WO2022138747A1 - 回路接続用接着剤フィルム、並びに、回路接続構造体及びその製造方法 - Google Patents

回路接続用接着剤フィルム、並びに、回路接続構造体及びその製造方法 Download PDF

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Publication number
WO2022138747A1
WO2022138747A1 PCT/JP2021/047653 JP2021047653W WO2022138747A1 WO 2022138747 A1 WO2022138747 A1 WO 2022138747A1 JP 2021047653 W JP2021047653 W JP 2021047653W WO 2022138747 A1 WO2022138747 A1 WO 2022138747A1
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WIPO (PCT)
Prior art keywords
adhesive layer
circuit connection
electrode
component
adhesive
Prior art date
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Ceased
Application number
PCT/JP2021/047653
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English (en)
French (fr)
Japanese (ja)
Inventor
智陽 山崎
剛幸 市村
亮太 小林
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Resonac Corp
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Showa Denko Materials Co Ltd
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Publication date
Application filed by Showa Denko Materials Co Ltd filed Critical Showa Denko Materials Co Ltd
Priority to CN202180084529.4A priority Critical patent/CN116601250A/zh
Priority to JP2022571571A priority patent/JPWO2022138747A1/ja
Priority to KR1020237023899A priority patent/KR20230125230A/ko
Publication of WO2022138747A1 publication Critical patent/WO2022138747A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/35—Heat-activated
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
    • C09J9/02—Electrically-conducting adhesives
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00—Apparatus or processes for manufacturing printed circuits
    • H05K3/30—Assembling printed circuits with electric components, e.g. with resistors
    • H05K3/32—Assembling printed circuits with electric components, e.g. with resistors electrically connecting electric components or wires to printed circuits
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00—Apparatus or processes for manufacturing printed circuits
    • H05K3/36—Assembling printed circuits with other printed circuits
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/001—Conductive additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/326—Applications of adhesives in processes or use of adhesives in the form of films or foils for bonding electronic components such as wafers, chips or semiconductors
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/20—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself
    • C09J2301/208—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself the adhesive layer being constituted by at least two or more adjacent or superposed adhesive layers, e.g. multilayer adhesive

Definitions

  • the present invention relates to an adhesive film for circuit connection, a circuit connection structure, and a method for manufacturing the same.
  • an adhesive material for, for example, a connection between a liquid crystal display and a tape carrier package (TCP), a connection between a flexible printed wiring board (FPC) and TCP, or a connection between an FPC and a printed wiring board
  • the conductive material is contained in an adhesive.
  • a circuit connection adhesive film in which particles are dispersed for example, a circuit connection adhesive film having idirectional conductivity
  • COG chip-on-glass
  • An adhesive film for example, an adhesive film for circuit connection having anisotropic conductivity
  • anisotropic conductivity means that it conducts in the pressurized direction and maintains the insulating property in the non-pressurized direction.
  • connection structure in which the distance between the connection electrodes is, for example, 15 ⁇ m or less is required, and the bump electrode of the connection member has also been reduced in area.
  • the bump electrode of the connection member In order to obtain a stable electrical connection in a bump connection with a small area, it is necessary that a sufficient number of conductive particles are interposed between the bump electrode and the circuit electrode on the substrate side.
  • Patent Document 1 proposes a two-layer adhesive film in which an adhesive layer (conductive particle layer) in which conductive particles are dispersed and a layer containing only an adhesive (adhesive layer) are laminated.
  • the adhesive component of the circuit connection adhesive film located between the opposing electrodes is extruded and extruded during thermocompression bonding at the time of manufacturing the circuit connection structure.
  • Conductive particles may flow depending on the agent component. As a result, conductive particles may aggregate between adjacent electrodes, causing a short circuit.
  • the present inventors suppressed the flow of the conductive particles at the time of circuit connection (during thermal pressure bonding) by pre-curing the adhesive in the region where the conductive particles are unevenly distributed, and conducted conductivity.
  • one object of the present invention is to manufacture a circuit connection structure in which the connection resistance between the opposing electrodes is sufficiently low while suppressing the occurrence of a short circuit due to the aggregation of conductive particles.
  • the present inventors have heat-bonded the resin cured layer formed by curing the adhesive layer containing the conductive particles so as to have a structure in which the resin cured layer is bent convexly between adjacent electrodes of the circuit connection structure (for the electrode connection portion). If this can be done, the adhesive component located between the facing electrodes will be reduced in the process of bending, and the connection resistance can be reduced while keeping the conductive particles between the adjacent electrodes separated from each other. I got the idea of not having it.
  • the present inventors have conducted studies based on such an idea, and by setting the flow rate of the adhesive layer containing conductive particles within a specific range, it is possible to form a resin cured layer having the above-mentioned convexly bent structure. And completed the present invention.
  • one aspect of the present invention relates to a method for manufacturing a circuit connection structure shown below.
  • a first adhesive layer containing conductive particles and a second adhesive layer provided on the first adhesive layer are provided, and the procedure (A1) to (A4) below is provided.
  • a step of preparing an adhesive film for circuit connection in which the flow rate of the first adhesive layer to be measured is 130 to 250%, and a first circuit member having a first electrode and a second electrode.
  • the circuit connection adhesive film is interposed between the first circuit member and the second circuit member so that the adhesive layer 2 is on the second circuit member side.
  • the first electrode and the second electrode are electrically attached to each other via the conductive particles in the thermal crimping step.
  • the first adhesive layer is bent so as to be connected to form an electrode connecting portion and to be convex toward the first circuit member side or the second circuit member side between adjacent electrode connecting portions.
  • a method for manufacturing a circuit connection structure which cures the circuit connection adhesive film. (A1) The circuit connection adhesive film is punched out in the thickness direction with the base material attached on both main surfaces of the circuit connection adhesive film, and the diameter R (unit: mm) is 0.
  • a disk-shaped evaluation adhesive film having a diameter of 1 to 1 mm is obtained.
  • the evaluation adhesive film After peeling the base material on the first adhesive layer side from the evaluation adhesive film, the evaluation adhesive film is attached to a glass having a thickness of 0.15 mm from the first adhesive layer side. It is placed on a plate and thermocompression-bonded under the conditions of a crimping temperature of 60 ° C., a crimping pressure of 1 MPa, and a crimping time of 0.1 s to obtain a temporary fixed body.
  • A3 After peeling the base material from the temporary fixing body, a glass plate having a thickness of 0.15 mm is placed on the second adhesive layer under the conditions of a crimping temperature of 170 ° C., a crimping pressure of 80 MPa, and a crimping time of 5 s.
  • Thermocompression bonding is performed to obtain a pressure-bonded body.
  • thermosetting component contains a (meth) acrylate compound as a thermosetting compound.
  • thermosetting component contains an organic peroxide as a curing agent for the thermosetting compound.
  • thermosetting component contains an epoxy compound or an oxetane compound as the thermosetting compound.
  • thermosetting component contains a sulfonium salt or an ammonium salt as a curing agent for the thermosetting compound.
  • the flow rate of the first adhesive layer is 250% or less, it is difficult for conductive particles to flow during thermocompression bonding, and the first adhesive layer after thermocompression bonding is difficult to occur.
  • the film shape is easy to maintain. Therefore, according to the method for manufacturing the circuit connection structure on the side surface, the occurrence of a short circuit due to aggregation of conductive particles is suppressed. Further, in the method for manufacturing the circuit connection structure on the side surface, since the flow rate of the first adhesive layer is 130% or more, the first adhesive layer is bent at the time of thermocompression bonding. Then, the bending causes the first adhesive layer to be stretched to reduce the adhesive component between the facing electrodes. Therefore, according to the method for manufacturing the circuit connection structure on the side surface, it is possible to manufacture a circuit connection structure in which the connection resistance between the opposing electrodes is sufficiently low.
  • Another aspect of the present invention relates to the following circuit connection adhesive film.
  • a first adhesive layer containing conductive particles and a second adhesive layer provided on the first adhesive layer are provided, and the procedure (A1) to (A4) below is provided.
  • An adhesive film for circuit connection wherein the flow ratio of the first adhesive layer to be measured is 130 to 250%.
  • the circuit connection adhesive film is punched out in the thickness direction with the base material attached on both main surfaces of the circuit connection adhesive film, and the diameter R (unit: mm) is 0.
  • a disk-shaped evaluation adhesive film having a diameter of 1 to 1 mm is obtained.
  • A2 After peeling the base material on the first adhesive layer side from the evaluation adhesive film, the evaluation adhesive film is attached to a glass having a thickness of 0.15 mm from the first adhesive layer side.
  • a glass plate having a thickness of 0.15 mm is placed on the second adhesive layer under the conditions of a crimping temperature of 170 ° C., a crimping pressure of 80 MPa, and a crimping time of 5 s. Thermocompression bonding is performed to obtain a pressure-bonded body.
  • a circuit connection adhesive film comprising a first adhesive layer containing conductive particles and a second adhesive layer provided on the first adhesive layer.
  • the first electrode of the first circuit member having the electrode of the above and the second electrode of the second circuit member having the second electrode are electrically connected to each other via the conductive particles.
  • the electrode connecting portion is formed, and the first adhesive layer is bent so as to be convex toward the first circuit member side or the second circuit member side between adjacent electrode connecting portions.
  • circuit connection adhesive film on the side surface it is possible to suppress the occurrence of a short circuit due to aggregation of conductive particles. Further, it is possible to manufacture a circuit connection structure in which the connection resistance between the facing electrodes is sufficiently low.
  • Another aspect of the present invention relates to the circuit connection structure shown below.
  • the electrode and the second electrode are electrically connected to each other via conductive particles, and a circuit connection portion for adhering a first circuit member and a second circuit member is provided, and the circuit connection portion is conductive.
  • the first resin cured layer includes a first resin cured layer containing particles and a second resin cured layer located on the side opposite to the first circuit member side of the first resin cured layer.
  • a plurality of electrode connecting portions for electrically connecting the first electrode and the second electrode to each other by conductive particles interposed between the first electrode and the second electrode are included, and between the adjacent electrode connecting portions.
  • a circuit connection structure that is bent so as to be convex toward the first circuit member side or the second circuit member side.
  • the circuit connection structure on the side surface can be manufactured by using the adhesive film for circuit connection on the side surface, and the structure of the first resin cured layer (adjacent to each other) characteristic of the circuit connection structure on the side surface.
  • a structure that is bent so as to be convex toward the first circuit member side or the second circuit member side between the electrode connection portions) is a novel structure that cannot be obtained when a conventional circuit connection adhesive film is used. Structure.
  • connection resistance between the facing electrodes is sufficiently low while suppressing the occurrence of a short circuit due to the aggregation of conductive particles.
  • FIG. 1 is a schematic cross-sectional view showing an adhesive film for circuit connection according to an embodiment.
  • FIG. 2 is a schematic cross-sectional view showing a main part of the adhesive film for circuit connection shown in FIG.
  • FIG. 3 is a schematic cross-sectional view showing an adhesive film for circuit connection according to another embodiment.
  • FIG. 4 is a schematic cross-sectional view showing a circuit connection structure of one embodiment.
  • FIG. 5 is a schematic cross-sectional view showing a manufacturing process of the circuit connection structure of one embodiment.
  • FIG. 6 is a schematic cross-sectional view showing a circuit connection structure of another embodiment.
  • FIG. 7 is an SEM (scanning electron microscope) photograph showing a cross-sectional structure of the circuit connection structure of the embodiment.
  • (meth) acrylate means at least one of acrylate and the corresponding methacrylate.
  • a or B may include either A or B, and may include both.
  • normal temperature means 25 ° C.
  • each component in the composition means the total amount of the plurality of substances present in the composition when a plurality of substances corresponding to each component are present in the composition, unless otherwise specified.
  • the numerical range indicated by using "-" indicates a range including the numerical values before and after "-" as the minimum value and the maximum value, respectively.
  • the upper limit value or the lower limit value of the numerical range of one step may be replaced with the upper limit value or the lower limit value of the numerical range of another step.
  • the upper limit value or the lower limit value of the numerical range may be replaced with the value shown in the examples.
  • the upper limit value and the lower limit value described individually can be arbitrarily combined.
  • One aspect of this embodiment is an adhesive film for circuit connection. Further, one aspect of the present embodiment is a circuit connection structure. Further, one aspect of the present embodiment is a method of manufacturing a circuit connection structure. Further, one aspect of this embodiment is the application of an adhesive film or a cured product thereof to a circuit connection. Further, one aspect of the present embodiment is the application of an adhesive film or a cured product thereof to a circuit connection structure or its manufacture.
