WO2022147914A1 - 一种高阻燃性汽车革用无溶剂聚氨酯树脂及其制备方法 - Google Patents

一种高阻燃性汽车革用无溶剂聚氨酯树脂及其制备方法 Download PDF

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WO2022147914A1
WO2022147914A1 PCT/CN2021/084272 CN2021084272W WO2022147914A1 WO 2022147914 A1 WO2022147914 A1 WO 2022147914A1 CN 2021084272 W CN2021084272 W CN 2021084272W WO 2022147914 A1 WO2022147914 A1 WO 2022147914A1
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component
modified
solvent
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preparation
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石磊
纪尚超
沈连根
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浙江禾欣科技有限公司
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/4808—Mixtures of two or more polyetherdiols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4825—Polyethers containing two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/146—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes characterised by the macromolecular diols used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/322—Ammonium phosphate
    • C08K2003/323—Ammonium polyphosphate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear

Definitions

  • the invention belongs to the technical field of industrial semi-finished products and relates to synthetic leather, in particular to a solvent-free polyurethane resin for automotive leather with high flame retardancy and a preparation method thereof
  • Urethane synthetic leather is widely used in automobile products of high-end brands at home and abroad such as Mercedes-Benz, BMW, Volkswagen, Audi, Hongqi, etc. , steering wheel, interior leather) has unique advantages and is considered as a perfect substitute for natural leather and has attracted much attention.
  • the traditional polyurethane has the problem of the release of toxic gases such as DMF in the process of production and consumption.
  • DMF toxic gases
  • solvent-free polyurethane does not add any solvent harmful to human body in the production process. It is a new type of polyurethane developed based on the combination of solvent-based polyurethane synthetic leather production process and two-component production process.
  • the synthetic leather preparation technology has the advantages of low energy consumption, no organic solvent release during the production process, safety and environmental protection, and almost no VOC (volatile organic compounds) residues in the finished leather, so it is sought after by consumers.
  • invention patent CN106008892A discloses that flame retardant hydrolysis-resistant and solvent-free polyurethane synthetic leather resin is prepared by adding additive flame retardant and reactive flame retardant to hydroxyl A component, so as to solve the problem of synthetic leather's flame retardant performance and hydrolysis resistance. Double requirements for performance.
  • Invention patent CN107503168A discloses that a solvent-free polyurethane layer is prepared by adding a compound flame retardant containing red phosphorus and aluminum hydroxide to the polyol A component system, thereby improving the flame retardant performance of solvent-free synthetic leather. Although its flame retardant performance has been improved to a certain extent, there are still problems such as poor dispersion and compatibility due to the large amount of flame retardant added.
  • hydroxyl-modified ammonium polyphosphate can chemically irreversibly combine with polyurethane, and at the same time has good compatibility with polyurethane, and can improve the performance of polyurethane to a certain extent, especially the resistance to Thermal, wear-resistant and flame-retardant properties.
  • nano-filling material nano-aluminum hydroxide has a certain reinforcement and flame-retardant effect on the product, but it is added in a large amount during use, and it is easy to agglomerate in the organic phase matrix and has poor compatibility. Therefore, relevant It is undoubtedly an effective way to process the surface of aluminum hydroxide. Unlike general synthetic leather, automotive leather has very high requirements in terms of flame retardancy. Therefore, how to use hydroxyl-modified ammonium polyphosphate and modified aluminum hydroxide to achieve high flame-retardant effect is of great significance.
  • the present invention proposes a solvent-free polyurethane resin for automotive leather with high flame retardancy and a preparation method thereof, which can effectively solve the above problems.
  • the object of the present invention is to provide a solvent-free polyurethane resin for automotive leather with high flame retardancy and a preparation method thereof, thereby solving the problem of taking into account the environmental protection performance and special functionality encountered in the use of automotive leather seats and decorative materials. question.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy which is composed of A component and B component in a mass ratio of 2:3 to 3:2, after being stirred and mixed at a high speed by a low-pressure casting machine, and then coated on a release paper. Then it is prepared by drying at high temperature at 110-130°C;
  • the A component is composed of the following components by mass fraction:
  • the B component is composed of the following components according to the mass fraction:
  • the isocyanate is any one or a mixture of IPDI, HDI and carbodiimide modified MDI;
  • the polyether glycol is polyethylene glycol and polypropylene glycol with molecular weights of 1000, 1500, 2000 and 2500.
  • the chain extender is one or any of ethylene glycol, 1,3-propanediol, 1,4-butanediol;
  • the catalyst is stannous octoate, two One of dibutyltin laurate.
  • the molecular weight of the hydroxyl-modified ammonium polyphosphate is 1000, 1500, 2000, and 2500, obtained from 3-aminopropanol-modified ammonium polyphosphate;
  • ammonium polyphosphate As an intumescent flame retardant containing phosphorus and nitrogen, ammonium polyphosphate has high nitrogen and phosphorus content, good flame retardant effect, good thermal stability and high temperature resistance mechanical properties; In solvent-free polyurethane, it can not only improve its flame retardancy, but also improve its heat resistance, wear resistance and other properties, and develop polyurethane polymer materials with superior performance.
