WO2022051912A1 - Laval nozzle and manufacturing method therefor - Google Patents

Laval nozzle and manufacturing method therefor Download PDF

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Publication number
WO2022051912A1
WO2022051912A1 PCT/CN2020/114078 CN2020114078W WO2022051912A1 WO 2022051912 A1 WO2022051912 A1 WO 2022051912A1 CN 2020114078 W CN2020114078 W CN 2020114078W WO 2022051912 A1 WO2022051912 A1 WO 2022051912A1
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WIPO (PCT)
Prior art keywords
laval nozzle
oxygen
channel
cooling liquid
wall
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PCT/CN2020/114078
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French (fr)
Chinese (zh)
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李长鹏
张卿卿
吴琪
陈国锋
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西门子股份公司
西门子(中国)有限公司
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Application filed by 西门子股份公司, 西门子(中国)有限公司 filed Critical 西门子股份公司
Priority to CN202080103594.2A priority Critical patent/CN115989325A/en
Priority to PCT/CN2020/114078 priority patent/WO2022051912A1/en
Publication of WO2022051912A1 publication Critical patent/WO2022051912A1/en

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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/068Decarburising
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/072Treatment with gases

Definitions

  • the invention relates to the field of additive manufacturing, in particular to a Laval nozzle and a manufacturing method thereof.
  • the Laval nozzle 220 is a key element of the steelmaking furnace 300 , which is arranged at the lower end of the oxygen pipe 210 and is used to remove the molten steel 310 of the steelmaking furnace 300 by spraying the oxygen supplementary blowing amount.
  • impurities such as carbon, silicon, manganese and phosphorus.
  • the Laval nozzle 220 as the main element is used to act as the outlet of oxygen, and it has the precisely machined air outlet 222 to obtain the ideal flow and parameters, in addition, the Laval nozzle 220 has a first cooling liquid channel 224 and The second cooling liquid passage 226 , the first cooling liquid passage 224 and the second cooling liquid passage 226 have circulating cooling liquid in them to avoid overheating and damage of the Laval nozzle 220 .
  • the first cooling liquid channel 224 is used for serving as a cooling liquid inlet
  • the second cooling liquid channel 226 is used for serving as a cooling liquid outlet.
  • the Laval nozzle 220 is usually disposed close to the surface of the molten steel 310 whose temperature is greater than 2000 degrees Celsius. Due to the extremely high operating temperature, the cooling liquid inside the Laval nozzle 220 is not sufficient to keep the nozzle surface from melting or premature burnout. Among them, the grains of the copper forging may gradually grow, which may lead to degradation of the heat transfer coefficient and cooling efficiency of the Laval nozzle 220 . Degraded cooling efficiency can further increase the copper grain growth rate and cause rapid damage to the Laval nozzle 220 . The clogging of the molten steel 310 not only leads to corrosion of the Laval nozzle 220, but also further reduces its heat transfer coefficient and cooling efficiency.
  • Laval nozzles have a very low lifespan, usually oxygen nozzles are damaged and need to be replaced after 100 to 200 furnaces. Nozzle replacement is also troublesome. The nozzle tip to be replaced needs to be cut from the oxygen pipe 210 and re-welded with a new nozzle, which not only causes extra operating costs but also affects the normal production process. This also leads to material waste and affects regular steel production processes.
  • the Laval nozzle 220 is copper forged, which has a high density and small grain size, which ensures a higher thermal conductivity than cast copper.
  • the oxygen tube 210 is stainless steel and the Laval nozzle 220 is copper (the two are connected by welding.
  • the high temperature gradient and different thermal expansion rates of stainless steel and copper can cause welding along the oxygen tube 210 and the Laval nozzle 220
  • the stitches are cracked, which can lead to premature failure.
  • the Laval nozzle 220 cannot be repaired by compensating heating or coating due to the grown grain size and degraded thermal conductivity.
  • a first aspect of the present invention provides a Laval nozzle, wherein the Laval nozzle includes: a casing having a first accommodating space; a first cooling liquid channel disposed in the first accommodating space and having a cooling liquid inlet; a second cooling liquid channel, which is arranged in the first accommodating space and has a cooling liquid outlet, wherein the first cooling liquid channel and the second cooling liquid channel communicate with each other and have a circulating cooling liquid liquid; a first oxygen channel, which accommodates and transports oxygen to the air outlet of the Laval nozzle; an oxygen cavity, which is communicated with the first oxygen channel and transports oxygen for the first oxygen channel; a diffusion wall, It is arranged at the bottom of the Laval nozzle and extends laterally to the casing, a second oxygen channel, which is communicated with the first oxygen channel or the oxygen chamber, and the bottom opening of the second oxygen channel is laterally around.
  • the first oxygen channel passes through the second accommodating space and the diffusion wall, wherein the bottom opening of the first oxygen channel serves as the air outlet of the Laval nozzle.
  • a plurality of supporting walls are vertically arranged between the partition wall and the diffusion wall.
  • the support wall extends from the central region of the Laval nozzle to the periphery thereof.
  • the thickness of the diffusion wall ranges from 3 mm to 10 mm.
  • the diameter of the pore size of the diffusion wall ranges from 5 to 30 microns.
  • partition wall and the diffusion wall are made of metal.
  • partition wall and the diffusion wall are made of metallic copper.
  • a second aspect of the present invention provides a method for manufacturing a Laval nozzle, wherein an additive manufacturing process is used to manufacture the Laval nozzle according to the first aspect of the present invention.
  • the Laval nozzle is manufactured in a selective laser melting facility.
  • the Laval nozzle provided by the present invention has various cooling strategies, and integrates sweat cooling technology and traditional cooling liquid cooling, which can achieve better cooling efficiency and prolong service life.
  • the Laval nozzle provided by the present invention can reduce the grain size growth and the thermal conduction attenuation of the copper layer, and thus can achieve a longer working life.
