WO2023100993A1 - Copolymère aromatique vinylique modifié, procédé de production associé, copolymère de diène conjugué modifié obtenu à partir de celui-ci, composition de résine, résine réticulée et élément structural - Google Patents

Copolymère aromatique vinylique modifié, procédé de production associé, copolymère de diène conjugué modifié obtenu à partir de celui-ci, composition de résine, résine réticulée et élément structural Download PDF

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WO2023100993A1
WO2023100993A1 PCT/JP2022/044472 JP2022044472W WO2023100993A1 WO 2023100993 A1 WO2023100993 A1 WO 2023100993A1 JP 2022044472 W JP2022044472 W JP 2022044472W WO 2023100993 A1 WO2023100993 A1 WO 2023100993A1
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copolymer
compound
modified
conjugated diene
vinyl aromatic
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PCT/JP2022/044472
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Japanese (ja)
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正直 川辺
格 倉富
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日鉄ケミカル＆マテリアル株式会社
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013—Fillers, pigments or reinforcing additives

Definitions

  • the present invention provides a modified vinyl aromatic copolymer having a branched structure, a method for producing the same, a modified conjugated diene copolymer having excellent processability, excellent tensile strength and abrasion resistance, and obtained therefrom.
  • the present invention relates to a resin composition, a cross-linked resin obtained by cross-linking the resin composition, and a structural member.
  • a compound having a plurality of vinyl groups in a molecule is likely to undergo an intermolecular cross-linking reaction due to polymerization. Using this property, it is possible to add such a compound to a polymerization system and copolymerize it to form a crosslinked product, thereby making the polymer insoluble or imparting functionality.
  • a compound having multiple vinyl groups in the molecule is divinylbenzene. Divinylbenzene can be used as an ion-exchange resin by adding a small amount of this to a styrene polymerization system, copolymerizing it, and introducing a functional group such as a sulfonic acid group. can be used.
  • styrenic resins such as synthetic rubbers, ABS resins, MBS resins and unsaturated polyester resins
  • a modifier for polyethylene As another example, it is expected to impart functionality to a thermoplastic resin by reacting a polyfunctional vinyl aromatic copolymer having a branched structure with the thermoplastic resin.
  • conjugated diene rubbers such as SBR (styrene-butadiene rubber), BR (butadiene rubber), IR (isoprene rubber), and styrene-isoprene rubber are excellent in wear resistance, elasticity, and water resistance, and are used as molding materials and resins. It is used for various purposes such as a modifier.
  • This conjugated diene rubber is automobile tires. Characteristics required for tires include mechanical strength, wear resistance, wet grip, and the like (hereinafter also referred to as strength and the like). Furthermore, in recent years, the development of tires with excellent energy-saving performance, ie, low fuel consumption (so-called “eco-tires”) has been actively carried out. Such eco-tires are required to have low rolling resistance in addition to strength and the like.
  • a terminal-modified solution polymerized SBR (terminal-modified S-SBR) is attracting attention as a material that imparts resistance.
  • the terminal-modified S-SBR has a functional group at the molecular terminal of SBR, and the functional group at the molecular terminal interacts with the filler. This interaction improves the dispersibility of the filler in the SBR and constrains the molecular ends of the SBR to reduce the mobility. As a result, hysteresis loss (internal friction) of the tire is reduced and rolling resistance is lowered. Taking advantage of this characteristic, eco-tires with both strength and low rolling resistance are being developed.
  • 6,200,300 discloses a star-block interpolymer having random copolymer blocks of conjugated diene and monovinyl aromatic monomers, a polyconjugated diene block, and functional groups derived from a multifunctional lithium-based initiator, and a rolling It is disclosed that it can be widely used as a rubber in making tire treads with excellent properties such as reduced drag and improved traction properties.
  • the techniques of Patent Documents 1 and 2 are considered to have the effect of ensuring the processability of rubber by introducing a branched structure into the rubber component. However, as for the interaction with the filler for ensuring the strength, there is no special device, and the contribution to the strength is not sufficient.
  • Patent Document 3 a rubber composition in which a predetermined amount of carbon black is blended with a blend rubber containing a plurality of diene rubbers has a functional group that interacts with carbon black at the molecular chain end, and a diene rubber A rubber composition is disclosed which comprises a low molecular weight functional group-containing polymer having a polymer structure similar to that of the rubber component.
  • This rubber composition can control the distribution amount of carbon black in each diene rubber component by blending a low-molecular-weight compound having interaction with carbon black into the rubber. Therefore, it is possible to effectively express the characteristics of each rubber component, and to achieve compatibility between rubber characteristics such as rolling characteristics and wet characteristics, which have a trade-off relationship.
  • Patent Document 4 crosslinked rubber particles containing a conjugated diene unit, an aromatic vinyl unit and a unit having at least two polymerizable unsaturated groups, and a conjugated diene/aromatic
  • a rubber composition containing a vinyl copolymer rubber is disclosed wherein the crosslinked rubber particles may contain monomeric units having carboxylic acid groups, amino groups, hydroxyl groups, epoxy groups and alkoxysilyl groups. .
  • Patent Document 4 The technique disclosed in Patent Document 4 is to add a carboxylic acid group, an amino group, a carboxylic acid group, an amino group, By using a polymerizable unsaturated monomer that contains at least one functional group selected from a hydroxyl group, an epoxy group, and an alkoxysilyl group and is copolymerizable with the monomer of the crosslinked rubber particles, It is disclosed that it has an appropriate interaction with inorganic fillers (fillers) such as silica when introduced, and is therefore excellent in dispersibility and workability of inorganic fillers.
  • inorganic fillers fillers
  • At least one functional group selected from carboxylic acid groups, amino groups, hydroxyl groups, epoxy groups and alkoxysilyl groups introduced into the three-dimensionally crosslinked crosslinked rubber particles according to the technique disclosed in the patent publication is Some of them enter the insoluble network structure of the crosslinked rubber particles and cannot contribute to the dispersibility of the inorganic filler outside the crosslinked rubber particles, so the effect of introducing the functional group was not sufficient.
  • Patent Document 5 a crosslinked polymer having a structural unit derived from an ethylenically unsaturated compound and a structural unit derived from a crosslinkable compound in which the glass transition temperature of the homopolymer is 10 ° C.
  • conjugated diene compound derived from A conjugated diene rubber composed of an interpenetrating network structure type polymer composed of a non-crosslinked polymer having structural units is disclosed.
  • a crosslinked polymer composed of styrene and divinylbenzene is polymerized, some of the active species are deactivated, and then butadiene and n-butyllithium as a polymerization initiator are added.
  • a conjugated diene-based rubber which is polymerized with a polymer, and after the polymerization is completed, a modifier such as N,N-bis(triethylsilyl)aminopropylmethyldimethoxysilane is added to modify the conjugated diene rubber.
  • a modifier such as N,N-bis(triethylsilyl)aminopropylmethyldimethoxysilane is added to modify the conjugated diene rubber.
  • the molecular terminal of the non-crosslinked polymer may be modified with a modifying agent comprising a functional group-containing silane compound having an amino group, a phosphino group, or a thiol group. It is disclosed, but does not show that the crosslinked polymer itself composed of styrene and divinylbenzene is modified with a modifying agent.
  • the crosslinked polymer composed of styrene and divinylbenzene disclosed in the patent publication is a three-dimensionally crosslinked solvent-insoluble polymer, and therefore has a structural unit derived from a conjugated diene compound. Even if the interpenetrating network structure type polymer is formed from the non-crosslinked polymer, it has a structurally fragile microgel, and thus the effect of improving the mechanical strength was not sufficient.
  • Patent Document 6 discloses crosslinked polymer particles characterized by having polysiloxane on the particle surface and having an average particle size of 0.01 to 10 ⁇ m.
  • divinylbenzene and styrene are subjected to suspension polymerization in the presence of a radical polymerization initiator to obtain polymer particles.
  • Polysiloxane-modified crosslinked polymer particles are recovered.
  • the resulting polysiloxane-modified crosslinked polymer particles can be blended with a polypropylene resin to improve the blocking resistance of the film.
  • the polysiloxane-modified crosslinked polymer particles of the patent publication are used as resin modifiers, toner fluidity improvers, resin film antiblocking agents, film lubricants, spacers, standard particles, antigen-antibody reaction test particles, and thermal paper.
  • polysiloxane-modified crosslinked polymer particles disclosed in the patent publication are solvent-insoluble crosslinked polymer particles and are hard and brittle. When used to modify polymers, they have not been able to improve strength.
  • US Pat. No. 6,200,303 discloses reacting a divinylidene polymerization initiator with a monomer to form the "omega, omega-carbanion" living polymer molecule of the present invention, comprising at least one living polymer molecule and at least one equivalent of a chain end modifier. It is disclosed that a modified polymer molecule is obtained by reacting with.
  • a coupling agent such as tin tetrachloride is reacted with the carbanionic polymer chain end positions to form a branched modified polymer molecule.
  • branched modified polymer molecules can be formed by adding to the polymerization mixture a monomer that can react with more than one growing polymer chain at any time during polymerization, such as divinylbenzene.
  • divinylbenzene is post-added as a coupling agent in accordance with the technique of the patent publication, there is a problem that a microscopic gel is generated and the strength improvement effect is not sufficient.
  • Patent Document 8 a polymer obtained by cross-linking aminomethylated polystyrene with 1% divinylbenzene is swelled with methylene chloride and then reacted with tolylene 2,4-diisocyanate (TDI) to obtain ferrocenyl silylate.
  • TDI tolylene 2,4-diisocyanate
  • the crosslinked polymer disclosed in the patent publication was swollen with methylene chloride, it is suggested that the crosslinked polymer disclosed in the patent publication is not solvent-soluble, and solvent-soluble branched The polymer was unimaginable.
  • the crosslinked polymer disclosed in the patent publication is useful as a catalyst for enantioselective hydrogenation, the possibility of contributing to the improvement of the properties of conjugated diene polymers was not suggested.
  • Patent Document 9 discloses an ethylene-styrene-divinylbenzene copolymer chain and a polystyrene chain obtained by anionic polymerization in the presence of an ethylene-styrene-divinylbenzene copolymer obtained by coordination polymerization and a styrene monomer.
  • a modified resin composition is disclosed by blending an antioxidant, a silane coupling agent, and a radical initiator with a copolymer (cross-copolymer) having and kneading.
  • the cross-copolymer used in the examples of the patent publication has a divinylbenzene content far below 0.5 mol%, and furthermore, the silane coupling agent added later is the cross-copolymer.
  • the ends are modified, and the possibility of coupling the conjugated diene-based living polymer to improve the properties of the conjugated diene-based polymer was not suggested.
  • Patent Document 10 a specific polyfunctional vinyl aromatic copolymer having both a branched structure and a function of interacting with a filler is used as a structural unit of a conjugated diene rubber to improve processability and strength. and homogeneity (Patent Document 10). Furthermore, Patent Documents 11 to 14 propose polyfunctional vinyl aromatic copolymers essentially containing an indane structural unit, a structural unit derived from a cycloolefin compound, or a structural unit derived from styrene. The present invention contributes to the modification of resins by a method different from the methods disclosed in Patent Documents 10 to 14, and is particularly useful for rubber compositions such as tires, and has properties such as strength and wear resistance. We propose a material that can contribute to the improvement.
  • JP-A-2003-73434 Japanese translation of PCT publication No. 2004-517202 JP 2005-213381 A WO 2002/000779 JP 2013-155268 A JP-A-7-207029 Japanese Patent Publication No. 2016-530361 JP-A-8-259584 JP 2012-92197 A WO2018/084128 JP-A-2004-123873 JP 2018-39995 A WO2018/181842 WO2020/67336
  • the present invention solves the above problems and provides a modified vinyl aromatic copolymer having reactivity and solubility that can be used for the production of a modified conjugated diene copolymer having a branched structure without producing a small amount of microgel by-products. It is an object of the present invention to provide a resin composition having a branched structure having coalescence, workability, strength and homogeneity, a crosslinked resin obtained by crosslinking the same, and a structural member.
  • a structural unit (a) derived from a specific divinyl aromatic compound a structural unit (b) derived from a monovinyl aromatic compound, and a conjugated diene compound derived from found that a copolymer obtained by modifying the active terminal of a branched vinyl aromatic copolymer containing the structural unit (c) with an amino group, an alkoxysilyl group, or a hydroxyl group can solve the above problems, We have completed the present invention.
  • the present invention contains a structural unit (a) derived from a divinyl aromatic compound, a structural unit (b) derived from a monovinyl aromatic compound, and a structural unit (c) derived from a conjugated diene compound, and a structural unit ( 95 mol% or more of a) is a crosslinked structural unit (a1) represented by the following formula (1),
  • R1 represents an aromatic hydrocarbon group having 6 to 30 carbon atoms.
  • the modified vinyl aromatic copolymer contains 0.5 mol% or more and 45.0 mol% or less of the structural unit (a) derived from the divinyl aromatic compound, and the structural unit (a) derived from the monovinyl aromatic compound ( It preferably contains 0.5 mol% or more and 99.0 mol% or less of b) and contains 0.5 mol% or more and 99.0 mol% or less of a structural unit (c) derived from a conjugated diene compound,
  • the molecular weight distribution (Mw/Mn) represented by the ratio of the weight average molecular weight Mw to the number average molecular weight Mn is preferably 10.0 or less. Also, the average number of functional groups per molecule may range from 2 to 20.
  • Examples of the monovinyl aromatic compounds include styrene, vinylnaphthalene, vinylbiphenyl, m-methylstyrene, p-methylstyrene, o,p-dimethylstyrene, m-ethylvinylbenzene, indene and p-ethylvinylbenzene.
  • the present invention uses an alkali metal compound or an alkaline earth metal compound as an anionic polymerization initiator, and a divinyl aromatic compound and a monovinyl aromatic compound, or a divinyl aromatic compound and a monovinyl aromatic compound can be anionically copolymerized therewith.
