is 200°C, and the expansion magnification is 45 times.
  • the nominal particle size was 92.1% by mass of particles that passed through a sieve with a nominal opening of 150 ⁇ m and did not pass through a sieve with a nominal opening of 75 ⁇ m.
  • phase transition temperature (Tg) of the acrylic resin "Boncoat” (registered trademark) S-5 manufactured by DIC Corporation is -10°C.
  • the catalog value of the phase transition temperature (Tg) is 80°C.
  • ⁇ Melamine resin E-4> Melamine resin "Amidia” (registered trademark) M-3 manufactured by DIC Corporation and Catalyst ACX, a crosslinking agent for melamine resin, are thermosetting resins, so there is no phase transition.
  • Example 1 Manufacture of fiber base layer
  • the drawn PPS fibers and the flame-resistant fibers are mixed by a spreader so that the mass blend ratio of the drawn PPS fibers and the flame-resistant fibers is 60:40, then further mixed by a mixing and batting machine, and then passed through a card machine to form a web.
  • the resulting web was laminated using a cross-lap machine and then felted using a needle punch machine to obtain a fiber base material layer having a basis weight of 150 g/m 2 and a thickness of 1.42 mm.
  • Expandable graphite D-1 9.5 parts by mass, acrylic resin E-1: 7.0 parts by mass, phosphate ester flame retardant (“ADEKA STAB” (registered trademark) FP-600 manufactured by ADEKA Corporation): 3
  • ADEKA STAB phosphate ester flame retardant
  • FP-600 manufactured by ADEKA Corporation
  • a dispersion of 0.5 parts by mass and 80 parts by mass of water was prepared, and xanthan gum was added to the resulting dispersion to adjust the viscosity to 2000 mPa ⁇ s, which was then coated with a knife coat. Thereafter, it was dried in a tenter at 110°C.
  • the coating amount of the resin layer containing expandable graphite was 45 g/m 2 , and the thickness of the fireproof sheet was 1.51 mm.
  • the phase transition temperature (Tg) of the resin layer taken from the fireproof sheet was -7°C.
  • the mechanical properties and abrasion durability are as shown in Table 1, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was B.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • a urethane cushion was coated with the obtained fireproof sheet and a flame retardant test was conducted on the seat cushion, the combustion length was within the acceptable range and the mass reduction rate was excellent at 3.9%.
  • the sensory evaluation of the comfort of the seat cushion was 3.0 points.
  • Example 2 Manufacture of fiber base layer
  • the same fiber base layer as that produced in Example 1 was used as the fiber base layer.
  • Resin layer containing expandable graphite A resin liquid was prepared, knife coated, and dried in the same proportions as in Example 1, except that the resin was changed from acrylic resin E-1 to styrene resin E-2.
  • the coating amount was 43 g/m 2
  • the obtained fireproof sheet had a basis weight of 193 g/m 2 and a thickness of 1.53 mm.
  • the phase transition temperature (Tg) of the resin layer taken from the fireproof sheet was 96°C.
  • the mechanical properties and abrasion durability are as shown in Table 1, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was B.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • the combustion length was within the acceptable range and the mass reduction rate was excellent at 4.2%.
  • the sensory evaluation of the comfort of the seat cushion was 3.0 points.
  • Example 3 Manufacture of fiber base layer
  • the same fiber base layer as that produced in Example 1 was used as the fiber base layer.
  • a resin liquid was prepared, knife coated, and dried in the same proportions as in Example 1, except that the resin was changed from acrylic resin E-1 to vinyl chloride resin E-3.
  • the coating amount was 46 g/m 2
  • the obtained fireproof sheet had a basis weight of 196 g/m 2 and a thickness of 1.51 mm.
  • the phase transition temperature (Tg) of the resin layer taken from the fireproof sheet was 82°C.
  • the mechanical properties and abrasion durability are as shown in Table 1, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was B.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • the combustion length was within the acceptable range and the mass reduction rate was excellent at 3.6%.
  • the sensory evaluation of the comfort of the seat cushion was 3.0 points.
  • Example 4 Manufacture of fiber base layer and reinforcing layer
  • the drawn PPS fibers and flame-resistant fibers are mixed in a spreader so that the mass blend ratio of drawn PPS fibers and flame-resistant fibers is 20:80, then further mixed in a mixing and batting machine, and then passed through a carding machine to form a web.