  • the circuit connection film of one embodiment includes a first adhesive layer containing conductive particles and a second adhesive layer provided on the first adhesive layer, and includes the following (A1) to A circuit connection adhesive film having a flow rate of the first adhesive layer measured in the procedure (A4) of 130 to 250%.
  • A1 The circuit connection adhesive film is punched out in the thickness direction with the base material attached on both main surfaces of the circuit connection adhesive film, and the diameter R (unit: mm) is 0.1.
  • a disk-shaped evaluation adhesive film having a diameter of about 1 mm is obtained.
  • A2 After peeling the base material on the first adhesive layer side from the evaluation adhesive film, the evaluation adhesive film is placed on a glass plate having a thickness of 0.15 mm from the first adhesive layer side.
  • Thermocompression bonding is performed under the conditions of a crimping temperature of 60 ° C., a crimping pressure of 1 MPa, and a crimping time of 0.1 s to obtain a temporary fixed body.
  • A3 After peeling the base material from the temporary fixing body, a glass plate having a thickness of 0.15 mm is placed on the second adhesive layer, and thermocompression bonding is performed under the conditions of a pressure bonding temperature of 170 ° C., a pressure bonding pressure of 80 MPa, and a pressure bonding time of 5 s. And obtain a crimped body.
  • the circuit connection film of another embodiment includes a first adhesive layer containing conductive particles and a second adhesive layer provided on the first adhesive layer, and the first.
  • the first electrode of the first circuit member having an electrode and the second electrode of the second circuit member having a second electrode are electrically connected to each other via conductive particles to connect the electrodes.
  • a circuit connection adhesive film is formed by forming a portion and bending the first adhesive layer so as to be convex toward the first circuit member side or the second circuit member side between adjacent electrode connection portions.
  • An adhesive film for circuit connection that is cured to form a circuit connection structure.
  • the circuit connection film of this embodiment may be the circuit connection adhesive film of the above embodiment.
  • FIG. 1 is a diagram schematically showing a vertical cross section of an adhesive film for circuit connection (hereinafter, also simply referred to as “adhesive film”) of one embodiment.
  • the adhesive film 1a shown in FIG. 1 includes a first adhesive layer 2 containing conductive particles 4 and an adhesive component 5, and a second adhesive layer 3 provided on the first adhesive layer 2.
  • the conductive particles 4 are present in the vertical cross section of the adhesive film 1a so as to be arranged in the horizontal direction (left-right direction in FIG. 1) with adjacent conductive particles separated from each other.
  • the "longitudinal cross section” means a cross section (cross section in the stacking direction) substantially orthogonal to the main surface (for example, the main surface of the adhesive film 1a).
  • the adhesive film 1a is an adhesive film for circuit connection.
  • for circuit connection means that it is used for connecting circuit members.
  • the adhesive film 1a is interposed between, for example, a first circuit member having a first electrode and a second circuit member having a second electrode, and is interposed between the first circuit member and the second circuit member. Is hot-bonded to be used to electrically connect the first electrode and the second electrode to each other via conductive particles.
  • the adhesive film 1a may or may not have anisotropic conductivity. That is, the adhesive film 1a may be an anisotropically conductive adhesive film or a non-anisotropically conductive (for example, isotropically conductive) adhesive film.
  • FIG. 2 is an enlarged view of a main part of the adhesive film 1a shown in FIG.
  • the adhesive film 1a includes a region (existing region) R1 in which the conductive particles 4 are present and R2 in which the conductive particles 4 are not present (absent region) when the vertical cross section thereof is viewed.
  • the first adhesive layer 2 is configured so that the first adhesive component 5, the conductive particles 4, and the first adhesive component 5 are arranged in this order in the stacking direction.
  • a second adhesive layer 3 is laminated on the adhesive layer 3. That is, the first adhesive component 5 is present between the surface 2a of the first adhesive layer 2 opposite to the second adhesive layer 3 and the conductive particles 4, and the conductive particles.
  • the first adhesive component 5 is also present on the surface of the fourth adhesive layer 3 on the side of the second adhesive layer 3 so as to cover the surface.
  • the shortest distance D from the surface 2a of the first adhesive layer 2 opposite to the second adhesive layer 3 to the surface of the conductive particles 4 suppresses an increase in connection resistance in a high temperature and high humidity environment, and makes a circuit connection. From the viewpoint of suppressing the flow of conductive particles at the time (during thermocompression bonding), it may be more than 0 ⁇ m and not more than 1 ⁇ m. From the same viewpoint, the shortest distance D may be 0.1 ⁇ m or more, 0.2 ⁇ m or more, or 0.8 ⁇ m or less.
  • the shortest distance d11 from the interface S of the first adhesive layer 2 and the second adhesive layer 3 to the surface of the conductive particles 4 may be, for example, 0.1 ⁇ m or more, 3.0 ⁇ m or less, 2.0 ⁇ m or less. It may be less than or equal to or less than 1.0 ⁇ m.
  • the first adhesive component 5 may not be present on the surface of the conductive particles 4 on the second adhesive layer 3 side. That is, it can be said that the shortest distance d11 may be 0 ⁇ m or more.
  • the shortest distance d21 from the interface S of the first adhesive layer 2 and the second adhesive layer 3 to the surface 3a of the second adhesive layer 3 opposite to the first adhesive layer 2 in the existing region R1. May be, for example, 3.0 ⁇ m or more, 5.0 ⁇ m or more, or 10.0 ⁇ m or more, and may be 50 ⁇ m or less.
  • the first adhesive component 5 exists so as to cover the surface of the conductive particles 4 (including the surface on the second adhesive layer 3 side), the first adhesive layer 2 and The interface S of the second adhesive layer 3 has a curved surface that follows the surface shape of the conductive particles 4 in the vicinity of the conductive particles 4 in the non-existent region R2, and the first is as the distance from the conductive particles 4 increases.
  • the surface 2a on the opposite side of the adhesive layer 2 from the second adhesive layer 3 and the surface 3a on the opposite side to the first adhesive layer 2 of the second adhesive layer 3 are substantially parallel to each other. Become.
  • the thickness of the first adhesive layer 2 is the thickest in the vicinity of the conductive particles 4, and becomes thinner as the distance from the conductive particles 4 increases.
  • the thickness of the second adhesive layer 3 is the thinnest in the vicinity of the conductive particles 4, and becomes thicker as the distance from the conductive particles 4 increases.
  • the thickness of the first adhesive layer 2 and the thickness of the second adhesive layer 3 are the thickness of the first adhesive layer 2 in the absent region R2 in which the conductive particles 4 do not exist and the thickness of the second adhesive layer 3. Each is defined as the thickness of the second adhesive layer 3. Further, a preferable range of the thickness of the first adhesive layer 2 and the thickness of the second adhesive layer 3 will be described below, but the following describes the first adhesion at an arbitrary position of the absent region R2.
  • the thickness of the agent layer 2 (for example, both the thickness d12 in the vicinity of the conductive particles 4 and the thickness d13 at a position away from the conductive particles 4) and the thickness of the second adhesive layer 3 (for example, in the vicinity of the conductive particles 4). It means that the thickness d22 and the thickness d23 at a position away from the thickness d22) may be within the range shown below.
  • the thickness of the first adhesive layer 2 is smaller than the average particle size of the conductive particles 4. Specifically, the thickness of the first adhesive layer 2 makes it easier for the conductive particles 4 to be captured between the electrodes facing each other, and from the viewpoint of further reducing the connection resistance, the average particle size of the conductive particles 4 is 0. It may be 6 times or more, 0.7 times or more, or 0.8 times or more. The thickness of the first adhesive layer 2 is such that when the conductive particles are sandwiched between the electrodes facing each other during thermal pressure bonding, the conductive particles are more easily crushed and the connection resistance can be further reduced. It may be less than 1.0 times, 0.9 times or less, or 0.8 times or less the average particle size. From these viewpoints, the thickness of the first adhesive layer 2 is 0.6 times or more and less than 1.0 times, 0.7 to 0.9 times, 0.7 to 0 times the average particle size of the conductive particles 4. It may be 0.8 times or 0.8 to 0.9 times.
  • the ratio of the thickness of the second adhesive layer 3 to the total thickness of the first adhesive layer 2 and the second adhesive layer 3 may be less than 96% from the viewpoint of suppressing the flow of the conductive particles 4 at the time of circuit connection (during thermal pressure bonding).
  • the above ratio may be 94% or less, 93% or less, 88% or less, or 86% or less from the viewpoint of further suppressing the flow of the conductive particles 4 at the time of circuit connection (thermocompression bonding).
  • the above ratio may be, for example, 75% or more, 78% or more, or 80% or more.
  • the thickness of the first adhesive layer 2 may be, for example, 1.0 ⁇ m or more, 2.0 ⁇ m or more, or 3.0 ⁇ m or more from the viewpoint of being able to capture conductive particles more efficiently. It may be 0 ⁇ m or less, 5.0 ⁇ m or less, or 4.0 ⁇ m or less, and may be 1.0 to 6.0 ⁇ m, 2.0 to 5.0 ⁇ m, or 3.0 to 4.0 ⁇ m.
  • the thickness of the second adhesive layer 3 is 5.0 ⁇ m or more and 8.0 ⁇ m from the viewpoint that the space between the electrodes can be sufficiently filled to seal the electrodes and better reliability can be obtained. It may be 15.0 ⁇ m or more or 10.0 ⁇ m or more, 15.0 ⁇ m or less, 13.0 ⁇ m or less, 12.0 ⁇ m or less, 11.0 ⁇ m or less, or 8.0 ⁇ m or less, 5.0 to 15.0 ⁇ m, 8. It may be 0 to 13.0 ⁇ m, 10.0 to 11.0 ⁇ m, 6.0 to 8.0 ⁇ m, 9.0 to 11.0 ⁇ m or 10.0 to 12.0 ⁇ m.
  • the total thickness of the first adhesive layer 2 and the second adhesive layer 3 is, for example, 6.0 ⁇ m or more, 8.0 ⁇ m or more, 10.0 ⁇ m or more, and 12.0 ⁇ m. It may be more than or equal to 14.0 ⁇ m, and may be 18.0 ⁇ m or less, 16.0 ⁇ m or less, 14.0 ⁇ m or less, or 10.0 ⁇ m or less, 6.0 to 18.0 ⁇ m, 8.0 to 16.0 ⁇ m. It may be 10.0 to 14.0 ⁇ m, 8.0 to 10.0 ⁇ m, 12.0 to 14.0 ⁇ m or 14.0 to 16.0 ⁇ m.
  • the thickness of the first adhesive layer 2 and the thickness of the second adhesive layer 3 described above are, for example, a bisphenol A type epoxy resin obtained by sandwiching an adhesive film between two sheets of glass (thickness: about 1 mm).
  • a resin composition consisting of 100 g (trade name: JER811, manufactured by Mitsubishi Chemical Co., Ltd.) and 10 g of a curing agent (trade name: Epomount curing agent, manufactured by Refine Tech Co., Ltd.) is cast and then cross-sectionald using a polishing machine. It can be obtained by polishing and measuring using a scanning electron microscope (SEM, trade name: SU-8000, manufactured by Hitachi High-Tech Science Co., Ltd.).
  • the first adhesive layer 2 has a flow rate of 130 to 250%.
  • the flow rate is an index indicating the fluidity (flow) at the time of thermocompression bonding, and specifically, it is measured by the following methods (A1) to (A4).
  • A1 The adhesive film 1a is punched in the thickness direction with the base material attached on both main surfaces of the adhesive film 1a, and a circle having a diameter R (unit: mm) of 0.1 to 1 mm. Obtain a plate-shaped evaluation adhesive film.
  • A2 After peeling the base material on the first adhesive layer side from the evaluation adhesive film, the evaluation adhesive film is applied from the first adhesive layer side to a glass plate having a thickness of 0.15 mm (first).
  • a glass plate (second glass plate) having a thickness of 0.15 mm is placed on the second adhesive layer, and the pressure bonding temperature is 170 ° C., the pressure bonding pressure is 80 MPa, and the pressure bonding is performed. Thermocompression bonding is performed under the condition of time 5s to obtain a pressure-bonded body.
  • an evaluation adhesive film having a diameter R (unit: mm) of 0.1 to 1 mm is obtained.
  • the diameter R (unit: mm) may be 1 mm, and when the width of the adhesive film 1a is less than 1 mm, the adhesive film 1a
  • the diameter R may be adjusted according to the width.
