WO2022163813A1 - 構造体、及び建築材料 - Google Patents

構造体、及び建築材料 Download PDF

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Publication number
WO2022163813A1
WO2022163813A1 PCT/JP2022/003319 JP2022003319W WO2022163813A1 WO 2022163813 A1 WO2022163813 A1 WO 2022163813A1 JP 2022003319 W JP2022003319 W JP 2022003319W WO 2022163813 A1 WO2022163813 A1 WO 2022163813A1
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WO
WIPO (PCT)
Prior art keywords
radio wave
less
ghz
reflected
reflector
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2022/003319
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English (en)
French (fr)
Japanese (ja)
Inventor
博之 野本
俊夫 江南
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Sekisui Chemical Co Ltd
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Sekisui Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sekisui Chemical Co Ltd filed Critical Sekisui Chemical Co Ltd
Priority to CA3206140A priority Critical patent/CA3206140A1/en
Priority to US18/273,125 priority patent/US20240088570A1/en
Priority to CN202280008412.2A priority patent/CN116670927A/zh
Priority to KR1020237027010A priority patent/KR20230135095A/ko
Priority to JP2022578514A priority patent/JP7271802B2/ja
Priority to EP22746032.6A priority patent/EP4287405A4/en
Publication of WO2022163813A1 publication Critical patent/WO2022163813A1/ja
Priority to JP2023070758A priority patent/JP2023084147A/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01Q—ANTENNAS, i.e. RADIO AERIALS
    • H01Q15/00—Devices for reflection, refraction, diffraction or polarisation of waves radiated from an antenna, e.g. quasi-optical devices
    • H01Q15/14—Reflecting surfaces; Equivalent structures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01Q—ANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00—Details of, or arrangements associated with, antennas
    • H01Q1/007—Details of, or arrangements associated with, antennas specially adapted for indoor communication
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01Q—ANTENNAS, i.e. RADIO AERIALS
    • H01Q15/00—Devices for reflection, refraction, diffraction or polarisation of waves radiated from an antenna, e.g. quasi-optical devices
    • H01Q15/14—Reflecting surfaces; Equivalent structures
    • H01Q15/147—Reflecting surfaces; Equivalent structures provided with means for controlling or monitoring the shape of the reflecting surface
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01Q—ANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00—Details of, or arrangements associated with, antennas
    • H01Q1/12—Supports; Mounting means
    • H01Q1/22—Supports; Mounting means by structural association with other equipment or articles
    • H01Q1/24—Supports; Mounting means by structural association with other equipment or articles with receiving set
    • H01Q1/241—Supports; Mounting means by structural association with other equipment or articles with receiving set used in mobile communications, e.g. GSM
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01Q—ANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00—Details of, or arrangements associated with, antennas
    • H01Q1/36—Structural form of radiating elements, e.g. cone, spiral, umbrella; Particular materials used therewith
    • H01Q1/364—Structural form of radiating elements, e.g. cone, spiral, umbrella; Particular materials used therewith using a particular conducting material, e.g. superconductor
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01Q—ANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00—Details of, or arrangements associated with, antennas
    • H01Q1/44—Details of, or arrangements associated with, antennas using equipment having another main function to serve additionally as an antenna, e.g. means for giving an antenna an aesthetic aspect
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01Q—ANTENNAS, i.e. RADIO AERIALS
    • H01Q15/00—Devices for reflection, refraction, diffraction or polarisation of waves radiated from an antenna, e.g. quasi-optical devices
    • H01Q15/0006—Devices acting selectively as reflecting surface, as diffracting or as refracting device, e.g. frequency filtering or angular spatial filtering devices
    • H01Q15/0013—Devices acting selectively as reflecting surface, as diffracting or as refracting device, e.g. frequency filtering or angular spatial filtering devices said selective devices working as frequency-selective reflecting surfaces, e.g. FSS, dichroic plates, surfaces being partly transmissive and reflective
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01Q—ANTENNAS, i.e. RADIO AERIALS
    • H01Q15/00—Devices for reflection, refraction, diffraction or polarisation of waves radiated from an antenna, e.g. quasi-optical devices
    • H01Q15/0006—Devices acting selectively as reflecting surface, as diffracting or as refracting device, e.g. frequency filtering or angular spatial filtering devices
    • H01Q15/0013—Devices acting selectively as reflecting surface, as diffracting or as refracting device, e.g. frequency filtering or angular spatial filtering devices said selective devices working as frequency-selective reflecting surfaces, e.g. FSS, dichroic plates, surfaces being partly transmissive and reflective
    • H01Q15/0046—Theoretical analysis and design methods of such selective devices
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01Q—ANTENNAS, i.e. RADIO AERIALS
    • H01Q15/00—Devices for reflection, refraction, diffraction or polarisation of waves radiated from an antenna, e.g. quasi-optical devices
    • H01Q15/0006—Devices acting selectively as reflecting surface, as diffracting or as refracting device, e.g. frequency filtering or angular spatial filtering devices
    • H01Q15/0086—Devices acting selectively as reflecting surface, as diffracting or as refracting device, e.g. frequency filtering or angular spatial filtering devices said selective devices having materials with a synthesized negative refractive index, e.g. metamaterials or left-handed materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01Q—ANTENNAS, i.e. RADIO AERIALS
    • H01Q15/00—Devices for reflection, refraction, diffraction or polarisation of waves radiated from an antenna, e.g. quasi-optical devices
    • H01Q15/14—Reflecting surfaces; Equivalent structures
    • H01Q15/141—Apparatus or processes specially adapted for manufacturing reflecting surfaces
    • H01Q15/142—Apparatus or processes specially adapted for manufacturing reflecting surfaces using insulating material for supporting the reflecting surface

Definitions

  • the present invention relates to structures and building materials for reflecting radio waves.
  • Patent Literature 1 proposes a communication system in which a monopole antenna and a metal reflector that reflects radio waves are arranged in an indoor underfloor space.
  • radio waves radiated from a monopole antenna are diffused in an underfloor space, and are prevented from leaking from the underfloor space to the outside of a living room (building) or being absorbed by the floor of a building.
  • a metal reflector that reflects radio waves is generally composed of a metal plate such as aluminum or copper. It is known that a metal reflector reflects radio waves with a short wavelength with high intensity in the normal reflection direction, but diffuses the radio waves and makes it difficult to reflect them. For this reason, if a reflector made of a metal plate is used, it is difficult for radio waves to reach a wide range of space. be.
  • the object of the present invention is to provide a structure and building materials that reflect radio waves over a wide range of space.
  • the present invention includes the subjects described in the following sections.
  • Section 1 A structure having a radio wave reflector including a radio wave reflector that reflects radio waves, When a radio wave having an incident angle of 15 degrees or more and 75 degrees or less and an incident wave frequency of 3 GHz or more and 5 GHz or less, 25 GHz or more and 30 GHz or less, or 150 GHz or more and 300 GHz or less is reflected on the radio wave reflector. , When the incident wave is regularly reflected, the intensity of the reflected wave is -30 dB or more with respect to the incident wave, and the reflected wave is measured on a virtual plane including the incident direction of the incident wave and the reflected direction of the reflected wave.
  • the kurtosis of the intensity distribution of the reflected wave at each reception angular position is -0.4 when the reception angular position is changed in an angular range of -15 degrees or more and +15 degrees or less with respect to the normal reflection direction.
  • a structure in which there is at least one frequency that is:
  • Section 2. The structure according to Item 1, wherein the kurtosis of the intensity distribution of the reflected wave at each of the reception angular positions is ⁇ 0.4 or less in the frequency range of the incident wave of 3 GHz or more and 300 GHz or less.
  • Item 3. The structure according to Item 1 or Item 2, wherein the radio wave reflector has at least a conductive thin film layer containing the radio wave reflecting material, and a substrate layer containing a substrate for holding the conductive thin film layer.
  • Item 4 The structure according to Item 3, wherein the conductive thin film layer has a developed interface area ratio of 0.5% or more and 600% or less.
  • Item 5. The structure according to Item 3 or 4, wherein the conductive thin film layer has a surface resistance value of 0.3 ⁇ / ⁇ or more and 10 ⁇ / ⁇ or less.
  • Item 6. The structure according to any one of Items 3 to 5, wherein the radio wave reflecting material of the conductive thin film layer is linear, and is arranged to surround a region without the radio wave reflecting material.
  • Item 7. The structure according to Item 6, wherein the radio wave reflecting material has a line width of 0.05 ⁇ m or more and 15 ⁇ m or less, a thickness of 0.05 ⁇ m or more and 10 ⁇ m or less, and a coverage of 50% or less.
  • Item 8. The structure according to any one of Items 3 to 5, wherein the conductive thin film layer includes a plurality of sheet-shaped radio wave reflecting materials arranged periodically.
