WO2023125894A1 - Cold-source schottky transistor and preparation process therefor - Google Patents

Cold-source schottky transistor and preparation process therefor Download PDF

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Publication number
WO2023125894A1
WO2023125894A1 PCT/CN2022/143750 CN2022143750W WO2023125894A1 WO 2023125894 A1 WO2023125894 A1 WO 2023125894A1 CN 2022143750 W CN2022143750 W CN 2022143750W WO 2023125894 A1 WO2023125894 A1 WO 2023125894A1
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region
source
drain
metal
layer
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PCT/CN2022/143750
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French (fr)
Chinese (zh)
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刘飞
谢晓鑫
刘晓彦
康晋锋
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北京大学
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66568Lateral single gate silicon transistors
    • H01L29/66643Lateral single gate silicon transistors with source or drain regions formed by a Schottky barrier or a conductor-insulator-semiconductor structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/7839Field effect transistors with field effect produced by an insulated gate with Schottky drain or source contact

Definitions

  • the invention relates to the technical field of semiconductors, in particular to a cold source Schottky transistor and a preparation process thereof.
  • MOSFETs metal-oxide-semiconductor field-effect transistors
  • SS sub-threshold swing
  • the invention provides a cold-source Schottky transistor and its preparation process, which are used to solve the defect that the sub-threshold swing of the MOSFET cannot exceed 60mV/dec in the prior art, so that the power supply voltage and power consumption of the MOSFET device cannot be further reduced.
  • the invention provides a cold source Schottky transistor, comprising:
  • the source region comprising a first source region and a metal region connected to the first source region, the first source region being a heavily doped region;
  • drain region disposed on the substrate, the drain region is a heavily doped region, and the doping type of the drain region is opposite to that of the first source region;
  • a channel region disposed on the substrate, the channel region is located between the metal region and the drain region, and a gate dielectric is provided on the upper side and/or lower side of the channel region;
  • the gate is arranged on the gate dielectric.
  • the channel region is an intrinsic region or a lightly doped region.
  • the first source region is a P-type heavily doped region
  • the drain region is an N-type heavily doped region
  • the first source region is an N-type heavily doped region
  • the drain region is a P-type heavily doped region
  • the doping concentration of the first source region is 1e 19 cm -3 -1e 22 cm -3 , and the length of the first source region is 20 nm, so The thickness of the first source region is 10 nm.
  • the doping concentration of the drain region is 1e 19 cm -3 -1e 22 cm -3 , and the length of the drain region is 20 nm, and the drain region The thickness is 10nm.
  • the doping concentration of the channel region is 1e 15 cm -3 , the length of the channel region is 20nm, and the thickness of the channel region is 10nm .
  • the work function of the metal region is 5.0 eV
  • the length of the metal region is 10 nm
  • the thickness of the metal region is 10 nm.
  • the material of the first source region, the drain region and the channel region is silicon.
  • the present invention also provides a preparation process of a cold source Schottky transistor, comprising:
  • a gate is formed on the gate dielectric, a source is formed on the metal region and the first source region, and a drain is formed on the drain region.
  • the formation of a metal region on the source terminal includes:
  • Etching the metal layer to remove the metal layer on the channel region and part of the metal layer at the source end;
  • the hard mask and the metal layer on the surface of the hard mask are removed.
  • the formation of the first source region on the source end and the drain region on the drain end includes:
  • Pre-amorphization implantation doping is performed on the first source region material layer and the drain region material layer to form the first source region and the drain region.
  • the source region of the cold source Schottky transistor is composed of a heavily doped first source region and a metal region, and the metal region is in contact with the channel region, and the metal region is in contact with the channel region.
  • a Schottky barrier is formed between the channel regions. In the case of no gate voltage, because the Schottky barrier is very wide, it is difficult for electrons in the source region to tunnel through the Schottky barrier.
  • the forbidden band filters the electrons injected by the external electrodes, and the thermal current is greatly reduced in the forbidden band energy range of the first source region, so that the corresponding off-state current will be very low.
  • the Schottky barrier between the channel region and the metal region is lowered, making the Schottky barrier thinner until the low-energy region
  • the tunneling current will increase rapidly, and the electrons in the low-energy region of the source region tunnel through the Schottky barrier, so that the subthreshold swing can be lower than 60mV/dec.
  • Fig. 1 is the structural representation of the cold source Schottky transistor provided by the present invention
  • Fig. 2 is the energy band structure diagram of the cold source Schottky transistor provided by the present invention without applying a bias voltage
  • Fig. 3 is the energy band structure diagram of the cold source Schottky transistor under the condition of applying positive bias provided by the present invention
  • Fig. 4 is the graph of Id-Vg provided by the present invention.
  • Fig. 5 is a side view of the device generated in step S1 provided by the present invention.
  • Fig. 6 is a side view of the device generated in step S2 provided by the present invention.
  • Fig. 7 is a side view of the device generated in step S3 provided by the present invention.
  • Fig. 8 is a side view of the device generated in step S4 provided by the present invention.
  • Fig. 9 is a side view of the device generated in step S5 provided by the present invention.
  • Fig. 10 is a side view of the device generated in step S6 provided by the present invention.
  • Fig. 11 is a side view of the device generated in step S7 provided by the present invention.
  • Fig. 12 is a side view of the device generated in step S8 provided by the present invention.
  • Fig. 13 is a side view of the device generated in step S9 provided by the present invention.
  • FIG. 14 and FIG. 15 are respectively a top view and a side view of the device generated in step S10 provided by the present invention.
  • Fig. 16 is a side view of the device generated in step S11 provided by the present invention.
  • Fig. 17 is a side view of the device generated in step S12 provided by the present invention.
  • Fig. 18 is a side view of the device generated in step S13 provided by the present invention.
  • FIG. 19 and FIG. 20 are respectively a top view and a side view of the device generated in step S14 provided by the present invention.
  • FIG. 21 and FIG. 22 are respectively a top view and a side view of the device generated in step S15 provided by the present invention.
  • Figure 23 and Figure 24 are the top view and side view of the device generated in step S16 provided by the present invention, respectively;
  • Figure 25 and Figure 26 are the top view and side view of the device generated in step S17 provided by the present invention, respectively;
  • FIG. 27 and FIG. 28 are respectively a top view and a side view of the device generated in step S18 provided by the present invention.
  • FIG. 29 and FIG. 30 are respectively a top view and a side view of the device generated in step S19 provided by the present invention.
  • FIG. 31 and FIG. 32 are respectively a top view and a side view of the device generated in step S20 provided by the present invention.
  • Figure 33 and Figure 34 are respectively the top view and the side view of the device generated in step S21 provided by the present invention.
  • Figure 35 and Figure 36 are the top view and side view of the device generated in step S22 provided by the present invention, respectively;
  • Figure 37 and Figure 38 are the top view and side view of the device generated in step S23 provided by the present invention, respectively;
  • FIG. 39 and FIG. 40 are respectively a top view and a side view of the device generated in step S24 provided by the present invention.
  • Figure 41 and Figure 42 are the top view and side view of the device generated in step S25 provided by the present invention, respectively;
  • Figure 43 and Figure 44 are respectively the top view and the side view of the device generated in step S26 provided by the present invention.
  • Fig. 45 is a side view of the device generated in step S27 provided by the present invention.
  • Fig. 46 is a side view of the device generated in step S28 provided by the present invention.
  • Fig. 47 is a side view of the device generated in step S29 provided by the present invention.
  • FIG. 48 and FIG. 49 are respectively a top view and a side view of the device generated in step S30 provided by the present invention.
  • Figures 50-52 are respectively the top view, side view and cross-sectional view of the device generated in step S31 provided by the present invention.
  • 53-55 are the top view, side view and cross-sectional view of the device generated in step S32 provided by the present invention.
  • 56-58 are the top view, side view and cross-sectional view of the device generated in step S33 provided by the present invention.
  • Figure 59 and Figure 60 are respectively a side view and a cross-sectional view of the device generated in step S34 provided by the present invention.
  • Figure 61 and Figure 62 are respectively a side view and a cross-sectional view of the device generated in step S35 provided by the present invention.
  • Figure 63 and Figure 64 are respectively a side view and a cross-sectional view of the device generated in step S36 provided by the present invention.
  • Figure 65- Figure 67 are respectively the top view, side view and cross-sectional view of the device generated in step S37 provided by the present invention.
  • Fig. 68 is a side view of the device generated in step S38 provided by the present invention.
  • FIG. 69 and FIG. 70 are respectively a top view and a cross-sectional view of the device generated in step S39 provided by the present invention.
  • Fig. 71 and Fig. 72 are respectively the top view and the sectional view of the device that step S40 provided by the present invention generates;
  • FIG. 73 and FIG. 74 are respectively a top view and a cross-sectional view of the device generated in step S41 provided by the present invention.
  • Fig. 75 is a cross-sectional view of the device generated in step S42 provided by the present invention.
  • 76-78 are respectively the top view, side view and cross-sectional view of the device generated in step S43 provided by the present invention.
  • 101 substrate; 102: shielding oxide layer; 103: well region; 104: pad oxide layer;
  • 108 fin region; 109: etch barrier layer; 110: amorphous silicon; 111: amorphous carbon;
  • 112 gate pattern; 113: polyoxide; 114: second silicon nitride;
  • 125 TiAi-based alloy
  • 126 the first metal tungsten
  • 127 the second phosphosilicate glass
  • the cold source Schottky transistor and its manufacturing process of the present invention will be described below with reference to FIGS. 1 to 78 .
  • a cold source Schottky transistor provided by the present invention includes a substrate 101 , a source region, a drain region 4 , a channel region 3 , a source electrode, a drain electrode and a gate electrode.
  • the source region, the drain region 4 and the channel region 3 are all arranged on the substrate 101, wherein the source region includes a first source region 1 and a metal region 2, and the metal region 2 is connected to the first source region 1;
  • the channel region 3 is located between the metal region 2 and the drain region 4, and the upper and/or lower sides of the channel region 3 are provided with a gate dielectric 5, the source is arranged on the source region, and the drain is arranged on the drain region 4 , the gate is arranged on the gate dielectric 5, and the first source region 1 is a heavily doped region, and the drain region 4 is a heavily doped region, so that the Fermi level of the first source region 1 and the drain region 4 in the price band. And the doping types of the first source region 1 and the drain region 4 are opposite.
  • the source region is composed of a heavily doped first source region 1 and a metal region 2, and the metal region 2 is in contact with the channel region 3, a Schottky barrier is formed between the metal region 2 and the channel region 3, and the gate is not applied.
  • a Schottky barrier is formed between the metal region 2 and the channel region 3, and the gate is not applied.
  • the Schottky barrier is very wide, it is difficult for the electrons in the source region to tunnel through the Schottky barrier, and because the forbidden band of the first source region 1 filters the electrons injected by the external electrode, in the first
  • the thermal current is greatly reduced in the forbidden band energy range of the source region 1, so that the corresponding off-state current will be very low.
  • the Schottky barrier between the channel region 3 and the metal region 2 is lowered, making the Schottky barrier thinner until When the Schottky barrier in the low-energy region is thin enough, the tunneling current will increase rapidly, and the electrons in the low-energy region of the source region tunnel through the Schottky barrier, so that the subthreshold swing can be lower than 60mV/dec.
  • the gate voltage when the gate voltage is applied, the electrons in the high-energy region of the Schottky barrier decrease, and no current will be generated in the high-energy region; at this time, the low-energy region of the Schottky barrier becomes narrower, and the electrons in the low-energy region of the source region Tunneling the Schottky barrier, the tunneling current increases rapidly, and the subthreshold swing is lower than 60mV/dec.
  • the Schottky barrier formed between the metal region 2 and the first source region 1 is very thin, it is almost an ohmic contact, so the metal region 2 and the first source region The Schottky barrier between 1 has little effect on the current flow.
  • the cold source is realized by the junction formed by the first source region 1 and the metal region 2 .
  • the cold source Schottky transistor can achieve a relatively large on-state current compared with the tunneling field effect transistor TFETs, and can achieve a higher switching rate than the negative capacitance field effect transistor NC-FETs, and there is no hysteresis;
  • the main body of the device uses silicon as the material.
  • the entire device structure has only been modified and adjusted in the source area, that is, the original N (or P) type semiconductor is replaced by a P (or N) type semiconductor + metal (Metal)
  • the structure is highly compatible with existing MOSFETs in terms of materials and processing technology, which increases the potential for practical applications; and, compared with P-Metal-N cold source transistors, this cold source Schottky transistor has no source The effect of electric phonon scattering brought by the N-type part of the region can realize more efficient cold source injection.
  • the channel region 3 can be an intrinsic region or a lightly doped region, so that the Schottky barrier formed between the channel region 3 and the metal region 2 is very wide, and when no gate voltage is applied In the case of , it is difficult for the electrons in the source region to tunnel through the Schottky barrier, thereby reducing the corresponding off-state current.
  • the first source region 1 can be a P-type heavily doped region
  • the drain region 4 can be an N-type heavily doped region, or the first source region 1 can be an N-type heavily doped region , the drain region 4 may be a P-type heavily doped region.
  • the doping concentration of the first source region 1 may be 1e 19 cm ⁇ 3 to 1e 22 cm ⁇ 3 , the length of the first source region 1 is 20 nm, and the thickness of the first source region 1 is 10 nm.
  • the doping concentration of the drain region 4 is 1e 19 cm -3 -1e 22 cm -3 , the length of the drain region 4 is 20nm, and the thickness of the drain region 4 is 10nm.
  • the doping concentration of the first source region 1 may be 1e 21 cm -3 (that is, 1*1021 per cubic centimeter), and the doping concentration of the drain region 4 may be 1e 19 cm -3 , specifically, the first source region
  • the doping concentration of the drain region 1 and the drain region 4 can be determined according to the material of the first source region and the drain region and the material of the substrate, and can be specifically determined according to the actual situation.
  • the channel region 3 may be a lightly doped region, and the doping concentration of the channel region 3 is 1e 15 cm ⁇ 3 , the length of the channel region 3 is 20 nm, and the thickness of the channel region 3 is 10 nm.
  • the channel region 3 may be lightly doped with N-type or lightly P-type according to the work function of the metal region.
  • the material of the gate dielectric 5 may be hafnium oxide, and the thickness of the gate dielectric 5 may be 1.5 nm.
  • the cold source Schottky transistor may include two gates, and the two gates are respectively arranged on the two gate dielectrics 5, so that under the action of the double gates, the gate control capability is effectively improved, and the device can be more efficient. well turned on and off.
  • the left end of the first source region 1 is a source contact
  • the right end of the drain region 4 is a drain contact
  • the upper and lower sides of the gate dielectric 5 are gate contacts, wherein the work function of the gate contact can be 4.5 eV.
  • the work function of the metal region 2 may be 5eV
  • the length of the metal region 2 may be 10 nm
  • the thickness of the metal region may be 10 nm.
  • the work function, length and thickness of the metal region are not specifically limited, but may be determined according to the actual material selected.
  • first source region 1 and the metal region 2 may be in contact horizontally, and the first source region 1 and the metal region 2 may also be in contact vertically or along other directions (that is, contact at an angle).
  • the material of the substrate can be silicon (Si) or germanium (Ge), or a III-V group material
  • the first source region can also be silicon (Si) or germanium (Ge), a III-V group material
  • III-V materials include: InSb, GaSb, InAs, AlSb, AlAs, GaAs, InGaAs, InAlAs, InP, InGaP, etc.
  • the material of the metal region can be Au, Co, Cu, Pd, Pt, Ti, W , TiN, NiSi 2 and so on.
  • the first source region 1, metal region 2, channel region 3 and drain region 4 have a uniform Fermi level; as shown in Figure 3, when the drain is applied When a voltage of 0.2V is applied to the gate and a voltage of 1V is applied to the gate, the first source region 1, metal region 2, channel region 3 and drain region 4 no longer have a uniform Fermi level, resulting in the formation of electrons and holes.
  • the applied forward bias reduces the height of the Schottky barrier
  • the diffusion movement of the carriers is greater than the drift movement
  • the carriers in the source region are injected into the channel region 3 and recombined while diffusing
  • the carriers in the channel region 3 are injected into the drain region 4 and diffused while recombining to generate a certain concentration gradient, forming a steady state distribution.
  • Figure 4 is the approximate Id-Vg curve obtained by simulation in Sentaurus TCAD, that is, the influence diagram of the gate voltage on the current, and the more bent lines in Figure 4 are the source region including the first A plot of drain current versus gate voltage for a cold-source Schottky transistor with source region 1 and metal region 2; the line with relatively few bends is the source region for a Schottky transistor whose source region includes only metal region 2 A plot of drain current versus gate voltage.
  • the subthreshold swing is lower than 60Mv/dec near 0.6V, and the current changes by about 3 orders of magnitude between 0.6V-0.7V, which shows that the tunneling current rapid increase.
  • the drain current is dominated by tunneling current rather than thermal current.
  • the on-state current is 1 to 2 orders of magnitude lower than that of traditional MOSFETs, but it can be passed Better on-state current characteristics are achieved by adjusting the work function of the gate contact, the work function of the metal at the source end, and the doping concentration of the first source region 1 .
  • the manufacturing process of the cold source Schottky transistor provided by the present invention is described below, and the manufacturing process of the cold source Schottky transistor described below and the cold source Schottky transistor described above can be referred to in correspondence.
  • the preparation process of a cold source Schottky transistor provided by the present invention includes:
  • a gate is formed on the gate dielectric, a source is formed on the metal region and the first source region 1 and a drain is formed on the drain region.
  • forming the metal region on the source end includes:
  • step S20 forming a layer of hard mask on the channel region, source terminal and drain terminal;
  • step S21 setting a pattern layer 117 on the hard mask
  • step S22 etching the hard mask without the pattern layer 117 to expose the source terminal and part of the channel region;
  • step S23 forming a layer of metal layer 118 on the entire device surface
  • step S24 etching the metal layer 118, removing the metal layer on the channel region and part of the metal layer at the source end, leaving a certain thickness of the channel region near the source end. a metal layer to form a metal region;
  • step S25 removing the hard mask and the metal layer attached to the surface of the hard mask.
  • a layer of second amorphous carbon 116 (Amorphous carbon) is grown on the channel region, the source terminal and the drain terminal as a hard mask, and the surface of the hard mask is polished by chemical mechanical polishing (CMP);
  • a photoresist pattern layer 117 is provided on the hard mask by a photolithography process to expose the source end and part of the channel region;
  • PVD physical vapor deposition
  • Etching the metal layer 118 removing the metal layer on the channel region and part of the metal layer at the source end, so that a certain thickness of the metal layer is left on the side of the channel region near the source end to form a metal region;
  • the metal layer on the surface of the hard mask refers to the redundant metal layer.
  • the redundant metal layer can be removed simultaneously, and no additional means are needed to remove the redundant metal layer. Therefore, when removing the redundant metal layer , will not affect the metal layer on the wall of the channel region.
  • forming the first source region 1 on the source end and forming the drain region on the drain end includes:
  • step S26 epitaxially grow silicon carbide 119 on the exposed source and drain ends of the well region 103 to form a first source region material layer and a drain region material layer;
  • step S27 performing pre-amorphization implantation doping on the first source region material layer and the drain region material layer to form the first source region and the drain region.
  • silicon carbide 119 (SiC) is epitaxially grown in the well region 103 (silicon region) exposed at the source end and the drain end, thereby forming a first source region material layer and a drain region material layer; then the first source region material layer Pre-amorphization and doping PAI (Silicon Pre-Amorphization Implant) is performed on the material layer of the drain region to form a layer of uniform, low-resistance silicon, that is, to form the first source region and the drain region.
  • the first source region material layer and the drain region material layer may be implanted with ions to form a metal silicide to reduce the contact resistance of the first source region and the drain region.
  • the doping method of the first source region and the drain region is not limited, and may be determined according to actual conditions.
  • forming the well region 103 on the substrate 101 includes:
  • step S1 grow a barrier oxide layer 102 on the silicon wafer (substrate 101); here, a barrier oxide layer can be grown on the silicon wafer by thermal oxidation or chemical vapor deposition 102.
  • step S2 perform ion implantation on the silicon wafer by an ion implanter, and form a well region 103 on the silicon wafer;
  • boron ions can be implanted into the silicon wafer by an ion implanter to form a P-well on the silicon wafer, and the peak of the implanted ion concentration can be controlled to be located in the middle region of the silicon wafer.
  • step S3 remove the shielding oxide layer 102 by etching, and then perform rapid annealing on the silicon wafer to repair the crystal lattice of the silicon wafer, thereby activating the well region 103 .
  • forming a channel region, a source terminal and a drain terminal on the well region 103 includes:
  • a channel region, a source terminal and a drain terminal are formed in the substrate 101 .
  • forming shallow trench isolation in the substrate 101 includes:
  • step S4 grow a pad oxide layer 104 (Pad Oxide) on the substrate 101;
  • first silicon nitride 105 Silicon Nitride, SiN
  • CVD chemical vapor deposition
  • step S5 etching the first silicon nitride 105 downward until the pad oxide layer 104 is exposed, and then removing the isolation pattern 106;
  • step S6 use the first silicon nitride 105 as a hard mask to continue etching downward until the well region 103 is etched to form shallow trenches and fin regions 108 (Fin);
  • step S7 filling the shallow groove with tetraethyl orthosilicate 107 (TEOS) by means of chemical vapor deposition (CVD);
  • TEOS tetraethyl orthosilicate 107
  • CVD chemical vapor deposition
  • step S8 grinding the tetraethyl orthosilicate 107 by chemical mechanical polishing (CMP) until the tetraethyl orthosilicate 107 is level with the first silicon nitride 105 in the fin region 108 (Fin) together;
  • CMP chemical mechanical polishing
  • step S9 use hot phosphoric acid solution to remove the remaining first silicon nitride 105, and then use etching to remove part of the orthosilicate around the fin region 108 (Fin), leaving The orthosilicate 107 in the region 103 serves as shallow trench isolation (STI, Shallow Trench Isolation).
  • STI shallow trench isolation
  • forming a channel region, a source terminal and a drain terminal in the substrate 101 includes:
  • step S10 growing an oxide layer as an etch stop layer 109 (ESL, etch stop layer) on the fin region 108 (Fin) by means of thermal oxidation;
  • ESL etch stop layer
  • step S11 Deposit a thick layer of amorphous silicon 110 (Amorphous Silicon) by chemical vapor deposition, and smooth the layer of amorphous silicon 110 by chemical mechanical polishing (CMP);
  • CMP chemical mechanical polishing
  • step S12 growing a layer of first amorphous carbon 111 as a hard mask
  • step S13 forming a gate pattern 112 on the first amorphous carbon 111 by photolithography; here, a layer of the first amorphous carbon 111 can be grown by chemical vapor deposition or physical vapor deposition.
  • step S14 etching the hard mask formed by the first amorphous carbon 111 outside the gate pattern 112, continuing to etch downward the amorphous silicon 110 outside the gate pattern 112, removing the gate pattern 112 and the remaining first amorphous carbon 111;
  • step S15 growing a layer of polyoxide 113 on the amorphous silicon 110 by means of thermal oxidation;
  • step S16 depositing a layer of second silicon nitride 114;
  • step S17 etching the second silicon nitride 114 to form a second silicon nitride 114 spacer on the side walls of the fin region 108 and the amorphous silicon 110 to form a channel region , source area, drain area;
  • step S18 forming a masking pattern 115 covering the channel region by photolithography
  • step S19 remove the exposed fin region 108 (Fin) of the source region and the drain region through spacer etching, and then remove the masking pattern 115 to form a channel region, source and sink.
  • forming the gate dielectric in the channel region includes:
  • step S28 form a layer of silicon oxide 120 (Silicon Oxide) and a third silicon nitride 121 (Silicon Nitride) on the surface of the channel region, source region, drain region and amorphous silicon 110 as contacts Stop layer for hole etching;
  • step S29 deposit a thick first phospho-silicate glass 122 (PSG, Phospho-Silicate Glass) on the surface of the third silicon nitride 121, to serve as pre-metal medium (PMD, pre -Metal-Dielectric);
  • PSG Phospho-Silicate Glass
  • step S30 use chemical mechanical polishing (CMP) to polish the pre-metal dielectric layer until the third silicon nitride 121, silicon oxide 120 and polyoxide 113 on the channel region Grinded away, exposing the amorphous silicon 110 inside;
  • CMP chemical mechanical polishing
  • step S31 removing the amorphous silicon 110 in the channel region by etching to expose the etch barrier layer 109 in the fin region 108 ;
  • step S32 continue to remove the etching barrier layer 109 by etching; here, the etching barrier layer 109 on the sidewall of the fin region 108 may be removed by etching.
  • step S33 form an oxide layer on the surface of the fin region 108 through a low-temperature oxidation reaction as a bottom interface layer 123 (BIL, bottom interface layer), so that the high dielectric medium 124 is at the bottom interface Growth on layer 123;
  • BIL bottom interface layer
  • step S34 Deposit a layer of high-k HfO 2 as the dielectric 124 by atomic layer deposition (ALD, Atomic Layer Deposition) process to form a gate dielectric.
  • ALD Atomic Layer Deposition
  • a layer of high dielectric hafnium oxide can be deposited only on the upper surface of the bottom interface layer 123 as the gate dielectric.
  • the gate is formed on the gate dielectric
  • the source is formed on the metal region and the first source region
  • the drain is formed on the drain region, including:
  • step S35 use atomic layer deposition (ALD, Atomic Layer Deposition) process to deposit a layer of work function metal TiAi base alloy 125 on the dielectric 124 layer as gate (gate TiAl);
  • ALD Atomic Layer Deposition
  • work The functional metal can be selected according to device characteristics, and is not limited to TiAi-based alloy 125.
  • step S36 deposit a thick layer of first metal tungsten 126 by means of physical vapor deposition (PVD), and the first metal tungsten 126 is filled in the cavity of the work function metal;
  • PVD physical vapor deposition
  • step S37 smoothen the metal tungsten by means of chemical mechanical polishing (CMP), so that the surface of the first metal tungsten 126 is flush with the surface of the first phosphosilicate glass 122 layer;
  • CMP chemical mechanical polishing
  • step S38 depositing a second layer of phosphosilicate glass 127;
  • step S39 providing a source-drain contact pattern 128 on the second phosphosilicate glass 127 by photolithography to expose the corresponding positions of the first source region and the drain region;
  • step S40 etch the second phosphosilicate glass 127 at the exposed parts corresponding to the source region and the drain region until the barrier layer of silicon nitride is exposed; and etch the corresponding part of the channel region The second phosphosilicate glass 127, until the first metal tungsten 126 in the channel region is exposed;
  • step S41 removing the third silicon nitride 121 and silicon oxide 120 corresponding to the first source region and drain region, exposing the silicon carbide 119 in the first source region and drain region;
  • step S42 Deposit a thick layer of second metal tungsten 129 by means of physical vapor deposition (PVD), and the second metal tungsten 129 will be filled in the cavities of the source contact and the drain contact;
  • PVD physical vapor deposition
  • step S43 Polish the second metal tungsten 129 through the process of chemical mechanical polishing (CMP), so that the second metal tungsten 129 forms the gate, source and drain, and completes the cold source Schott Fabrication of base transistors.
  • CMP chemical mechanical polishing

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Abstract

A cold-source Schottky transistor and a preparation process therefor. The cold-source Schottky transistor comprises a substrate (101), a source region, a drain region (4), a channel region (3), a source electrode, a drain electrode and a gate electrode, wherein the source region is arranged on the substrate (101), the source region comprises a first source region (1) and a metal region (2) connected to the first source region (1), and the first source region (1) is a heavily doped region; the drain region (4) is arranged on the substrate (101), the drain region (4) is a heavily doped region, and the doping type of the drain region (4) is opposite to that of the first source region (1); the channel region (3) is arranged on the substrate (101), the channel region (3) is located between the metal region (2) and the drain region (4), and a gate electrode dielectric (5) is arranged on the upper side and/or the lower side of the channel region (3); the source electrode is arranged on the source region; the drain electrode is arranged on the drain region (4); and the gate electrode is arranged on the gate electrode dielectric (5).

Description

冷源肖特基晶体管及其制备工艺Cold Source Schottky Transistor and Its Fabrication Process
相关申请的交叉引用Cross References to Related Applications
本申请要求于2021年12月31日提交的标题为“冷源肖特基晶体管及其制备工艺”的中国专利申请第2021116737179号的优先权。上述申请的全部内容通过引用全部并入本申请。This application claims the priority of Chinese Patent Application No. 2021116737179 filed on December 31, 2021, entitled "Cold Source Schottky Transistor and Its Manufacturing Process". The entire content of the above application is incorporated by reference into this application in its entirety.
技术领域technical field
本发明涉及半导体技术领域,尤其涉及一种冷源肖特基晶体管及其制备工艺。The invention relates to the technical field of semiconductors, in particular to a cold source Schottky transistor and a preparation process thereof.
背景技术Background technique
摩尔定律下金属氧化物半导体场效应晶体管(MOSFET)的小型化使得信息技术在过去几十年里不断发展,通过减少晶体管的通道长度,开关速度变得更快,器件密度变得更高,电路变得更强大和高效。然而,器件性能的指数增长不可能像摩尔定律所预测的那样永远持续下去,在当今晶体管技术面临的问题中,由于电源电压的减小存在限制,功耗问题突出。特别是在MOSFET的器件原理限制下,不管采用什么样的通道材料以及器件结构,室温情况的亚阈值摆幅(SS)的极限为60mV/dec。这是现有的MOSFET设计的物理局限,这阻止了MOSFET器件的电源电压和功耗的进一步降低。The miniaturization of metal-oxide-semiconductor field-effect transistors (MOSFETs) under Moore's Law has led to the continuous development of information technology over the past few decades. By reducing the channel length of transistors, switching speeds have become faster, device densities have become higher, and circuits become more powerful and efficient. However, the exponential increase in device performance cannot continue forever as predicted by Moore's Law. Among the problems faced by transistor technology today, power consumption is a prominent issue due to the limitation of reduction in supply voltage. Especially under the limitation of the device principle of MOSFET, no matter what kind of channel material and device structure are used, the limit of the sub-threshold swing (SS) at room temperature is 60mV/dec. This is a physical limitation of existing MOSFET designs, which prevents further reductions in supply voltage and power dissipation of MOSFET devices.
发明内容Contents of the invention
本发明提供一种冷源肖特基晶体管及其制备工艺,用以解决现有技术中MOSFET的亚阈值摆幅不能突破60mV/dec而致使MOSFET器件的电源电压和功耗无法进一步降低的缺陷。The invention provides a cold-source Schottky transistor and its preparation process, which are used to solve the defect that the sub-threshold swing of the MOSFET cannot exceed 60mV/dec in the prior art, so that the power supply voltage and power consumption of the MOSFET device cannot be further reduced.
本发明提供一种冷源肖特基晶体管,包括:The invention provides a cold source Schottky transistor, comprising:
衬底;Substrate;
源区,设置在所述衬底上,所述源区包括第一源区和与所述第一源区相连接的金属区,所述第一源区为重掺杂区;a source region disposed on the substrate, the source region comprising a first source region and a metal region connected to the first source region, the first source region being a heavily doped region;
漏区,设置在所述衬底上,所述漏区为重掺杂区,所述漏区与所述第一源区的掺杂类型相反;a drain region disposed on the substrate, the drain region is a heavily doped region, and the doping type of the drain region is opposite to that of the first source region;
沟道区,设置在所述衬底上,所述沟道区位于所述金属区和所述漏区之间,所述沟道区的上侧和/或下侧设置有栅极介质;a channel region, disposed on the substrate, the channel region is located between the metal region and the drain region, and a gate dielectric is provided on the upper side and/or lower side of the channel region;
源极,设置在所述源区上;a source disposed on the source region;
漏极,设置在所述漏区上;a drain disposed on the drain region;
栅极,设置在所述栅极介质上。The gate is arranged on the gate dielectric.
根据本发明提供的一种冷源肖特基晶体管,所述沟道区为本征区或轻掺杂区。According to a cold source Schottky transistor provided by the present invention, the channel region is an intrinsic region or a lightly doped region.
根据本发明提供的一种冷源肖特基晶体管,所述第一源区为P型重掺杂区,所述漏区为N型重掺杂区。According to the cold source Schottky transistor provided by the present invention, the first source region is a P-type heavily doped region, and the drain region is an N-type heavily doped region.
根据本发明提供的一种冷源肖特基晶体管,所述第一源区为N型重掺杂区,所述漏区为P型重掺杂区。According to the cold source Schottky transistor provided by the present invention, the first source region is an N-type heavily doped region, and the drain region is a P-type heavily doped region.
根据本发明提供的一种冷源肖特基晶体管,所述第一源区的掺杂浓度为1e 19cm -3-1e 22cm -3,且所述第一源区的长度为20nm,所述第一源区的厚度为10nm。 According to a cold source Schottky transistor provided by the present invention, the doping concentration of the first source region is 1e 19 cm -3 -1e 22 cm -3 , and the length of the first source region is 20 nm, so The thickness of the first source region is 10 nm.
根据本发明提供的一种冷源肖特基晶体管,所述漏区的掺杂浓度为1e 19cm -3-1e 22cm -3,且所述漏区的长度为20nm,所述漏区的厚度为10nm。 According to a cold source Schottky transistor provided by the present invention, the doping concentration of the drain region is 1e 19 cm -3 -1e 22 cm -3 , and the length of the drain region is 20 nm, and the drain region The thickness is 10nm.
根据本发明提供的一种冷源肖特基晶体管,所述沟道区的掺杂浓度为1e 15cm -3,且所述沟道区的长度为20nm,所述沟道区的厚度为10nm。 According to a cold source Schottky transistor provided by the present invention, the doping concentration of the channel region is 1e 15 cm -3 , the length of the channel region is 20nm, and the thickness of the channel region is 10nm .
根据本发明提供的一种冷源肖特基晶体管,所述金属区的功函数为5.0eV,且所述金属区的长度为10nm,所述金属区的厚度为10nm。According to a cold source Schottky transistor provided by the present invention, the work function of the metal region is 5.0 eV, the length of the metal region is 10 nm, and the thickness of the metal region is 10 nm.
根据本发明提供的一种冷源肖特基晶体管,所述第一源区、所述 漏区和所述沟道区的材质为硅。According to the cold source Schottky transistor provided by the present invention, the material of the first source region, the drain region and the channel region is silicon.
本发明还提供一种冷源肖特基晶体管的制备工艺,包括:The present invention also provides a preparation process of a cold source Schottky transistor, comprising:
在衬底上形成阱区;forming a well region on the substrate;
在阱区上形成沟道区、源端和漏端;forming a channel region, a source terminal and a drain terminal on the well region;
在源端上形成金属区;forming a metal region on the source;
在源端上形成第一源区和在漏端形成漏区;forming a first source region on the source end and forming a drain region on the drain end;
在沟道区形成栅极介质;forming a gate dielectric in the channel region;
在栅极介质上形成栅极、在金属区和第一源区上形成源极和在漏区上形成漏极。A gate is formed on the gate dielectric, a source is formed on the metal region and the first source region, and a drain is formed on the drain region.
根据本发明提供的一种冷源肖特基晶体管的制备工艺,所述在源端上形成金属区,包括:According to the preparation process of a cold source Schottky transistor provided by the present invention, the formation of a metal region on the source terminal includes:
在沟道区、源端和漏端上生成一层硬掩膜;Form a layer of hard mask on the channel region, source terminal and drain terminal;
在硬掩膜上设置图案层;providing a patterned layer on the hard mask;
刻蚀未设置图案层的硬掩膜,露出源端和部分沟道区;Etching the hard mask with no pattern layer, exposing the source end and part of the channel region;
在整个器件表面生成一层金属层;Generate a metal layer over the entire device surface;
刻蚀金属层,去除沟道区上的金属层和源端处部分金属层;Etching the metal layer to remove the metal layer on the channel region and part of the metal layer at the source end;
去除硬掩膜和硬掩膜表面的金属层。The hard mask and the metal layer on the surface of the hard mask are removed.
根据本发明提供的一种冷源肖特基晶体管的制备工艺,所述在源端上形成第一源区和在漏端形成漏区,包括:According to the preparation process of a cold source Schottky transistor provided by the present invention, the formation of the first source region on the source end and the drain region on the drain end includes:
在阱区上裸露的源端和漏端外延生长碳化硅,形成第一源区材料层和漏区材料层;growing silicon carbide epitaxially on the exposed source and drain ends of the well region to form a first source material layer and a drain material layer;
对第一源区材料层和漏区材料层进行预非晶化注入掺杂,形成第一源区和漏区。Pre-amorphization implantation doping is performed on the first source region material layer and the drain region material layer to form the first source region and the drain region.
本发明提供的冷源肖特基晶体管及其制备工艺,冷源肖特基晶体管的源区由重掺杂的第一源区和金属区构成,并且金属区与沟道区接触,金属区与沟道区之间形成肖特基势垒,在不施加栅压的情况下,由于肖特基势垒很宽,源区的电子很难隧穿肖特基势垒,由于第一源 区的禁带过滤了外部电极注入的电子,在第一源区的禁带能量范围内热电流大大减少,从而使相应的关态电流会很低。在有一定的源漏偏压的情况下,在增大栅压的过程中,沟道区和金属区之间的肖特基势垒被压低,使肖特基势垒变薄,直至低能区的肖特基势垒足够薄时,隧穿电流会迅速增加,源区的低能区的电子隧穿肖特基势垒,从而能够实现亚阈值摆幅低于60mV/dec。In the cold source Schottky transistor and its preparation process provided by the present invention, the source region of the cold source Schottky transistor is composed of a heavily doped first source region and a metal region, and the metal region is in contact with the channel region, and the metal region is in contact with the channel region. A Schottky barrier is formed between the channel regions. In the case of no gate voltage, because the Schottky barrier is very wide, it is difficult for electrons in the source region to tunnel through the Schottky barrier. The forbidden band filters the electrons injected by the external electrodes, and the thermal current is greatly reduced in the forbidden band energy range of the first source region, so that the corresponding off-state current will be very low. In the case of a certain source-drain bias, in the process of increasing the gate voltage, the Schottky barrier between the channel region and the metal region is lowered, making the Schottky barrier thinner until the low-energy region When the Schottky barrier is thin enough, the tunneling current will increase rapidly, and the electrons in the low-energy region of the source region tunnel through the Schottky barrier, so that the subthreshold swing can be lower than 60mV/dec.
附图说明Description of drawings
为了更清楚地说明本申请实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图是本申请的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions in the embodiments of the present application or the prior art, the following will briefly introduce the drawings that need to be used in the description of the embodiments or the prior art. Obviously, the accompanying drawings in the following description are For some embodiments of the present application, those of ordinary skill in the art can also obtain other drawings based on these drawings without creative effort.
图1是本发明提供的冷源肖特基晶体管的结构示意图;Fig. 1 is the structural representation of the cold source Schottky transistor provided by the present invention;
图2是本发明提供的没有施加偏压情况下的冷源肖特基晶体管的能带结构图;Fig. 2 is the energy band structure diagram of the cold source Schottky transistor provided by the present invention without applying a bias voltage;
图3是本发明提供的施加正偏压情况下的冷源肖特基晶体管的能带结构图;Fig. 3 is the energy band structure diagram of the cold source Schottky transistor under the condition of applying positive bias provided by the present invention;
图4是本发明提供的Id-Vg的曲线图;Fig. 4 is the graph of Id-Vg provided by the present invention;
图5是本发明提供的步骤S1生成的器件的侧视图;Fig. 5 is a side view of the device generated in step S1 provided by the present invention;
图6是本发明提供的步骤S2生成的器件的侧视图;Fig. 6 is a side view of the device generated in step S2 provided by the present invention;
图7是本发明提供的步骤S3生成的器件的侧视图;Fig. 7 is a side view of the device generated in step S3 provided by the present invention;
图8是本发明提供的步骤S4生成的器件的侧视图;Fig. 8 is a side view of the device generated in step S4 provided by the present invention;
图9是本发明提供的步骤S5生成的器件的侧视图;Fig. 9 is a side view of the device generated in step S5 provided by the present invention;
图10是本发明提供的步骤S6生成的器件的侧视图;Fig. 10 is a side view of the device generated in step S6 provided by the present invention;
图11是本发明提供的步骤S7生成的器件的侧视图;Fig. 11 is a side view of the device generated in step S7 provided by the present invention;
图12是本发明提供的步骤S8生成的器件的侧视图;Fig. 12 is a side view of the device generated in step S8 provided by the present invention;
图13是本发明提供的步骤S9生成的器件的侧视图;Fig. 13 is a side view of the device generated in step S9 provided by the present invention;
图14和图15分别是本发明提供的步骤S10生成的器件的俯视图和侧视图;FIG. 14 and FIG. 15 are respectively a top view and a side view of the device generated in step S10 provided by the present invention;
图16是本发明提供的步骤S11生成的器件的侧视图;Fig. 16 is a side view of the device generated in step S11 provided by the present invention;
图17是本发明提供的步骤S12生成的器件的侧视图;Fig. 17 is a side view of the device generated in step S12 provided by the present invention;
图18是本发明提供的步骤S13生成的器件的侧视图;Fig. 18 is a side view of the device generated in step S13 provided by the present invention;
图19和图20分别是本发明提供的步骤S14生成的器件的俯视图和侧视图;FIG. 19 and FIG. 20 are respectively a top view and a side view of the device generated in step S14 provided by the present invention;
图21和图22分别是本发明提供的步骤S15生成的器件的俯视图和侧视图;FIG. 21 and FIG. 22 are respectively a top view and a side view of the device generated in step S15 provided by the present invention;
图23和图24分别是本发明提供的步骤S16生成的器件的俯视图和侧视图;Figure 23 and Figure 24 are the top view and side view of the device generated in step S16 provided by the present invention, respectively;
图25和图26分别是本发明提供的步骤S17生成的器件的俯视图和侧视图;Figure 25 and Figure 26 are the top view and side view of the device generated in step S17 provided by the present invention, respectively;
图27和图28分别是本发明提供的步骤S18生成的器件的俯视图和侧视图;FIG. 27 and FIG. 28 are respectively a top view and a side view of the device generated in step S18 provided by the present invention;
图29和图30分别是本发明提供的步骤S19生成的器件的俯视图和侧视图;FIG. 29 and FIG. 30 are respectively a top view and a side view of the device generated in step S19 provided by the present invention;
图31和图32分别是本发明提供的步骤S20生成的器件的俯视图和侧视图;FIG. 31 and FIG. 32 are respectively a top view and a side view of the device generated in step S20 provided by the present invention;
图33和图34分别是本发明提供的步骤S21生成的器件的俯视图和侧视图;Figure 33 and Figure 34 are respectively the top view and the side view of the device generated in step S21 provided by the present invention;
图35和图36分别是本发明提供的步骤S22生成的器件的俯视图和侧视图;Figure 35 and Figure 36 are the top view and side view of the device generated in step S22 provided by the present invention, respectively;
图37和图38分别是本发明提供的步骤S23生成的器件的俯视图和侧视图;Figure 37 and Figure 38 are the top view and side view of the device generated in step S23 provided by the present invention, respectively;
图39和图40分别是本发明提供的步骤S24生成的器件的俯视图和侧视图;FIG. 39 and FIG. 40 are respectively a top view and a side view of the device generated in step S24 provided by the present invention;
图41和图42分别是本发明提供的步骤S25生成的器件的俯视图和侧视图;Figure 41 and Figure 42 are the top view and side view of the device generated in step S25 provided by the present invention, respectively;
图43和图44分别是本发明提供的步骤S26生成的器件的俯视图和侧视图;Figure 43 and Figure 44 are respectively the top view and the side view of the device generated in step S26 provided by the present invention;
图45是本发明提供的步骤S27生成的器件的侧视图;Fig. 45 is a side view of the device generated in step S27 provided by the present invention;
图46是本发明提供的步骤S28生成的器件的侧视图;Fig. 46 is a side view of the device generated in step S28 provided by the present invention;
图47是本发明提供的步骤S29生成的器件的侧视图;Fig. 47 is a side view of the device generated in step S29 provided by the present invention;
图48和图49分别是本发明提供的步骤S30生成的器件的俯视图和侧视图;FIG. 48 and FIG. 49 are respectively a top view and a side view of the device generated in step S30 provided by the present invention;
图50-图52分别是本发明提供的步骤S31生成的器件的俯视、侧视和剖视图;Figures 50-52 are respectively the top view, side view and cross-sectional view of the device generated in step S31 provided by the present invention;
图53-图55分别是本发明提供的步骤S32生成的器件的俯视、侧视和剖视图;53-55 are the top view, side view and cross-sectional view of the device generated in step S32 provided by the present invention;
图56-图58分别是本发明提供的步骤S33生成的器件的俯视、侧视和剖视图;56-58 are the top view, side view and cross-sectional view of the device generated in step S33 provided by the present invention;
图59和图60分别是本发明提供的步骤S34生成的器件的侧视图和剖视图;Figure 59 and Figure 60 are respectively a side view and a cross-sectional view of the device generated in step S34 provided by the present invention;
图61和图62分别是本发明提供的步骤S35生成的器件的侧视图和剖视图;Figure 61 and Figure 62 are respectively a side view and a cross-sectional view of the device generated in step S35 provided by the present invention;
图63和图64分别是本发明提供的步骤S36生成的器件的侧视图和剖视图;Figure 63 and Figure 64 are respectively a side view and a cross-sectional view of the device generated in step S36 provided by the present invention;
图65-图67分别是本发明提供的步骤S37生成的器件的俯视、侧视和剖视图;Figure 65-Figure 67 are respectively the top view, side view and cross-sectional view of the device generated in step S37 provided by the present invention;
图68是本发明提供的步骤S38生成的器件的侧视图;Fig. 68 is a side view of the device generated in step S38 provided by the present invention;
图69和图70分别是本发明提供的步骤S39生成的器件的俯视图和剖视图;FIG. 69 and FIG. 70 are respectively a top view and a cross-sectional view of the device generated in step S39 provided by the present invention;
图71和图72分别是本发明提供的步骤S40生成的器件的俯视图 和剖视图;Fig. 71 and Fig. 72 are respectively the top view and the sectional view of the device that step S40 provided by the present invention generates;
图73和图74分别是本发明提供的步骤S41生成的器件的俯视图和剖视图;FIG. 73 and FIG. 74 are respectively a top view and a cross-sectional view of the device generated in step S41 provided by the present invention;
图75是本发明提供的步骤S42生成的器件的剖视图;Fig. 75 is a cross-sectional view of the device generated in step S42 provided by the present invention;
图76-图78分别是本发明提供的步骤S43生成的器件的俯视、侧视和剖视图。76-78 are respectively the top view, side view and cross-sectional view of the device generated in step S43 provided by the present invention.
附图标记:Reference signs:
1:第一源区;2:金属区;3:沟道区;4:漏区;5:栅极介质;1: first source region; 2: metal region; 3: channel region; 4: drain region; 5: gate dielectric;
101:衬底;102:屏蔽氧化层;103:阱区;104:垫氧化层;101: substrate; 102: shielding oxide layer; 103: well region; 104: pad oxide layer;
105:第一氮化硅;106:隔离图案;107:正硅酸乙酯;105: first silicon nitride; 106: isolation pattern; 107: tetraethyl orthosilicate;
108:鳍区;109:蚀刻阻挡层;110:非晶硅;111:非晶碳;108: fin region; 109: etch barrier layer; 110: amorphous silicon; 111: amorphous carbon;
112:栅极图案;113:多氧化物;114:第二氮化硅;112: gate pattern; 113: polyoxide; 114: second silicon nitride;
115:遮盖图案;116:第二非晶碳;117:图案层;118:金属层;115: cover pattern; 116: second amorphous carbon; 117: pattern layer; 118: metal layer;
119:碳化硅;120:氧化硅;121:第三氮化硅;119: silicon carbide; 120: silicon oxide; 121: third silicon nitride;
122:第一磷硅酸盐玻璃;123:底界面层;124:电介质;122: first phosphosilicate glass; 123: bottom interface layer; 124: dielectric;
125:TiAi基合金;126:第一金属钨;127:第二磷硅酸盐玻璃;125: TiAi-based alloy; 126: the first metal tungsten; 127: the second phosphosilicate glass;
128:源漏接触图案;129:第二金属钨。128: source-drain contact pattern; 129: second metal tungsten.
具体实施方式Detailed ways
为使本发明的目的、技术方案和优点更加清楚,下面将结合本发明中的附图,对本发明中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。In order to make the purpose, technical solutions and advantages of the present invention clearer, the technical solutions in the present invention will be clearly and completely described below in conjunction with the accompanying drawings in the present invention. Obviously, the described embodiments are part of the embodiments of the present invention , but not all examples. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without creative efforts fall within the protection scope of the present invention.
下面结合图1至图78描述本发明的冷源肖特基晶体管及其制备工艺。The cold source Schottky transistor and its manufacturing process of the present invention will be described below with reference to FIGS. 1 to 78 .
如图1所示,本发明提供的一种冷源肖特基晶体管,包括衬底101、源区、漏区4、沟道区3、源极、漏极和栅极。As shown in FIG. 1 , a cold source Schottky transistor provided by the present invention includes a substrate 101 , a source region, a drain region 4 , a channel region 3 , a source electrode, a drain electrode and a gate electrode.
具体地,源区、漏区4和沟道区3均设置在衬底101上,其中,源区包括第一源区1和金属区2,金属区2与第一源区1相连接;沟道区3位于金属区2和漏区4之间,并且沟道区3的上侧和/或下侧设置有栅极介质5,源极设置在源区上,漏极设置在漏区4上,栅极设置在栅极介质5上,并且,第一源区1为重掺杂区,漏区4为重掺杂区,这样,使第一源区1和漏区4的费米能级处于价带里面。并且第一源区1和漏区4的掺杂类型相反。Specifically, the source region, the drain region 4 and the channel region 3 are all arranged on the substrate 101, wherein the source region includes a first source region 1 and a metal region 2, and the metal region 2 is connected to the first source region 1; The channel region 3 is located between the metal region 2 and the drain region 4, and the upper and/or lower sides of the channel region 3 are provided with a gate dielectric 5, the source is arranged on the source region, and the drain is arranged on the drain region 4 , the gate is arranged on the gate dielectric 5, and the first source region 1 is a heavily doped region, and the drain region 4 is a heavily doped region, so that the Fermi level of the first source region 1 and the drain region 4 in the price band. And the doping types of the first source region 1 and the drain region 4 are opposite.
源区由重掺杂的第一源区1和金属区2构成,并且金属区2与沟道区3接触,金属区2与沟道区3之间形成肖特基势垒,在不施加栅压的情况下,由于肖特基势垒很宽,源区的电子很难隧穿肖特基势垒,并且,由于第一源区1的禁带过滤了外部电极注入的电子,在第一源区1的禁带能量范围内热电流大大减少,从而使相应的关态电流会很低。在有一定的源漏偏压的情况下,在增大栅压的过程中,沟道区3和金属区2之间的肖特基势垒被压低,使肖特基势垒变薄,直至低能区的肖特基势垒足够薄时,隧穿电流会迅速增加,源区的低能区的电子隧穿肖特基势垒,从而能够实现亚阈值摆幅低于60mV/dec。The source region is composed of a heavily doped first source region 1 and a metal region 2, and the metal region 2 is in contact with the channel region 3, a Schottky barrier is formed between the metal region 2 and the channel region 3, and the gate is not applied. In the case of high pressure, because the Schottky barrier is very wide, it is difficult for the electrons in the source region to tunnel through the Schottky barrier, and because the forbidden band of the first source region 1 filters the electrons injected by the external electrode, in the first The thermal current is greatly reduced in the forbidden band energy range of the source region 1, so that the corresponding off-state current will be very low. In the case of a certain source-drain bias, in the process of increasing the gate voltage, the Schottky barrier between the channel region 3 and the metal region 2 is lowered, making the Schottky barrier thinner until When the Schottky barrier in the low-energy region is thin enough, the tunneling current will increase rapidly, and the electrons in the low-energy region of the source region tunnel through the Schottky barrier, so that the subthreshold swing can be lower than 60mV/dec.
需要说明的是,当施加栅压时,肖特基势垒高能区域的电子减少,高能区域不会产生电流;这时,肖特基势垒的低能区域变窄,源区的低能区域的电子隧穿肖特基势垒,隧穿电流迅速增加,实现亚阈值摆幅低于60mV/dec。It should be noted that when the gate voltage is applied, the electrons in the high-energy region of the Schottky barrier decrease, and no current will be generated in the high-energy region; at this time, the low-energy region of the Schottky barrier becomes narrower, and the electrons in the low-energy region of the source region Tunneling the Schottky barrier, the tunneling current increases rapidly, and the subthreshold swing is lower than 60mV/dec.
并且,需要注意的是,由于金属区2和第一源区1(重掺杂区)之间形成的肖特基势垒很薄,几乎是一个欧姆接触,所以金属区2和第一源区1之间的肖特基势垒对于电流的影响很小。Moreover, it should be noted that since the Schottky barrier formed between the metal region 2 and the first source region 1 (heavily doped region) is very thin, it is almost an ohmic contact, so the metal region 2 and the first source region The Schottky barrier between 1 has little effect on the current flow.
这里,通过第一源区1和金属区2构成的结来实现冷源极。Here, the cold source is realized by the junction formed by the first source region 1 and the metal region 2 .
如此设置,本冷源肖特基晶体管相对于隧穿场效应晶体管TFETs能实现相对大的开态电流,相对于负电容场效应晶体管NC-FETs能够实现更高的开关速率,并没有迟滞现象;器件主体采用硅作为材料, 相对于传统MOSFET整个器件结构只在源区做了一些修正调整,即将原本的N(或者P)型半导体换成了P(或者N)型半导体+金属(Metal)的结构,与现有的MOSFET不论在材料还是加工工艺方面兼容程度都很高,增大了实际应用的潜力;并且,本冷源肖特基晶体管相对于P-Metal-N冷源晶体管,没有源区N型部分带来的电声子散射的影响,能够实现更有效的冷源注入。In this way, the cold source Schottky transistor can achieve a relatively large on-state current compared with the tunneling field effect transistor TFETs, and can achieve a higher switching rate than the negative capacitance field effect transistor NC-FETs, and there is no hysteresis; The main body of the device uses silicon as the material. Compared with the traditional MOSFET, the entire device structure has only been modified and adjusted in the source area, that is, the original N (or P) type semiconductor is replaced by a P (or N) type semiconductor + metal (Metal) The structure is highly compatible with existing MOSFETs in terms of materials and processing technology, which increases the potential for practical applications; and, compared with P-Metal-N cold source transistors, this cold source Schottky transistor has no source The effect of electric phonon scattering brought by the N-type part of the region can realize more efficient cold source injection.
本发明的可选实施例中,沟道区3可以为本征区或轻掺杂区,使沟道区3和金属区2之间形成的肖特基势垒很宽,在不施加栅压的情况下,使源区的电子很难隧穿肖特基势垒,从而减小相应的关态电流。In an optional embodiment of the present invention, the channel region 3 can be an intrinsic region or a lightly doped region, so that the Schottky barrier formed between the channel region 3 and the metal region 2 is very wide, and when no gate voltage is applied In the case of , it is difficult for the electrons in the source region to tunnel through the Schottky barrier, thereby reducing the corresponding off-state current.
本发明的可选实施例中,第一源区1可以为P型重掺杂区,漏区4可以为N型重掺杂区,或者,第一源区1可以为N型重掺杂区,漏区4可以为P型重掺杂区。In an optional embodiment of the present invention, the first source region 1 can be a P-type heavily doped region, and the drain region 4 can be an N-type heavily doped region, or the first source region 1 can be an N-type heavily doped region , the drain region 4 may be a P-type heavily doped region.
并且,第一源区1的掺杂浓度可以为1e 19cm -3-1e 22cm -3,第一源区1的长度为20nm,第一源区1的厚度为10nm。漏区4的掺杂浓度为1e 19cm -3-1e 22cm -3,漏区4的长度为20nm,漏区4的厚度为10nm。 Moreover, the doping concentration of the first source region 1 may be 1e 19 cm −3 to 1e 22 cm −3 , the length of the first source region 1 is 20 nm, and the thickness of the first source region 1 is 10 nm. The doping concentration of the drain region 4 is 1e 19 cm -3 -1e 22 cm -3 , the length of the drain region 4 is 20nm, and the thickness of the drain region 4 is 10nm.
这里,第一源区1的掺杂浓度可以为1e 21cm -3(即1*1021每立方厘米),漏区4的掺杂浓度可以为1e 19cm -3,具体地,第一源区1和漏区4的掺杂浓度可以根据第一源区和漏区的材质及衬底的材质等确定,具体可以根据实际情况确定。 Here, the doping concentration of the first source region 1 may be 1e 21 cm -3 (that is, 1*1021 per cubic centimeter), and the doping concentration of the drain region 4 may be 1e 19 cm -3 , specifically, the first source region The doping concentration of the drain region 1 and the drain region 4 can be determined according to the material of the first source region and the drain region and the material of the substrate, and can be specifically determined according to the actual situation.
本实施例中,沟道区3可以为轻掺杂区,并且沟道区3的掺杂浓度为1e 15cm -3,沟道区3的长度为20nm,沟道区3的厚度为10nm。具体地,沟道区3可以根据金属区的功函数确定采用N型轻掺杂或P型轻掺杂。 In this embodiment, the channel region 3 may be a lightly doped region, and the doping concentration of the channel region 3 is 1e 15 cm −3 , the length of the channel region 3 is 20 nm, and the thickness of the channel region 3 is 10 nm. Specifically, the channel region 3 may be lightly doped with N-type or lightly P-type according to the work function of the metal region.
在可选的实施例中,栅极介质5的材质可以为氧化铪,并且栅极介质5的厚度可以为1.5nm。并且,该冷源肖特基晶体管可以包括两个栅极,两个栅极分别设置在两个栅极介质5上,这样,在双栅的作用下,栅控能力得到有效提升,器件能较好地导通和关闭。In an optional embodiment, the material of the gate dielectric 5 may be hafnium oxide, and the thickness of the gate dielectric 5 may be 1.5 nm. Moreover, the cold source Schottky transistor may include two gates, and the two gates are respectively arranged on the two gate dielectrics 5, so that under the action of the double gates, the gate control capability is effectively improved, and the device can be more efficient. well turned on and off.
