WO2023063876A1 - Dispositif applicateur de produit cosmétique et similaire - Google Patents

Dispositif applicateur de produit cosmétique et similaire Download PDF

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Publication number
WO2023063876A1
WO2023063876A1 PCT/SG2022/050589 SG2022050589W WO2023063876A1 WO 2023063876 A1 WO2023063876 A1 WO 2023063876A1 SG 2022050589 W SG2022050589 W SG 2022050589W WO 2023063876 A1 WO2023063876 A1 WO 2023063876A1
Authority
WO
WIPO (PCT)
Prior art keywords
applicator device
twisted blade
cosmetic applicator
elongated core
twisted
Prior art date
Application number
PCT/SG2022/050589
Other languages
English (en)
Inventor
Weixiong Li
Original Assignee
Kindu Packing Pte. Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kindu Packing Pte. Ltd. filed Critical Kindu Packing Pte. Ltd.
Publication of WO2023063876A1 publication Critical patent/WO2023063876A1/fr

Links

Classifications

    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B9/00Arrangements of the bristles in the brush body
    • A46B9/02Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups
    • A46B9/021Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups arranged like in cosmetics brushes, e.g. mascara, nail polish, eye shadow
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D40/00Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
    • A45D40/26Appliances specially adapted for applying pasty paint, e.g. using roller, using a ball
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B9/00Arrangements of the bristles in the brush body
    • A46B9/02Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups
    • A46B9/026Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups where the surface of the brush body or carrier is not in one plane, e.g. not flat
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D2200/00Details not otherwise provided for in A45D
    • A45D2200/10Details of applicators
    • A45D2200/1009Applicators comprising a pad, tissue, sponge, or the like

