WO2023135445A1 - Procédé de production de biocharbon - Google Patents

Procédé de production de biocharbon Download PDF

Info

Publication number
WO2023135445A1
WO2023135445A1 PCT/IB2022/050224 IB2022050224W WO2023135445A1 WO 2023135445 A1 WO2023135445 A1 WO 2023135445A1 IB 2022050224 W IB2022050224 W IB 2022050224W WO 2023135445 A1 WO2023135445 A1 WO 2023135445A1
Authority
WO
WIPO (PCT)
Prior art keywords
coal
bio
raw materials
sintering furnace
production method
Prior art date
Application number
PCT/IB2022/050224
Other languages
English (en)
Chinese (zh)
Inventor
钟永康
钟沛熙
Original Assignee
钟永康
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 钟永康 filed Critical 钟永康
Priority to PCT/IB2022/050224 priority Critical patent/WO2023135445A1/fr
Publication of WO2023135445A1 publication Critical patent/WO2023135445A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/08—Non-mechanical pretreatment of the charge, e.g. desulfurization
    • C10B57/10—Drying
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00—Solid fuels
    • C10L5/40—Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel

Definitions

  • the invention relates to a method for making bio-coal by regenerating plant waste.
  • sulfur dioxide SO2
  • SO2 sulfur dioxide
  • the residue left over from coal after complete combustion is called ash, extrinsic ash and intrinsic ash.
  • the external ash comes from the rock fragments in the roof and the interlayer, and it has a lot to do with the reasonableness of the coal mining method. Most of the external ash can be removed by sorting.
  • Intrinsic ash is the inorganic matter contained in the original coal-forming plant itself. The higher the intrinsic ash, the poorer the selectivity of coal. Ash is a harmful substance.
  • the increase of ash content in steam coal will reduce the calorific value and increase the amount of slag discharge, and the coal will be prone to slagging; generally, for every 2% increase in ash content, the calorific value will decrease by about 100kcal/kg.
  • the present invention provides a method for producing bio-coal, which uses discarded plant parts as raw materials to produce bio-coal with high calorific value, low emission and low price.
  • the present invention achieves the above object like this:
  • the preparation method of biological coal comprises the following steps:
  • the sintering furnace stops heating and maintains negative pressure, the molten raw material cools down and crystallizes into bio-coal crystals.
  • the raw materials before placing the raw materials into the sintering furnace in step S1-1, the raw materials need to be dried to control the water content of the raw materials within 15%.
  • step S2-3 the solidified bio-coal is also cut into shape, and the bio-coal crystal waste generated by cutting is recycled and re-fed to step S2-2 after mixing the crystal powder. Formed in one go.
  • the negative pressure is minus one atmosphere.
  • the discarded plant parts include palm, coconut, corn, canola, rice, barley, wheat branches, leaves, stems, roots, seed shells, and waste wood.
  • the discarded plant parts include seaweed and seaweed.
  • the finished product of bio-coal is oval.
  • the preparation method of biological coal comprises the following steps:
  • the waste parts of the plants come from a wide range of sources, such as terrestrial annual or perennial plants, such as branches, leaves, stems, roots, and seed shells of palm, coconut, corn, canola, rice, barley, and wheat , waste wood, etc., can also use plants growing in the ocean, such as seaweed and seaweed, etc., so the source of raw materials is very extensive, abundant and low in cost.
  • sources such as terrestrial annual or perennial plants, such as branches, leaves, stems, roots, and seed shells of palm, coconut, corn, canola, rice, barley, and wheat , waste wood, etc.
  • the raw materials need to be dried, and the water content of raw materials needs to be controlled within 15%.
  • the present invention preferably uses negative pressure, and the negative pressure is minus one atmospheric pressure, that is, a vacuum environment.
  • the sintering temperature needs to be adjusted or selected according to the characteristics of different raw materials.
  • a lower sintering temperature can be selected for raw materials with relatively soft materials and smaller sizes, such as plant leaves, straw and other materials. The lower temperature is enough to completely melt such raw materials.
  • a higher temperature should be selected so that the raw material can be fully melted.
  • the main element of the raw material is hydrocarbon, which will be carbonized first under vacuum or high temperature. After a certain period of time, the carbonized substance will melt and be sintered after exceeding its melting point.
  • the sintering furnace stops heating and maintains negative pressure, the molten raw material cools down and crystallizes into bio-coal crystals.
  • the overall shape of the bio-coal crystals obtained by sintering is similar to that of the raw materials, so it is very unfavorable for transportation and storage, and the stacking of bio-coal crystals may affect the combustion effect during combustion. To this end, it is also necessary to carry out a shaping operation on the bio-coal crystals.
  • the operation steps are as follows:
  • the molded mixture is placed in an oven and heated to 90-200°C for curing.
  • the curing temperature depends on the curing temperature of the glue used. Due to factors such as mold clamping accuracy and the amount of mixture added, the solidified bio-coal will have burrs, etc., so it needs to be cut and shaped.
  • the bio-coal crystal waste produced by cutting and molding is recovered and re-fed into step S2-2, where the crystal powder is mixed and then re-molded.
  • the bio-coal product is oval in shape. When this shape is used, an appropriate gap can still be reserved between the bio-coal products in the stacked combustion chamber, so that air can circulate in the gap, which is more conducive to the combustion.
  • the sources of discarded plant parts mentioned above can be very wide, and can be any discarded parts of annual or perennial plants. Some specific examples are given below to illustrate: Land plants, including palm, coconut, corn, mustard Flower seeds, rice, barley, wheat branches, leaves, stems, roots, seed shells, waste wood; marine plants, including seaweed and seaweed, etc.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

