WO2022050326A1 - 甘味の増大した果汁飲料 - Google Patents
甘味の増大した果汁飲料 Download PDFInfo
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- WO2022050326A1 WO2022050326A1 PCT/JP2021/032208 JP2021032208W WO2022050326A1 WO 2022050326 A1 WO2022050326 A1 WO 2022050326A1 JP 2021032208 W JP2021032208 W JP 2021032208W WO 2022050326 A1 WO2022050326 A1 WO 2022050326A1
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- Prior art keywords
- less
- sweetness
- fruit juice
- sweetener
- rebaugioside
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- 229960001462 sodium cyclamate Drugs 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- WPLOVIFNBMNBPD-ATHMIXSHSA-N subtilin Chemical compound CC1SCC(NC2=O)C(=O)NC(CC(N)=O)C(=O)NC(C(=O)NC(CCCCN)C(=O)NC(C(C)CC)C(=O)NC(=C)C(=O)NC(CCCCN)C(O)=O)CSC(C)C2NC(=O)C(CC(C)C)NC(=O)C1NC(=O)C(CCC(N)=O)NC(=O)C(CC(C)C)NC(=O)C(NC(=O)C1NC(=O)C(=C/C)/NC(=O)C(CCC(N)=O)NC(=O)C(CC(C)C)NC(=O)C(C)NC(=O)CNC(=O)C(NC(=O)C(NC(=O)C2NC(=O)CNC(=O)C3CCCN3C(=O)C(NC(=O)C3NC(=O)C(CC(C)C)NC(=O)C(=C)NC(=O)C(CCC(O)=O)NC(=O)C(NC(=O)C(CCCCN)NC(=O)C(N)CC=4C5=CC=CC=C5NC=4)CSC3)C(C)SC2)C(C)C)C(C)SC1)CC1=CC=CC=C1 WPLOVIFNBMNBPD-ATHMIXSHSA-N 0.000 description 2
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- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 1
- IUVCFHHAEHNCFT-INIZCTEOSA-N 2-[(1s)-1-[4-amino-3-(3-fluoro-4-propan-2-yloxyphenyl)pyrazolo[3,4-d]pyrimidin-1-yl]ethyl]-6-fluoro-3-(3-fluorophenyl)chromen-4-one Chemical compound C1=C(F)C(OC(C)C)=CC=C1C(C1=C(N)N=CN=C11)=NN1[C@@H](C)C1=C(C=2C=C(F)C=CC=2)C(=O)C2=CC(F)=CC=C2O1 IUVCFHHAEHNCFT-INIZCTEOSA-N 0.000 description 1
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- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
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- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- CSMWJXBSXGUPGY-UHFFFAOYSA-L sodium dithionate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)S([O-])(=O)=O CSMWJXBSXGUPGY-UHFFFAOYSA-L 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
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- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 description 1
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Images
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/52—Adding ingredients
- A23L2/60—Sweeteners
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/02—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation containing fruit or vegetable juices
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/385—Concentrates of non-alcoholic beverages
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/42—Preservation of non-alcoholic beverages
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/52—Adding ingredients
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/20—Synthetic spices, flavouring agents or condiments
- A23L27/21—Synthetic spices, flavouring agents or condiments containing amino acids
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/30—Artificial sweetening agents
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/84—Flavour masking or reducing agents
Definitions
- the present invention relates to a fruit juice beverage having an increased sweetness and a method for producing the fruit juice beverage.
- the present invention also relates to a method for enhancing the sweetness of a fruit juice beverage and a concentrate for providing the fruit juice beverage.
- Taste receptors that receive taste are called taste buds, and are present in the mushroom-shaped papillae that exist in a wide range around the tip of the tongue, and in the circumvallate papillae and foliate papillae that exist in a limited area in the back of the tongue.
- taste buds are cell aggregates composed of elongated taste cells and basal cells. Taste cells produce fine line hair toward the tongue surface, and at the bottom of the cell, they make synapses with taste nerve fibers that invade the taste buds, and the taste that we usually feel is sent to the brain via the taste nerve as taste information and recognized.
- T1R2 and T1R3 are known as sweet taste receptors. It has been reported that T1R2 and T1R3 form a heterodimer (Non-Patent Documents 1 to 3).
- Non-Patent Document 4 As an example of the contrasting effect, which is one of the taste interactions, it has long been known that the sweetness increases when salt is added to soup powder. There are examples of reports on the interaction between saltiness and sweetness focusing on this phenomenon, but the interaction between sweetness and saltiness has a somewhat strong sweetness (15% solution) and a somewhat strong salt concentration (0.1-0.2%). It is concluded that this is required (Non-Patent Document 4).
- Patent Document 1 It is also being studied to increase the sweetness by adding a low concentration of sodium to natural sugar and a specific high-sweetness sweetener.
- the present invention includes the following aspects of the invention.
- It contains (a) a high-sweetness sweetener in an amount equivalent to the sweetness intensity X1 and (b) an amino acid below the taste recognition threshold or a derivative thereof or a salt thereof.
- a fruit juice beverage having a sweetness intensity of X3 and 0.1 ⁇ X1 ⁇ X3 due to the components (a) and (b).
- B Amino acids below the taste recognition threshold or derivatives thereof or salts thereof, and (c) less than 50 mg / 100 ml of sodium.
- amino acid according to any one of [1] to [5], wherein the amino acid comprises an amino acid selected from glycine, alanine, valine, isoleucine, leucine, serine, threonine, glutamine, asparagine, arginine, lysine, histidine and a combination thereof.
- Fruit juice drink [7] The fruit juice beverage according to any one of [1] to [6], which has an energy of 50 Kcal / 100 ml or less.
- the fruit juice beverage according to any one of [1] to [8], wherein the fruit juice ratio of the fruit juice beverage is 1 to 100%, 4 to 95%, 5 to 80%, 5 to 50% or 5 to 30%.
- the juice contained in the fruit juice beverage is orange, citrus, lemon, grapefruit, lime, pineapple, strawberry, raspberry, blueberry, cassis, cranberry, blueberry, guaba, banana, acerola, papaya, passion fruit, mango, apple, grape,
- the low-sweetness sweetener comprises at least one selected from the group consisting of glucose, sucrose, fructose, maltose, oligosaccharides, high fructose corn syrup, lactose, psicose, allose, tagatose and combinations thereof, [1] to The fruit juice beverage according to any one of [10].
- the high-sweetness sweetener is selected from the group consisting of steviol glycoside, Luo Han Guo extract, mogrol glycoside, Thaumataococcus daniellii Benth plant-containing sweetener, Pentadiplandra brazzeana plant-containing sweetener, artificial sweetener and combinations thereof.
- the fruit juice beverage according to any one of [1] to [11], which comprises at least one.
- the high-intensity sweeteners are rebaugioside A, rebaugioside B, rebaugioside C, rebaugioside D, rebaugioside E, rebaugioside F, rebaugioside I, rebaugioside J, rebaugioside K, rebaugioside M, rebaugioside O, rebaugioside O, rebaugioside O, and rebaugioside.
- the fruit juice beverage according to any one of [1] to [12], which comprises at least one thereof.
- [A1] (corresponding to Japanese Patent Application No. 202-147848 / 2020-185335) It contains (a) a high-sweetness sweetener in an amount equivalent to the sweetness intensity Xa, and (b) an amino acid below the taste recognition threshold or a derivative thereof or a salt thereof.
- a fruit juice beverage having a sweetness intensity of Xb and 0.1 ⁇ Xa ⁇ Xb due to the components (a) and (b).
- [A3] The fruit juice beverage according to [A1] or [A2], wherein the amino acid comprises a basic amino acid, a neutral amino acid having an alkyl group, an OH group or an amide group in the side chain, and an amino acid selected from a combination thereof.
- [A4] The fruit juice beverage according to any one of [A1] to [A3], wherein the amino acid is at least one selected from amino acids having a molecular weight of 70 to 260.
- [A5] Described in any of [A1] to [A4], wherein the amino acid comprises an amino acid selected from glycine, alanine, valine, isoleucine, leucine, serine, threonine, glutamine, asparagine, arginine, lysine, histidine and combinations thereof.
- Fruit juice drink [A6] The fruit juice beverage according to any one of [A1] to [A5], which has an energy of 50 Kcal / 100 ml or less.
- [A7] The fruit juice beverage according to any one of [A2] to [A6], wherein the sweetness intensity of the low-sweetness sweetener is 0.1 to 5.9.
- the fruit juice beverage according to any one of [A1] to [A7], wherein the fruit juice ratio of the fruit juice beverage is 1 to 100%, 4 to 95%, 5 to 80%, 5 to 50%, or 5 to 30%.
- the juice contained in the fruit juice beverage is orange, citrus, lemon, grapefruit, lime, pineapple, strawberry, raspberry, blueberry, cassis, cranberry, blueberry, guaba, banana, acerola, papaya, passion fruit, mango, apple, grape,
- the low-sweetness sweetener comprises at least one selected from the group consisting of glucose, sucrose, fructose, maltose, oligosaccharides, high fructose corn syrup, lactose, psicose, allose, tagatose and combinations thereof, [A1] to The fruit juice beverage according to any one of [A9].
- the high-sweetness sweetener is selected from the group consisting of steviol glycoside, Luo Han Guo extract, mogrol glycoside, Thaumataococcus daniellii Benth plant-containing sweetener, Pentadiplandra brazzeana plant-containing sweetener, artificial sweetener and combinations thereof.