  • the obtained web was laminated using a cross-lap machine, and then felted using a needle punch machine to obtain a felt having a basis weight of 62 g/m 2 .
  • the obtained felt and reinforcing layer 1 were further bonded using a needle punch machine to obtain a fiber sheet having a basis weight of 171 g/m 2 and a thickness of 1.78 mm.
  • Example 2 Manufacture of fireproof sheet
  • the coating amount was 39 g/m 2
  • the obtained fireproof sheet had a basis weight of 210 g/m 2 and a thickness of 1.89 mm.
  • the phase transition temperature (Tg) of the resin layer taken from the fireproof sheet was -5°C.
  • the mechanical properties and abrasion durability are as shown in Table 1, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was B.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • a urethane cushion was coated with the obtained fireproof sheet and a flame retardant test was conducted on the seat cushion, the combustion length was within the acceptable range and the mass reduction rate was excellent at 3.9%.
  • the sensory evaluation of the comfort of the seat cushion was 2.7 points.
  • Example 5 Manufacture of fiber base layer and reinforcing layer
  • the drawn PPS fibers and the flame-resistant fibers are mixed by a spreader so that the mass blend ratio of the drawn PPS fibers and the flame-resistant fibers is 60:40, then further mixed by a mixing and batting machine, and then passed through a card machine to form a web.
  • the obtained web was laminated using a cross-lap machine, and then felted using a needle punch machine to obtain a felt having a basis weight of 150 g/m 2 .
  • the obtained felt and reinforcing layer 2 were further bonded using a needle punch machine to obtain a fiber sheet having a basis weight of 175 g/m 2 and a thickness of 1.42 mm.
  • Example 2 Manufacture of fireproof sheet
  • the coating amount was 43 g/m 2
  • the resulting fireproof sheet had a basis weight of 218 g/m 2 and a thickness of 1.44 mm.
  • the phase transition temperature (Tg) of the resin layer taken from the fireproof sheet was -6°C.
  • the mechanical properties and abrasion durability are as shown in Table 2, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was B.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • the combustion length was within the acceptable range and the mass reduction rate was 7.8%, which was within the acceptable range.
  • the sensory evaluation of the comfort of the seat cushion was 2.7 points.
  • Example 6 Manufacture of fiber base layer
  • the drawn PPS fibers and flame-resistant fibers are mixed in a spreader so that the mass blend ratio of drawn PPS fibers and flame-resistant fibers is 10:90, then further mixed in a mixing and batting machine, and then passed through a carding machine to form a web.
  • the obtained web was laminated using a cross-lap machine and then felted using a needle punch machine to obtain a fiber base material layer having a basis weight of 156 g/m 2 and a thickness of 1.65 mm.
  • Example 2 Manufacture of fireproof sheet
  • the coating amount was 45 g/m 2
  • the obtained fireproof sheet had a basis weight of 201 g/m 2 and a thickness of 1.64 mm.
  • the phase transition temperature (Tg) of the resin layer taken from the fireproof sheet was -9°C.
  • the mechanical properties and abrasion durability are as shown in Table 2, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was B.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • a urethane cushion was coated with the obtained fireproof sheet and a flame retardant test was conducted on the seat cushion, the combustion length was within the acceptable range and the mass reduction rate was 7.9%, which was within the acceptable range.
  • the sensory evaluation of the comfort of the seat cushion was 3.0 points.
  • Example 7 Manufacture of fiber base layer
  • the drawn PPS fibers and the flame-resistant fibers are mixed by a spreader so that the mass blend ratio of the drawn PPS fibers and the flame-resistant fibers is 90:10, then further mixed by a mixing and batting machine, and then passed through a carding machine to form a web.
  • the resulting web was laminated using a cross-lap machine and then felted using a needle punch machine to obtain a fiber base material layer having a basis weight of 154 g/m 2 and a thickness of 1.45 mm.
  • Example 2 Manufacture of fireproof sheet
  • the coating amount was 46 g/m 2
  • the obtained fireproof sheet had a basis weight of 200 g/m 2 and a thickness of 1.59 mm.
  • the phase transition temperature (Tg) of the resin layer taken from the fireproof sheet was -8°C.