  • a polymerization step of obtaining a vinyl aromatic copolymer having a branched structure and an active terminal by copolymerizing such monomers, and adding amino groups, alkoxysilyl groups is a manufacturing method.
  • the present invention provides a modified vinyl aromatic copolymer obtained by reacting a polymer of a conjugated diene compound or a copolymer of a conjugated diene compound and an aromatic vinyl compound with the modified vinyl aromatic copolymer. It is a conjugated diene copolymer.
  • the modified conjugated diene-based copolymer contains 0.001 to 6% by weight of the structural unit (A1) derived from the modified vinyl aromatic copolymer, and 29 to 99% of the structural unit (B1) derived from the conjugated diene compound. .999% by weight and 0 to 70% by weight of the structural unit (C1) derived from an aromatic vinyl compound. Then, in the differential molecular weight distribution curve obtained by gel permeation chromatography (GPC) measurement, when the total area is 100%, the number average molecular weight (Mn ) is preferably 10% or more.
  • the present invention provides at least one reinforcing agent selected from the group consisting of silica-based inorganic fillers, metal oxides, metal hydroxides and carbon black for 100 parts by weight of the modified conjugated diene-based copolymer.
  • the resin composition is characterized by containing 0.5 to 200 parts by weight of a filler.
  • the resin composition can further contain a cross-linking agent.
  • the present invention is a cross-linked resin product obtained by cross-linking a resin composition further containing a cross-linking agent. Further, the present invention is a structural member characterized by including this resin crosslinked product.
  • the modified vinyl aromatic copolymer of the present invention can be used as a raw material for a modified conjugated diene copolymer.
  • a crosslinked resin composition obtained by containing a filler in this modified conjugated diene copolymer and crosslinked has excellent filler dispersibility, excellent mechanical strength, and excellent abrasion resistance.
  • seismic isolation rubber, rubber hoses, rubber rollers, footwear materials, etc. It can also be applied to molding materials, resin modifiers, and the like.
  • films and sheets coated with the curable resin composition containing the modified vinyl aromatic copolymer of the present invention are suitably used in plastic optical parts, touch panels, flat displays, film liquid crystal devices and the like.
  • the modified vinyl aromatic copolymer of the present invention is used as the main material of films, sheets and prepregs for thermoplastic resins or curable resin compositions. It can also be used as a modifier to modify the properties of Moreover, the curable resin composition containing the polyfunctional vinyl aromatic copolymer of the present invention as a main material can be processed into films, sheets and prepregs for use. Furthermore, the curable resin composition containing the modified vinyl aromatic copolymer of the present invention can also be used as various optical elements including optical waveguides and optical lenses.
  • the modified vinyl aromatic copolymer of the present invention (hereinafter also referred to as a modified copolymer or copolymer) comprises a structural unit (a) derived from a divinyl aromatic compound and a structural unit derived from a monovinyl aromatic compound. (b) and a copolymer containing a structural unit (c) derived from a conjugated diene compound, wherein 95 mol% or more of the structural unit (a) is a crosslinked structural unit represented by the above formula (1) (a1).
  • the structural unit (a) derived from the divinyl aromatic compound contained in the modified vinyl aromatic copolymer of the present invention plays an important role as a cross-linking component that branches the copolymer and makes it multifunctional.
  • a polyfunctional modified vinyl aromatic copolymer is used to modify polymers of conjugated diene compounds, a high-molecular-weight multi-branched component is produced, and abrasion resistance can be improved.
  • divinyl aromatic compounds that are preferably used include divinylbenzene (including each isomer), divinylnaphthalene (including each isomer), and divinylbiphenyl (including each isomer), but are limited to these. isn't it. Moreover, these can be used individually or in combination of 2 or more types. Divinylbenzene (m-isomer, p-isomer, or isomer mixture thereof) is more preferable from the viewpoint of moldability.
  • the structural unit (b) derived from the monovinyl aromatic compound contained in the modified vinyl aromatic copolymer of the present invention improves the solvent solubility, compatibility and processability of the copolymer.
  • monovinylaromatic compounds include vinylaromatic compounds such as styrene, vinylnaphthalene, vinylbiphenyl, ⁇ -methylstyrene; o-methylstyrene, m-methylstyrene, p-methylstyrene, o,p-dimethylstyrene, Nuclear alkyl-substituted vinyl aromatic compounds such as o-ethylvinylbenzene, m-ethylvinylbenzene and p-ethylvinylbenzene; cyclic vinyl aromatic compounds such as indene, acenaphthylene, benzothiophene and coumarone; It is not limited.
  • compatibility and processability especially styrene, ethyl vinyl benzene (including each isomer), ethyl vinyl biphenyl (including each isomer), Ethylvinylnaphthalene (including each isomer) and indene are preferably used from the viewpoint of cost and availability. From the viewpoint of compatibility and cost, styrene, ethylvinylbenzene (m-form, p-form or isomer mixture thereof) and indene are more preferred.
  • the structural unit (c) derived from the conjugated diene compound contained in the modified vinyl aromatic copolymer of the present invention has the following properties: 1) to increase the efficiency of introduction of modifying groups to be introduced into the modified vinyl aromatic copolymer; 2) When a polymer of a conjugated diene compound having an active terminal or a copolymer of a conjugated diene compound having an active terminal and an aromatic vinyl compound is reacted with a modified vinyl aromatic copolymer, the modified vinyl aromatic It has the function of increasing the reactivity of the terminal modification group of the group copolymer.
  • the conjugated diene compound is preferably a conjugated diene compound containing 4 to 12 carbon atoms per molecule, more preferably a conjugated diene compound containing 4 to 8 carbon atoms.
  • conjugated diene compounds include, but are not limited to, 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, 1,3-pentadiene, 3-methyl-1 ,3-pentadiene, 1,3-hexadiene, and 1,3-heptadiene.
  • 1,3-butadiene and isoprene are preferred from the viewpoints of ease of copolymerization reaction with an aromatic vinyl compound and ease of industrial availability. These may be used individually by 1 type, and may use 2 or more types together.
  • the modified vinyl aromatic copolymer of the present invention has at least one functional group selected from the group consisting of amino groups (-NR), alkoxysilyl groups (Si-OR) and hydroxyl groups (-OH). modified with an agent or modifier, and the amount of the modifier introduced is such that the average number of functional groups per molecule is 2.0 or more. If the value obtained by dividing the number average molecular weight of the copolymer by the functional group equivalent is 2.0 or more, it can be determined that two or more are functionalized.
  • the introduction amount of the polymerization initiator or modifier having a functional group is preferably 2.0 to 20, more preferably 2.0 to 5.0, more preferably 2.0 to 5.0, more preferably 2.0 to 5.0 functional groups per molecule. 0 to 4.0.
  • the modified vinyl aromatic copolymer of the present invention is preferably 30 mol% or more, more preferably 60 mol% or more of the modifying agent having a functional group introduced as a terminating terminal by reacting with the living terminal at the time of polymerization termination. is modified by binding to the structural unit (c) derived from the conjugated diene compound.
  • the structural unit (c) derived from the conjugated diene compound For example, in an anionic living polymerization, when the monomers are sequentially added and the diene monomer is added later, the molecular weight distribution shifts to the high molecular weight side, and the active terminal is converted to a diene monomer unit. I can confirm. More preferably 80 mol% or more, optimally 90 mol% or more of the modifying agent having a functional group is modified by binding to the structural unit (c) derived from the conjugated diene compound.
  • the modified copolymer of the invention can be produced by the production method of the invention.
  • an alkali metal compound or an alkaline earth metal compound is used as an anionic polymerization initiator, and anionic copolymerization with a divinyl aromatic compound and a monovinyl aromatic compound, or a divinyl aromatic compound and a monovinyl aromatic compound and these and anionic copolymerization is performed.
  • the modified vinyl aromatic copolymer of the present invention comprises a structural unit (a) derived from a divinyl aromatic compound, a structural unit (b) derived from a monovinyl aromatic compound, and a structural unit derived from a conjugated diene compound.
  • a copolymer containing (c), but other monomers requiring anionic polymerizability such as trivinyl aromatic compounds are used within a range that does not impair the effects of the structural units (a) to (c).
  • structural units (e) derived from these other monomers can be introduced into the copolymer.
  • the above other monomers preferably include 1,3,5-trivinylbenzene and 1,3,5-trivinylnaphthalene, but are not limited to these. These can be used alone or in combination of two or more. Other monomers may be used within the range of less than 30 mol % of the total monomers. Accordingly, the structural unit (e) derived from other monomers is within the range of less than 30 mol % relative to the total amount of structural units in the copolymer.
  • a cationic polymerization method after synthesizing a vinyl aromatic copolymer containing a structural unit (a) derived from a divinyl aromatic compound and a structural unit (b) derived from a monovinyl aromatic compound as a precursor,
  • a polymer initiator derived from a polymerization initiator comprising this precursor prepolymer and an alkali metal compound or an alkaline earth metal compound
  • monomers introduced into the precursor prepolymer as other monomers include isobutylene, diisobutylene, cyclobutene, cyclopentene, cyclooctene, norbornene, dicyclopentadiene, 2-methyl-1-butene, 2-methyl-1-pentene, 1-methyl-1-cyclopentene, 2-methyl-1-hexene, 1-methyl-1-cyclohexene, 2-methyl-1-heptene, 2-methyl-1-octen
  • the structural unit (e) derived from other monomers is within the range of less than 30 mol % relative to the total amount of structural units in the copolymer.
  • a divinyl aromatic compound and a monovinyl aromatic compound, or optionally further monomers containing other monomers are combined with an alkali metal compound or an alkaline earth metal.
  • a copolymer is produced by polymerizing in the presence of a polymerization initiator comprising the compound.
  • At least part of the structural unit (a) is the crosslinked structural unit (a1) represented by the formula (1), and the crosslinked structural unit (a1) derived from the divinyl aromatic compound for the structural unit (a) ) is 0.95 or more.
  • the degree of cross-linking of the cross-linked structural unit (a1) is in the range of 0.95 or more, but the lower limit thereof is preferably 0.98 or more, more preferably 0.99 or more.
  • the degree of cross-linking is a parameter that can be arbitrarily controlled and varied.
  • this polymer when this polymer is used to modify a conjugated diene-based (co)polymer, due to heat history in the subsequent steps, intramolecular changes starting from the pendant vinyl groups remaining in the copolymer It is prone to cross-linking reactions and tends to form microgels during compounding and vulcanization.
  • the method for producing the modified copolymer of the present invention includes a polymerization step and a terminal modification step as described above.
  • a polymerization initiator comprising an alkali metal compound or an alkaline earth metal compound used in the polymerization step will be described.
  • the alkali metal compound used as the polymerization initiator is not particularly limited, for example, an organic lithium compound is preferable.
  • the organolithium compound may be either a low molecular weight organolithium compound or a solubilized oligomer organolithium compound. Compounds having a carbon-lithium bond, compounds having a nitrogen-lithium bond, compounds having a tin-lithium bond, and the like can be mentioned in the bonding mode between the organic group and lithium.
  • an organolithium compound provides good initiation efficiency and a good living rate of the polymer.
  • organic lithium compounds include, but are not limited to, organic monolithium compounds, organic dilithium compounds, and organic polylithium compounds.
  • a hydrocarbon containing a functional group is suitable as the organic group, and in that case, there is an advantage that the solubility in an organic solvent is excellent, and the initiation speed is also excellent.
  • a compound having a nitrogen-lithium bond or a compound having a tin-lithium bond a modifying group containing a functional group can be imparted to the starting end.
  • organic alkali metal compounds other than organic lithium compounds include, but are not particularly limited to, organic sodium compounds, organic potassium compounds, organic rubidium compounds, organic cesium compounds, and the like. More specific examples include sodium naphthalene and potassium naphthalene. Other examples include alkoxides such as lithium, sodium and potassium, sulfonates, carbonates, amides, and the like. Moreover, you may use together with another organometallic compound.
  • Alkaline earth metal compounds used as polymerization initiators include organic magnesium compounds, organic calcium compounds, organic strontium compounds, and the like. Compounds such as alkaline earth metal alkoxides, sulfonates, carbonates and amides may also be used. These organic alkaline earth metal compounds may be used in combination with the above alkali metal compounds and other organic metal compounds.
  • an amino group (-NR) includes a primary amino group (-NH2), a secondary amino group (-NHR1) or a tertiary amino group (-NR1R2).
  • An alkoxysilyl group (-Si-OR) is one to three alkoxy groups bonded to silicon. Examples of alkoxy groups that bond to alkoxysilyl groups include methoxy, ethoxy, propoxy, butoxy, pentoxy, and hexoxy groups.
  • the alkoxysilyl group is preferably a methoxysilyl group (-Si-OCH3) or an ethoxysilyl group (-Si-OC2H5).
  • the alkali metal compound having a functional group that can be used as a polymerization initiator is not particularly limited. Alkyllithium, etc. These can impart a functional group to the polymerization initiation terminal of the conjugated diene copolymer.
  • the functional group is not particularly limited, but is preferably a functional group that is inert to alkali metals. Also referred to as a "substituted amino group”), and a protected amino group (hereinafter also referred to as a "protected disubstituted amino group”) are preferred.
  • the protected monosubstituted amino group or protected amino group includes, for example, those obtained by substituting one hydrogen of the monosubstituted amino group or two hydrogens of the amino group with a trialkylsilyl group. .
  • the organic lithium compound used as a polymerization initiator is not particularly limited, and examples thereof include mono-organic compounds such as n-butyllithium, sec-butyllithium, tert-butyllithium, n-propyllithium, iso-propyllithium and benzyllithium.
