WO2022218333A1 - 微细气泡发生方法及发生装置 - Google Patents
微细气泡发生方法及发生装置 Download PDFInfo
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- WO2022218333A1 WO2022218333A1 PCT/CN2022/086569 CN2022086569W WO2022218333A1 WO 2022218333 A1 WO2022218333 A1 WO 2022218333A1 CN 2022086569 W CN2022086569 W CN 2022086569W WO 2022218333 A1 WO2022218333 A1 WO 2022218333A1
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Definitions
- the invention relates to the technical field of gas-liquid two-phase interface interaction, in particular to a method and a generating device for generating fine bubbles.
- micro-nano bubbles As early as the 1960s, people discovered the existence of micro-nano bubbles and applied them to imaging technology. After 2000, Japan took the lead in researching more characteristics and applications of micro-nano bubbles, and found that micro-nano bubbles have the characteristics of extremely slow rise in water, self-pressurized dissolution, and extremely high mass transfer efficiency (over 95%). It also has the characteristics of greatly improving the solubility of gas, large surface-specific contact area, high interface potential, excellent air flotation effect, reducing the flow resistance of liquid, and explosion in the microscopic field of bubbles breaking the chemical bonds of surrounding water molecules to generate free radicals.
- micro-nano bubbles can increase rice production by more than 50%, make the root system of rice more developed, and greatly improve its lodging resistance.
- the principle is that the root system of plants needs to absorb oxygen, and most microorganisms in the soil are aerobic. , the more active the microorganisms, the stronger the soil fertility, the more developed the root system, so as to achieve the effect of increasing production. Planting crops with micro-nano bubble water can increase production and improve the soil environment at the same time.
- micro-nano bubbles can also reduce the sliding resistance of the liquid and achieve the effect of speeding up the ship.
- Micro-nano bubbles are not only limited to air, oxygen, but also carbon dioxide, ozone and other gases.
- Ozone water with high concentration and high contact area is an advanced oxidation technology in the industry, and its application is of great significance. Not only industry, ozone water is used in food disinfection. Sterilization can also make a big difference.
- high-concentration carbon dioxide water can help the industrialization of microalgae oil production.
- the essence of micro-nano bubble technology is a high-efficiency gas-liquid mixing technology, breaking the routine that non-polar gases are insoluble in water. It is a basic process that will penetrate into various fields like electricity, bringing technological breakthroughs.
- Micro-nano bubbles have such an important role, but they have not been widely used in production practice, and they have only stayed in the research of application experiments.
- the core problem is that the energy consumption of micro-nano bubble generators is extremely high, and the increase in production does not increase income. So far, there has been no breakthrough in the energy consumption of various generators.
- Most of the micro-nano bubble generators use the high-speed water flow generated by the water pump to cut the gas.
- the existing design ideas are limited to how to recycle the high-speed water. Water flow, in essence, can not achieve the purpose of greatly reducing energy consumption.
- micro-bubbles there are many methods for generating micro-bubbles, such as ultrasonic method, pressure-releasing dissolved gas method, venturi jet method and rotary cutting method, etc.
- the pressure-releasing dissolved gas method Due to the complex structure of the equipment required by the method and the difficulty of implementation, the commonly used methods for generating microbubbles are the Venturi jet method and the rotary cutting method.
- the principle of the rotary cutting method is essentially the same as that of the pressure release method. Both are pressurized and dissolved gas through a liquid rotating at a high speed, and the pressure is released at the outlet to generate fine air bubbles.
- the rotary cutting method Compared with the pressure release method, the rotary cutting method Compared with the Venturi jet method, the water flow rotates forward, the water and gas fusion process is longer, and the particle size of the bubbles formed at the outlet is more delicate. .
- the front end of the Venturi jet method and the rotary cutting method both need to use a large water pump or a dissolved air pump (requires a lift of 20m to 40m and a water pressure of 0.2MPa to 0.5MPa).
- the object of the present invention is to provide a method and a generating device for generating fine bubbles.
- By applying pressure to the gas it passes through the microporous material and forms fine bubbles at the interface between the microporous material and the liquid, and then passes through the micropores.
- the relative motion between the material and the liquid cuts the micro-bubbles before the bubbles become larger and merge with the adjacent micro-bubbles, so that the micro-bubbles are peeled off the surface of the micro-porous material and enter in the form of micro-bubbles (diameter less than 100 ⁇ m).
- the equipment has a simple structure and is easy to operate, and has great economic benefits. Benefit, suitable for promotion and use.
- the present invention can adopt following technical scheme to realize:
- the present invention provides a method for generating micro-bubbles, the method for generating micro-bubbles includes:
- the gas passes through the microporous material and forms fine bubbles at the interface between the microporous material and the liquid;
- the fine air bubbles adsorbed on the microporous material are impacted, so that the fine air bubbles are separated from the microporous material and enter into the liquid Inside.
- the invention provides a micro-bubble generating device, the micro-bubble generating device comprises a gas-accommodating chamber arranged below the liquid surface and a gas-conveying pipeline for transporting gas into the gas-accommodating chamber.
- the outer ring is provided with a microporous material layer through which the gas in the gas-containing chamber can pass, one end of the gas pipeline is located above the liquid level and connected to the gas source, and the other end of the gas pipeline extends entering into the gas-containing chamber, so that the gas in the gas-containing chamber can pass through the microporous material layer and form fine air bubbles on the outer surface of the microporous material layer by air pressure;
- the microporous material layer moves and/or the liquid located outside the microporous material layer moves, so as to cut the fine air bubbles, so that the fine air bubbles enter the liquid.
- the micro-bubble generating device forms a certain pressure in the air-accommodating chamber by introducing gas into the air-accommodating chamber, and makes the gas in the air-accommodating chamber pass through the microporous material layer under the action of the air pressure
- Micro bubbles are formed on the interface between the outer surface of the microporous material layer and the liquid.
- the main energy consumption of the present invention during the working process is not the energy consumption of moving the gas, but the energy consumption of overcoming the frictional resistance of the gas-containing chamber to rotate in the liquid, but the present invention requires the gas-containing chamber to rotate or the liquid to rotate.
- the speed of the rotating flow along the gas chamber is higher than the speed of the gas passing through the microporous material layer, and the speed of the gas flow is usually centimeters per second.
- the microporous material with a small surface friction coefficient is preferred as the microporous material.
- the flow rate of the driven liquid can be completely controlled below one meter per second, so the required rotational speed during the working process is low, and the conditions required for the generation of fine bubbles in the present invention are not limited by the water-air ratio, and the process does not require high-speed water flow Therefore, it can effectively reduce production energy consumption, save production costs, and can quickly generate a large number of fine bubbles with uniform particle size, which has great economic benefits.
