WO2022057074A1 - Chemical thinning process and device for producing flexible glass coiled material by using continuous method - Google Patents

Chemical thinning process and device for producing flexible glass coiled material by using continuous method Download PDF

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WO2022057074A1
WO2022057074A1 PCT/CN2020/129686 CN2020129686W WO2022057074A1 WO 2022057074 A1 WO2022057074 A1 WO 2022057074A1 CN 2020129686 W CN2020129686 W CN 2020129686W WO 2022057074 A1 WO2022057074 A1 WO 2022057074A1
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chemical thinning
flexible glass
finished
chemical
drum
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PCT/CN2020/129686
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French (fr)
Chinese (zh)
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徐强
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徐强
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C15/00Surface treatment of glass, not in the form of fibres or filaments, by etching
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C23/00Other surface treatment of glass not in the form of fibres or filaments

Definitions

  • the invention relates to the field of flexible glass coil processing, in particular to a chemical thinning process and a device for producing a flexible glass coil by a continuous method.
  • Flexible glass refers to glass with a thickness of less than or equal to 0.12mm. Flexible glass belongs to the category of ultra-thin glass, and its preparation method is often improved on the basis of the preparation method of ultra-thin glass.
  • the preparation methods of flexible glass mainly include physical methods and chemical thinning methods.
  • the purpose of the present invention is to solve the shortcoming of low production efficiency in the production of flexible glass at the present stage, and propose a chemical thinning process for producing flexible glass coils by a continuous method.
  • the present invention provides a chemical thinning process for producing a flexible glass coil by a continuous method, and the specific technical scheme is as follows:
  • the flexible glass coil wound on the semi-finished drum can be thinned to any required thickness through chemical thinning grooves and chemical etching.
  • the obtained flexible glass coil with preset thickness is wound on the finished drum. Realize continuous production; among them, the speed of the semi-finished product drum and the finished product drum can be adjusted; after drying, the finished flexible glass with the required thickness is obtained.
  • 0.12mm thick glass can be chemically thinned to 0.03mm.
  • the thickness of the thinning can be controlled by speed, temperature, and potion concentration. Specifically, if the speed is fast, the thinning will be slow; if the temperature is high, the thinning will be fast; if the concentration of the liquid medicine is high, the thinning will be fast.
  • the flexible glass coil on the semi-finished drum is etched through the chemical thinning groove by pulling from one side of the chemical thinning groove to the finished barrel on the opposite side of the chemical thinning groove.
  • Another object of the present invention is to provide a chemical thinning groove with a chemical thinning function in a chemical thinning process.
  • the present invention provides a chemical thinning device, comprising a chemical thinning tank, a semi-finished drum located on one side of the chemical thinning tank, and a finished drum located on the other side of the chemical thinning tank, so
  • the semi-finished product drum is used for winding the semi-finished product of the flexible glass coil
  • the finished product drum is used for winding the finished flexible glass coil.
  • the settling baffle at the bottom of the thin tank, the limit roller shaft located in the middle of the chemical thinning tank, and the corrosion-resistant heating rod located at the bottom of the chemical thinning tank, make the flexible glass coil on the semi-finished drum from the chemical thinning tank.
  • continuous production is achieved by pulling the etched through the chemical thinning groove to the finished cartridge on the opposite side of the chemical thinning groove.
  • both the semi-finished product drum and the finished product drum are provided with speed regulating motors.
  • the chemical thinning device further comprises a filter tank and a circulating water pump, and the circulating water pump is connected to the chemical thinning tank through the filter tank.
  • the chemical thinning tank is made of acid and alkali resistant plastic.
  • the chemical thinning device provided by the present invention can also be used for cleaning the glass coil wound on the drum. That is, the same set of devices can also be used for cleaning.
  • FIG. 1 is a schematic structural diagram of a chemical thinning device for continuous production of flexible glass coils according to the present invention.
