WO2022088116A1 - Peinture aqueuse super résistante aux intempéries, son procédé de préparation et son utilisation - Google Patents

Peinture aqueuse super résistante aux intempéries, son procédé de préparation et son utilisation Download PDF

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Publication number
WO2022088116A1
WO2022088116A1 PCT/CN2020/125597 CN2020125597W WO2022088116A1 WO 2022088116 A1 WO2022088116 A1 WO 2022088116A1 CN 2020125597 W CN2020125597 W CN 2020125597W WO 2022088116 A1 WO2022088116 A1 WO 2022088116A1
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WO
WIPO (PCT)
Prior art keywords
parts
water
agent
based paint
paint
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Application number
PCT/CN2020/125597
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English (en)
Chinese (zh)
Inventor
袁洪青
Original Assignee
河北比尔尼克新材料科技股份有限公司
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Application filed by 河北比尔尼克新材料科技股份有限公司 filed Critical 河北比尔尼克新材料科技股份有限公司
Priority to PCT/CN2020/125597 priority Critical patent/WO2022088116A1/fr
Publication of WO2022088116A1 publication Critical patent/WO2022088116A1/fr

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes

Definitions

  • the invention relates to a water-based paint, a preparation method and an application, in particular to a super-weather-resistant water-based paint, a preparation method and an application thereof, and belongs to the field of coatings.
  • solvent-based coatings contain a large amount of volatile organic solvents (VOCs), which are discharged into the atmosphere during use, which not only damages the atmospheric environment, but also endangers people's health. At the same time, it also wastes resources and wastes energy.
  • VOCs volatile organic solvents
  • water-based coatings, powder coatings, high-solid coatings and radiation-cured coatings are generally referred to as environmentally friendly coatings.
  • Coatings based on water-soluble resins or water-dispersible resins, including synthetic polymer emulsions, are called water-based coatings. Therefore, water-based coatings are also often referred to as water-based coatings. Coatings based on synthetic polymer emulsions are called water-based coatings.
  • the present invention provides a kind of ultra-weather-resistant water-based paint and its preparation method and application, specifically adopt the following technical scheme:
  • a super weather-resistant water-based paint comprising the following raw materials in parts by weight:
  • methyl etherified amino resin 20-30 parts of water-based saturated polyester resin, 20-30 parts of water-based polyether modified silicone resin, 15-20 parts of color paste, 3-5 parts of defoamer, leveling 2-5 parts of agent, 2-10 parts of wetting agent, 3-10 parts of dispersant, 5-10 parts of adhesion promoter.
  • it includes the following raw materials by weight: 30-37 parts of methyl etherified amino resin, 20-27 parts of water-based saturated polyester resin, 20-27 parts of water-based polyether-modified silicone resin, and 15-17 parts of color paste , 3-5 parts of defoamer, 2-5 parts of leveling agent, 2-7 parts of wetting agent, 3-7 parts of dispersant, and 5-7 parts of adhesion promoter.
  • it includes the following raw materials in parts by weight: 30-35 parts of methyl etherified amino resin, 20-25 parts of water-based saturated polyester resin, 20-25 parts of water-based polyether-modified silicone resin, and 15-16 parts of color paste , 3-4 parts of defoamer, 2-3 parts of leveling agent, 2-5 parts of wetting agent, 3-5 parts of dispersant, and 5-6 parts of adhesion promoter.
  • the color paste is an inorganic color paste.
  • the defoamer is TSA-10A;
  • the leveling agent is AFCONA-3777;
  • Wetting agent is SINPOLS530;
  • the dispersant is XN3800;
  • the adhesion promoter was TL-BPA.
  • the present invention also provides the preparation method of the above-mentioned super weather-resistant water-based paint, comprising the following steps:
  • step 2) the stirring speed is 1000-1200 rpm, and the stirring time is 20-30 minutes.
  • step 3 the rotating speed of continuous stirring is 200-300 rpm, and the stirring time is 5-10 minutes.
  • step 4) the operation of adding defoaming agent, leveling agent, wetting agent, dispersing agent, and adhesion promoter also includes the operation of stirring while adding.
  • the present invention also provides the application of the above-mentioned super weather-resistant water-based paint on a coil.