  • the above steps do not prevent the adhesive film 1a from having a disk shape of 0.1 to 1 mm.
  • the details of the evaluation method are shown in Examples.
  • the second adhesive layer 3 may have a minimum melt viscosity of, for example, 200 to 4000 Pa ⁇ s.
  • the minimum melt viscosity of the second adhesive layer 3 may be less than 200 Pa ⁇ s, but when the minimum melt viscosity of the second adhesive layer 3 is 200 Pa ⁇ s or more, the flow of conductive particles due to resin flow. Is suppressed, and conductive particles tend to be easily captured between the electrodes.
  • the minimum melt viscosity of the second adhesive layer 3 may be larger than 4000 Pa ⁇ s, but when the minimum melt viscosity of the second adhesive layer 3 is 4000 Pa ⁇ s or less, better resin exclusion property is obtained. And the connection resistance tends to be lower.
  • the minimum melt viscosity of the second adhesive layer 3 may be 500 Pa ⁇ s or more or 800 Pa ⁇ s or more, 3000 Pa ⁇ s or less, 2500 Pa ⁇ s or less, 2000 Pa ⁇ s or less, or 1500 Pa ⁇ s. It may be less than or equal to 500 to 2500 Pa ⁇ s or 800 to 1500 Pa ⁇ s.
  • the minimum melt viscosity of the second adhesive layer 3 can be measured by the method described in Examples.
  • the temperature at which the minimum melt viscosity of the second adhesive layer 3 is reached may be, for example, 50 to 100 ° C.
  • the minimum melt viscosity reaching temperature of the second adhesive layer 3 may be less than 50 ° C., but when the minimum melt viscosity reaching temperature of the second adhesive layer 3 is 50 ° C. or higher, the storage stability of the film is stable. Also tends to be improved, and hardening during temporary crimping tends to be suppressed.
  • the temperature at which the minimum melt viscosity of the second adhesive layer 3 is reached may be higher than 100 ° C., but when the temperature at which the minimum melt viscosity of the second adhesive layer 3 is reached is 100 ° C. or lower, the temperature is 130 to 180 ° C.
  • the minimum melt viscosity reaching temperature of the second adhesive layer 3 may be 60 ° C. or higher, 70 ° C. or higher, or 75 ° C. or higher, and 90 ° C. or lower, 85 ° C. or lower, or 80 ° C. or lower. It may be 60 to 90 ° C, 70 to 90 ° C, 75 to 85 ° C or 75 to 80 ° C.
  • the first adhesive layer 2 is, for example, conductive particles 4 (hereinafter, may be referred to as “(A) component”) and a thermosetting component (hereinafter, may be referred to as “(B) component”). And a cured product (photo-cured product) of a photocurable component (hereinafter, may be referred to as “(C) component”).
  • the component (B) is a component that can flow at the time of connection, and is, for example, an uncured curable component (for example, a resin component).
  • the cured product of the component (C) may be a cured product obtained by completely curing the component (C), or may be a cured product obtained by curing a part of the component (C).
  • the first adhesive layer 2 does not have to contain the cured product of the component (C).
  • the components other than the component (A) constituting the first adhesive layer 2 are, for example, non-conductive components (for example, an insulating resin component).
  • the component (A) is not particularly limited as long as it is conductive particles, such as metal particles made of metal such as Au, Ag, Ni, Cu, and solder, and conductive carbon particles made of conductive carbon. May be.
  • the component (A) may be a coated conductive particle containing a nucleus containing non-conductive glass, ceramic, plastic (polystyrene, etc.) and the like, and a coating layer containing the metal or conductive carbon and covering the nucleus. good.
  • coated conductive particles including metal particles formed of a heat-meltable metal or a nucleus containing plastic and a coating layer containing metal or conductive carbon and covering the nucleus is used.
  • the adhesive layer can be easily deformed by heating or pressurizing. Therefore, when the electrodes are electrically connected to each other, the contact area between the electrodes and the component (A) can be increased, and the conductivity between the electrodes can be further improved.
  • the component (A) may be an insulating coated conductive particle including the above-mentioned metal particles, conductive carbon particles, or coated conductive particles and an insulating material such as a resin and having an insulating layer covering the surface of the particles. good.
  • the component (A) is an insulating coated conductive particle, even when the content of the component (A) is large, the surface of the particle is coated with the resin, so that the component (A) is short-circuited due to contact with each other. The generation can be suppressed, and the insulation between adjacent electrode circuits can be improved.
  • one of the above-mentioned various conductive particles may be used alone or in combination of two or more.
  • the maximum particle size of the component (A) is smaller than the minimum distance between the electrodes (the shortest distance between adjacent electrodes).
  • the maximum particle size of the component (A) may be 2.5 ⁇ m or more, 3.0 ⁇ m or more, or 3.5 ⁇ m or more from the viewpoint of excellent dispersibility and conductivity.
  • the maximum particle size of the component (A) may be 6.0 ⁇ m or less, 5.0 ⁇ m or less, 4.5 ⁇ m or less, or 4.0 ⁇ m from the viewpoint of excellent dispersibility and conductivity. It may be: From these viewpoints, the maximum particle size of the component (A) may be 2.5 to 6.0 ⁇ m, 3.0 to 5.0 ⁇ m, or 3.0 to 4.0 ⁇ m. , 3.5-4.5 ⁇ m.
  • the particle size of any 300 conductive particles (pcs) is measured by observation using a scanning electron microscope (SEM), and the largest value obtained is the maximum particle size of the component (A). And.
  • the particle size of the component (A) is the diameter of a circle circumscribing the conductive particles in the SEM image.
  • the average particle size of the component (A) may be 2.5 ⁇ m or more, 3.0 ⁇ m or more, or 3.5 ⁇ m or more from the viewpoint of excellent dispersibility and conductivity.
  • the average particle size of the component (A) may be 6.0 ⁇ m or less, 5.0 ⁇ m or less, 4.5 ⁇ m or less, or 4.0 ⁇ m from the viewpoint of excellent dispersibility and conductivity. It may be: From these viewpoints, the average particle size of the component (A) may be 2.5 to 6.0 ⁇ m, 3.0 to 5.0 ⁇ m, or 3.0 to 4.0 ⁇ m. , 3.5-4.5 ⁇ m.
  • the particle size of any 300 conductive particles is measured by observation using a scanning electron microscope (SEM), and the average value of the obtained particle sizes is taken as the average particle size.
  • the particle density of the component (A) in the first adhesive layer 2 may be 5000 pieces / mm 2 or more, and may be 10000 pieces / mm 2 or more, from the viewpoint that stable connection resistance can be easily obtained. It may be 20000 pieces / mm 2 or more.
  • the particle density of the component (A) in the first adhesive layer 2 may be 50,000 pieces / mm 2 or less, and 40,000 pieces / mm 2 or less, from the viewpoint of improving the insulating property between adjacent electrodes. It may be 30,000 pieces / mm 2 or less. From these viewpoints, the particle density of the component (A) may be 5000 to 50,000 pieces / mm 2 , 10,000 to 40,000 pieces / mm 2 or 20,000 to 30,000 pieces / mm 2 .
  • the content of the component (A) is, for example, 5% by mass or more, 15% by mass or more, or 20% by mass or more based on the total mass of the first adhesive layer from the viewpoint of further improving the conductivity. It may be there.
  • the content of the component (A) may be, for example, 50% by mass or less, 40% by mass or less, or 30% by mass or less based on the total mass of the first adhesive layer from the viewpoint of easily suppressing a short circuit. From these viewpoints, the content of the component (A) may be, for example, 5 to 50% by mass, 10 to 40% by mass, or 20 to 30% by mass based on the total mass of the first adhesive layer.
  • the content of the component (A) in the composition for forming the first adhesive layer 2 (the first adhesive composition described later) (based on the total mass of the composition) is the same as the above range. It may be there.
  • the component (B) is not particularly limited as long as it is a component that is cured by heat.
  • the component (B) is, for example, a resin component, and is a thermosetting compound (hereinafter, may be referred to as “(B1) component”) and a curing agent for the thermosetting compound (hereinafter, “(B2)). It may be referred to as "ingredient").
  • Thermosetting compound The component (B1) is a compound that reacts and crosslinks by heating in the coexistence with the component (B2).
  • the component (B1) may be, for example, a radically polymerizable compound (hereinafter, may be referred to as “(B1-1) component”) and a cationically polymerizable compound (hereinafter, referred to as “(B1-2) component”). In some cases).
  • a radically polymerizable compound hereinafter, may be referred to as “(B1-1) component”
  • (B1-2) component a cationically polymerizable compound
  • As the component (B1) one type may be used alone, or a plurality of types may be used in combination.
  • Component (B1-1) Radical Polymerizable Compound
  • the component (B1-1) has at least one radically polymerizable group.
  • the radically polymerizable group include a (meth) acryloyl group, a vinyl group, an allyl group, a styryl group, an alkenyl group, an alkenylene group, a maleimide group and the like.
  • the number of radically polymerizable groups (number of functional groups) of the component (B1) is 2 or more from the viewpoint that the desired melt viscosity can be easily obtained after polymerization, the effect of reducing the connection resistance is further improved, and the connection reliability is superior. It may be 10 or less from the viewpoint of suppressing curing shrinkage during polymerization. Further, in order to balance the crosslink density and the curing shrinkage, in addition to the compound having the number of radically polymerizable groups within the above range, a compound having the number of radically polymerizable groups outside the above range may be used. good
  • the component (B1-1) may contain a (meth) acrylate compound as a radically polymerizable compound from the viewpoint of suppressing the flow of conductive particles.
  • the (meth) aclate compound may be a monofunctional (meth) acrylate having one (meth) acryloyl group, or may be a polyfunctional (meth) acrylate having two or more (meth) acryloyl groups. , These may be used together.
  • the component (B1-1) may be a polyfunctional (meth) acrylate from the viewpoint of further suppressing the flow of conductive particles.
  • Examples of the monofunctional (meth) acrylate include (meth) acrylic acid; methyl (meth) acrylate, ethyl (meth) acrylate, butyl (meth) acrylate, isobutyl (meth) acrylate, and tert-butyl (meth) acrylate.
  • examples thereof include (meth) acrylate having an oxetanyl group such as (3-ethyloxetane-3-yl) methyl (meth) acrylate.
  • polyfunctional (meth) acrylate examples include ethylene glycol di (meth) acrylate, diethylene glycol di (meth) acrylate, triethylene glycol di (meth) acrylate, tetraethylene glycol di (meth) acrylate, and polyethylene glycol di (meth) acrylate.
  • the content of the monofunctional (meth) acrylate may be, for example, 0 to 60% by mass, 0 to 50% by mass, or 0 to 40% by mass based on the total mass of the component (B1-1).
  • the content of the polyfunctional (bifunctional or higher) (meth) acrylate is, for example, 40, based on the total mass of the component (B1-1), from the viewpoint of achieving both the effect of reducing the connection resistance and the suppression of particle flow. It may be up to 100% by mass, 50 to 100% by mass, or 60 to 100% by mass.
  • the component (B1-1) may be an epoxy (meth) acrylate from the viewpoint that a first adhesive layer having a flow rate of 250% or less can be easily obtained. From the same viewpoint, the component (B1-1) may be an aromatic epoxy (meth) acrylate as described above.
  • the content of the epoxy (meth) acrylate may be, for example, 40 to 100% by mass, 50 to 100% by mass, or 60 to 100% by mass based on the total mass of the component (B1-1).
  • the component (B1-1) has a tricyclodecane structure, a crosslinked structure such as norbornane structure, and / or an aromatic structure from the viewpoint that a first adhesive layer having a flow rate of 250% or less can be easily obtained. You can do it.
  • a (meth) acrylate having a tricyclodecane structure, a crosslinked structure such as norbornane structure, and / or an aromatic structure is used as the component (B1-1), the first adhesive having a flow rate of 250% or less. Layers are easier to obtain.
  • the content of the (meth) acrylate having a tricyclodecane structure, a crosslinked structure such as norbornane structure, and / or an aromatic structure is, for example, 40 to 100% by mass based on the total mass of the component (B1-1). , 50-100% by mass or 60-100% by mass.
  • the component (B1-1) may contain a compound having a weight average molecular weight of 300 to 4000 from the viewpoint that a first adhesive layer having a flow rate of 130 to 250% can be easily obtained.
