WO2023092811A1 - Double patterning method and semiconductor structure - Google Patents

Double patterning method and semiconductor structure Download PDF

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WO2023092811A1
WO2023092811A1 PCT/CN2021/143024 CN2021143024W WO2023092811A1 WO 2023092811 A1 WO2023092811 A1 WO 2023092811A1 CN 2021143024 W CN2021143024 W CN 2021143024W WO 2023092811 A1 WO2023092811 A1 WO 2023092811A1
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layer
mask layer
groove
mask
shielding
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French (fr)
Chinese (zh)
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陈海华
侯永强
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上海集成电路研发中心有限公司
上海集成电路装备材料产业创新中心有限公司
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/027Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
    • H01L21/033Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers
    • H01L21/0334Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane
    • H01L21/0337Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane characterised by the process involved to create the mask, e.g. lift-off masks, sidewalls, or to modify the mask, e.g. pre-treatment, post-treatment
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/027Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
    • H01L21/033Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers
    • H01L21/0332Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their composition, e.g. multilayer masks, materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/027Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
    • H01L21/033Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers
    • H01L21/0334Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane
    • H01L21/0338Process specially adapted to improve the resolution of the mask
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

In the double patterning method of the present invention, a layer to be etched, a first mask layer and a second mask layer which are sequentially stacked from bottom to top are provided, wherein the layer to be etched comprises an interconnection region and a peripheral non-interconnection region, the interconnection region comprises first regions and second regions which are alternately arranged in a first axial direction, some of the second regions comprise second parts, and the second parts protrude out of the boundaries of adjacent first regions in a second axial direction; several shielding layer grooves are formed in the second mask layer on the non-interconnection region, wherein the shielding layer grooves are arranged in the first axial direction, and some of the shielding layer grooves are distributed on the side edges of the second parts; the shielding layer grooves are filled to form shielding layers; a photoresist layer is formed on the second mask layer, wherein the photoresist layer is provided with etching openings corresponding to the second regions and auxiliary openings corresponding to the shielding layers. In a photolithography process, a manufacturing process window for the etching openings corresponding to the second parts is increased. The semiconductor structure of the present invention is manufactured by means of the patterning method.

Description

双重构图的图形化方法和半导体结构Patterning method and semiconductor structure of double patterning
交叉引用cross reference
[根据细则91更正 14.01.2022] 
本发明要求2021年11月24日提交的申请号为202111407232.5的中国专利申请的优先权。上述申请的内容以引用方式被包含于此。
[Corrected 14.01.2022 under Rule 91]
The present invention claims the priority of the Chinese patent application with application number 202111407232.5 filed on November 24, 2021. The content of the above application is incorporated herein by reference.
技术领域technical field
本发明涉及半导体技术领域,特别涉及一种双重构图的图形化方法和半导体结构。The invention relates to the technical field of semiconductors, in particular to a double-patterning patterning method and a semiconductor structure.
技术背景technical background
在10nm及以下节点,图形复杂度增加带来的工艺薄弱点(Weak point)越来越多;通常采用双重构图技术(Double Patterning,DP)以克服上述工艺薄弱点。图1至图3为不同的半导体结构的平面示意图。参考图1至图3,图1中的孤立凹槽图形(isolated line)端点、图2中的头对头图形(head to head)和图3中的多线条桥结构(bridge)等通过光刻工艺和刻蚀工艺直接形成,光刻工艺中,工艺薄弱点图形直接形成图形化缺陷,导致半导体器件的性能较差。At the node of 10nm and below, there are more and more process weaknesses (Weak points) brought about by the increase of graphics complexity; double patterning technology (Double Patterning, DP) is usually used to overcome the above process weaknesses. 1 to 3 are schematic plan views of different semiconductor structures. Referring to Figures 1 to 3, the isolated groove pattern (isolated line) endpoint in Figure 1, the head-to-head pattern (head to head) in Figure 2, and the multi-line bridge structure (bridge) in Figure 3 are passed through the photolithography process It is formed directly with the etching process. In the photolithography process, the weak point pattern of the process directly forms a patterned defect, resulting in poor performance of the semiconductor device.
发明概要Summary of the invention
本发明提供一种双重构图的图形化方法和半导体结构,可以增大孤立区图形制作的工艺窗口,提高半导体器件的性能。The invention provides a double-patterning patterning method and a semiconductor structure, which can increase the process window for making isolated region patterns and improve the performance of semiconductor devices.
为了实现上述目的,本发明一方面提供一种双重构图的图形化方法,包括:提供自下而上依次叠加的待刻蚀层、第一掩膜层和第二掩膜层;所述待刻蚀层包括互联区和非互联区,所示非互联区位于互联区外围,所述互联区包括沿第一轴向交替排布的若干第一区和若干第二区,所述第一区和所述第 二区均沿第二轴向延长,所示第二轴向垂直于所述第一轴向;所述第二区均包括第一部分,所述第一部分与相邻的所述第一区邻接;部分所述第二区包括第二部分,同一所述第二区对应的第一部分和第二部分沿所述第二轴向排布,且所述第二部分凸出于相邻的所述第一区的边界;刻蚀所述第二掩膜层并停止在所述第一掩膜层的上表面,在所述非互联区上的所述第二掩膜层中形成沿所述第一轴向排布的若干遮挡层凹槽;所述遮挡层凹槽均沿所述第二轴向延长,并分布在所述第二部分的侧边,且和所述第二部分在所述第二轴向的投影至少部分交叠;填充所述遮挡层凹槽形成若干遮挡层;在所述第二掩膜层上形成光刻胶层,所述光刻胶层具有与所述第二区对应的刻蚀开口、及与所述遮挡层对应的辅助开口;以及以所述光刻胶层和所述遮挡层为掩膜,刻蚀所述第二掩膜层形成若干第二凹槽,第二凹槽对应所述第二区,并底部露出所述第一掩膜层的上表面。In order to achieve the above object, the present invention provides a double-patterning patterning method on the one hand, comprising: providing a layer to be etched, a first mask layer and a second mask layer stacked sequentially from bottom to top; The etch layer includes an interconnected area and a non-interconnected area. The non-interconnected area is located on the periphery of the interconnected area. The interconnected area includes several first areas and several second areas alternately arranged along the first axis. The first area and the The second regions are all extended along the second axis, and the second axis is perpendicular to the first axis; the second regions each include a first part, and the first part is adjacent to the first The regions are adjacent; part of the second region includes a second part, the first part and the second part corresponding to the same second region are arranged along the second axial direction, and the second part protrudes from the adjacent The boundary of the first region; etching the second mask layer and stopping on the upper surface of the first mask layer, forming a A plurality of shielding layer grooves arranged in the first axial direction; the shielding layer grooves are all extended along the second axial direction and distributed on the side of the second part, and are in the same position as the second part The projections of the second axial direction are at least partially overlapped; filling the grooves of the shielding layer to form several shielding layers; forming a photoresist layer on the second mask layer, and the photoresist layer has the The etching opening corresponding to the second area and the auxiliary opening corresponding to the shielding layer; and using the photoresist layer and the shielding layer as a mask, etching the second mask layer to form a plurality of second A groove, the second groove corresponds to the second region, and the bottom of which exposes the upper surface of the first mask layer.
可选的,在所述非互联区上的所述第二掩膜层中形成所述遮挡层凹槽的同时,在部分所述第二区上的所述第二掩膜层中形成第二分割槽,所述第二分割槽沿所述第二轴向分割对应的所述第二区。Optionally, while forming the shielding layer groove in the second mask layer on the non-interconnected region, a second mask layer is formed in part of the second region on the second mask layer A division groove, the second division groove divides the corresponding second region along the second axial direction.
可选的,在形成所述遮挡层凹槽之前,所述图形化方法包括:去除所述第一区上的所述第二掩膜层,形成若干第一凹槽,所述第一凹槽的底部露出部分所述第一掩膜层的上表面。Optionally, before forming the barrier layer grooves, the patterning method includes: removing the second mask layer on the first region, forming several first grooves, and the first grooves The bottom part of the upper surface of the first mask layer is exposed.