Definitions

  • the present disclosure generally relates to a cosmetic applicator device and in particular a cosmetic applicator device comprising an improved brush member.
  • Conventional cosmetic applicator device for applying cosmetic compositions onto lips, eyelashes, eyebrows, and other parts of a human body
  • a cosmetic container e.g., a vessel or tube containing the cosmetic compositions and substances
  • Such technical disadvantages have become apparent as the types of cosmetic products get more diverse, e.g., with a diverse range of viscosity, stickiness, density, and friction properties.
  • the conventional designs are often configured to comprise a flocking brush head made up of cotton wrapped round the tip of an elongated core (e.g., a stick -like structure) or bristles planted/glued around the tip of the elongated core or any other processes that depose many small fiber particles (flock) onto the tip of the elongated core.
  • a flocking brush head made up of cotton wrapped round the tip of an elongated core (e.g., a stick -like structure) or bristles planted/glued around the tip of the elongated core or any other processes that depose many small fiber particles (flock) onto the tip of the elongated core.
  • Such brushes are often not able to adequately cater to the needs of different cosmetic applications, because the cosmetic compositions/substances required might have diverse properties and the shapes of lips can be irregular and various. For certain shapes of lip, such lip brushes are inefficient in transferring the cosmetic products from the brushes onto the lip surfaces.
  • cotton-made brushes often retain an excessive amount of cosmetic products among the cotton fibers which cannot be easily transferred or removed, unnecessarily wasting cosmetic products.
  • their bristles if not bundled tightly enough, might shed over time.
  • the shedding problem of the conventional brushes can gradually get worse because washing and drying the brushes gradually weaken the glue that binds the bristles to the elongated core.
  • the potential toxicity of glue should not be overlooked especially in consideration of the fact that these makeup brushes are used daily and for a long period of time. Similar problems are also observed in makeup brushes for eyelashes and eyebrows, which in general also adopt the conventional structure made of the central core and the bristles/spikes stand on end.
  • the present disclosure contemplates that it would be desirous to provide a cosmetic applicator device and the like which may at least alleviate or mitigate the aforementioned technical problems.
  • a cosmetic applicator device for applying a composition, comprising a brush member (10), wherein the brush member (10) comprises an elongated core (11) and a plurality of twisted blade members (12); wherein each twisted blade member (12) is configured to comprise: a fixed edge (121), wherein the each twisted blade member (12) is attached at the fixed edge (121) onto the elongated core (11), a free edge (122), a root end (123), and a tip end (124); wherein there is a first continuous twist (125) between the root end (123) and the tip end (124), and the fixed edge (121) is configured to be spirally located around the elongated core (11) from the root end (123) to the tip end (124).
  • the fixed edge (121) and the free edge (122) converges at both the root end (123) and the tip end (124).
  • the twisted blade member (12) is configured to have a thickness (127) gradually decreasing from the fixed edge (121) to the free edge (122).
  • the twisted blade member (12) is configured to have a thickness (127) gradually increasing from the fixed edge (121) to the free edge (122). [0011] In some embodiments, the twisted blade member (12) is configured to have a width (128) gradually increasing from the root end (123) first, and then gradually decreasing till the tip end (124).
  • the plurality of twisted blade members (12) is equally spaced apart from one another about the elongated core (11).
  • each twisted blade member is configured to comprise one or more grooves (129).
  • the groove (129) is configured to take a V-shape, a U- shape, a semicircular arc shape, a rectangular shape or a trapezoidal shape.
  • the groove (129) is configured to cut through the twisted blade member (12) from the free edge (122) to the fixed edge (121).
  • the adjacent grooves (129) from the plurality of twisted blade members (12) are configured to be on a groove plane (130).
  • the groove plane (130) is configured to have an angle between 0 and 90 degrees with respect to horizontal plane.
  • the plurality of twisted blade members (12) comprises at least twelve twisted blade members (12).
  • the elongated core (11) and a plurality of twisted blade members (12) are integrally formed.
  • the elongated core (11) and a plurality of twisted blade members (12) are made of a material selected from the group consisting of thermoplastic polymer, thermoplastic elastomer polymer, vulcanized rubber, polyethylene, and polypropylene.
  • the elongated core (11) is configured to have a higher rigidity than the twisted blade member (12).
  • the free edge (122) is configured to comprise a blade peak (131), wherein the width (128) of the twisted blade member (12) is the largest at the blade peak (131).
  • the blade peak (131) is sharp, blunt or round.
  • the first continuous twist (125) comprises a first segment
  • the first continuous twist is configured to gradually curve and twist away from the elongated core (11) starting from the root end (123) in the first segment (125a), and the first continuous twist (125) is configured to gradually curve and twist towards the elongated core (11) approaching the tip end (124) in the second segment (125b).