  • the conductive thin film layer has a shortest distance between adjacent radio wave reflectors of 1 mm or less, a thickness of 0.010 ⁇ m or more and 0.35 ⁇ m or less, and a coverage of 5% or more and 99.9% or less. 8. The structure of claim 8.
  • Item 10. The structure according to any one of items 1 to 9, wherein the radio wave reflector is transparent.
  • Item 11 The structure according to any one of Items 1 to 10, wherein the radio wave reflector is obtained by laminating the radio wave reflector with a resin.
  • Item 12. The structure according to any one of Items 1 to 10, wherein the radio wave reflector is a resin in which the radio wave reflector is dispersed.
  • Item 13 The structure according to any one of Items 1 to 10, wherein the radio wave reflector is a sheet-shaped radio wave reflector made of resin.
  • Item 14 The structure according to any one of Items 1 to 13, wherein the radio wave reflector is flexible.
  • Item 15. The structure according to any one of items 1 to 14, wherein the radio wave reflector has a thickness of 1 mm or less.
  • Item 16 14. The structure according to any one of items 11 to 13, wherein the resin has a dielectric loss tangent of 0.018 or less.
  • Item 17. 14 The structure according to any one of items 11 to 13, wherein the resin has a dielectric constant that changes according to an electric field.
  • Item 18 A building material comprising the structure according to any one of Items 1 to 17.
  • Item 19 The building material according to item 18, wherein the structure has flexibility and is used on a curved surface.
  • a building material comprising a radio wave reflector including a radio wave reflector that reflects radio waves, When a radio wave having an incident angle of 15 degrees or more and 75 degrees or less and an incident wave frequency of 3 GHz or more and 5 GHz or less, 25 GHz or more and 30 GHz or less, or 150 GHz or more and 300 GHz or less is reflected on the radio wave reflector. , When the incident wave is regularly reflected, the intensity of the reflected wave is -30 dB or more with respect to the incident wave, and the reflected wave is measured on a virtual plane including the incident direction of the incident wave and the reflected direction of the reflected wave.
  • the kurtosis of the intensity distribution of the reflected wave at each reception angular position is -0.4 when the reception angular position is changed in an angular range of -15 degrees or more and +15 degrees or less with respect to the normal reflection direction.
  • a building material that has at least one frequency that:
  • radio waves can be reflected over a wide range of space.
  • FIG. 1 is a side view showing the overall schematic configuration of a structure according to one embodiment of the present invention
  • FIG. 3 is a plan view showing a schematic configuration of the entire structure shown in FIG. 2
  • FIG. 11 is a side view showing the overall schematic configuration of a structure according to another embodiment
  • FIG. 5 is a plan view showing a schematic configuration of the entire structure shown in FIG. 4
  • 7B is a cross-sectional view showing a schematic configuration of a structure according to another embodiment, and is a cross-sectional view taken along line BB in FIG. 7B.
  • FIG. FIG. 7 shows a schematic configuration of the entire radio wave reflector shown in FIG.
  • FIG. 11 is a side view showing the overall schematic configuration of a structure according to another embodiment; It is a sectional view showing a schematic structure of a structure concerning other embodiments. It is a sectional view showing a schematic structure of a structure concerning other embodiments.
  • (A) is an explanatory diagram showing an example of application of the building material to a building, and (B) is a plan view showing an example of application of the building material to a room.
  • the structure 10 of this embodiment forms a radio wave reflector 11 .
  • the radio waves output from the radio wave source 20 are reflected.
  • the reflected wave is received by the receiver 21 .
  • the radio wave source 20 is a communication device or the like having a transmission antenna capable of transmitting radio waves.
  • the receiver 21 is a device capable of receiving radio waves.
  • the receiving unit 21 according to this embodiment is a communication device having a receiving antenna. Examples of communication devices include smartphones, mobile phones, tablet terminals, notebook PCs, portable game machines, repeaters, radios, and televisions.
  • the radio wave reflector 11 includes a radio wave reflector 12 that reflects radio waves.
  • the frequency of the incident wave is 3 GHz or more and 5 GHz or less, 25 GHz or more and 30 GHz or less, at least at a predetermined angle of 15 degrees or more and 75 degrees or less, preferably in the entire angle range of 15 degrees or more and 75 degrees or less.
  • the radio wave reflector 11 reflects radio waves of 150 GHz or more and 300 GHz or less.
  • the intensity of the reflected wave when the incident wave is regularly reflected by the radio wave reflector 11 (hereinafter also referred to as “regular reflection intensity”) is ⁇ 30 dB or more and 0 dB or less with respect to the incident wave, and the kurtosis (described later) There is at least one frequency at which is -0.4 or less.
  • the regular reflection intensity is -30 dB or more and 0 dB or less with respect to the incident wave, and the kurtosis is -0.4 or less.
  • the regular reflection intensity is preferably -25 dB or more and 0 dB or less, more preferably -22 dB or more and 0 dB or less, further preferably -20 dB or more and 0 dB or less, and even more preferably -15 dB or more and 0 dB or less with respect to the incident wave.
  • the regular reflection intensity is ⁇ 30 dB or more with respect to the incident wave
  • the receiving section 21 can receive the radio wave with practical intensity.
  • the normal reflection intensity and the reflection intensity are the distance between the reflection point 11a of the radio wave reflector 11 and the radio wave source 20 and the distance between the reflection point 11a of the radio wave reflector 11 and the receiver 21. is a value when the distance between is set to 1 m.
  • the normal reflection means that when the radio wave emitted from the radio wave source 20 (transmitting antenna) is reflected by the radio wave reflector 11, the incident angle ⁇ 1 of the incident wave and the reflection of the reflected wave It means that the angle ⁇ 2 is equal.
  • the reflection direction of the reflected wave when the radio wave is regularly reflected is also called “regular reflection direction”.
  • the incident angle ⁇ 1 is defined by the incident wave traveling in the incident direction (indicated by arrow A1 in FIG. 1) when the radio wave enters the radio wave reflector 11 and the normal line 22 of the reflecting surface of the radio wave reflector 11.
  • the angle of reflection ⁇ 2 is the angle formed between the reflected wave traveling in the reflection direction of the reflected wave (indicated by arrow A2 in FIG. 1) and the normal line 22 of the reflecting surface.
  • the normal line 22 is a straight line perpendicular to the tangent line (or tangent plane) at the reflection point 11a.
  • the radio wave reflector 11 is arranged such that the receiving angular position of the reflected wave is -15 degrees or more and +15 degrees with respect to the normal reflection direction of the radio wave on a virtual plane including the incident direction of the incident wave and the reflection direction of the reflected wave.
  • the kurtosis of the intensity distribution of the reflected wave at each receiving angular position is ⁇ 0.4 or less when the angular range ⁇ is varied as follows.
  • the kurtosis is more preferably ⁇ 1.0 or less, still more preferably ⁇ 1.1 or less, and even more preferably ⁇ 1.2 or less.
  • the lower limit of the kurtosis is not particularly limited, it is usually about -5.0.
  • the intensity of the reflected wave at each reception angle position is hereinafter also referred to as "reflection intensity”.
  • the virtual plane can also be said to be a plane including the reflection point 11a on the reflecting surface of the reflector, the radio wave source 20, and the reflected wave receiver 21.
  • Kurtosis is a statistic that indicates how much a distribution deviates from a normal distribution, and indicates the degree of kurtosis and the spread of tails.
  • a radio wave output from the radio wave source 20 located 1 m away from the reflecting point 11a is incident on the radio wave reflector 11 at a predetermined incident angle ⁇ 1.
  • the reception angular position i of the receiving unit 21 is set at a predetermined angle (for example, at a time of 5 degrees) from the normal reflection direction of the radio wave centering on the reflection point 11a, and is -15 degrees or more and +15 degrees or less with respect to the normal reflection direction of the radio waves.
  • the reflection intensity x is measured by moving within the angle range ⁇ .
  • the reception angular position i of the receiver 21 is located on an arc with a radius of 1 m centered on the reflection point 11a. Reflection intensity value at each reception angular position i the average value of , and the standard deviation is s, the kurtosis is obtained from the following formula.
  • kurtosis indicates that the intensity data at each angular position is distributed flatter than the normal distribution. The smaller is, the flatter the distribution.
  • the kurtosis can be adjusted by the type and structure of the resin layers (substrate layer 13, adhesive layer 14, and protective layer 15, which will be described later) forming the radio wave reflector 11, the developed interface area ratio Sdr, and the like.
  • the radio wave reflector 11 may have visible light transmittance as a whole, that is, may be transparent.
  • the base material layer 13, the adhesive layer 14, and the protective layer 15, which will be described later, may each be made of a resin having visible light transparency. may be formed.