- the fruit juice beverage according to any one of [A1] to [A10], which comprises at least one.
- the high-intensity sweeteners are rebaugioside A, rebaugioside B, rebaugioside C, rebaugioside D, rebaugioside E, rebaugioside F, rebaugioside I, rebaugioside J, rebaugioside K, rebaugioside M, rebaugioside O, rebaugioside O, rebaugioside O, and rebaugioside.
- the fruit juice beverage according to any one of [A1] to [A11], which comprises at least one thereof.
- [A13] It contains one or more amino acids selected from alanine, serine and glycine, has an energy of 50 Kcal / 100 ml or less, and has a total sweetness intensity of the high-sweetness sweetener and the low-sweetness sweetener of 6 or more.
- [A14] The fruit juice beverage according to any one of [A1] to [A13], which is packed in a container.
- [A15] For raw materials [A1] to [A14], which comprises adding (a) a high-intensity sweetener in an amount of sweetness intensity Xa, and (b) adding an amino acid or a derivative thereof or a salt thereof below the taste recognition threshold.
- [A16] Described in any of [A1] to [A15], which comprises (a) a high-sweetness sweetener in an amount equivalent to the sweetness intensity Xaa, and (b) an amino acid or a derivative thereof or a salt thereof having a taste recognition threshold of less than 10 times.
- the sweetness intensity of a fruit juice beverage is characterized by containing (a) a high-intensity sweetener in an amount equivalent to the sweetness intensity Xa, and (b) an amino acid below the taste recognition threshold or a derivative thereof or a salt thereof. How to enhance.
- A High-sweetness sweetener in an amount equivalent to sweetness intensity Xa
- B Amino acid below the taste recognition threshold or a derivative thereof or a salt thereof
- a low-sweetness sweetener in an amount equivalent to the sweetness intensity Xc.
- a fruit juice beverage having a sweetness intensity of Xd due to the components (a) to (c) and 0.1 ⁇ Xa + Xc ⁇ Xd.
- the amino acid comprises a basic amino acid, a neutral amino acid having an alkyl group, an OH group or an amide group in the side chain, and an amino acid selected from a combination thereof.
- the juice contained in the fruit juice beverage is orange, citrus, lemon, grapefruit, lime, pineapple, strawberry, raspberry, blueberry, cassis, cranberry, blueberry, guaba, banana, acerola, papaya, passion fruit, mango, apple, grape,
- the fruit juice beverage according to any one of [A18] to [A24], which is one or more selected from peach, plum, pear, apricot, peach, melon, kiwi fruit, blueberry and a combination thereof.
- the low-sweetness sweetener comprises at least one selected from the group consisting of glucose, sucrose, fructose, maltose, oligosaccharides, high fructose corn syrup, lactose, psicose, allose, tagatose and combinations thereof, [A18] to The fruit juice beverage according to any one of [A25].
- the high-sweetness sweetener is selected from the group consisting of steviol glycoside, Luo Han Guo extract, mogrol glycoside, Thaumataococcus daniellii Benth plant-containing sweetener, Pentadiplandra brazzeana plant-containing sweetener, artificial sweetener and combinations thereof.
- the fruit juice beverage according to any one of [A18] to [A26], which comprises at least one.
- the high-intensity sweeteners are rebaugioside A, rebaugioside B, rebaugioside C, rebaugioside D, rebaugioside E, rebaugioside F, rebaugioside I, rebaugioside J, rebaugioside K, rebaugioside M, rebaugioside O, rebaugioside O, rebaugioside O, and rebaugioside.
- the fruit juice beverage according to any one of [A18] to [A28], which comprises one or more amino acids selected from alanine, serine and glycine, has an energy of 50 Kcal / 100 ml or less, and has an Xa + Xc of 6 or more.
- [A30] The fruit juice beverage according to any one of [A18] to [A29], which is packed in a container.
- [A31] For raw materials [A18]-[A30], which comprises adding (a) a high-intensity sweetener in an amount of sweetness intensity Xa, and (b) adding an amino acid or a derivative thereof or a salt thereof below the taste recognition threshold.
- [A32] Described in any of [A18] to [A31], which comprises (a) a high-sweetness sweetener in an amount equivalent to the sweetness intensity Xaa, and (b) an amino acid or a derivative thereof or a salt thereof having a taste recognition threshold of less than 10 times. Concentrate for providing fruit juice beverages.
- [B1] (corresponding to Japanese Patent Application No. 2020-147833 / 2020-185333)
- [B2] The fruit juice beverage according to [B1], wherein the components (a) and (b) exhibit sweetness with a sweetness intensity of X3, and 0.1 ⁇ X1 ⁇ X3 ⁇ X2.
- [B3] The fruit juice beverage according to [B1] or [B2], further comprising a low-sweetness sweetener.
- [B4] The fruit juice beverage according to any one of [B1] to [B3], wherein the amino acid comprises a basic amino acid, a neutral amino acid having an alkyl group, an OH group or an amide group in the side chain, and an amino acid selected from a combination thereof. .. [B5]
- [B6] Described in any of [B1] to [B5], wherein the amino acid comprises an amino acid selected from glycine, alanine, valine, isoleucine, leucine, serine, threonine, glutamine, asparagine, arginine, lysine, histidine and combinations thereof.
- Fruit juice drink [B7] The fruit juice beverage according to any one of [B1] to [B6], wherein the sodium content is 1 to 25 mg / 100 ml.
- [B8] The fruit juice beverage according to any one of [B1] to [B7], which has an energy of 50 Kcal / 100 ml or less.
- the juice contained in the fruit juice beverage is orange, citrus, lemon, grapefruit, lime, pineapple, strawberry, raspberry, blueberry, cassis, cranberry, blueberry, guaba, banana, acerola, papaya, passion fruit, mango, apple, grape,
- the fruit juice beverage according to any one of [B1] to [B10], which is one or more selected from peach, plum, pear, apricot, smoky, melon, kiwi fruit, blueberry and a combination thereof.
- the low-sweetness sweetener comprises at least one selected from the group consisting of glucose, sucrose, fructose, maltose, oligosaccharides, high fructose corn syrup, lactose, psicose, allose, tagatose and combinations thereof, [B1] to The fruit juice beverage according to any one of [B11].
- the high-sweetness sweetener is selected from the group consisting of steviol glycoside, Luo Han Guo extract, mogrol glycoside, Thaumataococcus daniellii Benth plant-containing sweetener, Pentadiplandra brazzeana plant-containing sweetener, artificial sweetener and combinations thereof.
- the fruit juice beverage according to any one of [B1] to [B12], which comprises at least one.
- the high-intensity sweeteners are rebaugioside A, rebaugioside B, rebaugioside C, rebaugioside D, rebaugioside E, rebaugioside F, rebaugioside I, rebaugioside J, rebaugioside K, rebaugioside M, rebaugioside O, rebaugioside O, rebaugioside Select from the group consisting of Zulcoside A, Zulcoside C, Rubusoside, Steviolmonoside, Steviolbioside, Stevioside, Luo Han Guo extract, Mogloside V, Thaumatin, Brazzein, Kanzo extract, Saccharin, Aspartame, Acesulfam K, Sucralose, and combinations thereof.
- the fruit juice beverage according to any one of [B1] to [B13], which comprises at least one thereof.
- the sodium is sodium chloride, sodium hydroxide, sodium malate, sodium sulfate, sodium citrate, sodium phosphate, sodium carbonate, sodium disulfide, sodium bicarbonate, sodium alginate, sodium arginate, sodium glucoheptate, glucon.
- [B1] to [B14] which are contained in at least one form selected from the group consisting of sodium acid, sodium glutamate, sodium tartrate, sodium aspartate, sodium lactate, sodium caseinate, sodium ascorbate and mixtures thereof.
- the fruit juice beverage described in either.
- [B16] Contains one or more amino acids selected from alanine, serine and glycine, 1-25 mg / 100 ml sodium, energy 50 Kcal / 100 ml or less, and the sweetness intensity of the high sweetener and the low sweetener.
- [B17] The fruit juice beverage according to any one of [B1] to [B16], which is packed in a container.
- [B23] The fruit juice beverage according to [B21] or [B22], wherein the amino acid is at least one selected from amino acids having a molecular weight of 70 to 260.
- the amino acid comprises an amino acid selected from glycine, alanine, valine, isoleucine, leucine, serine, threonine, glutamine, asparagine, arginine, lysine, histidine and combinations thereof.
- Fruit juice drink [B25] The fruit juice beverage according to any one of [B21] to [B24], which has a sodium content of 1 to 25 mg / 100 ml.
- [B26] The fruit juice beverage according to any one of [B21] to [B25], which has an energy of 50 Kcal / 100 ml or less.
- [B27] The fruit juice beverage according to any one of [B21] to [B26], wherein X4 is 0.1 to 5.9.
- [B28] The fruit juice beverage according to any one of [B21] to [B27], wherein the fruit juice ratio of the fruit juice beverage is 1 to 100%, 4 to 95%, 5 to 80%, 5 to 50%, or 5 to 30%.
- the juice contained in the fruit juice beverage is orange, citrus, lemon, grapefruit, lime, pineapple, strawberry, raspberry, blueberry, cassis, cranberry, blueberry, guaba, banana, acerola, papaya, passion fruit, mango, apple, grape,
- the fruit juice beverage according to any one of [B21] to [B28], which is one or more selected from peach, plum, pear, apricot, smoky, melon, kiwi fruit, karin and a combination thereof.
