WO2022215668A1 - 加熱蒸散用組成物およびそれを用いた有害節足動物の駆除方法 - Google Patents
加熱蒸散用組成物およびそれを用いた有害節足動物の駆除方法 Download PDFInfo
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- WO2022215668A1 WO2022215668A1 PCT/JP2022/016996 JP2022016996W WO2022215668A1 WO 2022215668 A1 WO2022215668 A1 WO 2022215668A1 JP 2022016996 W JP2022016996 W JP 2022016996W WO 2022215668 A1 WO2022215668 A1 WO 2022215668A1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P17/00—Pest repellants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P7/00—Arthropodicides
- A01P7/04—Insecticides
Definitions
- TECHNICAL FIELD The present invention relates to a thermal transpiration composition containing natural pyrethrins and pyrethroids and a method for exterminating arthropod pests using the same.
- Patent Literature 1 describes that a certain composition for heat vaporization has an exterminating effect on mosquitoes.
- composition for heat transpiration may not necessarily have a sufficient extermination effect on arthropod pests.
- the present inventor conducted studies in order to provide a composition for heat transpiration that is highly effective in exterminating harmful arthropods. As a result, the present inventors have found that a composition for heat vaporization containing natural pyrethrin and a pyrethroid compound in a specific ratio exhibits an excellent extermination effect against arthropod pests, and completed the present invention.
- the present invention includes, but is not limited to, the following aspects.
- a composition for thermal transpiration comprising natural pyrethrins and a pyrethroid compound, wherein the weight ratio of the active ingredient of the natural pyrethrins to the pyrethroid compound is in the range of 20:1 to 200:1.
- 2. The composition for thermal evaporation according to the preceding item 1, wherein the pyrethroid compound has a vapor pressure of 0.00001 Pa to 0.1 Pa at 25°C. 3.
- the pyrethroid compound is at least one pyrethroid compound selected from the group consisting of metofluthrin, dimefluthrin, transfluthrin, profluthrin, mepafluthrin, heptafluthrin, tetramethylfluthrin, and lenofluthrin.
- composition 4.
- An incense stick containing the composition according to any one of the preceding items 1 to 3.
- a mat preparation comprising the composition according to any one of the preceding Items 1 to 3. 7.
- a pest control preparation for heat transpiration comprising the composition according to any one of the preceding items 1 to 3.
- composition for thermal evaporation of the present invention exhibits excellent efficacy.
- the natural pyrethrin used in the invention includes six active ingredients: Pyrethrin I, Pyrethrin II, Cinerin I, Cinerin II, Jasmoline I, and Jasmoline II. Contains compounds. Natural pyrethrins are typically obtained by extracting only the flower antlers of pyrethrum (scientific name: Tanacetum cinerariifolium or Chrysanthemum cinerariaefolium), drying and pulverizing them, and adding an appropriate solvent such as methanol to dissolve the active ingredients in the powder. It can be obtained as an extract obtained by extracting using a pyrethrum dry powder.
- Natural pyrethrins may contain plant-derived impurities (fatty acids, flavonoids, etc.) in addition to the above six compounds.
- plant-derived impurities fatty acids, flavonoids, etc.
- As plants from which natural pyrethrins can be obtained in addition to the above-mentioned Pyrethrin, Calendula officinalis, Chrysanthemum coccinum, Tagetes erecta, Tagetes minuta, Zinnia elegans, Zinia linnearis, etc. are also known (Reference 1: Adnane). H. Alain, C. & Chantal, B. 2000. The Production of Pyrethrins by Plant Cell and Tissue Cultures of Chrysanthemum cinerariaefolium and Tagetes Species.
- the plant species and cultivars that serve as sources thereof are not limited to those mentioned above.
- the cultivation method, cultivation conditions (weather, production area, soil properties, etc.), harvest time, harvest part, harvest method, washing method, extraction method and purification method of the plant are not particularly limited.
- the natural pyrethrins used in the present invention include, for example, natural pyrethrins obtained using vectors incorporating genes encoding pyrethrin biosynthetic enzymes.
- the weight ratio of the six compounds of pyrethrin I, pyrethrin II, synerin I, synerin II, jasmolin I, and jasmolin II in natural pyrethrin is not particularly limited, and may be any weight ratio within the range of 0.001 to 99%. can be set, typically 10-70% pyrethrin I, 10-70% pyrethrin II, 1-20% synerin I, 1-20% synerin II, and 1-20% jasmolin I , jasmolin II in a weight ratio of 1-20%.
- Natural pyrethrins include pyrethrin I (total amount of pyrethrin I, synerin I, jasmolin I) and pyrethrin II (total amount of pyrethrin II, synerin II, jasmolin II), pyrethrin I at 20-40%, pyrethrin II , and the total amount of pyrethrins I and II in natural pyrethrins is usually 10 to 99%, preferably 15 to 90%, more preferably 20 to 85%. .
- natural pyrethrins are usually plant extracts, they may contain plant-derived impurities and auxiliary ingredients such as solvents and stabilizers in addition to the above six compounds.
- Solvents that can be used include petroleum and vegetable oils, and stabilizers that can be used include synthetic stabilizers and natural stabilizers.
- the active ingredients of natural pyrethrins in the present invention refer to pyrethrins I and II, and the fact that the weight ratio of the active ingredient of natural pyrethrins to the pyrethroid compound is in the range of 20:1 to 200:1 means that The ratio of the total weight of pyrethrins I and II to the weight of the pyrethroid compound is defined to be in the range of 20:1 to 200:1.
- pyrethroid compounds used in the present invention include pyrethroid compounds described in Reference (The Pesticide manual, Eighteenth edition, J. A. Turner, British Crop Production Council, ISBN 978-1-9998966-1-4). be done. From the viewpoint of transpiration, a pyrethroid compound having a vapor pressure of 0.00001 Pa to 0.1 Pa at 25°C is preferred. More specifically, at least one compound selected from the group consisting of metofluthrin, dimefluthrin, transfluthrin, profluthrin, mepafluthrin, heptafluthrin, tetramethylfluthrin, and lenofluthrin from the viewpoint of transpiration and efficacy. . The vapor pressure is measured using the method described in Example 1 of JP-A-2006-284560.