  • transparent means that the other side of the radio wave reflector 11 can be viewed from one side, and includes semi-transparency, but is not limited to complete transparency with a total light transmittance of 100%.
  • the radio wave reflector 11 may be colored.
  • the radio wave reflector 11 has a total light transmittance of 65% or more, preferably 80% or more, more preferably 85% or more, and still more preferably 90% or more under a D65 standard light source.
  • the total light transmittance refers to the ratio of the total transmitted light flux to the parallel incident light flux of the test piece, and is measured according to JISK 7375:2008.
  • the radio wave reflector 11 preferably has a square overall shape in plan view and a side length L10 of 20 cm or more and 400 cm or less. Radio waves with a frequency of 3 GHz or more and 300 GHz or less are attenuated by distance, but in order to reflect with sufficient intensity at all points within a practical distance from the radio wave source 20, the length L10 of one side is set to 20 cm or more. is preferred. Although the upper limit of the length L10 of one side is not particularly limited, it is preferably 400 cm or less from the viewpoint of manufacturing.
  • the overall shape of the radio wave reflector 11 is not limited to a square, but may be a rectangle, or may be a polygon such as a triangle, a pentagon, or a hexagon.
  • the shortest distance between a certain vertex and the opposite side or the shortest distance between a certain side and the opposite side may be set to 20 cm or more and 400 cm or less.
  • the overall shape of the radio wave reflector 11 when the overall shape of the radio wave reflector 11 is circular, the diameter is set to 20 cm or more and 400 cm or less.
  • the overall shape of the radio wave reflector 11 is elliptical, the minor axis is set to 20 cm or more and 400 cm or less.
  • the overall shape of the radio wave reflector 11 is fan-shaped, the length of the arc or the shorter radius is set to 20 cm or more and 400 cm or less.
  • the overall shape of the radio wave reflector 11 may be a three-dimensional shape such as a cylindrical shape or a conical shape.
  • the overall shape of the radio wave reflector 11 has a shape and size that can reflect radio waves with a reflection intensity of -30 dB or more with respect to the incident wave. is appropriately selected according to the aspect of
  • the thickness L11 of the radio wave reflector 11 is set to about 0.5 mm in this embodiment, it is not limited to this, and the thickness L11 is preferably 1 mm or less.
  • the thicknesses of the base material layer 13, the radio wave reflector 12 of the conductive thin film layer 16, the adhesive layer 14, and the protective layer 15, which will be described later, are set so that the thickness L11 of the radio wave reflector 11 is 1 mm or less. Since the thickness L11 of the radio wave reflector 11 is small, the radio wave reflector 12 has flexibility. Flexibility refers to the property of having flexibility under normal temperature and normal pressure, and being able to bend, bend, bend, or otherwise deform without being sheared or broken even when a force is applied.
  • the radio wave reflector 11 has flexibility to the extent that it can be attached along a curved surface having a curvature radius R of about 300 mm, but the value of the curvature radius R is not limited.
  • the thickness L11 of the radio wave reflector 11 is the sum of the thickness L3 of the conductive thin film layer 16, the thickness L8 of the base layer 13, the thickness L4 of the adhesive layer 14, and the thickness L5 of the protective layer 15.
  • the thickness L3 of the conductive thin film layer 16 is much thinner than the respective thicknesses L8, L4, and L5 of the base layer 13, the adhesive layer 14, and the protective layer 15, when calculating the thickness L11 of the radio wave reflector 11, Alternatively, the thickness L3 of the conductive thin film layer 16 may be ignored.
  • the thickness L11 of the radio wave reflector 11, the thickness L3 of the conductive thin film layer 16, the thickness L8 of the base layer 13, the thickness L4 of the adhesive layer 14, and the thickness L5 of the protective layer 15 are measured at a plurality of arbitrary points. , is obtained by calculating the average value of the obtained measured values.
  • a reflectance spectroscopic film thickness measurement for example, F3-CS-NIR manufactured by Filmetrics Co., Ltd. is used as a measuring instrument. .
  • the incident angle ⁇ 1 of the incident wave is a predetermined angle of 15 degrees or more and 75 degrees or less, preferably at all angles in the range of 15 degrees or more and 75 degrees or less, and the regular reflection intensity and ⁇ 15 degrees as described above.
  • the radio wave reflected by the radio wave reflector 11 can be received by the receiving unit 21 in a wide range of space. rice field. Therefore, even if a radio wave with a short wavelength travels in a straight line, it is possible to suppress the occurrence of a dead space in the indoor space as much as possible.
  • the radio wave reflector 11 has, for example, a metamaterial structure.
  • the metamaterial structure is obtained by periodically arranging the radio wave reflectors 12, which are dielectrics, in an equal manner. Due to this periodic arrangement structure, the metamaterial structure has a negative dielectric constant and belongs to a specific frequency band determined based on the periodic interval. Reflect radio waves.
  • the radio wave reflector 11 includes a conductive thin film layer 16 including the radio wave reflecting material 12 and a resin that keeps the radio wave reflecting material 12 in a sheet shape.
  • the resin includes a substrate layer 13 containing a substrate, a protective layer 15 containing a protective material for protecting the conductive thin film layer 16, and an adhesive material for bonding the conductive thin film layer 16 and the protective layer 15 together.
  • layer 14 In the embodiment shown in FIG. 2, the radio wave reflector 11 has a conductive thin film layer 16 laminated on a substrate layer 13, and an adhesive layer 14 and a protective layer 15 laminated thereon in this order.
  • FIGS. 1-12 are not shown to scale. Also, in FIG. 7A, the adhesive layer 14 and the protective layer 15 are partially omitted from the radio wave reflector 11 .
  • the base material layer 13 has a square outer shape in plan view. However, it is not limited to this, and may be rectangular, circular, elliptical, fan-shaped, polygonal, three-dimensional, or the like in accordance with the overall shape of the radio wave reflector 11 .
  • a sheet made of a synthetic resin is used as the substrate which is the substrate layer 13 .
  • Examples of synthetic resins include PET (polyethylene terephthalate), polyethylene, polypropylene, polyvinyl chloride, polystyrene, polymethyl methacrylate, polyester, polyformaldehyde, polyamide, polyphenylene ether, vinylidene chloride, polyvinyl acetate, polyvinyl acetal, and AS resin. , ABS resin, acrylic resin, fluorine resin, nylon resin, polyacetal resin, polycarbonate resin, polyamide resin, and polyurethane resin.
  • the thickness L8 of the base material layer 13 (the length in the vertical direction in FIG. 2) is set to 50 ⁇ m in the present embodiment, but is not limited to this. It is set accordingly.
  • the base material layer 13 may contain an arbitrary material such as a synthetic resin or an arbitrary member.
  • the radio wave reflecting material 12 is formed as a square sheet-shaped thin film on the upper surface of the base material layer 13.
  • the radio wave reflecting material 12 is made of, for example, silver (Ag). preferably.
  • the radio wave reflecting material 12 may be composed of a metal, metal compound, or alloy having free electrons, and is not limited to silver. Examples include gold, copper, platinum, aluminum, titanium, silicon, indium tin oxide, and alloys. (for example, an alloy containing nickel, chromium and molybdenum) or the like.
  • a sheet shape means a shape in which the length in the longitudinal direction is approximately the same as or less than 3000 times the length in the direction orthogonal to the longitudinal direction.
  • each radio wave reflecting material 12 has a square shape in plan view, and the length L1 of one side and the distance between adjacent radio wave reflecting materials 12 are determined according to the frequency band of the radio wave to be reflected.
  • the shortest distance (interval) L2 is set. In this embodiment, it is set so as to reflect especially radio waves in the frequency band of 20 GHz or more and 300 GHz or less, which is the frequency band related to the fifth generation mobile communication system (5G).
  • the length L1 of one side is set to 77.460 mm, and the interval L2 between adjacent radio wave reflectors 12 is set to 100 ⁇ m.
  • the length L1 and the interval L2 may be set so that the radio wave reflector 12 reflects radio waves with a frequency of 3 GHz or more and 300 GHz or less.
  • the length L1 of one side of the radio wave reflector 12 may be 0.7 mm or more and 800 mm or less, and the interval L2 may be 1 ⁇ m or more and 1000 ⁇ m or less.
  • a total of four radio wave reflectors 12 are formed on the base material layer 13 in accordance with the size of the base material layer 13, two vertically and two horizontally. , the number of radio wave reflectors 12 is appropriately set according to the size (area) of the base material layer 13 .
  • the thickness (film thickness) L3 of the radio wave reflecting material 12 is a thickness that has visible light transmittance.
  • the thickness L3 of the radio wave reflector 12 is preferably 350 nm (0.35 ⁇ m) or less, more preferably 100 nm or less, and even more preferably 50 nm or less.