- the low-sweetness sweetener comprises at least one selected from the group consisting of glucose, sucrose, fructose, maltose, oligosaccharides, high fructose corn syrup, lactose, psicose, allose, tagatose and combinations thereof, [B21] to The fruit juice beverage according to any one of [B29].
- the high-sweetness sweetener is selected from the group consisting of steviol glycoside, Luo Han Guo extract, mogrol glycoside, Thaumataococcus daniellii Benth plant-containing sweetener, Pentadiplandra brazzeana plant-containing sweetener, artificial sweetener and combinations thereof.
- the fruit juice beverage according to any one of [B21] to [B30], which comprises at least one.
- the high-intensity sweeteners are rebaugioside A, rebaugioside B, rebaugioside C, rebaugioside D, rebaugioside E, rebaugioside F, rebaugioside I, rebaugioside J, rebaugioside K, rebaugioside M, rebaugioside O, rebaugioside O, rebaugioside Select from the group consisting of Zulcoside A, Zulcoside C, Rubusoside, Steviolmonoside, Steviolbioside, Stevioside, Luo Han Guo extract, Mogloside V, Thaumatin, Brazzein, Kanzo extract, Saccharin, Aspartame, Acesulfam K, Sucralose, and combinations thereof.
- the fruit juice beverage according to any one of [B21] to [B31], which comprises at least one thereof.
- the sodium is sodium chloride, sodium hydroxide, sodium malate, sodium sulfate, sodium citrate, sodium phosphate, sodium carbonate, sodium disulfide, sodium bicarbonate, sodium alginate, sodium arginate, sodium glucoheptate, glucon.
- [B21] to [B32] which are contained in at least one form selected from the group consisting of sodium acid, sodium glutamate, sodium tartrate, sodium aspartate, sodium lactate, sodium caseinate, sodium ascorbate and mixtures thereof.
- the fruit juice beverage described in either.
- the method of the present invention provides a method for increasing the sweetness of a fruit juice beverage and exhibiting a good taste quality, instead of the simple sweetness obtained by increasing the amount of sugar or a high-sweetness sweetener used.
- the method of the present invention provides a fruit juice beverage exhibiting a good taste in which the sweetness is increased by means other than controlling the amount of sugar and sweetener used.
- Example A2 to Example A7 with respect to Example A1 in Example 1 It is a graph which shows the sensory evaluation result of Example B2 to Example B7 with respect to Example B1 in Example 1. It is a graph which shows the sensory evaluation result of Example C2 to Example C7 with respect to Example C1 in Example 2. It is a graph which shows the sensory evaluation result of Example D2 to Example D7 with respect to Example D1 in Example 2. It is a graph which shows the sensory evaluation result of Example G2 and Example G3 with respect to Example G1 in Example 4. It is a graph which shows the sensory evaluation result of Example H2 and Example H3 with respect to Example H1 in Example 4.
- the description that "the content of the A component is X mg / 100 ml” means that "X mg of the A component is contained in 100 ml of the beverage". Since the specific gravity of the beverage is approximately 1, “mg / 100 g” can be equated with "mg / 100 ml” in the beverage. Further, for example, the description that "the content of the B component is Yppm” means that "the B component is contained in Yppm with respect to the total amount (100% by mass) of the beverage”.
- the present invention provides, as a first aspect, the following fruit juice beverage (hereinafter, referred to as "the fruit juice beverage of the present invention”). It contains (a) a high-sweetness sweetener in an amount equivalent to the sweetness intensity X1 and (b) an amino acid below the taste recognition threshold or a derivative thereof or a salt thereof.
- X1 and X3 correspond to Xa and Xb of the first aspect (corresponding to Japanese Patent Application No. 202-147848 / 2020-185335), respectively.
- the present invention provides the following fruit juice beverage (hereinafter, also referred to as "fruit juice beverage A of the present invention") as the first aspect of A1. It contains (a) a high-intensity sweetener in an amount equivalent to the sweetness intensity Xa, and (b) an amino acid below the taste recognition threshold or a derivative thereof or a salt thereof.
- a fruit juice beverage having a sweetness intensity of Xb and 0.1 ⁇ Xa ⁇ Xb due to the components (a) and (b).
- the component exhibiting sweetness is (a) a high-sweetness sweetener in an amount equivalent to the sweetness intensity Xa, and the sweetness exhibited by the fruit juice beverage of the present invention is calculated to be the sweetness intensity Xa. Should be. However, since (b) an amino acid or a derivative thereof or a salt thereof, which is low in concentration but below the taste recognition threshold, is present in the fruit juice beverage, (a) the sweetness exhibited by the high sweetness sweetener in an amount equivalent to the sweetness intensity Xa. Is increased to a sweetness intensity Xb (where 0.1 ⁇ Xa ⁇ Xb).
- the present invention further comprises sweeteners, acidulants, flavors, vitamins, pigments, antioxidants, emulsifiers, preservatives, seasonings, extracts, etc. other than (a). It means that it may contain additional components such as pH regulators, quality stabilizers and the like. For example, depending on the type of fruit juice, fructose derived from fruits is contained as a sweetener other than (a).
- the fruit juice beverage according to one aspect of the present invention does not contain a sweetening substance other than the component (a) and fructose derived from the fruit as a sweetener.
- the effect of improving the taste quality is exhibited in addition to the increase in sweetness.
- total sweetness “total sweetness”, “reduction of aftertaste of sweetness”, “body, thickness”, “flavor strength”, “miscellaneous taste (bitter taste, astringent taste, etc.)” It is preferred that at least one of "reduction” and “salt taste” is improved.
- alanine, glycine or serine improves "body, thickness” and "flavor intensity”.
- the "fruit juice beverage” means a beverage containing fruit juice which is squeezed fruit.
- Specific “juice beverages” include “fruit beverages” defined in the “Fair Competition Code for Labeling of Fruit Beverages” enforced in 2018 and “labeling of fruit beverages” enforced in 2016. Examples include “fruit juice,””fruit mixed juice,””fruit juice containing fruit grains,””fruit / vegetable mixed juice,””beverage containing fruit juice,” and “jelly beverage containing fruit juice,” which are the definitions of the “Fair Competition Code Enforcement Regulations.” Beverages in which the percentage of fruit juice used, which is classified as “other beverages” in the above regulations, is less than 10% are also included in the "fruit juice beverage” in the present invention as long as the beverage contains fruit juice.
- the fruit juice beverage of the present invention is also referred to as a "juice-containing beverage”.
- the fruit juice contained in the fruit juice beverage of the present invention is not particularly limited, and is, for example, orange, citrus, lemon, grapefruit, lime, pineapple, strawberry, raspberry, blueberry, cassis, cranberry, blueberry, guava, banana, acerola, papaya. , Passion fruit, mango, apple, grape, peach, plum, pear, apricot, peach, melon, kiwi fruit, and one or more selected from blueberry.
- the fruit juice contained in the fruit juice beverage of the present invention can be used regardless of the production method, such as straight fruit juice or concentrated fruit juice.
- the concentrated fruit juice may be prepared by either a heat concentration method or a freezing concentration method.
- the juice ratio of the juice beverage of the present invention is 1 to 100%, 5 to 100%, 10 to 100%, 15 to 100%, 20 to 100%, 25 to 100%, 30 to 100%, 35, depending on the embodiment. ⁇ 100%, 40-100%, 45-100%, 50-100%, 55-100%, 60-100%, 65-100%, 70-100%, 1-95%, 4-95%, 5 ⁇ 95%, 10-95%, 15-95%, 20-95%, 25-95%, 30-95%, 35-95%, 40-95%, 45-95%, 50-95%, 55 ⁇ 95%, 60-95%, 65-95%, 70-95%, 1-90%, 5-90%, 10-90%, 15-90%, 20-90%, 25-90%, 30 ⁇ 90%, 35 ⁇ 90%, 40 ⁇ 90%, 45 ⁇ 90%, 50 ⁇ 90%, 55 ⁇ 90%, 60 ⁇ 90%, 65 ⁇ 90%, 70 ⁇ 90%, 1 ⁇ 85%, 5 ⁇ 85%, 10-85%, 15-85%, 20-85%, 25-85%, 30-85%, 35-85%, 40-85%,
- the "fruit juice ratio" is a relative concentration when the straight fruit juice obtained by squeezing the fruit is taken as 100%, and is the sugar shown in the JAS standard (Japanese Agricultural Standard for fruit beverages). Can be converted based on the refractometer reading standard (° Bx) or acidity standard (%).
- Typical fruit sugar refractive index reading standards include orange: 11, plum: 9, grapefruit: 9, pineapple: 11, cranberry: 7, blueberry, guava: 8, Banana: 23, papaya: 9, passion fruit: 14, mango: 13, apple: 10, grape: 11, peach: 8, Japanese pear: 8, pear: 11, apricot: 7, plum: 6, melon, kiwi Fruit: 10.
- the standard (unit:%) of the acidity of a typical fruit is lemon: 4.5, lime: 6, plum: 3.5, and kabosu: 3.5.
- [Juice ratio (%)] [Juice content (g)] x [Concentration ratio] / 100 mL x 100
- the JAS standard for orange juice is Bx11 °
- the fruit juice ratio is 30%.
- the refractometer reading for sugar such as saccharides and honey added to the fruit juice shall be excluded.
- the fruit juice beverage of the present invention may be an alcoholic beverage.
- Alcoholic beverages refer to beverages containing alcoholic raw materials. It may be a chu-hi beverage or a highball beverage.