  • Lithium compounds 1,4-dilithiobutane, 1,5-dilithiopentane, 1,6-dilithiohexane, 1,10-dilithiodecane, 1,1-dilithiodiphenylene, dilithiopolybutadiene, dilithiopolyisoprene, 1,4 -dilithiobenzene, 1,2-dilithio-1,2-diphenylethane, 1,4-dilithio-2-ethylcyclohexane, 1,3,5-trilithiobenzene, 1,3,5-trilithio-2,4 , 6-triethylbenzene and other polyfunctional organolithium compounds.
  • monoorganolithium compounds such as n-butyllithium, sec-butyllithium and tert-butyllithium are preferred.
  • the polymerization initiator having a functional group is not particularly limited, specific examples thereof include the compounds shown below.
  • the types of functional groups that can be imparted to the polymer are described in parentheses. For example, dipropylaminolithium, diisopropylaminolithium, dibutylaminolithium, tetramethyleneiminolithium, pentamethyleneiminolithium, hexamethyleneiminolithium, heptamethyleneiminolithium, 2-dimethylaminoethyllithium, 3-dimethylaminopropyllithium, 3 -diethylaminopropyllithium, 4-dimethylaminobutyllithium (above 2-substituted amino groups), 2-trimethylsilylethylaminoethyllithium, 3-trimethylsilylmethylaminopropyllithium (above 1-substituted amino groups), 2-bistrimethylsilylaminoethyl Lithium, 3-
  • an oligomer initiator obtained by reacting various lithium-based initiators and monomers can be used. At that time, a monomer having at least one functional group selected from the group consisting of an amino group, an alkoxysilyl group and a hydroxyl group can be used.
  • the oligomer initiator is not particularly limited, but preferably has a molecular weight of 1,000 or less because it is industrially easy to handle.
  • Polymerization or copolymerization is carried out using a polymerization initiator having a functional group, and in the next step, at least one selected from the group consisting of an amino group, an alkoxysilyl group, and a hydroxyl group is added to the active terminal of the vinyl aromatic copolymer. or a compound that forms at least one functional group selected from the group consisting of an amino group, an alkoxysilyl group, and a hydroxyl group.
  • the polyfunctional initiator is not particularly limited, but specifically includes an organic dilithium compound and an organic polylithium compound.
  • the organic group is not particularly limited, hydrocarbon is suitable. As a result, there is an advantage that the solubility in an organic solvent is excellent, and the initiation rate is also excellent.
  • the method for preparing the polyfunctional initiator is not particularly limited, but specifically includes a method by reacting a dispersion of metallic lithium and a polyhalogenated hydrocarbon compound.
  • a polar compound may be added in the polymerization step. By adding a polar compound, it participates in the initiation reaction and the growth reaction, and is effective in controlling the molecular weight/molecular weight distribution and promoting the polymerization reaction.
  • polar compounds include ethers such as tetrahydrofuran, diethyl ether, dioxane, ethylene glycol dimethyl ether, ethylene glycol dibutyl ether, diethylene glycol dimethyl ether, diethylene glycol dibutyl ether, dimethoxybenzene, 2,2-bis(2-oxolanyl)propane; tertiary amine compounds such as methylethylenediamine, dipiperidinoethane, trimethylamine, triethylamine, pyridine, quinuclidine; alkali metal alkoxides such as potassium-tert-amylate, potassium-tert-butylate, sodium-tert-butylate, sodium amylate; Compound; phos
  • polar compounds may be used alone or in combination of two or more.
  • the amount of the polar compound to be used is not particularly limited, and can be selected according to the purpose and the like. Generally, it is preferably 0.01 to 100 mol per 1 mol of the polymerization initiator or polyfunctional initiator.
  • Such a polar compound can be used as a regulator of the initiation reaction and growth reaction of the modified vinyl aromatic copolymer (A) in an appropriate amount according to the desired molecular weight and molecular weight distribution.
  • Many polar compounds simultaneously have an effective randomizing effect in the copolymerization of divinyl aromatic compounds and monovinyl aromatic compounds, and can be used as agents for adjusting the distribution of aromatic vinyl compounds and adjusting the amount of styrene blocks. can.
  • the copolymerization of the divinyl aromatic compound and the monomer containing the monovinyl aromatic compound is preferably carried out by solution polymerization in an inert solvent.
  • the polymerization solvent is not particularly limited, and for example, hydrocarbon solvents such as saturated hydrocarbons and aromatic hydrocarbons are used.
  • aliphatic hydrocarbons such as butane, pentane, hexane, and heptane
  • alicyclic hydrocarbons such as cyclopentane, cyclohexane, methylcyclopentane, methylcyclohexane, dimethylcyclohexane, ethylcyclohexane, and decalin
  • benzene, toluene examples include hydrocarbon solvents comprising aromatic hydrocarbons such as xylene and mixtures thereof. It is preferable that each of the above monomers and polymerization solvent or a mixture of them is treated with an organometallic compound.
  • the polymerization temperature at the time of copolymerization is not particularly limited as long as it is a temperature at which living anion polymerization proceeds, but from the viewpoint of productivity, it is preferably 0 ° C. or higher. From the viewpoint of ensuring a sufficient reaction amount, the temperature is preferably 120° C. or less. More preferably, it is 50 to 100°C.
  • the mode of the polymerization reaction is not particularly limited, it can be carried out in a polymerization mode such as a batch system (also referred to as a "batch system") or a continuous system.
  • a polymerization mode such as a batch system (also referred to as a "batch system") or a continuous system.
  • continuous mode one or more connected reactors can be used.
  • the reactor a tank type, tubular type, or the like equipped with a stirrer is used.
  • the molecular weight distribution of the obtained polymer is generally narrow, and Mw/Mn tends to be 1.0 or more and less than 1.8.
  • the molecular weight distribution is generally wide, and Mw/Mn tends to be 1.8 or more and 3 or less.
  • At least one Compounds that have functional groups of the species.
  • the modifier may be a polymerization initiator that forms functional groups during the polymerization process. These polymerization initiators or modifiers introduce functional groups into the copolymer.
  • the reaction temperature, reaction time, and the like when reacting a compound (including a precursor) having a functional group at the active terminal are not particularly limited, but the reaction is preferably performed at 0 to 120° C. for 30 seconds or more.
  • the amount of the polymerization initiator having a functional group and the modifier is not particularly limited, but the total moles of the modifier having a functional group with respect to the number of equivalents of the active species induced by the polymerization initiator or the polyfunctional initiator
  • the number is preferably in the range of 0.05 to 6 times.
  • a more preferred lower limit is 0.3, still more preferably 0.5, and particularly preferably 0.7.
  • the upper limit is more preferably 3 times, more preferably 2 times, and particularly preferably 1.5 times.
  • An addition amount of 0.05 times or more is preferable from the viewpoint of obtaining a sufficient modification rate in the intended modified vinyl aromatic copolymer.
  • the modification reaction when the polymerization process is a batch system, the modification reaction may be performed subsequently in the reactor used in the polymerization process, or may be transferred to the next reactor. When the polymerization process is a continuous system, it is transferred to the next reactor.
  • the terminal modification step is preferably carried out immediately after the polymerization step, preferably within 5 minutes by mixing the modifier and allowing the reaction to proceed.
  • a reactor for the modification reaction is preferably sufficiently agitated. Specifically, there are a static mixer type reactor, a tank type reactor with a stirrer, and the like.
  • the structural unit (c) of the vinyl aromatic copolymer is reacted with a modifying agent having at least one functional group selected from an amino group, an alkoxysilyl group, and a hydroxyl group. It is a step of denaturation by allowing The modifier must have an amino group, an alkoxysilyl group or a hydroxyl group as a functional group, and other functional groups such as halogen groups, ketone groups, ester groups, amide groups, epoxy You may have a group.
  • the modifier having an amino group is not particularly limited, but specific examples include compounds that have an amino group and a functional group that binds to the active terminal of the polymer in the molecule, and preferably have no active hydrogen.
  • the amino group is not particularly limited, but specifically, a functional group inert to an alkali metal is preferable, and a disubstituted amino group, that is, a tertiary amine, a protected monosubstituted amino group, two hydrogen A protected amino group is preferred.
  • Examples of a protected monosubstituted amino group or an amino group in which two hydrogens are protected include one hydrogen in the monosubstituted amino group or two hydrogens in the amino group, each of which is substituted with a trialkylsilyl group. The following are listed.
  • the modifier having an alkoxysilyl group is not particularly limited, but specifically, a compound having multiple alkoxysilyl groups in the molecule (this includes compounds having a silyl group to which multiple alkoxy groups are bonded). , and compounds having in the molecule an alkoxysilyl group and a functional group that binds to the active terminal of the polymer. These compounds are preferably compounds having no active hydrogen.
  • the modifier that forms a hydroxyl group is not particularly limited, but specifically, a compound having a functional group that binds to the active terminal of the polymer and that generates a hydroxyl group after the bonding reaction, A compound having a functional group which does not bond and which subsequently generates a hydroxyl group by a reaction such as hydrolysis can be mentioned, and a compound having no active hydrogen is preferable.
  • Compounds having a functional group that forms a hydroxyl group after the bonding reaction include compounds having a ketone group, an ester group, an amide group, an epoxy group, and the like.
  • Compounds having a functional group that generates a hydroxyl group by a reaction such as hydrolysis after the bonding reaction include compounds having an alkoxysilyl group, an aminosilyl group, and the like.
  • the compound that binds to the active terminal of the polymer to form an amino group and a hydroxyl group at the terminal of the polymer is not particularly limited, but N,N,N',N'-tetramethyl-4,4'-diaminobenzophenone ( Michler's ketone), ketone compounds having an amino group such as N,N,N',N'-tetraethyl-4,4'-diaminobenzophenone; cyclic urea compounds such as N,N'-dimethylimidazolidinone and N-methylpyrrolidone ; Cyclic amides, ie lactam compounds; N,N,N',N'-tetraglycidyl-1,3-bisaminomethylcyclohexane and other amino group-containing epoxy compounds; Nitrogen-containing heterocyclic compounds described in JP-A-2001-131227 Epoxy compounds having groups are exemplified.
  • the compound that forms an alkoxysilyl group at the terminal of the polymer by binding to the active terminal of the polymer is not particularly limited, but includes halogenated alkoxysilane compounds such as trimethoxychlorosilane, triethoxychlorosilane, and diphenoxydicrylorosilane.
  • polyfunctional alkoxysilane compounds such as bis(trimethoxysilyl)ethane and bis(3-triethoxysilylpropyl)ethane;
  • the compound that forms an alkoxysilyl group and a hydroxyl group at the polymer terminal by bonding with the polymer active terminal is not particularly limited, but 3-glycidoxypropyltrimethoxysilane, 3-glycidoxypropyltriethoxysilane epoxy
  • a polysiloxane compound having a group and an alkoxysilyl group in the molecule is exemplified.
  • the compound that binds to the polymer active terminal to form an amino group and an alkoxysilyl group at the polymer terminal is not particularly limited, but 3-dimethylaminopropyltrimethoxysilane, 3-dimethylaminopropyldimethoxymethylsilane, 3 -Dimethylaminopropyltriethoxysilane, bis(3-trimethoxysilylpropyl)methylamine, bis(3-triethoxysilylpropyl)alkoxysilane compound having an alkyl group having an amino substituent such as methylamine; N-[ 3-(Triethoxysilyl)-propyl]-N,N'-diethyl-N'-trimethylsilyl-ethane-1,2-diamine, 3-(4-trimethylsilyl-1-piperazinyl)propyltriethoxysilane, etc.
  • WO2007/ 034785 Alkoxysilane compound with a protected monosubstituted amino group attached; N-[2-(trimethoxysilanyl)-ethyl]-N,N',N'-trimethylethane-1,2-diamine , 1-[3-(triethoxysilanyl)-propyl]-4-methylpiperazine, 2-(trimethoxysilanyl)-1,3-dimethylimidazolidine, bis-(3-dimethylaminopropyl)-dimethoxysilane WO2008/013090, such as alkoxysilane compounds having multiple substituted amino groups; 1,4-bis[3-(trimethoxysilyl)propyl]piperazine, 1,4-bis[3-(triethoxysilyl) Nitrogen-containing heterocyclic ring-bonded alkoxysilane compounds described in WO2011/040312 such as propyl]piperazine; 3-[N,N-bis(trimethyls
  • the modified copolymer of the present invention or the modified vinyl aromatic copolymer of the present invention obtained by the production method described above contains at least one reactive functional group selected from the group consisting of amino groups, alkoxysilyl groups and hydroxyl groups. modified by the group. Therefore, it may be molded and cured alone, but it is preferable to use other polymerizable resins for modifying functional groups and synthesizing high-molecular-weight multi-branched components.
  • the modified vinyl aromatic copolymer of the present invention is used when obtaining a conjugated diene compound alone and/or a conjugated diene copolymer (rubber) obtained by copolymerizing a conjugated diene compound with other monomers. , functional group modification and synthesis of high molecular weight hyperbranched components.
  • the proportion of multi-branched components is preferably 40 area % or more, more preferably 50 to 80 area %.
  • the modified copolymer of the present invention is excellent as a modifier for conjugated diene-based (co)polymers (rubbers). Although the detailed mechanism is unknown, by introducing an appropriate amount of functional groups into the modified copolymer of the present invention, the rubber is modified to form a modified conjugated diene copolymer (modified rubber). It is presumed that this tends to concentrate in the vicinity of the reinforcing filler, increasing the reinforcing effect of the reinforcing filler and leading to an improvement in the wear resistance of the obtained crosslinked product.
  • modified rubber modified conjugated diene copolymer
  • the affinity between the modified conjugated diene copolymer of the present invention and the reinforcing filler is improved, and the dispersed state of each component such as the reinforcing filler in the resin composition is improved. It is presumed to be ideal for improving the physical properties of the resulting crosslinked product (for example, improving wear resistance, improving steering stability, dry grip performance, and wet grip performance).
