WO2023003546A1 - Étiquette adhésive thermofusible sensible à la pression à base d'oléfine recyclable et ses procédés de production et d'utilisation - Google Patents
Étiquette adhésive thermofusible sensible à la pression à base d'oléfine recyclable et ses procédés de production et d'utilisation Download PDFInfo
- Publication number
- WO2023003546A1 WO2023003546A1 PCT/US2021/042479 US2021042479W WO2023003546A1 WO 2023003546 A1 WO2023003546 A1 WO 2023003546A1 US 2021042479 W US2021042479 W US 2021042479W WO 2023003546 A1 WO2023003546 A1 WO 2023003546A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- adhesive
- pressure sensitive
- hmpsa
- inch
- range
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 32
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 239000004820 Pressure-sensitive adhesive Substances 0.000 title claims description 32
- 239000012943 hotmelt Substances 0.000 title claims description 14
- 238000000034 method Methods 0.000 title description 10
- 239000000853 adhesive Substances 0.000 claims abstract description 71
- 230000001070 adhesive effect Effects 0.000 claims abstract description 70
- 239000000463 material Substances 0.000 claims abstract description 33
- 239000004014 plasticizer Substances 0.000 claims abstract description 33
- 229920001400 block copolymer Polymers 0.000 claims abstract description 23
- 238000004064 recycling Methods 0.000 claims abstract description 22
- 239000000470 constituent Substances 0.000 claims abstract description 10
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 8
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 8
- 239000004831 Hot glue Substances 0.000 claims abstract description 5
- 239000004743 Polypropylene Substances 0.000 claims description 25
- 229920001903 high density polyethylene Polymers 0.000 claims description 20
- 239000004700 high-density polyethylene Substances 0.000 claims description 20
- 229920000098 polyolefin Polymers 0.000 claims description 12
- 239000003963 antioxidant agent Substances 0.000 claims description 9
- 239000010410 layer Substances 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 9
- 239000004698 Polyethylene Substances 0.000 claims description 8
- 239000011111 cardboard Substances 0.000 claims description 8
- 230000009477 glass transition Effects 0.000 claims description 7
- -1 polypropylene Polymers 0.000 claims description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 5
- 239000005977 Ethylene Substances 0.000 claims description 5
- 230000003078 antioxidant effect Effects 0.000 claims description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 5
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 3
- 229920001083 polybutene Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 239000004711 α-olefin Substances 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 239000000758 substrate Substances 0.000 abstract description 15
- 230000008961 swelling Effects 0.000 abstract description 12
- 238000004383 yellowing Methods 0.000 abstract description 7
- 239000000203 mixture Substances 0.000 description 17
- 239000003921 oil Substances 0.000 description 14
- 238000009472 formulation Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 7
- 238000004806 packaging method and process Methods 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 6
- 239000004033 plastic Substances 0.000 description 6
- 229920006132 styrene block copolymer Polymers 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 235000013305 food Nutrition 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 229920002367 Polyisobutene Polymers 0.000 description 3
- 239000000123 paper Substances 0.000 description 3
- FFNMBRCFFADNAO-UHFFFAOYSA-N pirenzepine hydrochloride Chemical compound [H+].[H+].[Cl-].[Cl-].C1CN(C)CCN1CC(=O)N1C2=NC=CC=C2NC(=O)C2=CC=CC=C21 FFNMBRCFFADNAO-UHFFFAOYSA-N 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 230000002522 swelling effect Effects 0.000 description 3
- 230000006750 UV protection Effects 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 235000013361 beverage Nutrition 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000011094 fiberboard Substances 0.000 description 2