  • the brush member (10) is configured to have a rigidity of lOHA to 50HA.
  • each twisted blade member (12) is configured to have a thickness of 0.1mm to 0.35mm.
  • Figure la shows a side view of a brush member (10) of the cosmetic applicator device according to an embodiment of the present invention.
  • Figure lb shows atop view of a brush member (10) according to an embodiment of the present invention.
  • Figure 1c shows a front side view of an elongated core (11) with a single twisted blade member (12) according to an embodiment of the present invention.
  • Figure Id shows a back side view of an elongated core (11) with a single twisted blade member (12) according to an embodiment of the present invention.
  • Figure le shows a top view of an elongated core (11) with a single twisted blade member (12) according to an embodiment of the present invention.
  • Figure 2a shows a top view of a brush member (10) according to the first embodiment of the present invention.
  • Figure 2b shows a top view of a brush member (10) according to the second embodiment of the present invention.
  • Figure 2c shows a top view of a brush member (10) according to the third embodiment of the present invention.
  • Figure 2d shows a top view of a brush member (10) according to the fourth embodiment of the present invention.
  • Figure 3a shows a side view of a brush member (10) according to the first embodiment of the present invention.
  • Figure 3b shows a side view of a brush member (10) according to the second embodiment of the present invention.
  • Figure 3c shows a side view of a brush member (10) according to the third embodiment of the present invention.
  • Figure 3d shows a side view of a brush member (10) according to the fourth embodiment of the present invention.
  • Figure 4a shows a cross-sectional side view of a brush member (10) according to the first embodiment of the present invention.
  • Figure 4b shows a cross-sectional side view of a brush member (10) according to the second embodiment of the present invention.
  • Figure 4c shows a cross-sectional side view of a brush member (10) according to the third embodiment of the present invention.
  • Figure 4d shows a cross-sectional side view of a brush member (10) according to the fourth embodiment of the present invention.
  • Figure 5a shows a side view of a brush member (10) with grooves (129) located on the twisted blade members (12) according to an embodiment of the present invention.
  • Figure 5b shows a side view of a brush member (10) with grooves (129) located on the twisted blade members (12) according to an embodiment of the present invention.
  • Similar parts of the embodiments may have the same names, similar part numbers, or similar part numbers with an alphabet symbol or prime symbol. The description of one part applies by reference to another similar part, where appropriate, thereby reducing repetition of text without limiting the disclosure.
  • a cosmetic applicator device for applying a cosmetic composition (e.g., lipstick, lip gloss, lipliner, mascara, eyeliner, eyeshadow and any other milky, liquid or creamy products, fluid or pasty product), comprising a brush member (10), wherein the brush member (10) comprises an elongated core (11) that extends along a longitudinal axis XX’ and a plurality of twisted blade members (12).
  • a cosmetic composition e.g., lipstick, lip gloss, lipliner, mascara, eyeliner, eyeshadow and any other milky, liquid or creamy products, fluid or pasty product
  • Each twisted blade member (12) is configured to comprise a fixed edge (121) and a free edge (122), wherein each twisted blade member (12) is attached at the fixed edge (121) onto the surface of the elongated core (11), and the free edge (122) extends outwards away from the elongated core (11) along a transverse axis YY ’.
  • the free edges of the plurality of the twisted blade members (12) are configured to stick out from the elongated core (11) in. a radial direction and serve for the efficient application of a cosmetic compositions/substances onto the intended surfaces.
  • the blade intervals (13) (also known as “blade gaps”) between the adjacent twisted blade members (12) are operable to retrieve the cosmetic compositions from the composition container as well as to hold the cosmetic compositions therein.
  • the brush member (10) in a direction perpendicular to the longitudinal axis of the brush member (10), i.e., XX’ axis, while rotating the same.
  • the brush member (10) will then get pressed against and rotated on the intended surfaces (e.g., lip, eyelashes, eyebrows, and other parts of human body), the adjacent twisted blade members (12) get pushed and twisted, changing the size and dimension of the blade intervals (13) so that the cosmetic compositions held inside the blade intervals (13) get expelled out of the blade intervals (13) and further onto the intended surfaces.
  • the intended surfaces e.g., lip, eyelashes, eyebrows, and other parts of human body
  • the brush member (10) is attached on a wand (15), which forms a handle for user to hold.
  • the elongated core (11) extends into the wand (15) along the longitudinal direction XX’ and gets firmly embedded inside the wand (15).
  • the elongated core (11) is also known as central core, which forms the “center” of the brush member (10) for twisted blade members (12) to be mounted thereon.
