WO2022180440A1 - Testing mould to test micro- and nano-coatings on al and fe materials - Google Patents

Testing mould to test micro- and nano-coatings on al and fe materials Download PDF

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Publication number
WO2022180440A1
WO2022180440A1 PCT/IB2021/055826 IB2021055826W WO2022180440A1 WO 2022180440 A1 WO2022180440 A1 WO 2022180440A1 IB 2021055826 W IB2021055826 W IB 2021055826W WO 2022180440 A1 WO2022180440 A1 WO 2022180440A1
Authority
WO
WIPO (PCT)
Prior art keywords
testing
mould
inserts
coatings
nano
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IB2021/055826
Other languages
English (en)
French (fr)
Inventor
Stefan MICHNA
Jan Novotny
Jaroslava SVOBODOVA
Petr Horcica
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
UNIVERZITA J E PURKYNE V USTI NAD LABEM
Original Assignee
UNIVERZITA J E PURKYNE V USTI NAD LABEM
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UNIVERZITA J E PURKYNE V USTI NAD LABEM filed Critical UNIVERZITA J E PURKYNE V USTI NAD LABEM
Priority to EP21927753.0A priority Critical patent/EP4277775A4/en
Publication of WO2022180440A1 publication Critical patent/WO2022180440A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/56Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/30Mounting, exchanging or centering
    • B29C33/306Exchangeable mould parts, e.g. cassette moulds, mould inserts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/42Moulds or cores; Details thereof or accessories therefor characterised by the shape of the moulding surface, e.g. ribs or grooves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/36Moulds for making articles of definite length, i.e. discrete articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D30/00Producing pneumatic or solid tyres or parts thereof
    • B29D30/06Pneumatic tyres or parts thereof (e.g. produced by casting, moulding, compression moulding, injection moulding, centrifugal casting)
    • B29D30/0601Vulcanising tyres; Vulcanising presses for tyres
    • B29D30/0662Accessories, details or auxiliary operations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D35/00Producing footwear
    • B29D35/0054Producing footwear by compression moulding, vulcanising or the like; Apparatus therefor
    • B29D35/0063Moulds
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/20Metals
    • G01N33/208Coatings, e.g. platings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D30/00Producing pneumatic or solid tyres or parts thereof
    • B29D30/06Pneumatic tyres or parts thereof (e.g. produced by casting, moulding, compression moulding, injection moulding, centrifugal casting)
    • B29D30/0601Vulcanising tyres; Vulcanising presses for tyres
    • B29D30/0662Accessories, details or auxiliary operations
    • B29D2030/0663Mould maintenance, e.g. cleaning, washing, repairing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2021/00Use of unspecified rubbers as moulding material
    • B29K2021/006Thermosetting elastomers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2905/00Use of metals, their alloys or their compounds, as mould material
    • B29K2905/02Aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2905/00Use of metals, their alloys or their compounds, as mould material
    • B29K2905/08Transition metals
    • B29K2905/12Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2030/00Pneumatic or solid tyres or parts thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/40Test specimens ; Models, e.g. model cars ; Probes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/48Wearing apparel
    • B29L2031/50Footwear, e.g. shoes or parts thereof
    • B29L2031/504Soles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/732Floor coverings
    • B29L2031/7324Mats