  • the modified aluminum hydroxide has a mesh number of 1000 and is obtained from stearic acid modified aluminum hydroxide nano-powder.
  • a further scheme is that the small molecule chain extender is selected from any one or more of ethylene glycol, 1,3-propanediol, 1,4-butanediol, 2-methylpropanediol and dipropylene glycol. mixture.
  • a further scheme is that the amine catalyst is any one of triethylenediamine, N,N-bis(dimethylaminopropyl) isopropanolamine, and N-(dimethylaminopropyl) diisopropanolamine. kind.
  • the metal catalyst is a delayed organic catalyst, which is any one or a mixture of organic tin and organic bismuth, preferably any one or more of TEGOKAT 722, BICAT 8108 and Borchi Kat24.
  • the leveling agent is selected from any one or mixtures of BYK-UV3510, BYK-UV3500, TEGO Flow300, TEGO Rad 2200N and TEGO Rad 2100.
  • the diisocyanate is any one or a mixture of MDI, TDI, MDI-50, carbodiimide-modified MDI, HDI-100, and dicyclohexylmethane diisocyanate.
  • the antioxidant is selected from any one or mixtures of antioxidant 264, antioxidant 1076 and triphenyl phosphite.
  • the polytetrahydrofuran diol is selected from any one or a mixture of PTMEG-1000, PTMEG-1500, PTMEG-2000 and PTMEG-3000.
  • the present invention also provides a preparation method for preparing the solvent-free polyurethane resin for automobile leather with high flame retardancy, comprising the following steps:
  • the present invention has the following advantages and beneficial effects:
  • the present invention utilizes the solvent-free polyurethane synthesis and production process of the semi-prepolymer method to first synthesize the A component and the prepolymer B component with the modified ammonium polyphosphate respectively, and then mix the A and B components.
  • component A introduces hydroxyl-modified ammonium polyphosphate as a kind of chain extension component, and further reacts with the prepolymer of component B, and the modified structure of ammonium polyphosphate can be embedded in the polyurethane structure,
  • the flame retardancy of solvent-free polyurethane is improved by chemical modification.
  • nano aluminum hydroxide is introduced into solvent-free polyurethane, which has a certain reinforced flame-retardant effect. After surface modification, it can be evenly distributed in the polyurethane, and the solvent-free polyurethane can be improved by physical blending.
  • the flame retardancy of resin further solves the requirements for high flame retardancy and high abrasion resistance of automotive leather.
  • the present invention uses the method of combining physical and chemical modification, and utilizes the synergistic effect of organic in-situ flame retardant and inorganic filling flame retardant, which well balances the effects of high-content filling.
  • the improvement of flame retardant performance and the decrease of physical and mechanical properties are contradictory.
  • Figure 1 is the SEM images of the solvent-free synthetic leather (a) containing ammonium polyphosphate filler particles and the solvent-free synthetic leather (b) containing surface-modified aluminum hydroxide and hydroxyl-modified ammonium polyphosphate block copolymer;
  • Figure 2 shows the surface-modified aluminum hydroxide (mAl(OH)3) (a), the block copolymerized hydroxyl modified ammonium polyphosphate (HAPP) (b), and the compound modified by mAl(OH)3 and HAPP (c). ) Morphology of the solvent-free polyurethane resin for automotive leather after transverse combustion.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • Polyether glycol is a polypropylene glycol product with a molecular weight of 1000 produced by Tianjin Zhonghe Shengtai Chemical Co., Ltd.
  • the modified ammonium polyphosphate is prepared from the following components according to the mass fraction:
  • ammonium polyphosphate HT-208 product with a molecular weight of 1000 produced by Jinan Taixing Chemical Co., Ltd. was selected as the ammonium polyphosphate
  • the IPA product of Shanghai Senxu Chemical Technology Co., Ltd. was selected for 3-aminopropanol.
  • the modified aluminum hydroxide is prepared from the following components according to mass fraction:
  • the aluminum hydroxide powder was selected as the AH-1 product with a mesh number of 1000 from Yuejiang New Materials Co., Ltd., and the stearic acid was selected as the 1801 product of Jinan Shuangping Chemical Industry.
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 from the German YOUNGING Group are selected, and the ratio is 3:1
  • Polytetrahydrofuran ether glycol with a molecular weight of 2000 produced by Zhengzhou Bolian Trading Co., Ltd. was selected.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of the -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is made up of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is prepared by mixing 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • the antioxidants are selected from the products of Antioxidant 264 and Antioxidant 1076 of the German YOUNGING Group, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen through the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is made up of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is prepared by mixing 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of the -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of the -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is made up of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of the -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of the -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of the -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen through the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of the -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of the -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of the -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is made up of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of the -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is prepared by mixing 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen into the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen through the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of the -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • a solvent-free polyurethane resin for automotive leather with high flame retardancy is prepared by mixing A component and B component in a mass ratio of 3:2 to 2:3,
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the water in the reactor was removed by passing nitrogen through the reactor, then the liquid diisocyanate and antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether diol 2000 was added and the temperature was raised to 80 ° C , stirring at a constant temperature for 3 hours, until the content m of the detected value of the -NCO group is controlled at 8% ⁇ m ⁇ 10% by weight percentage to obtain component B, which is sealed and packaged for use.