  • FIG. 1 it is an embodiment of a chemical thinning device for continuous production of flexible glass coils provided by the present invention, comprising a speed regulating motor 1, a chemical thinning groove 4 made of acid and alkali-resistant plastic, Inlet 3 and outlet 10 for circulating chemical liquid, sedimentation baffle 6 at the bottom of the chemical thinning tank, limit roller 5 located in the middle of the chemical thinning tank, corrosion-resistant heating rod 7 located at the bottom of the chemical thinning tank , filter tank 9, circulating water pump 8, semi-finished material barrel 2, finished material barrel 11.
  • the speed-adjustable motor 1 can choose a speed-adjustable stepping motor to control the speed of thinning; the semi-finished product barrel 2 is placed on the flexible glass coil that has not been thinned, and the thinned flexible glass coil is set On the finished reel 11; the acid chemical etching solution enters the chemical thinning tank through the inlet 3, and flows out of the acid chemical etching solution through the outlet 10, and the circulating process is powered by the circulating water pump 8; the limit roller shaft 5 is used to prevent glass The sheet floats up and down; the settling partition 6 is used to isolate the insolubles produced by etching; the heating rod 7 can heat the etching solution to speed up the etching process; the filter tank 9 is used to filter the insolubles produced by the etching.
  • the invention also provides a chemical thinning process for producing a flexible glass coil by a continuous method.
  • the flexible glass coil wound on a semi-finished drum is thinned to a preset thickness through a chemical thinning groove and chemical etching. , the obtained flexible glass coil with preset thickness is wound on the finished drum to realize continuous production.
  • the state of the flexible glass in the chemical thinning tank can be a horizontal lying state or a vertical state.
  • the semi-finished drum and the finished drum are speed-adjustable drums; the etched flexible glass is dried to obtain a flexible glass coil with a preset thickness; specifically, the flexible glass coil on the semi-finished drum is reduced from chemical One side of the thin groove is etched by pulling through the chemical thinning groove to the finished cartridge on the opposite side of the chemical thinning groove.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

A chemical thinning process for producing a flexible glass coiled material by using a continuous method. According to the chemical thinning process, a flexible glass coiled material wound around a semi-finished product roller (2) passes through a chemical thinning tank (4), is etched by means of a chemical agent and is thinned to a preset thickness; and the resulting flexible glass coiled material with the preset thickness is wound around a finished product roller (11), thereby realizing continuous production. The state of the glass in the chemical thinning tank (4) may be a flat laid-out state or a vertical state. Further provided is a corresponding chemical thinning device for producing the flexible glass coiled material by using the continuous method.

Description

一种连续法生产柔性玻璃卷材的化学减薄工艺及其装置A chemical thinning process and device for continuous production of flexible glass coils
相关申请的交叉引用CROSS-REFERENCE TO RELATED APPLICATIONS
本申请主张2020年9月18日提交的申请号为202010985301.X的中国发明专利申请的优先权,其内容通过引用的方式并入本申请中。This application claims the priority of the Chinese patent application for invention with application number 202010985301.X filed on September 18, 2020, the content of which is incorporated into this application by reference.
技术领域technical field
本发明涉及柔性玻璃卷材加工领域,具体涉及一种连续法生产柔性玻璃卷材的化学减薄工艺及其装置。The invention relates to the field of flexible glass coil processing, in particular to a chemical thinning process and a device for producing a flexible glass coil by a continuous method.
背景技术Background technique
传统玻璃是脆性材料,它们以板状或块体的形式存在,柔韧性很差,但其厚度一旦低于某个值,玻璃的可弯曲性和柔软性就显现出来。Traditional glass is brittle material, they exist in the form of plate or block, and the flexibility is very poor, but once its thickness falls below a certain value, the bendability and softness of glass show.
柔性玻璃是指厚度小于等于0.12mm的玻璃,柔性玻璃属于超薄玻璃范畴,它的制备方法往往是在超薄玻璃的制备方法基础上进行改进。Flexible glass refers to glass with a thickness of less than or equal to 0.12mm. Flexible glass belongs to the category of ultra-thin glass, and its preparation method is often improved on the basis of the preparation method of ultra-thin glass.