  • the Laval nozzle provided by the present invention can protect the nozzle from possible clogging and corrosion, and further improve the life of the nozzle. Since the present invention adds a sweat cooling strategy to the traditional cooling strategy, the demand for cooling water is reduced, thus saving cooling water and energy consumption, and saving energy. At the same time, the present invention utilizes a small amount of oxygen as the working gas and cooling medium, and does not affect the normal working environment.
  • the diffusion layer of the present invention is provided with tiny pores therein as microchannels, the fabrication can be facilitated by an additive manufacturing process. Also, pore size and porosity can be adjusted by printing parameters for optimized cooling.
  • Fig. 1 is the structural representation of the oxygen delivery device in the steelmaking furnace
  • Figure 2 is a schematic cross-sectional view of a Laval nozzle of the prior art
  • Figure 3 is a comparison diagram of cooling efficiency using different cooling strategies
  • Fig. 4 is the principle schematic diagram of sweat cooling
  • FIG. 5 is a schematic cross-sectional view of a Laval nozzle according to an embodiment of the present invention.
  • the invention provides a Laval nozzle and a manufacturing method thereof.
  • the bottom of the nozzle adopts sweating and cooling technology.
  • a gas film is formed on the bottom surface.
  • the surface heat of the Laval nozzle is removed for cooling purposes.
  • the diffusion layer acts as an insulating layer and a cooling layer.
  • the oxygen flowing out through the microchannels of the diffusion layer can also blow the molten steel away.
  • the present invention can be manufactured by additive manufacturing technology, which can achieve high cooling efficiency and increase Laval nozzle life.
  • FIG. 3 is a comparison diagram of cooling efficiency using different cooling strategies.
  • commonly used cooling strategies include impingement cooling A, convective cooling B, perspiration cooling C, and full-film cooling D, where the abscissa of the coordinate system is the cooling air flow and the ordinate is the cooling efficiency.
  • the sweat cooling technology has the best cooling efficiency under the same cooling air flow, so the present invention chooses to adopt the sweat cooling strategy.
  • the direction of the arrow in FIG. 4 shows the flow direction of oxygen.
  • the cooling gas from the cooling pipes penetrates through the porous walls and forms a cooling gas barrier to protect the components from corrosion by high heat fluxes.
  • a small part of the working gas in the oxygen will be utilized as the coolant for the intended sweat cooling strategy, without the need for additional cooling medium and incurring additional costs, as well as avoiding the impact on the working environment.
  • sweat cooling requires only a small amount of cooling gas flow to form a barrier that does not hinder the normal operating flow conditions of Laval nozzles.
  • the gas barrier also protects the printhead from clogging or corrosion and further increases Laval nozzle life.
  • the Laval nozzle 100 includes a casing 160, a first cooling liquid channel 110, a second cooling liquid channel 120, a first oxygen channel 130, a plurality of air outlet holes 170a, and a second oxygen channel 140 , the partition wall 150 and the oxygen chamber 180 .
  • the housing 160 has a first accommodating space.
  • the first cooling liquid passage 110 is provided in the first accommodating space and has a cooling liquid inlet 110a.
  • the second cooling liquid channel 120 is disposed in the first accommodating space and has a cooling liquid outlet 120a, wherein the first cooling liquid channel 110 and the second cooling liquid channel 120 communicate with each other and have a circulating cooling liquid.
  • the first oxygen channel 130 accommodates and delivers oxygen to the air outlet of the Laval nozzle 100 ; the oxygen chamber 180 communicates with the first oxygen channel 130 and delivers oxygen for the first oxygen channel 130 ; the diffusion wall 170 is provided At the bottom of the Laval nozzle 100 and extending laterally to the casing 160, the second oxygen channel 140 communicates with the first oxygen channel 130 or the oxygen chamber 180, and the bottom of the second oxygen channel 140 opens to the The periphery extends laterally to the outer shell 160 to form a partition wall 150, wherein a second accommodating space is provided between the partition wall 150 and the diffusion wall 170, so that a small amount of oxygen can flow from the first oxygen channel 130 or all the
  • the oxygen chamber 180 is delivered to the second oxygen channel 140 and diffused through the plurality of air holes of the diffusion wall 170 in the second accommodating space.
  • first oxygen channel 130 passes through the second accommodating space and the diffusion wall 170 , wherein the bottom opening of the first oxygen channel 130 serves as the air outlet of the Laval nozzle 100 .
  • the Laval nozzle provided by the present invention is still directly cooled by the cooling liquid in the heat conduction mode through the high-density pure copper layer.
  • the additional diffusion layer added to the front surface of the Laval nozzle is supplemented by the dendritic cooling liquid channels and oxygen pipes in the first accommodation space, so as to achieve the purpose of sweat cooling.
  • the side walls of the dendritic coolant channels ensure the mechanical strength of the Laval nozzle, therefore, the coolant channels act as reinforcement.
  • the present invention would further control the cooling liquid channel and the oxygen channel based on optimized cooling and airflow effects.
  • the main cooling mechanism of the diffusion layer is not direct heat conduction, it is not necessary to consider the grain size and concentration as the influencing factors of thermal conductivity.
  • the barrier is protected from the high heat flux by the diffusion layer, so grain growth and degradation are significantly slower to maintain high thermal conductivity.
  • the Laval nozzle provided by the present invention has a porous diffusion layer and internal cooling channels, so it can be manufactured by additive manufacturing technology, and can be manufactured by adjusting the laser scanning strategy and printing parameters
  • the pure copper isolation layer and the porous metal copper diffusion layer of the Laval nozzle of the present invention can also adjust the size and porosity of the holes based on design requirements, so as to achieve the expected cooling effect.
  • a plurality of support walls 150a are vertically disposed between the partition wall 150 and the diffusion wall 170 .
  • the support wall 150a extends from the central region of the Laval nozzle 100 to the periphery thereof.
  • the diameters of the diffusion wall and the size of the pores are also selected specifically, wherein the thickness of the diffusion wall 170 ranges from 3 mm to 10 mm, and the diameter of the size of the pores of the diffusion wall 170 ranges from 5 to 30 mm. microns.
  • partition wall and the diffusion wall are made of metal.
  • the partition wall and the diffusion wall are made of metallic copper.