  • the content of the compound having a weight average molecular weight of 300 to 4000 may be, for example, 20% by mass or more, 30% by mass or more, or 40% by mass or more, based on the total mass of the component (B1-1), 100. It may be 0% by mass or less, 80% by mass or less, or 60% by mass or less, and may be 20 to 100% by mass, 30 to 80% by mass, or 40 to 60% by mass.
  • the weight average molecular weight of all (B1-1) components may be 300 to 4000.
  • the weight average molecular weight in the present specification means a value measured by a gel permeation chromatograph (GPC) using a calibration curve using standard polystyrene.
  • the component (B1-1) may contain other radically polymerizable compounds in addition to the (meth) acrylate compound.
  • examples of other radically polymerizable compounds include maleimide compounds, vinyl ether compounds, allyl compounds, styrene derivatives, acrylamide derivatives, nadiimide derivatives and the like.
  • the content of the other radically polymerizable compound may be, for example, 0 to 40% by mass based on the total mass of the component (B1).
  • Component (B1-2) Cationicly polymerizable compound
  • the component (B1-2) may be a compound having a cyclic ether group from the viewpoint of further improving the effect of reducing the connection resistance and improving the connection reliability.
  • the effect of reducing the connection resistance tends to be further improved.
  • the component (B1-2) may be a compound having a plurality of cyclic ether groups.
  • the epoxy compound is a compound having an epoxy group, for example, having two or more epoxy groups in one molecule.
  • Epoxy compounds include an epoxy resin derived from bisphenol A and epichlorohydrin (bisphenol A type epoxy resin) and an epoxy compound having an alicyclic epoxy group (3', 4'-epoxycyclohexylmethyl-3,4. -Epoxycyclohexanecarboxylate, etc.) can be used.
  • an epoxy compound having an alicyclic epoxy group it is easy to obtain a first adhesive layer having a flow rate of 250% or less. From the viewpoint that a first adhesive layer having a flow rate of 130 to 250% can be easily obtained, the functional group equivalent of the epoxy compound may be 100 to 500 g / eq.
  • Examples of commercially available epoxy compounds include YL-980 (trade name, manufactured by Mitsubishi Chemical Co., Ltd.), jER1007 (trade name, manufactured by Mitsubishi Chemical Co., Ltd.), which is a bisphenol A type epoxy resin, and an alicyclic epoxy compound.
  • Examples thereof include EHPE3150, EHPE3150CE, CEL (celloxide) 8010, CEL (celloxide) 2021P, CEL (celloxside) 2081 (trade name, manufactured by Daicel Co., Ltd.). These may use one kind of compound alone or may use a plurality of kinds in combination.
  • the oxetane compound is a compound having an oxetaneyl group, for example, having two or more oxetanel groups in one molecule.
  • the functional group equivalent of the oxetane compound may be 100 to 500 g / eq.
  • the oxetane compound may be used in combination with an epoxy compound having an alicyclic epoxy group. In this case, it becomes easier to obtain a first adhesive layer having a flow rate of 250% or less.
  • Examples of commercially available oxetane compounds include ETERNACOLL OXBP (trade name, 4,4'-bis [(3-ethyl-3-oxetanyl) methoxymethyl] biphenyl, manufactured by Ube Kosan Co., Ltd.), OXSQ, OXT-121, and the like. Examples thereof include OXT-221, OXT-101, and OXT-212 (trade name, manufactured by Toagosei Corporation). These may use one kind of compound alone or may use a plurality of kinds in combination.
  • Component (B2) Curing agent of component (B1)
  • the component (B2) is, for example, a thermal polymerization initiator.
  • the component (B2) may be, for example, a thermal radical generator (hereinafter, may be referred to as “(B2-1) component”) and a thermal acid generator (hereinafter, referred to as “(B2-2) component”). In some cases).
  • the component (B2) may be selected according to the type of the component (B1).
  • a thermal radical generator thermal radical polymerization initiator
  • a thermal acid generator thermal cation polymerization initiator
  • Component (B2-1) Thermal radical generator
  • the component (B2-1) is decomposed by heat to generate free radicals. That is, the component (B2-1) is a compound that generates radicals by applying thermal energy from the outside.
  • the component (B2-1) can be arbitrarily selected from conventionally known organic peroxides and azo compounds.
  • the component (B2-1) may be an organic peroxide from the viewpoint of further improving the effect of suppressing the flow of conductive particles and the effect of suppressing peeling after transfer, and is more stable, reactive and compatible. From a good viewpoint, it may be an organic peroxide having a 1-minute half-life temperature of 90 to 175 ° C. and a weight average molecular weight of 180 to 1000.
  • the 1-minute half-life temperature of the organic peroxide is within the above range, the storage stability tends to be further excellent, and a sufficiently high radical polymerizable property can be obtained, so that the organic peroxide can be cured in a short time.
  • the 1-minute half-life temperature of the component (B2-1) is 90 to 175 ° C., it becomes easy to obtain a first adhesive layer having a flow rate of 250% or less.
  • component (B2-1) examples include 1,1,3,3-tetramethylbutylperoxyneodecanoate, di (4-t-butylcyclohexyl) peroxydicarbonate, and di (2-ethylhexyl).
  • the content of the component (B2-1) is, for example, (B1-1) from the viewpoint of excellent quick-curing property, and further improving the effect of suppressing the flow of conductive particles and the effect of suppressing exfoliation after transfer.
  • it may be 0.1 to 20 parts by mass, 1 to 18 parts by mass, 3 to 15 parts by mass, or 5 to 12 parts by mass with respect to 100 parts by mass of the component.
  • the (B2-2) component is a thermal polymerization initiator (thermal latent cation generator) that generates an acid or the like by heating to initiate polymerization.
  • the component (B2-2) may be a salt compound composed of a cation and an anion.
  • Examples thereof include onium salts such as sulfonium salts, phosphonium salts, ammonium salts, diazonium salts, iodonium salts and anilinium salts having anions such as SbF 6 ⁇ and AsF 6 ⁇ . These may be used individually by 1 type, and may be used in combination of a plurality of types.
  • the component (B2-2) may be, for example, a salt compound having an anion containing boron as a constituent element from the viewpoint of quick curing.
  • a salt compound having BF 4- or BR 4- R indicates a phenyl group substituted with two or more fluorine atoms or two or more trifluoromethyl groups). Be done.
  • the anion containing boron as a constituent element may be BR 4- , and more specifically, tetrakis (pentafluorophenyl) borate.
  • the component (B2-2) may be a sulfonium salt or an ammonium salt from the viewpoint of storage stability.
  • the sulfonium salt may be, for example, a salt compound having a cation represented by the following formula (I).
  • R 5 and R 6 each independently represent a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, or an organic group containing a substituent or an unsubstituted aromatic hydrocarbon group.
  • R 7 represent an alkyl group having 1 to 6 carbon atoms.
  • the salt compound having a cation represented by the formula (I) may be an aromatic sulfonium salt compound from the viewpoint of achieving both storage stability and low temperature activity. That is, at least one of R5 and R6 in the formula (I) may be an organic group having a substituent or containing an unsubstituted aromatic hydrocarbon group.
  • the anion in the salt compound having a cation represented by the formula (I) may be an anion containing antimony as a constituent element, and may be, for example, hexafluoroantimonate (hexafluoroantimonic acid).
  • Specific examples of the compound having a cation represented by the formula (I) include 1-naphthylmethyl-p-hydroxyphenylsulfonium hexafluoroantimonate (manufactured by Sanshin Chemical Co., Ltd., SI-60 main agent).
  • the ammonium salt may be, for example, a salt compound having a cation represented by the following formula (II).
  • R 8 and R 9 each independently represent a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, or an organic group containing a substituent or an unsubstituted aromatic hydrocarbon group.
  • R 10 and R 11 each independently represent an alkyl group having 1 to 6 carbon atoms.
  • the salt compound having a cation represented by the formula (II) may be, for example, an anilinium salt compound because it has resistance to a substance that can cause curing inhibition to cation curing. That is, at least one of R 8 and R 9 in the formula (II) may be an organic group having a substituent or containing an unsubstituted aromatic hydrocarbon group.
  • the anilinium salt compound include N, N-dialkylanilinium salts such as N, N-dimethylanilinium salt and N, N-diethylanilinium salt.
  • the anion in the salt compound having a cation represented by the formula (II) may be an anion containing boron as a constituent element, and may be, for example, tetrakis (pentafluorophenyl) borate.
  • the compound having a cation represented by the formula (II) may be an anilinium salt having an anion containing boron as a constituent element.
  • anilinium salt compounds include CXC-1821 (trade name, manufactured by King Industries) and the like.
  • the content of the component (B2-2) is based on 100 parts by mass of the component (B1-2) from the viewpoint of ensuring the formability and curability of the adhesive film for forming the first adhesive layer.
  • it may be 0.1 to 20 parts by mass, 1 to 18 parts by mass, 3 to 15 parts by mass, or 5 to 12 parts by mass.
  • the component (B) is not limited to the combination of the component (B1) and the component (B2).
  • the component (B1) contains the above-mentioned epoxy compound and / or oxetane compound
  • a known amine-based curing agent or imidazole-based curing agent may be used as the component (B2).
  • the content of the component (B) is the adhesive component (first adhesive layer) in the first adhesive layer from the viewpoint of ensuring the curability of the adhesive film for forming the first adhesive layer. Based on the total amount of the components (components other than the component (A)) in the mixture, for example, it may be 5% by mass or more, 10% by mass or more, 15% by mass or more, or 20% by mass or more.
  • the content of the component (B) is the adhesive component (first adhesive layer) in the first adhesive layer from the viewpoint of ensuring the formability of the adhesive film for forming the first adhesive layer.
  • the content of the component (B) is, for example, based on the total amount of the adhesive components (components other than the component (A) in the first adhesive layer) in the first adhesive layer. It may be 5 to 70% by mass, 10 to 60% by mass, 15 to 50% by mass, or 20 to 40% by mass.
  • the content of the component (B) in the composition for forming the first adhesive layer 2 (the first adhesive composition described later) (based on the total amount of the adhesive components in the composition) is It may be the same as the above range.
  • the component (C) is not particularly limited as long as it is a component that is cured by light.
  • the component (C) is, for example, a resin component, and is a photocurable compound (hereinafter, may be referred to as “(C1) component”) and a curing agent for the photocurable compound (hereinafter, “(C2)). It may be referred to as "ingredient").
  • the cured product of the component (C) has a thermosetting property
  • the cured product does not correspond to the component (B).
  • Component (C1) Photocurable compound
  • the component (C1) is a compound that reacts and crosslinks by irradiating with light in the coexistence with the component (C2).
  • the component (C1) may be, for example, a radically polymerizable compound (hereinafter, may be referred to as “(C1-1) component”) and a cationically polymerizable compound (hereinafter, referred to as “(C1-2) component”). In some cases).
  • the component (C1) is a compound having a radically polymerizable group and a cationically polymerizable group such as a (meth) acrylate having an epoxy group and a (meth) acrylate having an oxetanyl group ((C1-1) component and (C1-2). It may be a compound corresponding to both of the components).
  • the component (C1-1) the compound described in detail as the component (B1-1) can be used, and the details (preferable aspects for setting the content ratio and the flow rate to 130 to 250%, etc.) are (B1). -1) It is the same as the case of the component.
  • the compound described in detail as the component (B1-2) can be used, and the details thereof (content ratio, preferred embodiment for setting the flow rate to 130 to 250%, etc.). Is the same as in the case of the (B1-2) component.
  • the component (C1) one type may be used alone, or a plurality of types may be used in combination.
  • Component (C2) Curing agent of component (C1)
  • the component (C2) is, for example, a photopolymerization initiator.
  • the component (C2) may be, for example, a photoradical generator (hereinafter, may be referred to as “(C2-1) component”) and a photoacid generator (hereinafter, referred to as “(C2-2) component”). In some cases).
  • the component (C2) may be selected according to the type of the component (C1).
  • a photoradical generator photoradical polymerization initiator
  • the component (C1) is a cationically polymerizable compound, (C2).
  • a photoacid generator (photocationic polymerization initiator) may be used as a component.
  • the component (C2) is a component that does not function as a curing agent for the component (B1).
  • the component (C2) is a compound that does not generate radicals by light (for example, a photocationic polymerization initiator)
  • the component (B) is a cationically polymerizable compound.
  • (C2) component is a compound that does not generate a cation by light (for example, a photoradical polymerization initiator).