本实施例中,第一源区1的左端是源极接触,漏区4的右端是漏极接触,栅极介质5的上下两侧是栅极接触,其中栅极接触的功函数可以为4.5eV。In this embodiment, the left end of the first source region 1 is a source contact, the right end of the drain region 4 is a drain contact, and the upper and lower sides of the gate dielectric 5 are gate contacts, wherein the work function of the gate contact can be 4.5 eV.
一些实施例中,金属区2的功函数可以为5eV,并且金属区2的长度可以为10nm,金属区的厚度可以为10nm。这里,不对金属区的功函数、长度和厚度做具体限定,具体可以根据实际选用的材质确定。In some embodiments, the work function of the metal region 2 may be 5eV, the length of the metal region 2 may be 10 nm, and the thickness of the metal region may be 10 nm. Here, the work function, length and thickness of the metal region are not specifically limited, but may be determined according to the actual material selected.
本实施例中,第一源区1和金属区2可以水平接触,第一源区1和金属区2也可以垂直接触或沿其他方向接触(即成夹角接触)。In this embodiment, the first source region 1 and the metal region 2 may be in contact horizontally, and the first source region 1 and the metal region 2 may also be in contact vertically or along other directions (that is, contact at an angle).
本实施例中,衬底的材质可以为硅(Si)或锗(Ge),或Ⅲ-V族材料,第一源区也可以是硅(Si)或锗(Ge),Ⅲ-V族材料,其中Ⅲ-Ⅴ族材料包括:InSb,GaSb,InAs,AlSb,AlAs,GaAs,InGaAs,InAlAs,InP,InGaP等等;金属区的材料可以是Au,Co,Cu,Pd,Pt,Ti,W,TiN,NiSi 2等等。 In this embodiment, the material of the substrate can be silicon (Si) or germanium (Ge), or a III-V group material, and the first source region can also be silicon (Si) or germanium (Ge), a III-V group material , where III-V materials include: InSb, GaSb, InAs, AlSb, AlAs, GaAs, InGaAs, InAlAs, InP, InGaP, etc.; the material of the metal region can be Au, Co, Cu, Pd, Pt, Ti, W , TiN, NiSi 2 and so on.
如图2所示,在没有施加偏压情况下,第一源区1、金属区2、沟道区3和漏区4具有统一的费米能级;如图3所示,在漏极施加0.2V的电压,栅极施加1V的电压的情况下,第一源区1、金属区2、沟道区3和漏区4不再具有统一的费米能级,产生了电子和空穴的准费米能级,施加的正向偏压使得肖特基势垒的高度减小,载流子的扩散运动大于漂移运动,源区的载流子注入到沟道区3后边扩散边复合产生一定的浓度梯度,沟道区3的载流子注入到漏区4后边扩散边复合产生一定的浓度梯度,形成稳态分布。As shown in Figure 2, when no bias voltage is applied, the first source region 1, metal region 2, channel region 3 and drain region 4 have a uniform Fermi level; as shown in Figure 3, when the drain is applied When a voltage of 0.2V is applied to the gate and a voltage of 1V is applied to the gate, the first source region 1, metal region 2, channel region 3 and drain region 4 no longer have a uniform Fermi level, resulting in the formation of electrons and holes. The quasi-Fermi level, the applied forward bias reduces the height of the Schottky barrier, the diffusion movement of the carriers is greater than the drift movement, and the carriers in the source region are injected into the channel region 3 and recombined while diffusing With a certain concentration gradient, the carriers in the channel region 3 are injected into the drain region 4 and diffused while recombining to generate a certain concentration gradient, forming a steady state distribution.
如图4所示,图4为在Sentaurus TCAD中仿真得到的近似的Id-Vg的曲线图,即为栅极电压对电流的影响图,图4中弯折较多的线条为源区包括第一源区1和金属区2的冷源肖特基晶体管的漏极电流与栅极电压的曲线图;弯折相对较少的线条为源区仅包括金属区2的肖特基晶体管的源区漏极电流与栅极电压的曲线图。其中,由图4可知,在0.6V附近出现了亚阈值摆幅低于60Mv/dec的情况,并且在 0.6V-0.7V之间实现了大约3个数量级电流的变化,从而表明了隧穿电流的迅速增加。As shown in Figure 4, Figure 4 is the approximate Id-Vg curve obtained by simulation in Sentaurus TCAD, that is, the influence diagram of the gate voltage on the current, and the more bent lines in Figure 4 are the source region including the first A plot of drain current versus gate voltage for a cold-source Schottky transistor with source region 1 and metal region 2; the line with relatively few bends is the source region for a Schottky transistor whose source region includes only metal region 2 A plot of drain current versus gate voltage. Among them, it can be seen from Figure 4 that the subthreshold swing is lower than 60Mv/dec near 0.6V, and the current changes by about 3 orders of magnitude between 0.6V-0.7V, which shows that the tunneling current rapid increase.
需要说明的是,由于存在肖特基势垒,漏极电流以隧穿电流为主而不是以热电流为主,这时的开态电流相对传统MOSFET偏低1到2个数量级,但是可以通过调节栅极接触功函数、源端的金属功函数以及第一源区1的掺杂浓度等来实现更好的开态电流特性。It should be noted that due to the presence of Schottky barriers, the drain current is dominated by tunneling current rather than thermal current. At this time, the on-state current is 1 to 2 orders of magnitude lower than that of traditional MOSFETs, but it can be passed Better on-state current characteristics are achieved by adjusting the work function of the gate contact, the work function of the metal at the source end, and the doping concentration of the first source region 1 .
下面对本发明提供的冷源肖特基晶体管的制备工艺进行描述,下文描述的冷源肖特基晶体管的制备工艺与上文描述的冷源肖特基晶体管可相互对应参照。The manufacturing process of the cold source Schottky transistor provided by the present invention is described below, and the manufacturing process of the cold source Schottky transistor described below and the cold source Schottky transistor described above can be referred to in correspondence.
如图5-图78所示,本发明提供的一种冷源肖特基晶体管的制备工艺,包括:As shown in Figure 5-Figure 78, the preparation process of a cold source Schottky transistor provided by the present invention includes:
在衬底101上形成阱区103;forming a well region 103 on the substrate 101;
在阱区103上形成沟道区、源端和漏端;forming a channel region, a source terminal and a drain terminal on the well region 103;
在源端上形成金属区;forming a metal region on the source;
在源端上形成第一源区1,在漏端上形成漏区;forming a first source region 1 on the source end, and forming a drain region on the drain end;
在沟道区形成栅极介质;forming a gate dielectric in the channel region;
在栅极介质上形成栅极,在金属区和第一源区1上形成源极和在漏区上形成漏极。A gate is formed on the gate dielectric, a source is formed on the metal region and the first source region 1 and a drain is formed on the drain region.
其中,在源端上形成金属区中,包括:Wherein, forming the metal region on the source end includes:
如图31和图32所示,步骤S20:在沟道区、源端和漏端上生成一层硬掩膜;As shown in FIG. 31 and FIG. 32, step S20: forming a layer of hard mask on the channel region, source terminal and drain terminal;
如图33和图34所示,步骤S21:在硬掩膜上设置图案层117;As shown in FIG. 33 and FIG. 34, step S21: setting a pattern layer 117 on the hard mask;
如图35和图36所示,步骤S22:刻蚀未设置图案层117的硬掩膜,露出源端和部分沟道区;As shown in FIG. 35 and FIG. 36 , step S22: etching the hard mask without the pattern layer 117 to expose the source terminal and part of the channel region;
如图37和图38所示,步骤S23:在整个器件表面生成一层金属层118;As shown in Figure 37 and Figure 38, step S23: forming a layer of metal layer 118 on the entire device surface;
如图39和图40所示,步骤S24:刻蚀金属层118,去除沟道区 上的金属层和源端处的部分金属层,使沟道区的靠近源端的一侧留有一定厚度的金属层,以形成金属区;As shown in FIG. 39 and FIG. 40, step S24: etching the metal layer 118, removing the metal layer on the channel region and part of the metal layer at the source end, leaving a certain thickness of the channel region near the source end. a metal layer to form a metal region;
如图41和图42所示,步骤S25:去除硬掩膜和附着在硬掩膜表面的金属层。As shown in FIG. 41 and FIG. 42 , step S25 : removing the hard mask and the metal layer attached to the surface of the hard mask.
具体地,在沟道区、源端和漏端上生长一层第二非晶碳116(Amorphous carbon)作为硬掩膜,用化学机械抛光(CMP)的方式将硬掩膜表面磨平;Specifically, a layer of second amorphous carbon 116 (Amorphous carbon) is grown on the channel region, the source terminal and the drain terminal as a hard mask, and the surface of the hard mask is polished by chemical mechanical polishing (CMP);
然后,通过光刻工艺在硬掩膜上设置光刻胶图案层117,露出源端和部分沟道区;Then, a photoresist pattern layer 117 is provided on the hard mask by a photolithography process to expose the source end and part of the channel region;
接着通过刻蚀的方式将源端和部分沟道区的第二非晶碳116去除,然后去除图案层117;Next, remove the second amorphous carbon 116 at the source end and part of the channel region by etching, and then remove the pattern layer 117;
通过物理气相沉积(PVD)的方式生长一层金属层118;growing a metal layer 118 by physical vapor deposition (PVD);
刻蚀金属层118,去除沟道区上的金属层和源端处的部分金属层,使沟道区的靠近源端的一侧留有一定厚度的金属层,以形成金属区;Etching the metal layer 118, removing the metal layer on the channel region and part of the metal layer at the source end, so that a certain thickness of the metal layer is left on the side of the channel region near the source end to form a metal region;
最后去除硬掩膜和附着在硬掩膜表面的金属层。这里,硬掩膜表面的金属层指的是多余的金属层,在去除硬掩膜的同时可以将多余的金属层同步去除,无需额外的手段去除多余金属层,因此,在去除多余金属层时,不会对沟道区壁上的金属层产生影响。Finally, the hard mask and the metal layer attached to the surface of the hard mask are removed. Here, the metal layer on the surface of the hard mask refers to the redundant metal layer. When removing the hard mask, the redundant metal layer can be removed simultaneously, and no additional means are needed to remove the redundant metal layer. Therefore, when removing the redundant metal layer , will not affect the metal layer on the wall of the channel region.
在本发明的可选实施例中,在源端上形成第一源区1和在漏端形成漏区中,包括:In an optional embodiment of the present invention, forming the first source region 1 on the source end and forming the drain region on the drain end includes:
如图43和图44所示,步骤S26:在阱区103上裸露的源端和漏端外延生长碳化硅119,形成第一源区材料层和漏区材料层;As shown in FIG. 43 and FIG. 44 , step S26: epitaxially grow silicon carbide 119 on the exposed source and drain ends of the well region 103 to form a first source region material layer and a drain region material layer;
如图45所示,步骤S27:对第一源区材料层和漏区材料层进行预非晶化注入掺杂,形成第一源区和漏区。As shown in FIG. 45 , step S27 : performing pre-amorphization implantation doping on the first source region material layer and the drain region material layer to form the first source region and the drain region.
具体地,在源端和漏端部分暴露的阱区103(硅区)外延生长碳化硅119(SiC),从而形成第一源区材料层和漏区材料层;然后对第一源区材料层和漏区材料层进行预非晶化掺杂PAI(Silicon  Pre-Amorphization Implant),形成一层均匀的、低电阻的硅,即形成第一源区和漏区。或者,还可以向第一源区材料层和漏区材料层进行离子注入、使其形成金属硅化物等操作来降低第一源区和漏区的接触电阻。Specifically, silicon carbide 119 (SiC) is epitaxially grown in the well region 103 (silicon region) exposed at the source end and the drain end, thereby forming a first source region material layer and a drain region material layer; then the first source region material layer Pre-amorphization and doping PAI (Silicon Pre-Amorphization Implant) is performed on the material layer of the drain region to form a layer of uniform, low-resistance silicon, that is, to form the first source region and the drain region. Alternatively, the first source region material layer and the drain region material layer may be implanted with ions to form a metal silicide to reduce the contact resistance of the first source region and the drain region.