  • the number of functional groups of the modified conjugated diene-based copolymer becomes too large, the interaction between the copolymers adsorbed on the reinforcing filler causes the reinforcing filler to agglomerate. It is presumed that coalescence does not contribute to improving the affinity between the modified conjugated diene-based copolymer and the reinforcing filler.
  • the average number of functional groups per molecule of the modified vinyl aromatic copolymer is calculated from the functional group equivalent (g/eq) of the modified vinyl aromatic copolymer (A) and the number average molecular weight Mn in terms of styrene, and the following formula (1).
  • Average number of functional groups per molecule [(number average molecular weight Mn)/(average molecular weight of divinyl aromatic compound unit and monovinyl aromatic compound)]/(equivalent weight of functional group) (1)
  • the functional group equivalent of the modified vinyl aromatic copolymer (A) means the mass of the divinyl aromatic compound unit and the monovinyl aromatic compound bonded per functional group.
  • the equivalent weight of the functional group can be calculated from the area ratio of the peak derived from the functional group and the peak derived from the polymer main chain using 1 H-NMR or 13 C-NMR.
  • the amount of the modifier added to the modified vinyl aromatic copolymer (A) is preferably 1 to 200 parts by mass with respect to 100 parts by mass of the unmodified polyfunctional vinyl aromatic copolymer.
  • a more preferable upper limit is 100 parts by weight, more preferably 60 parts by weight, still more preferably 50 parts by weight, and particularly preferably 40 parts by weight. If the amount of modifier added is more than 200 parts by mass, the dispersibility effect of the reinforcing filler (D) is poor, the workability is deteriorated, and the wear resistance of the resulting crosslinked product tends to be reduced. .
  • the addition amount of the modifier having at least one functional group selected from an amino group, an alkoxysilyl group, and a hydroxyl group added to the modified vinyl aromatic copolymer (A) can be determined, for example, by nuclear magnetic resonance spectroscopy. It can be determined using various analytical instruments such as the method.
  • the modified vinyl aromatic copolymer of the present invention contains 0.5 to 45.0 mol % of the structural unit (a) derived from a divinyl aromatic compound.
  • the structural unit consists only of structural units (a), (b) and (c)
  • the molar fraction of structural unit (a) is the total sum of structural units (a), (b) and (c). 0.005 to 0.45. That is, it is 0.5 to 45 mol %.
  • This mole fraction is calculated by the following formula (2).
  • the preferred lower limit of the molar fraction of structural unit (a) is 0.006, more preferably 0.007.
  • a preferred upper limit is 0.40, more preferably 0.35. More preferably, it is 0.01 to 0.30. That is, it is more preferably 1 to 30 mol %. Optimally, it is between 0.03 and 0.15.
  • the lower limit of the preferred content is 0.2 mol%, more preferably 0.4 mol%, and even more preferably. is 0.6 mol %.
  • the upper limit is preferably 35 mol %, more preferably 30 mol %, and still more preferably 25 mol %.
  • the molar fraction of structural unit (b) is calculated by the following formula (3) when it consists only of structural units (a), (b) and (c). (b)/[(a)+(b)+(c)] (3)
  • (a), (b), and (c) are synonymous with formula (2).
  • the modified vinyl aromatic copolymer of the present invention contains 0.5 to 99.0 mol % of the structural unit (b) derived from a monovinyl aromatic compound. In terms of molar fraction, it is 0.005 to 0.99. A preferred lower limit is 0.006. A more preferable lower limit is 0.007. A preferred upper limit is 0.90, more preferably 0.85. Optimally, it is between 0.015 and 0.65.
  • structural unit (b) is more preferably 1 to 85 mol %, most preferably 1.5 to 65 mol %. Even when structural units other than structural units (a), (b) and (c) are included, the preferred mole fraction of structural unit (b) is within the above range.
  • the molar fraction of structural unit (c) is calculated by the following formula (4) when it consists only of structural units (a), (b) and (c). (c)/[(a)+(b)+(c)] (4)
  • (a), (b), and (c) are synonymous with formula (2).
  • the modified vinyl aromatic copolymer of the present invention contains 0.5 to 99.0 mol % of the structural unit (c) derived from the conjugated diene compound. In terms of molar fraction, it is 0.005 to 0.99.
  • a preferred lower limit is 0.05.
  • a more preferable lower limit is 0.010.
  • a more preferable lower limit is 0.10.
  • the upper limit is preferably 0.90, more preferably 0.85. It is more preferably 0.20 to 0.85.
  • structural unit (c) is more preferably 20 to 85 mol %, most preferably 20 to 80 mol %. Even when structural units other than structural units (a), (b) and (c) are included, the preferred molar fraction of structural unit (c) is within the above range.
  • the modified vinyl aromatic copolymer of the present invention preferably contains 1 to 30 mol% of structural units derived from a compound having a functional group.
  • the lower limit is more preferably 3 mol %, still more preferably 5 mol %.
  • the upper limit is more preferably 30 mol %, still more preferably 20 mol %.
  • the modified vinyl aromatic copolymer of the present invention may contain other structural units in addition to the above structural units. Details of other structural units are understood from the description of the manufacturing method.
  • the modified vinyl aromatic copolymer of the present invention has an Mn (standard polystyrene equivalent number average molecular weight measured using gel permeation chromatography) of 500 to 30,000.
  • Mn standard polystyrene equivalent number average molecular weight measured using gel permeation chromatography
  • a preferred lower limit is 600, more preferably 700, still more preferably 800, and particularly preferably 900.
  • the upper limit is preferably 25,000, more preferably 20,000, even more preferably 15,000, and particularly preferably 10,000.
  • Mn is less than 500, the amount of functional groups contained in the copolymer is reduced, so the reactivity of the conjugated diene copolymer with active terminals tends to decrease. Gel formation tends to occur, and molding processability and tensile elongation at break tend to decrease.
  • the molecular weight distribution is 30.0 or less, preferably 25.0 or less.
  • a more preferable lower limit is 1.3, more preferably 1.6.
  • the upper limit is more preferably 20.0, more preferably 15.0, and particularly preferably 10.0. If Mw/Mn exceeds 30.0, the processing properties of the copolymer rubber tend to deteriorate, and gel tends to occur.
  • the modified vinyl aromatic copolymer of the present invention is soluble in a solvent selected from toluene, xylene, tetrahydrofuran, dichloroethane or chloroform, and is preferably soluble in any of the above solvents. Since the modified vinyl aromatic copolymer of the present invention is polyfunctionally modified, 95 mol % or more of the structural units (a) derived from divinylbenzene are crosslinked structural units (a1) represented by the above formula (1). At the same time, solvent solubility requires that the active species and the vinyl group of divinylbenzene fall within a specific ratio range. It is preferable that 50 g or more of the solvent be dissolved in 100 g of the solvent. More preferably, 80 g or more is dissolved.
  • the resulting modified vinyl aromatic copolymer of the present invention has at least one reactive functional group selected from the group consisting of an amino group, an alkoxysilyl group and a hydroxyl group.
  • the modified vinyl aromatic copolymer of the present invention is used when obtaining a conjugated diene compound alone and/or a conjugated diene copolymer (rubber) obtained by copolymerizing a conjugated diene compound with other monomers. , functional group modification and synthesis of high molecular weight hyperbranched components.
  • a modified conjugated diene copolymer having a branched polymer type modifying group (A) based on the modified vinyl aromatic copolymer of the present invention is obtained.
  • a modified diene rubber such as butadiene rubber or isoprene rubber can be obtained.
  • a conjugated diene copolymer can be obtained.
  • an alkali metal compound or an alkaline earth metal compound is used as a polymerization initiator, and the conjugated diene compound (B) is polymerized, or the conjugated diene compound (B) and A polymerization step of copolymerizing an aromatic vinyl compound (C) to obtain a conjugated diene copolymer having an active terminal, and a branched polymer type modifying group (A ) and a terminal denaturation step.
  • conjugated diene compound (B) examples include 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, 1,3-pentadiene, 3-methyl-1,3-pentadiene, 1,3 -heptadiene, 1,3-hexadiene and the like.
  • 1,3-butadiene and isoprene are preferred. These may be used alone or in combination of two or more.
  • aromatic vinyl compound (C) examples include styrene, ⁇ -methylstyrene, 1-vinylnaphthalene, 3-vinyltoluene, ethylvinylbenzene, vinylxylene, 4-cyclohexylstyrene, 2,4,6-trimethylstyrene, tert- Butoxydimethylsilylstyrene, isopropoxydimethylsilylstyrene, and the like can be used alone or in combination of two or more. Among these, styrene is particularly preferred.
  • styrene-butadiene rubber SBR
  • styrene-butadiene rubber BR
  • isoprene is used as the conjugated diene compound (B) and there is no structural unit of the aromatic vinyl compound (C)
  • the isoprene rubber (IR) is obtained.
  • a styrene-butadiene rubber (SBR) structure is particularly preferred because it is excellent in wear resistance, heat resistance, and aging resistance.
  • the polymerization step and terminal modification step can be performed in the same manner as the polymerization step and terminal modification step of the modified vinyl aromatic copolymer described above.
  • the polymerization initiator used in the polymerization step and the compound having a functional group used in the terminal modification step the polymerization initiator and the compound having a functional group described above can be used.
  • the polymerization or copolymerization of the conjugated diene compound (B) is preferably carried out by solution polymerization in an inert solvent.
  • the polymerization solvent is not particularly limited, and for example, hydrocarbon solvents such as saturated hydrocarbons and aromatic hydrocarbons are used.
  • aliphatic hydrocarbons such as butane, pentane, hexane, and heptane
  • alicyclic hydrocarbons such as cyclopentane, cyclohexane, methylcyclopentane, methylcyclohexane, dimethylcyclohexane, ethylcyclohexane, and decalin
  • benzene, toluene examples include hydrocarbon solvents comprising aromatic hydrocarbons such as xylene and mixtures thereof. It is preferable that the conjugated diene-based compound and the polymerization solvent described above are treated with an organometallic compound either singly or as a mixture thereof.
  • allenes and acetylenes contained in the conjugated diene compound and the polymerization solvent can be treated.
  • a polymer having a high concentration of active terminals can be obtained, and a high modification rate can be achieved.
  • the polymerization temperature at which the conjugated diene compound (B) or the conjugated diene compound (B) and the aromatic vinyl compound (C) are copolymerized is not particularly limited as long as it is a temperature at which living anionic polymerization proceeds. From the viewpoint of, it is preferably 0 ° C. or higher, and the structural unit (c ), the reaction temperature is preferably 120° C. or less from the viewpoint of ensuring a sufficient amount of reaction of the modified vinyl aromatic copolymer. More preferably, it is 50 to 100°C.
  • the polymerization mode for copolymerizing the conjugated diene compound (B) or the conjugated diene compound (B) and the aromatic vinyl compound (C) is not particularly limited, but may be a batch system (also referred to as a "batch system"). , continuous polymerization, and the like.
  • continuous mode one or more connected reactors can be used.
  • a tank type, tubular type, or the like equipped with a stirrer is used as the reactor.
  • the molecular weight distribution of the obtained polymer is generally narrow, and Mw/Mn tends to be 1.0 or more and less than 1.8.
  • the continuous type the molecular weight distribution is generally wide, and Mw/Mn tends to be 1.8 or more and 3 or less.
  • the modified conjugated diene-based copolymer obtained is further subjected to a main chain modification step to modify the main chain.
  • a vinyl group in the main chain of the modified conjugated diene-based polymer whose terminal is modified and a silicon having at least one functional group selected from the group consisting of an amino group, an alkoxysilyl group, and a hydroxyl group.
  • This step is the same when using a polymerization initiator and when using the polyfunctional initiator.
  • the hydrosilylation reaction can be carried out in an organic solvent solution or as a polymer (without solvent) in a kneader.
  • the vinyl group of the main chain of the conjugated diene copolymer can be modified by reacting a silicon compound such as a hydrosilane compound having a functional group in the presence of a catalyst.
  • the silicon compound into which the silicon modifying group having a functional group is introduced is not particularly limited, and specific examples include hydrosilane compounds.
  • Such a hydrosilane compound is not particularly limited, and specifically, any hydrosilane compound having at least one functional group selected from the group consisting of an amino group, an alkoxysilyl group, and a hydroxyl group may be used.
  • the general formula HSiR''3-nXn (R'' is not particularly limited, but represents a hydrocarbon group having 1 to 20 carbon atoms, X is an amino group, an alkoxy group, a hydroxyl group or an amino group, represents a hydrocarbon or organosilane compound group having at least one functional group selected from the group consisting of an alkoxysilyl group and a hydroxyl group, and n is 1 to 3.). More preferably n is 1, and preferably R'' represents a hydrocarbon having 1 to 3 carbon atoms. When the hydrosilane compound has such a structure, the yield of the hydrosilylation reaction is high.
  • an amino group (monosubstituted amino group, disubstituted amino group), an alkoxysilyl group, or a hydroxyl group
  • an amino group can be obtained by performing hydrolysis or the like after the hydrosilanization reaction.
  • It may be a silicon compound forming at least one functional group selected from the group consisting of.
  • Such a silicon compound is not particularly limited, and specifically, a functional group that forms at least one functional group selected from the group consisting of an amino group, an alkoxysilyl group, and a hydroxyl group by hydrolysis or the like. Hydrosilane compounds having groups may be mentioned.
  • More specific examples include hydrosilane compounds having a protected monosubstituted amino group, a protected disubstituted amino group, a protected hydroxyl group, and the like.
  • the “protected hydroxyl group” includes, for example, a hydroxyl group in which hydrogen is substituted with a trimethylsilyl group.
  • the silicon compound having an alkoxy group is not particularly limited, but specific examples include dimethylmonomethoxysilane, dimethylmonoethoxysilane, dimethylmonopropoxysilane, dimethylmonobutoxysilane, methyldimethoxysilane, methyldiethoxysilane, Organosiloxane compounds having an H—Si group and an alkoxysilyl group in the molecule, such as propoxysilane, ethyldiethoxysilane, trimethoxysilane, and triethoxysilane.