- composition for thermal transpiration of the present invention can also be described as an insecticidal composition for thermal transpiration as its aspect.
- Formulations using heat-transpiration compositions include, for example, incense sticks, mosquito mats, and heat-transpiration pest control formulations. However, it is not intended to be limited to the configurations described in the embodiments described below.
- the incense stick of the present invention typically comprises the composition for heat transpiration, a carbide base material, a combustion support agent, a bulking agent, a caking agent, and the like.
- carbide base material examples include charcoal, bamboo charcoal, vegetable activated carbon, coconut shell charcoal, and coffee grounds charcoal.
- Non-vegetable carbonized substrates such as activated carbon and petroleum activated carbon can be used, and vegetable-derived carbonized substrates are particularly preferred. Usually, these are used individually or in mixture of 2 or more types.
- fire-supporting agents examples include wood powder, tab powder (tab tree bark powder), lees powder (pyrrethrum extract powder), citrus skin powder, tea powder, palm oil powder, coconut shell powder, walnut shell powder, and other plants. Dry powders and carbon powders such as charcoal powder, activated carbon powder, and coal powder can be mentioned, and these can be used alone or in combination of two or more.
- Bulking agents include diatomaceous earth, talc, clay, and kaolin. These extenders are usually used alone or in combination of two or more.
- binders include polymeric compounds such as tab powder, starch (pregelatinized starch, tapioca starch, corn starch, wheat starch, etc.), casein, sham flour, methylcellulose, carboxymethylcellulose, and polyvinyl alcohol. are used alone or in combination of two or more.
- the amount of the carbide base material, the combustion support agent, the bulking agent, the binder, etc. can be freely adjusted according to the desired quality, but the total amount thereof is 85% by weight based on the weight of the entire mosquito coil. or more, more preferably 90% by weight or more.
- the incense stick of the present invention is, for example, kneaded by adding an appropriate amount of water to a mixture containing a composition for heat transpiration and an incense base material, molded by an extruder, a punching machine, etc., and then dried naturally or by heating.
- the composition for thermal evaporation may not be directly mixed with the mixture containing the base material for incense sticks, but may be coated or sprayed with a liquid agent containing the composition for thermal evaporation after molding only the base material for incense sticks.
- the shape of the incense stick of the present invention is not particularly limited. Rod-shaped, spiral-shaped and plate-shaped are preferred.
- the size is also not particularly limited, but for example, when the shape of the incense stick is rod-shaped, it is preferable to set the total length to 100 mm or less, the thickness to 7 mm or less, and the weight to 5 g or less. It is more preferable to set the weight to 0.2g or more and 3g or less, and if the shape of the incense stick is spiral, it is preferable to set the total length to 150cm or less, the thickness to 7mm or less, and the weight to 50g or less.
- the thickness is more preferable to set the thickness to 90 cm or more, the thickness to 2 mm or more to 5 mm or less, and the weight to 5 g or more and 20 g or less.
- the size is usually about 12 cm in diameter and 3 to 5 mm in thickness for a set of two.
- incense sticks are usually scented with appropriate scents, and recently, various volatile fragrance ingredients have been added for the purpose of obtaining aroma effects and relaxing effects. be.
- Various fragrance components can be added to the incense stick of the present invention for the purpose of obtaining aroma effects and relaxing effects.
- perfume ingredients include galaxolide, musk ketone, hexyl cinnamic aldehyde, isoe super, methyl dihydrojasmonate, ethylene brassylate, geraniol, methyl atralate, hexyl salicylate, tricyclodecenyl acetate, oranger crystal, ambro Xane, Tonalide (6-acetyl-1,1,2,4,4,7-hexamethyltetralin), ⁇ -Undecalactone, Cashmelan, Charon, Heliotropine, Dihydroindenyl-2,4-dioxane, ⁇ -isomethylionone, indole, methyl cedryl ketone, methyl beta-naphthyl ketone, rosephenone, coumarin, vanillin, styrax resinoid, benzyl benzoate, undecanal, benzyl salicylate, ionone, alpha-
- the content of the perfume component is preferably 0.001 to 5% by weight, more preferably 0.01 to 1% by weight, based on the total weight of the incense stick. If the content of the perfume component is less than 0.001% by weight, it may not be possible to create a sufficient fragrance. If the content of the perfume component exceeds 5% by weight, the odor and irritation may become too strong.
- the incense stick of the present invention can contain antifungal agents, preservatives, stabilizers, potency enhancers, deodorants, etc. as other ingredients.
- antifungal agents or preservatives include dehydroacetate, sorbate, p-hydroxybenzoate, and the like.
- stabilizers examples include 2,6-di-tert-butyl-4-methylphenol (BHT), 2,2'-methylenebis(4-methyl-6-tert-butylphenol), 2,2'-methylenebis(4 -ethyl-6-tertiarybutylphenol), 4,4'-butylidenebis(3-methyl-6-tertiarybutylphenol), 4,4'-thiobis(3-methyl-6-tertiarybutylphenol), 2-tertiary Butyl-6-(3-tert-butyl-2-hydroxy-5-methylbenzyl)-4-methylphenyl acrylate, 2,4-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxy benzoate and the like.
- BHT 2,6-di-tert-butyl-4-methylphenol
- BHT 2,2'-methylenebis(4-methyl-6-tert-butylphenol)
- the incense stick of the present invention can contain colorants such as malachite green and food additives (food blue No. 1, food yellow No. 4, food red No. 106, etc.).