  • the twisted blade member (12) is configured to also comprise a root end (123) and a tip end (124), wherein the root end (123) is located at or in close proximity to the bottom portion (1 la) of the elongated core (11); and the tip end (124) is located at or in close proximity to the tip portion (1 lb) of the elongated core (11).
  • the fixed edge (121) is configured to be spirally located around the elongated core (11) from the root end (123) to the tip end (124).
  • each twisted blade member (12) is configured to curve in a spiral about the surface of the elongated core (11) along its longitudinal axis XX’.
  • first continuous twist (125) between the root end (123) and the tip end (124).
  • first continuous twist (125) from the root end (123) to the tip end (124)
  • elastic materials e.g., thermoplastic polymer, thermoplastic elastomer polymer, vulcanized rubber, polyethylene, and polypropylene.
  • the twisted blade members (12) when the twisted blade members (12) are being pressed against the lip, the twisted blade members (12) get bended and twisted under pressure, distorting the blade intervals (13) between the adjacent twisted blade members (12), which accordingly directs the cosmetic composition held within the blade intervals (13) out towards the lip.
  • the first continuous twist (125) comprises at least two segments: the first segment (125a) relatively closer to the root end (123) and the second segment (125b) closer to the tip end (124).
  • the first continuous twist (125) is configured to gradually curve and twist away from the surface of the elongated core (11); whereas in the second segment (125b), approaching the tip end ( 124), the first continuous twist ( 125 ) is configured to gradually curve and twist towards the surface of the elongated core (11).
  • the first segment and the second segment will bend and twist in different directions: i.e., the first segment will tend to twist towards the root end (123), while the second segment will tend to twist towards the tip end (124).
  • the portion of the twisted blade member (12) between the first segment and the second segment will get particularly stretched, exposing the cosmetic composition carried within the blade intervals (13).
  • the fixed edge (121) and the free edge (122) converge at both the root end (123) and the tip end (124).
  • the fixed edge (121), the free edge (122), the root end (123) and the tip end (124) together form the boundary of the twisted blade member (12) and accordingly determine the shape and configuration of the twisted blade member (12).
  • the root end (123) and the tip end (124) can be shaped in various forms, such as pointed end, blunt end and rounded end.
  • the second continuous twist (126) is operable to further improve the overall elasticity of the twisted blade members (12) and strengthen the distortion of the blade intervals (13) when the twisted blade members (12) are pressed against a surface (e.g., lip). More specifically, with both the first continuous twist (125) and the second continuous twist (126), each twisted blade member (12) is operable to twist not just along the longitudinal direction XX’ of the elongated core (11), but also along the transversal direction YY’ of the elongated core (11) away or towards the surface of the elongated core (11). This arrangement makes the twisted blade members (12) easier to twist and bend during the use of the cosmetic applicator device.
  • Figures 2 to 4 show four embodiments (the first embodiment (a), the second embodiment (b), the third embodiment (c) and the fourth embodiment (d)) of the improved brush member (10) with different blade shapes.
  • the twisted blade member (12) is configured to have a thickness of 0. 1mm to 0.35mm.
  • the twisted blade member (12) is configured to have a thickness (127) gradually decreasing from the fixed edge (121) to the free edge (122). In some other embodiments, the twisted blade member (12) is configured to have a thickness (127) gradually increasing from the fixed edge (121) to the free edge (122).
  • the cosmetic applicator device can be made suitable for cosmetic compositions with different viscosities stickiness, density, and friction properties.
  • the twisted blade member (12) is configured to have a width (128) gradually increasing from the root end (123) first, and then gradually decreasing till the tip end (124).
  • the width of the twisted blade member (12) is relatively shorter near the root end (123) and the tip end (124), and is relatively longer in length in the middle of the twisted blade member (12).
  • the twisted blade members (12) can be beneficial for the twisted blade members (12) to have a wider width in the middle portion (or somewhere close to the middle portion), which protrudes outwards from the elongated core (11) to create a blade peak (131) on the free edge (122).
  • the blade peak (131) is operable to guide the cosmetic compositions out of the blade intervals (13) to the intended place more efficiently. In other words, at the blade peak (131), the width (128) of the twisted blade member (12) is the largest.
  • Such a configuration is particularly useful when the viscosity of the cosmetic composition is relatively high (e.g., cream-like, or pasty-like substance), having a relatively sharp blade peak (131) helps direct those composition onto the intended surface (see Figures 2c, 2d, 3c, 3d, 4c and 4d). Also, when a more a distinct and tense effect is desired (e.g., for the lip, the eyelashes, and the eyebrows to be applied with more cosmetic substances), having a relatively sharp blade peak (131) also facilitates the transfer of the cosmetic substances (see Figures 2c, 2d, 3c, 3d, 4c and 4d).