- the alcohol raw material include brewed liquor, distilled liquor, and mixed liquor. Examples of brewed liquor include wine and beer. Examples of distilled liquor include spirits (for example, gin, wokka, lamb, tequila, new spirits, etc., and alcohol for raw materials), liqueurs, whiskeys (for example, whiskey, brandy, etc.), shochu, and the like.
- the alcohol raw material may be a fermented fruit juice contained in the fruit juice beverage of the present invention.
- the alcoholic beverage may contain alcohol in a detectable amount, and for example, it contains 1% by volume or more, 2% by volume or more, 3% by volume or more, 4% by volume or more, and 5% by volume or more of alcohol. ..
- the form of the fruit juice beverage of the present invention is not limited, and may be, for example, a beverage in which a concentrated fruit juice extract is dissolved, or may be a container-filled fruit juice beverage enclosed in a container such as a can or a PET bottle. good.
- sweetness intensity means the intensity of sweetness exhibited by a substance.
- sweetness degree 1 the sweetness degree of glucose is 0.6 to 0.7 (median value 0.65).
- the fruit juice beverage of the present invention contains a high-intensity sweetener in an amount equivalent to the sweetness intensity Xa, exhibits sweetness of the sweetness intensity Xb by the components (a) and (b), and is 0.1 ⁇ Xa ⁇ Xb. be.
- Xa of "Sweetness intensity Xa" is more than 0.1 and 0.5 or less, more than 0.1 and 1.0 or less, more than 0.1 and 1.5 or less, more than 0.1 and 2.0 or less, more than 0.1 and 2.5 or less, more than 0.1 and 3.0 or less, more than 0.1 and 3.5 or less, More than 0.1 4.0 or less, more than 0.1 4.5 or less, more than 0.1 5.0 or less, more than 0.1 5.5 or less, 0.5-1.0, 0.5-1.5, 0.5-2.0, 0.5-2.5, 0.5-3.0, 0.5-3.5, 0.5-4.0, 0.5-4.5, 0.5-5.0, 0.5-5.5, 1.0-1.5, 1.0-2.0, 1.0-2.5, 1.0-3.0, 1.0-3.5, 1.0-4.0, 1.0-4.5, 1.0-5.0, 1.0- 5.5, 1.5-2.0, 1.5-2.5, 1.5-3.0, 1.5-3.5, 1.5-4.0, 1.5-4.5, 1.5-5.0, 1.5-5.5, 2.0-2.5,
- Xa also exceeds 0.1 and 6.0 or less, 0.1 and 6.5 or less, 0.1 and 7.0 or less, 0.1 and 7.5 or less, 0.1 and 8.0 or less, 0.1 or 8.5 or less, 0.1 or 9.0 or less, 0.1 or more and 9.5.
- 0.1 to 10.0 or less 0.1 to 10.5 or less, 0.1 to 11.0 or less, 0.1 to 11.5 or less, 0.1 to 12.0 or less, 0.1 to 13.0 or less, 0.1 to 14.0 or less, 0.1 to 15.0 or less, More than 0.1 and 16.0 or less, more than 0.1 and 17.0 or less, more than 0.1 and 18.0 or less, 0.5 to 6.0, 0.5 to 6.5, 0.5 to 7.0, 0.5 to 7.5, 0.5 to 8.0, 0.5 to 8.5, 0.5 to 9.0, 0.5 to 9.5, 0.5-10.0, 0.5-10.5, 0.5-11.0, 0.5-11.5, 0.5-12.0, 0.5-13.0, 0.5-14.0, 0.5-15.0, 0.5-16.0, 0.5-17.0, 0.5-18.0, 1.0-6.0, 1.0- 6.5, 1.0-7.0, 1.0-7.5, 1.0-8.0, 1.0-8.5, 1.0-9.0, 1.0-9.5, 1.0-10.0, 1.0-10.5, 1.0-10.5,
- Xa is preferably 0.5 to 10.0, more preferably 1.5 to 9.0, and even more preferably 2.0 to 8.0. Further, in another aspect of the present invention, Xa is preferably 0.5 to 5.5, more preferably 1.0 to 5.5, and even more preferably 2.0 to 5.0.
- the amount equivalent to the sweetness intensity Xa of the high sweetness sweetener means the amount that exhibits the sweetness of the sweetness intensity Xa under the condition that the high sweetness sweetener is dissolved in water at 20 ° C. having the same volume as the fruit juice beverage of the present invention.
- the amount of the high-sweetness sweetener may be Pa ppm, where Pa ppm is an amount equivalent to the sweetness intensity Xa.
- Pa is about 20 to about 800, about 25 to about 800, about 30 to about 800, about 35 to about 800, about 40 to about 800, about 45 to about 800, about 50 to about 800, about 55 to.
- Pa is also 1-1500, 1-1200, 5-1200, 1-1000, 5-1000, 10-1000, 1-900, 5-900, 10-900, 15-900, 20-900, 25- 900, 30-900, 35-900, 40-900, 45-900, 50-900, 55-900, 1-800, 5-800, 10-800, 15-800, 20-800, 25-800, 30-800, 35-800, 40-800, 45-800, 50-800, 55-800, 1-700, 5-700, 10-700, 15-700, 20-700, 25-700, 30- 700, 35-700, 40-700, 45-700, 50-700, 55-700, 1-600, 5-600, 10-600, 15-600, 20-600, 25-600, 30-600, 35-600, 40-600, 45-600, 50-600, 55-600, 1-550, 1-540, 1-530, 1-520, 1-510, 1-505, 1-500, 1- 495, 1-490, 5-550, 5-540, 5-530, 5-520, 5-510, 5-505, 5-500, 5-495
- Pa is also about 20-about 200, about 100-about 500, about 100-about 450, about 100-about 400, about 100-about 350, about 100-about 300, about 100-about 250, about 100-about. 200, about 150 to about 500, about 150 to about 450, about 150 to about 400, about 150 to about 350, about 150 to about 300, about 150 to about 250, about 150 to about 200, about 200 to about 500, It can take values of about 200 to about 450, about 200 to about 400, about 200 to about 350, about 200 to about 300, or about 200 to about 250.
- Xb is not particularly limited as long as it is larger than Xa, but 0.5 to 6.0, 0.5 to 6.5, 0.5 to 7.0, 0.5 to 7.5, 0.5 to 8.0, 0.5 to 8.5, 0.5 to 9.0, 0.5 to 9.5, 0.5 to 10.0, 0.5. ⁇ 10.5, 0.5 ⁇ 11.0, 0.5 ⁇ 11.5, 0.5 ⁇ 12.0, 0.5 ⁇ 13.0, 0.5 ⁇ 14.0, 0.5 ⁇ 15.0, 0.5 ⁇ 16.0, 0.5 ⁇ 17.0, 0.5 ⁇ 18.0, 1.0 ⁇ 6.0, 1.0 ⁇ 6.5, 1.0 ⁇ 7.0 , 1.0-7.5, 1.0-8.0, 1.0-8.5, 1.0-9.0, 1.
- Xb is also 4.0-18, 4.0-16, 4.0-15.5, 4.0-14, 4.5-18, 4.5-16, 4.5-15.5, 4.5-14, 5.0-18, 5.0-16, 5.0-15.5, 5.0- 14, 5.5-18, 5.5-16, 5.5-15.5, 5.5-14, 6.0-18, 6.0-16, 6.0-15.5, 6.0-14, 6.
- the fruit juice beverage of the present invention exhibits an enhanced sweetness. Whether or not the sweetness of the fruit juice beverage of the present invention is enhanced can be evaluated by a panelist trained in sensuality. Further, the sweetness intensity of the fruit juice beverage of the present invention is such that the standard fruit juice beverage, which is the standard of sweetness, has a sweetness intensity of 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, The sweetness of the fruit juice beverage of the present invention can be measured by adjusting the sucrose concentration to 14 and 15 and comparing the sweetness of the fruit juice beverage of the present invention with the sweetness of the standard fruit juice beverage. can. In addition, the standard fruit juice beverage with sweetness intensity 1, 2, ... 15 has a sucrose content of 1 g / 100 g, 2 g / 100 g, ...
- the standard fruit juice beverage having less sweetness than the fruit juice beverage of the present invention in the above measurement the standard fruit juice beverage having the closest sweetness to the fruit juice beverage of the present invention is selected, and sucrose is added to the selected standard fruit juice beverage.
- the sweetness is adjusted to be the same as that of the fruit juice beverage of the present invention, and at that time, the sweetness intensity of the fruit juice beverage of the present invention is measured from the sucrose content contained in the adjusted reference fruit juice beverage. You can also.
- VAS method sweetness intensity evaluation
- the evaluator defines the intensity of sweetness as "not sweet at all" at the lower end and "I can't think of anything sweeter than this" at the upper end.
- the sweetness intensity felt at that time is evaluated by expressing it at a position on the straight line using a paper on which a vertical line representing the intensity is drawn.