- the mat preparation of the present invention is prepared by applying a solution obtained by mixing a composition for thermal evaporation, a solvent, a pigment, an antioxidant, a synergist, a stabilizer, a perfume, etc., to a fibrous carrier or porous carrier. It can be produced by impregnation.
- the mat formulation can be used, for example, as an electric mosquito mat.
- fibrous carriers include natural fibers such as pulp, cellulose and cotton, synthetic fibers such as polyester and acrylic, and inorganic fibers such as glass fibers and asbestos.
- porous carriers include diatomaceous earth. porous inorganic substances, porous magnetic substances such as bisque, and porous resins such as urethane foam and polypropylene foam.
- the size of the electric mosquito repelling mat is usually about 2.2 cm ⁇ 3.5 cm ⁇ 0.28 cm, but it is not limited to this shape, and the shape, size, and thickness of the mat
- the amounts and ratios of the composition for thermal evaporation and other components to be blended can be appropriately adjusted in accordance with changes such as the above.
- the content of the composition for heating and transpiration per sheet of the 2.2 cm ⁇ 3.5 cm ⁇ 0.28 cm mat is the type and content of the composition for heating and transpiration, and the use of an electric mosquito mat. Although it varies depending on time, etc., it is usually about 1 to 2000 mg, preferably about 1 to 100 mg.
- the heat-transpiration pest control formulation of the present invention is a formulation that can be used, for example, in a heat-transpiration type insecticidal device as shown in FIG.
- a chemical solution bottle 4 is filled with a solution 1 containing a composition for thermal evaporation.
- Part of the absorbent core 3 is immersed in the solution 1, the absorbent core is made to absorb the solution containing the composition for thermal evaporation, and the upper part of the absorbent core is heated by the heating element 2. can be done.
- the heat-transpiration pest control preparation of the present invention is not limited to the apparatus shown in FIG. Heat-transpiration-type insecticidal devices to which the heat-transpiration pest control preparation of the present invention can be applied are described in, for example, Japanese Patent Publication No. 52-12106, Japanese Utility Model Publication No. 58-45670, and Japanese Patent Application Laid-Open No. 2012-176947. there is
- the composition for heat transpiration is prepared in the form of a solution (solution 1) containing the composition for heat transpiration.
- An oily solvent or an aqueous solvent is used as the solvent for preparing the pest control formulation for thermal evaporation.
- an oily solvent having a boiling point of 350° C. or lower is usually used.
- various organic solvents typically hydrocarbon solvents, can be used.
- aliphatic hydrocarbons paraffinic hydrocarbons and unsaturated aliphatic hydrocarbons
- solvents include deodorized kerosene, n-paraffin, isoparaffin (eg, IP Solvent (manufactured by Idemitsu Kosan Co., Ltd.)), sewing lube (manufactured by ENEOS), and the like.
- non-hydrocarbon organic solvents include glycerin, propylene glycol, methanol, acetone, xylene, chloroform, isopropanol, and chloroform.
- an aqueous solvent usually glycol ether and water are used.
- glycol ethers include, for example, ethylene glycol-based ethers, propylene glycol-based ethers, and dialkyl glycol-based ethers, preferably ethylene glycol-based ethers.
- ethylene glycol-based ethers ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, and propylene glycol monopropyl ether are preferred.
- Glycol ethers can be used singly or as a mixture of two or more.
- the weight ratio of glycol ether to water is usually in the range of 1:0.4 to 1:8.5, preferably in the range of 1:1 to 1:8.5, more preferably in the range of 1:1.4 to 1:3. .6 range.
- the concentration of the composition for heat transpiration in the pest control preparation for heat transpiration is usually adjusted to about 6 to 80% by weight, preferably about 10 to 75% by weight, more preferably about 15 to 50% by weight.
- the heat transpiration pest control preparation of the present invention may contain other components such as thickeners, surfactants, stabilizers, preservatives, and synergists.
- heat generating element 2 used in the thermal transpiration type insecticidal apparatus
- a heat generating element that generates heat when energized is generally used, but is not limited to this. Any known heating element such as a heating material using a platinum catalyst or the like can be used.
- the absorbent core 3 is generally made of a porous material.
- the porous material include inorganic powders such as clay, talc, kaolin, diatomaceous earth, gypsum, perlite, bentonite, acid clay, glass fiber and asbestos, and inorganic powders such as carboxymethylcellulose, starch, gum arabic, gelatin and polyvinyl alcohol. It is usually used after it has been caking and molded with a paste.
- the absorbent core may contain pigments, preservatives, antioxidants, etc., as appropriate, and can be contained, for example, by mixing the inorganic powder and the paste at the time of caking.
- Pests to be controlled by the composition for thermal transpiration of the present invention and formulations using the composition for thermal transpiration include various harmful insects and arthropods such as mites, particularly harmful flying insects such as Culex pipiens, Culex species such as Culex pipiens, Culex aegypti, and Culex pipiens, Aedes mosquitoes such as Aedes aegypti and Aedes albopictus, Anopheles mosquitoes such as China anopheles, Chironomid, House flies such as house fly, Japanese house fly, and lesser flies, blow flies, flesh flies, fruit flies, fruit flies, fleas flies Diptera pests such as genus, gadflies, blackflies, biting flies, biting midges and the like. Among them, mosquitoes such as Culex, Aedes, and Anopheles are particularly mentioned as insect pests to be controlled.
- Production example 1 (kneaded incense stick 1) 1 part by weight of natural pyrethrin, 0.05 part by weight of dimeflutrin, 39 parts by weight of tab powder, 30 parts by weight of lees powder, and 30 parts by weight of wood powder as a combustion improver are mixed, and 0.3 part by weight of green pigment is added to obtain a uniform mixture. After stirring and mixing, 120 parts by weight of water was added and sufficiently kneaded. The kneaded product is molded into a sheet, punched out in a spiral shape, and dried until the moisture content reaches about 7 to 10% by weight to prepare the incense preparation of the present invention.