- 238000002372 labelling Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- 101100184147 Caenorhabditis elegans mix-1 gene Proteins 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 235000013351 cheese Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 235000013611 frozen food Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/387—Block-copolymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/334—Applications of adhesives in processes or use of adhesives in the form of films or foils as a label
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/006—Presence of polyolefin in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2453/00—Presence of block copolymer
Abstract
L'invention concerne un adhésif thermofusible sensible à la pression, comprenant au moins un copolymère séquencé d'oléfine, un agent poisseux hydrocarboné hydrogéné et un plastifiant. L'adhésif est exempt de tout composant contenant de l'huile et l'étiquette sensible à la pression avec l'adhésif présente des performances d'adhérence souhaitées à basse température ainsi qu'à température normale pour un hôte de différents substrats. L'adhésif résiste également au jaunissement, au blanchiment par l'eau et est non gonflant. L'adhésif et l'étiquette permettent le recyclage dans des flux de recyclage lorsque le matériau de face et/ou le substrat étiqueté sont également constitués d'un matériau à base d'oléfine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2021/042479 WO2023003546A1 (fr) | 2021-07-21 | 2021-07-21 | Étiquette adhésive thermofusible sensible à la pression à base d'oléfine recyclable et ses procédés de production et d'utilisation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2021/042479 WO2023003546A1 (fr) | 2021-07-21 | 2021-07-21 | Étiquette adhésive thermofusible sensible à la pression à base d'oléfine recyclable et ses procédés de production et d'utilisation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2023003546A1 true WO2023003546A1 (fr) | 2023-01-26 |
Family
ID=77398638
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2021/042479 WO2023003546A1 (fr) | 2021-07-21 | 2021-07-21 | Étiquette adhésive thermofusible sensible à la pression à base d'oléfine recyclable et ses procédés de production et d'utilisation |
Country Status (1)
| Country | Link |
|---|---|
| WO (1) | WO2023003546A1 (fr) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6582829B1 (en) * | 1996-03-14 | 2003-06-24 | H.B. Fuller Licensing & Financing Inc. | Hot melt adhesive composition comprising homogeneous ethylene interpolymer and block copolymer |
| US20040191459A1 (en) * | 2003-03-12 | 2004-09-30 | Driesten Sjoerd Johannes Van | Reusable closures for packages and methods of making and using the same |
| US20060079617A1 (en) * | 2004-10-08 | 2006-04-13 | Nicolas Kappes | Combinations of tackifier and polyalphaolefin oil |
| US20060229411A1 (en) * | 2005-04-06 | 2006-10-12 | Stephen Hatfield | Hot melt pressure sensitive adhesives based on blends of styrene/butadiene copolymers |
| US20170292048A1 (en) * | 2016-04-08 | 2017-10-12 | Avery Dennison Corporation | Clear hot melt adhesives |
| WO2021108160A1 (fr) * | 2019-11-25 | 2021-06-03 | Exxonmobil Chemical Patents Inc. | Adhésifs thermofusibles sensibles à la pression et leurs procédés de fabrication |
-
2021
- 2021-07-21 WO PCT/US2021/042479 patent/WO2023003546A1/fr unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6582829B1 (en) * | 1996-03-14 | 2003-06-24 | H.B. Fuller Licensing & Financing Inc. | Hot melt adhesive composition comprising homogeneous ethylene interpolymer and block copolymer |
| US20040191459A1 (en) * | 2003-03-12 | 2004-09-30 | Driesten Sjoerd Johannes Van | Reusable closures for packages and methods of making and using the same |
| US20060079617A1 (en) * | 2004-10-08 | 2006-04-13 | Nicolas Kappes | Combinations of tackifier and polyalphaolefin oil |
| US20060229411A1 (en) * | 2005-04-06 | 2006-10-12 | Stephen Hatfield | Hot melt pressure sensitive adhesives based on blends of styrene/butadiene copolymers |
| US20170292048A1 (en) * | 2016-04-08 | 2017-10-12 | Avery Dennison Corporation | Clear hot melt adhesives |
| WO2021108160A1 (fr) * | 2019-11-25 | 2021-06-03 | Exxonmobil Chemical Patents Inc. | Adhésifs thermofusibles sensibles à la pression et leurs procédés de fabrication |
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