  • the beneficial effects of the present invention are that the present invention uses water as a solvent, is odorless, saves a lot of resources, does not contain volatile harmful substances such as benzene, xylene, ethane, formaldehyde, etc., has excellent anti-corrosion performance, good overcoating performance, radiation resistance, and non-combustibility. It does not explode, eliminates fire hazards during construction and storage, reduces air pollution, and can be constructed as usual in a closed environment. It can be directly stirred without any grinding procedure, and the preparation method is simple and reliable. It is widely used on the coil material, can be constructed in a large area outdoors, and the method is simple and easy to construct (spraying, brushing, rolling, electrostatic spraying, etc.). The coating tools can be washed directly with water, which can greatly reduce the damage to the construction workers.
  • methyl etherified amino resin model M12-80 the manufacturer is Tianjin Development Zone Guolong Chemical Co., Ltd.;
  • Water-based saturated polyester resin model W6050 the manufacturer is Tianjin Development Zone Guolong Chemical Co., Ltd.;
  • Waterborne polyether modified silicone resin model HL5010 the manufacturer is Anshan Huihong New Material Chemical Co., Ltd.;
  • the defoamer model is TSA-10A, and the manufacturer is Jiangsu Tengda Auxiliary Co., Ltd.;
  • leveling agent is AFCONA-3777, and the manufacturer is Haimen Efcona Co., Ltd.;
  • the wetting agent model is SINPOLS530, and the manufacturer is Shanghai Zhongjihang Chemical Co., Ltd.;
  • the dispersant model is XN3800, and the manufacturer is Shanghai Zhongjihang Chemical Co., Ltd.;
  • the model of adhesion promoter is TL-BPA, and the manufacturer is Okte Chemical Co., Ltd.
  • the preparation method of super weather-resistant water-based paint comprises the following steps:
  • methyl etherified amino resin 30g of water-based saturated polyester resin, 30g of water-based polyether modified silicone resin, 20g of color paste, 5g of defoamer, 5g of leveling agent, 10g of wetting agent, 10g of dispersant, Adhesion promoter 10g weighs the raw material;
  • the preparation method of super weather-resistant water-based paint comprises the following steps:
  • the preparation method of super weather-resistant water-based paint comprises the following steps:
  • methyl etherified amino resin 38g water-based saturated polyester resin 20g, water-based polyether modified silicone resin 28g, color paste 15g, defoamer 5g, leveling agent 5g, wetting agent 2g, dispersant 3g, Adhesion promoter 8g weighs the raw material;
  • the preparation method of super weather-resistant water-based paint comprises the following steps:
  • methyl etherified amino resin 37g water-based saturated polyester resin 20g, water-based polyether modified silicone resin 27g, color paste 15g, defoamer 5g, leveling agent 5g, wetting agent 2g, dispersant 7g, Adhesion promoter 7g weighs the raw material;
  • the preparation method of super weather-resistant water-based paint comprises the following steps:
  • methyl etherified amino resin 30g water-based saturated polyester resin 26g, water-based polyether modified silicone resin 26g, color paste 16.5g, defoamer 3g, leveling agent 4g, wetting agent 2g, dispersant 6g , the adhesion promoter 6g weighs the raw material;
  • the preparation method of super weather-resistant water-based paint comprises the following steps:
  • methyl etherified amino resin 35g water-based saturated polyester resin 25g, water-based polyether modified silicone resin 20g, color paste 16g, defoamer 4g, leveling agent 3g, wetting agent 2g, dispersant 3g, Adhesion promoter 6g weighs the raw material;
  • the performance detection is carried out to the prepared super weather-resistant water-based paint of the above-described embodiment, and the detection items and the results are as follows:
  • the water-based paint of the present invention is a uniform and non-hard-block water-based liquid product with low fineness, high gloss and hardness, and excellent in blocking resistance, scratch resistance, water resistance, alkali resistance and solvent resistance.
  • MDL means detection limit
  • ND means not detected.
  • the water-based paint of the present invention does not contain soluble heavy metal elements such as lead, arsenic, palladium, cadmium, chromium and mercury, nor does it contain soluble pollution elements such as selenium, and the water-based paint of the present invention is safe and environmentally friendly, and has no pollution.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