  • the improvement of cooling efficiency can reduce the requirements for the thermal conductivity of the separation wall and the diffusion wall, so that copper alloys that are more suitable for additive manufacturing processes can be selected instead of pure copper materials in material selection.
  • a second aspect of the present invention provides a method for manufacturing a Laval nozzle, characterized in that the Laval nozzle according to the first aspect of the present invention is manufactured using an additive manufacturing process.
  • the Laval nozzle is manufactured in a selective laser melting apparatus.
  • the Laval nozzle is manufactured in a selective laser melting facility.
  • the Laval nozzle provided by the present invention has various cooling strategies, and integrates sweat cooling technology and traditional cooling liquid cooling to achieve better cooling efficiency.
  • the Laval nozzle provided by the present invention can reduce the grain size growth and the thermal conduction attenuation of the copper layer, and thus can achieve a longer working life.
  • the Laval nozzle provided by the present invention protects the spray head from possible clogging and corrosion, and further improves the life of the spray head. Since the present invention adds a sweat cooling strategy to the traditional cooling strategy, the demand for cooling water is reduced, thus saving cooling water and energy consumption, and saving energy. At the same time, the present invention utilizes a small amount of oxygen as the working gas and cooling medium, and does not affect the normal working environment.
  • the diffusion layer of the present invention is provided with tiny pores therein as microchannels, the fabrication can be facilitated by an additive manufacturing process. Also, pore size and porosity can be adjusted by printing parameters for optimized cooling.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Nozzles (AREA)

Abstract

A Laval nozzle (100) and a manufacturing method therefor. The Laval nozzle (100) comprises: a housing (160); a first cooling liquid channel (110), which is disposed in a first accommodating space and is provided with a cooling liquid inlet (110a); a second cooling liquid channel (120), which is disposed in the first accommodating space and is provided with a cooling liquid outlet (120a), wherein the first cooling liquid channel (110) and the second cooling liquid channel (120) are in communication with each other and are provided with cooling liquids that flow circularly; a first oxygen channel (130), which accommodates oxygen and transfers same to an air outlet of the Laval nozzle (100); an oxygen cavity (180); a diffusion wall (170), which is disposed at the bottom of the Laval nozzle (100) and transversely extends to the housing (160); and a second oxygen channel (140), wherein a bottom opening of the second oxygen channel (140) peripherally transversely extends to the housing (160) so as to form an isolation wall (150), and a second accommodating space is provided between the isolation wall (150) and the diffusion wall (170), such that the oxygen is transferred from the first oxygen channel (130) to the second oxygen channel (140) and is diffused in the second accommodating space through a plurality of air holes in the diffusion wall (170), thereby improving the cooling efficiency of the Laval nozzle (100) and prolonging the service life thereof.

Description

拉伐尔喷嘴及其制造方法Laval nozzle and method of making the same 技术领域technical field
本发明涉及增材制造领域,尤其涉及拉伐尔喷嘴及其制造方法。The invention relates to the field of additive manufacturing, in particular to a Laval nozzle and a manufacturing method thereof.
背景技术Background technique
如图1和图2所示,拉伐尔喷嘴220是炼钢炉300的关键元件,其设置于氧气管210的下端并用于通过喷出氧气补吹量来去除炼钢炉300的钢水310中的碳、硅、锰和磷等杂质。其中,作为主要元件的拉伐尔喷嘴220用于充当氧气的出口,其具有精确机械加工的出气孔222以获得理想流量和参数,此外,拉法尔喷嘴220内部具有第一冷却液体通道224和第二冷却液通道226,第一冷却液体通道224和第二冷却液通道226中具有循环流动的冷却液体以避免拉伐尔喷嘴220过热以及损坏。其中,所述第一冷却液通道224用于充当冷却液入口,第二冷却液通道226用于充当冷却液出口。As shown in FIG. 1 and FIG. 2 , the Laval nozzle 220 is a key element of the steelmaking furnace 300 , which is arranged at the lower end of the oxygen pipe 210 and is used to remove the molten steel 310 of the steelmaking furnace 300 by spraying the oxygen supplementary blowing amount. impurities such as carbon, silicon, manganese and phosphorus. Among them, the Laval nozzle 220 as the main element is used to act as the outlet of oxygen, and it has the precisely machined air outlet 222 to obtain the ideal flow and parameters, in addition, the Laval nozzle 220 has a first cooling liquid channel 224 and The second cooling liquid passage 226 , the first cooling liquid passage 224 and the second cooling liquid passage 226 have circulating cooling liquid in them to avoid overheating and damage of the Laval nozzle 220 . Wherein, the first cooling liquid channel 224 is used for serving as a cooling liquid inlet, and the second cooling liquid channel 226 is used for serving as a cooling liquid outlet.
为了保护通常拉伐尔喷嘴220,需要利用高速率的冷却液体(高到每小时60立方米)。此外,由于拉伐尔喷嘴220的工业制造难度,冷却液体管道设计并不能最优化。如图2所示,由于流动紊流(flow turbulence),拉伐尔喷嘴中存在相当慢流速的区域A,虽然冷却液体流速非常高,但是冷却液体在类似区域A的区域难以流动从而汇聚在一起形成死水区,其会导致更低冷却速率和保护能力。因此,拉伐尔喷嘴220在区域A就更容易过热甚至损坏。In order to protect a typical Laval nozzle 220, it is necessary to utilize a high rate of cooling liquid (up to 60 cubic meters per hour). Furthermore, due to the difficulty of industrial manufacturing of the Laval nozzle 220, the cooling liquid piping design cannot be optimized. As shown in Figure 2, due to flow turbulence, there is a relatively slow flow area A in the Laval nozzle. Although the cooling liquid flow rate is very high, the cooling liquid is difficult to flow in areas like the area A and converge together. Dead water areas are created, which result in lower cooling rates and protection. Therefore, the Laval nozzle 220 is more prone to overheating or even damage in the region A.