- the sweetness intensity of the fruit juice beverage of the present invention is not particularly limited as long as it is acceptable as a fruit juice beverage, and for example, the sweetness degree is 4.0 to 20, 4.0 to 15, 4.0 to 12.5, 4.0 to 10, 4.5. ⁇ 20, 4.5 ⁇ 15, 4.5 ⁇ 12.5, 4.5 ⁇ 10, 5.0 ⁇ 20, 5.0 ⁇ 15, 5.0 ⁇ 12.5, 5.0 ⁇ 10, 5.5 ⁇ 20, 5.5 ⁇ 15, 5.5 ⁇ 12.5, 5.5 ⁇ 10, 6.0 ⁇ 20, 6.0 ⁇ 15, 6.0 ⁇ 12.5, 6.0 ⁇ 10, 6.5 ⁇ 20, 6.5 ⁇ 15, 6.5 ⁇ 12.5, 6.5 ⁇ 10, 7.0 ⁇ 20, 7.0 ⁇ 15, 7.0 ⁇ 12.5, 7.0 ⁇ 10, 7.5 ⁇ 20, 7.5 ⁇ 15, 7.5 ⁇ 12.5, 7.5 ⁇ 10, 7.5 ⁇ 9, 7.5 ⁇ 8, 8.0 ⁇ 20, 8.0 ⁇ 20, 8.0 ⁇ 20, 8.0 ⁇ 15, 8.0 ⁇ 12.5, 8.0 ⁇ 10, 8.5 ⁇ 20, 8.5 ⁇ 15
- the energy (total energy amount) of the fruit juice beverage of the present invention is 0 to 50 Kcal / 100 ml, 0 to 45 Kcal / 100 ml, 0 to 40 Kcal / 100 ml, 0 to 35 Kcal / 100 ml, 0 to 30 Kcal / 100 ml, 0 to 24 Kcal depending on the embodiment.
- the energy (total energy amount, TE) of the fruit juice beverage of the present invention is 0 ⁇ TE ⁇ 50 Kcal / 100 ml, 0 ⁇ TE ⁇ 45 Kcal / 100 ml, 0 depending on the embodiment (for example, an embodiment containing a caloric sweetener).
- the components (a) and (b) can be arbitrarily combined. As shown in Examples described later, by adding the component (b) to the component (a), it is possible to obtain a sweetness intensity Xb higher than the sweetness intensity Xa of the component (a) alone. That is, the sweetness of the component (a) can be enhanced by the component (b). Therefore, it is possible to produce a fruit juice beverage while maintaining the same sweetness as that of a fruit juice beverage containing sucrose, without using sucrose having a high calorie content, or while reducing the amount of sucrose used. Therefore, it is possible to design a new low-calorie fruit juice beverage.
- a high-intensity sweetener having particularly excellent taste such as rebaugioside D (hereinafter, rebaugioside may be abbreviated as Reb) or rebaugioside M as the component (a).
- Reb rebaugioside D
- rebaugioside M rebaugioside M
- D-allulose, erythritol, etc. are used as substances, and low-concentration amino acids improve sweetness.
- you want to adjust the calories of food to low calories instead of zero you can also add calorie sweeteners such as sucrose, glucose, fructose, and sorbitol as additional sweeteners.
- High sweetness sweetener in the present specification, may be abbreviated as "sweetener (a)” or “ingredient (a)" means a compound having a stronger sweetness than sucrose, and is a naturally derived compound. , Synthetic compounds or combinations of naturally occurring compounds and synthetic compounds. High sweetness sweetener is 5 times or more, 10 times or more, 50 times or more, 100 times or more, 500 times or more, 1,000 times or more, 5,000 times or more, 10,000 times or more, 50,000 times in the same amount as sucrose. It has a sweetness of 100,000 times or more.
- high-sweetness sweeteners include peptide-based sweeteners such as aspartame, neotheme, and advanced, and sucrose derivatives such as sucralose, such as acesurfam K, saccharin, sodium saccharin, sodium cyclamate, zultin, and diglycyrrhizinate.
- Synthetic sweeteners such as sodium, trisodium glycyrrhizinate, neohesperidin dihydrochalcone (including naturally occurring but predominantly synthetic products such as neohesperidin dihydrocarcon), such as somatin and monerin.
- Thunberg Extracts Thaumataococcus daniellii Benth extract, Dioscoreophyllum volkensii extract, Curculigo latifolia extract, Richadella dulcifica extract, Richadella dulcifica extract, Pentadiplandra Masaikai extract, Lippia dulcis (sweet herb Mexican) extract, etc. and sweeteners in the extract, such as stevia extract and stevia derivative such as enzyme-treated stevia, which is obtained by enzymatically treating stevia and adding glucose.
- Glycyrrhiza glabra Plant-containing sweeteners eg, triterpene such as glycyrrhizin
- sugars obtained from plant extracts such as steviol sugar, mogloside obtained by processing Luo Han Guo and Luo Han Guo extract.
- Sugar steviol sugar
- mogloside obtained by processing Luo Han Guo and Luo Han Guo extract.
- Plant-containing sweet ingredients eg, diterpen sugars such as rubusoside
- Hydrorangea macrophylla var eg, diterpen sugars such as rubusoside
- Thaumataococcus daniellii Benth plant-containing sweet components eg, proteins such as somatin
- Dioscoreophyllum volkensii plant-containing sweet components eg, proteins such as monerin
- Curculigo latifolia plant-containing sweet components eg, proteins such as curculin
- Richadella dulcifica plant-containing sweet ingredients eg, proteins such as miraculin
- Pentadiplandra brazzeana plant-containing sweet ingredients eg, brazein, pentadin, etc.
- Capparis masaikai plant-containing sweet ingredients eg, mabinlin, etc.
- Lippia dulcis plant-containing Examples include sweetening components (eg, sesquitelpen such as hernanzultin, 4 ⁇ -hydroxyhernanzultin) and the like.
- Steviol glycosides include rebaugioside A, rebaugioside B, rebaugioside C, rebaugioside D, rebaugioside E, rebaugioside F, rebaugioside I, rebaugioside J, rebaugioside K, rebaugioside M, rebaugioside Q, rebaugioside O, and rebaugioside O.
- A, Zulcoside C, rubusoside, steviol, steviol monoside, steviolbioside, stevioside and the like can be mentioned.
- mogroside include mogroside IV and mogroside V.
- the licorice (licorice) extract is obtained from the roots or rhizomes of Glycyrrhiza uralensis, Glycyrrhiza chinensis or Glycyrrhiza vulgaris, and is mainly composed of glycyrrhizic acid.
- licorice extract include licorice extract, glycyrrhizin, and licorice extract.
- the sucrose derivative includes, for example, one obtained by substituting the OH group or H group of sucrose with another substituent, and examples thereof include a halogen derivative (sucralose) of sucrose and an oxathiadinone dioxide derivative. And so on.
- the high sweetness sweetener is selected from the good quality high sweetness sweeteners.
- the "good-quality, high-sweetness sweetener” has (1) less astringent taste, (2) less metallic taste, and (3) less sweetness aftertaste than Rebaugioside A (RebA).
- (4) Less bitterness means a high-sweetness sweetening substance having one or more taste characteristics selected from. Whether or not a certain sweet substance has the above-mentioned taste characteristics is known or can be determined based on a sensory evaluation or the like.
- Non-limiting examples of good-tasting, high-sweetness sweeteners include, for example, RebD, RebM, Luo Han Guo extract, mogroside (eg, mogroside V), thaumatin, brazzein or a combination thereof.
- the high sweetness sweetener may be naturally occurring in a plant or the like, or may be artificially produced (for example, bioconversion, chemical synthesis, etc.). However, it is preferably a naturally occurring sweetener.
- the term "naturally occurring" does not mean that the high-intensity sweetening substance contained in the fruit juice beverage of the present invention is a natural product, as long as the same substance is naturally present.
- the high-intensity sweetening substance contained in the fruit juice beverage of the present invention may be artificially produced (for example, by bioconversion) (non-natural product).
- Non-limiting examples of the sweetening agent (a) include, for example, rebaugioside A (RebA), rebaugioside D (RebD), rebaugioside M (RebM), neohesperidin dihydrocalcone, glycyrrhizin, thaumatin, monerin, mogloside, rubusoside, curculin, mabinlin. , Brazein, Pentazine, Philozlutin, Hernanzultin, Miraclen, Stevia rebaudiana Plant-containing sweetness ingredient, Siraitia grosvenorii Plant-containing sweetening ingredient, Glycyrrhiza glabra Plant-containing sweetening ingredient, Rubus suavissimus S.
- RebA rebaugioside A
- RebD rebaugioside D
- RebM rebaugioside M
- neohesperidin dihydrocalcone glycyrrhizin, thaumatin, mon
- the sweetener (a) comprises RebA, RebD, RebM, mogroside (eg, mogroside V) or a combination thereof.
- the sweetener (a) comprises RebA, RebD, RebM, mogroside (eg, mogroside V), thaumatin or a combination thereof.
- the high sweetness sweetener comprises at least one selected from the group consisting of RebA, RebD, RebM, mogroside V, Luo Han Guo extract and combinations thereof.
- the sweetener (a) is substantially composed of sweeteners other than the major components of stevia sweeteners such as RebA and stevioside.
- substantially from means that the sweetener used in the present invention may contain the main components of the stevia sweetener as long as the effects of the present invention are not impaired.
- the sweeteners (a) used in the present invention preferably 90% or more, more preferably 95% or more, still more preferably 98% or more consist of sweeteners other than RebA and stevioside.
- RebA, RebD and RebM may be extracted directly from Stevia, or may be obtained by adding glucose to a compound having another structure contained in the Stevia extract.
- Luo Han Guo extract as a sweetener is an extract of Luo Han Guo containing a sweetening substance derived from Luo Han Guo, and is approved as a food additive in various countries including Japan and is commercially available.
- sweetening substance derived from Luo Han Guo include mogroside V, mogroside IV, 11-oxo-mogroside V, and siamenoside I.