  • the thickness L3 is preferably 5 nm or more from the viewpoint of ensuring appropriate radio wave intensity.
  • the conductive thin film layer 16 preferably has a surface resistance value of 0.3 ⁇ / ⁇ or more and 10 ⁇ / ⁇ or less, more preferably 3.5 ⁇ / ⁇ or less.
  • the surface resistance value of the conductive thin film layer 16 is the surface resistance value of the radio wave reflector 11 .
  • the surface resistance value can be measured in accordance with the four-terminal method specified in JISK7194:1994 by contacting the measurement terminals to the surface of the conductive thin film layer.
  • the eddy current is measured using a non-contact resistance measuring device (manufactured by Napson Co., Ltd., trade name: EC-80P, or its equivalent). can be measured by the method.
  • the spread interface area ratio Sdr of the conductive thin film layer 16 is not particularly limited, it is preferably 0.05% or more and 600% or less, more preferably 1% or more and 580% or less, and 2% or more and 180% or less. More preferably, 3% or more and 90% or less is even more preferable.
  • the developed interface area ratio Sdr is within this range, it becomes easier to adjust the regular reflection intensity and the kurtosis within the above ranges. As a result, it becomes easier to diffusely reflect radio waves.
  • the developed interface area ratio Sdr has a calculation formula shown in JIS B-0681-2:2018, and is measured in accordance with JIS B-0681-6:2014. Using a laser microscope (product name VK-X1000/1050, manufactured by Keyence Corporation, or equivalent), the height is measured at multiple points on the surface of the conductive thin film layer 16 (radio wave reflector 12). By calculating the developed area from the measured value, the developed interface area ratio Sdr of the radio wave reflecting material 12 can be obtained.
  • the conductive thin film layer 16 has a plurality of sheet-like radio wave reflecting materials 12, and the height of each radio wave reflecting material 12 is measured at a plurality of locations, and the obtained measurement value , respectively, to calculate the developed interface area ratio Sdr. After that, by calculating the arithmetic average value, the developed interface area ratio Sdr of the conductive thin film layer 16 can be obtained.
  • the conductive thin film layer 16 preferably has a coverage of 5% or more and 99.9% or less.
  • the coverage rate refers to the ratio of the area occupied by the radio wave reflecting material 12 per unit area in plan view, and in the embodiments shown in FIGS. It means the ratio of the area of the material 12 in plan view.
  • the coverage rate can also be said to be the area of the base material layer 13 covered with the radio wave reflecting material 12 with respect to the area of the base material layer 13 in plan view.
  • the coverage is measured using a scanning electron microscope (SEM), a transmission electron microscope (TEM), an optical microscope, or the like.
  • the shape of the radio wave reflector 12 is not limited to a square, and may be any shape.
  • the side of a certain radio wave reflecting material 12 and the side of an adjacent radio wave reflecting material 12 are parallel, and the distances between a certain radio wave reflecting material 12 and all adjacent radio wave reflecting materials 12 are equal. Possible shapes are, for example, rectangular, triangular, hexagonal, and the like.
  • the number of radio wave reflectors 12 formed on the base material layer 13 is set according to the size (area) of the radio wave reflectors 11 .
  • FIGS. 4 and 5 show another embodiment of the radio wave reflector 12, which is the conductive thin film layer 16.
  • FIG. The embodiment of FIGS. 4 and 5 differs from the embodiment of FIGS. 2 and 3 in the size and number of radio wave reflectors 12 .
  • the radio wave reflector 12 of the present embodiment is particularly suitable for wireless LAN (Wi-Fi (registered trademark)), sixth-generation mobile communication systems (6G), or later-generation mobile communication systems.
  • the length L1 of one side and the interval L2 between the adjacent radio wave reflectors 12 are set so as to reflect radio waves in the frequency band. In this embodiment, the length L1 of one side is set shorter than in the embodiment shown in FIGS.
  • the length L1 of one side is set to 7.7460 mm.
  • the length L1 of one side may be 0.7 mm or more and 800 mm or less, and the interval L2 may be 1 ⁇ m or more and 1000 ⁇ m or less.
  • the substrate layer 13 is set to have the same size as the substrate layer 13 in the embodiment shown in FIGS. 2 and 3. As shown in FIG. A total of 121 radio wave reflectors 12 of 11 are formed laterally. However, the number of radio wave reflectors 12 is appropriately set according to the size of the base material layer 13 . Other configurations of the conductive thin film layer 16 are the same as those of the embodiment shown in FIGS.
  • the periodic intervals of the radio wave reflectors 12 arranged periodically are small, it is possible to reflect the radio waves of 3 GHz or more and 10 GHz or less, which is the frequency band corresponding to the periodic intervals, in a wide angular range ⁇ . . Since other configurations and actions are the same as those of the embodiment shown in FIGS. 2 and 3, the same reference numerals are assigned to the corresponding configurations, and detailed description thereof will be omitted.
  • the conductive thin film layer 16 has one or a plurality of linear radio wave reflectors 12 arranged around a region 12a where there are no radio wave reflectors 12 . That is, the radio wave reflecting material 12 and the regions 12a without the radio wave reflecting material 12 are periodically arranged at predetermined intervals. The interval between adjacent regions 12a without the radio wave reflecting material 12 may be equal to the line width L6 of the radio wave reflecting material 12, or may be greater than the line width L6.
  • the term "linear" means that the length in the longitudinal direction is 3000 times or more the length in the direction orthogonal to the longitudinal direction.
  • the radio wave reflecting materials 12 are arranged at regular intervals along the vertical and horizontal directions, and the area 12a surrounded by the radio wave reflecting materials 12 and having no radio wave reflecting material 12 is a square. is. That is, the regions 12a without the radio wave reflecting material 12 are arranged with the line width L6 of the radio wave reflecting material 12 therebetween.
  • the radio wave reflecting materials 12A and 12B are electrically connected at intersections where the radio wave reflecting material 12 (12A) extending in the horizontal direction and the radio wave reflecting material 12 (12B) extending in the vertical direction overlap each other.
  • a line width L6 of the radio wave reflecting material 12 is preferably set to 0.05 ⁇ m or more and 15 ⁇ m or less.
  • the length L7 (the length of one side of the square area 12a without the radio wave reflecting material 12) between the radio wave reflecting materials 12 adjacent in the vertical direction or the horizontal direction is sufficiently larger than the wavelength of visible light, and the radio wave reflecting It is set to be shorter than the wavelength of radio waves reflected by the body 11, and in this example, is set to 2 ⁇ m or more and 10 cm or less. It is more preferably 20 ⁇ m or more and 1 cm or less, still more preferably 25 ⁇ m or more and 1 mm or less. More preferably, it is 30 ⁇ m or more and 250 ⁇ m or less.
  • the thickness L3 of the radio wave reflector 12 is preferably 0.05 ⁇ m or more and 10 ⁇ m or less.
  • the coverage of the conductive thin film layer 16 in this embodiment is preferably 50% or less, preferably 1% or more, and more preferably 10% or less.
  • the surface resistance value of the conductive thin film layer 16 in this embodiment is preferably 0.3 ⁇ / ⁇ or more and 10 ⁇ / ⁇ or less.
  • the preferable range, calculation formula, and measurement method of the developed interface area ratio Sdr of the conductive thin film layer 16 are the same as those of the embodiment shown in FIGS.
  • the conductive thin film layer 16 has a plurality of linear wave reflectors 12 .
  • the height is measured at a plurality of locations on the conductive thin film layer 16, and the developed interface area ratio Sdr is calculated from the obtained measured values. After that, by calculating the arithmetic average value, the developed interface area ratio Sdr of the conductive thin film layer 16 can be obtained.
  • the shape of the region 12a without the radio wave reflecting material 12 is a square.
  • the interval between the adjacent radio wave reflecting members 12B extending in the vertical direction may be different, and the shape of the region 12a without the radio wave reflecting member 12 may be rectangular.
  • the radio wave reflectors 12 may be arranged in the arrangement patterns shown in FIGS. 8(A) to (E).
  • FIG. 8A a plurality of radio wave reflecting materials 12A extend in the horizontal direction and are arranged at predetermined intervals in the vertical direction.
  • radio wave reflectors 12B are arranged in a zigzag pattern.
  • the zigzag pattern means that a plurality of radio wave reflecting materials 12B extending in the vertical direction are arranged at predetermined intervals in the horizontal direction, and the plurality of radio wave reflecting materials 12B forming one row are arranged in the vertical direction of the row.
  • the radio wave reflecting materials 12B positioned between the plurality of radio wave reflecting materials 12B forming adjacent lines are arranged so as to be aligned on a straight line.