  • the solvent-free A and B components which are fully mixed in a low pressure casting machine according to the mass fraction of 1:1.15, are cast and coated on the release paper, and dried in an oven at 110-130 ° C to obtain high flame retardant automotive leather.
  • the present invention also provides a comparative example of the above-mentioned solvent-free polyurethane resin for automotive leather with high flame retardancy, that is, the hydroxyl-modified ammonium polyphosphate and modified aluminum hydroxide are removed in the scheme of Example 2, as follows:
  • the A component is made of the following components according to the mass fraction:
  • the B component is made of the following components according to the mass fraction:
  • the isocyanate-modified diol is composed of the following components according to mass fraction:
  • IPDI Isocyanate
  • the small molecule chain extender is a mixture of 1,4-butanediol and dipropylene glycol at a ratio of 2:1.
  • the amine catalyst is a low-odor N,N-bis(dimethylaminopropyl)isopropanolamine product from Dow Corporation of the United States.
  • the metal catalyst is a delayed organic catalyst, and the BICAT 8108 product produced by Jiaxing Hexin Chemical Co., Ltd. is selected.
  • antioxidant 264 and antioxidant 1076 products of Germany YOUNGING Group are selected, and the ratio is 3:1.
  • the preparation method comprises the following steps:
  • the water in the reactor was removed by passing nitrogen into the reactor, then the carbodiimide-modified MDI and the antioxidant were put into the reactor and stirred evenly, and then the dehydrated polytetrahydrofuran ether glycol 2000 was heated up.
  • the solvent-free A and B components which are fully mixed in a low-pressure casting machine according to the mass fraction of 3:2 to 2:3, are cast and coated on the release paper, and dried in an oven at 110-130 °C to obtain a solvent-free solution.
  • Polyurethane resin
  • the softness and hardness of the hand are tested by a hardness tester. The higher the value, the softer the hand feel.
  • the limit oxygen index is tested by an oxygen index tester. A high oxygen index indicates that the material is not easy to burn; a low oxygen index indicates that the material is easy to burn. It is generally believed that the oxygen index ⁇ 22% is a flammable material, the oxygen index is between 22% and 27% is a combustible material, and the oxygen index > 27% is a flame retardant material.
  • the synthetic leather obtained by using the high flame-retardant solvent-free polyurethane resin of the present invention has a slightly better hand feel than the comparative example, and the peel strength is reduced to some extent, but the flame retardant performance is greatly improved. It shows that this technology can greatly improve the flame retardant properties of synthetic leather without changing the performance of the original solvent-free synthetic leather. And this technology can be used in the field of automotive leather that requires relatively high flame retardant properties.

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Abstract