- the weight and volume of the micro-bubble generating device are greatly reduced.
- the power equipment used in the present invention is a motor.
- the power requirement of some specifications is below 1KW, and the microporous material is also a lightweight material.
- the weight of the present invention is mainly due to the supporting equipment such as the fixed base. Therefore, the weight of the overall device can be controlled within 10 kg, and the volume of the entire device can be The diameter is 30cm and the height is within 120cm. It can be installed manually during the actual use.
- the volume of the micro-bubble generating device can be adjusted according to actual needs, and then the amount of micro-bubble generated can be regulated.
- the entire device can be miniaturized.
- the power equipment adopts low-power micro-motors, and other parts can also be reduced accordingly.
- the application field of bubbles such as can enter the household and civilian field, people can make and drink high-oxygen water, high-hydrogen water to protect their health, in addition, can also be used to make ozone water, used for vegetables, fruits, meat preservation, removal of pesticide residues, etc.
- the micro-bubble generating device has a simple structure and is easy to handle.
- the raw materials are industrial finished products and are suitable for large-scale production; in addition, the invention has low energy consumption and low power, and the device needs about 30 watts of power to generate micro-bubbles.
- the solar panels supply power and can produce micro-bubbles in the fields, rivers and lakes.
- the micro-bubbles have been proven to have a significant effect on increasing crop yields and treating river sewage, making full use of sunlight, air and water. It is not possible for the rotary cutting method.
- the particle size distribution of the micro-bubble generated by the micro-bubble generating device is highly consistent.
- the particle size distribution of the micro-bubble generated by the existing micro-bubble generating device can exist from nano-scale to micro-scale (1 nanometer to 200 microns), and the consistency of the micro-bubble particle size in the invention depends on the pore size distribution of the microporous material. Consistency, the microporous material is now of good quality, and the particle size range of the resulting microbubbles has good consistency.
- micro-bubble generating device rotates with gas to form high-speed airflow cutting liquid through the operation of microporous materials.
- the conversion of this idea can reduce energy consumption by more than 100 times, and through the improvement of the device, there are more When energy consumption is no longer the bottleneck of micro-nano bubbles, the changes brought by micro-nano bubbles to various industries will be of extraordinary significance.
- Fig. 1 is a flow chart of the method for generating fine bubbles of the present invention.
- Fig. 2 is one of the structural schematic diagrams of the micro-bubble generating device of the present invention.
- FIG. 3 is a schematic view of the structure of the part below the liquid level in FIG. 2 .
- Fig. 4 is the second schematic view of the structure of the micro-bubble generating device of the present invention.
- FIG. 5 is a schematic view of the structure of the part below the liquid level in FIG. 4 .
- FIG. 6 is the third schematic view of the structure of the micro-bubble generating device of the present invention.
- FIG. 7 is a schematic view of the structure of the part below the liquid level in FIG. 6 .
- Fig. 8 is the fourth schematic diagram of the structure of the micro-bubble generating device of the present invention.
- Fig. 9 is the fifth structural schematic diagram of the micro-bubble generating device of the present invention.
- Fig. 10 is the sixth schematic diagram of the structure of the micro-bubble generating device of the present invention.
- FIG. 11 is a plan view of the micro-bubble generating device in FIG. 10 .
- the present invention provides a method for generating fine bubbles, which comprises the following steps:
- Step S1 the gas passes through the microporous material and forms fine bubbles on the interface between the microporous material and the liquid;
- step S1 includes:
- Step S101 a microporous material layer 2 is arranged around the periphery of the gas-containing chamber 1 along the circumference of the gas-containing chamber 1, and the gas-containing chamber 1 is placed below the liquid level;
- Step S102 one end of the gas transmission pipeline 3 is located above the liquid level and connected to the gas source, the other end of the gas transmission pipeline 3 is connected to the gas-containing chamber 1, and the gas-containing chamber 1 is filled with gas through the gas transmission pipeline 3 , so as to form a certain air pressure in the gas-containing chamber 1;
- Step S103 under the action of the air pressure in the gas containing chamber 1 , the gas in the gas containing chamber 1 passes through the microporous material layer 2 and forms fine bubbles on the outer surface of the microporous material layer 2 .
- Step S2 impacting the micro-bubbles adsorbed on the micro-porous material through the relative motion of the micro-porous material and the liquid, so that the micro-bubbles can be separated from the micro-porous material and enter into the liquid before the micro-bubble becomes larger to 100 ⁇ m.
- the microporous material layer 2 is driven to rotate along its own circumferential direction and/or the liquid located outside the microporous material layer 2 is driven to flow along the circumferential direction of the microporous material layer 2, so as to pass through the gap between the microporous material layer 2 and the liquid.
- the relative motion cuts the fine bubbles, so that the fine bubbles escape from the adsorption force of the microporous material layer 2 and/or the surface tension between the bubbles and the microporous material layer 2 and enter the liquid, thereby generating a large number of fine bubbles.
- step S2 the shear force of the liquid on the micro-bubbles is greater than the adsorption force of the micro-porous material capillary effect on the micro-bubbles and/or the surface tension between the bubbles and the micro-porous material layer 2, so that the bubbles can be impacted and detached.
- the microporous material enters the liquid in the form of fine air bubbles.
- the time from the formation of the micro-bubbles to being cut and detached from the microporous material is less than the time required for the micro-bubbles to grow in size and rapidly grow to form large bubbles (with a diameter of 100 ⁇ m) after merging with adjacent micro-bubbles.
- the bubbles generated on the surface of the micro-porous material with small pore size will be in the capillary adsorption force of the micro-porous material and/or the bubble and the micro-porous material layer 2 Under the action of the surface tension between the bubbles, it gradually becomes larger and merges with the adjacent bubbles to form larger bubbles, until the buoyancy of the bubbles can overcome the capillary adsorption force and/or the surface tension between the bubbles and the microporous material layer 2.
- the surface detached from the microporous material enters the liquid in the form of large bubbles (200 ⁇ m or more in diameter). Therefore, it is necessary to quickly cut the micro-bubbles after they are formed on the interface between the microporous material and the liquid to ensure that the bubbles enter the liquid before the diameter of the bubbles increases to 100 ⁇ m.
- step S2 the liquid is in a static state and the microporous material is in a moving state, and drives the gas entering the microporous material to move synchronously, so as to form a pair of microporous materials through the movement of the microporous material.
- the fine air bubbles at the interface between the microporous material and the liquid are impacted (or cut).