Procédé de production de biocharbon, dans lequel des parties de plantes éliminées sont utilisées comme matière première, un frittage est réalisé sous vide et dans un environnement à haute température, un biocharbon présentant un pouvoir calorifique élevé, de faibles émissions et un faible prix est produit. Par comparaison avec du charbon actuellement utilisé, des gaz polluants, tels que le dioxyde de soufre, le sulfure d'hydrogène, l'oxyde nitrique et analogues, qui sont générés au cours d'une combustion peuvent être considérablement réduits, de sorte que la combustion est plus propre. Selon un autre aspect, le pouvoir calorifique généré par la combustion du produit fini obtenu est de 15 à 20 % plus élevé que le pouvoir calorifique du charbon, de sorte que ledit procédé peut être largement appliqué à la fusion de l'acier, à la génération d'énergie thermique et analogues et représente une source d'énergie substitut du charbon plus idéale et respectueuse de l'environnement.
PCT/IB2022/050224 2022-01-13 2022-01-13 Procédé de production de biocharbon WO2023135445A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/IB2022/050224 WO2023135445A1 (fr) 2022-01-13 2022-01-13 Procédé de production de biocharbon

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IB2022/050224 WO2023135445A1 (fr) 2022-01-13 2022-01-13 Procédé de production de biocharbon

Publications (1)

Publication Number Publication Date
WO2023135445A1 true WO2023135445A1 (fr) 2023-07-20

Family

ID=87280153

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2022/050224 WO2023135445A1 (fr) 2022-01-13 2022-01-13 Procédé de production de biocharbon

Country Status (1)

Country Link
WO (1) WO2023135445A1 (fr)

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1810928A (zh) * 2006-03-07 2006-08-02 李峰耀 一种生物质固化炭化气化综合应用方法
CN1858158A (zh) * 2006-05-17 2006-11-08 江国庆 高温炭的烧制方法
CN1931974A (zh) * 2006-10-13 2007-03-21 黄振华 生产无煤蜂窝煤的制作方法及其设备
US20100263271A1 (en) * 2009-04-21 2010-10-21 Lai Kuei Tsai Clean burning bio-coal
CN103242928A (zh) * 2012-02-03 2013-08-14 中国钢铁股份有限公司 生物质煤的制造方法
CN108003959A (zh) * 2017-12-05 2018-05-08 北京科技大学 生物质炭化代替煤粉喷吹高炉内的方法
CN109575967A (zh) * 2018-12-17 2019-04-05 轻工业环境保护研究所 利用农林废弃物制备生物炭及生物质活性炭的方法
TWI701214B (zh) * 2019-07-19 2020-08-11 陳宣甫 高溫生成之生物炭製備方法
US10865356B1 (en) * 2020-08-14 2020-12-15 Komax Systems, Inc. Torrefaction process
CN114525149A (zh) * 2022-01-11 2022-05-24 钟永康 生物煤的制作方法