  • the silicon compound having a disubstituted amino group is not particularly limited, but specific examples include dimethylaminodimethylsilane, diethylaminodimethylsilane, diethylaminodiethylsilane, 3-diethylaminopropyldimethylsilane, 4-dimethylaminobutyldimethylsilane, - diethylaminohexyldimethylsilane.
  • the silicon compound having a protected monosubstituted amino group is not particularly limited, but specific examples include N-methyl-N-trimethylsilylaminodimethylsilane and N-ethyl-N-trimethylsilylaminodiethylsilane.
  • the silicon compound having a protected disubstituted amino group is not particularly limited, but specific examples include N,N-bistrimethylsilylaminodimethylsilane and N,N-bistrimethylsilylaminodiethylsilane.
  • the silicon compound having a protected hydroxyl group is not particularly limited, but specific examples include dimethyltrimethylsilyloxysilane, diethyltrimethylsilysilane, and dibutyltrimethylsilysilane.
  • the silicon compound that forms a hydroxyl group by hydrolysis is not particularly limited, but specific examples include alkoxysilane compounds such as dimethylmonomethoxysilane, dimethylmonoethoxysilane, methyldimethoxysilane, trimethoxysilane, and triethoxysilane; Examples include silane compounds having an epoxy group such as glycidylsilane and diethylglycidylsilane.
  • the amount of the reacted hydrosilane compound is arbitrary according to the purpose, but is preferably 1 per 1 mol of the main chain of the butadiene-based polymer. ⁇ 10 moles.
  • 1 to 10 mol with respect to 1 mol of the main chain good affinity can be obtained when obtaining a resin composition by mixing the modified butadiene-based polymer and silica, as described later. It becomes excellent in workability. More preferably, it is 2 to 5 mol per 1 mol of the main chain.
  • a predetermined catalyst may be used when performing the hydrosilylation reaction.
  • the catalyst is not particularly limited, for example, platinum or platinum-containing catalysts are mainly used.
  • homogeneous platinum catalysts are suitably used, such as chloroplatinic acid solution (ie Speier catalyst), Pt 2 (divinyltetramethyldisiloxane) 3 solution (ie Karstedt catalyst), dichloro( ⁇ -cyclo-1, 5-diene)Pt(II) and the like.
  • the amount of platinum catalyst used in the reaction is preferably 0.01-10 mmol/mol, more preferably 0.1-1 mmol/mol, per hydrosilane compound.
  • the catalyst used in the hydrosilylation reaction includes, for example, a metallocene compound containing any one of Ti, Zr, Hf, Ni, Co, Ru, and Rh. is preferred.
  • the hydrosilylation reaction is preferably carried out in the range of 20-150°C, more preferably in the range of 50-120°C. Within this range, the reaction can be carried out in an appropriate reaction time, and side reactions such as gelation are less likely to occur, making it practical.
  • the reaction time is preferably 10 minutes to 5 hours, more preferably 30 minutes to 2 hours.
  • the weight-average molecular weight (in terms of polystyrene) of the modified conjugated diene-based copolymer of the present invention is preferably 100,000 to 2,000,000, more preferably 150,000 to 1,000,000 in consideration of workability and physical properties.
  • the weight-average molecular weight can be obtained by measuring a chromatogram using GPC using a column filled with polystyrene gel and obtaining a calibration curve using standard polystyrene.
  • the area of the region having the region is 10% or more. More preferably, it is 20 area % or more. Particularly preferably, it is 25 to 80 area %.
  • the modified conjugated diene copolymer of the present invention contains 0.001 to 6% by weight of the structural unit (A1) derived from the modified vinyl aromatic copolymer, and 29 structural units (B1) derived from the conjugated diene compound. 99.999% by weight and 0 to 70% by weight of the structural unit (C1) derived from an aromatic vinyl compound.
  • the structural unit (A1) derived from the modified vinyl aromatic copolymer (A) is preferably 0.001 to 5% by weight, more preferably 0.005 to 5% by weight, still more preferably 0.01 to 5% by weight. % by weight, optimally between 0.001 and 1% by weight.
  • the structural unit (B1) derived from the conjugated diene compound (B) is 29 to 99.999% by weight, preferably 80 to 99.999% by weight, more preferably 90 to 99.995% by weight, and further It is preferably 95 to 99.99% by weight.
  • the structural unit (A1) is in the same range as above, and the structural unit (B1) is 30 to 97.999% by weight, preferably 45 to 94.995% by weight. %, more preferably 55 to 89.99% by weight.
  • the structural unit (C1) derived from the aromatic vinyl compound (C) is 2 to 50% by weight, preferably 5 to 45% by weight, more preferably 10 to 40% by weight.
  • the microstructure (cis, trans, vinyl bond content) of the modified conjugated diene-based copolymer can be arbitrarily changed by using a polar compound, etc., but in the state before terminal modification, the conjugated diene unit occupies
  • the content of vinyl bonds (1,2-bonds) is preferably 10 to 80 mol %.
  • the modified conjugated diene-based copolymer of the present invention is made into a resin composition described later and further crosslinked to be used as an automobile tire, the rolling resistance performance and wear resistance are highly balanced, 20 to 75. mol % is preferred, 25 to 75 mol % is more preferred, and 25 to 70 mol % is even more preferred. Optimally it is 25 to 45 mol %.
  • reaction terminator may be added to the polymer solution of the modified conjugated diene copolymer obtained by the polymerization method described above.
  • the reaction terminator include alcohols such as methanol, ethanol and propanol; organic acids such as stearic acid, lauric acid and octanoic acid; and water.
  • the metals contained in the polymer may be deashed if necessary.
  • a deashing method for example, a method is used in which water, an organic acid, an inorganic acid, an oxidizing agent such as hydrogen peroxide, or the like is brought into contact with the polymer solution to extract the metals, and then the aqueous layer is separated. .
  • the modified conjugated diene-based polymer obtained as described above is obtained as a solution, antioxidants and additives may be added as necessary, and then the solvent may be removed and dried by a conventional method. can. Thereby, it can be used as a raw material for a resin composition to be described later.
  • Specific examples include a method using steam stripping and dehydration drying, and a direct stripping method using a drum dryer, flushing and vent extruder.
  • the antioxidant is not particularly limited, and known ones can be used.
  • Antioxidants include phenol-based stabilizers, phosphorus-based stabilizers, sulfur-based stabilizers, and the like. Specific examples include 2,6-di-tert-butyl-4-hydroxytoluene (BHT), n-octadecyl-3-(4'-hydroxy-3',5'-di-tert-butylphenol ) propinate, 2-methyl-4,6-bis[(octylthio)methyl]phenol and the like are preferred.
  • BHT 2,6-di-tert-butyl-4-hydroxytoluene
  • n-octadecyl-3-(4'-hydroxy-3',5'-di-tert-butylphenol ) propinate 2-methyl-4,6-bis[(octylthio)methyl]phenol and the like are preferred.
  • additives such as water, methanol, ethanol, isopropanol and other alcohols are added to remove or neutralize ionic substances, stearic acid, oleic acid, myristic acid, lauric acid, decanoic acid,
  • a carboxylic acid such as citric acid or malic acid, an inorganic acid aqueous solution, carbon dioxide gas, or the like may be added.
  • the resin composition of the present invention contains 100 parts by mass of raw rubber containing 20 parts by mass or more of a modified conjugated diene-based polymer, and 5 to 200 parts by mass of a filler.
  • the content of the modified conjugated diene polymer in 100 parts by mass of the raw rubber is 20 parts by mass or more, preferably 40 parts by mass or more, more preferably 50 parts by mass or more, and still more preferably 60 parts by mass or more.
  • the filler dispersibility which is the object of the present invention, is excellent, and when the resin composition of the present embodiment is used as a vulcanized composition, performance such as tensile properties and viscoelastic properties is excellent.
  • the content of the modified conjugated diene-based polymer is preferably 90 parts by mass or less, more preferably 80 parts by mass or less. By setting the amount to 90 parts by mass or less, the Mooney viscosity of the unvulcanized resin composition of the present invention is lowered to improve processability.
  • the raw material rubber other than the modified conjugated diene-based polymer is not particularly limited. block copolymers of conjugated diene compounds and vinyl aromatic compounds or hydrogenated products thereof, other conjugated diene copolymers or hydrogenated products thereof, non-diene polymers, natural rubber, and the like.
  • conjugated diene polymer or its hydrogenated product examples include butadiene rubber or its hydrogenated product, isoprene rubber or its hydrogenated product, and the like.
  • random copolymers of conjugated diene compounds and vinyl aromatic compounds or hydrogenated products thereof are not particularly limited, and include, for example, styrene-butadiene copolymer rubbers and hydrogenated products thereof.
  • a block copolymer of a conjugated diene compound and a vinyl aromatic compound or a hydrogenated product thereof are not particularly limited.
  • Styrenic elastomers such as copolymers or hydrogenated products thereof may be mentioned.
  • conjugated diene copolymers or hydrogenated products thereof are not particularly limited, and include, for example, acrylonitrile-butadiene rubber or hydrogenated products thereof.
  • the non-diene polymer is not particularly limited, and examples thereof include olefin elastomers such as ethylene-propylene rubber, ethylene-propylene-diene rubber, ethylene-butene-diene rubber, ethylene-butene rubber, ethylene-hexene rubber, ethylene-octene rubber, and butyl rubber. , brominated butyl rubber, acrylic rubber, fluorine rubber, silicone rubber, chlorinated polyethylene rubber, epichlorohydrin rubber, ⁇ , ⁇ -unsaturated nitrile-acrylic acid ester-conjugated diene copolymer rubber, urethane rubber, polysulfide rubber, etc. .
  • olefin elastomers such as ethylene-propylene rubber, ethylene-propylene-diene rubber, ethylene-butene-diene rubber, ethylene-butene rubber, ethylene-hexene rubber, ethylene-octene rubber, and butyl rubber. ,
  • the modified conjugated diene polymer is modified styrene-butadiene rubber
  • polybutadiene is preferable as the other rubber.
  • the other rubber is preferably natural rubber or polyisoprene rubber.
  • the weight-average molecular weight of the various rubber-like polymers described above is preferably from 2,000 to 2,000,000, more preferably from 5,000 to 1,500,000, from the viewpoint of the balance between performance and processability. is more preferred.
  • a so-called liquid rubber having a low molecular weight can also be used.
  • These rubber-like polymers may be used singly or in combination of two or more.
  • the weight average molecular weight as used herein is the polystyrene-equivalent weight average molecular weight (Mw) obtained by gel permeation chromatography (GPC) measurement.
  • the amount of filler used relative to the raw rubber is adjusted so that if a large amount of filler is used, the hardness and modulus increase, and the desired physical properties are obtained according to the application. Within this range, the dispersion of the filler is good and the workability is good.
  • the filler is from 5 to 150 parts by weight and for footwear applications preferably from 30 to 200 parts by weight. Within the scope of this embodiment, it is possible to deal with a wide range of materials from soft to hard.
  • At least one reinforcing filler selected from the group consisting of silica-based inorganic fillers, metal oxides, metal hydroxides and carbon black is added to 100 parts by mass of the raw rubber. .5 to 200 parts by mass.
  • the silica-based inorganic filler contained in the resin composition it is preferable to use solid particles containing SiO2 or silicate as the main component of the structural unit.
  • the main component means a component that accounts for 50 mass % or more of the whole, preferably a component that accounts for 70 mass % or more, and more preferably a component that accounts for 90 mass % or more.
  • silica-based inorganic fillers include inorganic fibrous substances such as silica, clay, talc, mica, diatomaceous earth, wollastonite, montmorillonite, zeolite, and glass fiber.
  • Silica-based inorganic fillers may be used singly or in combination of two or more.
  • a silica-based inorganic filler having a hydrophobized surface, and a mixture of a silica-based inorganic filler and a non-silica-based inorganic filler can also be used.
  • silica and glass fiber are preferred, and silica is more preferred.
  • silica dry-process silica, wet-process silica, synthetic silicate silica, etc. can be used. Among them, wet-process silica is preferable from the viewpoint of better compatibility between improvement in fracture characteristics and wet skid resistance performance.
  • silica silica having a BET specific surface area of 50 to 500 m 2 /g is used. By blending such silica, excellent fuel efficiency, wear resistance, wet skid performance and steering stability can be obtained. In addition, silica having a high specific surface area, that is, fine particle size silica can be used for good dispersion.
  • the fine particle size silica may contain silica having a CTAB (cetyltrimethylammonium bromide) specific surface area of 180 m 2 /g or more and a BET specific surface area of 185 m 2 /g or more.
  • CTAB cetyltrimethylammonium bromide
  • the average primary particle size is, for example, 25 nm or less.
  • the aggregate size of the fine particle size silica is not particularly limited, and can be 30 nm or more. By having such an aggregate size, while having good dispersibility, excellent reinforcing properties and low fuel consumption can be achieved. durability, wear resistance, wet skid performance and handling stability.
  • the aggregate size is also called the aggregate diameter or the maximum frequency Stokes equivalent diameter, and is the particle diameter when a silica aggregate composed of a series of multiple primary particles is regarded as one particle. It is equivalent.
  • Aggregate size can be measured using, for example, a disk centrifugal sedimentation particle size distribution analyzer such as BI-XDC (manufactured by Brookhaven Instruments Corporation). Specifically, it can be measured by the method described in JP-A-2011-132307.
  • the average primary particle size of fine particle silica is not particularly limited, and is preferably 25 nm or less.
  • the amount of the fine particle size silica compounded in the resin composition of the present invention is not particularly limited, and is preferably 5 parts by mass or more, more preferably 15 parts by mass or more, and even more preferably 20 parts by mass or more, more preferably 25 parts by mass or more, and even more preferably 30 parts by mass or more. When the amount is 5 parts by mass or more, the effect of blending the fine particle silica can be sufficiently obtained.
  • the amount of fine-grained silica is 200 parts by mass or less, preferably 100 parts by mass or less, more preferably 80 parts by mass or less, still more preferably 60 parts by mass or less, and even more preferably 55 parts by mass or less. If it is 200 parts by mass or less, substantially good workability can be obtained.
  • the resin composition of the present invention is preferably the above resin composition further containing 5 to 100 parts by mass of silica or carbon black having a BET specific surface area of less than 185 m 2 /g as a reinforcing filler.
  • silica having a BET nitrogen adsorption specific surface area (NSA) of less than 185 m 2 /g, more preferably less than 150 m 2 /g is preferably used as a reinforcing filler, Preferably 50 m 2 /g or more is used. Within this range, the balance between reinforcing properties and dispersibility is good. In addition, suitable particle size is used depending on the application.
  • NSA BET nitrogen adsorption specific surface area
  • Carbon black there are N110, N220, N330, N339, N550, N660, etc. from the classification of carbon black for rubber according to ASTM, and it is selected according to the application. By using carbon black together, it is possible to improve the reinforcing property and improve the dry grip performance when used for tire tread applications.
  • Carbon black preferably has a BET nitrogen adsorption specific surface area (NSA) of less than 185 m 2 /g, preferably 30 m 2 /g or more, more preferably in the range of 50 to 130 m 2 /g. . Within this range, the balance between reinforcing properties and dispersibility is good.
  • NSA BET nitrogen adsorption specific surface area
  • reinforcing fillers can be used in addition to the silica described above.
  • Other reinforcing fillers are not particularly limited, but metal oxides as reinforcing fillers have the chemical formula MxOy (M represents a metal atom, and x and y each represent an integer of 1 to 6).
  • Solid particles are preferred as the main component of the composition.
  • the main component means a component that accounts for 50 mass % or more of the whole, preferably a component that accounts for 70 mass % or more, and more preferably a component that accounts for 90 mass % or more.
  • metal oxides that can be used include alumina, titanium oxide, magnesium oxide, and zinc oxide.
  • Metal hydroxides as reinforcing fillers include, for example, aluminum hydroxide, magnesium hydroxide, zirconium hydroxide and the like.
  • the metal oxides and metal hydroxides as other reinforcing fillers may be used singly or in combination of two or more. Mixtures with inorganic fillers other than these can also be used.
  • a silane coupling agent may be used in the resin composition of the present invention.
  • the silane coupling agent is not particularly limited, but is, for example, a compound having both a silica-affinity moiety and a polymer-affinity moiety in the molecule, such as sulfide-based compounds, mercapto-based compounds, vinyl-based compounds, amino-based compounds, Examples include glycidoxy-based compounds, nitro-based compounds, chloro-based compounds, and the like.
  • sulfide compounds include bis(3-triethoxysilylpropyl)tetrasulfide, bis(2-triethoxysilylethyl)tetrasulfide, bis(3-trimethoxysilylpropyl)tetrasulfide, bis(2-trimethoxy silylethyl) tetrasulfide, bis(3-triethoxysilylpropyl) trisulfide, bis(3-trimethoxysilylpropyl) trisulfide, bis(3-triethoxysilylpropyl) disulfide, bis(3-trimethoxysilylpropyl) Disulfide, 3-trimethoxysilylpropyl-N,N-dimethylthiocarbamoyl tetrasulfide, 3-triethoxysilylpropyl-N,N-dimethylthiocarbamoyl tetrasulfide, 2-
  • Mercapto-based compounds include, for example, 3-mercaptopropyltrimethoxysilane, 3-mercaptopropyltriethoxysilane, 2-mercaptoethyltrimethoxysilane, and 2-mercaptoethyltriethoxysilane.
  • vinyl compounds include vinyltriethoxysilane and vinyltrimethoxysilane.
  • amino compounds include 3-aminopropyltriethoxysilane, 3-aminopropyltrimethoxysilane, 3-(2-aminoethyl)aminopropyltriethoxysilane, 3-(2-aminoethyl)aminopropyltrimethoxysilane. silane and the like.
  • Examples of glycidoxy compounds include ⁇ -glycidoxypropyltriethoxysilane, ⁇ -glycidoxypropyltrimethoxysilane, ⁇ -glycidoxypropylmethyldiethoxysilane, ⁇ -glycidoxypropylmethyldimethoxysilane, and the like. mentioned. Nitro compounds include, for example, 3-nitropropyltrimethoxysilane and 3-nitropropyltriethoxysilane. Examples of chloro-based compounds include 3-chloropropyltrimethoxysilane, 3-chloropropyltriethoxysilane, 2-chloroethyltrimethoxysilane, and 2-chloroethyltriethoxysilane. Other compounds include, for example, octyltriethoxysilane, methyltriethoxysilane, methyltrimethoxysilane, hexadecyltrimethoxysilane, and the like.
  • silane coupling agents may be used singly or in combination of two or more.
  • silane coupling agents containing sulfur such as sulfide-based compounds and mercapto-based compounds are preferable from the viewpoint of a large reinforcing effect, and bis (3-triethoxysilylpropyl) disulfide, bis (3- Triethoxysilylpropyl)tetrasulfide, 3-mercaptopropyltrimethoxysilane are more preferred.
  • the amount of the silane coupling agent compounded is 1 to 20 parts by mass, preferably 2 to 15 parts by mass, per 100 parts by mass of silica. When the silane coupling agent is blended in this range, the dispersibility of silica is further improved, the processability is improved, and the performance of the vulcanized rubber is improved, such as improved abrasion resistance.
  • the plasticizer is not particularly limited, but for example, the same oils as the extender oils described above can be used, and in addition, various natural oils, synthetic oils, low-molecular-weight polymers, etc. can be used. Also, known processing aids can be used.
  • the resin composition of the present invention may be a resin composition further subjected to cross-linking treatment by adding a vulcanizing agent (cross-linking agent), a compounding agent, and the like.
  • a cross-linking agent is not particularly limited, but for example, sulfur-based vulcanizing agents, organic peroxides, and the like are used.
  • sulfur-based vulcanizing agent include, but are not limited to, sulfur, morpholine disulfide, etc.
  • Organic peroxides include, for example, benzoyl peroxide, dicumyl peroxide, di-t-butyl peroxide, t-Butylcumyl peroxide, cumene hydroperoxide and the like are used.
  • the amount of the vulcanizing agent used is not particularly limited, but is preferably 0.01 to 20 parts by mass, more preferably 0.1 to 15 parts by mass, relative to 100 parts by mass of the conjugated diene copolymer.
  • the vulcanization method conventionally known methods can be applied, and the vulcanization temperature is, for example, preferably 120°C to 200°C, more preferably 140°C to 180°C.
  • a vulcanization accelerator or vulcanization aid may be blended.
  • vulcanization accelerators include, but are not limited to, sulfenamides, thiazoles, thiurams, thioureas, and guanidine. system, dithiocarbamate, aldehyde-amine or aldehyde-ammonia, imidazoline, or xanthate vulcanization accelerators can be used.
  • a vulcanizing aid may be blended as necessary, and although the vulcanizing aid is not particularly limited, for example, zinc oxide, stearic acid, etc. can be used. Furthermore, anti-aging agents can be used.
  • the resin composition of the present invention can be produced by mixing the components described above.
  • the method of mixing is not particularly limited.
  • a melt-kneading method using a general kneader such as an open roll, Banbury mixer, kneader, single screw extruder, twin screw extruder, multi-screw extruder, etc. After dissolving and mixing each component, a solvent is added. A method of removing by heating and the like can be mentioned.
  • melt-kneading methods using rolls, Banbury mixers, kneaders, and extruders are preferred from the viewpoint of productivity and good kneading properties.
  • melt-kneading methods using rolls, Banbury mixers, kneaders, and extruders are preferred from the viewpoint of productivity and good kneading properties.
  • both a method of kneading the rubber component and various compounding agents at once and a method of kneading the mixture in multiple batches can be applied.
  • the degree of ability to concentrate the polymer on the surface of the filler can be represented by the amount of bound rubber (ability to generate bound rubber) of the modified conjugated diene-based polymer at 25°C.
  • the amount of bound rubber in the resin composition after kneading is preferably 15% by mass or more, more preferably 20% by mass or more.
  • the resin composition may be a vulcanized composition that has been vulcanized with a vulcanizing agent.
  • vulcanizing agents include radical generators such as organic peroxides and azo compounds, oxime compounds, nitroso compounds, polyamine compounds, sulfur, and sulfur compounds.
  • Sulfur compounds include sulfur monochloride, sulfur dichloride, disulfide compounds, polymeric polysulfur compounds, and the like.
  • a vulcanization accelerator may be used as necessary during vulcanization.
  • the vulcanization accelerator conventionally known materials can be used, for example, sulfenamide, guanidine, thiuram, aldehyde-amine, aldehyde-ammonia, thiazole, thiourea, dithiocarbamate. and other vulcanization accelerators.
  • Zinc white, stearic acid and the like can be used as the vulcanizing aid.
  • a rubber softener may be added to the resin composition of the present invention in order to improve workability.
  • Mineral oils, liquid or low molecular weight synthetic softeners are suitable as rubber softeners.
  • Mineral oil-based rubber softeners called process oils or extender oils, used to soften, expand, and improve the processability of rubber are mixtures of aromatic rings, naphthenic rings, and paraffinic chains, The number of carbon atoms in the paraffin chain accounts for 50% or more of the total carbon is called paraffinic, the number of naphthenic ring carbon atoms is 30 to 45% naphthenic, and the number of aromatic carbon atoms exceeds 30% is aromatic. called a system. Naphthene-based and/or paraffin-based softeners are preferable as the rubber softener used in the present embodiment.
  • the amount of the softener for rubber is not particularly limited, but it is preferably 10 to 80 parts by mass, more preferably 20 to 50 parts by mass, based on 100 parts by mass of the conjugated diene copolymer.
  • the resin composition of the present invention may contain softening agents and fillers other than those mentioned above, as well as heat stabilizers, antistatic agents, weather stabilizers, anti-aging agents, and coloring agents, as long as they do not impair the purpose of the present embodiment.
  • Various additives such as agents and lubricants may be used.
  • Specific examples of fillers include calcium carbonate, magnesium carbonate, aluminum sulfate, barium sulfate, and the like.
  • softening agents that are optionally blended in order to adjust the hardness and fluidity of the desired product include liquid paraffin, castor oil, linseed oil, and the like.
  • Known materials can be applied as the heat stabilizer, antistatic agent, weather stabilizer, anti-aging agent, colorant, and lubricant.
  • the cross-linked resin product of the present invention is obtained by cross-linking the resin composition.
  • a tire is manufactured by extruding a resin composition according to the shape of the tire (for example, the shape of the tread), molding it, and heating and pressurizing it in a vulcanizer to produce a tread. By assembling the parts, the desired tire can be manufactured.
  • the resin composition of the present invention is excellent in mechanical strength and abrasion resistance when made into a resin crosslinked product. Therefore, as described above, it can be suitably applied to treads of tires such as fuel-efficient tires, large tires, and high-performance tires, and structural members such as sidewall members. In addition to structural members, it can also be suitably used for rubber belts, rubber hoses, materials for footwear, and the like.
  • the area (%) of the multi-branched component is in the molecular weight range of not less than twice the peak top molecular weight Mp of the uncoupled unbranched diene copolymer (2 Mp). Area % is indicated. Furthermore, the area (%) of 3 Mp or more indicates the area % of the molecular weight range of 3 times the peak top molecular weight Mp of the uncoupled unbranched diene copolymer (3 Mp) or more.
  • the weight of the polymer on the filter is calculated, and when the dry weight of the polymer is less than 0.025 g, ⁇ , 0.025 g or more and less than 0.25 g, ⁇ , and 0.25 g or more. x.
  • TGA Weight reduction
  • Haze A sample obtained by dissolving 0.5 g of copolymer rubber in 100 g of toluene is placed in a quartz cell, and its haze (turbidity) is measured using an integrating sphere type light transmittance measuring device (manufactured by Nippon Denshoku Co., Ltd., manufactured by Nippon Denshoku Co., Ltd.). SZ- ⁇ 90) was used to measure the Haze value.
  • Amount of bound rubber 0.4 g of unvulcanized rubber after kneading was cut into 2 mm squares, placed in a sample tube together with 50 mL of toluene, and allowed to stand at room temperature for 48 hours. Thereafter, extraction was performed using a glass filter, and the toluene solution portion and the rubber portion were dried. Then, the weight of the rubber portion on the filter was calculated and used as the amount of bound rubber. Further, the dried toluene solution portion was dissolved in chloroform, and the ratio of polybutadiene was calculated by proton NMR. The amount of bound rubber in Comparative Example 3 was set to 100 and indicated as an index.
  • Raw materials used in Examples and their abbreviations are as follows.
  • DVB-630 mixture of divinylbenzene component and ethylvinylbenzene component; divinylbenzene component content 63.0 wt%, manufactured by Nippon Steel Chemical & Material) BHT; 2,6-di-tert-butyl-p-cresol BTESPA; bis(3-trimethoxysilylpropyl)methylamine
  • Example 1 Synthesis of Modified Vinyl Aromatic Copolymer (A-1) 120 ml (93.5 g) of ethylcyclohexane and 0.77 ml (4.0 mmol) of 2,2-di(2-tetrahydrofuryl)propane were charged.
  • TESPTADSP 1-(3-triethoxysilylpropyl)-2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopentane
  • the resulting modified vinyl aromatic copolymer A-1 had Mn of 2650, Mw of 5560 and Mw/Mn of 2.10.
  • GC analysis, 13 C-NMR and 1 H-NMR analysis revealed that the modified vinyl aromatic copolymer A-1 contained 4.55 mol% (4.94 wt%) of structural units derived from divinylbenzene. , 2.84 mol% (3.09 wt%) of structural units derived from ethylvinylbenzene, 56.25 mol% (48.88 wt%) of structural units derived from styrene, and 27.27 mol% (48.88 wt%) of structural units derived from isoprene.