  • the (C2-1) component is light containing a wavelength in the range of 150 to 750 nm, preferably light containing a wavelength in the range of 254 to 405 nm, and more preferably light containing a wavelength in the range of 254 to 405 nm. It is a photopolymerization initiator that generates radicals by irradiation with light containing a wavelength (for example, ultraviolet light).
  • a wavelength for example, ultraviolet light.
  • the component (C2-1) one type may be used alone, or a plurality of types may be used in combination.
  • the (C2-1) component is decomposed by light to generate free radicals. That is, the component (C2-1) is a compound that generates radicals by applying light energy from the outside.
  • the component (C2-1) is an oxime ester structure, a bisimidazole structure, an acridine structure, an ⁇ -aminoalkylphenone structure, an aminobenzophenone structure, an N-phenylglycine structure, an acylphosphine oxide structure, a benzyldimethylketal structure, and an ⁇ -hydroxyalkyl. It may be a compound having a structure such as a phenone structure.
  • the component (C2-1) is composed of a group consisting of an oxime ester structure, an ⁇ -aminoalkylphenone structure, and an acylphosphine oxide structure from the viewpoint that the desired melt viscosity can be easily obtained and the effect of reducing the connection resistance is superior. It may be a compound having at least one structure selected.
  • the compound having an oxime ester structure examples include 1-phenyl-1,2-butandion-2- (o-methoxycarbonyl) oxime and 1-phenyl-1,2-propanedione-2- (o-methoxycarbonyl).
  • the compound having an ⁇ -aminoalkylphenone structure include 2-methyl-1- [4- (methylthio) phenyl] -2-morpholinopropane-1-one and 2-benzyl-2-dimethylamino-1. -Morphorinophenyl) -butanone-1 and the like.
  • compounds having an acylphosphine oxide structure include bis (2,6-dimethoxybenzoyl) -2,4,4-trimethyl-pentylphosphine oxide and bis (2,4,6, -trimethylbenzoyl) -phenylphosphine.
  • examples thereof include oxides, 2,4,6-trimethylbenzoyl-diphenylphosphine oxide and the like.
  • the content of the component (C2-1) is 100 parts by mass of the component (C1-1) from the viewpoint of easily obtaining a first adhesive layer having a flow rate of 130 to 250% and suppressing the flow of conductive particles.
  • it may be 0.1 to 10 parts by mass, 0.3 to 7 parts by mass, or 0.5 to 5 parts by mass.
  • the (C2-2) component is light containing a wavelength in the range of 150 to 750 nm, preferably light containing a wavelength in the range of 254 to 405 nm, and more preferably light containing a wavelength in the range of 254 to 405 nm. It is a photopolymerization initiator that generates a cationic species by irradiation with light containing a wavelength (for example, ultraviolet light).
  • a wavelength for example, ultraviolet light.
  • one type may be used alone, or a plurality of types may be used in combination.
  • Examples of the (C2-2) component include onium salts such as aromatic diazonium salt, aromatic sulfonium salt, aliphatic sulfonium salt, aromatic iodonium salt, phosphonium salt, pyridinium salt, and selenonium salt, metal arene complex, and silanol /.
  • Examples thereof include complex compounds such as aluminum complexes, benzointosylate, o-nitrobenzyltosylate and the like.
  • aromatic sulfonium salts for example, triarylsulfonium salts
  • sulfonium salts such as aliphatic sulfonium salts
  • iodinenium salts such as aromatic iodinenium salts
  • iron-alene complexes have high efficiency of cation species generation. Therefore, good reactivity can be easily obtained.
  • the component (C2-2) is an onium salt and the counter anion is hexafluoroantimonate, hexafluorophosphonate, tetrafluoroborate, tetrakis (pentafluorophenyl) borate or the like, better reactivity can be easily obtained. ..
  • the component (C2-2) is BF 4- , BR 4- ( R is 2 or more fluorine atoms or 2 or more birds) from the viewpoint that a first adhesive layer having a flow rate of 250% or less can be easily obtained. It indicates a phenyl group substituted with a fluoromethyl group.), A sulfonium salt, a phosphonium salt, an ammonium salt, a diazonium salt, an iodonium salt, an anilinium salt having anions such as PF 6 ⁇ , SbF 6 ⁇ , AsF 6 ⁇ . It's okay.
  • component (C2-2) light irradiation or heating of a triarylsilyl peroxide derivative, an acylsilane derivative, an ⁇ -sulfonyloxyketone derivative, an ⁇ -hydroxymethylbenzoin derivative, a nitrobenzyl ester derivative, an ⁇ -sulfonylacetophenone derivative, etc.
  • Derivatives that generate organic acids can also be used.
  • CPI series manufactured by Sun Apro Co., Ltd. Adecaoptomer SP series manufactured by Asahi Denka Kogyo Co., Ltd., Adeka Opton CP series manufactured by Asahi Denka Kogyo Co., Ltd., Union Carbide Co., Ltd.
  • CyracureUVI series manufactured by Cyracure UVI and IRGACURE series manufactured by Ciba Specialty Chemicals are preferably used.
  • a known singlet sensitizer or triplet sensitizer typified by anthracene, thioxanthone derivative and the like can be used in combination.
  • the content of the component (C2-2) is 100 parts by mass of the component (C1-2) from the viewpoint of easily obtaining a first adhesive layer having a flow rate of 130 to 250% and suppressing the flow of conductive particles.
  • it may be 0.1 to 10 parts by mass, 0.3 to 7 parts by mass, or 0.5 to 5 parts by mass.
  • the content of the cured product of the component (C) is the entire content of the first adhesive layer from the viewpoint of easily obtaining the first adhesive layer having a flow rate of 130% or more and suppressing the flow of conductive particles. It may be 1% by mass or more, 5% by mass or more, or 10% by mass or more based on the mass.
  • the content of the cured product of the component (C) is the content of the first adhesive layer from the viewpoint of easily obtaining the first adhesive layer having a flow rate of 250% or less and from the viewpoint of developing low resistance in low-pressure mounting. Based on the total mass, it may be 50% by mass or less, 40% by mass or less, or 30% by mass or less.
  • the content of the cured product of the component (C) is, for example, 1 to 50% by mass, 5 to 40% by mass, or 10 to 30% by mass, based on the total mass of the first adhesive layer. It may be there.
  • the content of the component (C) in the composition for forming the first adhesive layer 2 (the first adhesive composition described later) (based on the total mass of the composition) is the same as the above range. It may be there.
  • the first adhesive layer 2 may further contain other components in addition to the cured product of the component (A), the component (B) and the component (C).
  • other components include a thermoplastic resin (hereinafter, may be referred to as “(D) component”), a coupling agent (hereinafter, may be referred to as “(E) component”), and a filler. (Hereinafter, it may be referred to as "(F) component”.) And the like.
  • a resin that functions as a film-forming component can be used.
  • the component (D) include phenoxy resin, polyester resin, polyamide resin, polyurethane resin, polyester urethane resin, acrylic rubber, epoxy resin (solid at 25 ° C.) and the like. These may be used individually by 1 type, and may be used in combination of a plurality of types.
  • the film formability is improved by using the component (D). Among these, when the component (D) is a phenoxy resin, the film formability is more likely to be improved.
  • the weight average molecular weight (Mw) of the component (D) is, for example, 5000 to 200,000 from the viewpoint of easily obtaining a first adhesive layer having a flow rate of 130 to 250% and resin exclusion during mounting. It may be 10,000 to 100,000, 20,000 to 80,000, 40,000 to 70,000 or 40,000 to 60,000.
  • Mw means a value measured by gel permeation chromatography (GPC) and converted using the calibration curve by standard polystyrene.
  • the glass transition temperature Tg of the component (D) may be, for example, 80 to 160 ° C. from the viewpoint that a first adhesive layer having a flow rate of 130 to 250% can be easily obtained.
  • the glass transition temperature Tg of the component (D) is a value measured using a differential scanning calorimeter (DSC). Specifically, for example, using DSC, differential scanning calorimetry from room temperature (25 ° C.) to 270 ° C. is performed for two cycles at a heating rate of 10 ° C./min, and Tg is performed from the baseline shift in the second cycle. Can be asked.
  • DSC differential scanning calorimeter
  • the elastic modulus of the component (D) at room temperature (25 ° C.) is, for example, 1.5 to 2.3 GPa from the viewpoint that a first adhesive layer having a flow rate of 130 to 250% can be easily obtained. good.
  • the content of the component (D) is such that the first adhesive layer having a flow rate of 130 to 250% can be easily obtained, the film formability, and the resin exclusion property at the time of mounting. Based on the total mass of the agent layer, it may be 1% by mass or more, 5% by mass or more, 10% by mass or more or 20% by mass or more, and 70% by mass or less, 60% by mass or less, 50% by mass or less or 40% by mass. It may be less than or equal to%.
  • the content of the component (D) in the composition for forming the first adhesive layer 2 (the first adhesive composition described later) (based on the total mass of the composition) is the same as the above range. It may be there.
  • the ratio of the content of the component (B) to the content of the component (D) is, for example, 0.8 to 0.95 from the viewpoint that a first adhesive layer having a flow rate of 130 to 250% can be easily obtained. May be.
  • the component (E) examples include a silane coupling agent having an organic functional group such as a (meth) acryloyl group, a mercapto group, an amino group, an imidazole group and an epoxy group, a silane compound such as tetraalkoxysilane, and a tetraalkoxy titanate derivative. , Polydialkyl titanate derivatives and the like. These may be used individually by 1 type, and may be used in combination of a plurality of types. When the first adhesive layer 2 contains the component (E), the adhesiveness can be further improved.
  • the component (E) may be, for example, a silane coupling agent.
  • the content of the component (E) may be 0.1 to 10% by mass based on the total mass of the first adhesive layer.
  • the content of the component (E) in the composition for forming the first adhesive layer 2 (the first adhesive composition described later) (based on the total mass of the composition) is the same as the above range. It may be there.
  • the component (F) include non-conductive fillers (for example, non-conductive particles).
  • the component (F) may be either an inorganic filler or an organic filler.
  • the inorganic filler include metal oxide fine particles such as silica fine particles, alumina fine particles, silica-alumina fine particles, titania fine particles, and zirconia fine particles; and inorganic fine particles such as metal nitride fine particles.
  • the organic filler include organic fine particles such as silicone fine particles, methacrylate / butadiene / styrene fine particles, acrylic / silicone fine particles, polyamide fine particles, and polyimide fine particles. These may be used individually by 1 type, and may be used in combination of a plurality of types.
  • the component (F) can be appropriately blended as long as the effect of the present invention is not impaired.
  • the first adhesive layer 2 may further contain other additives such as a softener, an accelerator, a deterioration inhibitor, a colorant, a flame retardant, and a thixotropic agent as other components.
  • the content (total amount) of the other additives may be, for example, 0.1 to 10% by mass based on the total mass of the first adhesive layer.
  • the content of other additives (based on the total mass of the composition) in the composition for forming the first adhesive layer 2 (the first adhesive composition described later) is the same as the above range. It may be there.
  • the second adhesive layer 3 contains, for example, a thermosetting component (component (B)).
  • component (B) The details of the component (B) are the same as those of the component (B) contained in the first adhesive layer 2.
  • the content of the component (B) is 5% by mass or more, 10% by mass or more, 15% by mass or more, or 20% by mass or more based on the total mass of the second adhesive layer from the viewpoint of maintaining reliability. It may be there.
  • the content of the component (B) is 70% by mass or less and 60% by mass or less based on the total mass of the second adhesive layer from the viewpoint of preventing the resin seepage problem in the reel, which is one aspect of the supply form. , 50% by mass or less, or 40% by mass or less. From these viewpoints, the content of the component (B) is, for example, 5 to 70% by mass, 10 to 60% by mass, 15 to 50% by mass, or 20 to 40, based on the total mass of the second adhesive layer. It may be% by mass.
  • the content of the component (B) in the composition for forming the second adhesive layer 3 (the second adhesive composition described later) (based on the total mass of the composition) is the same as the above range. It may be there.
  • the second adhesive layer 3 may further contain a filler (component (F)).
  • the details of the component (F) are the same as those of the component (F) contained in the first adhesive layer 2.
  • the second adhesive layer 3 contains an inorganic filler as the component (F) from the viewpoint of facilitating the adjustment of fluidity, the viewpoint of improving the elastic modulus after curing, and the viewpoint of lowering the coefficient of linear expansion. good.
  • a silica filler such as silica fine particles can be used from the viewpoint of improving reliability.
  • the content of silica in the silica filler may be 99% by mass or more, or 100% by mass, based on the total amount of the silica filler.