- Production example 2 (kneaded incense stick 2) 1 part by weight of natural pyrethrin, 0.05 part by weight of dimeflutrin, 50 parts by weight of charcoal as a carbonized base material, 0.8 parts by weight of a mixed perfume containing galaxolide, musk ketone, etc. as a perfume component, 17 parts by weight of lees powder as a combustion-supporting agent, and 10.7 parts by weight of wood flour, 3 parts by weight of diatomaceous earth as a bulking agent, and 14 parts by weight of pregelatinized starch and 3 parts by weight of carboxymethyl cellulose as a binding agent are mixed, and 90 parts by weight of water is added to the mixture. Kneaded. The kneaded product is extruded into a rod shape and then dried until the moisture content reaches about 7 to 10% by weight to prepare the incense preparation of the present invention.
- Production Example 3 (mat preparation 1) Obtained by mixing 10.5 parts by weight of natural pyrethrins, 0.5 parts by weight of transfluthrin, 39.5 parts by weight of acetyltributyl citrate, 39.5 parts by weight of isononyl adipate, 5 parts by weight of blue pigment and 5 parts by weight of perfume. 120 mg of the resulting solution was uniformly impregnated into an electric mat base material (fibrous carrier made of pulp and cotton linter) of 2.1 cm x 3.4 cm and 0.22 cm thickness to obtain the electric mosquito mat preparation of the present invention. to make.
- an electric mat base material fibrous carrier made of pulp and cotton linter
- Production Example 4 (mat formulation 2) 20.0% by weight of natural pyrethrin, 1.0% by weight of metofluthrin, 10% by weight of dibutylhydroxytoluene, 25% by weight of diisononyl adipate, 30% by weight of tributyl acetate citrate, and an isoparaffin-based solvent (manufactured by Showa Shell Sekiyu K.K., trade name : Merveille 40) Dissolve 8 mg of 1,4-dibutylaminoanthraquinone and 40 mg of 1,8-bis(phenylthio)dodecahydroanthraquinone in 5 g of a solution consisting of 14.0% by weight.
- a base material for an electric mat (a fibrous carrier made of pulp and cotton linter) having a thickness of 0.28 cm is uniformly impregnated to prepare the electric mosquito mat formulation of the present invention.
- Production Example 6 (mat formulation 4) 50.0% by weight of natural pyrethrin, 0.25% by weight of metofluthrin, 15% by weight of dibutylhydroxytoluene, 4.75% by weight of diisononyl adipate, 20% by weight of tributyl acetate citrate, and an isoparaffin solvent (manufactured by Showa Shell Sekiyu K.K., Trade name: Merveille 40) 8 mg of 1,4-dibutylaminoanthraquinone and 40 mg of 1,8-bis(phenylthio)dodecahydroanthraquinone are dissolved in 5 g of a 10% by weight solution, and 2000 mg of the solution is 2.2 cm x 3.5 cm. , a base material for an electric mat (fibrous carrier made of pulp and cotton linter) having a thickness of 0.28 cm is uniformly impregnated with the material to prepare the electric mosquito mat formulation of the present invention.
- an electric mat
- Production Example 8 (Insect Control Formulation 2 for Thermal Transcription) 10.5 parts by weight of natural pyrethrin and 0.5 parts by weight of metofluthrin are mixed and dissolved in 89 parts by weight of deodorized kerosene, the resulting solution is filled in a 45 mL vinyl chloride container, and the upper part is closed through an inner plug. By inserting a porous liquid-absorbent wick (inorganic powder solidified with a binder and sintered) that can be heated by a heater, the insect pest control preparation for heating and transpiration of the present invention is prepared.
- a porous liquid-absorbent wick inorganic powder solidified with a binder and sintered
- Production Example 9 (pest control preparation for heat transpiration 3) 10.5 parts by weight of natural pyrethrin and 0.5 parts by weight of metofluthrin are mixed and dissolved in 50 parts of diethylene glycol monobutyl ether, 1.8 parts of dibutylhydroxytoluene, and 46.7 parts of water.
- the pest control preparation for thermal transpiration of the present invention is prepared by filling a plastic container and inserting a porous liquid-absorbing wick whose upper part can be heated by a heater through an inner plug.
- test preparation 75 parts by weight of wood flour, 5 parts by weight of tab powder, 5 parts by weight of lees powder, 10 parts by weight of Siamese powder and 5 parts by weight of tapioca starch are mixed, and an appropriate amount of water is added to make the test preparation (incense stick). Kneaded. The kneaded material was molded into a sheet, punched out in a spiral shape, and then dried until the water content reached about 7 to 10% by weight to prepare a blank incense stick. An acetone solution of the test compound diluted to a predetermined concentration was evenly dripped onto the blank incense stick thus obtained, and air-dried to prepare a test formulation.
- Test example 1 Twenty adult female Culex pipiens pallens were placed in a glass tube with a diameter of 4.5 cm and a height of 12 cm. A metal tube having a diameter of 22 cm and a height of 83 cm was placed upright, and two glass tubes containing the Culex pipiens were placed upright and fixed in the upper opening. The formulation prepared by the above method was ignited and placed in the lower opening of the metal cylinder. The knockdown population of Culex pipiens was recorded after 6 minutes. The experiment was repeated three times to determine the knockdown rate (hereinafter abbreviated as KD rate).
- KD rate the knockdown rate
- the KD rate expected when these are mixed is calculated from Colby's formula and is shown in Table 1 below as an expected value.
- the concentration of natural pyrethrins represents the concentration of the active ingredient in natural pyrethrins.