可选的,所述遮挡层凹槽沿所述第一轴向的宽度小于或等于所述第二分割槽沿所述第二轴向的宽度。Optionally, the width of the shielding layer groove along the first axis is smaller than or equal to the width of the second dividing groove along the second axis.
可选的,填充所述遮挡层凹槽形成所述遮挡层的方法包括:形成填充层,所述填充层覆盖所述第一凹槽、所述第二分割槽和所述遮挡层凹槽的内表面 以及所述第二掩膜层的上表面;对所述填充层进行回刻蚀,直至露出所述第二掩膜层上表面、及位于所述第一凹槽底面的所述第一掩膜层的上表面,保留所述第一凹槽侧壁上的填充层作为侧墙,并保留位于所述第二分割槽作为第二分割掩膜层,且保留所述遮挡层凹槽内的所述填充层作为所述遮挡层。Optionally, the method for filling the shielding layer groove to form the shielding layer includes: forming a filling layer, the filling layer covering the first groove, the second dividing groove and the shielding layer groove. The inner surface and the upper surface of the second mask layer; the filling layer is etched back until the upper surface of the second mask layer and the first groove located at the bottom surface of the first groove are exposed. The upper surface of the mask layer retains the filling layer on the sidewall of the first groove as a sidewall, and remains in the second division groove as the second division mask layer, and remains in the shielding layer groove The filling layer is used as the shielding layer.
可选的,在刻蚀所述第二掩膜层形成所述第二凹槽后,所述图形化方法包括:去除所述光刻胶层;以所述第二分割掩膜层、所述侧墙、所述遮挡层和剩余的所述第二掩膜层为掩膜,依次刻蚀所述第一掩膜层和所述待刻蚀层并停止于所述待刻蚀层,以在所述第一区和所述第二区内形成对应的图形。Optionally, after etching the second mask layer to form the second groove, the patterning method includes: removing the photoresist layer; using the second split mask layer, the The sidewall, the shielding layer and the remaining second mask layer are masks, and the first mask layer and the layer to be etched are sequentially etched and stopped at the layer to be etched, so as to Corresponding graphics are formed in the first area and the second area.
可选的,所述遮挡层凹槽沿所述第一轴向的宽度大于所述第二分割槽沿所述第二轴向的宽度。Optionally, the width of the shielding layer groove along the first axis is greater than the width of the second dividing groove along the second axis.
可选的,部分所述第二区仅包括第一部分,至少部分所述遮挡层凹槽与仅包括第一部分的第二区位置对应,且设置在对应的第二区的端部侧边。Optionally, some of the second regions only include the first part, and at least part of the shielding layer grooves correspond to the positions of the second regions that only include the first part, and are arranged on the side of the end of the corresponding second region.
可选的,同一所述第二区对应的第一部分和第二部分相连接;或者,同一所述第二区对应的第一部分和第二部分沿所述第二轴向间隔排列。Optionally, the first part and the second part corresponding to the same second zone are connected; or, the first part and the second part corresponding to the same second zone are arranged at intervals along the second axial direction.
本发明的另一方面提供一种半导体结构,所述半导体结构利用上述的双重构图的图形化方法形成。Another aspect of the present invention provides a semiconductor structure, which is formed by using the above-mentioned patterning method of double patterning.
附图说明Description of drawings
图1至图3为不同的半导体结构的平面示意图。1 to 3 are schematic plan views of different semiconductor structures.
图4至图7为利用一种图形化方法制作半导体结构的过程结构示意图。4 to 7 are schematic structural diagrams of a process of fabricating a semiconductor structure using a patterning method.
图8为本发明一实施例的双重构图的图形化方法的流程示意图。FIG. 8 is a schematic flowchart of a double-patterning graphics method according to an embodiment of the present invention.
图9至图21为利用本发明一实施例的双重构图的图形化方法制作半导体结构的过程结构示意图。FIG. 9 to FIG. 21 are schematic structural diagrams of the process of fabricating a semiconductor structure by using the patterning method of double patterning according to an embodiment of the present invention.
发明内容Contents of the invention
以下结合附图和具体实施例对本发明提出的双重构图的图形化方法和半导体结构作进一步详细说明。根据下面说明,本发明的优点和特征将更清楚。需说明的是,附图均采用非常简化的形式且均使用非精准的比例,仅用以方便、明晰地辅助说明本发明实施例的目的。The double-patterning patterning method and semiconductor structure proposed by the present invention will be further described in detail below with reference to the accompanying drawings and specific embodiments. The advantages and features of the present invention will become clearer from the following description. It should be noted that all the drawings are in very simplified form and use inaccurate scales, and are only used to facilitate and clearly assist the purpose of illustrating the embodiments of the present invention.
图4至图7为利用一种图形化方法制作半导体结构的过程结构示意图。其中,图4至图7均为半导体结构的俯视图。该图形化方法包括:4 to 7 are schematic structural diagrams of a process of fabricating a semiconductor structure using a patterning method. 4 to 7 are top views of semiconductor structures. The graphical method includes:
步骤一,参考图4,提供自下而上(即沿图4中垂直纸面向外的方向)依次叠加的待刻蚀层、第一掩膜层20和第二掩膜层30。待刻蚀层包括互联区和非互联区,所述非互联区位于互联区外围,所述互联区包括若干第一区(图4中未示出)和若干第二区102,第一区和第二区102沿第一轴向(例如为X轴向)交替排布,且均沿与第一轴向垂直的第二轴向(例如为Y轴向)延长。第二区102均包括第一部分102a,部分第二区102包括第二部分102b,同一第二区102对应的第一部分102a和第二部分102b沿第二轴向依次排布,且第二部分102b超出与第二区102相邻第一区的边界。Step 1, referring to FIG. 4 , provides a layer to be etched, a first mask layer 20 and a second mask layer 30 stacked sequentially from bottom to top (that is, along the direction perpendicular to the surface of the paper in FIG. 4 ). The layer to be etched includes an interconnected area and a non-interconnected area, the non-interconnected area is located at the periphery of the interconnected area, and the interconnected area includes several first areas (not shown in Figure 4) and several second areas 102, the first area and The second regions 102 are alternately arranged along a first axis (eg, X axis), and all extend along a second axis (eg, Y axis) perpendicular to the first axis. The second regions 102 each include a first portion 102a, and part of the second region 102 includes a second portion 102b, the first portion 102a and the second portion 102b corresponding to the same second region 102 are arranged in sequence along the second axial direction, and the second portion 102b Beyond the boundary of the first zone adjacent to the second zone 102 .
步骤二,参考图4,去除第一区(图4中未示出)上的第二掩膜层20,形成第一凹槽301,第一凹槽301的底部露出第一掩膜层20的上表面。Step 2, referring to FIG. 4, removing the second mask layer 20 on the first region (not shown in FIG. 4) to form a first groove 301, the bottom of the first groove 301 exposes the bottom of the first mask layer 20. upper surface.
步骤三,如图4所示,刻蚀第二掩膜层30并停止在第一掩膜层20的上表面,在部分第二区102上形成第二分割槽302,第二分割槽302沿第二轴向分割第二区102。Step 3, as shown in FIG. 4, etching the second mask layer 30 and stopping on the upper surface of the first mask layer 20, forming a second dividing groove 302 on part of the second region 102, the second dividing groove 302 is along the The second axis divides the second zone 102 .
步骤四,如图5所示,在第一凹槽301和第二分割槽302的内表面上沉积填充层,并对所述第一凹槽301内的填充层进行回刻蚀,以在第一凹槽301的侧壁上形成侧墙303以及在第二分割槽302内形成第二分割掩膜层302a。Step 4, as shown in FIG. 5 , deposit a filling layer on the inner surfaces of the first groove 301 and the second dividing groove 302, and etch back the filling layer in the first groove 301, so as to A sidewall 303 is formed on a sidewall of a groove 301 and a second division mask layer 302 a is formed in the second division groove 302 .