  • the average particle size (primary particle size) of the inorganic filler may be 0.01 ⁇ m or more, 0.03 ⁇ m or more, 0.05 ⁇ m or more, 0.1 ⁇ m or more, or 0.3 ⁇ m or more from the viewpoint of excellent dispersibility.
  • the average particle size (primary particle size) of the inorganic filler may be 5.0 ⁇ m or less, 1.0 ⁇ m or less, or 0.5 ⁇ m or less from the viewpoint of excellent dispersibility. From these viewpoints, the average particle size of the inorganic filler is 0.01 to 5.0 ⁇ m, 0.03 to 1.0 ⁇ m, 0.05 to 0.5 ⁇ m, 0.05 to 5.0 ⁇ m, 0.1 to 0. It may be .5 ⁇ m or 0.3-0.5 ⁇ m.
  • the content of the inorganic filler may be 20% by mass or more, 30% by mass or more, or 40% by mass or more based on the total mass of the second adhesive layer from the viewpoint of improving the elastic modulus after curing.
  • the content of the inorganic filler is 60% by mass or less, 50% by mass or less, or 40% by mass or less based on the total mass of the second adhesive layer from the viewpoint of improving film formation and thermosetting property. It's okay. From these viewpoints, the content of the inorganic filler is 20 to 60% by mass, 30 to 50% by mass, 20 to 40% by mass or 40 to 50% by mass, based on the total mass of the second adhesive layer. It's okay.
  • the content of the inorganic filler (based on the total mass of the composition) in the composition for forming the second adhesive layer 3 is the same as the above range. good.
  • the second adhesive layer 3 may further contain other components other than the component (F) in the first adhesive layer 2.
  • the details of the other components are the same as the details of the other components in the first adhesive layer 2.
  • the content of the component (D) may be 1% by mass or more, 5% by mass or more or 10% by mass or more, and 80% by mass or less and 60% by mass or less, based on the total mass of the second adhesive layer. Alternatively, it may be 40% by mass or less.
  • the content of the component (D) in the composition for forming the second adhesive layer 3 (the second adhesive composition described later) (based on the total mass of the composition) is the same as the above range. It may be there.
  • the content of the component (E) may be 0.1 to 10% by mass based on the total mass of the second adhesive layer.
  • the content of the component (E) in the composition for forming the second adhesive layer 3 (the second adhesive composition described later) (based on the total mass of the composition) is the same as the above range. It may be there.
  • the content of the other additives may be, for example, 0.1 to 10% by mass based on the total mass of the second adhesive layer.
  • the content of other additives (based on the total mass of the composition) in the composition for forming the second adhesive layer 3 (the second adhesive composition described later) is the same as the above range. It may be there.
  • the content of the conductive particles (component (A)) in the second adhesive layer 3 is, for example, 1% by mass or less, even if it is 0% by mass, based on the total mass of the second adhesive layer. good. That is, the second adhesive layer 3 does not have to contain the component (A).
  • the content of the component (A) in the composition for forming the second adhesive layer 3 (the second adhesive composition described later) (based on the total mass of the composition) is the same as the above range. It may be there.
  • the adhesive film 1a is a first adhesive containing, for example, a component (A), a component (B) (a first thermosetting component), and a component (C), and if necessary, other components.
  • the step of irradiating the layer made of the composition with light to form the first adhesive layer 2 (first step) and the component (B) component (second) on the first adhesive layer 2 It is manufactured by a method including a step (second step) of laminating a second adhesive layer 3 composed of a second adhesive composition containing a thermosetting component) and, if necessary, other components. Can be done.
  • the first step it is not necessary to include the component (C) in the first adhesive composition. In this case, the light irradiation in the first step does not have to be performed.
  • the first adhesive composition is dissolved or dispersed by stirring and mixing in an organic solvent, kneading, or the like, and the varnish composition (varnish-like first adhesive) is used.
  • Composition is prepared.
  • the varnish composition is applied onto the mold-released substrate using a knife coater, roll coater, applicator, comma coater, die coater, etc., and then the organic solvent is volatilized by heating to form the substrate.
  • the thickness of the first adhesive layer can be adjusted by adjusting the coating amount of the varnish composition.
  • the layer composed of the first adhesive composition is irradiated with light to cure the component (C) in the layer. Let me.
  • the first adhesive layer 2 is formed on the base material, and the first adhesive film provided with the first adhesive layer 2 is obtained.
  • the organic solvent used in the preparation of the varnish composition is not particularly limited as long as it has the property of being able to dissolve or disperse each component substantially uniformly.
  • examples of such an organic solvent include toluene, acetone, methyl ethyl ketone, methyl isobutyl ketone, ethyl acetate, propyl acetate, butyl acetate and the like. These organic solvents can be used alone or in combination of two or more.
  • Stirring and mixing or kneading in the preparation of the varnish composition can be carried out by using, for example, a stirrer, a raider, a three-roll, a ball mill, a bead mill, a homodisper or the like.
  • the base material is not particularly limited as long as it has heat resistance that can withstand the heating conditions when volatilizing the organic solvent.
  • a substrate examples include stretched polypropylene (OPP), polyethylene terephthalate (PET), polyethylene naphthalate, polyethylene isophthalate, polyvinylidene terephthalate, polyolefin, polyacetate, polycarbonate, polyvinylidene sulfide, polyamide, polyimide, cellulose, and the like.
  • a substrate (for example, a film) made of an ethylene / vinyl acetate copolymer, polyvinyl chloride, polyvinylidene chloride, a synthetic rubber system, a liquid crystal polymer or the like can be used.
  • the heating conditions for volatilizing the organic solvent from the varnish composition applied to the base material can be appropriately set according to the organic solvent to be used and the like.
  • the heating conditions may be, for example, 40 to 120 ° C. for 0.1 to 10 minutes.
  • a part of the solvent may remain on the first adhesive layer 2 without being removed.
  • the content of the solvent in the first adhesive layer 2 may be, for example, 10% by mass or less based on the total mass of the first adhesive layer.
  • irradiation light for example, ultraviolet light
  • Light irradiation can be performed using, for example, a low-pressure mercury lamp, a medium-pressure mercury lamp, a high-pressure mercury lamp, an ultra-high-pressure mercury lamp, a xenon lamp, a metal halide lamp, an LED light source, or the like.
  • the integrated light amount of light irradiation can be appropriately set, but may be, for example, 500 to 3000 mJ / cm 2 .
  • the second step is a step of laminating the second adhesive layer 3 on the first adhesive layer 2.
  • the base is the same as in the first step except that the second adhesive composition is used instead of the first adhesive composition and the light irradiation is not performed.
  • the obtained second adhesive film and the first adhesive film are bonded to each other to form a second adhesive on the first adhesive layer 2.
  • the agent layer 3 is laminated.
  • Examples of the method of adhering the first adhesive film and the second adhesive film include a method of heat pressing, roll laminating, vacuum laminating and the like. Lamination can be performed, for example, under temperature conditions of 0 to 80 ° C.
  • a varnish-like second adhesive composition is applied onto the first adhesive layer 2 and the organic solvent is volatilized to cause a second on the first adhesive layer 2.
  • the adhesive layer 3 of the above may be laminated.
  • a part of the solvent may remain on the second adhesive layer 3 without being removed.
  • the content of the solvent in the second adhesive layer 3 may be, for example, 10% by mass or less based on the total mass of the second adhesive layer.
  • the adhesive film 1a described above since the flow rate of the first adhesive layer 2 is 250% or less, it is difficult for conductive particles to flow during thermocompression bonding, and the film of the first adhesive layer after thermocompression bonding is performed. The shape is easy to maintain. Therefore, according to the adhesive film 1a, it is possible to suppress the occurrence of a short circuit due to aggregation of conductive particles. Further, since the adhesive film 1a has a flow rate of 130% or more of the first adhesive layer, the adhesive film 1a is bent during thermocompression bonding, and the bending causes the first adhesive layer to be stretched between the facing electrodes. Adhesive component is reduced.
  • the flow rate of the first adhesive layer 2 may be 150% or more, 160% or more, 170% or more or 180% or more, and 230% or less or 200%. It may be 150 to 230% or 180 to 200%.
  • the flow rate of the first adhesive layer 2 is, for example, the content of the cured product of the component (A), the component (B) and the component (C), and the components (C1) and (C2) in the component (C). It can be adjusted according to the type and amount of the above, the type and content of any component (particularly the component (D)), and the like.
  • the cured product of the component (C) is contained in the first adhesive layer 2, for example, by adjusting the curing rate of the component (C) by adjusting the light irradiation amount, the flow rate in the above range can be easily obtained. It is also possible to obtain the first adhesive layer 2 having the above.
  • the flow rate is higher than 250% in the conventional adhesive composition, but the weight average molecular weight of the component (D) is 40,000 or more.
  • a thermoplastic resin having a glass transition temperature of 70,000, a glass transition temperature of 80 to 160 ° C., and an elastic modulus of 1.5 to 2.3 GPa at room temperature (25 ° C.) with respect to the content of the component (D).
  • the first adhesive layer 2 having a flow rate in the above range can be obtained by a method such as setting the ratio of the content of the components to 0.8 to 0.95.
  • circuit connection adhesive film of one embodiment and the method for manufacturing the same have been described above, the circuit connection adhesive film of the present invention is not limited to the above embodiment.
  • the circuit connection adhesive film may be composed of three or more layers including layers other than the first adhesive layer 2 and the second adhesive layer 3.
  • the adhesive film for circuit connection may be the adhesive film 1b shown in FIG.
  • the adhesive film 1b has the same configuration as the adhesive film 1a except that the third adhesive layer 6 is laminated on the side of the first adhesive layer 2 opposite to the second adhesive layer 3. Has.
  • the third adhesive layer 6 contains, for example, a thermosetting component (component (B)).
  • component (B) thermosetting component
  • the details of the component (B) are the same as those of the component (B) contained in the first adhesive layer 2.
  • the component (B) (third thermosetting component) contained in the third adhesive layer 6 may be the same as or different from the first thermosetting component, and the second heat may be different. It may be the same as or different from the curable component.
  • the content of the component (B) is 5% by mass or more, 10% by mass or more, and 15% by mass or more based on the total mass of the third adhesive layer from the viewpoint of imparting good transferability and peeling resistance. Alternatively, it may be 20% by mass or more.
  • the content of the component (B) is 70% by mass or less based on the total mass of the third adhesive layer from the viewpoint of imparting good half-cut property and blocking resistance (suppression of resin seepage of the reel). It may be 60% by mass or less, 50% by mass or less, or 40% by mass or less. From these viewpoints, the content of the component (B) is, for example, 5 to 70% by mass, 10 to 60% by mass, 15 to 50% by mass, or 20 to 40, based on the total mass of the third adhesive layer. It may be% by mass.
  • the third adhesive layer 6 may further contain other components in the first adhesive layer 2.
  • the content of the component (D) may be 10% by mass or more, 20% by mass or more or 30% by mass or more, and 80% by mass or less and 70% by mass or less, based on the total mass of the third adhesive layer. Alternatively, it may be 60% by mass or less.
  • the content of the component (E) may be 0.1 to 10% by mass based on the total mass of the third adhesive layer.
  • the content of the component (F) can be appropriately set as long as the effect of the present invention is not impaired.
  • the content of the other additives may be, for example, 0.1 to 10% by mass based on the total mass of the third adhesive layer.
  • the thickness of the third adhesive layer 6 may be appropriately set according to the minimum melt viscosity of the adhesive film, the height of the electrodes of the circuit members to be adhered, and the like.
  • the thickness of the third adhesive layer 6 is preferably smaller than the thickness of the second adhesive layer 3.
  • the thickness of the third adhesive layer 6 is 0.5 ⁇ m or more from the viewpoint that the space between the electrodes can be sufficiently filled to seal the electrodes and better connection reliability can be obtained. It may be 0 ⁇ m or more or 1.2 ⁇ m or more, 2.0 ⁇ m or less, 1.8 ⁇ m or less, or 1.5 ⁇ m or less, 0.5 to 2.0 ⁇ m, 1.0 to 1.8 ⁇ m, or 1.2. It may be up to 1.6 ⁇ m.
  • the thickness of the third adhesive layer 6 can be obtained, for example, by the same method as the method for measuring the thickness of the first adhesive layer 2 and the thickness of the second adhesive layer 3.