Peinture aqueuse super résistante aux intempéries, son procédé de préparation et son utilisation. La peinture comprend une résine amino méthylée, une résine de polyester saturée aqueuse, une résine d'organosilicium modifiée par polyéther et aqueuse, une pâte de couleur, un agent antimousse, un agent d'étalement, un agent mouillant, un agent dispersant et un promoteur d'adhésion. La peinture comprend de l'eau en tant que solvant, est inodore, permet d'économiser une grande quantité de ressources, et ne contient pas de substances dangereuses volatiles telles que le benzène, le xylène, l'éthane et le formaldéhyde. La peinture présente une excellente résistance à la corrosion et de bonnes performances de surpeinture, et est résistante aux rayonnements, ininflammable et non explosive, ce qui élimine le risque d'incendie lors de la construction et du stockage associés, et ce qui réduit la pollution de l'atmosphère. La peinture peut être appliquée en construction dans un environnement fermé comme à l'accoutumée, c.-à-d., elle peut être directement agitée sans procédure de broyage, et son procédé de préparation est simple et fiable. La peinture est largement appliquée sur des matériaux enroulés et peut être appliquée en construction dans de grandes zones extérieures. Le procédé est simple et facile à construire, et la peinture présente une adhérence élevée à la surface du matériau enroulé, une résistance aux intempéries élevée et des performances d'utilisation simples. L'outil de revêtement peut être directement nettoyé avec de l'eau, ce qui réduit considérablement les dommages aux travailleurs de la construction.
PCT/CN2020/125597 2020-10-30 2020-10-30 Peinture aqueuse super résistante aux intempéries, son procédé de préparation et son utilisation WO2022088116A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/CN2020/125597 WO2022088116A1 (fr) 2020-10-30 2020-10-30 Peinture aqueuse super résistante aux intempéries, son procédé de préparation et son utilisation

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Application Number Priority Date Filing Date Title
PCT/CN2020/125597 WO2022088116A1 (fr) 2020-10-30 2020-10-30 Peinture aqueuse super résistante aux intempéries, son procédé de préparation et son utilisation

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WO2022088116A1 true WO2022088116A1 (fr) 2022-05-05

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116239811A (zh) * 2023-03-03 2023-06-09 长沙荣思达科技有限公司 一种户外高耐候功能膜及制备方法

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04110367A (ja) * 1990-08-31 1992-04-10 Toyo Ink Mfg Co Ltd 塗料組成物
CN101429319A (zh) * 2008-12-12 2009-05-13 重庆斯耐博涂料有限公司 水性丙烯酸改性饱和聚酯、其制备方法及水性烘烤铝粉漆
US20100210745A1 (en) * 2002-09-09 2010-08-19 Reactive Surfaces, Ltd. Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes
CN102382556A (zh) * 2011-09-19 2012-03-21 中华制漆(深圳)有限公司 抗冲击耐水洗的烤漆涂料及其制备方法和应用
CN102746725A (zh) * 2012-06-29 2012-10-24 宝山钢铁股份有限公司 硅钢水溶性环保极厚绝缘涂层及其制备方法
CN106280921A (zh) * 2016-08-25 2017-01-04 浙江港流高分子科技有限公司 一种高温耐磨卷材及其制备方法
CN107033727A (zh) * 2017-06-14 2017-08-11 合肥市旺友门窗有限公司 一种用于门窗的隔热抗氧化涂料及其制备方法
CN108250917A (zh) * 2018-01-22 2018-07-06 河北晨阳工贸集团有限公司 一种高耐候耐沾污清漆及其制备方法和应用
CN109504265A (zh) * 2018-12-03 2019-03-22 天津梓明涂料制造有限公司 一种适用于汽车轮毂的水性涂料
CN109627879A (zh) * 2018-12-07 2019-04-16 中山大学 一种功能纳米散热涂料及其制备方法和应用

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04110367A (ja) * 1990-08-31 1992-04-10 Toyo Ink Mfg Co Ltd 塗料組成物
US20100210745A1 (en) * 2002-09-09 2010-08-19 Reactive Surfaces, Ltd. Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes
CN101429319A (zh) * 2008-12-12 2009-05-13 重庆斯耐博涂料有限公司 水性丙烯酸改性饱和聚酯、其制备方法及水性烘烤铝粉漆
CN102382556A (zh) * 2011-09-19 2012-03-21 中华制漆(深圳)有限公司 抗冲击耐水洗的烤漆涂料及其制备方法和应用
CN102746725A (zh) * 2012-06-29 2012-10-24 宝山钢铁股份有限公司 硅钢水溶性环保极厚绝缘涂层及其制备方法
CN106280921A (zh) * 2016-08-25 2017-01-04 浙江港流高分子科技有限公司 一种高温耐磨卷材及其制备方法
CN107033727A (zh) * 2017-06-14 2017-08-11 合肥市旺友门窗有限公司 一种用于门窗的隔热抗氧化涂料及其制备方法
CN108250917A (zh) * 2018-01-22 2018-07-06 河北晨阳工贸集团有限公司 一种高耐候耐沾污清漆及其制备方法和应用
CN109504265A (zh) * 2018-12-03 2019-03-22 天津梓明涂料制造有限公司 一种适用于汽车轮毂的水性涂料
CN109627879A (zh) * 2018-12-07 2019-04-16 中山大学 一种功能纳米散热涂料及其制备方法和应用

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116239811A (zh) * 2023-03-03 2023-06-09 长沙荣思达科技有限公司 一种户外高耐候功能膜及制备方法

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