如图所示,为了获得足够氧气出气效率,通常拉伐尔喷嘴220设置于靠近温度大于2000摄氏度钢水310的表面。由于极高的工作温度,拉伐尔喷嘴220内部的冷却液体并不足以持续避免喷头表面融化或者过早烧毁。其中,铜锻的晶粒会逐渐生长,其会导致拉伐尔喷嘴220的热传系数和冷却效率退化。退化的冷却效率会进一步增加铜晶粒生长速率并导致拉伐尔喷嘴220的快速损坏。钢水310的堵塞不是仅仅导致拉伐尔喷嘴220的腐蚀,还会进一步降低其热传系数和冷却效率。As shown in the figure, in order to obtain sufficient oxygen outgassing efficiency, the Laval nozzle 220 is usually disposed close to the surface of the molten steel 310 whose temperature is greater than 2000 degrees Celsius. Due to the extremely high operating temperature, the cooling liquid inside the Laval nozzle 220 is not sufficient to keep the nozzle surface from melting or premature burnout. Among them, the grains of the copper forging may gradually grow, which may lead to degradation of the heat transfer coefficient and cooling efficiency of the Laval nozzle 220 . Degraded cooling efficiency can further increase the copper grain growth rate and cause rapid damage to the Laval nozzle 220 . The clogging of the molten steel 310 not only leads to corrosion of the Laval nozzle 220, but also further reduces its heat transfer coefficient and cooling efficiency.
拉伐尔喷嘴的寿命很低,通常氧气喷嘴会损坏并需要在100到200炉以后进行更换。喷嘴更换也很麻烦,需要更换的喷嘴头需要从氧气管210上切 割下来,并重新焊接上新喷头,其并不仅仅导致额外操作成本也会影响正常生产过程。这也导致了材料浪费,并影响常规钢铁生产流程。此外,为了改善冷却速率,拉伐尔喷嘴220是铜锻的,铜锻具有高密度和小晶粒尺寸,这样能保证比铸铜具有高热传导率。氧气管210是不锈钢材料的,拉伐尔喷嘴220是铜材料的(两者通过焊接连接。不锈钢和铜的高温度梯度和不同热膨胀率会导致沿着氧气管210和拉伐尔喷嘴220的焊缝线出现裂纹,这会导致过早故障。由于长大的晶粒尺寸和退化的热传导性,拉伐尔喷嘴220不能通过补偿加热或者涂敷来修复。Laval nozzles have a very low lifespan, usually oxygen nozzles are damaged and need to be replaced after 100 to 200 furnaces. Nozzle replacement is also troublesome. The nozzle tip to be replaced needs to be cut from the oxygen pipe 210 and re-welded with a new nozzle, which not only causes extra operating costs but also affects the normal production process. This also leads to material waste and affects regular steel production processes. In addition, to improve the cooling rate, the Laval nozzle 220 is copper forged, which has a high density and small grain size, which ensures a higher thermal conductivity than cast copper. The oxygen tube 210 is stainless steel and the Laval nozzle 220 is copper (the two are connected by welding. The high temperature gradient and different thermal expansion rates of stainless steel and copper can cause welding along the oxygen tube 210 and the Laval nozzle 220 The stitches are cracked, which can lead to premature failure. The Laval nozzle 220 cannot be repaired by compensating heating or coating due to the grown grain size and degraded thermal conductivity.
发明内容SUMMARY OF THE INVENTION
本发明第一方面提供了拉伐尔喷嘴,其中,所述拉伐尔喷嘴包括:外壳,其具有一个第一容纳空间;第一冷却液体通道,其设置于所述第一容纳空间中并具有冷却液入口;第二冷却液通道,其设置于所述第一容纳空间中并具有冷却液出口,其中,所述第一冷却液体通道和所述第二冷却液通道联通并具有循环流动的冷却液体;第一氧气通道,其容纳并输送氧气至所述拉伐尔喷嘴的出气口;氧腔,其联通于所述第一氧气通道,并为所述第一氧气通道输送氧气;扩散壁,其设置于所述拉伐尔喷嘴底部并横向延伸至所述外壳,第二氧气通道,其和所述第一氧气通道或者所述氧腔联通,所述第二氧气通道的底部开口向四周横向延伸至所述外壳以形成一个隔离壁,其中,所述隔离壁和所述扩散壁之间具有一个第二容纳空间,使得氧气从所述第一氧气通道输送至所述第二氧气通道并在所述第二容纳空间中通过扩散壁的多个气孔扩散。A first aspect of the present invention provides a Laval nozzle, wherein the Laval nozzle includes: a casing having a first accommodating space; a first cooling liquid channel disposed in the first accommodating space and having a cooling liquid inlet; a second cooling liquid channel, which is arranged in the first accommodating space and has a cooling liquid outlet, wherein the first cooling liquid channel and the second cooling liquid channel communicate with each other and have a circulating cooling liquid liquid; a first oxygen channel, which accommodates and transports oxygen to the air outlet of the Laval nozzle; an oxygen cavity, which is communicated with the first oxygen channel and transports oxygen for the first oxygen channel; a diffusion wall, It is arranged at the bottom of the Laval nozzle and extends laterally to the casing, a second oxygen channel, which is communicated with the first oxygen channel or the oxygen chamber, and the bottom opening of the second oxygen channel is laterally around. extending to the housing to form a partition wall, wherein there is a second containment space between the partition wall and the diffusion wall, so that oxygen is transported from the first oxygen channel to the second oxygen channel and at The second accommodating space is diffused through a plurality of air holes of the diffusion wall.
进一步地,所述第一氧气通道穿过所述第二容纳空间以及所述扩散壁,其中,所述第一氧气通道的底部开口充当所述拉伐尔喷嘴的出气口。Further, the first oxygen channel passes through the second accommodating space and the diffusion wall, wherein the bottom opening of the first oxygen channel serves as the air outlet of the Laval nozzle.
进一步地,所述所述隔离壁和所述扩散壁之间垂直设置有复数个支撑壁。Further, a plurality of supporting walls are vertically arranged between the partition wall and the diffusion wall.
进一步地,所述支撑壁从所述拉伐尔喷嘴的中心区域向其周围延伸。Further, the support wall extends from the central region of the Laval nozzle to the periphery thereof.