- Mogroside V is one of the major mogroside glycosides contained in Luo Han Guo, and it has been reported that it exhibits high-quality sweetness characteristics close to those of sucrose as compared with rebaugioside A.
- Mogroside V can be obtained by purifying from Luo Han Guo extract (for example, alcohol extract of Luo Han Guo) by chromatography or the like.
- mogroside V may be obtained by adding glucose to a compound having another structure contained in the Luo Han Guo extract.
- the Luo Han Guo extract preferably contains mogloside V, the proportion thereof is not limited, and is 10% by weight or more, 15% by weight or more, 20% by weight or more, 25% by weight or more, 30 by weight of the total dry weight of the Luo Han Guo extract. By weight% or more, 35% by weight or more, 40% by weight or more, 45% by weight or more, 50% by weight or more, 55% by weight or more, 60% by weight or more, 65% by weight or more, 70% by weight or more or 75% by weight or more. It may be there.
- the content of mogroside V can be determined by known techniques such as liquid chromatography.
- the fruit of Rakan fruit (Siraitia grosvenorii) is used as an appropriate solvent (for example, an aqueous solvent such as water, an alcohol solvent such as ethanol and methanol, a mixed solvent of an aqueous solvent such as hydrous ethanol and hydrous methanol, and an alcohol solvent. Etc.), and then optionally, degreasing, purification, concentration, drying and the like can be performed.
- an aqueous solvent such as water
- an alcohol solvent such as ethanol and methanol
- a mixed solvent of an aqueous solvent such as hydrous ethanol and hydrous methanol
- an alcohol solvent such as ethanol and methanol
- Mogroside V may be of high purity, for example, purity of 80% or more, 85% or more, 90% or more, 91% or more, 92% or more, 93% or more, 94% or more, 95% or more, 96. It may be% or more, 97% or more, 98% or more, and the like. As a matter of course, the higher the purity of mogroside V obtained by purifying the Luo Han Guo extract, the smaller the amount of the Luo Han Guo extract components other than the mogroside V mixed.
- the mogroside V may be of lower purity, eg, 50% or more, 55% or more, 60% or more, 65% or more, 70% or more or 75% or more. It may be a mogroside.
- sweetness degree 1 the sweetness intensity exhibited by sucrose per unit concentration Brix 1
- the calculated value of the sweetness degree of MogV having a purity of about 65% is about 175.
- Luo Han Guo extract containing about 30% by weight of MogV may be used as a high-sweetness sweetener, and the sweetness intensity exhibited by sucrose per unit concentration Brix 1 is defined as sweetness 1. In this case, the calculated sweetness of this Luo Han Guo extract is about 100.
- the high sweetness sweetener is contained in an amount equivalent to the sweetness intensity Xa as described above.
- sweetness intensity of sucrose per unit concentration Brix 1 is defined as sweetness 1
- the sweetness of rebaugioside D is about 225
- the sweetness of rebaugioside M is about 230
- the sweetness of rebaugioside B is about 325
- the sweetness of rebaugioside A is about 325.
- the degree is 200-300 (median 250)
- the sweetness of rebaugioside N is 200-250 (center value 225)
- the sweetness of rebaugioside O is 200-250 (median 225)
- the sweetness of rebaugioside E is 70-80.
- Luo Han Guo extract (containing 40% MogV) has a sweetness of about 130
- Mogroside V has a sweetness of about 270
- Thaumatin has a sweetness of 2,000
- Brazzein has a sweetness of 500-2000 (Median 1250).
- the value obtained by multiplying these sweetnesses by the concentration of the high-sweetness sweetener in the fruit juice beverage (w / v% (in the case of a beverage, it can be equated with w / w%)) is the sweetness of the high-sweetness sweetener. It becomes strength.
- the above-mentioned sweetness degree center value for those shown in the numerical range
- the relative ratio of the sweetness of various sweeteners to the sweetness of sucrose 1 can be obtained from a known sugar sweetness conversion table (for example, Beverage Japan Co., Ltd. "Beverage Glossary", page 11). In the present specification, the median value is used for those whose sweetness is shown in the numerical range. However, for sweeteners whose sweetness values differ depending on the literature, the relative ratio of the sweetness to the sweetness 1 of sucrose can be determined by a sensory test. As such a sensory test, for example, a sample in which sucrose is added to pure water from Brix 3.0 to 5.0 in 0.5 increments is prepared, and the sample is equivalent to an aqueous solution of a sweetener having a predetermined concentration. A method of selecting a sucrose-added sample having a sweetness intensity can be mentioned.
- the high sweetness sweetener is derived from steviol glycoside, Luo Han Guo extract, mogrol glycoside, Thaumataococcus daniellii Benth plant-containing sweetener, Pentadiplandra brazzeana plant-containing sweetener, artificial sweetener and combinations thereof.
- the high-intensity sweeteners are rebaugioside A, rebaugioside B, rebaugioside C, rebaugioside D, rebaugioside E, rebaugioside F, rebaugioside I, rebaugioside J, rebaugioside K, rebaugioside M, rebaugioside N, rebaugioside.
- Lebaugioside Q Lebaugioside Q, Levaugioside R, Zulcoside A, Zulcoside C, Lubusoside, Steviolmonoside, Steviolbioside, Stevioside, Luo Han Guo extract, Mogloside V, Thaumatin, Brazzein, Aspartame, Acesulfam K, Sclarose, Canzo extract, Saccharin, and its Includes at least one selected from the group consisting of combinations.
- the sweetener (a) comprises the following combinations: RebA and RebM, RebA and RebD, RebD and RebM, RebA and RebD and RebM, RebA and mogroside V, RebD and mogroside V, RebM and mogroside V. , RebA and RebM and mogroside V, RebA and RebD and mogroside V, RebD and RebM and mogroside V, RebA and neohesperidin dihydrocalcon, RebD and neohesperidin dihydrocalcon, RebM and neohesperidin dihydrocalcon, RebA and RebM and neohesperidin dihydro.
- the sweetener (a) comprises the following combinations: RebA and thaumatin, RebD and thaumatin, RebM and thaumatin, Mogloside V and thaumatin, RebA and RebM and thaumatin, RebA and RebD and thaumatin, RebD and RebM. Thaumatin, RebA and Mogroside V and Thaumatin, RebD and Mogroside V and Thaumatin, RebM and Mogroside V and Thaumatin, RebD and RebM and Mogloside V and Thaumatin.
- the sweetener (a) is a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably rebaugioside D, rebaugioside M. And one or more high sweetness sweeteners selected from the combination thereof may be contained.
- the amount of the sweetener (a) contained in the fruit juice beverage according to one aspect of the present invention is an amount obtained by combining all the sweet substances.
- the amount of sweetener (a) is Pa (ppm)
- Pa is, for example, about 20 to about 800, about 25 to about 800, about 30 to about 800, about 35 to about 800, about 40 to about 800, About 45 to about 800, about 50 to about 800, about 55 to about 800, about 20 to about 750, about 25 to about 750, about 30 to about 750, about 35 to about 750, about 40 to about 750, about 45 ⁇ 750 ⁇ 50 ⁇ 750, 55 ⁇ 750, about 20 ⁇ 700, about 25 ⁇ 700, about 30 ⁇ 700, about 35 ⁇ 700, about 40 ⁇ 700, about 45 ⁇ about 700, about 50 to about 700, about 55 to about 700, about 20 to about 650, about 25 to about 650, about 30 to about 650, about 35 to
- the amount of high-sweetness sweetener Pa ppm is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm, or about 150. It may be up to about 350 ppm.
- the fruit juice beverage of the present invention contains (b) an amino acid below the taste recognition threshold, a derivative thereof, or a salt thereof.
- the amino acid or amino acid salt used in the present invention is not particularly limited as long as it is an organic compound having both functional groups of an amino group and a carboxyl group or a salt thereof and which can obtain an effect of increasing sweetness.
- proline and hydroxyproline in which hydrogen of an amino group replaces a side chain portion in a molecule to form a cyclic structure are also included in amino acids herein.
- the amino acid derivative used in the present invention also includes a derivative having no carboxyl group such as taurine.
- amino acids mean free amino acids.
- the amino acid used in the present invention may be D-form, L-form, or racemic-form (also referred to as DL amino acid in the present specification) consisting of D-form and L-form.
- the amino acid can be selected from neutral amino acids, basic amino acids and acidic amino acids.
- the neutral amino acid include glycine having an alkyl group, alanine, valine, isoleucine, leucine, etc., serine having an OH group (hydroxy group), threonine, etc., tyrosine having an aromatic group (or aromatic ring), phenylalanine, tryptophan, etc.
- Metionine having a sulfur-containing group, cysteine and the like, proline having an imino group, hydroxyproline and the like, glutamine having an amide group, asparagine and the like can be suitably selected.
- the basic amino acid arginine, lysine, histidine and the like can be preferably selected.
- the acidic amino acid can be preferably selected from glutamic acid, aspartic acid and the like.
- the amino acid is selected from neutral or basic amino acids.
- the amino acid comprises a basic amino acid and an amino acid selected from a combination thereof among neutral amino acids having an alkyl group, an OH group or an amide group in the side chain.
- those having an alkyl group in the side chain include, for example, glycine, alanine, valine, isoleucine and leucine, and those having an OH group in the side chain include, for example, serine and threonine.
- examples of those having an amide group in the side chain include glutamine and asparagine.
- the amino acid contained in the fruit juice beverage in one aspect of the present invention is one or more of the 22 amino acids forming a protein. Specifically, alanine (Ala), arginine (Arg), asparagine (Asn), aspartic acid (Asp), cysteine (Cys), glutamine (Gln), glutamic acid (Glu), glycine (Gly), histidine (His).