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1810928A (zh) * 2006-03-07 2006-08-02 李峰耀 一种生物质固化炭化气化综合应用方法
CN1858158A (zh) * 2006-05-17 2006-11-08 江国庆 高温炭的烧制方法
CN1931974A (zh) * 2006-10-13 2007-03-21 黄振华 生产无煤蜂窝煤的制作方法及其设备
US20100263271A1 (en) * 2009-04-21 2010-10-21 Lai Kuei Tsai Clean burning bio-coal
CN103242928A (zh) * 2012-02-03 2013-08-14 中国钢铁股份有限公司 生物质煤的制造方法
CN108003959A (zh) * 2017-12-05 2018-05-08 北京科技大学 生物质炭化代替煤粉喷吹高炉内的方法
CN109575967A (zh) * 2018-12-17 2019-04-05 轻工业环境保护研究所 利用农林废弃物制备生物炭及生物质活性炭的方法
TWI701214B (zh) * 2019-07-19 2020-08-11 陳宣甫 高溫生成之生物炭製備方法
US10865356B1 (en) * 2020-08-14 2020-12-15 Komax Systems, Inc. Torrefaction process
CN114525149A (zh) * 2022-01-11 2022-05-24 钟永康 生物煤的制作方法

Similar Documents

Publication Publication Date Title
CN102260567B (zh) 一种铁矿烧结用生物质成型燃料及应用
CN103937574B (zh) 一种生物质颗粒燃料
CN114525149A (zh) 生物煤的制作方法
CN110257575A (zh) 一种基于水热反应处理农林废弃物制备炭化物用于高炉喷煤的工艺
CN110218826A (zh) 一种生物质水热炭进行高炉喷吹的方法
CN105087098B (zh) 用于循环流化床锅炉的抗结渣生物质复合燃料
JP6142765B2 (ja) 焼結鉱の製造方法
KR101409516B1 (ko) 소결광의 제조 방법
CN105154164A (zh) 一种生物质颗粒燃料的添加剂及其制备方法
WO2024174972A1 (fr) Engrais de phosphate de calcium et de magnésium amélioré par des déchets solides combustibles à valeur calorifique élevée, procédé de préparation s'y rapportant et utilisation associée
CN109401791B (zh) 一种气化炉灰渣干燥熔融炉气化工艺
CN107586220B (zh) 一种生物炭基尿素肥料的渗透融合成肥方法
CN113862009A (zh) 有机废弃物三无法热解气化制取绿氢能联产生物炭的方法
WO2023135445A1 (fr) Procédé de production de biocharbon
CN101824348A (zh) 利用橡胶籽壳制备生物质致密燃料的方法
CN102010770A (zh) 一种复合生物质颗粒燃料
CN106520246A (zh) 一种生物质成型燃料应用于配煤炼焦的方法
CN108329970A (zh) 一种环保型生物质燃料及制备方法
CN101705130A (zh) 以秸秆为主要原料制备的环保固化煤
CN101220310A (zh) 一种利用秸秆生产燃料的加工工艺
CN114381310A (zh) 一种生物质木屑颗粒燃料及其制备方法
CN101638601A (zh) 永生煤
CN207877601U (zh) 一种熔融镍渣制备镁橄榄石的系统
CN106517120A (zh) 一种窑法制磷酸联产轻质骨料的方法
CN107177394B (zh) 一种耐贮存的生物质燃料的加工方法

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 22920129

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE