WO2023092344A1 - 电池单体、电池、用电装置、制备电池单体的方法和装置 - Google Patents
电池单体、电池、用电装置、制备电池单体的方法和装置 Download PDFInfo
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- WO2023092344A1 WO2023092344A1 PCT/CN2021/132869 CN2021132869W WO2023092344A1 WO 2023092344 A1 WO2023092344 A1 WO 2023092344A1 CN 2021132869 W CN2021132869 W CN 2021132869W WO 2023092344 A1 WO2023092344 A1 WO 2023092344A1
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- wall
- electrode assembly
- battery
- cylindrical electrode
- battery cell
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- H01M50/204—Racks, modules or packs for multiple batteries or multiple cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the present application relates to the field of battery technology, in particular to a battery cell, a battery, an electrical device, and a method and device for preparing a battery cell.
- the battery is usually assembled from multiple battery cells.
- the life and safety performance of the battery are directly affected by the battery cells.
- the thermal runaway of the electrode components in the battery cells is easy to cause thermal runaway of other electrode components through heat conduction.
- the battery cells Thermal runaway directly affects the safety and life of the battery. Therefore, how to improve the safety performance and lifespan of battery cells is an urgent technical problem to be solved.
- the present application provides a battery cell, a battery, an electrical device, and a method and device for preparing the battery cell, which can reduce the thermal diffusion of the battery cell during thermal runaway, improve the safety of the battery cell, and prolong the service life of the battery.
- a battery cell comprising: a hexahedral housing, the housing has a first wall and a second wall oppositely disposed, the positive terminal is disposed on the first wall, and the positive terminal is disposed on the second wall.
- Negative terminal connection comprising: a hexahedral housing, the housing has a first wall and a second wall oppositely disposed, the positive terminal is disposed on the first wall, and the positive terminal is disposed on the second wall.
- the six walls of the hexahedral casing are divided into adjacent walls and opposite walls, and a cylindrical electrode assembly is used in the hexahedral casing, and the positive electrode tab and the negative electrode tab of the cylindrical electrode assembly are The positive terminal and the negative terminal on the two opposite walls of the hexahedral casing are respectively connected, so that the positive and negative electrodes of the hexahedral battery cell can be drawn from the opposite two walls, and the arrangement of the hexahedral casing and the cylindrical electrode assembly makes the electrode The contact area between the component and the casing is reduced.
- the heat transfer between the electrode assembly and the casing only relies on the tangent position between the cylinder and the hexahedron, which reduces the thermal diffusion of the electrode assembly, thereby reducing the cost of a battery.
- the thermal runaway of a single cell causes the possibility of thermal runaway of multiple battery cells, which improves the safety performance of the battery cells and prolongs the service life of the battery.
- the tabs of the cylindrical electrode assembly are respectively connected to the electrode terminals on the opposite first wall and the second wall at both ends of the cylinder, without winding the tabs to other walls, which improves the space utilization inside the battery cell efficiency; the lugs of the cylindrical electrode assembly are set at both ends of the cylinder, so there is no need for die cutting and winding alignment during processing, which effectively improves the production efficiency of the battery cell and reduces the manufacturing cost; and, except for the hexahedral shell There is also a remaining space outside the cylindrical electrode assembly, which can store the gas generated by the electrode assembly during the electrochemical reaction, avoiding the gas from causing the battery cell to bulge or break and causing safety problems, and improving the safety performance of the battery cell.
- the positive tab is connected to the positive terminal through a first connecting piece, and the negative tab is connected to the negative terminal through a second connecting piece.
- the tab is connected to the electrode terminal through a connector.
- the connector can electrically connect the tab to the electrode terminal without welding, which facilitates the production and processing of the battery cell;
- the positive and negative pole lugs of the cylindrical electrode assembly are respectively arranged at both ends of the cylinder, and the electrode terminals are also respectively arranged on the opposite walls of the hexahedral shell, so that the transfer distance of the connector is relatively short, and the connector can be saved.
- the occupied space improves the space utilization rate inside the battery cell.
- the battery cell includes: a plurality of cylindrical electrode assemblies, the plurality of cylindrical electrode assemblies are arranged side by side in the hexahedral casing along a first direction, and the first The direction is parallel to the first wall.
- a plurality of cylindrical electrode assemblies are arranged in the battery cell, and the cylindrical electrode assemblies are arranged side by side along a direction parallel to the first wall, that is, the plurality of cylindrical electrode assemblies in the hexahedral casing are arranged on the first side.
- the infiltration of the electrode assembly in the electrolyte is relatively consistent, which improves the consistency of the electrode assembly, thereby improving the stability of the battery cell.
- Electrochemical properties in addition, multiple electrode assemblies are arranged side by side so that the contact area between each cylindrical electrode assembly and between each cylindrical electrode assembly and the shell is very small.
- the housing includes: a housing and an end cover, the housing has at least one opening, the end cover covers the opening, the first wall and/or the second The second wall is the end cap.
- both the first wall and the second wall are the end covers, which are arranged at both ends of the housing.
- the first wall and the second wall opposite to each other among the six walls of the hexahedral shell are end covers, and the remaining four walls surround the shell with two upper and lower openings, that is, the shell has two opposite openings.
- the positive and negative poles of the hexahedral battery cell are drawn from the two opposite faces, so that the poles of the battery cell can be directly connected in the direction perpendicular to the end cap, without the need for converging parts, thus saving on
- the space for assembling battery cells perpendicular to the direction of the end cap helps to improve the space utilization inside the battery.
- the housing includes a side wall and a bottom wall, the side wall and the bottom wall are adjacent to each other, and the bottom wall is a wall with the largest area of the housing.
- the wall with the largest area in the casing of the battery cell is the bottom wall, that is, the battery cell is assembled in the battery in a flat manner.
- the axis of the cylindrical electrode assembly is parallel to
- the bottom wall, that is, the axis of the cylindrical electrode assembly is parallel to the horizontal plane.
- the cylindrical electrode assembly includes: a positive pole piece, a negative pole piece, and a spacer structure arranged between the positive pole piece and the negative pole piece, and the spacer structure is used for The space between the positive pole piece and the negative pole piece is configured, and the space is used for absorbing expansion and deformation of the cylindrical electrode assembly.
- a spacer structure is provided between the pole pieces of the cylindrical electrode assembly, and the spacer structure can form a reserved area between the pole pieces during the process of winding the pole pieces into a cylindrical electrode assembly. Therefore, after the electrode assembly expands and deforms in the electrochemical reaction, the reserved space can accommodate the expansion of the electrode assembly, so that the cylindrical electrode assembly can expand inward, reduce the degree of outward expansion of the electrode assembly, and reduce the The influence of the expansion and deformation of the electrode assembly on the casing makes it unnecessary to use additional end plates on the bottom wall and top wall of the casing to increase the strength of the battery cell, reduce the manufacturing cost of the battery cell and improve the stability and safety of the battery cell .
- the length h of the housing along the axial direction and the length t along the second direction satisfy the following formula:
- the diameter D of the cylindrical electrode assembly satisfies the following formula:
- t is the length of the housing along the second direction, 0.01mm ⁇ c1 ⁇ 5mm.
- the length of the housing along the first direction is 150-1200 mm.
- a battery including: a plurality of battery cells according to the first aspect or any possible implementation manner of the first aspect; and a box body, configured to accommodate the plurality of battery cells.
- the battery is assembled from battery cells that can reduce thermal diffusion and improve safety performance, helping to avoid thermal diffusion of the battery and improve the safety performance of the battery.
- the first battery cell and the second battery cell are arranged along the axial direction, and the negative terminal of the first battery cell is connected to the second battery cell.
- the positive terminals of the two battery cells are connected.
- the battery cells in the battery can move axially, that is, in the direction perpendicular to the end cap
- the direct connection between the electrode terminals and the electrode terminals saves the converging parts between the battery cells in the axial direction, and improves the space utilization ratio inside the battery.
- the first battery cell and the second battery cell among the plurality of battery cells are arranged in the box along the second direction.
- the battery cells are arranged along the second direction, that is, multiple battery cells are stacked on each other to form a battery through the wall with the largest area, so that the battery can accommodate more battery cells and increase the space inside the battery. utilization rate.
- the battery includes: a water-cooled plate disposed inside the box and attached to the third wall of the battery cell, the third wall is parallel to the axial direction and Connected to the first wall and the second wall.
- the third wall may be the bottom wall or the top wall of the housing, or may be the side wall of the housing.
- the water cooling plate is attached to the top wall or bottom wall of the battery cell, that is, the wall with the largest area, so as to increase the contact area between the water cooling plate and the battery cell, improve the cooling effect of the water cooling plate on the battery, and avoid the temperature of the battery cell
- the safety problem caused by too high temperature helps to improve the safety performance and life of the battery.
- the length H of the box in the second direction satisfies the following formula:
- m is the number of layers of the battery cells arranged in the second direction
- t is the length of the casing along the second direction, 10mm ⁇ c ⁇ 40mm, 1 ⁇ m ⁇ 8.
- an electric device including the battery in the second aspect or any possible implementation manner of the second aspect, where the battery is used to provide power for the electric device.
- a method for preparing a battery cell comprising: providing a hexahedral casing, the casing has a first wall and a second wall oppositely disposed, the first wall is provided with a positive terminal, and the second wall is provided with a positive terminal.
- a negative electrode terminal is provided on the wall;
- a cylindrical electrode assembly is provided, the cylindrical electrode assembly is arranged in the casing, and the axial direction of the cylindrical electrode assembly is perpendicular to the first wall or the second wall, so The positive pole tab of the cylindrical electrode assembly is arranged on the first end of the cylindrical electrode assembly and connected to the positive terminal, and the negative pole ear of the cylindrical electrode assembly is arranged on the second end of the cylindrical electrode assembly. terminal and connected with the negative terminal; the cylindrical electrode assembly is installed in the hexahedral casing.
- a battery cell preparation device including: providing a module for providing a hexahedral casing, the casing has a first wall and a second wall oppositely arranged, and a positive terminal is arranged on the first wall , a negative terminal is provided on the second wall; a cylindrical electrode assembly is provided, the cylindrical electrode assembly is arranged in the casing, and the axial direction of the cylindrical electrode assembly is perpendicular to the first wall or the The second wall, the positive pole lug of the cylindrical electrode assembly is arranged on the first end of the cylindrical electrode assembly and connected to the positive terminal, the negative pole lug of the cylindrical electrode assembly is arranged on the cylindrical electrode assembly The second end of the electrode assembly is connected to the negative terminal; an installation module is used to install the cylindrical electrode assembly in the hexahedral casing.
- a cylindrical electrode assembly is arranged in a battery cell with a hexahedral casing, and the cylindrical electrode assembly is placed without stacking in the hexahedral casing, so that between the cylindrical electrode assembly and the casing, the cylindrical electrode
- the contact area between the components is small, which can effectively control the thermal diffusion of the electrode components during thermal runaway, improve the safety performance of the battery cell and prolong the service life of the battery; in addition, this design can also make the battery cell with a hexahedral shell
- the electrode terminals are arranged on two opposite walls, and the internal electrode terminals of the battery cells can be directly connected to the tabs of the cylindrical electrode assembly, and the battery cells can be directly connected through the electrode terminals, without the need for connectors inside the battery cells and
- the confluence part between the battery cells reduces the manufacturing cost and effectively saves the space inside the battery along the direction perpendicular to the end caps of the battery cells.
- Fig. 1 is the structural representation of a kind of vehicle of the present application
- Fig. 2 is a schematic diagram of an exploded structure of a battery of the present application
- FIG. 3 is a schematic diagram of a partial structure of a battery cell of the present application.
- FIG. 4 is a schematic structural diagram of a battery cell according to an embodiment of the present application.
- FIG. 5 is a schematic cross-sectional view of the battery cell in FIG. 4;
- FIG. 6 is a schematic structural diagram of another battery cell according to the embodiment of the present application.
- FIG. 7 is a schematic cross-sectional view of the battery cell in FIG. 6;
- Fig. 8 is a schematic structural diagram of a casing according to an embodiment of the present application.
- Fig. 9 is a schematic top view of a battery according to an embodiment of the present application.
- Figure 10 is a schematic cross-sectional view of the battery in Figure 9;
- Fig. 11 is a schematic top view of another battery according to the embodiment of the present application.
- Figure 12 is a schematic cross-sectional view of the battery in Figure 11;
- Fig. 13 is a schematic structural diagram of an electrical device according to an embodiment of the present application.
- Fig. 14 is a schematic flowchart of a method for preparing a battery cell according to an embodiment of the present application.
- FIG. 15 is a schematic structural view of a battery cell manufacturing device according to an embodiment of the present application.
- a battery refers to a physical module including one or more battery cells to provide electrical energy.
- the battery mentioned in this application may include a battery module or a battery pack, and the like.
- Batteries generally include a case for enclosing one or more battery cells. The box can prevent liquid or other foreign objects from affecting the charging or discharging of the battery cells.
- the battery cells may include lithium-ion secondary batteries, lithium-ion primary batteries, lithium-sulfur batteries, sodium-lithium-ion batteries, sodium-ion batteries, or magnesium-ion batteries, which are not limited in this embodiment of the present application.
- a battery cell may also be referred to as a battery cell.
- the battery cell includes an electrode assembly and an electrolyte, and the electrode assembly is composed of a positive electrode sheet, a negative electrode sheet, and a separator.
- a battery cell works primarily by moving metal ions between the positive and negative plates.
- the positive electrode sheet includes a positive electrode current collector and a positive electrode active material layer.
- the positive electrode active material layer is coated on the surface of the positive electrode current collector.
- the current collector not coated with the positive electrode active material layer protrudes from the current collector coated with the positive electrode active material layer.
- the current collector coated with the positive electrode active material layer serves as the positive electrode tab.
- the material of the positive electrode current collector can be aluminum, and the positive electrode active material can be lithium cobaltate, lithium iron phosphate, ternary lithium or lithium manganate, etc.
- the negative electrode sheet includes a negative electrode current collector and a negative electrode active material layer.
- the negative electrode active material layer is coated on the surface of the negative electrode current collector.
- the current collector without the negative electrode active material layer protrudes from the current collector coated with the negative electrode active material layer.
- the current collector coated with the negative electrode active material layer serves as the negative electrode tab.
- the material of the negative electrode current collector may be copper, and the negative electrode active material may be carbon or silicon.
- the number of positive pole tabs is multiple and stacked together, and the number of negative pole tabs is multiple and stacked together.
- the material of the diaphragm can be polypropylene (Polypropylene, PP) or polyethylene (Polyethylene, PE).
- the electrode assembly may be a wound structure or a laminated structure, which is not limited in the embodiment of the present application.
- a plurality of battery cells are firstly integrated into a battery module, and then the battery module is installed in a battery box to form a battery pack.
- multiple battery cells can also be directly installed in the box to form a battery pack, eliminating the intermediate state of the battery module, thereby reducing the quality of the battery pack and increasing the energy density of the battery.
- the second packaging technology may also be referred to as a packaging technology from a battery cell to a battery pack (cell to pack) in the related art, and the battery pack may be referred to as a battery for short in this application.
- Conventional battery cells include cylindrical battery cells and prismatic battery cells (such as blade battery cells), where a prismatic battery cell typically has a square housing and an electrode assembly wound into an elliptical cylinder, a plurality of elliptical cylindrical electrodes Components are stacked in a square shell, and the positive and negative tabs of the elliptical cylindrical electrode assembly are obtained by die-cutting the pole piece, and are arranged on one end of the elliptical cylinder by winding and aligning, and are respectively connected to the positive and negative poles at one end of the elliptical cylindrical shell. terminal.
- the electrode assemblies are placed in a stacked manner, and there are obvious differences in the heights of the stacked electrode assemblies that are infiltrated by the electrolyte in the battery, resulting in different infiltration conditions of the electrode assemblies and poor consistency, which is not conducive to The electrochemical reaction of the battery proceeds stably.
- the stacked placement method also makes the contact area between the electrode assembly and the electrode assembly, and between the electrode assembly and the casing larger. After thermal runaway occurs in one electrode assembly, the heat is easily transferred to another electrode assembly or to another electrode assembly through the casing. The battery cell causes severe heat dissipation, which leads to thermal runaway of the entire battery.
- the electrode assembly will expand and deform during the electrochemical reaction, and the walls of the square casing are usually thin. Additional end plates are needed to improve the strength of the casing to resist the influence of the expansion and deformation of the electrode assembly on the walls of the square casing.
- the present application provides a technical solution, in which a cylindrical electrode assembly is arranged in a battery cell with a hexahedral casing, and the cylindrical electrode assembly is placed in the hexahedral casing without stacking, so that between the cylindrical electrode assembly and the casing,
- the contact area between the cylindrical electrode assemblies is small, which can effectively control the thermal diffusion of the electrode assemblies during thermal runaway, improve the safety performance of the battery cell and prolong the service life of the battery; in addition, this design can also make the battery with a hexahedral shell
- the electrode terminals of the battery cell are arranged on two opposite walls.
- the internal electrode terminals of the battery cell can be directly connected to the tabs of the cylindrical electrode assembly, and the battery cells can be directly connected through the electrode terminals, without the need for a battery inside the battery cell.
- the connection piece and the confluence part between the battery cells reduce the manufacturing cost and effectively save the space inside the battery along the direction perpendicular to the end cap of the battery cells.
- the vehicle 1 can be a fuel vehicle, a gas vehicle or a new energy vehicle, and the new energy vehicle can be a pure electric vehicle, a hybrid vehicle or an extended-range vehicle, etc. .
- a motor 11 , a controller 12 and a battery 10 can be arranged inside the vehicle 1 , and the controller 12 is used to control the battery 10 to supply power to the motor 11 .
- the battery 10 may be provided at the bottom or front or rear of the vehicle 1 .
- the battery 10 can be used for power supply of the vehicle 1 , for example, the battery 10 can be used as an operating power source of the vehicle 1 , for a circuit system of the vehicle 1 , for example, for starting, navigating and running power requirements of the vehicle 1 .
- the battery 10 can not only be used as an operating power source for the vehicle 1 , but can also be used as a driving power source for the vehicle 1 , replacing or partially replacing fuel or natural gas to provide driving power for the vehicle 1 .
- the battery may include multiple battery cells, wherein the multiple battery cells may be connected in series, in parallel or in parallel, and the hybrid connection refers to a mixture of series and parallel connections. Batteries can also be called battery packs.
- a plurality of battery cells can be connected in series, parallel or mixed to form a battery module, and then a plurality of battery modules can be connected in series, parallel or mixed to form a battery. That is to say, multiple battery cells can directly form a battery, or form a battery module first, and then form a battery from the battery module.
- the battery 10 may include a plurality of battery cells 20 .
- the battery 10 may further include a 100 (or called a cover), the inside of the box 100 is a hollow structure, and a plurality of battery cells 20 are accommodated in the box 100 .
- the box body 100 may include two parts, referred to here as a first part 111 and a second part 112 respectively, and the first part 111 and the second part 112 are fastened together.
- the shapes of the first part 111 and the second part 112 may be determined according to the combined shape of a plurality of battery cells 20, and each of the first part 111 and the second part 112 may have an opening.
- both the first part 111 and the second part 112 can be hollow cuboids and each has only one face as an open face, the opening of the first part 111 and the opening of the second part 112 are arranged oppositely, and the first part 111 and the second part 112 are interlocked combined to form a box 100 with a closed chamber.
- a plurality of battery cells 20 are combined in parallel, in series or in parallel and placed in the box 100 formed by fastening the first part 111 and the second part 112 .
- the battery 10 may also include other structures, which will not be repeated here.
- the battery 10 may also include a confluence part, which is used to realize electrical connection between a plurality of battery cells 20 , such as parallel connection, series connection or mixed connection.
- the current-combining component can realize the electrical connection between the battery cells 20 by connecting the electrode terminals of the battery cells 20 .
- the bus member may be fixed to the electrode terminal of the battery cell 20 by welding. The electric energy of the plurality of battery cells 20 can be further drawn out through the case body 100 through the conductive mechanism.
- the conduction means can also belong to the current-collecting part.
- the number of battery cells 20 can be set to any value. Multiple battery cells 20 can be connected in series, in parallel or in parallel to achieve greater capacity or power.
- FIG. 3 it is a schematic structural diagram of a battery cell 20 of the present application.
- the battery cell 20 includes one or more electrode assemblies 22 , a casing 21
- the casing 21 includes a casing 211 and an end cap 212 .
- the walls of the housing 211 and the end cover 212 are both referred to as walls of the housing 21 .
- the casing 211 is determined according to the combined shape of one or more electrode assemblies 22 .
- the casing 211 shown in FIG. 3 may be a hollow cuboid.
- One surface of the casing 211 has an opening so that one or more electrode assemblies 22 can be placed in the casing 211 .
- the end cap 212 covers the opening and is connected with the casing 211 to form a closed cavity for placing the electrode assembly 22 .
- the casing 211 is filled with electrolyte, such as electrolytic solution.
- the battery cell 20 may further include two electrode terminals 214 , and the two electrode terminals 214 may be disposed on the end cap 212 .
- the end cap 212 is usually in the shape of a flat plate, and two electrode terminals 214 are fixed on the flat surface of the end cap 212, and the two electrode terminals 214 are positive electrode terminals 214a and negative electrode terminals 214b respectively.
- Each electrode terminal 214 is respectively provided with a connecting member 23 , or also called a current collecting member 23 , which is located between the end cap 212 and the electrode assembly 22 for electrically connecting the electrode assembly 22 and the electrode terminal 214 .
- each electrode assembly 22 has a first tab 221a and a second tab 222a.
- the polarities of the first tab 221a and the second tab 222a are opposite.
- the first tab 221a is a positive tab
- the second tab 222a is a negative tab.
- the first tab 221a of one or more electrode assemblies 22 is connected to an electrode terminal through a connecting member 23, and the second tab 222a of one or more electrode assemblies 22 is connected to another electrode terminal through another connecting member 23.
- the positive electrode terminal 214a is connected to the positive electrode tab 221a through one connecting member 23
- the negative electrode terminal 214b is connected to the negative electrode tab 222a through another connecting member 23 .
- the electrode assembly 22 can be arranged as a single one or in multiples. As shown in FIG. 3 , four independent electrode assemblies 22 are arranged in the battery cell 20 .
- a pressure relief mechanism 213 may also be provided on one wall of the battery cell 20 .
- the pressure relief mechanism 213 is activated to release the internal pressure or temperature when the internal pressure or temperature of the battery cell 20 reaches a threshold.
- the present embodiment provides a battery cell, which can reduce thermal diffusion during thermal runaway of the electrode assembly, improve the safety of the battery cell and prolong the service life of the battery.
- FIG. 4 shows a schematic structural diagram of a battery cell 20 according to an embodiment of the present application.
- the battery cell 20 includes:
- a hexahedral housing 21, the housing 21 has a first wall 21a and a second wall 21b oppositely arranged, the first wall 21a is provided with a positive terminal 214a, and the second wall 21b is provided with a negative terminal 214b;
- the cylindrical electrode assembly 22 is arranged in the casing 21, the axial direction of the cylindrical electrode assembly 22 is perpendicular to the first wall 21a or the second wall 21b, and the positive electrode tab 221a of the cylindrical electrode assembly 22 is arranged on the cylindrical electrode assembly 22.
- the first end 22a is connected to the positive terminal 214a, and the negative tab 222a of the cylindrical electrode assembly 22 is disposed on the second end 22b of the cylindrical electrode assembly 22 and connected to the negative terminal 214b.
- the hexahedral housing 21 includes six walls: 21a, 21b, 21c, 21d, 21e and 21f, wherein the six walls can be divided into adjacent walls and opposite walls.
- the adjacent walls are, for example, the first wall 21a and the third wall 21c
- the opposite walls are, for example, the first wall 21a and the second wall 21b.
- the remaining four walls are side walls of a hexahedron.
- two adjacent walls in the hexahedral housing 21 are perpendicular to each other.
- the electrode assembly 22 is wound into a cylindrical structure and arranged in the hexahedral casing 21.
- the tabs 221a and 222a of the electrode assembly 22 are respectively located at the two ends of the cylinder, respectively facing the first wall 21a and the second wall 21a of the hexahedral casing.
- the electrode terminals 214a and 214b on the second wall 21b are connected.
- Fig. 5 is a cross-sectional view of the battery cell 20 in Fig. 4 along the direction A-A'.
- the cylindrical electrode assembly 22 is tangent to the four walls (21c, 21d, 21e, 21f) on the hexahedral shell 21 parallel to the cylinder axis.
- a battery cell 20 is obtained by assembling a cylindrical electrode assembly 22 in a hexahedral casing 21 .
- the positive pole tab 221a and the negative pole tab 222a of the cylindrical electrode assembly 22 are respectively connected to the positive terminal 214a and the negative pole terminal 214b on the two walls 21a and 21b opposite to the hexahedral casing 21, so that the hexahedral battery cell 20
- the positive and negative electrodes can be drawn from the first wall 21a and the second wall 21b which are arranged oppositely.
- the arrangement of the hexahedral casing 21 and the cylindrical electrode assembly 22 makes the contact area between the electrode assembly 22 and the casing 21 reduce.
- the heat transfer between the electrode assembly 22 and the casing 21 only relies on the tangential position between the cylinder and the hexahedron, which reduces the thermal diffusion of the electrode assembly 22, thereby reducing the thermal runaway of one battery cell 20 and causing multiple battery cells.
- the possibility of thermal runaway 20 improves the safety performance of the battery cell 20 and prolongs the service life of the battery 10 .
- the tabs 221a and 222a of the cylindrical electrode assembly 22 are respectively connected to the electrode terminals 214 on the opposite first wall 21a and the second wall 21b at the two ends (22a and 22b) of the cylinder, without connecting the tabs 221a and 222a wraps around to other walls, improving the space utilization ratio inside the battery cell 20 .
- the tabs 221a and 222a of the cylindrical electrode assembly 22 are arranged at both ends of the cylinder (22a and 22b), so there is no need for die cutting and winding alignment during processing, which effectively improves the production efficiency of the battery cell 20 and reduces the manufacturing cost.
- the hexahedral casing 21 also has a remaining space, which can store the gas generated by the electrode assembly 22 in the electrochemical reaction, so as to prevent the gas from causing the battery cell 20 to bulge or damage, thereby causing safety problems and improving the battery life.
- the safety performance of the battery cell 20 is also possible.
- the positive tab 221a is connected to the positive terminal 214a through the first connecting piece 23a
- the negative tab 222a is connected to the negative terminal 214b through the second connecting piece 23b.
- the tabs 221a and 222a are connected to the electrode terminals 214 through the connecting piece 23.
- the connecting piece 23 can electrically connect the tabs 221a and 222a to the electrode terminals 214a and 214b without welding.
- the positive electrode tab 221a and the negative electrode tab 222a of the cylindrical electrode assembly 22 are respectively arranged on the two ends 22a and 22b of the cylinder, and the electrode terminals 214a and 214b are also arranged on the hexahedron
- the opposite walls 21 a and 21 b of the housing 21 make the transition distance of the connector 23 shorter, which can save the space occupied by the connector 23 and improve the space utilization rate inside the battery cell 20 .
- the positive tab 221a is directly connected to the positive terminal 214a
- the negative tab 222a is directly connected to the negative terminal 214b.
- the positive electrode tab 221a and the negative electrode tab 222a can form connection areas at both ends of the cylindrical electrode assembly 22 through processes such as kneading or leveling, and the connection areas are directly connected, that is, the tabs 221a and 222a are made Electrical connection is made with the electrode terminals 214a and 214b.
- the connecting piece 23 by avoiding the use of the connecting piece 23 , the space occupied by the connecting piece 23 inside the battery cell 20 is further saved, and the utilization rate of the space inside the battery cell 20 is further improved.
- FIG. 6 is another schematic structural view of the battery cell 20 of the present application.
- Fig. 7 is a cross-sectional view of the battery cell 20 shown in Fig. 6 along the direction A-A'.
- the battery cell 20 includes: a plurality of cylindrical electrode assemblies 22 , and the plurality of cylindrical electrode assemblies 22 are arranged side by side in a hexahedral casing 21 along a first direction. One direction is parallel to the first wall 21a.
- one battery cell 20 includes 1-5 electrode assemblies 22 .
- a plurality of cylindrical electrode assemblies 22 are not stacked and placed side by side in the casing 21. Therefore, in the state where the axial direction of the cylindrical electrode assemblies 22 is parallel to the horizontal plane, the electrode assemblies 22 in the electrolyte The wetting condition is relatively consistent, which improves the consistency of the electrode assembly 22, thereby improving the electrochemical performance of the battery cell 20; in addition, a plurality of electrode assemblies 22 are arranged side by side so that between each cylindrical electrode assembly 22, each cylindrical electrode assembly 22 The contact area between the electrode assembly 22 and the casing 21 is very small.
- the housing 21 includes: a housing 211 and an end cover 212, the housing 21 has at least one opening, the end cover 212 covers the opening, the first wall 21a and/or The second wall 21b is an end cover 212 .
- the first wall 21a is the end cap 212
- the second wall 21b, the third wall 21c, the fourth wall 21d, the fifth wall 21e and the sixth wall 21f of the hexahedron shell are processed to have A hexahedral structure with an opening, that is, the shell 211 has five walls
- the first wall 21a can cover the opening to form the shell 21, the opening can make the electrode assembly installed in the shell and provide an operating space for the processing of the end cap and the electrode assembly .
- the electrode assembly 22 is installed into the casing 211 from the opening, and is electrically connected with the first wall 21a at the opening to form an electrical connection; the electrode assembly 22 and the second wall 21b are welded or other penetrating processing to form an electrical connection.
- both the first wall 21 a and the second wall 21 b are end caps 212 disposed at both ends of the casing 21 .
- the third wall 21c, the fourth wall 21d, the fifth wall 21e and the sixth wall 21f of the hexahedron shell are processed into the four side walls of the hollow hexahedron structure to form the shell 211, and the first wall 21a Both the second wall and the second wall 21b are end caps 212 for covering the opening of the housing 211 to form the shell 21 .
- the casing 21 has two opposite end caps 212, and the positive and negative poles of the battery cell 20 in the shape of a hexahedron are drawn from the two opposite faces, so that the electrode terminals 214 of the battery cell 20 can be vertically
- the direction of the end cover 212 is directly connected without the need for confluence parts, thereby saving the space for assembling the battery cells 20 in the direction perpendicular to the end cover 212, and the housing 211 has two openings, which is more convenient for the processing of the battery cells, and at the same time Help to improve the space utilization ratio inside the battery 10 .
- the housing 211 includes a side wall and a bottom wall, the side wall and the bottom wall are arranged adjacently, and the bottom wall is the wall with the largest area of the housing 211 .
- the four walls that make up the housing 211 include two side walls 21c and 21e, a bottom wall 21d and a top wall 21e, and the bottom wall 21d is equal in area to the top wall 21e. is the wall with the largest area of the casing 211 .
- the wall with the largest area in the casing 211 of the battery cell 21 is used as the bottom wall 21d, that is, the battery cell 21 is assembled in the battery 10 in a flat manner, and the cylindrical electrode assembly 22 in this placed state
- the axis is parallel to the bottom wall 21d, that is, the axis of the cylindrical electrode assembly 22 is parallel to the horizontal plane.
- the electrode assemblies 22 are arranged side by side without stacking, which helps to improve the consistency of the electrode assembly 22 .
- the cylindrical electrode assembly 22 includes: a positive pole piece, a negative pole piece, and a spacer structure arranged between the positive pole piece and the negative pole piece, and the spacer structure is used to construct the positive pole piece and the negative pole piece.
- the space between the pole pieces is used to absorb the expansion and deformation of the columnar electrode assembly 22 .
- the spacer structure can be constructed through the structure on the electrode sheet or the diaphragm, so that there is a reserved space inside the electrode assembly 22 wound into a cylindrical shape; it can also be provided with other structural structures on the electrode sheet or the diaphragm.
- a spacer structure can be constructed between the positive pole piece and the negative pole piece by embossing a pattern on the electrode pole piece or diaphragm, such as bumps or pits. At this time, the spacer structure is the pole piece or diaphragm. a part of.
- the spacer structure may be constructed by brushing polycarbosilane (Polysilacarbosilane, PCS) on the electrode sheet or diaphragm.
- a spacer structure is provided between the pole pieces of the cylindrical electrode assembly 22, and the spacer structure can form a reserved space between the pole pieces during the process of winding the pole pieces into a cylindrical electrode assembly 22. Therefore, after the electrode assembly 22 expands and deforms in the electrochemical reaction, the reserved space can accommodate the expansion of the electrode assembly 22, so that the cylindrical electrode assembly 22 can expand inwardly, reducing the degree of outward expansion of the electrode assembly 22 , reducing the influence of the expansion and deformation of the electrode assembly 22 on the casing 211, so that the bottom wall 21d and the top wall 21e of the casing 211 do not need to use additional end plates to increase the strength of the battery cell 20, and reduce the manufacturing cost of the battery cell 20 at the same time Improve the stability and safety of the battery cell 20 .
- the length h of the casing 211 along the axial direction and the length t along the second direction satisfy the following formula:
- the second direction is a direction perpendicular to the bottom wall 21d.
- part of the space can be reserved for the cylindrical electrode assembly 22 in the hexahedral shell 21 , further reducing the influence of the expansion and deformation of the electrode assembly 22 on the shell 21 .
- the diameter D of the cylindrical electrode assembly 22 satisfies the following formula:
- t is the length of the housing 211 along the second direction, 0.01mm ⁇ c1 ⁇ 5mm, preferably 0.8mm ⁇ c1 ⁇ 2mm.
- the length of the casing 21 along the first direction is 150-1200 mm, preferably 280-450 mm.
- the battery cell 20 in the embodiment of the present application has been introduced above with reference to FIGS. arrangement.
- FIG. 9 is a schematic top view of a battery 10 of the present application.
- Fig. 10 is a schematic cross-sectional view of the battery 10 in Fig. 9 along the direction A-A'.
- the battery 10 includes: a plurality of battery cells 20 , and a case body 100 for accommodating the plurality of battery cells 20 .
- the battery 10 is assembled from battery cells 20 that can reduce thermal diffusion and improve safety performance, which helps avoid thermal diffusion of the battery 10 and improves the safety performance of the battery 10 .
- the first battery cell 201 and the second battery cell 202 are arranged axially in the case 100, and the negative terminal 214b of the first battery cell 201 is connected to the second battery cell 201.
- the positive terminal 214a of the battery cell 202 is connected.
- the plurality of battery cells 20 are arranged in columns along the axial direction in the case 100, and arranged in rows along the first direction.
- the negative terminal 214 b of the first battery cell 201 is connected to the positive terminal 214 a of the second battery cell 202 . That is, multiple rows of battery cells 20 are assembled in the axial direction by directly connecting the electrode terminals 214 to the plurality of battery cells 20 in the axial direction.
- the assembly of multiple rows of battery cells 20 in the direction perpendicular to the axial direction is realized by connecting the flow-combining components.
- the battery cell 20 in the battery 10 can pass through in the axial direction.
- the electrode terminals 214 are directly connected, thereby eliminating the need for a confluence component between the battery cells 20 in the axial direction, and improving the space utilization ratio inside the battery 10 .
- the number of rows of the plurality of battery cells 20 arranged in the axial direction is less than the number of columns of the plurality of battery cells 20 arranged in the first direction.
- FIG. 11 is another schematic top view of a battery 10 of the present application.
- Fig. 12 is a schematic cross-sectional view of the battery 10 in Fig. 11 along the direction A-A'.
- the number of rows of battery cells 20 arranged in the axial direction is greater than or equal to the number of columns of battery cells 20 arranged in the first direction.
- the first battery cells 201 and the second battery cells 202 of the plurality of battery cells 20 are arranged in the case 100 along a second direction, and the second direction is perpendicular to the axial direction and perpendicular to the first direction.
- the battery 10 includes multiple layers of battery cells 20 in the second direction.
- the battery 10 includes two layers of battery cells 20 in the second direction.
- the plurality of battery cells in the box can be arranged in both the axial direction and the second direction, or only one of them. No restrictions.
- the bottom wall 21d of the first battery cell 201 may be in direct contact with the top wall 21e of the second battery cell 202 , or may be in contact between the bottom wall 21d of the first battery cell 201 and the top wall of the second battery cell 202 . 21e directly set structural glue or heat insulation pad, etc.
- the battery cells are arranged along the second direction, that is, multiple battery cells are stacked on each other to form a battery through the wall with the largest area, so that the battery can accommodate more battery cells and increase the space inside the battery. utilization rate.
- the battery 10 includes: a water cooling plate 122 disposed inside the case 100 and attached to the third wall 21c of the battery cell 20, the third wall 21c is parallel to the axial direction and is parallel to the first The wall 21a is connected to the second wall 21b.
- the third wall 21 c may be the top wall or the bottom wall of the housing 211 , and may also be a side wall of the housing 211 .
- the water cooling plate 122 is attached to the top wall or the bottom wall of the casing 211 , that is, the wall with the largest area.
- the water cooling plate 122 is arranged between the layers of the battery cells 20 .
- the heat dissipation caused by thermal runaway is further reduced by installing the water cooling plate 122 in the battery 10, and the cooling effect of the water cooling plate 122 on the battery 10 is improved by increasing the contact area between the water cooling plate 211 and the battery cell 20 As a result, the safety problem caused by the overheating of the battery cell 20 can be avoided, and the safety performance and service life of the battery 10 can be improved.
- the length H of the box body 100 in the second direction satisfies the following formula:
- m is the number of layers of the plurality of battery cells 20 arranged in the second direction
- t is the length of the casing along the second direction, 10mm ⁇ c ⁇ 40mm, 1 ⁇ m.
- an embodiment of the present application also provides an electrical device 1300 , which may include the battery 10 in the foregoing embodiments, and the battery 10 is used to provide electrical energy to the electrical device 1300 .
- the electrical device 1300 may be a vehicle 1 , a ship or a spacecraft.
- the battery cell 20, the battery 10, and the electrical device 1300 of the embodiment of the present application are described above, and the method and equipment for preparing the battery cell 20 of the embodiment of the present application will be described below.
- FIG. 14 shows a schematic flowchart of a method 300 for preparing a battery cell 20 according to an embodiment of the present application. As shown in FIG. 14 , the method 400 may include the following steps.
- the casing 21 has a first wall 21a and a second wall 21b opposite to each other, the first wall 21a is provided with a positive terminal 214a, and the second wall 21b is provided with a negative terminal 214b.
- the cylindrical electrode assembly 22 is arranged in the casing 21, the axial direction of the cylindrical electrode assembly 22 is perpendicular to the first wall 21a or the second wall 21b, and the positive electrode tab 221a of the cylindrical electrode assembly 22
- the negative tab 222a of the cylindrical electrode assembly 22 is disposed on the second end 22b of the cylindrical electrode assembly 22 and connected to the negative terminal 214b.
- FIG. 15 shows a schematic block diagram of an apparatus 500 for preparing a battery cell 20 according to an embodiment of the present application.
- the device 500 for preparing a battery may include: a providing module 501 and an installation module 502 .