  • a relatively sharp blade peak (131) also facilitates the transfer of the cosmetic substances (see Figures 2c, 2d, 3c, 3d, 4c and 4d).
  • the plurality of twisted blade members (12) is equally spaced apart from one another about the elongated core (11).
  • the blade intervals (13) are configured to have the same size and dimension, so that no matter which side of the brush member (10) presses against the intended surface, the effects are the same, making it easier for common users to control the cosmetic applicator device.
  • a first side of the brush member (10) can be configured to have the adjacent twisted blade members (12) spaced apart more closely, so that these narrow blade intervals (13) are only able to hold fewer cosmetic substances, and accordingly the first side of the brush member (10) is more suitable for cosmetic applications that require fewer substances.
  • a second side of the brush member (10) can be configured to have the adjacent twisted blade members (12) spaced apart more widely, so that more cosmetic substances can be carried inside the wider blade intervals (13) on the second side of the brush, which is accordingly suitable for cosmetic applications that require more cosmetic substances.
  • each twisted blade member (12) is configured to comprise one or more grooves (129), which divide a twisted blade member
  • the grooves (129) increase the surface for holding the cosmetic compositions and are operable to create more microstructures (e.g., channels, passages, pathways, and voids) for the cosmetic substances to flow out of the blade intervals
  • These groove (129) structures are particularly useful when the cosmetic applicator device (10) is used for surfaces that have hairs or any type of keratin fibers, such as eyelashes and eyebrows, because these grooves (129) are operable for these hairs to pass through and even get entangled therein, during which, cosmetic substances carried inside the grooves (129) are efficiently and firmly applied onto these hairs.
  • the grooves (129) are also operable to lengthen, thicken and/or separate the hairs. It is advantageous for the twisted blade members (12) to have such grooves (123) particularly when the cosmetic substances are in liquid form and/or are made of a composition that has low stickiness.
  • the groove (129) structures can take various forms, such as V-shape, a U-shape, a semicircular arc shape, a rectangular shape, and a trapezoidal shape, depending on the cosmetic applications intended. For example, if it is preferred to have hairs strongly entangled inside the grooves (129), then groove (129) structure in the form of a straight thin line are probably suitable. In other cosmetic applications that do not require strong and intense interactions between the hairs and grooves (129), then grooves (129) in the form of a wide- opening V shape (wherein the opening is positioned to face outwards away from the elongated core (11)) are likely to be suitable.
  • the groove (129) is configured to cut through the twisted blade member (12) from the free edge (122) to the fixed edge (121).
  • two adjacent segments of the twisted blade member (12) are operable to move freely with respect to each other.
  • the elasticity of the twisted blade members (12) accordingly gets increased, and the blade intervals (13) can also deform and get distorted in a greater extent when the twisted blade members (12) are pressed against the intended surfaces.
  • the adjacent grooves (129) from the plurality of twisted blade members (12) are configured to be on a groove plane (130) (i.e., a virtual plane, used here to geometrically define the characteristic elements of the invention) (see Figure 5).
  • the groove plane (130) is configured to have an angle between 0 and 90 degrees with respect to horizontal plane.
  • the plurality of twisted blade members (12) is configured to have more than one such groove plane (130).
  • the number (or density) of the twisted blade members (12) of a brush member (10) can be adjusted.
  • some brush member (10) is configured to have at least twelve twisted blade members (12). Having more twisted blade members (12) inside a brush member (10) results in more blade intervals (13) but with smaller size and dimension.
  • the elongated core (11) and a plurality of twisted blade members (12) are integrally formed, i.e., formed in one piece.
  • the brush member (10) can be obtained in different ways: by mono-injection, bi-injection or tri -injection molding; the integral cosmetic applicator device according to the invention can also be obtained by additive manufacturing, machining or compression.
  • the materials that can be used include a thermoplastic polymer or a thermoplastic elastomer polymer or even a vulcanizable rubber.
  • integrally formed brushes minimize the use of glue, improving the health safety of the makeup brushes.
  • the brush member (10) is configured to wherein the brush member is configured to have a rigidity of 10HA to 50HA (Shore hardness A).
  • the elongated core (11) is configured to have a higher rigidity than the twisted blade members (12).
  • the elongated core (11) ideally should not bend or twist easily so that it will be easier for the user to handle the cosmetic applicator device, as force exerted by the user onto the cosmetic applicator device can be more efficiently transferred to the twisted blade members (12).
  • the twisted blade members (12) can be manufactured using materials with higher elasticity, avoiding any unpleasant, firm, and rough feeling when the twisted blade members (12) are pressed against the lip, eyelashes, eyebrows, and other parts of a human body.