- Theoretical expected value (%) based on Colby's formula A + (100-A) x B/100
- a and B mean the following numbers A: KD rate (%) when only A is processed B: KD rate (%) when only B is treated
- Test example 2 Twenty adult female Culex pipiens pallens were placed in a glass tube with a diameter of 4.5 cm and a height of 12 cm. A metal cylinder having a diameter of 22 cm and a height of 83 cm was placed upright, and two glass tubes containing the Culex pipiens were erected and fixed in the upper opening. The formulation prepared by the above method was ignited and placed in the lower opening of the metal cylinder. After 7 minutes, the number of knockdown (hereinafter referred to as KD) populations of Culex pipiens was recorded. The experiment was repeated three times to obtain the KD rate. In addition, the KD ratio expected from the KD ratio when natural pyrethrin and each pyrethroid compound are used alone is calculated from Colby's formula and shown in Table 2 below as an expected value.
- KD knockdown
- Test example 3 Twenty adult female Culex pipiens pallens were placed in a glass tube with a diameter of 4.5 cm and a height of 12 cm. A metal cylinder having a diameter of 22 cm and a height of 83 cm was placed upright, and two glass tubes containing the Culex pipiens were erected and fixed in the upper opening. The formulation prepared by the above method was ignited and placed in the lower opening of the metal cylinder. After 10 minutes, the number of knockdown (hereinafter referred to as KD) populations of Culex pipiens was recorded. The experiment was repeated three times to obtain the KD rate. The KD ratios expected from the KD ratios when the natural pyrethrin and each pyrethroid compound were used alone were calculated from Colby's formula and shown in Table 3 below as expected values.
- KD knockdown
- the incense sticks of the present invention containing natural pyrethrins and pyrethroid compounds at a predetermined mixing ratio are more effective than those expected from the effects of natural pyrethrins or pyrethroid compounds alone. was also shown to be highly effective.
- Test example 4 Twenty Culex pipiens pallens female adults are placed in a glass tube with a diameter of 4.5 cm and a height of 12 cm. A metal cylinder with a diameter of 22 cm and a height of 83 cm is erected, and two glass tubes containing the Culex pipiens are erected and fixed in the upper opening. A mat preparation of the present invention prepared according to Formulation Example 3 or 4 is obtained. The mat preparation is set in a commercially available insecticidal mat heater, placed in the lower opening of a metal cylinder, and heated. After 10 minutes, the knockdown (hereinafter referred to as KD) population of Culex pipiens is recorded to obtain the KD rate.
- KD knockdown
- the mat preparation of the present invention containing natural pyrethrins and pyrethroid compounds in a predetermined mixing ratio exerts a higher effect than expected from the effects of natural pyrethrins or pyrethroid compounds alone. can.
- the composition for heat transpiration shown in Table 4 below can be mentioned.
- the mat formulation of the present invention containing natural pyrethrin and each pyrethroid compound in a predetermined mixing ratio exhibited a higher effect than expected from the effect of natural pyrethrin or each pyrethroid compound alone. It can be confirmed that it works.
- Test example 5 Twenty Culex pipiens pallens female adults are placed in a glass tube with a diameter of 4.5 cm and a height of 12 cm. A metal cylinder with a diameter of 22 cm and a height of 83 cm is erected, and two glass tubes containing the Culex pipiens are erected and fixed in the upper opening. A pest control preparation for thermal evaporation of the present invention prepared according to Formulation Examples 7, 8 or 9 is obtained. The heat-transpiration pest control preparation is set in the heat-transpiration type insecticidal device shown in FIG. 1, placed in the lower opening of the metal cylinder, and heated. After 10 minutes, the knockdown (hereinafter referred to as KD) population of Culex pipiens is recorded to obtain the KD rate.
- KD knockdown
- the thermally transpirable pest control preparation of the present invention which contains natural pyrethrins and pyrethroid compounds in a predetermined mixing ratio, exhibits a higher effect than is expected from the effects of the natural pyrethrins or the pyrethroid compounds alone. can be confirmed.
- the composition for heat transpiration used in the pest control preparation for heat transpiration which can be confirmed to be highly effective in this test example, the composition for heat transpiration shown in Table 5 below can be mentioned.
- the thermally transpirable pest control preparation of the present invention containing natural pyrethrin and each pyrethroid compound at a predetermined mixing ratio is more effective than expected from the effect of natural pyrethrin or each pyrethroid compound alone. It can be confirmed that a high effect is exhibited.
- composition for thermal transpiration of the present invention By using the composition for thermal transpiration of the present invention, it is possible to control harmful arthropods.