步骤五,如图6所示,在部分第一凹槽301内形成第一分割掩膜层304,第一分割掩膜层304沿第二轴向分割第一凹槽301。In step five, as shown in FIG. 6 , a first division mask layer 304 is formed in part of the first groove 301 , and the first division mask layer 304 divides the first groove 301 along the second axis.
步骤六,如图7所示,通过光刻和刻蚀工艺,去除第二区102上剩余的 第二掩膜层30,形成若干第二凹槽305。In step six, as shown in FIG. 7 , the remaining second mask layer 30 on the second region 102 is removed through photolithography and etching processes to form a plurality of second grooves 305 .
步骤七,以侧墙303、第二分割掩模层302a、第一分割掩模层304和第一掩膜层20上剩余的第二掩膜层30为掩模,向下依次刻蚀第一掩模层20和待刻蚀层并停止在待刻蚀层中,在待刻蚀层的第一区和第二区102内形成对应的图形。Step 7, using the sidewall 303, the second split mask layer 302a, the first split mask layer 304 and the remaining second mask layer 30 on the first mask layer 20 as a mask, etch the first The mask layer 20 and the layer to be etched are stopped in the layer to be etched, and corresponding patterns are formed in the first region and the second region 102 of the layer to be etched.
由于第二部分102b超出相邻的第一区的边界,即第二部分102b为相对孤立的区域,第二部分102b的图形在形成过程中,不受到第一区上的侧墙303等图形的影响,而是通过光刻工艺和刻蚀工艺直接形成,使得第二部分102b的图形制作的工艺窗口较窄,第二部分102b的图形容易存在工艺薄弱点,这样就会造成光刻工艺中工艺薄弱点直接会形成图形化缺陷,进而导致半导体器件的性能较差。Since the second part 102b exceeds the boundary of the adjacent first area, that is, the second part 102b is a relatively isolated area, the pattern of the second part 102b is not affected by the side wall 303 and other figures on the first area during the formation process. However, it is directly formed by the photolithography process and the etching process, so that the process window for the pattern production of the second part 102b is relatively narrow, and the pattern of the second part 102b is likely to have a weak point in the process, which will cause the process in the photolithography process Weak points directly lead to patterning defects, which in turn lead to poor performance of semiconductor devices.
为了增大孤立区(即第二区的第二部分)图形制作的工艺窗口,提高半导体器件的性能,图8为本发明一实施例的双重构图的图形化方法的流程示意图。如图8所示,所述双重构图的图形化方法包括:In order to increase the process window for patterning the isolated region (ie, the second part of the second region) and improve the performance of the semiconductor device, FIG. 8 is a schematic flowchart of a patterning method for double patterning according to an embodiment of the present invention. As shown in Figure 8, the graphical method of the double composition includes:
S1,提供自下而上依次叠加的待刻蚀层、第一掩膜层和第二掩膜层;所述待刻蚀层包括互联区和非互联区,所示非互联区位于互联区外围,所述互联区包括沿第一轴向交替排布的若干第一区和若干第二区,所述第一区和所述第二区均沿第二轴向延长,所示第二轴向垂直于所述第一轴向;所述第二区均包括第一部分,所述第一部分与相邻的所述第一区邻接;部分所述第二区包括第二部分,同一所述第二区对应的第一部分和第二部分沿所述第二轴向排布,且所述第二部分凸出于相邻的所述第一区的边界;S1, providing a layer to be etched, a first mask layer, and a second mask layer stacked sequentially from bottom to top; the layer to be etched includes an interconnected area and a non-interconnected area, and the non-interconnected area is located at the periphery of the interconnected area , the interconnected area includes a number of first areas and a number of second areas alternately arranged along the first axis, the first area and the second area are all extended along the second axis, the second axis shown perpendicular to the first axial direction; each of the second regions includes a first portion, and the first portion is adjacent to the adjacent first region; part of the second region includes a second portion, the same as the second The first part and the second part corresponding to the zone are arranged along the second axial direction, and the second part protrudes beyond the boundary of the adjacent first zone;
S2,刻蚀所述第二掩膜层并停止在所述第一掩膜层的上表面,在所述非互联区上的所述第二掩膜层中形成沿所述第一轴向排布的若干遮挡层凹槽;所述遮挡层凹槽均沿所述第二轴向延长,并分布在所述第二部分的侧边,且和所述第二部分在所述第二轴向的投影至少部分交叠;S2. Etching the second mask layer and stopping on the upper surface of the first mask layer, forming rows along the first axial direction in the second mask layer on the non-interconnected region Several shielding layer grooves of the cloth; the shielding layer grooves are all extended along the second axial direction and distributed on the side of the second part, and are in the second axial direction with the second part The projections of are at least partially overlapping;
S3,填充所述遮挡层凹槽形成若干遮挡层;S3, filling the grooves of the shielding layer to form several shielding layers;
S4,在所述第二掩膜层上形成光刻胶层,所述光刻胶层中具有分别与所 述第二区对应的刻蚀开口以及与所述遮挡层对应的辅助开口;S4, forming a photoresist layer on the second mask layer, the photoresist layer has etching openings corresponding to the second region and auxiliary openings corresponding to the shielding layer;
S5,以所述光刻胶层和所述遮挡层为掩膜,刻蚀所述第二掩膜层形成分别与所述第二区对应的第二凹槽,所述第二凹槽的底部露出所述第一掩膜层的上表面。S5, using the photoresist layer and the shielding layer as a mask, etching the second mask layer to form second grooves respectively corresponding to the second regions, the bottom of the second grooves exposing the upper surface of the first mask layer.
图9至图21为利用本发明一实施例的双重构图的图形化方法制作半导体结构的过程结构示意图。图9示出了半导体结构中待刻蚀层的平面示意图,参考图9,步骤S1中,首先提供一待刻蚀层10。所述待刻蚀层10包括互联区和非互联区,所示非互联区位于互联区外围103。作为示例,所述非互联区可以包围所述互联区。一实施例中,所述待刻蚀层10形成在半导体基底上。一实施例中,所述待刻蚀层10为半导体基底的一部分。FIG. 9 to FIG. 21 are schematic structural diagrams of the process of fabricating a semiconductor structure by using the patterning method of double patterning according to an embodiment of the present invention. FIG. 9 shows a schematic plan view of a layer to be etched in a semiconductor structure. Referring to FIG. 9 , in step S1 , a layer 10 to be etched is firstly provided. The layer to be etched 10 includes an interconnected area and a non-interconnected area, and the non-interconnected area is located at the periphery 103 of the interconnected area. As an example, the non-interconnected region may surround the interconnected region. In one embodiment, the layer to be etched 10 is formed on a semiconductor substrate. In one embodiment, the layer to be etched 10 is a part of a semiconductor substrate.
待刻蚀层10可以为单层,也可以为不同材料堆叠的多层结构。优选的,待刻蚀层10可以包括第一材料层和第二材料层,所述第二材料层位于所述第一材料层上,且介电常数高于所述第一材料层的介电常数,后续在刻蚀待刻蚀层的工艺中,第二材料层受到的刻蚀损耗较小,且可以作为第一材料层的刻蚀停止层,第二材料层中图形传递到第一材料层的过程中,图形传递的稳定性较高,提高待刻蚀层10整体的图形精度。The layer 10 to be etched can be a single layer, or a multi-layer structure stacked with different materials. Preferably, the layer 10 to be etched may include a first material layer and a second material layer, the second material layer is located on the first material layer, and the dielectric constant is higher than that of the first material layer. Constant, in the subsequent process of etching the layer to be etched, the etching loss of the second material layer is small, and can be used as an etching stop layer for the first material layer, and the pattern in the second material layer is transferred to the first material layer In the process of layering, the stability of pattern transfer is relatively high, which improves the overall pattern accuracy of the layer 10 to be etched.