  • the mechanical properties and abrasion durability are as shown in Table 2, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was B.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • the resulting fireproof sheet was coated on a urethane cushion, and a flame retardant test was conducted on the seat cushion.
  • the combustion length was within the acceptable range, and the mass reduction rate was 8.9%, which was within the acceptable range.
  • the sensory evaluation of the comfort of the seat cushion was 2.7 points.
  • Example 8 (Manufacture of fiber base layer and reinforcing layer) Stretched PPS fibers and meta-aramid fibers are mixed in a spreader so that the mass blend ratio of stretched PPS fibers and meta-aramid fibers is 60:40, then further mixed in a mixing and batting machine, and then passed through a carding machine to produce a web. did. The obtained web was laminated using a cross-lap machine and then felted using a needle punch machine to obtain a fiber sheet having a basis weight of 152 g/m 2 and a thickness of 1.45 mm.
  • Example 2 Manufacture of fireproof sheet
  • the coating amount was 45 g/m 2
  • the obtained fireproof sheet had a basis weight of 197 g/m 2 and a thickness of 1.55 mm.
  • the phase transition temperature (Tg) of the resin layer taken from the fireproof sheet was -7°C.
  • the mechanical properties and abrasion durability are as shown in Table 2, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was B.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • a urethane cushion was coated with the obtained fireproof sheet and a flame retardant test was conducted on the seat cushion, the combustion length was within the acceptable range and the mass reduction rate was excellent at 4.9%.
  • the sensory evaluation of the comfort of the seat cushion was 2.3 points.
  • Example 9 Manufacture of fiber base layer and reinforcing layer
  • the drawn PPS fibers and para-aramid fibers are mixed in a spreader so that the mass blend ratio of drawn PPS fibers and para-aramid fibers is 60:40, then further mixed in a mixing and batting machine, and then passed through a carding machine to form a web.
  • the obtained web was laminated using a cross-lap machine and then felted using a needle punch machine to obtain a fiber sheet having a basis weight of 150 g/m 2 and a thickness of 1.46 mm.
  • Example 2 Manufacture of fireproof sheet
  • the coating amount was 43 g/m 2
  • the obtained fireproof sheet had a basis weight of 193 g/m 2 and a thickness of 1.53 mm.
  • the phase transition temperature (Tg) of the resin layer taken from the fireproof sheet was -8°C.
  • the mechanical properties and abrasion durability are as shown in Table 3, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was B.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • the combustion length was within the acceptable range and the mass reduction rate was excellent at 4.2%.
  • the sensory evaluation of the comfort of the seat cushion was 2.3 points.
  • Example 10 (Manufacture of fiber base layer and reinforcing layer) Stretched PPS fibers and phenolic fibers are mixed using a spreader so that the mass blend ratio of the stretched PPS fibers and phenolic fibers is 60:40, then further mixed using a mixing and batting machine, and then passed through a carding machine to produce a web. did. The obtained web was laminated using a cross-lap machine and then felted using a needle punch machine to obtain a fiber sheet having a basis weight of 152 g/m 2 and a thickness of 1.44 mm.
  • Example 2 Manufacture of fireproof sheet
  • the coating amount was 45 g/m 2
  • the obtained fireproof sheet had a basis weight of 197 g/m 2 and a thickness of 1.56 mm.
  • the phase transition temperature (Tg) of the resin layer taken from the fireproof sheet was -7°C.
  • the mechanical properties and abrasion durability are as shown in Table 3, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was B.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • the obtained fireproof sheet was coated on a urethane cushion, and the seat cushion was subjected to a flame retardant test.
  • the combustion length was within the acceptable range, and the mass reduction rate was 5.8%, which was within the acceptable range.
  • the sensory evaluation of the comfort of the seat cushion was 2.7 points.
  • Example 11 Manufacture of fiber base layer and reinforcing layer
  • the drawn PPS fibers, the anisotropic molten polyester, and the flame-resistant fibers are mixed using a fiber opening machine so that the mass blend ratio of the drawn PPS fibers, the anisotropic molten polyester, and the flame-resistant fibers are 20:40:40, respectively. Further mixing was performed by a batting machine and then passed through a carding machine to form a web. The obtained web was laminated using a cross-lap machine and then felted using a needle punch machine to obtain a fiber sheet having a basis weight of 157 g/m 2 and a thickness of 1.57 mm.