这里,不对第一源区和漏区的掺杂方式进行限定,具体可以根据实际情况确定。Here, the doping method of the first source region and the drain region is not limited, and may be determined according to actual conditions.
在本发明的可选实施例中,在衬底101上形成阱区103中,包括:In an optional embodiment of the present invention, forming the well region 103 on the substrate 101 includes:
如图5所示,步骤S1:在硅片(衬底101)上生长一层屏蔽氧化层102;这里,可以通过热氧化的方式或化学气相沉积的方式在硅片上生长一层屏蔽氧化层102。As shown in Figure 5, step S1: grow a barrier oxide layer 102 on the silicon wafer (substrate 101); here, a barrier oxide layer can be grown on the silicon wafer by thermal oxidation or chemical vapor deposition 102.
如图6所示,步骤S2:通过离子注入机对硅片进行离子注入,在硅片上形成阱区103;As shown in FIG. 6, step S2: perform ion implantation on the silicon wafer by an ion implanter, and form a well region 103 on the silicon wafer;
这里,可以通过离子注入机向硅片注入硼离子,使硅片上形成P-阱,并且,可以控制注入离子浓度的峰值位于硅片的中部区域。Here, boron ions can be implanted into the silicon wafer by an ion implanter to form a P-well on the silicon wafer, and the peak of the implanted ion concentration can be controlled to be located in the middle region of the silicon wafer.
然后,如图7所示,步骤S3:通过刻蚀的方式去除屏蔽氧化层102,接着对硅片进行快速退火处理,修复硅片的晶格,从而活化阱区103。Then, as shown in FIG. 7 , step S3 : remove the shielding oxide layer 102 by etching, and then perform rapid annealing on the silicon wafer to repair the crystal lattice of the silicon wafer, thereby activating the well region 103 .
在可选的实施例中,在阱区103上形成沟道区、源端和漏端中,包括:In an optional embodiment, forming a channel region, a source terminal and a drain terminal on the well region 103 includes:
在衬底101中形成浅槽隔离;forming shallow trench isolation in the substrate 101;
在衬底101中形成沟道区、源端和漏端。A channel region, a source terminal and a drain terminal are formed in the substrate 101 .
具体地,在衬底101中形成浅槽隔离,包括:Specifically, forming shallow trench isolation in the substrate 101 includes:
如图8所示,步骤S4:在衬底101上生长一层垫氧化层104(Pad Oxide);As shown in FIG. 8, step S4: grow a pad oxide layer 104 (Pad Oxide) on the substrate 101;
通过化学气相沉积(CVD)的方式在垫氧化层104上形成一层第一氮化硅105(Silicon Nitride,SiN);Forming a layer of first silicon nitride 105 (Silicon Nitride, SiN) on the pad oxide layer 104 by chemical vapor deposition (CVD);
通过光刻工艺在第一氮化硅105上设置光刻胶隔离图案106;disposing a photoresist isolation pattern 106 on the first silicon nitride 105 through a photolithography process;
如图9所示,步骤S5:向下刻蚀第一氮化硅105,直至露出垫氧化层104为止,然后去除隔离图案106;As shown in FIG. 9, step S5: etching the first silicon nitride 105 downward until the pad oxide layer 104 is exposed, and then removing the isolation pattern 106;
如图10所示,步骤S6:以第一氮化硅105作为硬掩膜继续向下刻蚀,一直刻蚀到阱区103,形成浅槽和鳍区108(Fin);As shown in FIG. 10 , step S6: use the first silicon nitride 105 as a hard mask to continue etching downward until the well region 103 is etched to form shallow trenches and fin regions 108 (Fin);
如图11所示,步骤S7:通过化学气相沉积(CVD)的方式在浅槽填充正硅酸乙酯107(TEOS);As shown in FIG. 11 , step S7: filling the shallow groove with tetraethyl orthosilicate 107 (TEOS) by means of chemical vapor deposition (CVD);
如图12所示,步骤S8:通过化学机械抛光(CMP)的方式对正硅酸乙酯107研磨,直至正硅酸乙酯107与鳍区108(Fin)的第一氮化硅105相平齐;As shown in FIG. 12 , step S8: grinding the tetraethyl orthosilicate 107 by chemical mechanical polishing (CMP) until the tetraethyl orthosilicate 107 is level with the first silicon nitride 105 in the fin region 108 (Fin) together;
如图13所示,步骤S9:利用热磷酸溶液去除剩余的第一氮化硅105,然后利用刻蚀的方式移除鳍区108(Fin)周围的部分正硅酸乙酯,留下位于阱区103部分的正硅酸乙酯107作为浅槽隔离(STI,Shallow Trench Isolation)。As shown in FIG. 13 , step S9: use hot phosphoric acid solution to remove the remaining first silicon nitride 105, and then use etching to remove part of the orthosilicate around the fin region 108 (Fin), leaving The orthosilicate 107 in the region 103 serves as shallow trench isolation (STI, Shallow Trench Isolation).
具体地,在衬底101中形成沟道区、源端和漏端中,包括:Specifically, forming a channel region, a source terminal and a drain terminal in the substrate 101 includes:
如图14和图15所示,步骤S10:在鳍区108(Fin)上通过热氧化的方式生长一层氧化层作为蚀刻阻挡层109(ESL,etch stop layer);As shown in FIG. 14 and FIG. 15 , step S10: growing an oxide layer as an etch stop layer 109 (ESL, etch stop layer) on the fin region 108 (Fin) by means of thermal oxidation;
如图16所示,步骤S11:通过化学气相沉积的方式沉积一层厚厚的非晶硅110层(Amorphous Silicon),并通过化学机械抛光(CMP)的方式将非晶硅110层磨平;As shown in FIG. 16, step S11: Deposit a thick layer of amorphous silicon 110 (Amorphous Silicon) by chemical vapor deposition, and smooth the layer of amorphous silicon 110 by chemical mechanical polishing (CMP);
如图17所示,步骤S12:生长一层第一非晶碳111作为硬掩膜;As shown in FIG. 17, step S12: growing a layer of first amorphous carbon 111 as a hard mask;
如图18所示,步骤S13:通过光刻方式在第一非晶碳111上形成栅极图案112;这里,可以通过化学气相沉积或物理气相沉积的方式生长一层第一非晶碳111。As shown in FIG. 18 , step S13 : forming a gate pattern 112 on the first amorphous carbon 111 by photolithography; here, a layer of the first amorphous carbon 111 can be grown by chemical vapor deposition or physical vapor deposition.
如图19和图20所示,步骤S14:刻蚀栅极图案112外的第一非晶碳111形成的硬掩膜,继续向下刻蚀掉栅极图案112外的非晶硅110,去除栅极图案112和剩余的第一非晶碳111;As shown in FIG. 19 and FIG. 20, step S14: etching the hard mask formed by the first amorphous carbon 111 outside the gate pattern 112, continuing to etch downward the amorphous silicon 110 outside the gate pattern 112, removing the gate pattern 112 and the remaining first amorphous carbon 111;
如图21和图22所示,步骤S15:通过热氧化的方式在非晶硅110 上生长一层多氧化物113;As shown in FIG. 21 and FIG. 22, step S15: growing a layer of polyoxide 113 on the amorphous silicon 110 by means of thermal oxidation;
如图23和图24所示,步骤S16:沉积一层第二氮化硅114;As shown in FIG. 23 and FIG. 24, step S16: depositing a layer of second silicon nitride 114;
如图25和图26所示,步骤S17:刻蚀第二氮化硅114,使鳍区108和非晶硅110的侧壁上生成一层第二氮化硅114垫片,形成沟道区域、源端区域、漏端区域;As shown in FIG. 25 and FIG. 26, step S17: etching the second silicon nitride 114 to form a second silicon nitride 114 spacer on the side walls of the fin region 108 and the amorphous silicon 110 to form a channel region , source area, drain area;
如图27和图28所示,步骤S18:通过光刻工艺形成遮盖沟道区域的遮盖图案115;As shown in FIG. 27 and FIG. 28, step S18: forming a masking pattern 115 covering the channel region by photolithography;
如图29和图30所示,步骤S19:将源端区域和漏端区域裸露的鳍区108(Fin)通过间隙壁刻蚀去除,然后去除遮盖图案115,在衬底上形成沟道区、源端和漏端。As shown in FIG. 29 and FIG. 30 , step S19: remove the exposed fin region 108 (Fin) of the source region and the drain region through spacer etching, and then remove the masking pattern 115 to form a channel region, source and sink.
本实施例中,在沟道区形成栅极介质中,包括:In this embodiment, forming the gate dielectric in the channel region includes:
如图46所示,步骤S28:在沟道区、源区和漏区及非晶硅110的表面形成一层氧化硅120(Silicon Oxide)和第三氮化硅121(Silicon Nitride),作为接触孔刻蚀的阻挡层(stop layer);As shown in Figure 46, step S28: form a layer of silicon oxide 120 (Silicon Oxide) and a third silicon nitride 121 (Silicon Nitride) on the surface of the channel region, source region, drain region and amorphous silicon 110 as contacts Stop layer for hole etching;
如图47所示,步骤S29:在第三氮化硅121的表面沉积一层厚厚的第一磷硅酸盐玻璃122(PSG,Phospho-Silicate Glass),以充当预金属介质(PMD,pre-Metal-Dielectric);As shown in Figure 47, step S29: deposit a thick first phospho-silicate glass 122 (PSG, Phospho-Silicate Glass) on the surface of the third silicon nitride 121, to serve as pre-metal medium (PMD, pre -Metal-Dielectric);
如图48和图49所示,步骤S30:利用化学机械抛光(CMP)的方式将预金属介质层磨平,直至沟道区上的第三氮化硅121、氧化硅120以及多氧化物113被磨掉,露出里面的非晶硅110;As shown in FIG. 48 and FIG. 49, step S30: use chemical mechanical polishing (CMP) to polish the pre-metal dielectric layer until the third silicon nitride 121, silicon oxide 120 and polyoxide 113 on the channel region Grinded away, exposing the amorphous silicon 110 inside;
如图50-52所示,步骤S31:通过刻蚀的方式将沟道区的非晶硅110移除,露出鳍区108的蚀刻阻挡层109;As shown in FIGS. 50-52 , step S31 : removing the amorphous silicon 110 in the channel region by etching to expose the etch barrier layer 109 in the fin region 108 ;
如图53-图55所示,步骤S32:继续通过刻蚀的方式将蚀刻阻挡层109去除;这里,可以通过刻蚀的方式去除鳍区108侧壁上的蚀刻阻挡层109。As shown in FIGS. 53-55 , step S32 : continue to remove the etching barrier layer 109 by etching; here, the etching barrier layer 109 on the sidewall of the fin region 108 may be removed by etching.
如图56-图58所示,步骤S33:通过低温氧化反应在鳍区108表面形成一层氧化层,作为底界面层123(BIL,bottom interface layer), 以使高介电介质124在底界面层123上生长;As shown in FIGS. 56-58 , step S33: form an oxide layer on the surface of the fin region 108 through a low-temperature oxidation reaction as a bottom interface layer 123 (BIL, bottom interface layer), so that the high dielectric medium 124 is at the bottom interface Growth on layer 123;
如图59和图60所示,步骤S34:通过原子层沉积(ALD,Atomic Layer Deposition)工艺沉积一层高介电氧化铪(High-k HfO 2)作为电介质124,形成栅极介质。这里可以只在底界面层123的上表面沉积一层高介电氧化铪作为栅极介质。 As shown in FIG. 59 and FIG. 60 , step S34 : Deposit a layer of high-k HfO 2 as the dielectric 124 by atomic layer deposition (ALD, Atomic Layer Deposition) process to form a gate dielectric. Here, a layer of high dielectric hafnium oxide can be deposited only on the upper surface of the bottom interface layer 123 as the gate dielectric.