本发明公开了一种高阻燃性汽车革用无溶剂聚氨酯树脂及其制备方法。A组分和B组分按质量比为2∶3～3∶2经低压浇注机高速搅拌混合后涂覆于离型纸上，然后在高温下烘干从而制备而成，其中A组分由异氰酸酯改性的二元醇、羟基改性聚磷酸铵、改性氢氧化铝、小分子扩链剂、胺类催化剂、金属催化剂和流平剂制备而成；B组分由含异氰酸酯端基的预聚物和抗氧化剂制备而成。本发明的高阻燃性汽车革用无溶剂聚氨酯树脂具有快速成型的特点，且不含任何有机溶剂，工艺效果稳定，导热系数低，柔软度可达6.0以上，同时，本发明所用的阻燃材料引入到聚氨酯中，可在增强汽车革阻燃性的同时提高聚氨酯树脂耐磨、柔软等物性。

Description

一种高阻燃性汽车革用无溶剂聚氨酯树脂及其制备方法 技术领域
本发明属于工业半成品涉及合成革技术领域，具体涉及一种高阻燃性汽车革用无溶剂聚氨酯树脂及其制备方法
背景技术
氨酯合成革因其具有柔软、耐寒、防水、透湿、保暖的优异特性而被广泛应用在奔驰、宝马、大众、奥迪、红旗等国内外高端品牌的汽车产品当中，尤其在(座垫革、方向盘、内饰革)等方面具有独特优势，被认为作为天然皮革完美的替代品而备受关注。但传统的聚氨酯在生产和服用过程中存在DMF等有毒气体释放的问题。随着国内外对于产品环保性的愈加重视，不少上游品牌对于聚氨酯生产低VOC的要求逐渐严格，甚至要求无DMF的释放，以致不少下游企业也逐步开始对传统聚氨酯生产工艺进行改善和优化。
无溶剂聚氨酯相较于传统的聚氨酯，在生产过程中未添加对人体有害的溶剂，它是基于溶剂型聚氨酯合成革生产工艺和双组份制件的生产工艺相结合而开发的一种新型聚氨酯合成革制备技术，具有能耗低、生产过程中无任何有机溶剂释放、安全环保等优点，且成品革几乎无VOC(挥发性有机化合物)残留，因此受到消费者的追捧。
聚氨酯合成革作为一种易燃的材料，其在燃烧时产生大量有害气体，在用于汽车座椅和装饰材料时存在着极大的安全隐患。目前对于如何提高无溶剂聚氨酯合成革阻燃性能鲜有报道。发明专利CN106008892A公开了通过在羟基A组分中加入添加型阻燃剂和反应性阻燃剂，制得阻燃型耐水解无溶剂聚氨酯合成革树脂，从而解决合成革对阻燃性能及耐水解性能的双重要求。该专利存在的问题：从实施例检测结果可以看出，其无溶剂聚氨酯成膜后贴合在基布上，其阻燃效果有很大的差异，阻燃剂在无溶剂层分散并不均匀，且阻燃剂含量较少，阻燃效果并不十分理想。
发明专利CN107503168A公开了通过在多元醇A组分体系中加入含红磷和氢氧化铝的复配阻燃剂制备出无溶剂聚氨酯层，从而提高无溶剂合成革的阻燃性能。虽然其在阻燃性能上有一定的提高，但仍存在由于阻燃剂添加量较大所导致的分散性、相容性差等问题。羟基改性聚磷酸铵作为一种磷系阻燃材料，它能与聚氨酯发生化学不可逆的结合，同时与聚氨酯具有很好的相容性，对聚氨酯的性能能够产生一定程度的改善，尤其是耐热、耐磨和阻燃等性能。纳米氢氧化铝作为一种纳米填充材料，对该产品具有一定的补强阻燃作用，但其在使用时添加量较大，于有机相基体中容易凝聚，相容性较差，因此采取相关技术对氢氧化铝表面进行加工，无疑是一种有效的途径。汽车革不同于一般的合成革，在阻燃等方面要求非常高，因此如何利用羟基改性聚磷酸铵和改性氢氧化铝达到高阻燃的效果具有十分重要的意义。
基于以上情况，本发明提出了一种高阻燃性汽车革用无溶剂聚氨酯树脂及其制备方法，可以有效的解决以上问题。
发明内容
本发明的目的在于提供一种高阻燃性汽车革用无溶剂聚氨酯树脂及其制备方法，从而解决了汽车革座椅和装饰材料在使用过程中所遇到的环保性能和特殊功能性兼顾的问题。
本发明的技术方案如下
一种高阻燃性汽车革用无溶剂聚氨酯树脂，其由A组分和B组分按质量比为2:3～3:2经低压浇注机高速搅拌混合后涂覆于离型纸上，然后在110～130℃下高温烘干从而制备而成；
其中A组分是由以下组分按质量分数组成：
Figure PCTCN2021084272-appb-000001
所述羟基改性聚磷酸铵的结构式为：
Figure PCTCN2021084272-appb-000002
其中B组分是由以下组分按照质量分数组成：
二异氰酸酯         150～250份
抗氧化剂           2～3份
聚四氢呋喃醚二醇   30～60份
进一步方案，所述异氰酸酯改性的二元醇是由以下组分按照质量分数制备而成：
Figure PCTCN2021084272-appb-000003
所述异氰酸酯为IPDI、HDI、碳化二亚胺改性MDI中的任意一种或几种的混合物；所述聚醚二元醇为分子量1000、1500、2000、2500的聚乙二醇、聚丙二醇中的一种或任意几种，所述扩链剂为乙二醇、1,3-丙二醇、1,4-丁二醇中的一种或任意几种；所述催化剂为辛酸亚锡、二月桂酸二丁基锡中的一种。
进一步方案，所述羟基改性聚磷酸铵的分子量为1000、1500、2000、2500，由3-氨基丙醇改性聚磷酸铵所得；
聚磷酸铵作为一种含磷、氮的膨胀型阻燃剂，它的氮、磷含量较高，阻燃效果好，同时它的热稳定性较好，耐高温力学性能也好；将其应用到无溶剂聚氨酯当中既可以提高它的阻燃性，又可以提高它的耐热、耐磨等性能，开发出性能优越的聚氨酯高分子材料。
进一步方案，所述改性氢氧化铝目数为1000，由硬脂酸改性氢氧化铝纳米粉末所得。
进一步方案是，所述小分子扩链剂选自乙二醇、1,3-丙二醇、1,4-丁二醇、2-甲基丙二醇和一缩二丙 二醇中的任意一种或几种的混合物。
进一步方案是，所述胺类催化剂为三乙烯二胺、N,N-双(二甲氨基丙基)异丙醇胺、N-(二甲氨丙基)二异丙醇胺中的任意一种。
进一步方案是，所述金属催化剂为延迟类有机催化剂，为有机锡、有机铋中的任意一种或几种的混合物，优选TEGOKAT 722、BICAT 8108和Borchi Kat24中的任意一种或几种。
优选方案是，所述的流平剂选自BYK-UV3510、BYK-UV3500、TEGO Flow300、TEGO Rad 2200N和TEGO Rad 2100中任意一种或几种的混合物。
进一步方案，所述二异氰酸酯为MDI、TDI、MDI-50、碳化二亚胺改性MDI、HDI-100、二环己基甲烷二异氰酸酯中的任意一种或几种的混合物。
进一步方案，所述抗氧剂选自抗氧剂264、抗氧剂1076和亚磷酸三苯酯中任意一种或几种的混合物。
进一步方案，所述聚四氢呋喃二元醇选自PTMEG-1000、PTMEG-1500、PTMEG-2000和PTMEG-3000中的任意一种或几种的混合物。
本发明还提供制备所述的高阻燃性汽车革用无溶剂聚氨酯树脂的制备方法，包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇20～30份倒入进乙醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到90℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(1)改性氢氧化铝的制备：
将氢氧化铝超细粉末100份与去离子水混合配制成浓度为5％～8％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸2～5份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干即可制得改性氢氧化铝。