- the micro-nano bubbles can also be cut by the movement of the liquid as described above, in a more preferred embodiment of the present invention, the movement of the microporous material is adopted, and the liquid is in a static state, which is in phase with the movement of the liquid outside the microporous material. It can greatly reduce energy consumption.
- the energy consumption required for the liquid to accelerate to the same speed ie: the same rotation speed as that of the microporous material
- the energy consumption of speeding up to the same speed (there was a difference of nearly 6 orders of magnitude before the two).
- step S2 the microporous material is in a static state and the liquid is in a moving state, and the fine bubbles formed on the interface between the microporous material and the liquid are removed by the movement of the liquid. Impact (or cut).
- the microporous material is not limited to the material with micropores, and it can also be a cathode or an anode that generates fine air bubbles on the surface of the material during the electrolysis process.
- the present invention provides a micro-bubble generating device.
- the micro-bubble generating device includes an air-accommodating chamber 1 and a gas-transporting pipeline 3 , and the gas-transporting pipeline 3 is used to send the gas into the air-accommodating chamber 1 .
- the gas is transported to form a certain air pressure in the gas-containing chamber 1.
- the periphery of the gas-containing chamber 1 is provided with a microporous material layer 2 along the circumferential ring of the gas-containing chamber 1 for the gas in the gas-containing chamber 1 to pass through.
- the gas in the gas-containing chamber 1 passes through the gaps of the microporous material layer 2 and forms fine bubbles on the outer surface of the microporous material layer 2; drives the microporous material layer 2 to rotate circumferentially and/or drives the microporous material layer 2
- the liquid on the outside flows along the circumferential direction of the microporous material layer 2, and the micro-bubbles on the outer surface of the micro-porous material layer 2 are cut through the relative motion of the liquid and the micro-porous material layer 2, so that the micro-bubbles enter the liquid.
- the microporous material layer 2 is not limited to circumferential rotation, and the liquid is not limited to flow along the circumferential direction of the microporous material layer 2.
- Various motion forms such as left and right swinging, etc.
- the fine air bubbles on the outer surface of the porous material layer 2 may be quickly cut.
- the micro-nano bubbles can also be cut through the movement of the liquid, the movement of the microporous material is used, and the liquid is in a static state, which can greatly reduce the energy consumption compared with the movement of the liquid outside the microporous material. After the microporous material obtains the required speed for motion, no additional energy is consumed, and the gas continuously entering the microporous material is driven up with extremely low energy consumption. If the microporous bubbles generated on the static microporous material are cut by the movement of the liquid, the energy consumption required for the liquid to accelerate to the same speed is much greater than the energy consumption for the microporous material to drive the gas to the same speed.
- the gas pipeline 3 is sequentially provided with an air pump 5, a primary filter 6 and a secondary filter 7 along the flow direction of the gas, the air pump 5, the primary filter 6
- the pore size of the filter element on the secondary filter 7 is smaller than the pore size of the filter element on the primary filter 6 and the pore size of the microporous material layer 2 .
- the dust in the gas is filtered by the primary filter 6 and the secondary filter 7, wherein the primary filter 6 is used to filter out the large particle size dust in the gas, and the secondary filter 7 is used to filter out the dust in the gas
- the small particle size of dust ensures that the microporous material layer 2 will not be blocked by dust under long-term working conditions and prolongs the service life of the device.
- the filter elements on the primary filter 6 and the secondary filter 7 are consumables that are easy to replace, and can be replaced regularly.
- the gas in the gas containing chamber 1 can pass through the microporous material layer 2 through the centrifugal force generated by the rotation of the gas containing chamber 1, and form a negative pressure in the gas containing chamber 1, so that the gas of the gas source enters the gas containing chamber
- a flow meter 8 is provided on the gas pipeline 3 upstream of the air pump 5, and a pressure gauge 10 is provided on the gas pipeline 3 downstream of the secondary filter 7,
- the flow meter 8 is provided with an adjustment knob 9 that can control the gas flow.
- the flow rate of the gas can be monitored in real time through the flow meter 8, and the adjustment knob 9 on the flow meter 8 can be adjusted according to the actual situation, so as to control the flow rate of the gas per unit time and adjust the particle size of the fine bubbles.
- the flow meter 8 may be, but not limited to, a glass rotameter.
- the thickness of the microporous material layer 2 is gradually increased from bottom to top to balance the problem of uneven air outlet caused by the pressure difference between the upper and lower water in the gas chamber 1, so as to ensure the consistency of the bubble particle size, and the microporous material
- the thickness of the layer 2 at each position can be adjusted according to the different gas barrier properties of the microporous material actually used. In the actual use process, the thickness of the microporous material layer 2 can ensure that it has enough strength to support the gas-containing chamber 1 to move.
- the size of the gas-containing chamber 1 is not limited, the larger the volume of the gas-containing chamber 1, the larger the surface area of the microporous material layer 2, and the greater the ventilation volume, but the corresponding frictional resistance during the rotation process. will be bigger.
- the pore size of the microporous material layer 2 is less than 5 ⁇ m.
- the micro-bubble generating device further includes an outer rotor motor 13 that drives the air-accommodating chamber 1 to rotate in the circumferential direction, and the outer rotor motor 13 is disposed in the air-accommodating chamber.
- the rotor of the outer rotor motor 13 and the lower inner wall seal of the microporous material layer 2 are sealed and fixedly connected by a sealant, and the rotor of the outer rotor motor 13 can drive the microporous material layer 2 to rotate.
- the outer rotor motor 13 and the microporous material layer 2 are combined to form the shearing head 4 capable of rotating under the liquid.
- the movement of the microporous material drives the movement of the gas penetrating into the microporous material, and the liquid is cut by rotating to generate fine bubbles. It is a difference of more than two orders of magnitude from the theoretical energy consumption of allowing the liquid to reach the same moving speed.
- the outer rotor motor 13 is an outer rotor brushless motor for underwater operation.
- the micro-bubble generating device further includes a first fixed base 12, the microporous material layer 2 is a cylindrical structure arranged vertically, with a top sealed and an open bottom.
- the top of 2 is provided with a sealing cover 11 made of microporous material and integrally formed with the microporous material layer 2.
- the sealing cover 11 has a hollow hemispherical structure that protrudes upward. The top is sealed and fixedly connected, and the first fixed base 12 supports the microporous material layer 2 to ensure that the device is in a stable working state.
- the gas transmission pipeline 3 includes a first gas transmission main pipe 301, one end of the first gas transmission main pipe 301 is located above the liquid level, and the other end of the first gas transmission main pipe 301 passes through the first gas transmission main pipe 301 in turn.