  • mol % (15.50 wt%) and derived from 1-(3-triethoxysilylpropyl)-2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopentane (TESPTADSP) It was confirmed that 9.09 mol % (27.59 wt %) of the structural unit that was used for the modified vinyl aromatic copolymer was contained, and that 2.01 modifiers were introduced per molecule of the modified vinyl aromatic copolymer. Since the crosslinked structural unit (a1) derived from the divinyl aromatic compound represented by the formula (1) is 4.36 mol% (4.74 wt%), the degree of crosslinking (a1/a) is 0.96. Met.
  • the structural unit (a2) derived from divinylbenzene having a residual vinyl group contained in the modified vinyl aromatic copolymer (A-1) is 0.18 mol% (0.20 wt%)
  • the molar fraction of the vinyl group-containing structural unit (a2) with respect to the sum of the structural units (a) and (b) was 0.002.
  • About 100 mol % of structural units derived from TESPTADSP were bound to structural units derived from isoprene.
  • TGA 350 weight loss at 350° C. was 0.72 wt %.
  • a sample obtained by dissolving 0.5 g of the modified vinyl aromatic copolymer (A-1) in 100 g of toluene was placed in a quartz cell, and the haze (turbidity) was measured using toluene as a standard sample, and the integrating sphere type light transmittance was measured.
  • the haze value measured using the measuring device was 0.02.
  • the obtained copolymer B-1 had Mn of 624, Mw of 2360 and Mw/Mn of 3.79, and was a random copolymer.
  • resonance lines of end groups having anisole-derived benzene rings bonded to the ends of the main chain were observed in the NMR chart of copolymer B-1.
  • the introduction amount of structural units derived from anisole in the soluble polyfunctional vinyl aromatic polymer calculated from the results of elemental analysis and the number average molecular weight in terms of standard polystyrene was 1.6 (pieces/molecule).
  • copolymer B-1 was soluble in toluene, xylene, THF, dichloroethane, dichloromethane and chloroform, and gel formation was not observed.
  • Comparative Example 2 Synthesis of polysiloxane-modified crosslinked polymer particles (C-1) Divinylbenzene (purity 56%, remaining 38% ethyl vinylbenzene, remaining 6% impurities, hereinafter this divinylbenzene is used) 45 parts, styrene 55 parts of sodium dodecylbenzenesulfonate, 3 parts of sodium dodecylbenzenesulfonate, 0.5 parts of polyvinyl alcohol, 1000 parts of ion-exchanged water and 0.7 parts of ⁇ , ⁇ '-azoisobutyronitrile were charged into a reaction vessel and mixed with a homomixer at 15,000 rpm. for 60 minutes to homogenize.
  • C-1 Divinylbenzene (purity 56%, remaining 38% ethyl vinylbenzene, remaining 6% impurities, hereinafter this divinylbenzene is used) 45 parts, styrene 55 parts of sodium dodecyl
  • the mixture was heated to 80° C. while nitrogen gas was blown thereinto, and the mixture was continuously stirred for 3 hours for suspension polymerization to obtain polymer particles (C-0).
  • the pH was adjusted to 8.0, 30 parts of methyltriethoxysilane (MTES) was added, and the mixture was vigorously stirred for about 30 minutes.
  • MTES methyltriethoxysilane
  • the temperature of the reaction vessel was raised to 70° C., and the reaction was carried out for 3 hours to complete the condensation reaction and produce crosslinked polymer particles C-1. No coagulum formation was observed in this dispersion.
  • the average particle size of the resulting crosslinked polymer particles a was measured and found to be 1.9 ⁇ m.
  • the resulting aqueous slurry of crosslinked polymer particles was washed by centrifugation and then subjected to elemental analysis by ESCA, whereupon the presence of Si element was observed.
  • the obtained modified vinyl aromatic copolymer D-1 had Mn of 1960, Mw of 5150 and Mw/Mn of 2.63.
  • GC analysis, 13 C-NMR and 1 H-NMR analysis revealed that the modified vinyl aromatic copolymer D-1 contained 6.31 mol% (7.37 wt%) of structural units derived from divinylbenzene. , 3.94 mol% (4.61 wt%) of structural units derived from ethylvinylbenzene, 6.14 mol% (5.75 wt%) of structural units derived from styrene, and 71.88 mol% (5.75 wt%) of structural units derived from isoprene.
  • the structural unit (a2) derived from divinylbenzene having a residual vinyl group contained in the modified vinyl aromatic copolymer (D-1) is 0.32 mol% (0.37 wt%)
  • the structural units (a) and (b) the molar fraction of the vinyl group-containing structural unit (a2) was 0.004.
  • 92.9 mol % of structural units derived from TESPTADSP were bound to structural units derived from isoprene.
  • TGA350 thermogravimetry
  • GPTES 3-glycidoxypropyltriethoxysilane
  • GPTES 3-glycidoxypropyltriethoxysilane
  • succinic acid was added and stirred, followed by filtration.
  • GPTES is a modifier that generates a hydroxyl group by reacting an alkoxysilyl group as well as a glycidyl group with a carbanion which is an active species.
  • the obtained modified vinyl aromatic copolymer E-1 had Mn of 2750, Mw of 7480 and Mw/Mn of 2.72.
  • GC analysis, 13 C-NMR and 1 H-NMR analysis revealed that the modified vinyl aromatic copolymer E-1 contained 4.56 mol% (5.28 wt%) of structural units derived from divinylbenzene. , 2.83 mol% (3.30 wt%) of structural units derived from ethylvinylbenzene, 56.23 mol% (52.26 wt%) of structural units derived from styrene, and 27.26 mol% (52.26 wt%) of structural units derived from isoprene.
  • the structural unit (a2) derived from divinylbenzene having a residual vinyl group contained in the modified vinyl aromatic copolymer (E-1) is 0.14 mol% (0.16 wt%)
  • the structural units (a) and (b) the molar fraction of the vinyl group-containing structural unit (a2) was 0.002.
  • About 100 mol % of structural units derived from GPTES were bound to structural units derived from isoprene.
  • TGA350 thermogravimetry
  • a sample obtained by dissolving 0.5 g of the modified vinyl aromatic copolymer (E-1) in 100 g of toluene is placed in a quartz cell, and its haze (turbidity) is measured using toluene as a reference sample, and the integrating sphere type light transmittance is measured.
  • the haze value measured using the measuring device was 0.04.
  • the obtained polyfunctional vinyl aromatic copolymer (F-1) had Mn of 1040, Mw of 3310 and Mw/Mn of 3.19. 13 C-NMR and 1 H-NMR analysis revealed that the polyfunctional vinyl aromatic copolymer (F-1) contained 45.2 mol% (48.4 wt%) of structural units derived from divinylbenzene. It contained 7.7 mol % (8.3 wt %) of structural units derived from ethylvinylbenzene and 47.0 mol % (43.3 wt %) of structural units derived from diisobutylene.
  • the degree of crosslinking (a1/a) is 0.43. Met.
  • the divinylbenzene-derived structural unit (a2) having a residual vinyl group contained in the polyfunctional vinyl aromatic copolymer (F-1) is 25.8 mol% (27.6 wt%).
  • the structural unit derived from divinylbenzene, the structural unit derived from ethylvinylbenzene, and the structural unit derived from diisobutylene As a result of TMA measurement of the cured product, Tg was 188°C and the softening temperature was 280°C or higher.
  • thermogravimetry TGA
  • TGA350 weight loss at 350°C
  • Example 4 Synthesis of Modified Vinyl Aromatic Copolymer (G-1) 160 ml (124.6 g) of ethylcyclohexane and 0.61 ml (4.0 mmol) of N,N,N',N'-tetramethylethylenediamine were charged. At 50 ° C., 12.5 ml of n-hexane solution containing 1.28 g (20.0 mmol) of n-butyllithium as a pure content was added, and then the polyfunctional vinyl synthesized in Synthesis Example 1 was dried in advance.
  • G-1 Modified Vinyl Aromatic Copolymer
  • a solution prepared by dissolving 4.66 g of the aromatic copolymer (F-1) in 40 ml (31.2 g) of ethylcyclohexane was added to initiate the synthesis of the polyfunctional initiator in the first step.
  • a solution obtained by dissolving 16.36 g (80.0 mmol) of isoprene as a monomer in 40 ml (31.2 g) of ethylcyclohexane was added to the reactor to initiate the second-stage polymerization.
  • a small amount of the polymerization solution was sampled and subjected to GC analysis.
  • the resulting modified vinyl aromatic copolymer G-1 had Mn of 3350, Mw of 12200 and Mw/Mn of 3.64.
  • GC analysis, 13 C-NMR and 1 H-NMR analysis revealed that the modified vinyl aromatic copolymer G-1 contained 12.76 mol% (13.70 wt%) of structural units derived from divinylbenzene. , 2.18 mol % (2.34 wt %) of structural units derived from ethylvinylbenzene, 13.26 mol % (12.27 wt %) of structural units derived from diisobutylene, and 58 mol % (12.27 wt %) of structural units derived from isoprene.
  • the structural unit (a2) derived from divinylbenzene having a residual vinyl group contained in the modified vinyl aromatic copolymer (G-1) is 0.38 mol% (0.41 wt%)
  • the molar fraction of the vinyl group-containing structural unit (a2) with respect to the sum of the structural units (a) and (b) was 0.025.
  • About 100 mol % of structural units derived from TESPTADSP were bound to structural units derived from isoprene.
  • TGA350 thermogravimetry
  • a sample obtained by dissolving 0.5 g of the modified vinyl aromatic copolymer (G-1) in 100 g of toluene is placed in a quartz cell, and its Haze (turbidity) is measured using toluene as a reference sample, and integrating sphere type light transmittance.
  • the haze value measured using the measuring device was 0.03.
  • the polymerization conversion rate was approximately 100%.
  • GPC analysis revealed that the copolymer had an Mn of 2,910, an Mw of 6,630, and an Mw/Mn of 2.28 at the end of the second-stage polymerization. Comparing the GPC elution curve of the sample that completed the first stage polymerization with the elution curve of the sample that completed the second stage polymerization, the GPC elution curves maintained approximately the same molecular weight distribution with the addition of the additional monomer isoprene.
  • the resulting modified vinyl aromatic copolymer H-1 had Mn of 3470, Mw of 9260 and Mw/Mn of 2.67.
  • GC analysis, 13 C-NMR and 1 H-NMR analysis revealed that the modified vinyl aromatic copolymer H-1 contained 3.53 mol% (4.68 wt%) of structural units derived from divinylbenzene. , 2.21 mol% (2.93 wt%) of structural units derived from ethylvinylbenzene, 40.88 mol% (43.35 wt%) of structural units derived from styrene, and 46.62 mol% (43.35 wt%) of structural units derived from isoprene.
  • the structural unit (a2) derived from divinylbenzene having a residual vinyl group contained in the modified vinyl aromatic copolymer (H-1) is 0.14 mol% (0.19 wt%)
  • the structural units (a) and (b) the molar fraction of the vinyl group-containing structural unit (a2) was 0.0015.
  • About 100 mol % of structural units derived from GPTES were bound to structural units derived from isoprene.
  • TGA 350 the weight loss at 350° C.
  • a sample obtained by dissolving 0.5 g of the modified vinyl aromatic copolymer (H-1) in 100 g of toluene was placed in a quartz cell, and the haze (turbidity) was measured using toluene as a reference sample, and the integrating sphere type light transmittance was measured.
  • the haze value measured using the measuring device was 0.04.
  • LDIPA lithium diisopropylamide
  • DVB-630 divinylbenzene (mixture of m- and p-forms) component 10.6 mmol, ethylvinylbenzene (m- A mixture of (6.63 mmol) of a mixture of isomer and p-isomer) and 12.79 g (122.8 mmol) of styrene was added to initiate the first-stage polymerization.
  • the temperature of the reaction solution rose due to the heat of polymerization, reaching a maximum temperature of 77°C.
  • a small amount of the polymerization solution was sampled and analyzed by gas chromatography (GC). No unreacted monomer was observed, and it was confirmed that the polymerization conversion rate was approximately 100%. Further, GPC analysis revealed that Mn of the copolymer at the end of the first-stage polymerization was 2010, Mw was 3780, and Mw/Mn was 1.98.
  • the second stage polymerization was initiated by adding 9.54 g (140.0 mmol) of isoprene as an additional monomer to the reactor.
  • the obtained modified vinyl aromatic copolymer I-1 had Mn of 3630, Mw of 10090 and Mw/Mn of 2.78.
  • GC analysis, 13 C-NMR and 1 H-NMR analysis revealed that the modified vinyl aromatic copolymer I-1 contained 3.31 mol% (4.38 wt%) of structural units derived from divinylbenzene. , 2.07 mol% (2.74 wt%) of structural units derived from ethylvinylbenzene, 40.59 mol% (38.33 wt%) of structural units derived from styrene, and 43.71 mol% (38.33 wt%) of structural units derived from isoprene.
  • the structural unit (a2) derived from divinylbenzene having a residual vinyl group contained in the modified vinyl aromatic copolymer (I-1) is 0.10 mol% (0.13 wt%)
  • the structural units (a) and (b) the molar fraction of the vinyl group-containing structural unit (a2) was 0.0011.
  • About 100 mol % of structural units derived from GPTES were bound to structural units derived from isoprene.
  • TGA 350 the weight loss at 350° C.
  • a sample obtained by dissolving 0.5 g of the modified vinyl aromatic copolymer (I-1) in 100 g of toluene was placed in a quartz cell, and the haze (turbidity) was measured using toluene as a reference sample, and the integrating sphere type light transmittance was measured.
  • the Haze value measured using a measuring device was 0.05.