(2)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65-85℃，搅拌3-5h，检测水分含量在5000-9000ppm之间，然后降温至40℃投入胺类催化剂、流平剂、改性氢氧化铝粉末，恒温搅拌1.5～2h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(3)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇升温至80℃-85℃，恒温搅拌3-6h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％合格后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数2:3-3:2充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
与现有技术相比，本发明具有以下优点及有益效果：
(1)本发明利用半预聚体法的无溶剂聚氨酯合成生产工艺，分别先合成具有改性聚磷酸铵的A组分和预 聚体B组分，然后将A,B组分进行混合后发生一系列反应，制得具有高阻燃性汽车革用无溶剂聚氨酯树脂；该合成加工的有益效果表现在无需加入有毒的有机溶剂，直接反应成型，对环境友好；也表现在由于改性聚磷酸铵的加入降低了软硬段微相分离程度，同时结合聚磷酸铵优异的阻燃、耐热性能，加之纳米金属氢氧化铝的协同补强与阻燃效果，最终可以实现本发明高阻燃性车用革无溶剂聚氨酯树脂的设计。
(2)本发明中A组分引入羟基改性的聚磷酸铵作为扩链组分的一种，与B组分预聚体进一步反应，可以在聚氨酯结构中镶嵌聚磷酸铵的改性结构，通过化学改性的方法提高无溶剂聚氨酯的阻燃性。
(3)本发明将纳米氢氧化铝引入到无溶剂聚氨酯中，具有一定的补强阻燃效果，通过表面改性以后，它可以在聚氨酯中均匀分布，通过物理共混的方式提高无溶剂聚氨酯树脂的阻燃性，进一步解决车用革对于高阻燃性、高耐磨性的要求。
(4)本发明在无溶剂聚氨酯的合成基础上，通过物理和化学改性相结合的方法，利用有机原位阻燃和无机填充阻燃协同效应，很好的平衡了高含量填充带来的阻燃性能提升与物理机械性能下降这对矛盾。
附图说明
图1为含聚磷酸铵填料颗粒无溶剂合成革(a)和含表面改性氢氧化铝和羟基改性聚磷酸铵嵌段共聚无溶剂合成革(b)的SEM图；
图2为含表面改性氢氧化铝(mAl(OH)3)(a)、嵌段共聚羟基改性聚磷酸铵(HAPP)(b)和经mAl(OH)3、HAPP复合改性(c)汽车革用无溶剂聚氨酯树脂横向燃烧后的形貌图。
具体实施方式
下面结合具体实施例对本发明进行进一步描述，但本发明的保护范围并不限于此，凡是根据本发明的精神实质所作的等效变化或修饰，都应该涵盖在本发明的保护范围内。
实施例1
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000004
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)     180份
抗氧化剂                          2.5份
聚四氢呋喃醚二醇                  50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                100份
聚醚二元醇                    250份
扩链剂(1,4-丁二醇)            13份
聚醚二元醇选择天津中和盛泰化工有限公司生产的分子量1000的聚丙二醇产品。
优选的，所述的改性聚磷酸铵是由以下组分按照质量分数制备而成：
聚磷酸铵        80份
3-氨基丙醇      26份
乙醇溶液        300份
聚磷酸铵选择济南泰星化工有限公司生产的分子量1000的聚磷酸铵HT-208产品，3-氨基丙醇选择上海森旭化工科技有限公司的IPA产品。
优选的，所述的改性氢氧化铝是由以下组分按照质量分数制备而成：
氢氧化铝        100份
硬脂酸          4份
氢氧化铝粉末选择粤江新材料有限公司的目数为1000的AH-1产品，硬脂酸选择济南双萍化工的1801型产品。
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1
聚四氢呋喃醚二醇选择郑州博利安贸易有限公司生产的分子量为2000的聚四氢呋喃醚二醇产品。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例2
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000005
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例3
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000006
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                   100份
聚醚二元醇(PPG1000)              250份
扩链剂(1,4-丁二醇)               13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产 品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例4
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000007
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例5
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000008
Figure PCTCN2021084272-appb-000009
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例6
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000010
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例7
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000011
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                   100份
聚醚二元醇(PPG1000)              250份
扩链剂(1,4-丁二醇)               13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例8
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000012
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                 100份
聚醚二元醇(PPG1000)              250份
扩链剂(1,4-丁二醇)               13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例9