- a fixed base 12 and the outer rotor motor 13 protrude into the gas chamber 1 and a first blocking block 14 is sealed inside the first gas delivery main pipe 301 , and the first gas delivery main pipe 301 passes through the outer rotor motor 13 .
- the central hole is sealed with the outer rotor motor 13 through sealant, and four first gas delivery branch pipes 302 are connected to the first gas delivery main pipe 301 located in the gas storage chamber 1, and each first gas delivery branch pipe 302 runs along the first
- the gas transmission main pipe 301 is evenly distributed in the circumferential direction;
- the first gas transmission branch pipe 302 includes a horizontal pipe section and a vertical pipe section, one end of the horizontal pipe section is connected to the first gas transmission main pipe 301, and the other end of the horizontal pipe section extends along the horizontal direction to a distance close to the micropipette.
- the hole material layer 2 is positioned and connected to the top end of the vertical pipe section, and the bottom end of the vertical pipe section extends downward in the vertical direction.
- the gas from the gas source is transported into the gas containing chamber 1 through the first gas delivery main pipe 301 and each of the first gas delivery branch pipes 302 , and the gas can be evenly distributed on the inner wall of the microporous material layer 2 as much as possible.
- the micro-bubble generating device further includes an inner rotor motor 15, and the inner rotor motor 15 is used to drive the gas-containing chamber 1 to rotate in the circumferential direction, and to deliver gas.
- the pipeline 3 includes a second gas transmission main pipe 303 and a first hollow shaft 306.
- the first hollow shaft 306 is the output shaft of the inner rotor motor 15, and a second blocking block 307 is sealed inside the first hollow shaft 306.
- the hollow shaft 306 passes through the gas storage chamber 1 and is connected to one end of the second gas transmission main pipe 303 , the other end of the second gas transmission main pipe 303 is located above the liquid level, and is located in the second gas transmission main pipe 303 in the gas storage chamber 1
- the second gas transmission branch pipe 304 includes a horizontal pipe section and a vertical pipe section, and one end of the horizontal pipe section is Connected to the second gas transmission main pipe 303, the other end of the horizontal pipe section extends in the horizontal direction to the position close to the microporous material layer 2 and is connected with the top end of the vertical pipe section, and the bottom end of the vertical pipe section extends downward in the vertical direction, passing through
- the second gas delivery main pipe 303 and each second gas delivery branch pipe 304 deliver the gas from the gas source into the gas containing chamber 1 , and can make the gas evenly
- the micro-bubble generating device further includes a first upper cover 16 and a first lower cover 17
- the microporous material layer 2 is a vertical cylindrical structure with openings at both ends.
- An upper cover 16 is sealed at the top opening of the microporous material layer 2
- the first lower cover 17 is sealed at the bottom opening of the microporous material layer 2
- the first hollow shaft 306 sequentially passes through the first lower cover 17 from bottom to top , the gas containing chamber 1 and the first upper cover 16
- the first hollow shaft 306 is sealed and fixedly connected to the first lower cover 17 and the first upper cover 16 through the flange coupling 18 respectively.
- connection between the first upper cover 16 and the microporous material layer 2 and between the first lower cover 17 and the microporous material layer 2 may be sealed and fixed by means of a sealant or the like.
- the inner rotor motor 15 , the microporous material layer 2 , the first upper cover 16 and the first lower cover 17 are combined to form the shearing head 4 capable of rotating below the liquid.
- a straight pipe 308 is connected between the first hollow shaft 306 and the second gas transmission main pipe 303 , and a tracheal quick-release joint is used between the straight pipe 308 and the second gas transmission main pipe 303 .
- 305 is connected, so that the first hollow shaft is in non-contact communication with the second gas transmission main pipe.
- the micro-bubble generating device further includes a bearing seat fixing plate 20 and a second fixing base 19 , the bearing seat fixing plate 20 is located above the second fixing base 19 , and the bearing seat fixing plate 20 is connected to the second fixing base 19 .
- the second fixed bases 19 are connected by a plurality of connecting columns 21 , the air chamber 1 and the inner rotor motor 15 are both arranged between the bearing seat fixing plate 20 and the second fixed base 19 , and the inner rotor motor 15 is located in the air chamber Below the chamber 1, and the inner rotor motor 15 is fixed on the second fixed base 19, the first hollow shaft 306 protrudes through the bearing seat fixing plate 20; the first hollow shaft 306 above the bearing seat fixing plate 20 is from top to A bearing 24 and a first sealing ring 23 are sequentially sleeved at the bottom. Both the bearing 24 and the first sealing ring 23 are arranged in the bearing seat 22 , and the bottom of the straight tube 308 is bonded to the top of the bearing 24 through a sealant.
- the above structure can improve the overall stability of the device and prevent the inner rotor motor 15 from shaking under the action of external force during operation.
- the micro-bubble generating device further includes a micro-bubble generating box 30 and a brushless motor 28 , and the brushless motor 28 is used to drive the microporous material layer 2
- the liquid on the outside rotates and flows along the circumferential direction of the gas-accommodating chamber 1.
- the micro-bubble generating box 30 is a vertical cylindrical structure with an open top and a closed bottom.
- the brushless motor 28 is located below the gas-accommodating chamber 1.
- the output shaft of the brush motor 28 is arranged vertically upward, the output shaft of the brushless motor 28 is provided with an impeller 31 , and the outer wall of the impeller 31 is provided with a plurality of helical blades that provide upward thrust to the liquid, and the impeller 31 is close to the gas chamber 1
- the bottom of the micro-bubble generation box 30, and the gas-containing chamber 1 and the impeller 31 are both arranged inside the micro-bubble generation box 30, and a cutting water channel 34 is formed between the micro-porous material layer 2 and the inner wall of the micro-bubble generation box 30;
- the bottom is provided with an annular first liquid inlet 3001 along the circumference of the microbubble generating box 30 , a plurality of first liquid outlets 3002 are provided on the top of the microbubble generating box 30 , and the bottom of the microbubble generating box 30 is provided with a liquid circulation Tank 33, the liquid circulation tank 33 is an annular structure arranged along the horizontal direction, the liquid circulation tank 33 is provided with a plurality
- the circulation pipes 25 are communicated with the corresponding second liquid inlets 3301, and each second liquid inlet 3302 extends along the tangential direction of the inner wall of the liquid circulation tank 33 to form a rotating water flow in the liquid circulation tank 33 in the same direction as the impeller 31 rotates. .
- the impeller 31 rotates and forms a negative pressure in the micro-bubble generating box 30, and the liquid is sucked into the micro-bubble generating box 30 through the annular first liquid inlet 3001 and flows upward.