  • Example 2 Manufacture of fireproof sheet
  • the coating amount was 44 g/m 2
  • the obtained fireproof sheet had a basis weight of 201 g/m 2 and a thickness of 1.65 mm.
  • the phase transition temperature (Tg) of the resin layer taken from the fireproof sheet was -7°C.
  • the mechanical properties and abrasion durability are as shown in Table 3, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was B.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • a urethane cushion was coated with the obtained fireproof sheet and a flame retardant test was conducted on the seat cushion, the combustion length was within the acceptable range and the mass reduction rate was excellent at 4.3%.
  • the sensory evaluation of the comfort of the seat cushion was 2.3 points.
  • Example 12 (Manufacture of fiber base layer and reinforcing layer) Flame-retardant PET fibers and flame-retardant fibers are mixed in a spreader so that the mass blend ratio of flame-retardant PET fibers and flame-retardant fibers is 60:40, then further mixed in a mixing and batting machine, and then passed through a carding machine. A web was created. The obtained web was laminated using a cross-lap machine and then felted using a needle punch machine to obtain a fiber sheet having a basis weight of 152 g/m 2 and a thickness of 1.44 mm.
  • Example 2 Manufacture of fireproof sheet
  • the coating amount was 43 g/m 2
  • the resulting fireproof sheet had a basis weight of 195 g/m 2 and a thickness of 1.47 mm.
  • the phase transition temperature (Tg) of the resin layer taken from the fireproof sheet was -8°C.
  • the mechanical properties and abrasion durability are as shown in Table 3, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was B.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • the obtained fireproof sheet was coated on a urethane cushion, and the seat cushion was subjected to a flame retardant test.
  • the combustion length was within the acceptable range, and the mass reduction rate was 9.1%, which was within the acceptable range.
  • the sensory evaluation of the comfort of the seat cushion was 3.0 points.
  • Example 13 Manufacture of fiber base layer and reinforcing layer
  • the same fiber base layer as that produced in Example 4 was used as the fiber base layer.
  • a resin liquid was prepared, knife coated, and dried in the same proportions as in Example 1, except that expandable graphite D-1 was changed to D-4.
  • the coating amount was 41 g/m 2
  • the obtained fireproof sheet had a basis weight of 212 g/m 2 and a thickness of 1.89 mm.
  • the mechanical properties and abrasion durability are as shown in Table 4, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was B.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • the obtained fireproof sheet was coated on a urethane cushion, and the seat cushion was subjected to a flame retardant test.
  • the combustion length was within the acceptable range, and the mass reduction rate was 8.7%, which was within the acceptable range.
  • the sensory evaluation of the comfort of the seat cushion was 2.7 points.
  • Example 14 Manufacture of fiber base layer and reinforcing layer
  • the same fiber base layer as that produced in Example 4 was used as the fiber base layer.
  • a resin liquid was prepared, knife coated, and dried in the same proportions as in Example 1, except that expandable graphite D-1 was changed to D-5.
  • the coating amount was 43 g/m 2
  • the obtained fireproof sheet had a basis weight of 214 g/m 2 and a thickness of 1.90 mm.
  • the mechanical properties and abrasion durability are as shown in Table 4, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was A, which was excellent.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • a urethane cushion was coated with the obtained fireproof sheet and a flame retardant test was conducted on the seat cushion, the combustion length was within the acceptable range and the mass reduction rate was excellent at 4.0%.
  • the sensory evaluation of the comfort of the seat cushion was 2.7 points.
  • Example 15 Manufacture of fiber base layer
  • the same fiber base layer as that produced in Example 4 was used as the fiber base layer.
  • the mechanical properties and abrasion durability are as shown in Table 4, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was A, which was excellent.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • the combustion length was within the acceptable range and the mass reduction rate was excellent at 2.9%.
  • the sensory evaluation of the comfort of the seat cushion was a low 1.3 points.
  • Example 2 Manufacture of fireproof sheet
  • the coating amount was 43 g/m 2
  • the obtained fireproof sheet had a basis weight of 210 g/m 2 and a thickness of 1.61 mm.
  • the phase transition temperature (Tg) of the resin layer taken from the fireproof sheet was -8°C.