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000013
Figure PCTCN2021084272-appb-000014
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例10
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000015
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化 铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例11
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000016
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽 滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例12
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000017
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例13
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000018
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例14
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000019
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀， 然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例15
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000020
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃， 加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例16
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000021
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例17
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000022
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例18
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000023
Figure PCTCN2021084272-appb-000024
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例19
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000025
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例20
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000026
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例21
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000027
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                   100份
聚醚二元醇(PPG1000)              250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例22
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000028
Figure PCTCN2021084272-appb-000029
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例23
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000030
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
实施例24
一种高阻燃性汽车革用无溶剂聚氨酯树脂，由A组分和B组分按质量比为3:2～2:3混合而成，
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000031
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)                    100份
聚醚二元醇(PPG1000)               250份
扩链剂(1,4-丁二醇)                13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
其制备方法包括如下步骤：
(1)羟基改性聚磷酸铵的制备：
在氮气氛围下，先将3-氨基丙醇26份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
(2)改性氢氧化铝的制备：
将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为7％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸4份，恒温搅拌4～8h,然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
(3)组分A的制备：
将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂、金属催化剂、改性氢氧化铝粉末，恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(4)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数1:1.15充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
对比例
本发明还提供了上述高阻燃性汽车革用无溶剂聚氨酯树脂的对比例，即在实施例2方案中去掉羟基改性聚磷酸铵和改性氢氧化铝，具体如下：
由A组分和B组分按质量比为3:2～2:3混合而成；
其中A组分由以下组分按照质量分数制成：