- the outer side of the porous material layer 2 rotates and flows along its circumferential direction, thereby cutting the micro-bubbles on the outer surface of the micro-porous material layer 2, and then part of the liquid directly flows out through the top opening of the micro-bubble generating box 30, and the other part of the liquid passes through the micro-bubble generation box 30.
- Each liquid circulation pipe 25 on the bubble generating box 30 flows into the corresponding liquid circulation box 33, and then sequentially passes through each second liquid outlet 3302 on the liquid circulation box 33 and the first liquid outlet 3302 on the microbubble generating box 30 connected to it.
- the liquid inlet 3001 is circulated back to the micro-bubble generating box 30 for circulating use, and the circulating water flow has a certain kinetic energy, which can reduce the energy consumption of the impeller 31 .
- the brushless motor 28 is an inner rotor underwater brushless motor.
- the impeller 31 is a cylindrical hollow cavity with a top seal and a bottom seal.
- the output shaft of the brushless motor 28 passes through the center of the impeller 31.
- the impeller 31 is fixed on the output shaft of the brushless motor 28 through a coupling. It is arranged on the outer wall of the impeller 31 .
- the thrust of the control impeller 31 on the upward flow of the liquid is smaller than the thrust of the impeller 31 on the liquid in the circumferential direction, so it is necessary to adjust the helical blade to have as small an inclination angle as possible, so that the water flow through the microporous material layer 2 Rotate as many turns as possible in the process to make full use of the liquid that consumes energy to move.
- the above-mentioned purpose can also be achieved, which can be adjusted according to the actual situation during the working process.
- the liquid circulation pipe 25 is provided with a flow regulating valve 32 , and the flow rate of the liquid passing through the liquid circulation pipe 25 can be adjusted by the flow regulating valve 32 .
- the cross-sectional area of the cutting water channel 34 is slightly smaller than the cross-sectional area of the first liquid inlet 3001, so as to ensure that the water flow outside the gas-containing chamber 1 can be close to the outer surface of the microporous material layer 2 to cut the micro-bubbles.
- the cross-sectional area of the cutting water channel 34 should be slightly smaller than the cross-sectional area of the first liquid inlet 3001, otherwise the air outlet will be blocked, and the outlet pressure of the air pump 5 needs to be increased);
- the water flow on the side is essentially an invalid water flow (the fine air bubbles on the outer surface of the microporous material layer 2 cannot be cut), therefore, the smaller the cross-sectional area of the cutting water channel 34, the better the effect, and the water flow through the cutting water channel 34 Only then can it be in close contact with the outer surface of the microporous material layer 2 , thereby improving the cutting efficiency of the fine air bubbles on the microporous material layer 2 .
- the gas transmission pipeline 3 includes a third gas transmission main pipe 309, one end of the third gas transmission main pipe 309 is located above the liquid level, and the other end of the third gas transmission main pipe 309 extends into the container
- a third blocking block 311 is sealed in the air chamber 1 and inside the third air transmission main pipe 309, and four third air transmission branch pipes 310 are connected to the third air transmission main pipe 309 located in the air containing chamber 1,
- Each third gas transmission branch pipe 310 is evenly distributed along the circumferential direction of the third gas transmission main pipe 309;
- the third gas transmission branch pipe 310 includes a horizontal pipe section and a vertical pipe section, one end of the horizontal pipe section is connected to the third gas transmission main pipe 309, and the horizontal pipe section is connected to the third gas transmission main pipe 309.
- the other end of the pipe extends horizontally to a position close to the microporous material layer 2 and is connected to the top end of the vertical pipe section, and the bottom end of the vertical pipe section extends vertically downward.
- the gas from the gas source is transported into the gas containing chamber 1 through the third gas delivery main pipe 309 and each third gas delivery branch pipe 310 , and the gas can be distributed evenly on the inner wall of the microporous material layer 2 as much as possible.
- the micro-bubble generating device further includes a second upper cover 26 and a second lower cover 27
- the microporous material layer 2 is a vertical cylindrical structure with openings at both ends.
- the second upper cover 26 is sealed at the top opening of the microporous material layer 2
- the second lower cover 27 is sealed at the bottom opening of the microporous material layer 2
- the third gas delivery branch pipe 310 passes through the second upper cover from top to bottom
- the cover 26 extends into the gas-containing chamber 1 .
- the connection between the second upper cover 26 and the microporous material layer 2 and between the second lower cover 27 and the microporous material layer 2 may be sealed and fixed by means of a sealant or the like.
- the microporous material layer 2 , the second upper cover 26 and the second lower cover 27 are combined to form the shearing head 4 below the liquid, and the liquid can rotate and flow along its circumferential direction.
- the micro-bubble generating device further includes a third fixing base 29 , the third fixing base 29 is located below the micro-bubble generating box 30 , and the brushless motor 28 is fixed on the top of the third fixing base 29 .
- the stability of the brushless motor 28 is improved by the third fixing base 29 to prevent the brushless motor 28 from shaking under the action of external force during operation.
- the air-accommodating chamber 1 is a cylindrical structure enclosed by a microporous material layer 2 to form a seal at both ends, and the axial direction of the air-accommodating chamber 1 is horizontal
- a second hollow shaft 36 is arranged along the axial direction of the inner axis of the air-accommodating chamber 1.
- the second hollow shaft 36 is provided with a plurality of air intake holes 3601 that communicate with the air-accommodating chamber 1.
- the two hollow shafts 36 respectively protrude to the outside of the gas-containing chamber 1 and are respectively connected with the first driving motor 35 and the gas pipeline 3 .
- the length of the air-accommodating chamber 1 is not limited by the depth of water, and the length of the air-accommodating chamber 1 can be adjusted arbitrarily even in a shallow water environment.
- the length of the gas-containing chamber 1 is too long, it will lead to the problem of poor structural stability, but this problem is not considered in this application.
- the air-accommodating chamber 1 since the air-accommodating chamber 1 is arranged in the horizontal direction, it overcomes the large water pressure difference between the upper and lower ends of the air-accommodating chamber 1 when it is arranged in the vertical direction, which leads to the air output at the upper and lower ends.
- the pressure difference between the upper part and the lower part of the gas-containing chamber 1 depends on the diameter of the gas-containing chamber 1 .
- the diameter of the gas-containing chamber 1 is much smaller than the axial length of the gas-containing chamber 1 .
- the diameter of the gas-containing chamber 1 is about 10 cm, and the axial length of the gas-containing chamber 1 is greater than 1 m.
- annular first baffles are respectively provided along the circumferential direction of the air-accommodating chamber 1 . 37.
- the outer diameter of the first blocking piece 37 is larger than the diameter of the gas-containing chamber 1 .