目前关于柔性玻璃的制备方法主要有物理方法和化学减薄法。At present, the preparation methods of flexible glass mainly include physical methods and chemical thinning methods.
而物理方法要制备0.1mm以下的玻璃,有相当大的难度。However, it is quite difficult to prepare glass below 0.1mm by physical method.
而目前的化学减薄法都是拿一片片的玻璃,来进行化学蚀刻,效率很低。However, the current chemical thinning method is to use pieces of glass for chemical etching, which is very inefficient.
发明内容SUMMARY OF THE INVENTION
本发明的目的是为了解决现阶段在生产柔性玻璃时存在的生产效率低的缺点,而提出的一种连续法生产柔性玻璃卷材的化学减薄工艺。The purpose of the present invention is to solve the shortcoming of low production efficiency in the production of flexible glass at the present stage, and propose a chemical thinning process for producing flexible glass coils by a continuous method.
为了实现上述目的,本发明提供的一种连续法生产柔性玻璃卷材的化学减薄工艺,具体技术方案如下:In order to achieve the above object, the present invention provides a chemical thinning process for producing a flexible glass coil by a continuous method, and the specific technical scheme is as follows:
卷绕于半成品滚筒上的柔性玻璃卷材,通过化学减薄槽,经过化学药剂的蚀刻,可减薄至任意要求的厚度,获得的预设厚度的柔性玻璃卷材卷绕于成品滚筒上,实现连续式生产;其中,半成品滚筒和成品滚筒均可调速;干燥后得到所需厚度的柔性玻璃成品。The flexible glass coil wound on the semi-finished drum can be thinned to any required thickness through chemical thinning grooves and chemical etching. The obtained flexible glass coil with preset thickness is wound on the finished drum. Realize continuous production; among them, the speed of the semi-finished product drum and the finished product drum can be adjusted; after drying, the finished flexible glass with the required thickness is obtained.
例如,0.12毫米厚的玻璃,通过化学减薄后可以达到0.03毫米。减薄的厚度可以通过速度、温度、药水浓度来控制。具体地,速度快,减薄慢;温度高,减薄快;药水浓度高,减薄 快。For example, 0.12mm thick glass can be chemically thinned to 0.03mm. The thickness of the thinning can be controlled by speed, temperature, and potion concentration. Specifically, if the speed is fast, the thinning will be slow; if the temperature is high, the thinning will be fast; if the concentration of the liquid medicine is high, the thinning will be fast.
较佳地,半成品滚筒上的柔性玻璃卷材,从化学减薄槽的一侧,通过牵引经过化学减薄槽的蚀刻,至化学减薄槽的相对侧的成品料筒。Preferably, the flexible glass coil on the semi-finished drum is etched through the chemical thinning groove by pulling from one side of the chemical thinning groove to the finished barrel on the opposite side of the chemical thinning groove.
本发明的另一目的在于提供化学减薄工艺中的具有化学减薄功能的化学减薄槽。Another object of the present invention is to provide a chemical thinning groove with a chemical thinning function in a chemical thinning process.
本发明提供了一种化学减薄装置,包括化学减薄槽、位于所述的化学减薄槽的一侧的半成品滚筒、以及位于所述的化学减薄槽的另一侧的成品滚筒,所述的半成品滚筒用于卷绕柔性玻璃卷材半成品,所述的成品滚筒用于卷绕柔性玻璃卷材成品,所述的化学减薄槽具有用于循环药液的进口和出口、位于化学减薄槽底部的沉降隔板、以及位于化学减薄槽中间的限位辊轴、位于化学减薄槽底部的耐腐蚀的加热棒,使得半成品滚筒上的柔性玻璃卷材从化学减薄槽的一侧,通过牵引经过化学减薄槽的蚀刻,至化学减薄槽的相对侧的成品料筒,实现连续式生产。The present invention provides a chemical thinning device, comprising a chemical thinning tank, a semi-finished drum located on one side of the chemical thinning tank, and a finished drum located on the other side of the chemical thinning tank, so The semi-finished product drum is used for winding the semi-finished product of the flexible glass coil, and the finished product drum is used for winding the finished flexible glass coil. The settling baffle at the bottom of the thin tank, the limit roller shaft located in the middle of the chemical thinning tank, and the corrosion-resistant heating rod located at the bottom of the chemical thinning tank, make the flexible glass coil on the semi-finished drum from the chemical thinning tank. On the opposite side of the chemical thinning groove, continuous production is achieved by pulling the etched through the chemical thinning groove to the finished cartridge on the opposite side of the chemical thinning groove.