进一步地,扩散壁的厚度取值范围为3毫米到10毫米。Further, the thickness of the diffusion wall ranges from 3 mm to 10 mm.
进一步地,扩散壁的气孔尺寸的直径取值范围为5到30微米。Further, the diameter of the pore size of the diffusion wall ranges from 5 to 30 microns.
进一步地,所述隔离壁和所述扩散壁是由金属制成的。Further, the partition wall and the diffusion wall are made of metal.
进一步地,所述隔离壁和所述扩散壁是由金属铜制成的。Further, the partition wall and the diffusion wall are made of metallic copper.
本发明第二方面提供了拉伐尔喷嘴的制造方法,其中,采用增材制造工 艺制造根据本发明第一方面所述的拉伐尔喷嘴。A second aspect of the present invention provides a method for manufacturing a Laval nozzle, wherein an additive manufacturing process is used to manufacture the Laval nozzle according to the first aspect of the present invention.
进一步地,所述拉伐尔喷嘴是在选择性激光熔化设备中制造的。Further, the Laval nozzle is manufactured in a selective laser melting facility.
本发明提供的拉伐尔喷嘴具有多种冷却策略,并整合了发汗冷却技术和传统冷却液冷却,能达到更好的冷却效率以及延长使用寿命。本发明提供的拉伐尔喷嘴能够减少晶粒尺寸生长和铜层的热传导衰减,因此能够达到较长的工作寿命。本发明提供的拉伐尔喷嘴能保护喷头避免可能的阻塞和腐蚀,并进一步改善喷头的寿命。由于本发明在传统冷却策略上又增加了发汗冷却策略,因此对冷却水的需求量降低,因此节约了冷却水和能量消耗,节约了能源。同时,本发明利用了少部分氧气作为工作气体和冷却介质,并不会影响正常工作环境。The Laval nozzle provided by the present invention has various cooling strategies, and integrates sweat cooling technology and traditional cooling liquid cooling, which can achieve better cooling efficiency and prolong service life. The Laval nozzle provided by the present invention can reduce the grain size growth and the thermal conduction attenuation of the copper layer, and thus can achieve a longer working life. The Laval nozzle provided by the present invention can protect the nozzle from possible clogging and corrosion, and further improve the life of the nozzle. Since the present invention adds a sweat cooling strategy to the traditional cooling strategy, the demand for cooling water is reduced, thus saving cooling water and energy consumption, and saving energy. At the same time, the present invention utilizes a small amount of oxygen as the working gas and cooling medium, and does not affect the normal working environment.
此外,虽然本发明的扩散层虽然在其中设置了微小气孔作为微通道,但是通过增材制造工艺则可以利于制造。并且,毛孔尺寸和多孔性能够通过打印参数来调整,以获取优化的冷却效果。In addition, although the diffusion layer of the present invention is provided with tiny pores therein as microchannels, the fabrication can be facilitated by an additive manufacturing process. Also, pore size and porosity can be adjusted by printing parameters for optimized cooling.
附图说明Description of drawings
图1是炼钢炉里的氧气输送装置的结构示意图;Fig. 1 is the structural representation of the oxygen delivery device in the steelmaking furnace;
图2是现有技术的拉伐尔喷嘴的剖面示意图;Figure 2 is a schematic cross-sectional view of a Laval nozzle of the prior art;
图3是采用不同冷却策略的冷却效率对比图;Figure 3 is a comparison diagram of cooling efficiency using different cooling strategies;
图4是发汗冷却的原理示意图;Fig. 4 is the principle schematic diagram of sweat cooling;
图5是根据本发明一个具体实施例的拉伐尔喷嘴的剖面示意图。5 is a schematic cross-sectional view of a Laval nozzle according to an embodiment of the present invention.
具体实施方式detailed description
以下结合附图,对本发明的具体实施方式进行说明。The specific embodiments of the present invention will be described below with reference to the accompanying drawings.
本发明提供了拉伐尔喷嘴及其制造方法,其底部采用发汗致冷技术,通过在底部扩散层设置多个微通道,因此氧气通过微通道流出的时候则在底部表面形成一层气膜,将所述拉伐尔喷嘴的表面热量带走以达到冷却目的。其中,扩散层充当隔热层和冷却层。并且,如果钢水附着在扩散层上,通过扩散层微通道流出的氧气也可以将钢水吹走。本发明可以由增材制造技术制造,能够达到高冷却效率并提高拉伐尔喷嘴寿命。The invention provides a Laval nozzle and a manufacturing method thereof. The bottom of the nozzle adopts sweating and cooling technology. By setting a plurality of microchannels in the bottom diffusion layer, when oxygen flows out through the microchannels, a gas film is formed on the bottom surface. The surface heat of the Laval nozzle is removed for cooling purposes. Among them, the diffusion layer acts as an insulating layer and a cooling layer. And, if molten steel adheres to the diffusion layer, the oxygen flowing out through the microchannels of the diffusion layer can also blow the molten steel away. The present invention can be manufactured by additive manufacturing technology, which can achieve high cooling efficiency and increase Laval nozzle life.
图3是采用不同冷却策略的冷却效率对比图。如图3所示,常用的冷却策略包括撞击冷却A、对流冷却B、发汗冷却C和全膜冷却D,其中坐标系 的横坐标为冷却空气流量,纵坐标为冷却效率。如图3可知,发汗冷却技术具有在同样冷却空气流量下最好的冷却效率,因此本发明则选择采用发汗冷却策略。Figure 3 is a comparison diagram of cooling efficiency using different cooling strategies. As shown in Figure 3, commonly used cooling strategies include impingement cooling A, convective cooling B, perspiration cooling C, and full-film cooling D, where the abscissa of the coordinate system is the cooling air flow and the ordinate is the cooling efficiency. As can be seen from FIG. 3 , the sweat cooling technology has the best cooling efficiency under the same cooling air flow, so the present invention chooses to adopt the sweat cooling strategy.
图4的箭头方向示出了氧气的流动方向。从冷却管道来的冷却气体渗透通过多孔壁并形成一个冷却气体阻隔层来保护元件不被高热流腐蚀。针对氧气出气孔的应用场景,氧气中的一小部分工作气体会被利用成为预期发汗冷却策略的冷却剂,而不需要额外冷却介质并产生额外费用,以及避免对工作环境产生影响。与其他冷却策略不同,例如薄膜冷却,发汗冷却只需要很小量的冷却气体流量来形成阻隔层,其不会阻碍拉伐尔喷嘴的正常工作流量状况。除了利用发汗冷却,气体阻隔层也会保护喷头不被阻塞或者腐蚀,并进一步提高拉伐尔喷嘴寿命。The direction of the arrow in FIG. 4 shows the flow direction of oxygen. The cooling gas from the cooling pipes penetrates through the porous walls and forms a cooling gas barrier to protect the components from corrosion by high heat fluxes. For the application scenario of the oxygen vent, a small part of the working gas in the oxygen will be utilized as the coolant for the intended sweat cooling strategy, without the need for additional cooling medium and incurring additional costs, as well as avoiding the impact on the working environment. Unlike other cooling strategies, such as film cooling, sweat cooling requires only a small amount of cooling gas flow to form a barrier that does not hinder the normal operating flow conditions of Laval nozzles. In addition to cooling with sweat, the gas barrier also protects the printhead from clogging or corrosion and further increases Laval nozzle life.
如图5所示,本发明提供的拉伐尔喷嘴100包括一个外壳160、第一冷却液体通道110、第二冷却液通道120、第一氧气通道130、复数个出气孔170a、第二氧气通道140、隔离壁150和氧腔180。具体地,所述外壳160具有一个第一容纳空间。第一冷却液体通道110设置于所述第一容纳空间中并具有冷却液入口110a。第二冷却液通道120设置于所述第一容纳空间中并具有冷却液出口120a,其中,所述第一冷却液体通道110和所述第二冷却液通道120联通并具有循环流动的冷却液体。第一氧气通道130容纳并输送氧气至所述拉伐尔喷嘴100的出气口;氧腔180联通于所述第一氧气通道130,并为所述第一氧气通道130输送氧气;扩散壁170设置于所述拉伐尔喷嘴100底部并横向延伸至所述外壳160,第二氧气通道140和所述第一氧气通道130或者所述氧腔180联通,所述第二氧气通道140的底部开口向四周横向延伸至所述外壳160以形成一个隔离壁150,其中,所述隔离壁150和所述扩散壁170之间具有一个第二容纳空间,使得少量氧气从所述第一氧气通道130或者所述氧腔180输送至所述第二氧气通道140并在所述第二容纳空间中通过扩散壁170的多个气孔扩散。As shown in FIG. 5, the Laval nozzle 100 provided by the present invention includes a casing 160, a first cooling liquid channel 110, a second cooling liquid channel 120, a first oxygen channel 130, a plurality of air outlet holes 170a, and a second oxygen channel 140 , the partition wall 150 and the oxygen chamber 180 . Specifically, the housing 160 has a first accommodating space. The first cooling liquid passage 110 is provided in the first accommodating space and has a cooling liquid inlet 110a. The second cooling liquid channel 120 is disposed in the first accommodating space and has a cooling liquid outlet 120a, wherein the first cooling liquid channel 110 and the second cooling liquid channel 120 communicate with each other and have a circulating cooling liquid. The first oxygen channel 130 accommodates and delivers oxygen to the air outlet of the Laval nozzle 100 ; the oxygen chamber 180 communicates with the first oxygen channel 130 and delivers oxygen for the first oxygen channel 130 ; the diffusion wall 170 is provided At the bottom of the Laval nozzle 100 and extending laterally to the casing 160, the second oxygen channel 140 communicates with the first oxygen channel 130 or the oxygen chamber 180, and the bottom of the second oxygen channel 140 opens to the The periphery extends laterally to the outer shell 160 to form a partition wall 150, wherein a second accommodating space is provided between the partition wall 150 and the diffusion wall 170, so that a small amount of oxygen can flow from the first oxygen channel 130 or all the The oxygen chamber 180 is delivered to the second oxygen channel 140 and diffused through the plurality of air holes of the diffusion wall 170 in the second accommodating space.
进一步地,所述第一氧气通道130穿过所述第二容纳空间以及所述扩散壁170,其中,所述第一氧气通道130的底部开口充当所述拉伐尔喷嘴100的出气口。Further, the first oxygen channel 130 passes through the second accommodating space and the diffusion wall 170 , wherein the bottom opening of the first oxygen channel 130 serves as the air outlet of the Laval nozzle 100 .
本发明提供的拉伐尔喷嘴仍然通过高密度纯铜层直接用热传导方式的冷却液来冷却。拉伐尔喷嘴的前表面额外添加的扩散层辅以第一容纳空间中的 树枝状冷却液通道和氧气管道,从而达到发汗冷却的目的。树枝状冷却液通道的侧壁会确保拉伐尔喷嘴的机械强度,因此,冷却液通道是充当加强剂。本发明会进一步基于优化的冷却和气流量效果来控制冷却液通道和氧气通道。The Laval nozzle provided by the present invention is still directly cooled by the cooling liquid in the heat conduction mode through the high-density pure copper layer. The additional diffusion layer added to the front surface of the Laval nozzle is supplemented by the dendritic cooling liquid channels and oxygen pipes in the first accommodation space, so as to achieve the purpose of sweat cooling. The side walls of the dendritic coolant channels ensure the mechanical strength of the Laval nozzle, therefore, the coolant channels act as reinforcement. The present invention would further control the cooling liquid channel and the oxygen channel based on optimized cooling and airflow effects.
由于扩散层的主要冷却机理并不是直接热传导,因此不需要考虑晶粒尺寸和浓度作为热传导率的影响因素。隔离壁通过扩散层保护其不受高热流密度影响,因此晶粒生长和退化会明显变慢来保持高导热性。Since the main cooling mechanism of the diffusion layer is not direct heat conduction, it is not necessary to consider the grain size and concentration as the influencing factors of thermal conductivity. The barrier is protected from the high heat flux by the diffusion layer, so grain growth and degradation are significantly slower to maintain high thermal conductivity.