具体的,第一材料层的材料可以包括氧化硅、介电常数(K)小于或等于3.9的低介电常数材料。第二次材料层的材料可以为硬掩膜材料,例如包括氮化硅、氮化钛或者氮氧化硅。Specifically, the material of the first material layer may include silicon oxide, a low dielectric constant material with a dielectric constant (K) less than or equal to 3.9. The material of the second material layer may be a hard mask material, such as silicon nitride, titanium nitride or silicon oxynitride.
所述互联区包括若干第一区101和若干第二区102,且所述第一区101和所述第二区102沿第一轴向(例如为X轴向)交替排布,且均沿与第二轴向(例如为Y轴向)延长,所示第二轴向垂直于所述第一轴向。本实施例中,沿第一轴向,所述互联区的排列次序可以为:第一区101、第二区102、第一区101、……、第二区102、第一区101。在其它实施例中,沿第一轴向,所述互联区的排列次序可以为:第二区102、第一区101、第二区102、……、第一区101、第二区102。The interconnected region includes several first regions 101 and several second regions 102, and the first regions 101 and the second regions 102 are alternately arranged along the first axis (for example, the X axis), and are all along the The second axis is extended from the second axis (for example, the Y axis), and the second axis is perpendicular to the first axis. In this embodiment, along the first axis, the arrangement order of the interconnected regions may be: first region 101 , second region 102 , first region 101 , . . . , second region 102 , first region 101 . In other embodiments, along the first axis, the arrangement order of the interconnection regions may be: second region 102 , first region 101 , second region 102 , . . . , first region 101 , second region 102 .
所述第二区102均包括第一部分102a,所述第一部分102a与相邻的所 述第一区101邻接。作为示例,当第二区102位于两个第一区101之间时,该第一部分102a与相邻的两个第一区101邻接(连接);当第二区102仅一侧设置有第一区101时,该第一部分102a与其侧边的第一区101邻接。部分所述第二区102包括第二部分102b,同一个第二区102的第一部分102a和第二部分102b沿第二轴向依次排布(如图4所示,自左向右),且所述第二部分102b超出与所述第二区102相邻的第一区101的边界,即,第二部分102b为相对孤立的区域。需要说明的是,本实施例中,部分第二区102仅包括第一部分102a,没有第二部分102b。Each of the second regions 102 includes a first portion 102a, and the first portion 102a is adjacent to the adjacent first region 101. As an example, when the second region 102 is located between two first regions 101, the first part 102a is adjacent (connected) to two adjacent first regions 101; when only one side of the second region 102 is provided with the first In the area 101, the first portion 102a is adjacent to the first area 101 on its side. Part of the second region 102 includes a second portion 102b, and the first portion 102a and the second portion 102b of the same second region 102 are arranged sequentially along the second axis (as shown in FIG. 4 , from left to right), and The second portion 102b is beyond the boundary of the first area 101 adjacent to the second area 102 , that is, the second portion 102b is a relatively isolated area. It should be noted that, in this embodiment, part of the second region 102 only includes the first part 102a without the second part 102b.
本实施例中,同一个所述第二区102的第一部分102a和第二部分102b可以相连接。另一实施例中,同一个所述第二区102的第一部分102a和第二部分102b可以在第二轴向上间隔排列,即第一部分102a和第二部分102b不相连接。In this embodiment, the first part 102a and the second part 102b of the same second region 102 may be connected. In another embodiment, the first portion 102a and the second portion 102b of the same second zone 102 may be arranged at intervals along the second axis, that is, the first portion 102a and the second portion 102b are not connected.
图10为在待刻蚀层10上形成有第一掩膜层和第二掩膜层后半导体结构的剖面示意图。如图10所示,在待刻蚀层10上,依次叠加形成第一掩模层20和第二掩模层30,第一掩模层20覆盖待刻蚀层10的上表面,第二掩膜层30覆盖第一掩膜层20的上表面。FIG. 10 is a schematic cross-sectional view of the semiconductor structure after the first mask layer and the second mask layer are formed on the layer to be etched 10 . As shown in FIG. 10, on the layer to be etched 10, a first mask layer 20 and a second mask layer 30 are sequentially stacked and formed, the first mask layer 20 covers the upper surface of the layer to be etched 10, and the second mask layer The film layer 30 covers the upper surface of the first mask layer 20 .
所述第一掩膜层20可以为单层,也可以为堆叠的多层结构。第一掩膜层20可以包括多晶硅层、非晶硅层、二氧化硅层、氮化硅层、氧化钛层和氮化钛层中的至少一种。所述第二掩膜层30可以为单层,也可以为堆叠的多层结构。第二掩膜层30可以包括多晶硅层、非晶硅层、二氧化硅层、氮化硅层、氧化钛层和氮化钛层中的至少一种。The first mask layer 20 can be a single layer, or a stacked multi-layer structure. The first mask layer 20 may include at least one of a polysilicon layer, an amorphous silicon layer, a silicon dioxide layer, a silicon nitride layer, a titanium oxide layer, and a titanium nitride layer. The second mask layer 30 can be a single layer, or a stacked multi-layer structure. The second mask layer 30 may include at least one of a polysilicon layer, an amorphous silicon layer, a silicon dioxide layer, a silicon nitride layer, a titanium oxide layer, and a titanium nitride layer.
需要说明的是,第一掩膜层20和第二掩膜层30均为单层时,第一掩膜层20和第二掩膜层30的材料不同。第一掩膜层20和第二掩膜层30均为多层结构时,第一掩膜层20的底层和第二掩膜层30的底层的材料可以不同。It should be noted that when both the first mask layer 20 and the second mask layer 30 are single layers, the materials of the first mask layer 20 and the second mask layer 30 are different. When both the first mask layer 20 and the second mask layer 30 have a multi-layer structure, the bottom layer of the first mask layer 20 and the bottom layer of the second mask layer 30 may be made of different materials.
本实施例中,第一掩膜层20和第二掩膜层30均可以采用化学气相沉积法(CVD)和/或炉管工艺等方法形成,化学气相沉积法例如可以为低温化学气相沉积(LTCVD)、低压化学气相沉积(LPCVD)、快热化学气相沉积(RTCVD) 或等离子体增强化学气相沉积(PECVD)。但不限于此,本发明对第一掩膜层20和第二掩膜层30的形成方法不作限定。In this embodiment, both the first mask layer 20 and the second mask layer 30 can be formed by methods such as chemical vapor deposition (CVD) and/or furnace tube technology, and the chemical vapor deposition method can be, for example, low-temperature chemical vapor deposition ( LTCVD), Low Pressure Chemical Vapor Deposition (LPCVD), Rapid Thermal Chemical Vapor Deposition (RTCVD) or Plasma Enhanced Chemical Vapor Deposition (PECVD). But not limited thereto, the present invention does not limit the formation methods of the first mask layer 20 and the second mask layer 30 .
图11为在第二掩膜层中形成有第一凹槽后半导体结构的平面示意图。如图11所示,在步骤S1之后、步骤S2之前,所述双重构图的图形化方法可以包括:去除所述第一区101上的所述第二掩膜层30,形成第一凹槽301,所述第一凹槽301的底部露出部分所述第一掩膜层20的上表面。FIG. 11 is a schematic plan view of the semiconductor structure after the first groove is formed in the second mask layer. As shown in FIG. 11 , after step S1 and before step S2, the patterning method of double patterning may include: removing the second mask layer 30 on the first region 101 to form a first groove 301 , the bottom of the first groove 301 exposes part of the upper surface of the first mask layer 20 .
具体的,形成所述第一凹槽301的方法可以包括:在第二掩膜层30上形成第一图形化光刻胶层(图中未示出),以该第一图形化光刻胶层为掩膜,刻蚀第二掩膜层30并停止在第一掩膜层20的上表面,形成与所述第一区101对应的第一凹槽301,所述第一凹槽301的底部露出部分第一掩膜层20的上表面。Specifically, the method for forming the first groove 301 may include: forming a first patterned photoresist layer (not shown in the figure) on the second mask layer 30, using the first patterned photoresist layer is a mask, etch the second mask layer 30 and stop on the upper surface of the first mask layer 20 to form a first groove 301 corresponding to the first region 101, the first groove 301 The bottom exposes part of the upper surface of the first mask layer 20 .