较佳地,所述的半成品滚筒和成品滚筒均设置调速电机。Preferably, both the semi-finished product drum and the finished product drum are provided with speed regulating motors.
较佳地,所述的化学减薄装置还包括过滤槽和循环水泵,所述的循环水泵通过过滤槽与所述的化学减薄槽相连接。Preferably, the chemical thinning device further comprises a filter tank and a circulating water pump, and the circulating water pump is connected to the chemical thinning tank through the filter tank.
较佳地,所述的化学减薄槽由耐酸碱的塑料制成。Preferably, the chemical thinning tank is made of acid and alkali resistant plastic.
本发明提供的化学减薄装置也可以用作清洗卷绕于滚筒上的玻璃卷材。即,同样一套装置,也可以用于清洗作用。The chemical thinning device provided by the present invention can also be used for cleaning the glass coil wound on the drum. That is, the same set of devices can also be used for cleaning.
附图说明Description of drawings
图1为本发明的连续法生产柔性玻璃卷材的化学减薄装置的结构示意图。FIG. 1 is a schematic structural diagram of a chemical thinning device for continuous production of flexible glass coils according to the present invention.
具体实施方式detailed description
为了能够更清楚地描述本发明的技术内容,下面结合具体实施例来进行进一步的描述。In order to describe the technical content of the present invention more clearly, further description will be given below with reference to specific embodiments.
以下对本发明的优选实施例进行说明,应当理解,此处所描述的优选实施例仅用于说明和解释本发明,并不用于限定本发明。The preferred embodiments of the present invention will be described below, and it should be understood that the preferred embodiments described herein are only used to illustrate and explain the present invention, but not to limit the present invention.
如图1所示,为本发明提供的一种连续法生产柔性玻璃卷材的化学减薄装置的实施例,包括调速电机1、由耐酸碱的塑料制成的化学减薄槽4、用于循环药液的进口3和出口10、位于化学减薄槽底部的沉降隔板6、位于化学减薄槽中间的限位辊轴5、位于化学减薄槽底部的耐腐蚀的加热棒7、过滤槽9、循环水泵8、半成品料筒2、成品料筒11。As shown in FIG. 1, it is an embodiment of a chemical thinning device for continuous production of flexible glass coils provided by the present invention, comprising a speed regulating motor 1, a chemical thinning groove 4 made of acid and alkali-resistant plastic, Inlet 3 and outlet 10 for circulating chemical liquid, sedimentation baffle 6 at the bottom of the chemical thinning tank, limit roller 5 located in the middle of the chemical thinning tank, corrosion-resistant heating rod 7 located at the bottom of the chemical thinning tank , filter tank 9, circulating water pump 8, semi-finished material barrel 2, finished material barrel 11.