- the amino acid contained in the fruit juice beverage in one aspect of the present invention is one or more selected from amino acids having a molecular weight of 70 to 260.
- amino acids include alanine (molecular weight: 89), arginine (molecular weight: 174), asparagine (molecular weight: 132), aspartic acid (molecular weight: 133), cysteine (molecular weight: 121), glutamine (molecular weight: 146), Glutamic acid (molecular weight: 147), glycine (molecular weight: 75), histidine (molecular weight: 155), isoleucine (molecular weight: 131), leucine (molecular weight: 131), lysine (molecular weight: 146), methionine (molecular weight: 149), phenylalanine (Molecular weight: 165), Proline (Molecular weight: 115), Serine (Molecular weight: 105), Threonin (Molecular weight: 119), Tryptophan (Molecular
- the amino acid is one or more selected from amino acids having a molecular weight of 75 to 204, more preferably one or more selected from amino acids having a molecular weight of 75 to 174, and further preferably having a molecular weight. Is one or more selected from 75 to 146 amino acids.
- the amino acid or a salt thereof is L-Asparagine, L-Aspartic acid, Monosodium L-Aspartate, DL-Alanine, L-Alanine, L-Alanine solution, L-Arginine, L-Arginine L-glutamate, L-glutamate (L) -Glutamine), L-Cystine, L-Cystein Monohydrochloride, L-Serine, L-Tyrosine, L-Glutamic Acid Acid), L-Ammonium L-Glutamate (Monoammonium L-Glutamate), Potassium L-Glutamate (Monopotassium L-Glutamate), Calcium L-Glutamic Acid (Monocalcium Di-L-Glutamate), Sodium L-Glutamic Acid (also known as sodium glutamate) (Monosodium L -Glutamate), L-Glutamic Acid (Monomagnesium Di-L-Glutamate), Gly
- amino acids include amino acids selected from glycine, alanine, valine, isoleucine, leucine, serine, threonine, glutamine, asparagine, arginine, lysine, histidine and combinations thereof.
- the amino acid or derivative thereof or salt thereof comprises an amino acid selected from DL-alanine, L-serine, glycine, L-arginine, L-glutamic acid, L-valine and L-glutamine. May be good.
- the amino acid or derivative thereof or a salt thereof is arginine, lysine, histidine, phenylalanine, tyrosine, leucine, isoleucine, methionine, valine, alanine, glycine, proline, glutamic acid, serine, threonine, aspartic acid and It may contain one or more amino acids selected from tryptophan.
- the amino acid or derivative thereof or salt thereof comprises one or more amino acids selected from arginine, valine, alanine, glycine, proline, glutamic acid, serine, threonine, aspartic acid and tryptophan. You may.
- the amino acid threshold means a detection threshold or a taste recognition threshold.
- the detection threshold means a minimum concentration that can clearly indicate the difference from water, but does not necessarily have to be able to recognize the type of taste (eg, bitterness, acidity, sweetness, etc.).
- the taste cognitive threshold means the minimum concentration at which taste can be recognized (for example, Eur J Clin Nutr (2004) 58, 629-636).
- Amino acid thresholds are summarized in Susan S. Schiffman et al., “Comparison of Taste Qualities and Thresholds of D-and L-Amino Acids”, Physiology & Behavior, Vol. 27, pp. 51-59 (1981). ing.
- the detection thresholds for each amino acid are: glycine (30.9mM), L-threonine (25.7mM), L-serine (20.9mM), L-alanine (16.2mM), L-proline (15.1mM). ), L-Glutamine (9.77mM), L-isoleucine (7.41mM), L-phenylalanine (6.61mM), L-leucine (6.45mM), L-valine (4.16mM), L-methionine (3.72mM), L-tryptophan (2.29mM), L-aspartin (1.62mM), L-histidine (1.23mM), L-arginine (1.20mM), L-lysine (0.708mM), L-aspartic acid (0.182mM), L -Glutamic acid (0.063mM), L-cysteine (0.063mM).
- the taste recognition threshold is about 1.5 to 2 times the detection threshold (Yuki Yamauchi et al., "Whole oral taste test (1st report) -basic study and main component analysis-”. , Japan Otolaryngology Society Bulletin Vol. 98 (1995) No. 1, p.119-129, and Reiko Omori, "Comparison of Taste Sensitivity Between Generations", Utsunomiya University Faculty of Education Bulletin, Part 1 (2013) Vol.63 p.201-210)).
- the taste recognition threshold value of an amino acid can be obtained by a sensory test in which an amino acid-containing aqueous solution is prepared at a plurality of concentration levels, tasted in order from the one with the lowest concentration to the one with the highest concentration, and whether or not the taste is felt.
- the concentration at which it is detected to be different from water is defined as the detection threshold
- the concentration at which taste is recognized is defined as the cognitive threshold.
- an amino acid that already has a theoretical value (literature value) can be determined by preparing an aqueous solution having a plurality of concentration levels near the concentration and testing by a plurality of persons trained in sensory.
- the detection threshold described in the literature is 16.2 mM
- the theoretical cognitive threshold calculated from the detection threshold is 32.4 mM, so that 5 mM, 10 mM, 15 mM, 20 mM, 25 mM, and 30 mM.
- the cognitive threshold can be measured by performing a sensory test with multiple levels of aqueous solution selected from 35 mM.
- the amino acid taste recognition threshold means the taste recognition threshold in pure water.
- the taste recognition threshold value in pure water means the minimum concentration at which the taste can be recognized when only amino acids are added to water without adding a sweetener or the like.
- the fruit juice beverage contains glycine, and the content of glycine is more than 0 mM and 80 mM or less, 75 mM or less, less than 75 mM, 70 mM or less, 65 mM or less, 60 mM or less, 55 mM or less, 50 mM or less, less than 50 mM, 45 mM. Below, it may be 40 mM or less, 35 mM or less, 30 mM or less, 25 mM or less, 20 mM or less, 15 mM or less, or 10 mM or less.
- the fruit juice beverage contains alanine and the alanine content is more than 0 mM and less than 32.4 mM, less than 30 mM, less than 30 mM, 25 mM or less, 20 mM or less, less than 20 mM, less than 15 mM or less than 10 mM. good.
- Alanine may be L-form, D-form or racemic (DL-form), but is preferably L-form.
- the fruit juice beverage contains valine and the valine content is more than 0 mM and less than 50 mM, less than 50 mM, less than 45 mM, 40 mM or less, less than 40 mM, 35 mM or less, 30 mM or less, less than 30 mM, 25 mM or less, 20 mM.
- it may be 15 mM or less or 10 mM or less.
- the fruit juice beverage may contain isoleucine, and the content of isoleucine may be more than 0 mM and 25 mM or less, 20 mM or less, 15 mM or less, 10 mM or less or 5 mM or less. Alternatively, at 1-25mM, 5-25mM, 10-25mM, 15-25mM, 20-25mM, 1-20mM, 5-20mM, 10-20mM, 15-20mM, 1-15mM, 5-15mM or 10-15mM. There may be. Isoleucine may be L-form, D-form or racemic (DL-form), but is preferably L-form.
- the fruit juice beverage contains leucine, and the leucine content is more than 0 mM and 50 mM or less, 45 mM or less, 40 mM or less, 35 mM or less, 30 mM or less, less than 30 mM, 25 mM or less, 20 mM or less, less than 20 mM, 15 mM.
- it may be 13 mM or less, 12 mM or less, 11 mM or less, 10 mM or less, less than 10 mM, 9 mM or less, 8 mM or less, 7 mM or less, 6 mM or less, 5 mM or less, 4 mM or less, 3 mM or less, 2 mM or less or 1 mM or less.
- the fruit juice beverage contains serine, and the serin content is more than 0 mM and 130 mM or less, 100 mM or less, 80 mM or less, 50 mM or less, 50 mM or less, 45 mM or less, 40 mM or less, 40 mM or less, 35 mM or less, 30 mM.
- the serin content is more than 0 mM and 130 mM or less, 100 mM or less, 80 mM or less, 50 mM or less, 50 mM or less, 45 mM or less, 40 mM or less, 40 mM or less, 35 mM or less, 30 mM.
- it may be 25 mM or less, 20 mM or less, 15 mM or less, or 10 mM or less.
- 10 to 130mM 10 to 100mM, 10 to 80mM, 20 to 80mM, 30 to 80mM, 40 to 80mM, 50 to 80mM, 60 to 80mM, 70 to 80mM, 10 to 70mM, 20 to 70mM, 30 to 70mM, 40 to 70mM, 50 to 70mM, 60 to 70mM, 10 to 60mM, 20 to 60mM, 30 to 60mM, 40 to 60mM, 50 to 60mM, 10 to 50mM, 20 to 50mM, 30 to 50mM, 40 to 50mM, 10 to 40mM, 20-40mM, 30-40mM, 10-30mM, 20-30mM, 5-45mM, 5-40mM, 5-35mM, 5-30mM, 5-25mM, 5-20mM, 5-15mM, 5-10mM, It may be 1 to 45 mM, 1 to 40 mM, 1 mM or more and less than 40 mM, 1 to 35 mM, 1 to 30
- the fruit juice beverage contains threonine, and the threonine content is more than 0 mM and 70 mM or less, 65 mM or less, 60 mM or less, 55 mM or less, 50 mM or less, 50 mM or less, 45 mM or less, 40 mM or less, 40 mM or less, 35 mM.