- the micro-nano bubbles have diffused into a larger water body, and the concentration of Greatly reduced, the proportion of extruded large bubbles will also be greatly reduced, thereby greatly reducing the impact of water flow hedging on micro-nano bubbles.
- the larger the diameter of the first baffles 37 the better the blocking effect on the water flow, but because the water wrapped between the two first baffles 37 will be driven to rotate with the gas-containing chamber 1, there will be increased energy consumption Therefore, a balance needs to be made between the particle size of the generated bubbles and the energy consumption.
- annular second blocking piece 38 is provided on the outer wall of the gas-containing chamber 1 and located between the two first blocking pieces 37 along the circumferential direction of the gas-containing chamber 1 .
- the diameter of the second blocking piece 38 is larger than the diameter of the first blocking piece 37 .
- the second blocking piece 38 is located in the middle of the outer wall of the gas-containing chamber 1 , because the diameter of the two first blocking pieces 37 cannot be increased due to the consideration of power consumption, and the negative pressure outside the two first blocking pieces 37 will interfere with each other.
- the water flow is squeezed, so that the water flow will collide at the middle position of the two first baffles 37, resulting in an increase in the proportion of large air bubbles, and adding a second baffle 38 between the two first baffles 37 can effectively prevent For the hedging of the water flow, the disposition of the second baffle 38 will not lead to a large increase in power consumption except for increasing the friction between itself and the water body.
- the micro-bubble generating device further includes a fourth fixing base 39 and a first bracket 40 , the bottom of the first bracket 40 is fixed on the fourth fixing base 39 through screws and nuts, and the first driving motor 35 is fixedly arranged on the top of the first bracket 40, the rotating shaft of the first driving motor 35 is arranged in the horizontal direction and is connected with one end of the second hollow shaft 36 through the self-aligning coupling 41, and the other end of the second hollow shaft 36 passes through the bearing.
- the structure is rotatably arranged on the first bracket 40 , the second hollow shaft 36 and on both sides of the bearing structure are respectively sleeved with annular second sealing rings 42 , and the inside of the second hollow shaft 36 passes through the bearing seat and the bearing.
- the sealing pipe 43 is communicated with the gas pipeline 3 to ensure a good sealing effect.
- the micro-bubble generating device includes a mounting plate 44 that can vibrate in a horizontal direction, and the microporous material layer 2 is enclosed on the top of the mounting plate 44 to form a gas-containing chamber 1 (The microporous material layer 2 can also be sleeved on the outside of the mounting plate 44 to form the gas-containing chamber 1), the gas-containing chamber 1 is provided with an air inlet connected to the gas pipeline 3, and the A second driving motor 45 is disposed below, the second driving motor 45 is fixed at the bottom center position of the mounting plate 44, and the motor shaft of the second driving motor 45 is perpendicular to the surface of the mounting plate 44 arranged in the horizontal direction.
- the vibration force generated by the second drive motor 45 is distributed on the vertical plane of the motor shaft.
- the second drive motor 45 is installed vertically along the direction of the output shaft and the mounting plate 44.
- the eccentric block on the output shaft of the second drive motor 45 The generated centrifugal force drives the entire mounting plate 44 to generate high-frequency reciprocating motion in the horizontal direction under the cooperation of the spring 46 .
- the gas permeates from the microporous material layer 2 and is cut to form micro-nano bubbles, because the micro-nano bubbles will be affected by the capillary adsorption force and/or the surface between the bubbles and the microporous material layer 2.
- the effect of tension gradually increases and aggregates with surrounding bubbles.
- the micro-nano bubbles will be cut by the water body during the high-frequency reciprocating motion of the mounting plate 44 in the horizontal direction.
- the micro-nano bubbles enter the water body in the form of micro-nano bubbles with the original upward motion potential energy. If the mounting plate 44 does not vibrate in the horizontal direction in a still water body, the bubbles coming out of the microporous material layer 2 are sparse and rise rapidly. After the mounting plate 44 vibrates horizontally, the bubbles will It becomes dense and slowly rises. Therefore, in this embodiment, it has a better effect in the flowing water body.
- micro-nano bubbles will be washed away by the water flow to dilute and diffuse the micro-nano bubbles.
- the inertial trend of rising to the water surface caused by continuous generation is destroyed, and the micro-nano bubbles dispersed into the surrounding larger water body will appear dispersed in the water and be in a state of extremely slow rising.
- the second drive motor 45 drives the mounting plate 44 to vibrate, it can be clearly observed that the bubbles generated by the microporous material layer 2 begin to become smaller and denser.
- the vibration frequency increases to a certain value, the bubbles begin to become larger and sparser due to the collision and aggregation, and the frequency further increases, and the bubbles become larger and sparser. Therefore, micro-nano bubbles with different particle sizes can be obtained by adjusting the vibration frequency of the mounting plate 44; different microporous materials have different particle sizes of the initial bubbles.
- the particle sizes of the initial bubbles are also slightly different, and it is necessary to adjust the vibration frequency of the second driving motor 45 to ensure that the generated bubbles are within the required suitable range.
- the second drive motor 45 can be but is not limited to a vibration motor.
- the centrifugal force generated by the high-speed rotation of the eccentric block in the vibration motor is combined with the horizontally placed spring 46 to drive the mounting plate 44 to generate vibration in the horizontal direction.
- the conventional method is that the springs are placed vertically, and the output vibrates up and down to achieve the effect of vibrating and sieving objects. This is the need for an innovative use of the vibration motor in conjunction with the present invention.
- the micro-bubble generating device further includes a fifth fixing base 47 and a second bracket 48 , the bottom of the second bracket 48 is fixed on the fifth fixing base 47 through screws and nuts, and the mounting plate 44 is A square or circular plate-shaped structure arranged in the horizontal direction, the middle positions of each edge of the mounting plate 44 are welded with steel sheets respectively, and the steel sheets extend to the bottom of the mounting plate 44 in the vertical direction, and the edges of the mounting plate 44 are respectively
- a spring 46 is provided (the spring 46 is connected with the mounting plate 44 through screws and nuts), and the other end of the spring 46 is connected with the second bracket 48. Below the liquid level, the spring 46 is in a horizontal state.
- the mounting plate 44 can also be polygonal.
- the micro-bubble generating device includes a hollow column 51 arranged in a vertical direction, the top of the hollow column 51 is sealed, and the bottom is connected to the gas pipeline 3 , and the gas pipeline 3 extends into the interior of the hollow column 51, the bottom of the hollow column 51 is provided with a third drive motor 49 that can drive the hollow column 51 to rotate, and the hollow column 51 is connected with a plurality of air-holding chambers 1 communicated with its interior, each of which is Microporous material layers 2 are respectively provided on the gas-containing chambers 1 .