其中,调速电机1可以选择可调速步进电机,用于控制减薄的速度;半成品料筒2上放 置的是未经减薄的柔性玻璃卷材,减薄后的柔性玻璃卷材设置在成品卷料筒11上;酸性化学蚀刻液通过进口3进入化学减薄槽内,通过出口10流出酸性化学蚀刻液,该循环过程通过循环水泵8提供动力;限位辊轴5用于防止玻璃薄片上下漂浮;降沉隔板6用于隔离蚀刻产生的不溶物;加热棒7可以加热蚀刻液以加速蚀刻的进程;过滤槽9用于过滤蚀刻产生的不溶物。Among them, the speed-adjustable motor 1 can choose a speed-adjustable stepping motor to control the speed of thinning; the semi-finished product barrel 2 is placed on the flexible glass coil that has not been thinned, and the thinned flexible glass coil is set On the finished reel 11; the acid chemical etching solution enters the chemical thinning tank through the inlet 3, and flows out of the acid chemical etching solution through the outlet 10, and the circulating process is powered by the circulating water pump 8; the limit roller shaft 5 is used to prevent glass The sheet floats up and down; the settling partition 6 is used to isolate the insolubles produced by etching; the heating rod 7 can heat the etching solution to speed up the etching process; the filter tank 9 is used to filter the insolubles produced by the etching.
注:此装置配套的温控、电控、中和、水洗等常规设备,在此不一一说明。Note: The conventional equipment such as temperature control, electric control, neutralization, water washing, etc. matched with this device will not be explained one by one here.
本发明还提供了一种连续法生产柔性玻璃卷材的化学减薄工艺,卷绕于半成品滚筒上的柔性玻璃卷材,通过化学减薄槽,经过化学药剂的蚀刻,减薄至预设厚度,获得的预设厚度的柔性玻璃卷材卷绕于成品滚筒上,实现连续式生产。The invention also provides a chemical thinning process for producing a flexible glass coil by a continuous method. The flexible glass coil wound on a semi-finished drum is thinned to a preset thickness through a chemical thinning groove and chemical etching. , the obtained flexible glass coil with preset thickness is wound on the finished drum to realize continuous production.
在化学减薄槽中柔性玻璃的状态,可以是水平平躺状态,也可以是竖直状态。The state of the flexible glass in the chemical thinning tank can be a horizontal lying state or a vertical state.
其中,所述的半成品滚筒和成品滚筒均为可调速滚筒;蚀刻后的柔性玻璃经干燥后获得预设厚度的柔性玻璃卷材;具体地,半成品滚筒上的柔性玻璃卷材,从化学减薄槽的一侧,通过牵引经过化学减薄槽的蚀刻,至化学减薄槽的相对侧的成品料筒。Wherein, the semi-finished drum and the finished drum are speed-adjustable drums; the etched flexible glass is dried to obtain a flexible glass coil with a preset thickness; specifically, the flexible glass coil on the semi-finished drum is reduced from chemical One side of the thin groove is etched by pulling through the chemical thinning groove to the finished cartridge on the opposite side of the chemical thinning groove.
在此说明书中,本发明已参照其特定的实施例作了描述。但是,很显然仍可以作出各种修改和变换而不背离本发明的精神和范围。因此,说明书和附图应被认为是说明性的而非限制性的。In this specification, the invention has been described with reference to specific embodiments thereof. However, it will be evident that various modifications and changes can still be made without departing from the spirit and scope of the invention. Accordingly, the specification and drawings are to be regarded in an illustrative rather than a restrictive sense.

Claims (8)

  1. 一种连续法生产柔性玻璃卷材的化学减薄工艺,其特征在于,卷绕于半成品滚筒上的柔性玻璃卷材,通过化学减薄槽,经过化学药剂的蚀刻,减薄至预设厚度,获得的预设厚度的柔性玻璃卷材卷绕于成品滚筒上,实现连续式生产。A chemical thinning process for producing flexible glass coils by a continuous method, characterized in that, the flexible glass coils wound on a semi-finished drum are thinned to a preset thickness through chemical thinning grooves and chemical etching. The obtained flexible glass coil with preset thickness is wound on the finished drum to realize continuous production.
  2. 根据权利要求1所述的一种连续法生产柔性玻璃卷材的化学减薄工艺,其特征在于,所述的半成品滚筒和成品滚筒均为可调速滚筒。The chemical thinning process for continuous production of flexible glass coils according to claim 1, wherein the semi-finished product drum and the finished product drum are both speed-adjustable drums.