  • the radio wave reflecting material 12A extends in the horizontal direction
  • the radio wave reflecting materials 12B and 12C extend along an oblique direction symmetrically inclined with respect to the horizontal direction
  • the radio wave reflecting materials 12B and 12C cross each other on the radio wave reflector 12A.
  • the shape of the area 12a without the radio wave reflector 12 is an equilateral triangle.
  • the shape of the area 12a without the radio wave reflecting material 12 may be an isosceles triangle or a triangle with three sides of different lengths instead of an equilateral triangle.
  • regular hexagonal areas 12a without the radio wave reflecting material 12 surrounded by the linear radio wave reflecting material 12 are periodically arranged
  • the linear radio wave reflecting material Regular pentagonal areas 12a surrounded by the material 12 and having no radio wave reflecting material 12 are periodically arranged.
  • circular areas 12a surrounded by linear radio wave reflecting materials 12 and having no radio wave reflecting material 12 are arranged periodically.
  • 8A to 8E show only the radio wave reflector 12.
  • a method for manufacturing the conductive thin film layer 16 having the arrangement pattern shown in FIGS. 6 to 8 a method of forming a conductive film, forming a pattern by etching, and taking out a conductive thin film having a pattern, and providing a lift-off layer.
  • a method of coating a photosensitive resist on a base film, forming a pattern by photolithography, filling the patterned portion with a conductive material, and then taking out a conductive thin film having a pattern can be used.
  • the method of manufacturing the conductive thin film layer 16 is not limited to the above, and includes a method of adhering a metal thin film, a method of vapor-depositing metal, and the like.
  • the adhesive layer 14 adheres the protective layer 15 onto the base material layer 13 and the conductive thin film layer 16, and is made of an adhesive material.
  • the adhesive layer 14 has a size corresponding to that of the base material layer 13 in plan view.
  • An adhesive sheet made of synthetic resin or rubber is used as the adhesive material that is the adhesive layer 14 .
  • synthetic resins include acrylic resins, silicon resins, polyvinyl alcohol resins, and the like.
  • the thickness L4 of the adhesive layer 14 is set to 150 ⁇ m in this embodiment, it is not limited to this, and is set to 5 ⁇ m or more and 500 ⁇ m or less.
  • the adhesive layer 14 may contain an arbitrary substance such as synthetic resin or an arbitrary member in addition to the adhesive.
  • the adhesive layer 14 is preferably made of a synthetic resin material with a dielectric loss tangent (tan ⁇ ) of 0.018 or less.
  • a lower dielectric loss tangent is more preferable, but it is usually 0.0001 or more.
  • the dielectric loss tangent represents the degree of electrical energy loss within a dielectric, and the greater the dielectric loss tangent of a material, the greater the electrical energy loss.
  • the synthetic resin material of the adhesive layer 14 has a dielectric constant that changes according to the frequency of the electric field.
  • the dielectric constant is the ratio of the dielectric constant of a medium (synthetic resin material in this embodiment) to the dielectric constant of a vacuum.
  • the dielectric constant at a frequency of 10 GHz preferably varies between 1.5 and 7. More preferably, it changes between 1.8 and 6.5.
  • Inductive loss tangent and relative permittivity are measured using a known method (e.g., cavity resonator method, coaxial resonator method) using a measuring device (e.g., Toyo Technica, model number TTPX table-top cryogenic prober, material impedance analyzer MIA-5M). measured by
  • the synthetic resin material that constitutes the base layer 13 and the protective layer 15 may have a dielectric loss tangent of 0.018 or less, and the dielectric constant changes according to the electric field. can be anything.
  • the protective layer 15 has a size corresponding to that of the base material layer 13 in plan view, protects the radio wave reflector 12, and is made of a protective material.
  • a synthetic resin sheet (film) is used as a protective material that is the protective layer 15 .
  • synthetic resins include PET (polyethylene terephthalate), COP (cycloolefin polymer), polyethylene, polypropylene, polyvinyl chloride, polystyrene, polymethyl methacrylate, polyester, polyformaldehyde, polyamide, polyphenylene ether, vinylidene chloride, and polyvinyl acetate.
  • the thickness L5 of the protective layer 15 is set to 50 ⁇ m in this embodiment, it is not limited to this, and is set to 20 ⁇ m or more and 1000 ⁇ m or less.
  • the protective layer 15 may contain an arbitrary substance such as synthetic resin or an arbitrary member.
  • the angle of incidence is ⁇ 15 degrees with respect to the reflected waves when the incident radio waves are regularly reflected.
  • the radio waves can be reflected while maintaining a high reflection intensity within a wide angular range ⁇ of , and the radio waves can be delivered to a wide range of space. Therefore, it is not necessary to install a large number of reflectors in order to reduce the dead space, unlike the conventional reflectors made of metal plates.
  • the frequency of the radio wave reflected by the radio wave reflector 11 is determined by setting the length L1 of one side of the radio wave reflector 12 and the interval L2 between the adjacent radio wave reflectors 12. determined by By setting the length L1 of one side and the interval L2, radio waves of 20 GHz or more and 300 GHz or less, which is the frequency band related to the fifth generation mobile communication system (5G), can be reflected in a wide range.
  • 5G fifth generation mobile communication system
  • the structure 10, which is the radio wave reflector 11 is transparent, it is possible to prevent the structure 10 from blocking or impeding the scenery such as the interior when the structure 10 is provided in the room of the building.
  • radio wave reflector 11 is kept in a sheet shape with resin, it is possible to maintain a metamaterial structure in which fine radio wave reflectors 11 are arranged periodically.
  • the structure 10, which is the radio wave reflector 11 has a thin overall thickness L11 of 1 mm or less, it is easy to have flexibility, and the structure 10 can be mounted on a curved surface.
  • the loss of electric energy of radio waves in the structure 10 is reduced, and the intensity of the reflected wave can be increased. Furthermore, since the dielectric constant of the resin changes according to the electric field, the intensity of the reflected wave in the electric field of a specific frequency can be further increased.
  • FIG. 9 shows another embodiment of the invention.
  • the structure 10, which is the radio wave reflector 11 shown in FIG. 9, has two conductive thin film layers 16A and 16B having radio wave reflectors 12A and 12B laminated vertically by base layers 13A and 13B made of resin. is.
  • Each radio wave reflecting material 12A formed on the base material layer 13A and each radio wave reflecting material 12B formed on the base material layer 13B are aligned and laminated so as to overlap when viewed from the top.
  • the arrangement patterns of the conductive thin film layers 16A and 16B in FIG. 9 do not have to overlap in plan view, and the conductive thin film layers 16A and 16B may be formed in different arrangement patterns.
  • the lower surface of the base layer 13B is attached onto the radio wave reflecting material 12A with an adhesive layer 14A, and the protective layer 15 is attached onto the radio wave reflecting material 12B with an adhesive layer 14B.
  • the radio waves incident on the radio wave reflector 11 are reflected by the radio wave reflecting material 12B in the first layer, but part of the radio waves pass through the radio wave reflecting material 12B without being reflected by the radio wave reflecting material 12B.
  • the radio waves passing through the radio wave reflecting material 12B are reflected by the second layer of the radio wave reflecting material 12A.
  • the kurtosis of the distribution of the reflection intensity can be further reduced in the angle range ⁇ of ⁇ 15 degrees with respect to the normal reflection direction of the radio wave, and the difference in reflection intensity depending on the angular position within the angle range ⁇ is reduced.
  • the value of the dielectric loss tangent is even smaller than in the embodiments shown in FIGS. Since other configurations and actions are the same as those of the embodiment shown in FIGS. 2 and 3, the same reference numerals are assigned to the corresponding configurations, and detailed description thereof will be omitted.
  • the radio wave reflecting material 12 formed on the base material layer 13 is laminated in two layers, but may be laminated in three or more layers.
  • the number of laminated radio wave reflectors 12 increases, the reflection intensity increases, but the overall thickness of the radio wave reflector 11 increases, resulting in reduced flexibility and visible light transmittance. Therefore, the number of laminations is appropriately set according to the intended use, such as increasing the number of laminations when the structure 10 is provided in a place where flexibility or transparency is not particularly required.
  • the developed interface area ratio Sdr is determined for each of the radio wave reflectors 12A and 12B, and the arithmetic mean value of the determined developed interface area ratio Sdr is used as the developed interface ratio Sdr of the conductive thin film layers 16A and 16B. good too.
  • the preferred range, calculation formula, and measurement method of the developed interface area ratio Sdr are the same as those in the embodiment shown in FIGS.
  • the structure 10 which is the radio wave reflector 11 comprises the conductive thin film layer 16 and the substrate layer 13 and does not comprise the adhesive layer 14 and the protective layer 15 .
  • the radio wave reflecting material 12 of the conductive thin film layer 16 is formed in a square shape as a sheet-shaped thin film on substantially the entire upper surface of the base material layer 13 .