图12为在第二掩膜层中形成若干遮挡层凹槽后半导体结构的平面示意图。如图12所示,在形成所述第一凹槽301后,执行步骤S2,刻蚀第二掩膜层30并停止在所述第一掩膜层20的上表面,在非互联区103上的第二掩膜层30中形成沿所述第一轴向(X轴向)排布的遮挡层凹槽306;所述遮挡层凹槽306均沿所述第二轴向(Y轴向)延长,并分布在所述第二部分102b的侧边,且和所述第二部分102b在所述第二轴向的投影至少部分交叠。FIG. 12 is a schematic plan view of the semiconductor structure after forming a plurality of shielding layer grooves in the second mask layer. As shown in FIG. 12 , after the first groove 301 is formed, step S2 is performed to etch the second mask layer 30 and stop on the upper surface of the first mask layer 20 , on the non-interconnected region 103 The shielding layer grooves 306 arranged along the first axis (X axis) are formed in the second mask layer 30; the shielding layer grooves 306 are all along the second axis (Y axis) extended, distributed on the side of the second portion 102b, and at least partially overlap with the projection of the second portion 102b on the second axis.
一实施例中,每个所述遮挡层凹槽306和所述第二部分102b在所述第二轴向的投影至少部分交叠。一实施例中,部分遮挡层凹槽306和第二部分102b在第二轴向的投影至少部分交叠,优选的,靠近第二部分102b的遮挡层凹槽306和第二部分102b在第二轴向的投影至少部分交叠。In one embodiment, each of the shielding layer grooves 306 and the projection of the second portion 102b on the second axis at least partially overlap. In one embodiment, the projection of part of the blocking layer groove 306 and the second portion 102b on the second axial direction at least partially overlaps. Preferably, the blocking layer groove 306 close to the second portion 102b and the second portion 102b are in the The axial projections at least partially overlap.
参考图9和图12,部分第二区102仅包括第一部分102a,第一部分102a与第一区101邻接,例如沿X轴向,第一/第四个第二区102仅包括第一部分102a,而第二/第三个第二区102包括第一部分102a和第二部分102b。本实施例中,至少部分遮挡层凹槽306可以与仅包括第一部分的第二区102位置对应,且设置在对应的第二区102的端部侧边,并与仅包括第一部分的第二区102沿第一轴向的排布周期相同,进而在后续步骤S4中,沿第一轴 向,与第二部分102b对应的刻蚀开口和辅助图形的排布周期与第二区102的排列周期相同,增大第二部分102b对应的图形(刻蚀开口)的制作工艺窗口,提高第二部分102b对应的图形的精度,进而提高第二部分102b的图形精度。9 and 12, part of the second zone 102 includes only the first portion 102a, and the first portion 102a is adjacent to the first zone 101, for example, along the X axis, the first/fourth second zone 102 only includes the first portion 102a, And the second/third second region 102 includes a first portion 102a and a second portion 102b. In this embodiment, at least part of the shielding layer groove 306 may correspond to the position of the second region 102 that only includes the first part, and is disposed on the end side of the corresponding second region 102, and is connected to the second region that only includes the first part. The arrangement period of the regions 102 along the first axis is the same, and then in the subsequent step S4, along the first axis, the arrangement period of the etching openings and auxiliary patterns corresponding to the second part 102b is the same as the arrangement period of the second region 102 The period is the same, increasing the manufacturing process window of the pattern (etching opening) corresponding to the second part 102b, improving the precision of the pattern corresponding to the second part 102b, and further improving the pattern precision of the second part 102b.
本实施例中,如图12所示,在刻蚀所述第二掩膜层30并停止在所述第一掩膜层20的上表面,形成所述遮挡层凹槽306的同时,可以在所述第二区102上的第二掩膜层30中形成第二分割槽302,沿所述第二轴向,所述第二分割槽302分割对应的第二区102。也就是说,本实施例中,在形成分割第二区102的第二分割槽302的同时,形成遮挡层凹槽306,既不增加制作流程,也不增加额外的光罩,更不会增长制作时间。需要说明的是,通常沿第二轴向,部分第二区102的最终图形并不是连续的,因而需要形成第二分割槽302,以便后续形成第二分割掩膜层302a,以分割对应的第二区102。In this embodiment, as shown in FIG. 12 , while etching the second mask layer 30 and stopping on the upper surface of the first mask layer 20 to form the blocking layer groove 306 , it can be A second division groove 302 is formed in the second mask layer 30 on the second region 102 , and the second division groove 302 divides the corresponding second region 102 along the second axis. That is to say, in this embodiment, while forming the second dividing groove 302 for dividing the second region 102, the shielding layer groove 306 is formed at the same time, neither increasing the manufacturing process nor adding an additional photomask, let alone increasing production time. It should be noted that, generally along the second axis, the final pattern of part of the second region 102 is not continuous, so it is necessary to form the second dividing groove 302, so as to form the second dividing mask layer 302a in order to divide the corresponding District 2 102.
图13为本发明一实施例中形成若干遮挡层后的半导体结构的平面示意图。如图13所示,在形成所述遮挡层凹槽306之后,执行步骤S3,填充所述遮挡层凹槽306,形成遮挡层307。FIG. 13 is a schematic plan view of a semiconductor structure after forming several shielding layers according to an embodiment of the present invention. As shown in FIG. 13 , after the shielding layer groove 306 is formed, step S3 is performed to fill the shielding layer groove 306 to form a shielding layer 307 .
一实施例中,所述遮挡层凹槽306在第一轴向的宽度小于或等于第二分割槽302沿第二轴向的宽度。如图13所示,在填充所述遮挡层凹槽306形成遮挡层307的同时,可以在所述第一凹槽301的侧壁上形成侧墙303以及在所述第二分割槽302内形成第二分割掩膜层302a,简化制作流程,节约生产成本。In one embodiment, the width of the shielding layer groove 306 along the first axis is smaller than or equal to the width of the second dividing groove 302 along the second axis. As shown in FIG. 13 , while filling the shielding layer groove 306 to form a shielding layer 307 , a sidewall 303 can be formed on the sidewall of the first groove 301 and a sidewall 303 can be formed in the second dividing groove 302 . The second split mask layer 302a simplifies the manufacturing process and saves the production cost.
图14为图13的半导体结构沿AA线的剖视图。参考图13和图14,形成遮挡层307、侧墙303和第二分割掩膜层302a的方法可以包括:沉积形成填充层,所述填充层覆盖所述第一凹槽301的内表面和所述第二掩膜层30的上表面,且填满所述第二分割槽302和所述遮挡层凹槽306;对所述填充层进行回刻蚀,直至露出所述第二掩膜层30上表面和位于所述第一凹槽301底面的第一掩膜层20的上表面,保留第一凹槽301侧壁上的填充层作为侧墙303,并且保留位于所述第二分割槽302和遮挡层凹槽306内的填充层, 以分别作为第二分割掩膜层302a和所述遮挡层307。需要说明的是,在所述遮挡层凹槽306的宽度较窄(即小于或等于第二分割槽302沿第二轴向的宽度)时,所述遮挡层凹槽306可以一次性填满。FIG. 14 is a cross-sectional view of the semiconductor structure of FIG. 13 along line AA. Referring to FIG. 13 and FIG. 14, the method for forming the shielding layer 307, the sidewall 303 and the second segmentation mask layer 302a may include: depositing and forming a filling layer covering the inner surface of the first groove 301 and the inner surface of the first groove 301. the upper surface of the second mask layer 30, and fill the second dividing groove 302 and the shielding layer groove 306; etch back the filling layer until the second mask layer 30 is exposed The upper surface and the upper surface of the first mask layer 20 located at the bottom surface of the first groove 301 retain the filling layer on the side wall of the first groove 301 as the side wall 303, and retain the filling layer located at the second dividing groove 302. and the filling layer in the shielding layer groove 306 to serve as the second segmentation mask layer 302a and the shielding layer 307 respectively. It should be noted that, when the width of the shielding layer groove 306 is narrow (that is, less than or equal to the width of the second dividing groove 302 along the second axial direction), the shielding layer groove 306 can be filled up at one time.