Definitions

  • the invention relates to a testing mould to test micro- and nano-coatings on A1 and Fe materials during product pressing, particularly in a vulcanisation mould.
  • aluminium alloys are used to manufacture metal moulds for tyre production, especially for summer tyre moulds, or a combination of aluminium alloy and stainless-steel fins, especially for winter tyre moulds.
  • the metal mould is composed of a certain number of segments, usually ranging from 8 to 36 depending on the size of a tyre being produced.
  • the metal mould surface is not finished with any surface treatment technology.
  • the moulds are used to produce tyres by vulcanising a mixture of organic substances at higher temperatures, i.e., 150°C to 170°C. After a certain number of cycles, i.e., the number of tyres produced, the individual segments of the metal mould are necessary to be cleaned.
  • the test price for the testing mould for 2,400 pieces of mouldings is CZK 85,000; when testing directly on finished moulds, the price is CZK 510,000, i.e., 6 times more.
  • the price of one finished mould for production is CZK 0.7 to 1.2 million; the price of the testing mould is only CZK 292,000.
  • the testing mould comprises at least three Al-alloy testing inserts and three Al- alloy testing inserts with Fe fins having the same composition as the moulds for pressing the finished products themselves, wherein at least two Al-alloy testing inserts and at least two Al-alloy testing inserts with Fe fins are coated, i.e., six different variants in total.
  • the testing inserts correspond to moulds for pressing finished products selected from the groups of tyres, shoe soles, and mats.
  • the present invention introduces a so-called testing mould into the process of micro- and nano-coating; this mould is made of segments of the same composition as the moulds produced for the technology of manufacturing the finished products themselves, i.e., tyres, shoe soles, mats, etc.
  • the advantage of the testing mould consists in those three different coatings on the inserts or two inserts with coating and one insert without coating are possible to be tested at the same time for comparison purposes, and this can be done in combination on the A1 mould only or the A1 mould with Fe fins.
  • the complete assembled testing mould usually comprises three Al-alloy testing inserts and three Al-alloy testing inserts with Fe fins.
  • the mould allows six different combinations to be tested at the same time within a single process, effectively reducing the financial cost of testing and examining multiple micro- and nano-coatings at the same time and comparing them to each other but also testing under the same conditions and shortening the overall process time.
  • the testing equipment's low maintenance and cleaning requirements are also a great advantage.
  • the ability to test and compare six variants simultaneously under exactly the same technical conditions also represents a great benefit.
  • the cost of the produced testing mould is 3 to 7 times lower compared to the production of one mould for the finished production, wherein testing directly on the production mould is moreover impractical in terms of the exclusion thereof from the production process for a certain period, generating losses in production.
  • FIG.l is an outline of the complete testing mould consisting of six testing inserts ready to test.
  • FIG.2 is an outline of one of the testing inserts after coating.
  • FIG.3 is an outline of moulding from the test of the testing mould.
  • FIG.4a shows the mould in elevation and Fig. 4b in the side elevation.
  • An exemplary testing mould to test micro- and nano-coatings on A1 and Fe materials during product pressing in a vulcanisation mould comprises three Al-alloy testing inserts and three Al-alloy testing inserts with Fe fins, which have the same composition as the moulds for pressing the finished products themselves, wherein two Al-alloy testing inserts and two Al-alloy testing inserts with Fe fins are provided with nano coatings.
  • the testing inserts correspond to moulds used for pressing the fini hed products, i.e., tyres.
  • the overall description and procedure of the vulcanisation mould production technology including the materials used for testing the micro- and nano-coatings, are specified in Table 1.
  • the base plate for fitting the individual inserts is made by AlSilOMg material casting, followed by machining of the functional surfaces, par ticularly milling, turning, and drilling, to achieve the required surface quality and di mensional accuracy.
  • the inserts six pieces in total, were produced by the low-pressure casting of AlMg4.5Mn material, subjected to heat treatment by hardening and me chanically machined by blasting before coating.
  • the fin material is made of an alloy based on 1.4301, and the handles on the base plate are made of steel of grade 11.
  • An example mould size is 400 x 380 x 54 mm, and the insert size is 90 x 100 mm.
  • the testing mould to test micro- and nano-coatings on A1 and Fe materials during product pressing, in particular in a vulcanisation mould, according to the present invention will find the application mainly in the automotive and textile industries to test the moulds which have been coated during the manufacture of products made of vulcanisation compound, such as tyres, shoe soles, mats, etc.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Food Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
PCT/IB2021/055826 2021-02-25 2021-06-29 Testing mould to test micro- and nano-coatings on al and fe materials Ceased WO2022180440A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP21927753.0A EP4277775A4 (en) 2021-02-25 2021-06-29 TEST FORM FOR TESTING MICRO- AND NANO-COATINGS ON AL AND FE MATERIALS