在本实施例中,在栅极介质上形成栅极,在金属区和第一源区上形成源极和在漏区上形成漏极中,包括:In this embodiment, the gate is formed on the gate dielectric, the source is formed on the metal region and the first source region, and the drain is formed on the drain region, including:
如图61和图62所示,步骤S35:使用原子层沉积(ALD,Atomic Layer Deposition)工艺在电介质124层上沉积一层功函数金属TiAi基合金125作为栅极(gate TiAl);这里,功函数金属可以根据器件特性进行选择,不限定为TiAi基合金125。As shown in Figure 61 and Figure 62, step S35: use atomic layer deposition (ALD, Atomic Layer Deposition) process to deposit a layer of work function metal TiAi base alloy 125 on the dielectric 124 layer as gate (gate TiAl); Here, work The functional metal can be selected according to device characteristics, and is not limited to TiAi-based alloy 125.
如图63和图64所示,步骤S36:通过物理气相沉积(PVD)的方式沉积一层厚厚的第一金属钨126,第一金属钨126填充在功函数金属的空腔中;As shown in FIG. 63 and FIG. 64, step S36: deposit a thick layer of first metal tungsten 126 by means of physical vapor deposition (PVD), and the first metal tungsten 126 is filled in the cavity of the work function metal;
如图65-图67所示,步骤S37:通过化学机械抛光(CMP)的方式磨平金属钨,使第一金属钨126与第一磷硅酸盐玻璃122层的表面平齐;As shown in FIG. 65-FIG. 67, step S37: smoothen the metal tungsten by means of chemical mechanical polishing (CMP), so that the surface of the first metal tungsten 126 is flush with the surface of the first phosphosilicate glass 122 layer;
如图68所示,步骤S38:再沉积一层第二磷硅酸盐玻璃127;As shown in FIG. 68, step S38: depositing a second layer of phosphosilicate glass 127;
如图69和图70所示,步骤S39:通过光刻方式在第二磷硅酸盐玻璃127上设置源漏接触图案128,露出第一源区和漏区对应的位置;As shown in FIG. 69 and FIG. 70 , step S39: providing a source-drain contact pattern 128 on the second phosphosilicate glass 127 by photolithography to expose the corresponding positions of the first source region and the drain region;
如图71和图72所示,步骤S40:刻蚀源区和漏区对应的裸露部位的第二磷硅酸盐玻璃127,直至氮化硅的阻挡层露出;并刻蚀沟道区对应的第二磷硅酸盐玻璃127,直至沟道区的第一金属钨126露出;As shown in FIG. 71 and FIG. 72, step S40: etch the second phosphosilicate glass 127 at the exposed parts corresponding to the source region and the drain region until the barrier layer of silicon nitride is exposed; and etch the corresponding part of the channel region The second phosphosilicate glass 127, until the first metal tungsten 126 in the channel region is exposed;
如图73和图74所示,步骤S41:去除第一源区和漏区对应的第三氮化硅121和氧化硅120,暴露出第一源区和漏区的碳化硅119;As shown in FIG. 73 and FIG. 74, step S41: removing the third silicon nitride 121 and silicon oxide 120 corresponding to the first source region and drain region, exposing the silicon carbide 119 in the first source region and drain region;
如图75所示,步骤S42:通过物理气相沉积(PVD)的方式沉积一层厚厚的第二金属钨129,第二金属钨129会填充在源极接触和 漏接触的空腔中;As shown in FIG. 75, step S42: Deposit a thick layer of second metal tungsten 129 by means of physical vapor deposition (PVD), and the second metal tungsten 129 will be filled in the cavities of the source contact and the drain contact;
如图76-图78所示,步骤S43:通过化学机械抛光(CMP)的工艺磨平第二金属钨129,使第二金属钨129形成栅极、源极和漏极,完成冷源肖特基晶体管的制备。As shown in Fig. 76-Fig. 78, step S43: Polish the second metal tungsten 129 through the process of chemical mechanical polishing (CMP), so that the second metal tungsten 129 forms the gate, source and drain, and completes the cold source Schott Fabrication of base transistors.
以上所描述的装置实施例仅仅是示意性的,可以根据实际的需要选择其中的部分或者全部模块来实现本实施例方案的目的。本领域普通技术人员在不付出创造性的劳动的情况下,即可以理解并实施。The device embodiments described above are only illustrative, and some or all of the modules can be selected according to actual needs to achieve the purpose of the solution of this embodiment. It can be understood and implemented by those skilled in the art without any creative efforts.
最后应说明的是:以上实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的精神和范围。Finally, it should be noted that: the above embodiments are only used to illustrate the technical solutions of the present invention, rather than to limit them; although the present invention has been described in detail with reference to the foregoing embodiments, those of ordinary skill in the art should understand that: it can still be Modifications are made to the technical solutions described in the foregoing embodiments, or equivalent replacements are made to some of the technical features; and these modifications or replacements do not make the essence of the corresponding technical solutions deviate from the spirit and scope of the technical solutions of the various embodiments of the present invention.

Claims (13)

  1. 一种冷源肖特基晶体管,其特征在于,包括:A cold source Schottky transistor, characterized in that it comprises:
    衬底;Substrate;
    源区,设置在所述衬底上,所述源区包括第一源区和与所述第一源区相连接的金属区,所述第一源区为重掺杂区;a source region disposed on the substrate, the source region comprising a first source region and a metal region connected to the first source region, the first source region being a heavily doped region;
    漏区,设置在所述衬底上,所述漏区为重掺杂区,所述漏区与所述第一源区的掺杂类型相反;a drain region disposed on the substrate, the drain region is a heavily doped region, and the doping type of the drain region is opposite to that of the first source region;
    沟道区,设置在所述衬底上,所述沟道区位于所述金属区和所述漏区之间,所述沟道区的上侧和/或下侧设置有栅极介质;a channel region, disposed on the substrate, the channel region is located between the metal region and the drain region, and a gate dielectric is provided on the upper side and/or lower side of the channel region;
    源极,设置在所述源区上;a source disposed on the source region;
    漏极,设置在所述漏区上;a drain disposed on the drain region;
    栅极,设置在所述栅极介质上。The gate is arranged on the gate dielectric.
  2. 根据权利要求1所述的冷源肖特基晶体管,其特征在于,所述沟道区为本征区或轻掺杂区。The cold source Schottky transistor according to claim 1, wherein the channel region is an intrinsic region or a lightly doped region.
  3. 根据权利要求1所述的冷源肖特基晶体管,其特征在于,所述第一源区为P型重掺杂区,所述漏区为N型重掺杂区。The cold source Schottky transistor according to claim 1, wherein the first source region is a P-type heavily doped region, and the drain region is an N-type heavily doped region.
  4. 根据权利要求1所述的冷源肖特基晶体管,其特征在于,所述第一源区为N型重掺杂区,所述漏区为P型重掺杂区。The cold source Schottky transistor according to claim 1, wherein the first source region is an N-type heavily doped region, and the drain region is a P-type heavily doped region.
  5. 根据权利要求1所述的冷源肖特基晶体管,其特征在于,所述第一源区的掺杂浓度为1e 19cm -3-1e 22cm -3,且所述第一源区的长度为20nm,所述第一源区的厚度为10nm。 The cold source Schottky transistor according to claim 1, wherein the doping concentration of the first source region is 1e 19 cm −3 to 1e 22 cm −3 , and the length of the first source region is is 20nm, and the thickness of the first source region is 10nm.
  6. 根据权利要求1所述的冷源肖特基晶体管,其特征在于,所述漏区的掺杂浓度为1e 19cm -3-1e 22cm -3,且所述漏区的长度为20nm,所述漏区的厚度为10nm。 The cold source Schottky transistor according to claim 1, wherein the doping concentration of the drain region is 1e 19 cm −3 to 1e 22 cm −3 , and the length of the drain region is 20 nm, so The thickness of the drain region is 10nm.
  7. 根据权利要求2所述的冷源肖特基晶体管,其特征在于,所述沟道区的掺杂浓度为1e 15cm -3,且所述沟道区的长度为20nm,所述沟道区的厚度为10nm。 The cold source Schottky transistor according to claim 2, characterized in that, the doping concentration of the channel region is 1e 15 cm -3 , and the length of the channel region is 20nm, and the channel region The thickness is 10nm.
  8. 根据权利要求1所述的冷源肖特基晶体管,其特征在于,所述金属区的功函数为5.0eV,且所述金属区的长度为10nm,所述金属区的厚度为10nm。The cold source Schottky transistor according to claim 1, wherein the work function of the metal region is 5.0 eV, the length of the metal region is 10 nm, and the thickness of the metal region is 10 nm.
  9. 根据权利要求1所述的冷源肖特基晶体管,其特征在于,所述第一源区、所述漏区和所述沟道区的材质为硅。The cold source Schottky transistor according to claim 1, wherein the material of the first source region, the drain region and the channel region is silicon.
  10. 根据权利要求1所述的冷源肖特基晶体管,其特征在于,所述栅极介质的材质为氧化铪,且所述栅极介质的厚度为1.5nm。The cold source Schottky transistor according to claim 1, wherein the material of the gate dielectric is hafnium oxide, and the thickness of the gate dielectric is 1.5 nm.
  11. 一种权利要求1-10任意一项所述的冷源肖特基晶体管的制备工艺,其特征在于,包括:A preparation process for the cold source Schottky transistor described in any one of claims 1-10, characterized in that it comprises:
    在衬底上形成阱区;forming a well region on the substrate;
    在阱区上形成沟道区、源端和漏端;forming a channel region, a source terminal and a drain terminal on the well region;
    在源端上形成金属区;forming a metal region on the source;
    在源端上形成第一源区和在漏端形成漏区;forming a first source region on the source end and forming a drain region on the drain end;
    在沟道区形成栅极介质;forming a gate dielectric in the channel region;
    在栅极介质上形成栅极、在金属区和第一源区上形成源极和在漏区上形成漏极。A gate is formed on the gate dielectric, a source is formed on the metal region and the first source region, and a drain is formed on the drain region.
  12. 根据权利要求11所述的冷源肖特基晶体管的制备工艺,其特征在于,所述在源端上形成金属区,包括:The manufacturing process of the cold source Schottky transistor according to claim 11, wherein said forming a metal region on the source terminal comprises:
    在沟道区、源端和漏端上生成一层硬掩膜;Form a layer of hard mask on the channel region, source terminal and drain terminal;
    在硬掩膜上设置图案层;providing a patterned layer on the hard mask;
    刻蚀未设置图案层的硬掩膜,露出源端和部分沟道区;Etching the hard mask with no pattern layer, exposing the source end and part of the channel region;
    在整个器件表面生成一层金属层;Generate a metal layer over the entire device surface;
    刻蚀金属层,去除沟道区上的金属层和源端处部分金属层;Etching the metal layer to remove the metal layer on the channel region and part of the metal layer at the source end;
    去除硬掩膜和硬掩膜表面的金属层。The hard mask and the metal layer on the surface of the hard mask are removed.
  13. 根据权利要求12所述的冷源肖特基晶体管的制备工艺,其特征在于,所述在源端上形成第一源区和在漏端形成漏区,包括:The manufacturing process of the cold source Schottky transistor according to claim 12, wherein said forming the first source region on the source end and forming the drain region on the drain end comprises:
    在阱区上裸露的源端和漏端外延生长碳化硅,形成第一源区材料 层和漏区材料层;Epitaxially growing silicon carbide on the exposed source and drain ends of the well region to form a first source material layer and a drain material layer;
    对第一源区材料层和漏区材料层进行预非晶化注入掺杂,形成第一源区和漏区。Pre-amorphization implantation doping is performed on the first source region material layer and the drain region material layer to form the first source region and the drain region.
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