考虑到复杂结构和内部冷却液通道,本发明提供的拉伐尔喷嘴具有多孔扩散层和内部的冷却通道,因此能够通过增材制造技术来制造,并且可以通过调整激光扫描策略和打印参数来制造本发明拉伐尔喷嘴的纯铜隔离层以及多孔金属铜扩散层,此外还可以基于设计需求调整孔洞大小和多孔性,以达到预期的冷却效果。Considering the complex structure and internal cooling liquid channels, the Laval nozzle provided by the present invention has a porous diffusion layer and internal cooling channels, so it can be manufactured by additive manufacturing technology, and can be manufactured by adjusting the laser scanning strategy and printing parameters The pure copper isolation layer and the porous metal copper diffusion layer of the Laval nozzle of the present invention can also adjust the size and porosity of the holes based on design requirements, so as to achieve the expected cooling effect.
进一步地,所述所述隔离壁150和所述扩散壁170之间垂直设置有复数个支撑壁150a。Further, a plurality of support walls 150a are vertically disposed between the partition wall 150 and the diffusion wall 170 .
优选地,所述支撑壁150a从所述拉伐尔喷嘴100的中心区域向其周围延伸。Preferably, the support wall 150a extends from the central region of the Laval nozzle 100 to the periphery thereof.
为了成功形成气膜,对扩散壁和气孔尺寸的直径也有特定选择,其中,扩散壁170的厚度取值范围为3毫米到10毫米,扩散壁170的气孔尺寸的直径取值范围为5到30微米。In order to successfully form the gas film, the diameters of the diffusion wall and the size of the pores are also selected specifically, wherein the thickness of the diffusion wall 170 ranges from 3 mm to 10 mm, and the diameter of the size of the pores of the diffusion wall 170 ranges from 5 to 30 mm. microns.
进一步地,所述隔离壁和所述扩散壁是由金属制成的。优选地,所述隔离壁和所述扩散壁是由金属铜制成的。另外冷却效率的提升可以降低对于隔离壁和扩散壁热导率的要求,从而在材料选择上可以选取更适合增材制造工艺的铜合金而不是纯铜材料。Further, the partition wall and the diffusion wall are made of metal. Preferably, the partition wall and the diffusion wall are made of metallic copper. In addition, the improvement of cooling efficiency can reduce the requirements for the thermal conductivity of the separation wall and the diffusion wall, so that copper alloys that are more suitable for additive manufacturing processes can be selected instead of pure copper materials in material selection.
本发明第二方面提供了拉伐尔喷嘴的制造方法,其特征在于,采用增材制造工艺制造根据本发明第一方面所述的拉伐尔喷嘴。优选地,所述拉伐尔喷嘴是在选择性激光熔化设备中制造的。A second aspect of the present invention provides a method for manufacturing a Laval nozzle, characterized in that the Laval nozzle according to the first aspect of the present invention is manufactured using an additive manufacturing process. Preferably, the Laval nozzle is manufactured in a selective laser melting apparatus.
进一步地,所述拉伐尔喷嘴是在选择性激光熔化设备中制造的。Further, the Laval nozzle is manufactured in a selective laser melting facility.
本发明提供的拉伐尔喷嘴具有多种冷却策略,并整合了发汗冷却技术和传统冷却液冷却,能达到更好的冷却效率。本发明提供的拉伐尔喷嘴能够减少晶粒尺寸生长和铜层的热传导衰减,因此能够达到较长的工作寿命。本发明提供的拉伐尔喷嘴能保护喷头避免可能的阻塞和腐蚀,并进一步改善喷头 的寿命。由于本发明在传统冷却策略上又增加了发汗冷却策略,因此对冷却水的需求量降低,因此节约了冷却水和能量消耗,节约了能源。同时,本发明利用了少部分氧气作为工作气体和冷却介质,并不会影响正常工作环境。The Laval nozzle provided by the present invention has various cooling strategies, and integrates sweat cooling technology and traditional cooling liquid cooling to achieve better cooling efficiency. The Laval nozzle provided by the present invention can reduce the grain size growth and the thermal conduction attenuation of the copper layer, and thus can achieve a longer working life. The Laval nozzle provided by the present invention protects the spray head from possible clogging and corrosion, and further improves the life of the spray head. Since the present invention adds a sweat cooling strategy to the traditional cooling strategy, the demand for cooling water is reduced, thus saving cooling water and energy consumption, and saving energy. At the same time, the present invention utilizes a small amount of oxygen as the working gas and cooling medium, and does not affect the normal working environment.
此外,虽然本发明的扩散层虽然在其中设置了微小气孔作为微通道,但是通过增材制造工艺则可以利于制造。并且,毛孔尺寸和多孔性能够通过打印参数来调整,以获取优化的冷却效果。In addition, although the diffusion layer of the present invention is provided with tiny pores therein as microchannels, the fabrication can be facilitated by an additive manufacturing process. Also, pore size and porosity can be adjusted by printing parameters for optimized cooling.
尽管本发明的内容已经通过上述优选实施例作了详细介绍,但应当认识到上述的描述不应被认为是对本发明的限制。在本领域技术人员阅读了上述内容后,对于本发明的多种修改和替代都将是显而易见的。因此,本发明的保护范围应由所附的权利要求来限定。此外,不应将权利要求中的任何附图标记视为限制所涉及的权利要求;“包括”一词不排除其它权利要求或说明书中未列出的装置或步骤;“第一”、“第二”等词语仅用来表示名称,而并不表示任何特定的顺序。While the content of the present invention has been described in detail by way of the above preferred embodiments, it should be appreciated that the above description should not be construed as limiting the present invention. Various modifications and alternatives to the present invention will be apparent to those skilled in the art upon reading the foregoing. Accordingly, the scope of protection of the present invention should be defined by the appended claims. Furthermore, any reference signs in a claim shall not be construed as limiting the claim involved; the word "comprising" does not exclude other claims or means or steps not listed in the specification; Words such as "two" are used only to denote names and do not denote any particular order.