  • the thickness L3 of the radio wave reflecting material 12 is set to 10 nm in this embodiment, it is not limited to this.
  • the surface resistance value is 9.8 ⁇ / ⁇ in this embodiment.
  • the coverage is defined as the ratio of the area occupied by the radio wave reflecting material 12 per unit area in the portion where the conductive thin film layer 16 is provided on the base material layer 13, and the coverage is 100%.
  • the radio wave reflector 11 has a total light transmittance of 70%. Since other configurations and actions are the same as those of the embodiment shown in FIGS. 2 and 3, the same reference numerals are assigned to the corresponding configurations, and detailed description thereof will be omitted.
  • the size of the radio wave reflecting material 12 may be one size smaller than the size of the base layer 13 in plan view, and the radio wave reflecting material 12 may not be formed in a region near the side edge of the base layer 13 .
  • the conductive thin film layer 16 is composed of one sheet of the radio wave reflecting material 12 in this embodiment, it may be composed of a plurality of sheets of the radio wave reflecting material 12 .
  • a plurality of radio wave reflectors 12 are arranged on substantially the entire upper surface of the base material layer 13 at predetermined intervals.
  • the shape of the radio wave reflector 12 may be circular, rectangular, triangular, polygonal, or the like.
  • the radio wave reflector 12 is not formed on the upper surface of the base material layer 13, but is made of a synthetic resin material as shown in FIG. It may be dispersed inside the base material layer 13 . According to this embodiment as well, it is possible to maintain a high reflection intensity within a wide angular range ⁇ of ⁇ 15 degrees with respect to the reflection direction when the radio waves are regularly reflected.
  • the radio wave reflector 11 is not limited to one having a metamaterial structure, and may be, for example, any one of a metal nanowire laminated film, multilayer graphene, and partially exfoliated graphite.
  • the radio wave reflecting material 12 may be particulate, scale-like, rod-like, or fibrous.
  • the particle size of the radio wave reflecting material 12 is not particularly limited, but the average particle size is preferably 0.01 ⁇ m or more and 0.8 ⁇ m or less.
  • a scaly shape refers to a flaky shape formed by crushing a three-dimensional shape such as a sphere or a mass in one direction, and includes shapes such as a plate shape, and is also referred to as a flake shape.
  • the size of the scale-like radio wave reflecting material 12 is not particularly limited, but the maximum length of a straight line passing through two different points on the outer periphery and the center of gravity in a plan view should be 0.4 ⁇ m or more and 0.8 ⁇ m or less. is preferable, the minimum length of the straight line is preferably 0.4 ⁇ m or more and 0.6 ⁇ m or less, the thickness is preferably 0.01 ⁇ m or more and 0.20 ⁇ m or less, and the aspect ratio is 1 or more and 10 or less is preferred.
  • rod-like refers to a rod-like shape elongated in the axial direction
  • the cross-sectional shape of the rod is not particularly limited, and may be rectangular, circular, elliptical, or polygonal, for example.
  • the cross-sectional shape of the rod may vary along the axial direction, including conical, dendritic, needle-like, and the like.
  • the length in the axial direction is preferably 0.4 ⁇ m or more and 0.8 ⁇ m or less, and the maximum length of a straight line passing through two different points on the outer peripheral edge and the center of gravity in a cross section at an arbitrary position in the axial direction is 0. It is preferably 0.01 ⁇ m or more and 0.8 ⁇ m or less, and the aspect ratio is preferably 1 or more and 1000 or less.
  • the fibrous shape refers to an elongated filamentous shape, the length in the longitudinal direction is preferably 0.8 ⁇ m or more and 2000 ⁇ m or less, the diameter is preferably 0.01 ⁇ m or more and 0.8 ⁇ m or less, and the aspect ratio is It is preferably 100 or more and 1,000,000 or less.
  • the dielectric constant at a frequency of 10 GHz of the radio wave reflecting material 12 dispersed inside the base material layer 13 is preferably 1.0 ⁇ 10 4 or more and 1.0 ⁇ 10 8 or less.
  • the material of the radio wave reflecting material 12 dispersed inside the base layer 13 is not particularly limited as long as it has the above-described shape and dielectric constant, and metals, alloys, or metal compounds can be used. , silver, platinum, nickel, aluminum, indium tin oxide and alloys thereof are preferred, and gold, silver, platinum, nickel and aluminum are more preferred.
  • the content of the particles in the substrate layer 13 is preferably 10 parts by weight or more and 4000 parts by weight or less, and preferably 20 parts by weight or more and 2000 parts by weight with respect to 100 parts by weight of the synthetic resin material contained in the substrate layer 13. It is more preferably 25 parts by weight or more and 1900 parts by weight or less.
  • the preferable range, calculation formula, and measurement method of the developed interface area ratio Sdr are the same as in the embodiment shown in FIGS.
  • the height on the surface of the base material 13, that is, the radio wave reflector 11 is measured at a plurality of points, and the developed interface area ratio Sdr is calculated from the measured values. After that, the developed interface area ratio Sdr can be obtained by calculating the arithmetic average value.
  • the radio wave reflector 12, which is the conductive thin film layer 16 is dispersed inside the base material layer 13, the developed interface area ratio Sdr of the conductive thin film layer 16 is calculated using the height of the base material 13. .
  • the structure 10 composed of any of the radio wave reflectors 11 described above may be included in the building material 30 and used.
  • the building material 30 is, for example, as shown in FIG. 12(A), wall surfaces, ceiling surfaces, floor surfaces of rooms and corridors, wallpaper for partitions, decorative materials 30A such as posters, and decorative materials such as transparent stickers for light covers.
  • 30B can be installed in a building.
  • the structure 10 may be formed as a member made of a non-conductive material such as resin or held inside a building material.
  • the wall surface 31 itself, which is the building material 30 , or the lamp cover 32 itself may be composed of the radio wave reflector 11 .
  • the building materials 30 are not limited to indoor walls and light covers, and may be, for example, partitions, pillars, lintels, outer walls of buildings, windows, and the like.
  • FIG. 12B is a plan view of the interior of the room, and the building material 30, which is the radio wave reflector 11, is formed as a corner pillar 30C having a curved surface at the corner of the room. The radio wave entering from the window 33 is reflected by the corner post 30C and reaches a wider range of the indoor space S. 12(A) and 12(B) show an application example of the building material 30, and do not show the actual range of radio wave reflection.
  • Examples 1 to 8 were produced as the structure 10 which is the radio wave reflector 11, and an evaluation test was conducted on practicality of angle, landscape security, and ease of installation for Examples 1 to 8 and Comparative Examples 1 to 3. .
  • the structure of the present invention is not limited to Examples 1-8.
  • the structure 10 produced as Example 1 has the same configuration as the embodiment shown in FIGS.
  • a synthetic resin material sheet made of PET Limirror 50T60 manufactured by Toray Industries, Inc.
  • the base material layer 13 had a thickness of 50 ⁇ m and a side length of 620.5 mm.
  • the radio wave reflecting material 12 is a metal thin film made of silver (Ag), and has a thickness (film thickness) L3 of 50 nm, a side length L1 of 77.460 mm, and an interval L2 between adjacent radio wave reflecting materials 12 of 100 ⁇ m (tolerance ⁇ 10 ⁇ m).
  • the radio wave reflecting material 12 has a developed interface area ratio Sdr of 30%, a surface resistance value of 8.7 ⁇ / ⁇ , and a coverage of 99.7%.
  • an optically adhesive silicon adhesive sheet manufactured by Iwatani Corporation, ISR-SOC 150 ⁇ type
  • the induced tangent of the adhesion layer 14 is 0.04, which is greater than 0.018.
  • a synthetic resin sheet made of PET Limirror 50T60 manufactured by Toray Industries, Inc.
  • the thickness of the protective layer 15 was set to 50 ⁇ m.
  • the total light transmittance of structure 10 is 82%.
  • Example 1 A method for manufacturing the structure 10 of Example 1 will be described. First, the radio wave reflector 12 is formed on the base layer 13 .
  • a roll-to-roll type sputtering apparatus is used.
  • a target containing a metal for example, silver
  • a ground shield is provided in such a size that 5% of the cathode is covered with respect to the cathode.
  • a film forming chamber of the sputtering apparatus is evacuated by a vacuum pump, the pressure is reduced to 3.0 ⁇ 10 ⁇ 4 Pa, for example, and argon gas is supplied at a predetermined flow rate (100 sccm), for example.
  • the substrate layer 13 is conveyed under the cathode at a conveying speed of 0.1 m/min and a tension of 100 N, for example.
  • a pulsed power of 5 kW is supplied from a bipolar power supply connected to the cathode, whereby metal is ejected from the target and deposited on the surface of the substrate layer 13, thereby forming a metal thin film.