Figure PCTCN2021084272-appb-000032
所述B组分由以下组分按照质量分数制成：
二异氰酸酯(碳化二亚胺改性MDI)       180份
抗氧化剂                            2.5份
聚四氢呋喃醚二醇(PTMEG2000)         50份
所述A组分中异氰酸酯改性的二元醇由以下组分按照质量分数组成：
异氰酸酯(IPDI)          100份
聚醚二元醇(PPG1000)     250份
扩链剂(乙二醇)          13份
优选的，所述的小分子扩链剂为1,4-丁二醇、一缩二丙二醇按2:1混合而成。
优选的，所述的胺类催化剂选择美国陶氏公司的低气味N,N-双(二甲氨基丙基)异丙醇胺产品。
优选的，所述金属催化剂为延迟类有机催化剂，选择嘉兴禾欣化工有限公司生产的BICAT 8108产品。
优选的，抗氧化剂选择德国YOUNGING集团的抗氧剂264和抗氧剂1076产品，配比为3:1。
制备合成革用无溶剂聚氨酯树脂，该制备方法包括以下步骤：
(1)组分A的制备：
将异氰酸酯改性的二元醇、1,4-丁二醇投入反应釜中，升温至85℃，搅拌3h，检测水分含量在5000-9000ppm之间，然后降温至50℃投入胺类催化剂、流平剂，金属催化剂恒温搅拌1.5h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
(2)组分B的制备：
先通过将反应釜通氮气来除掉釜内的水份，再将碳化二亚胺改性MDI和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇2000升温至80℃，恒温搅拌3h，至-NCO基团检测值含量m以重量百分比控制在8％<m<10％后即可得到组分B，密封包装待用。
(3)无溶剂聚氨酯树脂的制备：
将经低压浇注机中按质量分数3:2～2:3充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得无溶剂聚氨酯树脂。
为了更好地体现本发明专利的有益性，下面对本发明实施例1～24得到的高阻燃性汽车革用无溶剂聚氨酯树脂以及对比例得到的无溶剂聚氨酯树脂进行性能测试，测试结果描述如下：
Figure PCTCN2021084272-appb-000033
Figure PCTCN2021084272-appb-000034
注：手感软硬度通过软硬度仪检测，数值越高，手感越软；极限氧指数通过氧指数测试仪进行测试，氧指数高表示材料不易燃烧；氧指数低表示材料容易燃烧。一般认为氧指数＜22％属于易燃材料，氧指数在22％～27％之间属可燃材料，氧指数＞27％属难燃材料。
由上表的数据可知，采用本发明的高阻燃性无溶剂聚氨酯树脂加工得到的合成革，其手感略优于对比例，剥离强度有所降低，但阻燃性能却有着很大的提升。说明了该技术能够在不改变原有无溶剂合成革性能的前提下，大幅改善合成革的阻燃性能。并且该技术能够运用于对阻燃性能要求比较高的车用革领域。
以上仅是本发明的优选实施方式，应当指出的是，上述优选实施方式不应视为对本发明的限制，本发明的保护范围应当以权利要求所限定的范围为准。对于本技术领域的普通技术人员来说，在不脱离本发明的精神和范围内，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。

Claims (9)

  1. 一种高阻燃性汽车革用无溶剂聚氨酯树脂，其特征在于，由A组分和B组分按质量比为2∶3～3∶2经低压浇注机高速搅拌混合后涂覆于离型纸上，然后在110～130℃下高温烘干从而制备而成，其中A组分按照以下质量份数组成：
    Figure PCTCN2021084272-appb-100001
    其中羟基改性聚磷酸铵的结构式为：
    Figure PCTCN2021084272-appb-100002
    所述B组分按照以下质量分数组成：
    二异氰酸酯             150～250份
    抗氧化剂               2～3份
    聚四氢呋喃醚二醇       30～60份
  2. 根据权利要求1所述的高阻燃性汽车革用无溶剂聚氨酯树脂，其特征在于：所述异氰酸酯改性的二元醇是由以下组分按照质量分数混合而成：
    Figure PCTCN2021084272-appb-100003
    所述异氰酸酯为IPDI、HDI、碳化二亚胺改性MDI中的任意一种或几种的混合物；所述聚醚二元醇为分子量1000、1500、2000、2500的聚乙二醇、聚丙二醇中的一种或任意几种，所述扩链剂为乙二醇、1，3-丙二醇、1，4-丁二醇中的一种或任意几种；所述催化剂为辛酸亚锡、二月桂酸二丁基锡中的一种。
  3. 根据权利要求1所述的高阻燃性汽车革用无溶剂聚氨酯树脂，其特征在于：所述的羟基改性聚磷酸铵是由以下组分按照质量分数制备而成：
    聚磷酸铵            80份
    3-氨基丙醇          20～30份
    所述聚磷酸铵分子量为1000～2500。
  4. 根据权利要求1所述的高阻燃性汽车革用无溶剂聚氨酯树脂，其特征在于：所述的改性氢氧化铝是由以下组分按照质量分数制备而成：
    氢氧化铝               100份
    硬脂酸                2～5份
    所述氢氧化铝为目数1000～1500的氢氧化铝粉末。
  5. 根据权利要求1所述的高阻燃性汽车革用无溶剂聚氨酯树脂，其特征在于：所述的小分子扩链剂选自乙二醇、1，3-丙二醇、1，4-丁二醇、2-甲基丙二醇和一缩二丙二醇中的任意一种或几种的混合物。
  6. 根据权利要求1所述的高阻燃性汽车革用无溶剂聚氨酯树脂，其特征在于：所述的胺类催化剂为三乙烯二胺、N，N-双(二甲氨基丙基)异丙醇胺、N-(二甲氨丙基)二异丙醇胺中的任意一种；所述的金属催化剂为有机锡、有机铋中的任意一种或几种的混合物。
  7. 根据权利要求1所述的高阻燃性汽车革用无溶剂聚氨酯树脂，其特征在于：所述异氰酸酯为MDI、TDI、MDI-50、HDI-100、二环己基甲烷二异氰酸酯中的任意一种或几种的混合物；所述的抗氧剂选自抗氧剂264、抗氧剂1076和亚磷酸三苯酯中任意一种或几种的混合物。
  8. 根据权利要求1所述的高阻燃性汽车革用无溶剂聚氨酯树脂，其特征在于：所述的聚四氢呋喃二元醇选自PTMEG-1000、PTMEG-1500、PTMEG-2000和PTMEG-3000中的任意一种或几种的混合物。
  9. 根据权利要求1～8中任意一项所述的高阻燃性汽车革用无溶剂聚氨酯树脂，其特征在于：包括如下步骤：(1)羟基改性聚磷酸铵的制备：
    在氮气氛围下，先将3-氨基丙醇20～30份倒入进乙二醇溶液中缓慢搅拌均匀，然后将聚磷酸铵80份加入其中，逐渐升温到80℃，通过冷凝回流装置处理2～3h；冷却到室温以后，产物经过滤、乙而醇水洗、干燥、抽滤等操作即可得到羟基改性的聚磷酸铵。
    (2)改性氢氧化铝的制备：
    将氢氧化铝纳米粉末100份与去离子水混合配制成浓度为5％～8％的浆料倒入反应釜中，控制温度为40～80℃，加入乙二醇稀释的硬脂酸2～5份，恒温搅拌4～8h，然后进行抽滤，过滤后在100～120℃条件下烘干，过1000目筛板，即可制得改性氢氧化铝。
    (2)组分A的制备：