Claims (10)

  1. 拉伐尔喷嘴,其特征在于,所述拉伐尔喷嘴(100)包括:A Laval nozzle, characterized in that the Laval nozzle (100) comprises:
    外壳(160),其具有一个第一容纳空间;a housing (160) having a first accommodating space;
    第一冷却液体通道(110),其设置于所述第一容纳空间中并具有冷却液入口(110a);a first cooling liquid passage (110), which is arranged in the first accommodating space and has a cooling liquid inlet (110a);
    第二冷却液通道(120),其设置于所述第一容纳空间中并具有冷却液出口(120a),其中,所述第一冷却液体通道(110)和所述第二冷却液通道(120)联通并具有循环流动的冷却液体;A second cooling liquid channel (120) is provided in the first accommodating space and has a cooling liquid outlet (120a), wherein the first cooling liquid channel (110) and the second cooling liquid channel (120) ) communicated and has a circulating cooling liquid;
    第一氧气通道(130),其容纳并输送氧气至所述拉伐尔喷嘴(100)的出气口;a first oxygen channel (130) that accommodates and delivers oxygen to the air outlet of the Laval nozzle (100);
    氧腔(180),其联通于所述第一氧气通道(130),并为所述第一氧气通道(130)输送氧气;an oxygen chamber (180), which is communicated with the first oxygen channel (130) and delivers oxygen for the first oxygen channel (130);
    扩散壁(170),其设置于所述拉伐尔喷嘴(100)底部并横向延伸至所述外壳(160),a diffuser wall (170) disposed at the bottom of the Laval nozzle (100) and extending laterally to the housing (160),
    第二氧气通道(140),其和所述第一氧气通道(130)或者所述氧腔(180)联通,所述第二氧气通道(140)的底部开口向四周横向延伸至所述外壳(160)以形成一个隔离壁(150),其中,所述隔离壁(150)和所述扩散壁(170)之间具有一个第二容纳空间,使得氧气从所述第一氧气通道(130)输送至所述第二氧气通道(140)并在所述第二容纳空间中通过扩散壁(170)的多个气孔(170a)扩散。The second oxygen channel (140) communicates with the first oxygen channel (130) or the oxygen cavity (180), and the bottom opening of the second oxygen channel (140) extends laterally to the outer casing (140). 160) to form a partition wall (150), wherein there is a second accommodation space between the partition wall (150) and the diffusion wall (170), so that oxygen is transported from the first oxygen channel (130) to the second oxygen channel (140) and diffuse through a plurality of air holes (170a) of the diffusion wall (170) in the second accommodation space.
  2. 根据权利要求1所述的拉伐尔喷嘴,其特征在于,所述第一氧气通道(130)穿过所述第二容纳空间以及所述扩散壁(170),其中,所述第一氧气通道(130)的底部开口充当所述拉伐尔喷嘴(100)的出气口。The Laval nozzle according to claim 1, wherein the first oxygen channel (130) passes through the second accommodating space and the diffusion wall (170), wherein the first oxygen channel The bottom opening of (130) acts as the air outlet of the Laval nozzle (100).
  3. 根据权利要求1所述的拉伐尔喷嘴,其特征在于,所述所述隔离壁(150)和所述扩散壁(170)之间垂直设置有复数个支撑壁(150a)。The Laval nozzle according to claim 1, wherein a plurality of supporting walls (150a) are vertically arranged between the partition wall (150) and the diffusion wall (170).
  4. 根据权利要求3所述的拉伐尔喷嘴,其特征在于,所述支撑壁(150a)从所述拉伐尔喷嘴(100)的中心区域向其周围延伸。The Laval nozzle according to claim 3, characterized in that the support wall (150a) extends from a central area of the Laval nozzle (100) to its periphery.
  5. 根据权利要求1所述的拉伐尔喷嘴,其特征在于,扩散壁(170)的厚度取值范围为3毫米到10毫米。The Laval nozzle according to claim 1, wherein the thickness of the diffuser wall (170) ranges from 3 mm to 10 mm.
  6. 根据权利要求1所述的拉伐尔喷嘴,其特征在于,扩散壁(170)的气 孔尺寸的直径取值范围为5到30微米。The Laval nozzle according to claim 1, wherein the diameter of the pores of the diffuser wall (170) ranges from 5 to 30 microns.
  7. 根据权利要求1所述的拉伐尔喷嘴,其特征在于,所述隔离壁(150)和所述扩散壁(170)是由金属制成的。The Laval nozzle according to claim 1, wherein the partition wall (150) and the diffusion wall (170) are made of metal.
  8. 根据权利要求7所述的拉伐尔喷嘴,其特征在于,所述隔离壁(150)和所述扩散壁(170)是由金属铜制成的。The Laval nozzle according to claim 7, wherein the partition wall (150) and the diffusion wall (170) are made of metallic copper.
  9. 拉伐尔喷嘴的制造方法,其特征在于,采用增材制造工艺制造根据权利要求1至7任一项所述的拉伐尔喷嘴。A method for manufacturing a Laval nozzle, characterized in that the Laval nozzle according to any one of claims 1 to 7 is manufactured using an additive manufacturing process.
  10. 根据权利要求9所述的拉伐尔喷嘴的制造方法,其特征在于,所述拉伐尔喷嘴是在选择性激光熔化设备中制造的。The method of manufacturing a Laval nozzle according to claim 9, wherein the Laval nozzle is manufactured in a selective laser melting apparatus.
PCT/CN2020/114078 2020-09-08 2020-09-08 Laval nozzle and manufacturing method therefor WO2022051912A1 (en)

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CN1037545A (en) * 1988-04-25 1989-11-29 奥地利钢铁联合企业阿尔帕工业设备制造有限公司 Spray gun
CN1124341A (en) * 1994-06-21 1996-06-12 普拉塞尔技术有限公司 Porous non-fouling nozzle
CN1708591A (en) * 2002-11-16 2005-12-14 韦富克斯有限公司 Method and device for cooling blowing lances
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