- the microporous material layer 2 can be a flat plate-like structure arranged in the horizontal direction, and the microporous material layer 2 is covered on the top of the gas-containing chamber 1; the microporous material layer 2 can also be cylindrical, so as to surround the gas-containing chamber The perimeter of chamber 1.
- the third driving motor 49 drives the hollow column 51 to rotate, each gas-containing chamber 1 and the microporous material layer 2 rotate synchronously with the hollow column 51, and the gas in each gas-containing chamber 1 flows from the microporous material layer. 2 It emerges and is cut by the water body, and the gas enters the water body under the drive of its original upward power to form micro-nano bubbles.
- a plurality of gas-accommodating chambers 1 are arranged in multiple layers at intervals in the vertical direction, and the gas-accommodating chambers 1 in each layer are spaced along the circumferential direction of the hollow column 51 and Evenly distributed.
- the cross-section of the gas-containing chamber 1 (that is, the cross-section of the microporous material layer 2 ) may be, but not limited to, a rectangle distributed at intervals. If the gas-containing chamber 1 is a complete annular ring arranged on the outer side of the hollow pillar 51 along the circumferential direction of the hollow pillar 51, it has its own shortcomings: that is, the complete annular ring is easily damaged by the centrifugal force during the rotation process.
- micro-nano bubbles generated by the inner ring of the porous material layer 2 are thrown outward (that is, the micro-nano bubbles generated by the inner ring of the microporous material layer 2 are driven to move to the outer ring of the microporous material layer 2) and interact with the microporous material layer 2.
- the micro-nano bubbles produced by the outer ring of the The spaced arrangement between the two adjacent microporous material layers 2 helps to shorten the continuous process of collision and aggregation, and has widely diffused into the water body before large bubbles larger than 100um in diameter are formed, greatly reducing the probability of collision.
- the micro-bubble generating device further includes a sixth fixed base 50 , the sixth fixed base 50 is a disk-shaped structure arranged in the horizontal direction, and the third drive motor 49 is an inner rotor motor,
- the third drive motor 49 is fixedly arranged on the top of the sixth fixed base 50, the bottom end of the hollow column 51 is connected to the inner rotor of the third drive motor 49, and the gas pipeline 3 passes through the sixth fixed base 50 and the first
- the central hole of the inner rotor of the three drive motors 49 extends into the hollow column 51, and the height of the gas pipeline 3 extending into the hollow column 51 is lower than the height of the gas chamber 1, so that the gas pipeline 3 can be transported through the gas pipeline.
- the gas in the hollow column 51 can smoothly enter into each gas-containing chamber 1, and the gas itself has upward kinetic energy.
- the particle size of the fine bubbles produced in the present invention can be adjusted according to actual needs.
- the present invention has four factors to determine the particle size of the micro-bubble: the first is the pore size and air permeability of the microporous material layer 2, the pore size and air permeability of different material parameters are different, and the parameters of the same material also have certain fluctuations according to the actual use environment ;
- the second is the rotational speed of the micro-bubble cutting. The higher the rotational speed, the smaller the particle size of the micro-bubble cut, but it is also affected by the air permeability of the material.
- the third is the air pressure in the air chamber 1, which can be regulated by the air pump 5, and the larger the air pressure The larger the air output, the larger the particle size of the micro-bubble, and vice versa.
- the outer diameter of the microporous material layer 2 is increased to 240mm, and the height is increased to 1000mm, and the energy consumption per liter in this case needs to be calculated.
- the energy consumption is 12W; when the height is 66mm, the energy consumption is 7.5W.
- the surface area of the microporous material layer 2 is doubled, the energy consumption increases by 4.5W.
- the second device selection the power of the motor (brushless motor 28) is 1500W; the aperture of the microporous material layer 2 is 1 ⁇ m, the outer diameter of the microporous material layer 2 is 80 mm, and the height of the microporous material layer 2 in the vertical direction is selected 200mm; the height of the impeller 31 is 30mm, the diameter is 70mm, the number of spiral blades is 4, and the width of the spiral blades is 5mm, and the inclination of the spiral blades (that is, the angle between the horizontal directions of the spiral blades) is 10°, The width of the first liquid inlet 3001 is 2 mm, and the width of the cutting water channel 34 is 1.5 mm.
- the motor speed is 1000 rpm
- the voltage of the motor is 30V
- the current of the motor is 10A
- the air pressure in the gas chamber 1 is 0.5 atmospheres
- the air flow is 3.9L/M.
- the energy consumption required by the air pump 5 for conveying each liter of gas is 0.8W
- the total energy consumption required for conveying each liter of flow gas is 77.7W.
- the energy consumption per liter of air intake is 275W (data published by the existing manufacturer).