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CZ2021-85A CZ202185A3 (cs) 2021-02-25 2021-02-25 Testovací forma pro testování mikro a nano povlaků na Al a Fe materiálech
CZPV2021-85 2021-02-25

Publications (1)

Publication Number Publication Date
WO2022180440A1 true WO2022180440A1 (en) 2022-09-01

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Family Applications (1)

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PCT/IB2021/055826 Ceased WO2022180440A1 (en) 2021-02-25 2021-06-29 Testing mould to test micro- and nano-coatings on al and fe materials

Country Status (3)

Country Link
EP (1) EP4277775A4 (cs)
CZ (1) CZ202185A3 (cs)
WO (1) WO2022180440A1 (cs)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023135451A1 (en) * 2022-01-15 2023-07-20 Univerzita J. E. Purkyne V Usti Nad Labem A method for testing micro- and nanocoatings on al and fe materials, in particular for moulds for moulding the finished products selected from the groups of the tyre, shoe sole, and mat.

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN205009448U (zh) * 2015-09-25 2016-02-03 安徽中马橡塑制品有限公司 一种硫化样品试验模具
JP2017128650A (ja) * 2016-01-19 2017-07-27 株式会社ブリヂストン ゴム組成物の製造方法、ゴム組成物及びタイヤ
CN209478726U (zh) * 2018-12-20 2019-10-11 浦林成山(山东)轮胎有限公司 一种用于制作测试帘布间覆胶粘合力的硫化模具
EP3560670A1 (en) * 2018-04-25 2019-10-30 Univerzita J. E. Purkyne V Usti Nad Labem Ptfe-based coating for moulds of aluminium alloys used in rubber vulcanization for tire production and method of production thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001187407A (ja) * 1999-10-22 2001-07-10 Bridgestone Corp タイヤモールドの検査方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN205009448U (zh) * 2015-09-25 2016-02-03 安徽中马橡塑制品有限公司 一种硫化样品试验模具
JP2017128650A (ja) * 2016-01-19 2017-07-27 株式会社ブリヂストン ゴム組成物の製造方法、ゴム組成物及びタイヤ
EP3560670A1 (en) * 2018-04-25 2019-10-30 Univerzita J. E. Purkyne V Usti Nad Labem Ptfe-based coating for moulds of aluminium alloys used in rubber vulcanization for tire production and method of production thereof
CN209478726U (zh) * 2018-12-20 2019-10-11 浦林成山(山东)轮胎有限公司 一种用于制作测试帘布间覆胶粘合力的硫化模具

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
MAGHSOUDI K., JAFARI R., MOMEN G., FARZANEH M.: "Micro-nanostructured polymer surfaces using injection mo ding: A review", MATERIALS TODAY COMMUNICATIONS, vol. 13, 2017, pages 126 - 1-3, XP055965934, ISSN: 2352-4928, DOI: 10.1016/i.mtcomm. 2017.09.01 3 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023135451A1 (en) * 2022-01-15 2023-07-20 Univerzita J. E. Purkyne V Usti Nad Labem A method for testing micro- and nanocoatings on al and fe materials, in particular for moulds for moulding the finished products selected from the groups of the tyre, shoe sole, and mat.
GB2627621A (en) * 2022-01-15 2024-08-28 Univerzita J E Purkyne V Usti Nad Labem A method for testing micro- and nanocoatings on AI and FE materials, in particular for moulds for moulding the finished products selected from the groups of

Also Published As

Publication number Publication date
EP4277775A1 (en) 2023-11-22
EP4277775A4 (en) 2025-01-01
CZ309304B6 (cs) 2022-08-10
CZ202185A3 (cs) 2022-08-10

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