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Abstract
Description
本発明は天然ピレトリンとピレスロイドを含有する加熱蒸散用組成物およびそれを用いた有害節足動物の駆除方法に関する。
1.天然ピレトリン及びピレスロイド系化合物を含み、天然ピレトリンの有効成分とピレスロイド系化合物の重量比が20:1~200:1の範囲であることを特徴とする加熱蒸散用組成物。
2.ピレスロイド系化合物が、25℃において0.00001Pa~0.1Paの蒸気圧を有するピレスロイド系化合物である前項1に記載の加熱蒸散用組成物。
3.ピレスロイド系化合物が、メトフルトリン、ジメフルトリン、トランスフルトリン、プロフルトリン、メパフルトリン、へプタフルトリン、テトラメチルフルトリン、およびレノフルトリンからなる群から選ばれる少なくとも1つのピレスロイド系化合物である前項1または2に記載の加熱蒸散用組成物。
4.前項1~3の何れか一項に記載の組成物を含んでなる線香。
5.前項1~4の何れか一項に記載の組成物または線香を用いる蚊の駆除方法。
6.前項1~3の何れか一項に記載の組成物を含んでなるマット製剤。
7.前項1~3および前項6の何れか一項に記載の組成物またはマット製剤を用いる蚊の駆除方法。
8.前項1~3の何れか一項に記載の組成物を含んでなる加熱蒸散用害虫防除製剤。
9.前項1~3および前項8の何れか一項に記載の組成物または加熱蒸散用害虫防除製剤を用いる蚊の駆除方法。
天然ピレトリンは、典型的には、除虫菊(シロバナムシヨケギク、学名Tanacetum cinerariifoliumもしくはChrysanthemum cinerariaefolium)の花愕部だけを採取し乾燥・粉砕した粉末より有効成分を溶解する適当な溶剤、例えばメタノール等の有機溶剤を用いて抽出して得られる抽出エキスもしくは除虫菊乾燥粉末として入手できる。天然ピレトリンは前記6種類の化合物の他に、植物由来の不純物(脂肪酸やフラボノイド類等)を含んでいることもある。天然ピレトリンが得られる植物としては、前記シロバナムシヨケギクの他にキンセンカCalendula officinalis, アカバナムシヨケギクChrysanthemum coccinum, センジュギクTagetes erecta, シオザキソウTagetes minuta, ヒャクニチソウZinnia elegans, ホソバヒャクニチソウZinia linnearisなども知られている(参考文献1:Adnane. H. Alain, C. & Chantal, B. 2000. The Production of Pyrethrins by Plant Cell and Tissue Cultures of Chrysanthemum cinerariaefolium and Tagetes Species. Critical Reviews in Plant Sciences, 19(1):69-89、参考文献2:Kudakasseril, G. J. and Staba, E. J. 1988. Insecticidal phytochemicals. In: Cell Culture and Somatic Cell Genetics of Plants. pp. 537-552. Constabel, F. and Vasil, I. K., Eds., Academic Press, New York、参考文献3:John E.Casida,Gary B.Quistad. 1995. PYRETHRUM FLOWERS, Production,Chemistry,Toxicology,and Uses. pp.123-125, Oxford University Press.)。
溶剤としては、石油系、植物油系等、安定化剤としては、合成安定化剤、天然系安定化剤等が使用可能である。
なお蒸気圧は、特開2006-284560号公報の実施例1に記載の方法を用いて測定される。
なお加熱蒸散用組成物は線香基材を含有する混合物に直接混合せずに、線香基材のみを成型後に加熱蒸散用組成物を含む液剤を塗布あるいはスプレーしてもよい。
なお、渦巻き型の場合は、通常、その大きさは通常2本一組で直径12cm、厚さ3~5mm程度である。
本発明のマット製剤は、例えば、加熱蒸散用組成物及び溶剤、色素、酸化防止剤、共力剤、安定化剤、香料などを混合して得られる溶液を、繊維質担体や多孔質担体に含浸させることによって製造することができる。該マット製剤は、例えば、電気蚊取り用マットとして用いることができる。
本発明の加熱蒸散用害虫防除製剤とは、例えば図1に示すような加熱蒸散型殺虫装置で用いることのできる製剤である。加熱蒸散用組成物を含む溶液1が薬液ボトル4に充填されている。溶液1中に吸液芯3の一部が浸漬されており、該吸液芯に該加熱蒸散用組成物を含む溶液を吸液させ、該吸液芯の上部を発熱体2で加熱することができるようになっている。該吸液芯の上部を約60℃~約135℃の温度に加熱体2で間接加熱することにより、該吸液芯に吸液された加熱蒸散用組成物を大気中に蒸散させることにより、害虫を防除することができる。本発明の加熱蒸散用害虫防除製剤は、図1に示すような装置に限定されず、従来公知の加熱蒸散型殺虫装置に適用して、いずれも優れた効果を奏し得る。本発明の加熱蒸散用害虫防除製剤の適用できる加熱蒸散型殺虫装置は、例えば特公昭52-12106号公報、実開昭58-45670号公報等、特開2012-176947号公報にも記載されている。
加熱蒸散用害虫防除製剤を調製するための溶剤としては、油性溶剤または水性溶剤が用いられる。
油性溶剤を用いる場合、通常、沸点が350℃以下の油性溶剤が用いられる。かかる油性溶剤としては、各種の有機溶剤、代表的には炭化水素系溶剤をいずれも使用できるが、特に沸点範囲が150~350℃の脂肪族系炭化水素(パラフィン系炭化水素及び不飽和脂肪族炭化水素)が好ましい。かかる溶媒としては、例えば、脱臭灯油、n-パラフィン、イソパラフィン(例えば、IPソルベント(出光興産株式会社製))、ソーイングルブ(ENEOS製)等が好ましい。上記炭化水素系以外の有機溶剤としては、例えばグリセリン、プロピレングリコール、メタノール、アセトン、キシレン、クロルセン、イソプロパノール、クロロホルム等が挙げられる。