图15为本发明另一实施例中形成遮挡层后的半导体结构的平面示意图。另一实施例中,如图15所示,所述遮挡层凹槽306沿第一轴向的宽度大于所述第二分割槽302沿第二轴向的宽度,可以通过多次填充遮挡层凹槽306形成所述遮挡层307,以确保所述遮挡层凹槽306被填满。FIG. 15 is a schematic plan view of a semiconductor structure after forming a shielding layer in another embodiment of the present invention. In another embodiment, as shown in FIG. 15 , the width of the shielding layer groove 306 along the first axial direction is greater than the width of the second dividing groove 302 along the second axial direction, and the shielding layer groove can be filled multiple times. Grooves 306 form the blocking layer 307 to ensure that the blocking layer grooves 306 are filled.
图16为图15所示的半导体结构沿BB线的剖面示意图。参考图15和图16,填充宽度较大的所述遮挡层凹槽306(例如遮挡层凹槽306的宽度大于第二区102的宽度),形成遮挡层307的方法可以包括:形成第填充层307a,所述第填充层307a覆盖所述第一凹槽301的内表面、所述遮挡层凹槽306的内表面和所述第二掩膜层30的上表面,并填满所述第二分割槽302,其中,第填充层307a未填满所述遮挡层凹槽306;形成覆盖所述第填充层307a的上表面的图形化层308,所述图形化层308中具有第一开口,所述第一开口露出位于所述遮挡层凹槽306上的第填充层307a的上表面;继续沉积形成第二填充层307b,第二填充层307b填满所述遮挡层凹槽306;进行第一次回刻蚀,直至露出所述第一开口对应的第填充层307a的上表面;去除所述图形化层308;进行第二次回刻蚀,直至暴露出所述第二掩膜层30的上表面和第一凹槽301底部的第一掩膜层20的上表面,保留第一凹槽301侧壁上的第填充层307a作为侧墙303,保留所述第二分割槽302内的第填充层307a作为第二分割掩膜层302a,并且第二填充层307b和遮挡层凹槽306内剩余的第填充层307a共同作为遮挡层307。FIG. 16 is a schematic cross-sectional view of the semiconductor structure shown in FIG. 15 along line BB. Referring to FIGS. 15 and 16 , filling the shielding layer groove 306 with a larger width (for example, the width of the shielding layer groove 306 is greater than the width of the second region 102), the method for forming the shielding layer 307 may include: forming a first filling layer 307a, the first filling layer 307a covers the inner surface of the first groove 301, the inner surface of the barrier layer groove 306 and the upper surface of the second mask layer 30, and fills up the second Separation groove 302, wherein, the first filling layer 307a does not fill the barrier layer groove 306; forming a patterned layer 308 covering the upper surface of the first filling layer 307a, the patterned layer 308 has a first opening, The first opening exposes the upper surface of the first filling layer 307a located on the shielding layer groove 306; continue to deposit to form a second filling layer 307b, and the second filling layer 307b fills up the shielding layer groove 306; Etch back once until the upper surface of the first filling layer 307a corresponding to the first opening is exposed; remove the patterned layer 308; etch back a second time until the upper surface of the second mask layer 30 is exposed On the upper surface and the upper surface of the first mask layer 20 at the bottom of the first groove 301, the first filling layer 307a on the side wall of the first groove 301 is reserved as the side wall 303, and the first filling layer 307a in the second dividing groove 302 is reserved. The filling layer 307 a serves as the second division mask layer 302 a , and the second filling layer 307 b and the remaining first filling layer 307 a in the shielding layer groove 306 together serve as the shielding layer 307 .
所述图形化层308可以为多层结构,例如包括在第填充层307a上依次叠加形成的第一图形化层308a、第二图形化层308b和第三图形化层308c;所述第一图形化层308a可以为氧化物层;所述第二图形化层308b可以作为底部抗反射层,其材料可以为高碳含量的聚合物;所述第三图形化层308c可以为光刻胶层,提高形成的第一开口的精度,并提高在回刻蚀第二填充层 307b时的遮挡效果。The patterned layer 308 may be a multi-layer structure, for example, comprising a first patterned layer 308a, a second patterned layer 308b and a third patterned layer 308c formed successively on the filling layer 307a; The patterned layer 308a can be an oxide layer; the second patterned layer 308b can be used as a bottom anti-reflection layer, and its material can be a polymer with high carbon content; the third patterned layer 308c can be a photoresist layer, The accuracy of the formed first opening is improved, and the shielding effect when etching back the second filling layer 307b is improved.
图17为本发明一实施例中的半导体结构形成第一分割掩膜层后的平面示意图。在形成遮挡层307之后(具体例如为形成侧墙303、第二分割掩膜层302a和遮挡层307后),所述双重构图的图形化方法还可以包括:在部分第一凹槽301内形成第一分割掩膜层304,沿所述第二轴向,所述第一分割掩膜层304分割对应的第一凹槽301。需要说明的是,通常,沿所述第二轴向,第一区101的最终图形并不是连续的,因而,需要形成第一分割掩膜层304以分割对应的第一区101。FIG. 17 is a schematic plan view of the semiconductor structure after forming the first split mask layer according to an embodiment of the present invention. After forming the shielding layer 307 (specifically, after forming the sidewall 303, the second segmentation mask layer 302a, and the shielding layer 307), the patterning method of the double patterning may further include: forming in part of the first groove 301 The first split mask layer 304 , along the second axis, the first split mask layer 304 splits the corresponding first groove 301 . It should be noted that, generally, along the second axis, the final pattern of the first regions 101 is not continuous, therefore, a first segmentation mask layer 304 needs to be formed to segment the corresponding first regions 101 .
本实施例中,形成第一分割掩膜层304的方法可以包括:形成一掩膜,该掩膜覆盖第二掩膜层30的上表面并填满第一凹槽301;在部分第一凹槽301内的掩膜中形成第一分割槽,第一分割槽露出第一掩膜层20的上表面;对第一分割槽进行填充,形成第一分割掩膜层304;去除该掩膜。In this embodiment, the method for forming the first split mask layer 304 may include: forming a mask covering the upper surface of the second mask layer 30 and filling the first groove 301; A first dividing groove is formed in the mask in the groove 301, and the first dividing groove exposes the upper surface of the first mask layer 20; the first dividing groove is filled to form the first dividing mask layer 304; and the mask is removed.
在部分第一凹槽301内形成第一分割掩膜层304后,执行步骤S4,在所述第二掩膜层30上形成光刻胶层(以下称为第二光刻胶层),所述第二光刻胶层中具有分别与所述第二区102对应的若干刻蚀开口以及与所述遮挡层307对应的若干辅助开口。After the first split mask layer 304 is formed in part of the first groove 301, step S4 is performed to form a photoresist layer (hereinafter referred to as the second photoresist layer) on the second mask layer 30, so that The second photoresist layer has a plurality of etching openings corresponding to the second region 102 and a plurality of auxiliary openings corresponding to the shielding layer 307 .
图18为本发明一实施例中半导体结构形成第二光刻胶层后的剖面示意图。如图18所示,第二光刻胶层309中具有若干刻蚀开口310和若干辅助开口311,刻蚀开口310位于对应的第二区102上方,辅助开口311位于对应的遮挡层307上方。18 is a schematic cross-sectional view of a semiconductor structure after forming a second photoresist layer according to an embodiment of the present invention. As shown in FIG. 18 , the second photoresist layer 309 has several etching openings 310 and several auxiliary openings 311 , the etching openings 310 are located above the corresponding second region 102 , and the auxiliary openings 311 are located above the corresponding shielding layer 307 .