  • the evaluation of whether or not the metal thin film is formed with the desired thickness is performed, for example, by the following procedure.
  • a nanoindenter TI950, manufactured by HYSITRON
  • HYSITRON a nanoindenter
  • the thickness of the metal thin film is measured from the gap caused by the indentation.
  • the average film thickness and standard deviation from the measured values of about 30 places, whether the average film thickness is the desired thickness L3 (e.g., 50 nm), and the variation in the measured values is within the desired range (e.g., the standard deviation is within 5).
  • the metal thin film is linearly scraped vertically and horizontally at predetermined intervals to divide it into a plurality of squares. Thereby, a plurality of radio wave reflectors 12 are formed on the base material layer 13 .
  • the protective layer 15 is attached to the layer radio wave reflecting material 12 with the adhesive layer 14 .
  • the adhesive layer 14 is used to adhere the protective layer 15 onto the radio wave reflector 12 of the base material layer 13 so as to prevent air bubbles from entering.
  • the structure 10, which is the radio wave reflector 11, is manufactured.
  • the structure 10 produced as Example 2 differs from Example 1 in the conductive thin film layer 16, the adhesive layer 14, and the protective layer 15.
  • the radio wave reflector 12 of the conductive thin film layer 16 has a developed interface area ratio Sdr of 27%, a surface resistance of 8.7 ⁇ / ⁇ , and a coverage of 99.7%.
  • the adhesive layer 14 the following rubber-based adhesive was used.
  • the adhesive layer 14 and the protective layer 15 of Example 2 have a dielectric loss tangent value of 0.002, which is 0.018 or less. Tangent value is small.
  • the total light transmittance of structure 10 is 82%. Other configurations are the same as those of the first embodiment.
  • the structure 10 produced as Example 3 has the same configuration as the embodiment shown in FIG.
  • the radio wave reflectors 12A and 12B of the conductive thin film layer 16 each have a developed interface area ratio Sdr of 60%, a surface resistance value of 8.7 ⁇ / ⁇ , and a coverage of 99.7%.
  • the total light transmittance of structure 10 is 80%.
  • Other configurations are the same as those of the first embodiment.
  • the structure 10 produced as Example 4 has the same configuration as the embodiment shown in FIGS. 4 and 5, and the radio wave reflector 12 has a side length L1 of 7.7460 mm.
  • the radio wave reflector 12 of the conductive thin film layer 16 has a developed interface area ratio Sdr of 21%, a surface resistance of 8.6 ⁇ / ⁇ , and a coverage of 97.4%.
  • the total light transmittance of structure 10 is 82%.
  • Other configurations of the radio wave reflector 12, the substrate layer 13, the adhesive layer 14, and the protective layer 15 are the same as those of the first embodiment.
  • the structure 10 produced as Example 5 has the same configuration as the embodiment shown in FIGS.
  • the radio wave reflector 11, which is the structure 10, has a square planar shape, the length L10 of one side is 20 cm, and the thickness L11 of the radio wave reflector 11 is 0.25 mm.
  • the total light transmittance of structure 10 is 85%.
  • a synthetic resin material sheet made of PET (Lumirror 50T60 manufactured by Toray Industries, Inc.) was used as the substrate layer 13, and the thickness L8 of the substrate layer 13 was set to 50 ⁇ m.
  • the radio wave reflector 12 of the conductive thin film layer 16 is a linear metal thin film made of silver (Ag), and has a thickness (film thickness) L3 of 0.5 ⁇ m (500 nm) and a line width L6 of 0.5 ⁇ m (500 nm).
  • the length L7 between the matching radio wave reflectors 12 was set to 60 ⁇ m.
  • the radio wave reflecting material 12 has a surface resistance value of 1.7 ⁇ / ⁇ and a coverage of 7%.
  • the spread interface area ratio Sdr of the radio wave reflector 12 is 10%.
  • the thickness L4 of the adhesive layer 14 was set to 150 ⁇ m.
  • the induced tangent of the adhesive layer 14 is 0.04.
  • a synthetic resin sheet made of PET Limirror 50T60 manufactured by Toray Industries, Inc.
  • the thickness L5 of the protective layer 15 was set to 50 ⁇ m.
  • the radio wave reflector 12 is formed on the base layer 13 .
  • a core layer of 0.01 ⁇ m or more and 3 ⁇ m or less is formed on one surface of a copper foil having a thickness of 5 ⁇ m or more and 200 ⁇ m or less, which has sufficient strength as a metal layer, by a method such as electrolytic or electroless plating.
  • a conductive thin film layer 16 having a predetermined arrangement pattern is formed on the surface of the core layer by a method such as electrolytic or electroless plating.
  • the entire conductive thin film layer 16 is covered with the base material layer 13 .
  • An adhesive is applied to the base layer 13 in advance.
  • the copper foil and core layer are removed by etching.
  • the radio wave reflector 12 is formed on the base material layer 13 .
  • the protective layer 15 is attached to the side of the radio wave reflecting material 12 opposite to the base layer 13 with the adhesive layer 14 .
  • the adhesive layer 14 is used to adhere the protective layer 15 onto the radio wave reflector 12 of the base material layer 13 so as to prevent air bubbles from entering.
  • the radio wave reflector 11 is manufactured.
  • the arrangement pattern of the radio wave reflectors 12 of the conductive thin film layer 16 is staggered as shown in FIG. 8A, and the line width L6 of the radio wave reflectors 12 is 0.4 ⁇ m. (400 nm), The coverage is 5%.
  • the radio wave reflector 12 has a surface roughness Sdr of 3%.
  • the total light transmittance of structure 10 is 87%.
  • Other configurations are the same as those of the fifth embodiment.
  • the arrangement pattern of the radio wave reflecting material 12 of the conductive thin film layer 16 is the same as that of Example 5, the thickness (film thickness) L3 of the radio wave reflecting material 12 is 5 ⁇ m, and the line width L6 is It was set to 0.2 ⁇ m (200 nm). The coverage is 10%.
  • the spread interface area ratio Sdr of the radio wave reflector 12 is 572%.
  • the total light transmittance of structure 10 is 90%.
  • Other configurations are the same as those of the fifth embodiment.
  • the structure 10 produced as Example 8 has a configuration similar to that of the embodiment shown in FIG.
  • the thickness L8 of the base material layer 13 is 128 ⁇ m.
  • the radio wave reflecting material 12 dispersed inside the base material layer 13 is particles made of silver and has an average particle diameter of 0.4 ⁇ m (400 nm).
  • the content of the particles is 110 parts by weight with respect to 100 parts by weight of the synthetic resin material content of the base material layer 13 .
  • the developed interface area ratio Sdr is 90%.
  • the total light transmittance of structure 10 is 80%.
  • Comparative Example 1 As Comparative Example 1, an aluminum plate with a thickness of 3 mm was used. Comparative Example 1 has a developed interface area ratio Sdr of 0.3% and a total light transmittance of 0%.
  • Comparative Example 2 an aluminum sheet (aluminum foil) with a thickness of 0.012 mm was used. Comparative Example 2 has a developed interface area ratio Sdr of 6% and a total light transmittance of 10%.
  • Comparative Example 3 an aluminum plate with a thickness of 0.6 mm was used. Comparative Example 2 has a developed interface area ratio Sdr of 0.3% and a total light transmittance of 0%.
  • radio waves with frequencies changed from 3 GHz to 300 GHz (4 GHz, 28.5 GHz, 47 GHz, 95 GHz, 144 GHz, 160 GHz, 300 GHz) are output, and the amount of reflection (reflection intensity) for the radio waves of each frequency is measured. It was measured.
  • a reference metal plate (aluminum A1050 plate, thickness 3 mm) was placed on the sample stand, and the reception level was measured and recorded using a scalar network analyzer.
  • the coaxial cables of the receiving antenna and the transmitting antenna were directly connected by a scalar network analyzer, and the signal level at each frequency was calibrated as 0.
  • the device was reconfigured and measurements were taken.
  • the reference metal plate was removed from the sample mount, the sample was placed on the sample mount, and the reception level was measured and recorded. By subtracting the reception level of the reference metal plate from the measured reception level, the reflection amount in the regular reflection direction of the structure 10 to be measured was obtained.
  • the receiving antenna was moved to angular positions of ⁇ 5 degrees, ⁇ 10 degrees, and ⁇ 15 degrees with respect to the normal reflection direction of the radio wave centering on the reflection point 11a of the sample, and the reception level was measured at each reception angle position. recorded. Similar measurements were repeated for each sample.
  • the frequency of the radio wave was 10 GHz or less
  • the sample was irradiated with a plane wave using an appropriate millimeter wave lens in consideration of the first Fresnel radius of the rectangular horn antenna.