水性溶剤を用いる場合、通常、グリコールエーテルおよび水が用いられる。かかるグリコールエーテルとしては、例えば、エチレングリコール系エーテル、プロピレングリコール系エーテル、およびジアルキルグリコール系エーテルが挙げられ、好ましくはエチレングリコール系エーテルが用いられる。また、エチレングリコール系エーテルにおいては、エチレングリコールモノブチルエーテル及びジエチレングリコールモノブチルエーテル、プロピレングリコールモノメチルエーテル、プロピレングリコールモノエチルエーテル、プロピレングリコールモノプロピルエーテルが好ましい。なお、グリコールエーテルは、1種又は2種以上の混合物を使用することができる。グリコールエーテルと水との重量比は通常1:0.4~1:8.5の範囲、好ましくは1:1~1:8.5の範囲、さらに好ましくは1:1.4~1:3.6の範囲である。
加熱蒸散用害虫防除製剤における加熱蒸散用組成物の濃度は、通常、約6~80重量%、好ましくは約10~75重量%、より好ましくは約15~50重量%となるように調製される。
本発明の加熱蒸散用害虫防除製剤には、その他の成分として、増粘剤、界面活性剤、安定化剤、防腐剤、共力剤等を含有させることも可能である。
天然ピレトリン1重量部、ジメフルトリン0.05重量部、支燃剤として、タブ粉39重量部、粕粉30重量部および木粉30重量部と混合し、さらに緑色色素0.3重量部を加え、均一に攪拌混合した後、水120重量部を添加して十分に混練した。混錬物をシート状に成型、渦巻き状に打ち抜いた後、水分含有量が7~10重量%程度となるまで乾燥させ、本発明の線香製剤を作製する。
天然ピレトリン1重量部、ジメフルトリン0.05重量部、炭化物基材として木炭 50重量部、香料成分として、ガラクソリドおよびムスクケトン等を含む混合香料 0.8重量部、 支燃剤として、粕粉 17重量部および木粉 10.7重量部、増量剤として珪藻土3重量部、さらに粘結剤として、α化澱粉14重量部およびカルボキシメチルセルロース3重量部を混合し、これらに水90重量部を添加して十分に混練した。混練物を押出機にかけて棒状に成型し、その後、水分含有量が7~10重量%程度となるまで乾燥させ、本発明の線香製剤を作製する。
天然ピレトリン10.5重量部トランスフルトリン0.5重量部、クエン酸アセチルトリブチル39.5重量部、アジピン酸イソノニル39.5重量部、青色色素5重量部および香料5重量部を混合して得られる溶液120mgを、2.1cm×3.4cm、厚さ0.22cmの電気マット用基材(パルプ及びコットンリンターからなる繊維質担体)に均一に含浸させて、本発明の電気蚊取り用マット製剤を作製する。
天然ピレトリン20.0重量%、メトフルトリン1.0重量%、ジブチルヒドロキシトルエン10重量%、アジピン酸ジイソノニル25重量%、クエン酸トリブチルアセテート30重量%およびイソパラフィン系溶剤(昭和シェル石油株式会社製、商品名:メルベイユ40)14.0量%からなる溶液5gに、1,4-ジブチルアミノアントラキノン8mg、1,8-ビス(フェニルチオ)ドデカヒドロアントラキノン40mgを溶かし、該溶液120mgを2.2cm×3.5cm、厚さ0.28cmの電気マット用基材(パルプ及びコットンリンターからなる繊維質担体)に均一含浸させて、本発明の電気蚊取り用マット製剤を作製する。
天然ピレトリン50.0重量%、メトフルトリン0.25重量%、ジブチルヒドロキシトルエン15重量%、アジピン酸ジイソノニル4.75重量%、クエン酸トリブチルアセテート20重量%およびイソパラフィン系溶剤(昭和シェル石油株式会社製、商品名:メルベイユ40)10重量%からなる溶液5gに、1,4-ジブチルアミノアントラキノン8mg、1,8-ビス(フェニルチオ)ドデカヒドロアントラキノン40mgを溶かし、該溶液500mgを2.2cm×3.5cm、厚さ0.28cmの電気マット用基材(パルプ及びコットンリンターからなる繊維質担体)に均一含浸させて、本発明の電気蚊取り用マット製剤を作製する。
天然ピレトリン50.0重量%、メトフルトリン0.25重量%、ジブチルヒドロキシトルエン15重量%、アジピン酸ジイソノニル4.75重量%、クエン酸トリブチルアセテート20重量%およびイソパラフィン系溶剤(昭和シェル石油株式会社製、商品名:メルベイユ40)10重量%からなる溶液5gに、1,4-ジブチルアミノアントラキノン8mg、1,8-ビス(フェニルチオ)ドデカヒドロアントラキノン40mgを溶かし、該溶液2000mgを2.2cm×3.5cm、厚さ0.28cmの電気マット用基材(パルプ及びコットンリンターからなる繊維質担体)に均一含浸させて、本発明の電気蚊取り用マット製剤を作製する。
天然ピレトリン2.0重量部及びメトフルトリン0.1重量部、IPソルベント2028(出光興産株式会社、50%留出温度 約233℃)9.965重量部にソーイングルブN-15(ENEOS(株)、50%留出温度 約265℃)を混合して100重量部とし、得られた溶液を45mL容量のプラスチック製容器に充填し、中栓を介して上部をヒーターで加熱できるようにした多孔性吸液芯を挿入することにより本発明の加熱蒸散用害虫防除製剤を作製する。
天然ピレトリン10.5重量部とメトフルトリン0.5重量部を、脱臭灯油89重量部に混合、溶解し、得られた溶液を45mL容量の塩化ビニル製容器に充填し、中栓を介して上部をヒーターで加熱できるようにした多孔性吸液芯(無機粉体をバインダーで固め、焼結したもの)を挿入することにより本発明の加熱蒸散用害虫防除製剤を作製する。
天然ピレトリン10.5重量部とメトフルトリン0.5重量部を、ジエチレングリコールモノブチルエーテル50部、ジブチルヒドロキシトルエン1.8部、及び水46.7部を混合、溶解し、得られた溶液を45mL容量のプラスチック製容器に充填し、中栓を介して上部をヒーターで加熱できるようにした多孔性吸液芯を挿入することにより本発明の加熱蒸散用害虫防除製剤を作製する。
木粉75重量部、タブ粉5重量部、粕粉5重量部、シャム粉10重量部およびタピオカ澱粉5重量部を混合し、適量の水を添加して十分に混練した。混錬物をシート状に成型、渦巻き状に打ち抜いた後、水分含有量が7~10重量%程度となるまで乾燥させることでブランク線香を作製した。