  3. 根据权利要求1所述的一种连续法生产柔性玻璃卷材的化学减薄工艺,其特征在于,蚀刻后的柔性玻璃经干燥后获得预设厚度的柔性玻璃卷材。The chemical thinning process for producing a flexible glass coil by a continuous method according to claim 1, wherein the etched flexible glass is dried to obtain a flexible glass coil with a preset thickness.
  4. 根据权利要求1所述的一种连续法生产柔性玻璃卷材的化学减薄工艺,其特征在于,半成品滚筒上的柔性玻璃卷材,从化学减薄槽的一侧,通过牵引经过化学减薄槽的蚀刻,至化学减薄槽的相对侧的成品料筒。The chemical thinning process for continuous production of flexible glass coils according to claim 1, wherein the flexible glass coils on the semi-finished drum are chemically thinned by pulling from one side of the chemical thinning groove. Etching of the groove to chemically thin the finished cartridge on the opposite side of the groove.
  5. 一种连续法生产柔性玻璃卷材的化学减薄装置,其特征在于,包括化学减薄槽、位于所述的化学减薄槽的一侧的半成品滚筒、以及位于所述的化学减薄槽的另一侧的成品滚筒,所述的半成品滚筒用于卷绕柔性玻璃卷材半成品,所述的成品滚筒用于卷绕柔性玻璃卷材成品,所述的化学减薄槽具有用于循环药液的进口和出口、位于化学减薄槽底部的沉降隔板、位于化学减薄槽中间的限位辊轴、以及位于化学减薄槽底部的耐腐蚀的加热棒,使得半成品滚筒上的柔性玻璃卷材从化学减薄槽的一侧,通过牵引经过化学减薄槽的蚀刻,至化学减薄槽的相对侧的成品料筒,实现连续式生产。A chemical thinning device for continuous production of flexible glass coils, characterized in that it comprises a chemical thinning tank, a semi-finished drum located on one side of the chemical thinning tank, and a chemical thinning tank located in the chemical thinning tank. The finished drum on the other side, the semi-finished drum is used for winding the semi-finished flexible glass coil material, the finished product drum is used for winding the finished flexible glass coil material, and the chemical thinning tank is used for circulating the liquid medicine. The inlet and outlet of the chemical thinning tank, the settling baffle at the bottom of the chemical thinning tank, the limit roller shaft in the middle of the chemical thinning tank, and the corrosion-resistant heating rod at the bottom of the chemical thinning tank, make the flexible glass roll on the semi-finished roll Continuous production is achieved by pulling the material from one side of the chemical thinning groove, through the etching of the chemical thinning groove, to the finished barrel on the opposite side of the chemical thinning groove.
  6. 根据权利要求5所述的连续法生产柔性玻璃卷材的化学减薄装置,其特征在于,所述的半成品滚筒和成品滚筒均设置调速电机。The chemical thinning device for continuous production of flexible glass coils according to claim 5, characterized in that both the semi-finished product drum and the finished product drum are provided with speed-regulating motors.
  7. 根据权利要求5所述的连续法生产柔性玻璃卷材的化学减薄装置,其特征在于,所述的化学减薄装置还包括过滤槽和循环水泵,所述的循环水泵通过过滤槽与所述的化学减薄槽相连接。The chemical thinning device for continuous production of flexible glass coils according to claim 5, wherein the chemical thinning device further comprises a filter tank and a circulating water pump, and the circulating water pump communicates with the connected to the chemical thinning tank.
  8. 根据权利要求5所述的一种连续法生产柔性玻璃卷材的化学减薄装置,其特征在于,所述的化学减薄槽由耐酸碱的塑料制成。The chemical thinning device for continuous production of flexible glass coils according to claim 5, wherein the chemical thinning tank is made of acid and alkali resistant plastics.
PCT/CN2020/129686 2020-09-18 2020-11-18 Chemical thinning process and device for producing flexible glass coiled material by using continuous method WO2022057074A1 (en)

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