对所述第二光刻胶层309进行图形化的过程(包括曝光和显影)中,在第二光刻胶层309中形成与第二区102(包括第一部分102a和第二部分102b)对应的刻蚀开口310的同时,还形成与遮挡层307对应的若干辅助开口311(即辅助图形),如此,在光刻工艺中,可以增大第二部分102b对应的图形(刻蚀开口310与第二部分102b对应的部分)的制作工艺窗口,以克服第二部分102b对应的图形存在的工艺薄弱点,提高第二部分102b对应的刻蚀开口310的精度。In the process of patterning the second photoresist layer 309 (including exposure and development), a pattern corresponding to the second region 102 (including the first part 102a and the second part 102b) is formed in the second photoresist layer 309. At the same time as the etching opening 310 of the shielding layer 307, a number of auxiliary openings 311 (that is, auxiliary patterns) corresponding to the shielding layer 307 are also formed. In this way, in the photolithography process, the pattern corresponding to the second part 102b (etching openings 310 and The manufacturing process window of the part corresponding to the second part 102b is to overcome the process weakness of the pattern corresponding to the second part 102b and improve the precision of the etching opening 310 corresponding to the second part 102b.
图19为本发明一实施例中半导体结构上形成第二凹槽后的平面示意图。在步骤S4后,执行步骤S5,以所述第二光刻胶层309和所述遮挡层307为掩膜,刻蚀所述第二掩膜层30形成分别与所述第二区102对应的第二凹槽305,所述第二凹槽305的底部露出所述第一掩膜层20的上表面。由于第二光刻胶层309中与第二部分102b对应的刻蚀开口310的精度较高,提高刻蚀第二掩膜层30形成的第二凹槽305中与第二部分102b对应的图形的精度。FIG. 19 is a schematic plan view of the second groove formed on the semiconductor structure according to an embodiment of the present invention. After step S4, step S5 is performed, using the second photoresist layer 309 and the shielding layer 307 as a mask, etching the second mask layer 30 to form regions corresponding to the second regions 102 respectively. The second groove 305 , the bottom of the second groove 305 exposes the upper surface of the first mask layer 20 . Since the etching opening 310 corresponding to the second portion 102b in the second photoresist layer 309 has higher precision, the pattern corresponding to the second portion 102b in the second groove 305 formed by etching the second mask layer 30 is improved. accuracy.
本实施例中,在刻蚀第二掩膜层30形成第二凹槽305的过程中,除了以第二光刻胶层309和遮挡层307为掩膜,同时还以第一分割掩膜层304、第二分割掩膜层302a和侧墙303为掩膜。In this embodiment, in the process of etching the second mask layer 30 to form the second groove 305, in addition to using the second photoresist layer 309 and the shielding layer 307 as masks, the first division mask layer is also used 304, the second division mask layer 302a and the sidewalls 303 are masks.
图20为本发明一实施例刻蚀第一掩膜层后半导体结构的平面示意图。在刻蚀所述第二掩膜层30形成所述第二凹槽305后,如图20所示,所述双重构图的图形化方法还可以包括:去除第二光刻胶层309;以第一分割掩膜层304、第二分割掩膜层30、侧墙303、遮挡层307和剩余的所述第二掩膜层30为掩膜,刻蚀第一掩膜层20并停止在所述待刻蚀层10上表面,如此可以将第一分割掩膜层304、第二分割掩膜层30、侧墙303、遮挡层307和剩余的所述第二掩膜层30构成的图形传递到第一掩膜层20中。FIG. 20 is a schematic plan view of the semiconductor structure after etching the first mask layer according to an embodiment of the present invention. After etching the second mask layer 30 to form the second groove 305, as shown in FIG. 20, the patterning method of the double patterning may further include: removing the second photoresist layer 309; A split mask layer 304, a second split mask layer 30, sidewalls 303, a shielding layer 307 and the rest of the second mask layer 30 are masks, and the first mask layer 20 is etched and stopped at the The upper surface of the layer 10 to be etched, so that the pattern formed by the first segmentation mask layer 304, the second segmentation mask layer 30, the sidewall 303, the shielding layer 307 and the remaining second mask layer 30 can be transferred to In the first mask layer 20 .
在刻蚀第一掩膜层20之后,继续向下刻蚀待刻蚀层10并停止在待刻蚀层10,以将第一掩膜层20中的图形传递到待刻蚀层10,以在第一区101和第二区102内形成对应的图形。After etching the first mask layer 20, continue to etch the layer 10 to be etched downward and stop at the layer 10 to be etched, so that the pattern in the first mask layer 20 is transferred to the layer 10 to be etched, to Corresponding patterns are formed in the first area 101 and the second area 102 .
图21为本发明一实施例中去除第一掩膜层和第二掩膜层后半导体结构的平面示意图。如图21所示,待刻蚀层10刻蚀完毕后,在第一区101内形成第一刻蚀槽101',在第二区102内形成第二刻蚀槽102',其中,部分第二刻蚀槽102'可以包括第一分刻蚀槽102a'和第二分刻蚀槽102b',第一区101中侧墙303和第一分割掩膜层304下的待刻蚀层10未被刻蚀,第二区102中第二分割掩膜层302a下的待刻蚀层10未被刻蚀,非互联区103中遮挡层307对应的位置未被刻蚀。FIG. 21 is a schematic plan view of the semiconductor structure after removing the first mask layer and the second mask layer according to an embodiment of the present invention. As shown in FIG. 21, after the etch layer 10 is etched, a first etch groove 101' is formed in the first region 101, and a second etch groove 102' is formed in the second region 102, wherein some of the first The second etching groove 102' may include a first sub-etching groove 102a' and a second sub-etching groove 102b', and the to-be-etched layer 10 under the sidewall 303 and the first split mask layer 304 in the first region 101 is not is etched, the layer 10 to be etched under the second division mask layer 302 a in the second region 102 is not etched, and the position corresponding to the shielding layer 307 in the non-interconnection region 103 is not etched.
在待刻蚀层10刻蚀结束后,所述图形化方法还可以包括:去除待刻蚀 层10上的第二掩膜层30、第一掩膜层20、侧墙303、第一分割掩膜层304、第二分割掩膜层302a和遮挡层307;在第一刻蚀槽101'和第二刻蚀槽102'内填充导电材料,以在待刻蚀层10中形成互联结构。所述导电材料可以为铝、铜、银或钨等金属材料。但不限于此,所述导电材料也可以为导电的金属合金等其它材料。After the etching of the layer to be etched 10 is completed, the patterning method may further include: removing the second mask layer 30 on the layer to be etched 10, the first mask layer 20, the sidewalls 303, the first division mask The film layer 304 , the second segmentation mask layer 302 a and the shielding layer 307 ; the first etching groove 101 ′ and the second etching groove 102 ′ are filled with conductive material to form an interconnection structure in the layer to be etched 10 . The conductive material may be metal materials such as aluminum, copper, silver or tungsten. But not limited thereto, the conductive material may also be other materials such as conductive metal alloys.
本实施例还提供一种半导体结构,所述半导体结构利用上述双重构图的图形化方法制作得到。所述半导体结构可以是执行上述双重构图的图形化方法的过程中形成的任一半导体结构。This embodiment also provides a semiconductor structure, which is manufactured by the above-mentioned patterning method of double patterning. The semiconductor structure may be any semiconductor structure formed during the above-mentioned patterning method of double patterning.
上述描述仅是对本发明较佳实施例的描述,并非对本发明权利范围的任何限定,任何本领域技术人员在不脱离本发明的精神和范围内,对本发明揭露的技术方案和技术内容做任何形式的等同替换或修改等变动,均属未脱离本发明的技术方案的内容,仍属于本发明的保护范围之内。The above description is only a description of the preferred embodiments of the present invention, and does not limit the scope of rights of the present invention. Any person skilled in the art may make any form of technical solution and technical content disclosed in the present invention without departing from the spirit and scope of the present invention. Changes such as equivalent replacement or modification, etc., all belong to the content that does not deviate from the technical solution of the present invention, and still belong to the protection scope of the present invention.