- the first type of equipment ie: driving the microporous material layer 2 to rotate
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- Fluid Mechanics (AREA)
- Aeration Devices For Treatment Of Activated Polluted Sludge (AREA)
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Abstract
Description
Claims (19)
- 一种微细气泡发生方法,其中,所述微细气泡发生方法包括:气体穿过微孔材料,并在所述微孔材料与液体之间的交界面上形成微细气泡;通过所述微孔材料与所述液体的相对运动,对吸附于所述微孔材料上的所述微细气泡进行冲击,以使所述微细气泡与所述微孔材料相脱离进入至所述液体内。
- 如权利要求1所述的微细气泡发生方法,其中,所述液体对所述微细气泡的剪切力大于所述微孔材料的毛细管效应对所述微细气泡的吸附力或表面张力。
- 如权利要求1或2所述的微细气泡发生方法,其中,所述液体处于静止状态,且所述微孔材料处于运动状态,并带动进入所述微孔材料中的气体同步运动,以对形成于所述微孔材料与液体之间的交界面上的微细气泡进行冲击。
- 如权利要求1或2所述的微细气泡发生方法,其中,所述微孔材料处于静止状态,且所述液体处于运动状态,以对形成于所述微孔材料与液体之间的交界面上的微细气泡进行冲击。
- 如权利要求1或2所述的微细气泡发生方法,其中,所述微孔材料为电解过程中在材料表面产生微细气泡的阴极或者阳极。
- 一种微细气泡发生装置,其中,所述微细气泡发生装置包括设置于液面以下的容气腔室和向所述容气腔室内输送气体的输气管道,所述容气腔室的外围环设有可供所述容气腔室内的气体穿过的微孔材料层,所述输气管道的一端位于所述液面以上并接入气体源,所述输气管道的另一端伸入至所述容气腔室内,以通过气压使所述容气腔室内的气体穿过所述微孔材料层并在所述微孔材料层的外表面形成微细气泡;所述微孔材料层运动和/或位于所述微孔材料层外侧的液体运动,以对所述微细气泡进行切割,使所述微细气泡进入液体内。
- 如权利要求6所述的微细气泡发生装置,其中,所述输气管道上沿气体的流向顺序设置有气泵、一级过滤器和二级过滤器,所述二级过滤器上滤芯的孔径小于所述一级过滤器上滤芯的孔径和所述微孔材料层的孔径。
- 如权利要求6或7所述的微细气泡发生装置,其中,所述输气管道上设置有流量计和压力表,所述流量计上设置有可控制气体流量的调节旋钮。
- 如权利要求8所述的微细气泡发生装置,其中,所述微细气泡发生装置还包括带动所述容气腔室周向旋转的外转子电机,所述外转子电机设置于所述容气腔室内,所述外转子电机的外转子与所述微孔材料层的下部内壁密封固定连接。
- 如权利要求9所述的微细气泡发生装置,其中,所述微细气泡发生装置还包括第一固定底座,所述微孔材料层为竖向设置的、顶部封口、底部开口的筒状结构,所述微孔材料层的顶部设置有微孔材料制成且与所述微孔材料层一体成型的密封盖,所述密封盖呈向上凸起的空心半球形结构,所述外转子电机的底部与所述第一固定底座的顶部密封固定连接。
- 如权利要求10所述的微细气泡发生装置,其中,所述输气管道包括第一输气主管,所述第一输气主管的一端位于所述液面以上,所述第一输气主管的另一端依次穿过所述第一固定底座和所述外转子电机伸入至所述容气腔室内并在所述第一输气主管的内部密封有第一封堵块,所述第一输气主管穿过所述外转子电机的中心孔并与所述外转子电机密封固定连接,位于所述容气腔室内的所述第一输气主管上连接有多根第一输气支管,各所述第一输气支管沿所述第一输气主管的周向均匀分布;所述第一输气支管包括水平管段和竖直管段,所述水平管段的一端连接于所述第一输气主管上,所述水平管段的另一端沿水平方向延伸至靠近所述微孔材料层位置并与所述竖直管段的顶端连接,所述竖直管段的底端沿竖向向下延伸。
- 如权利要求6所述的微细气泡发生装置,其中,所述容气腔室为所述微孔材料层围合形成两端封口的筒状结构,所述容气腔室的轴向沿水平方向设置,所述容气腔室的内部轴心位置沿其轴向设置有第二空心轴,所述第二空心轴上开设有与所述容气腔室相连通的多个进气孔,所述第二空心轴分别伸出至所述容气腔室的外部并分别与第一驱动电机和所述输气管道相连接。
- 如权利要求12所述的微细气泡发生装置,其中,所述容气腔室的外壁上且位于所述容气腔室的两端分别沿所述容气腔室的周向设置有环状的第一挡片。
- 如权利要求13所述的微细气泡发生装置,其中,所述容气腔室的外壁上且位于两所述第一挡片之间的位置上沿所述容气腔室的周向设置有环状的第二挡片,且所述第二挡片的直径大于所述第一挡片的直径。
- 如权利要求13所述的微细气泡发生装置,其中,所述微细气泡发生装置还包括第四固定底座和第一支架,所述第一支架的底部固定于所述第四固定底座上,所述第一驱动电机设置于所述第一支架上,所述第一驱动电机的转轴沿水平方向设置并通过调心 联轴器与所述第二空心轴的一端连接,所述第二空心轴的另一端通过轴承结构能转动地设置于所述第一支架上,且所述第二空心轴的内部通过轴承座及密封管与所述输气管道相连通。
- 如权利要求6所述的微细气泡发生装置,其中,所述微细气泡发生装置包括能沿水平方向振动的安装板,所述微孔材料层在所述安装板的顶部围合形成所述容气腔室,所述容气腔室上设置有与所述输气管道相连接的进气口,所述安装板的下方设置有第二驱动电机,所述第二驱动电机固定于所述安装板的底部中心位置,所述第二驱动电机的电机轴与沿水平方向设置的所述安装板的板面相垂直。
- 如权利要求16所述的微细气泡发生装置,其中,所述第二驱动电机为振动电机。
- 如权利要求16所述的微细气泡发生装置,其中,所述微细气泡发生装置还包括第五固定底座和第二支架,所述第二支架的底部固定于所述第五固定底座上,所述安装板为沿水平方向设置的平板状结构,且所述安装板的各边缘的中间位置分别通过弹簧与所述第二支架连接,在液面以下,所述弹簧处于水平状态。
- 如权利要求17所述的微细气泡发生装置,其中,所述安装板为方形或圆形。
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BR112023021273A BR112023021273A2 (pt) | 2021-04-15 | 2022-04-13 | Método de geração de microbolhas e dispositivo de geração |
US18/286,632 US20240198298A1 (en) | 2021-04-15 | 2022-04-13 | Micro bubble generation method and generation device |
CA3214297A CA3214297A1 (en) | 2021-04-15 | 2022-04-13 | Micro bubble generation method and generation device |
AU2022257157A AU2022257157A1 (en) | 2021-04-15 | 2022-04-13 | Micro bubble generation method and generation device |
JP2023563326A JP2024514214A (ja) | 2021-04-15 | 2022-04-13 | 微細気泡の発生方法および発生装置 |
KR1020237039029A KR20230170741A (ko) | 2021-04-15 | 2022-04-13 | 미세 기포 발생 방법 및 발생 장치 |
IL307427A IL307427A (en) | 2021-04-15 | 2022-04-13 | A method for producing micro bubbles and a device for producing micro bubbles |
EP22787555.6A EP4324550A1 (en) | 2021-04-15 | 2022-04-13 | Micro bubble generation method and generation device |
MX2023012147A MX2023012147A (es) | 2021-04-15 | 2022-04-13 | Metodo de generacion de microburbujas y dispositivo de generacion. |
ZA2023/09449A ZA202309449B (en) | 2021-04-15 | 2023-10-10 | Micro bubble generation method and generation device |
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CN116943398A (zh) * | 2023-07-20 | 2023-10-27 | 威海中远海运重工科技有限公司 | 一种微气泡与超重力组合式船舶烟气co2脱除装置 |
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IL307427A (en) | 2023-12-01 |
JP2024514214A (ja) | 2024-03-28 |
BR112023021273A2 (pt) | 2023-12-12 |
CN113144928A (zh) | 2021-07-23 |
US20240198298A1 (en) | 2024-06-20 |
ZA202309449B (en) | 2024-04-24 |
KR20230170741A (ko) | 2023-12-19 |
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