  • the thickness of the adhesive film 1b (the sum of the thickness of the first adhesive layer 2, the thickness of the second adhesive layer 3 and the thickness of the third adhesive layer 6) is, for example, 6.0 ⁇ m. As described above, it may be 8.0 ⁇ m or more, 10.0 ⁇ m or more, 12.0 ⁇ m or more, or 14.0 ⁇ m or more, 18.0 ⁇ m or less, 16.0 ⁇ m or less, 14.0 ⁇ m or less, or 10.0 ⁇ m or less. It may be 6.0 to 18.0 ⁇ m, 10.0 to 16.0 ⁇ m, 8.0 to 10.0 ⁇ m, 12.0-14.0 ⁇ m or 14.0 to 16.0 ⁇ m.
  • the adhesive film 1b is, for example, on the opposite side of the first adhesive layer 2 from the second adhesive layer 3 in addition to the first step and the second step in the method for producing the adhesive film 1a.
  • the second step may be performed first, or the third step may be performed first.
  • the third adhesive layer 6 is laminated on the side opposite to the side where the second adhesive layer 3 of the first adhesive layer 2 is to be laminated.
  • the method for laminating the third adhesive layer 6 in the third step is the same as the method for laminating the second adhesive layer 3 in the second step.
  • the circuit connection structure of one embodiment is located between a first circuit member having a first electrode, a second circuit member having a second electrode, and a first circuit member and a second circuit member. Arranged, the first electrode and the second electrode are electrically connected to each other via conductive particles, and a circuit connection portion for adhering the first circuit member and the second circuit member is provided, and the circuit connection is provided.
  • the portion includes a first resin cured layer containing conductive particles and a second resin cured layer located on the side opposite to the first circuit member side of the first resin cured layer, and is the first.
  • the resin cured layer includes a plurality of electrode connecting portions for electrically connecting the first electrode and the second electrode to each other by conductive particles interposed between the first electrode and the second electrode, and the adjacent electrode connecting portions. It is a circuit connection structure that is bent so as to be convex toward the first circuit member side or the second circuit member side.
  • the method for manufacturing the circuit connection structure of one embodiment includes a first adhesive layer containing conductive particles and a second adhesive layer provided on the first adhesive layer, and comprises the following ( A step of preparing an adhesive film for circuit connection, wherein the flow rate of the first adhesive layer measured in the procedures A1) to (A4) is 130 to 250%, and a first having a first electrode.
  • the first circuit connection adhesive film is interposed between the first circuit member and the second circuit member so that the second adhesive layer is on the side and the second circuit member side.
  • the first electrode and the second electrode are electrically connected to each other via conductive particles to form an electrode connection portion.
  • the first adhesive layer is bent so as to be convex toward the first circuit member side or the second circuit member side between the adjacent electrode connection portions, and the circuit connection adhesive film is cured.
  • a method for manufacturing a circuit connection structure (A1) The circuit connection adhesive film is punched out in the thickness direction with the base material attached on both main surfaces of the circuit connection adhesive film, and the diameter R (unit: mm) is 0.1. A disk-shaped evaluation adhesive film having a diameter of about 1 mm is obtained.
  • the evaluation adhesive film After peeling the base material on the first adhesive layer side from the evaluation adhesive film, the evaluation adhesive film is placed on a glass plate having a thickness of 0.15 mm from the first adhesive layer side. Thermocompression bonding is performed under the conditions of a crimping temperature of 60 ° C., a crimping pressure of 1 MPa, and a crimping time of 0.1 s to obtain a temporary fixed body.
  • the first adhesive layer may contain a first thermosetting component.
  • the first thermosetting component may contain a (meth) acrylate compound as the thermosetting compound.
  • the first thermosetting component may contain an organic peroxide as a curing agent for the thermosetting compound.
  • the first adhesive layer may contain a cured product of a photocurable component.
  • the density of the conductive particles in the first adhesive layer may be 5000 to 50,000 pieces / mm 2 .
  • the thickness of the first adhesive layer may be 0.6 times or more and less than 1.0 times the average particle size of the conductive particles.
  • the thickness of the first adhesive layer may be 1.0 to 6.0 ⁇ m.
  • the average particle size of the conductive particles may be 2.5 to 6.0 ⁇ m.
  • the second adhesive layer may contain a second thermosetting component.
  • the second thermosetting component may contain an epoxy compound or an oxetane compound as the thermosetting compound.
  • the second thermosetting component may contain a sulfonium salt or an ammonium salt as a curing agent for the thermosetting compound.
  • the second adhesive layer may contain an inorganic filler.
  • the average particle size of the inorganic filler may be 0.05 to 5.0 ⁇ m.
  • the content of the inorganic filler may be 20 to 60% by mass based on the total mass of the second adhesive layer.
  • FIG. 4 is a schematic cross-sectional view showing an embodiment of a circuit connection structure.
  • the circuit connection structure 10a includes a first circuit member 13 having a first electrode 12 formed on the main surface 11a of the first circuit board 11 and the first circuit board 11.
  • a second circuit member 16 having a second electrode 15 formed on the main surface 14a of the second circuit board 14 and the second circuit board 14, and the first circuit member 13 and the second circuit member. It is arranged between 16 and includes a circuit connection portion 17a that electrically connects the first electrode 12 and the second electrode 15 to each other via the conductive particles 4.
  • the first circuit member 13 and the second circuit member 16 may be the same or different from each other.
  • the first circuit member 13 and the second circuit member 16 are a glass substrate or a plastic substrate on which a circuit electrode is formed; a printed wiring board; a ceramic wiring board; a flexible wiring board; an IC chip such as a drive IC, or the like. It's okay.
  • the first circuit board 11 and the second circuit board 14 may be formed of an inorganic substance such as semiconductor, glass, or ceramic, an organic substance such as polyimide or polycarbonate, or a composite such as glass / epoxy.
  • the first circuit board 11 may be a plastic substrate.
  • the first circuit member 13 may be, for example, a plastic substrate on which a circuit electrode is formed (a plastic substrate made of an organic substance such as polyimide, polycarbonate, polyethylene terephthalate, or cycloolefin polymer), and the second circuit member 16 may be.
  • a plastic substrate on which a circuit electrode is formed a plastic substrate made of an organic substance such as polyimide, polycarbonate, polyethylene terephthalate, or cycloolefin polymer
  • the second circuit member 16 may be.
  • it may be an IC chip such as a drive IC.
  • a display region is formed by regularly arranging a pixel drive circuit such as an organic TFT or a plurality of organic EL elements R, G, and B on the plastic substrate in a matrix. It may be the one.
  • the first electrode 12 and the second electrode 15 are made of a metal such as gold, silver, tin, ruthenium, rhodium, palladium, osmium, iridium, platinum, copper, aluminum, molybdenum, titanium, indium tin oxide (ITO), and the like. It may be an electrode containing an oxide such as indium zinc oxide (IZO) or indium gallium zinc oxide (IGZO).
  • the first electrode 12 and the second electrode 15 may be electrodes formed by laminating two or more of these metals, oxides, and the like. The electrode formed by stacking two or more types may have two or more layers, and may have three or more layers.
  • the first electrode 12 and the second electrode 15 may be circuit electrodes or bump electrodes. At least one of the first electrode 12 and the second electrode 15 may be a bump electrode. In FIG. 4, the first electrode 12 is a circuit electrode and the second electrode 15 is a bump electrode.
  • the circuit connection portion 17a contains the cured product of the adhesive film 1a described above.
  • the circuit connection portion 17 may be made of the cured product of the adhesive film 1a described above.
  • the circuit connection portion 17 is, for example, a first resin curing located on the first circuit member 13 side in a direction in which the first circuit member 13 and the second circuit member 16 face each other (hereinafter, “opposite direction”).
  • the layer 18 includes a second resin cured layer 19 located on the side opposite to the first circuit member side of the first resin cured layer 18 (the second circuit member 16 side in the facing direction).
  • the first resin cured layer 18 is a layer formed by curing the first adhesive layer 2 in the adhesive film 1a, and cures the conductive particles 4 and the components other than the conductive particles 4 in the first adhesive. Including things. At least a part of the conductive particles 4 in the first resin cured layer 18 is interposed between the first electrode 12 and the second electrode 15, and electrically connects the first electrode 12 and the second electrode 15 to each other. Consists of the electrode connecting portion 21 to be connected. That is, the first resin cured layer 18 includes a plurality of electrode connecting portions 21.
  • the first resin cured layer 18 is in the form of a film that spreads in a direction substantially perpendicular to the facing direction of the circuit connection structure 10a, and is convex toward the second circuit member side between the adjacent electrode connection portions 21. (For example, it is arched when viewed from the cross section of the circuit connection structure in the opposite direction).
  • the first resin cured layer 18 can be bent so as to be convex toward the first circuit member between the adjacent electrode connecting portions 21 by adjusting the electrode height or the like.
  • the second resin cured layer 19 is a layer formed by curing the second adhesive layer 3 in the adhesive film 1a, and contains a cured product of the components in the second adhesive layer 3.
  • the second resin cured layer 19 fills between the second circuit member 16 and the first resin cured layer 18.
  • the method for manufacturing the circuit connection structure 10a includes a step of preparing an adhesive film 1a, a first circuit member 13 having a first electrode 12, and a second circuit member 16 having a second electrode 15. , The step of arranging the first electrode 12 and the second electrode 15 so as to face each other, and the first adhesive layer 2 is on the first circuit member 13 side, and the second adhesive layer 3 is the second. The first circuit member 13 and the second circuit member 16 are placed in a state where the adhesive film 1a is interposed between the first circuit member 13 and the second circuit member 16 so as to be on the circuit member 16 side. It is provided with a process of thermal crimping.
  • the first circuit member 13 and the first circuit member 13 are prepared.
  • the circuit member 16 of 2 is arranged so that the first electrode 12 and the second electrode 15 face each other, and the adhesive film 1a is arranged between the first circuit member 13 and the second circuit member 16. do.
  • the adhesive film 1a is placed on the first circuit member 13 so that the first adhesive layer 2 side faces the main surface 11a of the first circuit board 11. Temporarily crimping is performed, whereby the adhesive film 1a is temporarily fixed on the first circuit member 13.
  • the adhesive film 1a is laminated so that the first electrode 12 on the first circuit board 11 and the second electrode 15 on the second circuit board 14 face each other.
  • the second circuit member 16 is arranged on the circuit member 13.
  • the method of temporary crimping is not particularly limited, but it may be a method of laminating using a roll laminator, a diaphragm type laminator, a vacuum roll laminator, a vacuum diaphragm type laminator, etc., and after temporary laminating, crimping is performed using a thermocompression bonding device. It may be a method.
  • the conditions for temporary crimping may be appropriately set according to the type of crimping device (laminator or the like) to be used, the base material, the first circuit member 13, the second circuit member 16, and the like.
  • the crimping temperature at the time of temporary crimping may be, for example, 50 to 90 ° C.
  • the crimping pressure at the time of temporary crimping may be, for example, 0.5 to 1.5 MPa.
  • the crimping time at the time of temporary crimping may be, for example, 0.5 to 1.5 seconds.
  • the first circuit member 13 and the second circuit member 16 are heated while heating the first circuit member 13, the adhesive film 1a, and the second circuit member 16.
  • the first circuit member 13 and the second circuit member 16 are thermocompression-bonded to each other.
  • the second adhesive layer 3 has a flowable uncured thermosetting component
  • the second electrodes 15 are connected to each other. It flows so as to fill the voids of the above, and is cured by the above heating.
  • the first adhesive layer 2 has a flow rate of 130 to 250%, the conductive particles hardly flow during thermocompression bonding, and the film shape of the first adhesive layer 2 is maintained.
  • the temperature and time at the time of thermocompression bonding are temperatures at which the adhesive film 1a can be sufficiently cured and the first circuit member 13 and the second circuit member 16 can be adhered to each other.
  • the thermocompression bonding temperature (the maximum temperature reached by the adhesive film 1a) may be, for example, 150 to 200 ° C.
  • the thermocompression bonding time may be, for example, 4 to 7 seconds.
  • the pressurization is not particularly limited as long as it does not damage the adherend, and may be, for example, 20 to 80 MPa in terms of the area-equivalent pressure of the adhesive film 1a.
  • circuit connection structure of one embodiment and the method for manufacturing the same have been described above, the circuit connection structure of the present invention is not limited to the above embodiment.
  • the circuit connection structure 10b shown in FIG. 6 is a circuit connection structure except that the circuit connection portion 17b has a third resin cured layer 20 on the side opposite to the second resin cured layer 19 of the first resin cured layer 18. It has the same configuration as 10a.