Claims (10)

  1. 一种双重构图的图形化方法,其特征在于,包括:A graphical method for dual composition, characterized in that it includes:
    提供自下而上依次叠加的待刻蚀层、第一掩膜层和第二掩膜层;所述待刻蚀层包括互联区和非互联区,所示非互联区位于互联区外围,所述互联区包括沿第一轴向交替排布的若干第一区和若干第二区,所述第一区和所述第二区均沿第二轴向延长,所示第二轴向垂直于所述第一轴向;所述第二区均包括第一部分,所述第一部分与相邻的所述第一区邻接;部分所述第二区包括第二部分,同一所述第二区对应的第一部分和第二部分沿所述第二轴向排布,且所述第二部分凸出于相邻的所述第一区的边界;Provide a layer to be etched, a first mask layer, and a second mask layer stacked sequentially from bottom to top; the layer to be etched includes an interconnected area and a non-interconnected area, and the non-interconnected area shown is located at the periphery of the interconnected area, so The interconnected area includes a number of first areas and a number of second areas alternately arranged along the first axis, the first areas and the second areas are all extended along the second axis, and the second axis is perpendicular to The first axial direction; the second zone includes a first part, and the first part is adjacent to the adjacent first zone; part of the second zone includes a second part, corresponding to the same second zone The first part and the second part are arranged along the second axial direction, and the second part protrudes beyond the boundary of the adjacent first zone;
    刻蚀所述第二掩膜层并停止在所述第一掩膜层的上表面,在所述非互联区上的所述第二掩膜层中形成沿所述第一轴向排布的遮挡层凹槽;所述遮挡层凹槽均沿所述第二轴向延长,并分布在所述第二部分的侧边,且和所述第二部分在所述第二轴向的投影至少部分交叠;etching the second mask layer and stopping on the upper surface of the first mask layer, forming The shielding layer grooves; the shielding layer grooves are all extended along the second axial direction, distributed on the side of the second part, and at least the projection of the second part on the second axial direction partially overlap;
    填充所述遮挡层凹槽形成若干遮挡层;filling the grooves of the shielding layer to form several shielding layers;
    在所述第二掩膜层上形成光刻胶层,所述光刻胶层具有与所述第二区对应的刻蚀开口、及与所述遮挡层对应的辅助开口;以及forming a photoresist layer on the second mask layer, the photoresist layer has an etching opening corresponding to the second region, and an auxiliary opening corresponding to the shielding layer; and
    以所述光刻胶层和所述遮挡层为掩膜,刻蚀所述第二掩膜层形成若干第二凹槽,第二凹槽对应所述第二区,并底部露出所述第一掩膜层的上表面。Using the photoresist layer and the shielding layer as a mask, etch the second mask layer to form a plurality of second grooves, the second grooves correspond to the second region, and the bottom of the first groove is exposed. the upper surface of the mask layer.
  2. 如权利要求1所述的图形化方法,其特征在于,在所述非互联区上的所述第二掩膜层中形成所述遮挡层凹槽的同时,在部分所述第二区上的所述第二掩膜层中形成第二分割槽,所述第二分割槽沿所述第二轴向分割对应的所述第二区。The patterning method according to claim 1, characterized in that, while forming the shielding layer groove in the second mask layer on the non-interconnected region, part of the second region on the A second dividing groove is formed in the second mask layer, and the second dividing groove divides the corresponding second region along the second axial direction.
  3. 如权利要求2所述的图形化方法,其特征在于,在形成所述遮挡层凹槽之前,所述图形化方法包括:The patterning method according to claim 2, characterized in that, before forming the shielding layer groove, the patterning method comprises:
    去除所述第一区上的所述第二掩膜层,形成若干第一凹槽,所述第一凹槽的底部露出部分所述第一掩膜层的上表面。The second mask layer on the first region is removed to form a plurality of first grooves, and the bottoms of the first grooves expose part of the upper surface of the first mask layer.
  4. 如权利要求3所述的图形化方法,其特征在于,所述遮挡层凹槽沿所述第一轴向的宽度小于或等于所述第二分割槽沿第二轴向的宽度。The patterning method according to claim 3, wherein the width of the shielding layer groove along the first axis is smaller than or equal to the width of the second dividing groove along the second axis.
  5. 如权利要求4所述的图形化方法,其特征在于,填充所述遮挡层凹槽形成所述遮挡层的方法包括:The patterning method according to claim 4, wherein the method of filling the recess of the shielding layer to form the shielding layer comprises:
    形成填充层,所述填充层覆盖所述第一凹槽的内表面和所述第二掩膜层的上表面,且填满所述第二分割槽和所述遮挡层凹槽;forming a filling layer, the filling layer covers the inner surface of the first groove and the upper surface of the second mask layer, and fills up the second dividing groove and the barrier layer groove;
    对所述填充层进行回刻蚀,直至露出所述第二掩膜层上表面、及位于所述第一凹槽底面的所述第一掩膜层的上表面,保留所述第一凹槽侧壁上的填充层作为侧墙,并保留位于所述第二分割槽作为第二分割掩膜层,且保留所述遮挡层凹槽内的所述填充层作为所述遮挡层。The filling layer is etched back until the upper surface of the second mask layer and the upper surface of the first mask layer located at the bottom of the first groove are exposed, and the first groove is retained. The filling layer on the sidewall is used as a sidewall, and the filling layer in the shielding layer groove is kept as the shielding layer while remaining in the second division groove as a second division mask layer.
  6. 如权利要求5所述的图形化方法,其特征在于,在刻蚀所述第二掩膜层形成所述第二凹槽后,所述图形化方法包括:The patterning method according to claim 5, wherein after etching the second mask layer to form the second groove, the patterning method comprises:
    去除所述光刻胶层;removing the photoresist layer;
    以所述第二分割掩膜层、所述侧墙、所述遮挡层和剩余的所述第二掩膜层为掩膜,依次刻蚀所述第一掩膜层和所述待刻蚀层并停止于所述待刻蚀层,以在所述第一区和所述第二区内形成对应的图形。Using the second split mask layer, the sidewall, the shielding layer and the remaining second mask layer as masks, sequentially etch the first mask layer and the layer to be etched And stop at the layer to be etched, so as to form corresponding patterns in the first area and the second area.
  7. 如权利要求2所述的图形化方法,其特征在于,所述遮挡层凹槽沿所述第一轴向的宽度大于所述第二分割槽沿所述第二轴向的宽度。The patterning method according to claim 2, wherein the width of the shielding layer groove along the first axis is greater than the width of the second dividing groove along the second axis.
  8. 如权利要求1所述的图形化方法,其特征在于,部分所述第二区仅包括第一部分,至少部分所述遮挡层凹槽与仅包括第一部分的第二区位置对应,且设置在对应的第二区的端部侧边。The patterning method according to claim 1, wherein part of the second area only includes the first part, and at least part of the recesses of the shielding layer correspond to the positions of the second area only including the first part, and are arranged in corresponding positions. The end side of the second zone.
  9. 如权利要求1所述的图形化方法,其特征在于,同一所述第二区对应的第一部分和第二部分相连接;或者,同一所述第二区对应的第一部分和第二部分沿所述第二轴向间隔排列。The patterning method according to claim 1, wherein the first part and the second part corresponding to the same second area are connected; or, the first part and the second part corresponding to the same second area are connected along the The second axis is arranged at intervals.
  10. 一种半导体结构,其特征在于,利用如权利要求1至9任意一项所述的双重构图的图形化方法形成。A semiconductor structure, characterized in that it is formed by using the patterning method of double patterning as claimed in any one of claims 1 to 9.
PCT/CN2021/143024 2021-11-24 2021-12-30 Double patterning method and semiconductor structure WO2023092811A1 (en)

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