  • the mechanical properties and abrasion durability are as shown in Table 5, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was B.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • the obtained fireproof sheet was coated on a urethane cushion and the seat cushion was subjected to a flame retardant test, and the combustion length failed and the mass reduction rate failed at 27.8%.
  • the sensory evaluation of the comfort of the seat cushion was 3.0 points.
  • Example 2 Manufacture of fireproof sheet
  • the coating amount was 45 g/m 2
  • the obtained fireproof sheet had a basis weight of 245 g/m 2 and a thickness of 0.65 mm.
  • the phase transition temperature (Tg) of the resin layer taken from the fireproof sheet was -6°C.
  • the mechanical properties and abrasion durability are as shown in Table 5, and satisfied sufficient physical properties.
  • the abrasion durability of the expandable graphite was B.
  • self-extinguishment was achieved within a 38 mm gauge line.
  • both char length and afterflame failed, and when the resulting fireproof sheet was covered with a urethane cushion and a seat cushion flame retardant test was conducted, the test piece completely burned down.
  • the sensory evaluation of the comfort of the seat cushion was 3.0 points.
  • the mechanical properties and abrasion durability are as shown in Table 5, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was A, which was excellent.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • the obtained fireproof sheet was coated on a urethane cushion, and a flame retardant test was conducted on the seat cushion. Although the combustion length was within the acceptable range, the mass reduction rate was 15.6%, which was a failure.
  • the sensory evaluation of the comfort of the seat cushion was 2.0 points.
  • a resin liquid was prepared in the same proportion as in Example 1, except that the resin was changed from acrylic resin E-1 to melamine resin E-4, and the expandable graphite was changed from D-1 to D-2. A coat was applied and dried. The coating amount was 44 g/m 2 , and the resulting fireproof sheet had a basis weight of 194 g/m 2 and a thickness of 1.59 mm. No phase transition temperature was observed in the resin layer taken from the fireproof sheet.
  • the mechanical properties and abrasion durability are as shown in Table 5, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was A, which was excellent.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • the obtained fireproof sheet was coated on a urethane cushion, and a flame retardant test was conducted on the seat cushion. Although the combustion length was within the acceptable range, the mass reduction rate was 15.9%, which was a failure.
  • the sensory evaluation of the comfort of the seat cushion was 2.0 points.
  • a resin liquid was prepared in the same proportion as in Example 1, except that the resin was changed from acrylic resin E-1 to melamine resin E-4, and the expandable graphite was changed from D-1 to D-3. A coat was applied and dried. The coating amount was 45 g/m 2 , and the obtained fireproof sheet had a basis weight of 195 g/m 2 and a thickness of 1.56 mm. No phase transition temperature was observed in the resin layer taken from the fireproof sheet.
  • the mechanical properties and abrasion durability are as shown in Table 6, and the properties were sufficient for a fire-resistant sheet.
  • the abrasion durability of the expandable graphite was A, which was excellent.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • the obtained fireproof sheet was coated on a urethane cushion, and the seat cushion was subjected to a flame retardant test. Although the combustion length was within the acceptable range, the mass reduction rate was 20.8%, which was a failure.
  • the sensory evaluation of the comfort of the seat cushion was 2.0 points.
  • the above fiber base material layer was used as it was without forming a resin layer containing expandable graphite.
  • the mechanical properties and abrasion durability are as shown in Table 7, and the properties were sufficient for a fire-resistant sheet.
  • the flame retardant test for automobile interior materials showed self-extinguishment within a 38 mm gauge line, and the flame retardant test for aircraft interior materials had good results.
  • the combustion length was within the acceptable range and the mass reduction rate was 9.2%, which was within the acceptable range.
  • the sensory evaluation of the comfort of the seat cushion was 3.0 points.
  • Example 1 Comparing Example 1 and Reference Example 1, it is found that the fire-resistant sheet of the present invention, which includes a fiber base layer and a resin layer containing expandable graphite, is more effective than the sheet of Reference Example 1, which does not use a resin layer containing expandable graphite. This shows that even if the total basis weight of the fireproof sheet is the same and the thickness is thinner, the fire resistance and durability are improved.