  • Example 7 Synthesis of modified conjugated diene-based copolymer (A-2) 580 g of cyclohexane and 30.7 mg (0.16 mmol) of 2,2-di(2-tetrahydrofuryl)propane were placed in a nitrogen-purged autoclave reactor. 5 g of a cyclohexane solution containing 51.2 mg (0.80 mmol) of n-butyllithium as a pure content was added at 50 ° C., and then 34.29 g of styrene from which impurities had been removed in advance. , 3-butadiene was added to initiate the polymerization.
  • A-2 modified conjugated diene-based copolymer
  • the temperature of the reaction solution rose due to the heat of polymerization, reaching a maximum temperature of 78°C.
  • 15 g of a cyclohexane solution containing 0.527 g of the modified vinyl aromatic copolymer (A-1) obtained in Example 1 as an SBR modifier for modifying the obtained styrene-butadiene rubber (SBR). was added to carry out a modification reaction.
  • a modification reaction was performed at a temperature of 60° C. for 30 minutes to obtain a polymer solution.
  • 0.40 mmol of bis(3-trimethoxysilylpropyl)methylamine was added and modified reaction was performed for 30 minutes to obtain a modified conjugated diene copolymer-containing polymer solution.
  • the temperature of the reaction solution rose due to the heat of polymerization, reaching a maximum temperature of 79°C.
  • 15 g of a cyclohexane solution containing 0.379 g of the modified vinyl aromatic copolymer (B-1) obtained in Comparative Example 1 as an SBR modifier was added to carry out a modification reaction.
  • a modification reaction was carried out for 30 minutes under temperature conditions to obtain a polymer solution.
  • 0.40 mmol of bis(3-trimethoxysilylpropyl)methylamine was added and modified reaction was performed for 30 minutes to obtain a modified conjugated diene copolymer-containing polymer solution.
  • the temperature of the reaction solution rose due to the heat of polymerization, reaching a maximum temperature of 79°C.
  • 15 g of a cyclohexane solution containing 0.466 g of the modified vinyl aromatic copolymer (C-1) obtained in Comparative Example 2 as an SBR modifier was added to carry out a modification reaction.
  • a modification reaction was carried out for 30 minutes under temperature conditions to obtain a polymer solution.
  • 0.40 mmol of bis(3-trimethoxysilylpropyl)methylamine was added and modified reaction was performed for 30 minutes to obtain a modified conjugated diene copolymer-containing polymer solution.
  • Example 8 Synthesis of modified conjugated diene-based copolymer (D-2) 580 g of cyclohexane and 30.7 mg (0.16 mmol) of 2,2-di(2-tetrahydrofuryl)propane were placed in a nitrogen-purged autoclave reactor. 5 g of a cyclohexane solution containing 51.2 mg (0.80 mmol) of n-butyllithium as a pure content was added at 50 ° C., and then 34.29 g of styrene from which impurities had been removed in advance. , 3-butadiene was added to initiate the polymerization.
  • D-2 modified conjugated diene-based copolymer
  • the temperature of the reaction solution rose due to the heat of polymerization, reaching a maximum temperature of 81°C.
  • 15 g of a cyclohexane solution containing 0.363 g of the modified vinyl aromatic copolymer (D-1) obtained in Example 2 as an SBR modifier for modifying the obtained styrene-butadiene rubber (SBR). was added to carry out a modification reaction.
  • a modification reaction was performed at a temperature of 60° C. for 30 minutes to obtain a polymer solution.
  • 0.40 mmol of bis(3-trimethoxysilylpropyl)methylamine was added and modified reaction was performed for 30 minutes to obtain a modified conjugated diene copolymer-containing polymer solution.
  • Example 9 Synthesis of modified conjugated diene-based copolymer (E-2) 580 g of cyclohexane and 30.7 mg (0.16 mmol) of 2,2-di(2-tetrahydrofuryl)propane were placed in a nitrogen-purged autoclave reactor. 5 g of a cyclohexane solution containing 51.2 mg (0.80 mmol) of n-butyllithium as a pure content was added at 50 ° C., and then 34.29 g of styrene from which impurities had been removed in advance. , 3-butadiene was added to initiate the polymerization.
  • E-2 modified conjugated diene-based copolymer
  • the temperature of the reaction solution rose due to the heat of polymerization, reaching a maximum temperature of 81°C.
  • 15 g of a cyclohexane solution containing 0.493 g of the modified vinyl aromatic copolymer (E-1) obtained in Example 3 as an SBR modifier for modifying the obtained styrene-butadiene rubber (SBR). was added to carry out a modification reaction.
  • a modification reaction was performed at a temperature of 60° C. for 30 minutes to obtain a polymer solution.
  • 0.40 mmol of bis(3-trimethoxysilylpropyl)methylamine was added and modified reaction was performed for 30 minutes to obtain a modified conjugated diene copolymer-containing polymer solution.
  • Example 10 Synthesis of modified conjugated diene-based copolymer (G-2) 580 g of cyclohexane and 30.7 mg (0.16 mmol) of 2,2-di(2-tetrahydrofuryl)propane were placed in a nitrogen-purged autoclave reactor. 5 g of a cyclohexane solution containing 51.2 mg (0.80 mmol) of n-butyllithium as a pure content was added at 50 ° C., and then 34.29 g of styrene from which impurities had been removed in advance. , 3-butadiene was added to initiate the polymerization.
  • G-2 modified conjugated diene-based copolymer
  • the temperature of the reaction solution rose due to the heat of polymerization, reaching a maximum temperature of 81°C.
  • 15 g of a cyclohexane solution containing 0.348 g of the modified vinyl aromatic copolymer (G-1) obtained in Example 4 as an SBR modifier for modifying the obtained styrene-butadiene rubber (SBR). was added to carry out a modification reaction.
  • a modification reaction was performed at a temperature of 60° C. for 30 minutes to obtain a polymer solution.
  • 0.40 mmol of bis(3-trimethoxysilylpropyl)methylamine was added and modified reaction was performed for 30 minutes to obtain a modified conjugated diene copolymer-containing polymer solution.
  • Example 11 Synthesis of modified conjugated diene-based copolymer (H-2) 580 g of cyclohexane and 30.7 mg (0.16 mmol) of 2,2-di(2-tetrahydrofuryl)propane were placed in a nitrogen-purged autoclave reactor. 5 g of a cyclohexane solution containing 51.2 mg (0.80 mmol) of n-butyllithium as a pure content was added at 50 ° C., and then 34.29 g of styrene from which impurities had been removed in advance. , 3-butadiene was added to initiate the polymerization.
  • H-2 modified conjugated diene-based copolymer
  • the temperature of the reaction solution rose due to the heat of polymerization, reaching a maximum temperature of 81°C.
  • 15 g of a cyclohexane solution containing 0.596 g of the modified vinyl aromatic copolymer (H-1) obtained in Example 5 as an SBR modifier for modifying the obtained styrene-butadiene rubber (SBR). was added to carry out a modification reaction.
  • a modification reaction was performed at a temperature of 60° C. for 30 minutes to obtain a polymer solution.
  • 0.40 mmol of bis(3-trimethoxysilylpropyl)methylamine was added and modified reaction was performed for 30 minutes to obtain a modified conjugated diene copolymer-containing polymer solution.
  • Example 12 The modified conjugated diene-based copolymer (modified SBR) A-2 obtained in Example 7, process oil, carbon black, zinc oxide, stearic acid and an anti-aging agent were blended and heated at 155° C. using a Laboplastomill. Mixed for 4 minutes at 60 rpm. Sulfur and a vulcanization accelerator were added to the resulting kneaded product, and the mixture was kneaded at 70° C. and 60 rpm for 1 minute using a Laboplastomill and vulcanized to obtain a crosslinked rubber A-3.
  • Table 6 shows the blending ratio of each additive
  • Table 7 shows the physical properties of the obtained crosslinked rubber.
  • the additives used are as follows.
  • Zinc oxide Zinc oxide type 2 manufactured by Sakai Chemical Stearic acid: Anti-aging agent manufactured by Fujifilm Wako Pure Chemical Industries: Nocrac 6C manufactured by Ouchi Shinko Kagaku Kogyo Sulfur: Powdered sulfur manufactured by Tsurumi Chemical Industry JIS Class 2 vulcanization accelerator A: Noxcellar CZ-G manufactured by Ouchi Shinko Chemical Industry Vulcanization accelerator B: Noxcellar DP manufactured by Ouchi Shinko Chemical Industry Co., Ltd.
  • Examples 13 and 14, Comparative Examples 5 and 6 instead of the modified conjugated diene copolymer (modified SBR) A-2, the modified conjugated diene copolymer (modified SBR) B- synthesized in Example 8, Example 10, or Comparative Example 3, Comparative Example 4 Crosslinked rubbers B-3, C-3, D-3, and G-3 were obtained in the same manner as in Example 12, except that 2, C-2, D-2, and G-2 were used. Table 7 shows the physical properties of the obtained crosslinked rubber.
  • the crosslinked rubber using the modified conjugated diene copolymer (modified SBR) of the example is superior to the comparative example in terms of the round rubber index, resulting in the dispersibility of the inorganic filler and It can be seen that the loss during running is improved, the tensile strength and wear resistance are excellent, and it is a material that can contribute to both strength and wear resistance.
  • the modified vinyl aromatic copolymer of the present invention is particularly useful as a modifier for conjugated diene copolymers (such as SBR).
  • conjugated diene copolymers such as SBR
  • the resulting modified conjugated diene copolymer (modified SBR, etc.) containing a filler and crosslinked has excellent filler dispersibility, mechanical strength, and wear resistance. , seismic isolation rubber, rubber hoses, rubber rollers, footwear materials, etc.
  • the modified vinyl aromatic copolymer of the present invention is used in fields such as the electrical/electronics industry, space/aircraft industry, building/construction industry, etc., for dielectric materials, insulating materials, heat-resistant materials, structural materials, and adhesives for low-dielectric substrates.
  • the curable resin composition can be processed into films, sheets, and prepregs, and can be used for plastic optical parts, touch panels, flat displays, film liquid crystal elements, and various optical elements such as optical waveguides and optical lenses. be. It can also be used as a modifier for modifying properties such as heat resistance, dielectric properties, adhesion/adherence, and optical properties of thermoplastic resins or curable resin compositions.

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Abstract

L'invention concerne : un copolymère aromatique vinylique modifié ayant une réactivité et une solubilité qui rendent le copolymère utilisable dans la production de caoutchoucs copolymères; et un matériau de caoutchouc copolymère qui est obtenu à partir du copolymère aromatique vinylique modifié et présente une aptitude au traitement, une résistance et une homogénéité.　Ce copolymère aromatique vinylique modifié est caractérisé en ce qu'il contient des unités structurales (a) dérivées d'un composé aromatique divinylique, des unités structurales (b) dérivées d'un composé aromatique monovinylique, et des unités structurales (c) dérivé d'un composé diène conjugué, et caractérisé en ce que 95 % en moles ou plus des unités structurales (a) sont des unités structurales réticulées (a1) représentées par la formule (1), en ce que le copolymère est modifié par au moins un type de groupe fonctionnel sélectionné dans le groupe constitué par un groupe amino, un groupe alcoxysilyle et un groupe hydroxyle, 30 % en moles ou plus des groupes fonctionnels se liant à l'unité structurelle (c) dérivée d'un composé diène conjugué, et en ce que le poids moléculaire moyen en nombre Mn du copolymère est de 500 à 30 000.　
PCT/JP2022/044472 2021-12-03 2022-12-01 Copolymère aromatique vinylique modifié, procédé de production associé, copolymère de diène conjugué modifié obtenu à partir de celui-ci, composition de résine, résine réticulée et élément structural WO2023100993A1 (fr)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003029299A1 (fr) * 2001-09-27 2003-04-10 Jsr Corporation Caoutchouc (co)polymere diolefinique conjugue, procede de production de caoutchouc (co)polymere, composition de caoutchouc, composite et pneu
JP2013155268A (ja) * 2012-01-30 2013-08-15 Jsr Corp 共役ジエン系ゴムおよびその製造方法、ゴム組成物、ゴム弾性体並びにタイヤ
WO2020067336A1 (fr) * 2018-09-28 2020-04-02 日鉄ケミカル＆マテリアル株式会社 Copolymère aromatique polyfonctionnel de vinyle et son procédé de fabrication, caoutchouc copolymère obtenu à partir de celui-ci, composition de caoutchouc, matériau réticulé de caoutchouc, et élément de pneumatique
WO2020262371A1 (fr) * 2019-06-25 2020-12-30 日鉄ケミカル＆マテリアル株式会社 Copolymère vinylaromatique modifié, son procédé de production, copolymère de diène conjugué modifié obtenu à partir de celui-ci et sa composition, objet en caoutchouc réticulé et élément de pneu

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003029299A1 (fr) * 2001-09-27 2003-04-10 Jsr Corporation Caoutchouc (co)polymere diolefinique conjugue, procede de production de caoutchouc (co)polymere, composition de caoutchouc, composite et pneu
JP2013155268A (ja) * 2012-01-30 2013-08-15 Jsr Corp 共役ジエン系ゴムおよびその製造方法、ゴム組成物、ゴム弾性体並びにタイヤ
WO2020067336A1 (fr) * 2018-09-28 2020-04-02 日鉄ケミカル＆マテリアル株式会社 Copolymère aromatique polyfonctionnel de vinyle et son procédé de fabrication, caoutchouc copolymère obtenu à partir de celui-ci, composition de caoutchouc, matériau réticulé de caoutchouc, et élément de pneumatique
WO2020262371A1 (fr) * 2019-06-25 2020-12-30 日鉄ケミカル＆マテリアル株式会社 Copolymère vinylaromatique modifié, son procédé de production, copolymère de diène conjugué modifié obtenu à partir de celui-ci et sa composition, objet en caoutchouc réticulé et élément de pneu

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