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  • Brushes (AREA)

Abstract

La présente invention concerne un dispositif applicateur de produit cosmétique destiné à l'application d'une composition, comprenant un élément brosse (10), l'élément brosse (10) comprenant un noyau allongé (11) et une pluralité d'éléments lames torsadés (12) ; chaque élément lame torsadé (12) est conçu pour comprendre : un bord fixe (121), chaque élément lame torsadé (12) étant fixé au niveau du bord fixe (121) sur le noyau allongé (11), un bord libre (122), une extrémité racine (123), et une extrémité de pointe (124). Une première torsion continue (125) est présente entre l'extrémité racine (123) et l'extrémité de pointe (124), et le bord fixe (121) est conçu pour être disposé en spirale autour du noyau allongé (11) de l'extrémité racine (123) à l'extrémité de pointe (124). La pluralité d'éléments lames torsadés (12) est utilisable pour améliorer l'élasticité globale de l'élément brosse (10) et conçue pour créer de multiples intervalles de lame (13) destinés à retenir de manière stable les produits cosmétiques en leur sein, ainsi qu'à transférer efficacement les produits cosmétiques sur les surfaces prévues du corps humain telles que les lèvres, les cils et les sourcils.
PCT/SG2022/050589 2021-10-13 2022-08-18 Dispositif applicateur de produit cosmétique et similaire WO2023063876A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SG10202111374W 2021-10-13
SG10202111374W 2021-10-13

Publications (1)

Publication Number Publication Date
WO2023063876A1 true WO2023063876A1 (fr) 2023-04-20

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080245382A1 (en) * 2007-03-16 2008-10-09 Chanel Parfums Beaute Applicator for applying a composition to the eyelashes
US20090014022A1 (en) * 2007-07-11 2009-01-15 Chanel Parfums Beaute Applicator for making up the eyelashes and/or the eyebrows, the applicator including a furrow
US20090320872A1 (en) * 2006-04-28 2009-12-31 Yves Saint Laurent Parfums Application instrument of simplified construction, and associated manufacturing method
US20150110541A1 (en) * 2013-10-22 2015-04-23 Albea Services Applicator for a Cosmetic Product and Associated Applicator Assembly
US20170020266A1 (en) * 2013-12-17 2017-01-26 L'oreal Applicator for applying a cosmetic, makeup or care, product to the eyelashes and/or eyebrows
US20190307236A1 (en) * 2016-06-08 2019-10-10 Societe Industrielle De Matieres Plastiques Applicator device for applying a fluid or pasty product to keratin fibres

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090320872A1 (en) * 2006-04-28 2009-12-31 Yves Saint Laurent Parfums Application instrument of simplified construction, and associated manufacturing method
US20080245382A1 (en) * 2007-03-16 2008-10-09 Chanel Parfums Beaute Applicator for applying a composition to the eyelashes
US20090014022A1 (en) * 2007-07-11 2009-01-15 Chanel Parfums Beaute Applicator for making up the eyelashes and/or the eyebrows, the applicator including a furrow
US20150110541A1 (en) * 2013-10-22 2015-04-23 Albea Services Applicator for a Cosmetic Product and Associated Applicator Assembly
US20170020266A1 (en) * 2013-12-17 2017-01-26 L'oreal Applicator for applying a cosmetic, makeup or care, product to the eyelashes and/or eyebrows
US20190307236A1 (en) * 2016-06-08 2019-10-10 Societe Industrielle De Matieres Plastiques Applicator device for applying a fluid or pasty product to keratin fibres

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