得られたブランク線香に対し、所定濃度に希釈した供試化合物のアセトン溶液を均一に滴下処理し、風乾することにより、試験製剤を作製した。
直径4.5cm、高さ12cmのガラスチューブにアカイエカ(Culex pipiens pallens)雌成虫20頭を入れ、ガラスチューブ上下の開口部を16メッシュのナイロンネットを輪ゴムで固定し閉じ込めた。直径22cm、高さ83cmの金属製筒を立てて設置し、上部開口部に上記アカイエカの入ったガラスチューブを2本立てて固定した。上記の方法で作製した製剤に火をつけ、金属製筒の下部開口部に設置した。6分後にアカイエカのノックダウン個体数を記録した。実験は3反復実施してノックダウン率(以下KD率と略記する)を求めた。
また天然ピレトリンおよび各ピレスロイド系化合物をそれぞれ単独で用いた場合のKD率から、これらを混合した場合に期待されるKD率をコルビーの式から算出して以下の表1に期待値として併記する。天然ピレトリンの濃度は、天然ピレトリンの有効成分の濃度を表す。
コルビーの式に基づく理論上の期待値(%) = A+(100-A)×B/100
上式において、AおよびBは以下の数字を意味する
A:Aのみを処理した場合のKD率(%)
B:Bのみを処理した場合のKD率(%)
直径4.5cm、高さ12cmのガラスチューブにアカイエカ(Culex pipiens pallens)雌成虫20頭を入れ、ガラスチューブ上下の開口部を16メッシュのナイロンネットを輪ゴムで固定し閉じ込めた。直径22cm、高さ83cmの金属製筒を立てて設置し、上部開口部に上記アカイエカの入ったガラスチューブを2本立てて固定した。上記の方法で作製した製剤に火をつけ、金属製筒の下部開口部に設置した。7分後にアカイエカのノックダウン(以下KD)個体数を記録した。実験は3反復実施してKD率を求めた。
また天然ピレトリンおよび各ピレスロイド系化合物をそれぞれ単独で用いた場合のKD率から期待されるKD率をコルビーの式から算出して以下の表2に期待値として併記する。
直径4.5cm、高さ12cmのガラスチューブにアカイエカ(Culex pipiens pallens)雌成虫20頭を入れ、ガラスチューブ上下の開口部を16メッシュのナイロンネットを輪ゴムで固定し閉じ込めた。直径22cm、高さ83cmの金属製筒を立てて設置し、上部開口部に上記アカイエカの入ったガラスチューブを2本立てて固定した。上記の方法で作製した製剤に火をつけ、金属製筒の下部開口部に設置した。10分後にアカイエカのノックダウン(以下KD)個体数を記録した。実験は3反復実施してKD率を求めた。天然ピレトリンおよび各ピレスロイド系化合物をそれぞれ単独で用いた場合のKD率から期待されるKD率をコルビーの式から算出して以下の表3に期待値として併記する。
直径4.5cm、高さ12cmのガラスチューブにアカイエカ(Culex pipiens pallens)雌成虫20頭を入れ、ガラスチューブ上下の開口部を16メッシュのナイロンネットを輪ゴムで固定し閉じ込める。直径22cm、高さ83cmの金属製筒を立てて設置し、上部開口部に上記アカイエカの入ったガラスチューブを2本立てて固定する。製剤例3または4に準じて調製した本発明のマット製剤を得る。該マット製剤を市販の殺虫マットヒーターにセットして金属製筒の下部開口部に設置し、加熱する。10分後にアカイエカのノックダウン(以下KD)個体数を記録してKD率を求める。天然ピレトリンと各ピレスロイド系化合物を所定の混合比率で含有する本発明のマット製剤は、天然ピレトリンあるいは各ピレスロイド系化合物が単独で発揮する効果から期待される効果よりも高い効果を発揮することが確認できる。
本試験例で高い効果が確認できるマット製剤に用いられる加熱蒸散用組成物としては、以下、表4に示される加熱蒸散用組成物を挙げることができる。
直径4.5cm、高さ12cmのガラスチューブにアカイエカ(Culex pipiens pallens)雌成虫20頭を入れ、ガラスチューブ上下の開口部を16メッシュのナイロンネットを輪ゴムで固定し閉じ込める。直径22cm、高さ83cmの金属製筒を立てて設置し、上部開口部に上記アカイエカの入ったガラスチューブを2本立てて固定する。製剤例7、8または9に準じて調製した本発明の加熱蒸散用害虫防除製剤を得る。該加熱蒸散用害虫防除製剤を図1の加熱蒸散型殺虫装置にセットして金属製筒の下部開口部に設置し、加熱する。10分後にアカイエカのノックダウン(以下KD)個体数を記録してKD率を求める。天然ピレトリンと各ピレスロイド系化合物を所定の混合比率で含有する本発明の加熱蒸散用害虫防除製剤は、天然ピレトリンあるいは各ピレスロイド系化合物が単独で発揮する効果から期待される効果よりも高い効果を発揮することが確認できる。
本試験例で高い効果が確認できる加熱蒸散用害虫防除製剤に用いられる加熱蒸散用組成物としては、以下、表5に示される加熱蒸散用組成物を挙げることができる。
Claims (9)
- 天然ピレトリン及びピレスロイド系化合物を含み、天然ピレトリンの有効成分とピレスロイド系化合物の重量比が20:1~200:1の範囲であることを特徴とする加熱蒸散用組成物。
- ピレスロイド系化合物が、25℃において0.00001Pa~0.1Paの蒸気圧を有するピレスロイド系化合物である請求項1に記載の加熱蒸散用組成物。
- ピレスロイド系化合物が、メトフルトリン、ジメフルトリン、トランスフルトリン、プロフルトリン、メパフルトリン、へプタフルトリン、テトラメチルフルトリン、およびレノフルトリンからなる群から選ばれる少なくとも1つのピレスロイド系化合物である請求項1または2に記載の加熱蒸散用組成物。
- 請求項1~3の何れか一項に記載の組成物を含んでなる線香。
- 請求項1~4の何れか一項に記載の組成物または線香を用いる蚊の駆除方法。
- 請求項1~3の何れか一項に記載の組成物を含んでなるマット製剤。
- 請求項1~3および請求項6の何れか一項に記載の組成物またはマット製剤を用いる蚊の駆除方法。
- 請求項1~3の何れか一項に記載の組成物を含んでなる加熱蒸散用害虫防除製剤。
- 請求項1~3および請求項8の何れか一項に記載の組成物または加熱蒸散用害虫防除製剤を用いる蚊の駆除方法。
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