  • the kurtosis was calculated based on the above formula (1) from the measured values of the amount of reflection at each reception angle position.
  • Angle practicality is an index for evaluating whether or not reflected waves can be sufficiently received by the receiving antenna within an angular range ⁇ of ⁇ 15 degrees with respect to the normal reflection direction.
  • the installability is an index for evaluating whether or not it is possible to attach the structure 10 to a curved surface when installing the structure 10 on a building or the like. When it was possible, it was evaluated as "O”, and when it was not possible, it was evaluated as "X".
  • the landscape security property is an index for evaluating the transparency of the structure 10.
  • the texture of the wall can be seen with "O”, and the case when it cannot be seen with "X”. evaluated.
  • Tables 1 to 4 show experimental results. Table 1 shows the results of regular reflection intensity, kurtosis, and angle practicality when the incident angle of radio waves is set at 30 degrees.
  • the regular reflection intensity for radio waves of frequencies of 4 GHz, 28.5 GHz, 47 GHz, 95 GHz, 144 GHz, 160 GHz and 300 GHz was -30 dB or more.
  • the regular reflection intensity was ⁇ 30 dB for radio waves with a frequency of 300 GHz.
  • the receiving antenna is moved to angular positions of 0, ⁇ 5, ⁇ 10, and ⁇ 15 degrees with respect to the normal reflection direction of the radio wave centering on the reflection point 11a of the sample, and the reflection intensity is measured at each receiving angular position. was measured, the kurtosis was ⁇ 0.4 or less in all examples 1 to 8. In addition, in all examples of Examples 1 to 8, the reflection intensity was -45 dB or -40 dB or more at all reception angle positions, and the angle practicality was evaluated as "A" or "B". Table 1 also lists the surface roughness Sdr of Examples 1-8.
  • Comparative Examples 1 and 3 although the normal reflection intensity was -30 dB or more for radio waves of each frequency, the kurtosis was greater than -0.4, and the angle practicality was evaluated as "C”.
  • Comparative Example 2 the regular reflection intensity was smaller than ⁇ 30 dB for radio waves of each frequency, the kurtosis was ⁇ 0.4 or more, and the angle practicality was evaluated as “C”.
  • Table 2 shows the results of regular reflection intensity, kurtosis, and angle practicality when the incident angle of radio waves is set to 45 degrees.
  • the normal reflection intensity for radio waves of each frequency was -30 dB or more.
  • the kurtosis was -0.4 or less in all of Examples 1 to 8.
  • the reflection intensity was -45 dB or -40 dB or more at all reception angle positions, and the angle practicality was evaluated as "A" or "B".
  • Comparative Examples 1 and 3 although the normal reflection intensity was -30 dB or more for radio waves of each frequency, the kurtosis was greater than -0.4, and the angle practicality was evaluated as "C".
  • Comparative Example 2 the regular reflection intensity was less than -30 dB for radio waves of each frequency, the kurtosis was -0.4 or more, and the angle practicality was evaluated as "C”.
  • Table 3 shows the results of regular reflection intensity, kurtosis, and angle practicality when the incident angle of radio waves is set to 60 degrees.
  • the normal reflection intensity for radio waves of each frequency was -30 dB or more.
  • the kurtosis was -0.4 or less in all of Examples 1 to 8.
  • the reflection intensity was -45 dB or -40 dB or more at all reception angle positions, and the angle practicality was evaluated as "A" or "B".
  • Comparative Examples 1 and 3 although the normal reflection intensity was -30 dB or more for radio waves of each frequency, the kurtosis was greater than -0.4, and the angle practicality was evaluated as "C”.
  • Comparative Example 2 the regular reflection intensity was smaller than ⁇ 30 dB for radio waves of each frequency, the kurtosis was ⁇ 0.4 or more, and the angle practicality was evaluated as “C”.
  • the structures 10 of Examples 1 to 6 and 8 are 4 GHz and 28.5 GHz regardless of the incident angle of radio waves of 30 degrees, 45 degrees, and 60 degrees. , 47 GHz, 95 GHz, 144 GHz, 160 GHz, and 300 GHz. .
  • the structures 10 of Examples 1 to 8 have frequencies of 4 GHz, 28.5 GHz, 47 GHz, 95 GHz, 144 GHz, 160 GHz, and 300 GHz, regardless of whether the incident angle of radio waves is 30 degrees, 45 degrees, or 60 degrees. When the radio wave of each frequency was reflected, the kurtosis was -0.4 or less.
  • Example 1 The regular reflection intensity, kurtosis, and angle practicality of each of Examples 1 to 8 will be explained using a case where the incident angle of the radio wave is 45 degrees and the frequency of the radio wave is 28.5 GHz.
  • the regular reflection intensity is -24.8 dB, which is -30 dB or less.
  • the kurtosis is -1.27, less than -0.4.
  • the regular reflection intensity is greater than -40.3 dB in Comparative Example 6, and the kurtosis is -0.2 in Comparative Example 1, -0.4 in Comparative Example 2, and -0.2 in Comparative Example 3. small.
  • Example 1 is rated A, while Comparative Examples 1 to 3 are rated C.
  • Example 2 the regular reflection intensity is -22.6 dB, which is more than -30 dB, and the kurtosis is -1.14, which is less than -0.4.
  • Example 2 uses the adhesive layer 14 and the protective layer 15 having a smaller dielectric loss tangent value than Example 1, and although the kurtosis is higher than Example 1, the regular reflection intensity is high, and the angle practicality is A was an evaluation.
  • Example 3 the regular reflection intensity is -20.5 dB, which is -30 dB or more, and the kurtosis is -1.72, which is -0.4 or less.
  • Example 3 a plurality of radio wave reflecting materials 12 are laminated, and the regular reflection intensity is higher and the kurtosis value is smaller than in Example 1. Angle practicality was rated A.
  • Example 4 the length L1 of one side of the radio wave reflecting material 12 is smaller than that in Example 1, the normal reflection intensity is -22.1 dB and is -30 dB or more, and the kurtosis is -1.19. ⁇ 0.4 or less. Angle practicality was rated A.
  • the conductive thin film layer 16 is made of a linear wave reflecting material 12, and as shown in FIG. It is In this case, the regular reflection intensity is -20.1 dB, which is more than -30 dB, and the kurtosis is -1.01, which is less than -0.4. Angle practicality was rated A.
  • Example 6 the conductive thin film layer 16 is made of the linear radio wave reflecting material 12 in the same manner as in Example 5, but the conductive thin film layer 16 has the shape shown in FIG. less than In Example 6, the regular reflection intensity was ⁇ 20.2 dB and ⁇ 30 dB or more, the kurtosis was greater than that in Example 5, ⁇ 0.4, and the angle practicality was evaluated as B. rice field.
  • Example 7 the thickness L3 of the conductive thin film layer 16 is 10 times that of Example 5, and the line width L6 is smaller than that of Example 5.
  • the regular reflection intensity was ⁇ 28.3 dB and ⁇ 30 dB or more, the kurtosis was ⁇ 2.5 and ⁇ 0.4 or less, and the angle practicality was evaluated as A. .
  • Example 8 the particulate radio wave reflecting material 12 is dispersed in the base material layer 13, and in Example 7, the normal reflection intensity is -24.8 dB, which is -30 dB or more, and the kurtosis is was -4.5 and -0.4 or less, and the angle practicality was rated A.
  • Table 4 evaluates the installability and landscape security of Examples 1 to 8 and Comparative Examples 1 to 3.
  • Examples 1 to 8 have a total light transmittance of 80% or more and are transparent, and are evaluated as ⁇ .
  • Comparative Examples 1 to 3 had low total light transmittance and were not transparent, and were all evaluated as x.
  • Examples 1 to 8 are flexible and can be attached to a curved surface, so they were evaluated as ⁇ , but Comparative Examples 1 and 3 are aluminum plates and are difficult to bend. It was evaluated as ⁇ because it could not be attached to a curved surface.

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WO2023127710A1 (ja) * 2021-12-27 2023-07-06 積水化学工業株式会社 電波反射体
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WO2025013938A1 (ja) * 2023-07-13 2025-01-16 積水化学工業株式会社 電磁波反射体
WO2025100389A1 (ja) * 2023-11-08 2025-05-15 Ａｇｃ株式会社 電磁波反射フィルム、及び電磁波反射フィルムのタイリング方法
WO2025115482A1 (ja) * 2023-11-30 2025-06-05 Ａｇｃ株式会社 受信電力の測定方法、電力反射効率の計算方法、受信電力の測定プログラム、及び、電力反射効率の計算プログラム
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WO2025013938A1 (ja) * 2023-07-13 2025-01-16 積水化学工業株式会社 電磁波反射体
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