  • the third resin cured layer 20 is a layer formed by curing the third adhesive layer 6 in the adhesive film 1b, and contains a cured product of the components in the third adhesive layer 6.
  • the third resin cured layer 20 has a chevron shape so as to fill the space between the first circuit member 13 and the first resin cured layer 18 between the adjacent electrode connecting portions 21.
  • a varnish-like first adhesive composition (first varnish composition) by mixing each component shown in Table 1 with 2-butanone (methyl ethyl ketone) in the blending amount (unit: parts by mass) shown in the same table. 1 to 6 were prepared respectively. Further, by mixing each component shown in Table 2 with 2-butanone (methyl ethyl ketone) in the blending amount (unit: parts by mass) shown in the same table, a varnish-like second adhesive composition (second varnish composition) is formed. Thing) 1 was prepared. In addition, "-" in the table means not compounded.
  • Sun Aid SI-60 manufactured by Sanshin Chemical Co., Ltd.
  • Thermal acid generator ⁇ Sun Aid SI-60 (aromatic sulfonium salt, manufactured by Sanshin Kagaku Co., Ltd.)
  • Inorganic filler -Silica particle 1 (SE-2050, manufactured by Admatex, average particle size: 500 nm)
  • -Silica particles 2 YA-050C, manufactured by Admatex, average particle size: 50 nm
  • Conductive particles -The conductive particles produced in Production Example 1 below (average particle size: 3.8 ⁇ m, maximum particle size: 4.0 ⁇ m, specific gravity: 2.6).
  • ⁇ Production example 1> (Preparation of conductive particles) A layer made of nickel was formed on the surface of the crosslinked polystyrene particles so that the thickness of the layer was 0.1 ⁇ m. In this way, conductive particles having an average particle size of 3.8 ⁇ m, a maximum particle size of 4.0 ⁇ m, and a specific gravity of 2.6 were obtained.
  • the first adhesive films 1 to 7 were prepared by using the first varnish compositions 1 to 6 obtained above, respectively.
  • the first varnish compositions 1 and 3 to 6 were used for producing the first adhesive films 1, 4 to 7, respectively, and the first varnish composition was used for producing the first adhesive films 2 and 3, respectively.
  • the thing 2 was used.
  • the first varnish composition is placed on a PET film (manufactured by Toyobo Film Solutions Co., Ltd.) having a thickness of 38 ⁇ m, the layer thickness after drying is 3 ⁇ m, and the number of conductive particles is 22000 particles / mm 2 .
  • the film was formed so as to be.
  • the obtained coating film was dried in an oven at 60 ° C. for 3 minutes.
  • the coating film after drying (first).
  • the layer made of the adhesive composition) was irradiated with ultraviolet rays using an ultraviolet irradiation device.
  • the irradiation amount of ultraviolet rays was 3000 mJ / cm 2 when the first adhesive films 1, 2, 4, 6 and 7 were produced, and 2400 mJ / cm 2 when the first adhesive film 3 was produced.
  • the photocurable component in the layer made of the first adhesive composition was cured to obtain the first adhesive layer.
  • the first varnish composition 4 is used (at the time of producing the first adhesive film 5)
  • the above-mentioned ultraviolet irradiation is not performed, and the dried coating film (layer composed of the first adhesive composition) is used.
  • the first adhesive layer was used as the first adhesive layer.
  • the first adhesive films 1 to 7 having the first adhesive layer were obtained.
  • the thickness of the first adhesive layer was 2 ⁇ m in each case. Since the thickness of the first adhesive layer is smaller than the thickness (diameter) of the conductive particles, the thickness of the conductive particles is reflected when the thickness of the layer is measured using a contact type thickness gauge. The thickness of the area where the conductive particles are present is measured. Therefore, after producing a circuit connection adhesive film having a two-layer structure in which the first adhesive layer and the second adhesive layer are laminated, the first adhesive is located at a separated portion of adjacent conductive particles. The thickness of the layer was measured.
  • an adhesive film for circuit connection is sandwiched between two pieces of glass (thickness: about 1 mm), and 100 g of bisphenol A type epoxy resin (trade name: JER811, manufactured by Mitsubishi Chemical Co., Ltd.) and a curing agent (cure agent) ( Product name: Epomount curing agent, manufactured by Refine Tech Co., Ltd.)
  • the resin composition was cast with 10 g.
  • the cross section is polished using a polishing machine, and a scanning electron microscope (SEM, trade name: SU-8000, manufactured by Hitachi High-Tech Science Co., Ltd.) is used to perform the first section located at the separated portion of the adjacent conductive particles.
  • SEM scanning electron microscope
  • the second adhesive film 1 was prepared using the second varnish composition 1 obtained above.
  • the second varnish composition 1 was formed on a PET film (manufactured by Toyobo Film Solutions Co., Ltd.) having a thickness of 38 ⁇ m so that the layer thickness after drying was 12 ⁇ m.
  • the obtained coating film was dried in an oven at 60 ° C. for 3 minutes.
  • a second adhesive layer (a layer composed of the second adhesive composition) was formed, and a second adhesive film including the second adhesive layer was obtained.
  • the minimum melt viscosity of the second adhesive layer was measured by the following method. Specifically, first, the second adhesive film was laminated with a roll laminator while heating at 40 ° C., so that a plurality of second adhesive layers were laminated so that the total thickness was 400 ⁇ m. Then, it was cut into 0.8 cm ⁇ to obtain a test piece. Next, the obtained test piece was measured for melt viscosity using a melt viscosity measuring device (trade name: ARES-G2, manufactured by TA Instruments). The measurement conditions were measurement temperature: 0 to 200 ° C., temperature rise rate: 10 ° C./min, frequency: 10 Hz, strain: 0.5%. The minimum melt viscosity was 1000 Pa ⁇ s.
  • the evaluation adhesive film is applied from the first adhesive layer side to the cover glass manufactured by Matsunami Glass Industry (thickness 0. Placed on a 15 mm, width 18 mm, depth 18 mm), using a thermal crimping device LD-06 manufactured by Ohashi Seisakusho, the second adhesive layer side under the conditions of a crimping temperature of 60 ° C., a crimping pressure of 1 MPa, and a crimping time of 0.1 s.
  • a temporary fixing body (cover glass / evaluation adhesive film / PET film) was obtained by heat-pressing from the above.
  • the crimping temperature is the temperature reached when crimping for 1 second
  • the crimping pressure is the area-converted pressure of the evaluation adhesive film.
  • a cover glass manufactured by Matsunami Glass Industry Co., Ltd. (thickness 0.15 mm, width 18 mm, depth 18 mm) is placed on the second adhesive layer.
  • the laminate was thermocompression-bonded from the second adhesive layer side under the conditions of a crimping temperature of 170 ° C., a crimping pressure of 80 MPa, and a crimping time of 5 s to obtain a crimped body. rice field.
  • the crimping temperature is the maximum temperature reached by the evaluation adhesive film
  • the crimping pressure is the area-converted pressure of the evaluation adhesive film.
  • a dummy sample (the same laminate as the evaluation laminate) is prepared separately, and a thin temperature sensor (rationalization) is provided between the adhesive film of the dummy sample and the cover glass on the first adhesive layer side. It was adjusted by hot-pressing with ST-50) manufactured by Kogyo Co., Ltd. sandwiched between them and measuring the maximum temperature reached of the adhesive film in the dummy sample in advance.
  • circuit connection structure (Manufacturing and evaluation of circuit connection structure) Using the circuit connection adhesive films of Examples 1 to 5 and Comparative Examples 1 and 2 obtained above, a circuit connection structure is produced by the following method, and at the time of producing the circuit connection structure, the circuit connection is used. The transferability of the adhesive film was evaluated. First, a circuit board having an ITO circuit electrode (pattern width 31 ⁇ m, space between electrodes 7 ⁇ m) formed on the surface of a glass substrate (Corning: # 1737, 38 mm ⁇ 28 mm, thickness 0.3 mm) was prepared.
  • the circuit connection adhesive film is cut into a rectangular shape of 2.0 mm ⁇ 23 mm, the PET film on the first adhesive layer side of the circuit connection adhesive film is peeled off, and then the circuit connection adhesive film No. 1 is used.
  • the circuit connection adhesive film was temporarily pressure-bonded to the circuit board so that the adhesive layer of No. 1 was in contact with the surface of the circuit board on which the circuit electrodes were formed.
  • Temporary crimping was performed by heating and pressurizing the circuit connection adhesive film for 1 second under the conditions of the measured maximum temperature of the circuit connection adhesive film of 60 ° C. and the adhesive film area conversion pressure of 1 MPa. After temporary crimping, the PET film on the second adhesive layer side was pinched with tweezers and peeled off from the second adhesive layer.
  • transferability A floating occurs between the circuit connection adhesive film and the glass substrate, or the circuit
  • transferability B The case where the connecting adhesive film was completely peeled off from the glass substrate.
  • an IC chip in which the bump electrodes are arranged (outer diameter 2 mm ⁇ 20 mm, thickness 0.3 mm, bump electrode area 840 ⁇ m 2 (length 70 ⁇ m ⁇ width 12 ⁇ m), space between bump electrodes 12 ⁇ m, bump electrode height 15 ⁇ m) is prepared.
  • After aligning the bump electrode of the IC chip with the circuit electrode of the glass substrate heat for 5 seconds under the conditions of the measured maximum reached temperature of 130 ° C. of the adhesive film for circuit connection and the area conversion pressure of 40 MPa at the bump electrode. And pressure was applied to attach the second adhesive layer to the IC chip. As a result, a circuit connection structure was obtained.
  • connection resistance The resistance value between the facing electrodes of the circuit connection structure (between the bump electrode and the circuit electrode) was measured by a four-terminal measurement method using a multimeter (MLR21, manufactured by Kusumoto Kasei Co., Ltd.), and 14 points were measured. The connection resistance was evaluated by comparing the average values of the measured values.
  • the circuit connection structure was polished to expose the cross section of the circuit connection structure in the opposite direction.
  • the exposed surface is observed with a scanning electron microscope (SEM, trade name: SU-8000), and the conductive particles observed between the adjacent bump electrodes (between the connection portion between the bump electrode and the circuit electrode) are adjacent to each other.
  • SEM scanning electron microscope
  • the distance between the centers of the conductive particles to be measured is measured. The longer the distance between adjacent particles, the less the risk of short circuit due to connection, and the insulation reliability can be ensured.
  • the average value of the center-to-center distance was taken as the post-mounting particle distance.

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  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
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PCT/JP2021/047653 2020-12-25 2021-12-22 回路接続用接着剤フィルム、並びに、回路接続構造体及びその製造方法 Ceased WO2022138747A1 (ja)

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Publication number Priority date Publication date Assignee Title
US20230108567A1 (en) * 2020-07-30 2023-04-06 Furukawa Electric Co., Ltd. Adhesive composition and film-like adhesive, and semiconductor package using film-like adhesive and producing method thereof
WO2025063142A1 (ja) * 2023-09-19 2025-03-27 株式会社レゾナック 接着剤組成物、接着剤フィルム、積層体及び回路接続構造体の製造方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003187885A (ja) * 2001-12-20 2003-07-04 Sony Corp 異方性導電フィルムおよび異方性導電フィルムの製造方法ならびに電子部品の実装体
WO2019050006A1 (ja) * 2017-09-11 2019-03-14 日立化成株式会社 回路接続用接着剤フィルム及びその製造方法、回路接続構造体の製造方法、並びに、接着剤フィルム収容セット

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JP3656768B2 (ja) 1995-02-07 2005-06-08 日立化成工業株式会社 接続部材および該接続部材を用いた電極の接続構造並びに接続方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003187885A (ja) * 2001-12-20 2003-07-04 Sony Corp 異方性導電フィルムおよび異方性導電フィルムの製造方法ならびに電子部品の実装体
WO2019050006A1 (ja) * 2017-09-11 2019-03-14 日立化成株式会社 回路接続用接着剤フィルム及びその製造方法、回路接続構造体の製造方法、並びに、接着剤フィルム収容セット

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20230108567A1 (en) * 2020-07-30 2023-04-06 Furukawa Electric Co., Ltd. Adhesive composition and film-like adhesive, and semiconductor package using film-like adhesive and producing method thereof
WO2025063142A1 (ja) * 2023-09-19 2025-03-27 株式会社レゾナック 接着剤組成物、接着剤フィルム、積層体及び回路接続構造体の製造方法

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