    将异氰酸酯改性的二元醇、小分子扩链剂和羟基改性聚磷酸铵投入反应釜中，升温至65-85℃，搅拌3-5h，检测水分含量在5000-9000ppm之间，然后降温至40℃投入胺类催化剂、金属催化剂和改性氢氧化铝，恒温搅拌1.5～2h，再次检测羟值和水分含量，合格后即可得到A组分，密封包装待用。
    (3)组分B的制备：
    先通过将反应釜通氮气来除掉釜内的水份，再将液态的二异氰酸酯和抗氧剂投入到反应釜中并搅拌均匀，然后投入脱水后的聚四氢呋喃醚二醇升温至80℃-85℃，恒温搅拌3-6h，至-NCO基团检测值含量m以重量百分比控制在8％＜m＜10％合格后即可得到组分B，密封包装待用。
    (4)高阻燃性汽车革用无溶剂聚氨酯树脂的制备：
    将经低压浇注机中按质量分数2∶3-3∶2充分混合的无溶剂A、B组分浇注涂覆于离型纸上，在110-130℃烘箱中烘干即可制得高阻燃性汽车革用无溶剂聚氨酯树脂。
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115181230A (zh) * 2022-08-19 2022-10-14 盛鼎高新材料有限公司 一种嵌段共聚聚氨酯弹性体的制备方法

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113956427B (zh) * 2021-10-22 2023-06-23 东莞市米儿塑胶原料有限公司 永久型抗静电tpu的制备方法
CN114790277A (zh) * 2022-05-16 2022-07-26 浙江禾欣新材料有限公司 一种新能源汽车专用阻燃聚氨酯复合材料及其制备方法
CN115354505B (zh) * 2022-08-22 2024-03-08 浙江理工大学绍兴柯桥研究院有限公司 一种合成革用生物基无溶剂聚氨酯面层树脂及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070129456A1 (en) * 2005-12-07 2007-06-07 Baiksan Co., Ltd. Solvent-less polyurethane foam with micro pores and method of fabricating synthetic leather therefrom
CN104088161A (zh) * 2014-07-07 2014-10-08 旭川化学（苏州）有限公司 一种无溶剂环保聚氨酯汽车革的制备方法
CN110669198A (zh) * 2019-10-15 2020-01-10 浙江禾欣科技有限公司 一种poss基汽车革用无溶剂聚氨酯树脂及其制备方法
CN110746572A (zh) * 2019-10-15 2020-02-04 浙江禾欣科技有限公司 一种双重固化型汽车内饰革用无溶剂聚氨酯树脂及其制备方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106220817B (zh) * 2016-08-09 2018-11-23 合肥安利聚氨酯新材料有限公司 一种无溶剂型汽车内饰革用中间层聚氨酯树脂及其制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070129456A1 (en) * 2005-12-07 2007-06-07 Baiksan Co., Ltd. Solvent-less polyurethane foam with micro pores and method of fabricating synthetic leather therefrom
CN104088161A (zh) * 2014-07-07 2014-10-08 旭川化学（苏州）有限公司 一种无溶剂环保聚氨酯汽车革的制备方法
CN110669198A (zh) * 2019-10-15 2020-01-10 浙江禾欣科技有限公司 一种poss基汽车革用无溶剂聚氨酯树脂及其制备方法
CN110746572A (zh) * 2019-10-15 2020-02-04 浙江禾欣科技有限公司 一种双重固化型汽车内饰革用无溶剂聚氨酯树脂及其制备方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
LIU LIHUA, LI BINGHUAN, JIA JUNFANG, QI SHUANGHUA: "Experiment research on flame retardant of aluminium trihydrate modified by stearic acid", CHEMICAL TECHNOLOGY MARKET, vol. 31, no. 12, 1 December 2008 (2008-12-01), pages 27 - 29, XP055949595, ISSN: 1009-4725 *
YANG LIU, YE ZHI-BIN;AI LIANG-HUI;ZENG LI-JUAN;LIU PING: "Synergistic Flame Retardant Eff ect of Ammonium Polyphosphate and Aluminum Hydroxide on Polyurethane", SYNTHETIC MATERIALS AGING AND APPLICATION, GUANGZHOU SYNTHETIC MATERIALS RESEARCH INSTITUTE CO., LTD., CN, vol. 49, no. 5, 1 May 2020 (2020-05-01), CN , pages 1 - 5, XP055949592, ISSN: 1671-5381, DOI: 10.16584/j.cnki.issn1671-5381.2020.05.001 *
ZHANG PEIKUN, FAN HAOJUN, HU KUN, GU YIMING, CHEN YI, YAN JUN, TIAN SAIQI, HE YAZHOU: "Solvent-free two-component polyurethane conjugated with crosslinkable hydroxyl-functionalized ammonium polyphosphate: Curing behaviors, flammability and mechanical properties", PROCESS IN ORGANIC COATINGS, ELSEVIER BV, NL, vol. 120, 1 July 2018 (2018-07-01), NL , pages 88 - 99, XP055949589, ISSN: 0300-9440, DOI: 10.1016/j.porgcoat.2018.01.019 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115181230A (zh) * 2022-08-19 2022-10-14 盛鼎高新材料有限公司 一种嵌段共聚聚氨酯弹性体的制备方法
CN115181230B (zh) * 2022-08-19 2023-10-31 盛鼎高新材料有限公司 一种嵌段共聚聚氨酯弹性体的制备方法

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