  • the blend ratio of the fiber base material layer is the same, but the fiber base material layer is about 40 g/ m2 less, and instead, a resin layer containing expandable graphite is formed, so that the total basis weight is about the same. be.
  • the mass reduction rate of the urethane cushion is clearly smaller, indicating that the fire resistance is improved by combining with the resin layer containing expandable graphite.
  • the fireproof sheet of the present invention has excellent durability and high flame retardancy. Furthermore, coated articles with excellent flame retardancy can be obtained even when ordinary cushion foam is used instead of using cushions, whose stiffness is difficult to adjust due to the use of flame retardants, and as a result, coated articles with a soft texture can be obtained. It can be done.
  • Example 14 by adjusting the particle size distribution of the expandable graphite, the abrasion durability of the expandable graphite can be further improved.
  • the present invention has excellent flame retardancy, exhibits an excellent fire spread prevention effect when coated on combustible materials, and has excellent physical properties such as texture and abrasion durability, so it is suitable for automobiles, railways, ships, etc. It is suitable for use in interior materials such as seats, headrests, tonneau covers, sun visors, ceilings, etc., interior materials for high-rise buildings and public facilities, and surface materials for furniture (chairs, sofas, etc.), but requires high flame retardancy. It can be particularly suitably used for the interior of aircraft seats.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Laminated Bodies (AREA)
PCT/JP2023/006970 2022-03-17 2023-02-27 耐火シートおよび被覆物品 Ceased WO2023176391A1 (ja)

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EP23770350.9A EP4494862A1 (en) 2022-03-17 2023-02-27 Fire resistant sheet and covered article
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2025182458A1 (ja) * 2024-02-27 2025-09-04 東レ株式会社 シートおよびそれを用いた耐火材、二次電池
WO2025258497A1 (ja) * 2024-06-13 2025-12-18 東レ株式会社 遮炎断熱材

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017006807A1 (ja) * 2015-07-03 2017-01-12 東レ株式会社 遮炎性不織布
JP2018162628A (ja) 2017-03-27 2018-10-18 ケイミュー株式会社 耐火シート
JP2018172597A (ja) 2017-03-31 2018-11-08 東ソー株式会社 難燃性熱硬化性ポリウレタンフォーム
JP2019096410A (ja) * 2017-11-20 2019-06-20 タイガースポリマー株式会社 耐火積層体及びこれを用いた筒状積層体並びに電池隔離構造
WO2019188276A1 (ja) 2018-03-30 2019-10-03 東レ株式会社 不織布シート
JP2019213629A (ja) 2018-06-12 2019-12-19 タイガースポリマー株式会社 熱膨張性耐火材料および耐火成形体
JP2021195461A (ja) * 2020-06-15 2021-12-27 積水化学工業株式会社 熱膨張性耐火材

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2019188197A1 (ja) * 2018-03-29 2021-02-12 東レ株式会社 織編物
JP7283480B2 (ja) * 2019-04-25 2023-05-30 東レ株式会社 合成皮革および被覆物品

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017006807A1 (ja) * 2015-07-03 2017-01-12 東レ株式会社 遮炎性不織布
JP2018162628A (ja) 2017-03-27 2018-10-18 ケイミュー株式会社 耐火シート
JP2018172597A (ja) 2017-03-31 2018-11-08 東ソー株式会社 難燃性熱硬化性ポリウレタンフォーム
JP2019096410A (ja) * 2017-11-20 2019-06-20 タイガースポリマー株式会社 耐火積層体及びこれを用いた筒状積層体並びに電池隔離構造
WO2019188276A1 (ja) 2018-03-30 2019-10-03 東レ株式会社 不織布シート
JP2019213629A (ja) 2018-06-12 2019-12-19 タイガースポリマー株式会社 熱膨張性耐火材料および耐火成形体
JP2021195461A (ja) * 2020-06-15 2021-12-27 積水化学工業株式会社 熱膨張性耐火材

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2025182458A1 (ja) * 2024-02-27 2025-09-04 東レ株式会社 シートおよびそれを用いた耐火材、二次電池
JP7740598B1 (ja) * 2024-02-27 2025-09-17 東レ株式会社 シートおよびそれを用いた耐火材、二次電池
WO2025258497A1 (ja) * 2024-06-13 2025-12-18 東レ株式会社 遮炎断熱材

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