- the providing module 501 is used to provide the hexahedral housing 21, the housing 21 has a first wall 21a and a second wall 21b oppositely arranged, the positive terminal 214a is provided on the first wall 21a, and the negative terminal 214b is provided on the second wall 21b;
- a cylindrical electrode assembly 22 is provided, the cylindrical electrode assembly 22 is arranged in the housing 21, the axial direction of the cylindrical electrode assembly 22 is perpendicular to the first wall 21a or the second wall 21b, and the positive electrode tab 221a of the cylindrical electrode assembly 22 is arranged on The first end 22a of the cylindrical electrode assembly 22 is connected to the positive terminal 214a, and the negative tab 222a of the cylindrical electrode assembly 22 is disposed on the second end 22b of the cylindrical electrode assembly 22 and connected to the negative terminal 214b.
- the installation module 502 is used for installing the cylindrical electrode assembly 22 in the hexahedral casing 21 .
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Abstract
Description
Claims (17)
- 一种电池单体,其特征在于,所述电池单体包括:六面体外壳,所述外壳具有相对设置的第一壁和第二壁,所述第一壁上设置有正极端子,所述第二壁上设置有负极端子;圆柱状电极组件,所述圆柱状电极组件设置于所述外壳中,所述圆柱状电极组件的轴向垂直于所述第一壁或所述第二壁,所述圆柱状电极组件的正极极耳设置于所述圆柱状电极组件的第一端并与所述正极端子连接,所述圆柱状电极组件的负极极耳设置于所述圆柱状电极组件的第二端并与所述负极端子连接。
- 根据权利要求1所述的电池单体,其特征在于,所述正极极耳通过第一连接件与所述正极端子连接,所述负极极耳通过第二连接件与所述负极端子连接。
- 根据权利要求1所述的电池单体,其特征在于,所述电池单体包括:多个所述圆柱状电极组件,多个所述圆柱状电极组件在所述六面体外壳中沿第一方向并列设置,所述第一方向平行于所述第一壁。
- 根据权利要求3所述的电池单体,其特征在于,所述外壳包括:壳体和端盖,所述壳体具有至少一个开口,所述端盖盖合所述开口,所述第一壁和/或所述第二壁为所述端盖。
- 根据权利要求4所述的电池单体,其特征在于,所述壳体包括侧壁和底壁,所述侧壁和所述底壁相邻设置,所述底壁为所述壳体面积最大的壁。
- 根据权利要求1-5中任一项所述的电池单体,其特征在于,所述圆柱状电极组件包括:正极极片、负极极片以及设置于所述正极极片与所述负极极片之间的间隔结构,所述间隔结构用于构造所述正极极片与所述负极极片之间的间隔,所述间隔用于吸收所述圆柱状电极组件的膨胀变形。
- 根据权利要求4或5所述的电池单体,其特征在于,所述壳体沿所述轴向的长度h与沿第二方向的长度t满足下式:h=n*t’其中,n为所述圆柱状电极组件的数量,n≥1,t’=t±20mm,所述第二方向垂直于所述轴向和所述第一方向。
- 根据权利要求7所述的电池单体,其特征在于,所述圆柱状电极组件的直径D满足下式:D=t–c1其中,t为所述壳体沿所述第二方向的长度,0.01mm≤c1≤5mm。
- 根据权利要求3-8中任一项所述的电池单体,其特征在于,所述壳体沿所述第一方向的长度为150-1200mm。
- 一种电池,其特征在于,包括:多个如权利要求1-9中任一项所述的电池单体;箱体,用于容纳多个所述电池单体。
- 根据权利要求10所述的电池,其特征在于,多个所述电池单体中的第一电池单体和第二电池单体在所述箱体中沿所述轴向排列,所述第一电池单体的负极端子与所述第二电池单体的正极端子连接。
- 根据权利要求10所述的电池,其特征在于,多个所述电池单体中的第一电池单体和第二电池单体在所述箱体中沿所述第二方向排列。
- 根据权利要求10所述的电池,其特征在于,所述电池包括:水冷板,设置于所述箱体内部且与所述电池单体的第三壁附接,所述第三壁平行于所述轴向并与所述第一壁和所述第二壁连接。
- 根据权利要求12所述的电池,其特征在于,所述箱体在所述第二方向上的长度H满足下式:H–c=m*t其中,m为所述多个所述电池单体在所述第二方向上排列的层数,t为所述壳体沿所述第二方向的长度,10mm≤c≤40mm,1≤m≤8。
- 一种用电装置,其特征在于,包括如权利要求10-14中任一项所述的电池,所述电池用于为所述用电装置供电。
- 一种电池单体的制备方法,其特征在于,包括:提供六面体外壳,所述外壳具有相对设置的第一壁和第二壁,所述第一壁上设置有正极端子,所述第二壁上设置有负极端子;提供圆柱状电极组件,所述圆柱状电极组件设置于所述外壳中,所述圆柱状电极组件的轴向垂直于所述第一壁或所述第二壁,所述圆柱状电极组件的正极极耳设置于 所述圆柱状电极组件的第一端并与所述正极端子连接,所述圆柱状电极组件的负极极耳设置于所述圆柱状电极组件的第二端并与所述负极端子连接;将所述圆柱状电极组件安装于所述六面体外壳中。
- 一种电池单体的制备装置,其特征在于,包括:提供模块,用于提供六面体外壳,所述外壳具有相对设置的第一壁和第二壁,所述第一壁上设置有正极端子,所述第二壁上设置有负极端子;提供圆柱状电极组件,所述圆柱状电极组件设置于所述外壳中,所述圆柱状电极组件的轴向垂直于所述第一壁或所述第二壁,所述圆柱状电极组件的正极极耳设置于所述圆柱状电极组件的第一端并与所述正极端子连接,所述圆柱状电极组件的负极极耳设置于所述圆柱状电极组件的第二端并与所述负极端子连接;安装模块,用于将所述圆柱状电极组件安装于所述六面体外壳中。
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