- it may be 30 mM or less, 25 mM or less, 20 mM or less, 15 mM or less, or 10 mM or less.
- the fruit juice beverage contains phenylalanine, and the content of phenylalanine is more than 0 mM and 15 mM or less, 13 mM or less, 12 mM or less, 11 mM or less, 10 mM or less, 9 mM or less, 8 mM or less, 7 mM or less, 6 mM or less, 5 mM.
- it may be 4 mM or less, 3 mM or less, 2 mM or less, or 1 mM or less.
- Phenylalanine may be L-form, D-form or racemic (DL-form), but is preferably L-form.
- the fruit juice beverage may contain tryptophan and the tryptophan content may be more than 0 mM and 5 mM or less, 4 mM or less, 3 mM or less, 2 mM or less or 1 mM or less. Alternatively, it may be 1 to 5 mM, 2 to 5 mM, 3 to 5 mM or 4 to 5 mM. Tryptophan may be L-form, D-form or racemic (DL-form), but is preferably L-form.
- the fruit juice beverage contains methionine and the methionine content is more than 0 mM and 10 mM or less, 9 mM or less, 8 mM or less, 7 mM or less, 6 mM or less, 5 mM or less, 4 mM or less, 3 mM or less, 2 mM or less or 1 mM. It may be as follows. Alternatively, it may be 1 to 10 mM, 2 to 10 mM, 3 to 10 mM, 4 to 10 mM, 5 to 10 mM, 6 to 10 mM, 7 to 10 mM, 8 to 10 mM or 9 to 10 mM.
- the methionine may be L-form, D-form or racemic (DL-form), but is preferably L-form.
- the fruit juice beverage contains proline
- the content of proline is more than 0 mM and 120 mM or less, 100 mM or less, 80 mM or less, 50 mM or less, 50 mM or less, 45 mM or less, 40 mM or less, 40 mM or less, 35 mM or less, 30 mM.
- it may be 25 mM or less, 20 mM or less, 15 mM or less, or 10 mM or less.
- 10 to 120mM 10 to 100mM, 10 to 80mM, 20 to 80mM, 30 to 80mM, 40 to 80mM, 50 to 80mM, 60 to 80mM, 70 to 80mM, 10 to 70mM, 20 to 70mM, 30 to 70mM, 40-70mM, 50-70mM, 60-70mM, 10-60mM, 20-60mM, 30-60mM, 40-60mM, 50-60mM, 10-50mM, 20-50mM, 30-50mM, 40-50mM, 1mM or more It may be less than 40 mM, 10-40 mM, 20-40 mM, 30-40 mM, 1-30 mM, 5-30 mM, 10-30 mM, 15-30 mM, 20-30 mM or 25-30 mM.
- Proline may be L-form, D-form or racemic (DL-form), but is preferably L-form.
- the fruit juice beverage contains glutamine, and the glutamine content is more than 0 mM and 20 mM or less, 19 mM or less, 18 mM or less, 17 mM or less, 16 mM or less, 15 mM or less, 14 mM or less, 13 mM or less, 12 mM or less, 11 mM.
- it may be 10 mM or less, less than 10 mM, 9 mM or less, 8 mM or less, 7 mM or less, 6 mM or less, 5 mM or less, less than 5 mM, 4 mM or less, 3 mM or less, 2 mM or less or 1 mM or less.
- the fruit juice beverage contains asparagine, and the content of asparagine is more than 0 mM and less than 20 mM, less than 20 mM, 19 mM or less, 18 mM or less, 17 mM or less, 16 mM or less, 15 mM or less, 14 mM or less, 13 mM or less, 12 mM. Below, it may be 11 mM or less, 10 mM or less, less than 10 mM, 9 mM or less, 8 mM or less, 7 mM or less, 6 mM or less, 5 mM or less, 4 mM or less, 5 mM or less, 2 mM or less or 1 mM or less.
- the fruit juice beverage contains arginine, and the content of arginine is more than 0 mM and less than 4.0 mM, 3.5 mM or less, 3.0 mM or less, 2.5 mM or less, less than 2.5 mM, 2.0 mM or less, 1.5 mM or less, It may be 1.0 mM or less, less than 1.0 mM or 0.5 mM or less.
- Arginine may be L-form, D-form or racemic (DL-form), but is preferably L-form.
- the fruit juice beverage may contain lysine and the lysine content may be greater than 0 mM and less than 3.0 mM, 2.5 mM or less, 2.0 mM or less, 1.5 mM or less, 1.0 mM or less or 0.5 mM or less. .. Alternatively, 0.1-3.0mM, 0.1-2.5mM, 0.1-2.0mM, 0.1-1.5mM, 0.1-1.0mM, 0.1-0.5mM, 0.5-3.0mM, 0.5-2.5mM, 0.5-2.0mM, 0.5-1.5 It may be mM or 0.5-1.0 mM. Lysine may be L-form, D-form or racemic (DL-form), but is preferably L-form.
- the fruit juice beverage contains lysine hydrochloride, and the content of lysine hydrochloride is more than 0 mM and 1.0 mM or less, 0.9 mM or less, 0.8 mM or less, 0.7 mM or less, 0.6 mM or less, 0.5 mM or less, It may be less than 0.5 mM, 0.4 mM or less, less than 0.4 mM, 0.3 mM or less, or 0.2 mM or less.
- the fruit juice beverage contains histidine, and the histidine content is more than 0 mM and 4.0 mM or less, 3.5 mM or less, 3.0 mM or less, 2.5 mM or less, 2.0 mM or less, 1.5 mM or less, 1.0 mM or less or. It may be 0.5 mM or less.
- the fruit juice beverage contains glutamate, and the content of glutamate is more than 0 mM and less than 0.50 mM, less than 0.50 mM, 0.40 mM or less, less than 0.40 mM, 0.35 mM or less, 0.30 mM or less, 0.25 mM or less, Less than 0.25mM, 0.20mM or less, 0.15mM or less, 0.14mM or less, 0.13mM or less, 0.12mM or less, 0.11mM or less, 0.10mM or less, 0.09mM or less, 0.08mM or less, 0.07mM or less, 0.06mM or less, 0.05mM Hereinafter, it may be 0.04 mM or less, 0.03 mM or less, 0.02 mM or less, or 0.01 mM or less.
- the fruit juice beverage contains aspartic acid, and the content of aspartic acid is more than 0 mM and 1.5 mM or less, 1.4 mM or less, 1.3 mM or less, 1.2 mM or less, 1.1 mM or less, 1.0 mM or less, 0.9 mM.
- it may be 0.8 mM or less, 0.7 mM or less, 0.6 mM or less, 0.5 mM or less, 0.4 mM or less, 0.3 mM or less, 0.2 mM or less, or 0.1 mM or less.
- Aspartic acid may be L-form, D-form or racemic (DL-form), but is preferably L
- the fruit juice beverage according to one aspect of the present invention does not contain sodium aspartate as an amino acid salt.
- the amino acid content can be measured by automatic amino acid analysis or high performance liquid chromatography. If the blending amount of the amino acid blended in the beverage is known, the value calculated from the blending amount may be used.
- the amino acid is also included in the amino acid in the fruit juice beverage of the present invention. Therefore, the amount of amino acids contained in the fruit juice beverage of the present invention is the total value of those derived from fruit juice and those added from the outside.
- the content of at least one kind of amino acid may be less than the taste recognition threshold value, and the content of some amino acids sets the taste recognition threshold value. It may be exceeded.
- the content of each amino acid may be less than the taste recognition threshold value.
- Yet another aspect of the fruit juice beverage of the present invention is DL-alanine ⁇ 20 mM, L-serine ⁇ 40 mM, glycine ⁇ 50 mM, L-arginine ⁇ 1 mM, L-glutamic acid ⁇ 0.25 mM, L ⁇ 40 mM.
- -Selected from valine, L-glutamine less than 5 mM, L-leucine less than 20 mM, L-threonine less than 40 mM, L-proline less than 40 mM, L-asparagin less than 10 mM and L-lysine hydrochloride less than 0.4 mM May contain one or more amino acids.
- Yet another aspect of the fruit juice beverage of the present invention is DL-alanine of 1 mM or more and less than 20 mM, L-serine of 1 mM or more and less than 40 mM, glycine of 1 mM or more and less than 50 mM, L-arginine of 0.1 mM or more and less than 1.0 mM, 0.10 mM.
- the fruit juice beverage of the present invention may contain a sweetener in addition to the high sweetness sweetener of the component (a).
- sweetener means any substance or group of substances that causes a sweetening response.
- the sweeteners can be divided into sugar-based sweeteners and non-sugar-based sweeteners according to their structural characteristics, and low-sweetness sweeteners and high-sweetness sweeteners based on the degree of sweetness.
- sweeteners can be divided into caloric sweeteners and non-caloric sweeteners.
- it can be divided into natural sweeteners and artificial sweeteners based on the acquisition method. If the fruit juice contains a fruit-derived sweetener (fructose, etc.), the sweetener shall also be included in the sweeteners described here.
- Carbohydrate-based sweeteners are not limited to starch sugars such as sucrose, lactose, glucose, maltose, water candy, isomerized sugar, and fructose, and sugar alcohols such as erythritol, sorbitol, mannitol, martitol, xylitol, and palatinit. , Sucrose, palatinose, fructo-oligosaccharide, coupling sugar (R) , galactooligosaccharide, milk fruit oligosaccharide, raffinose, soybean oligosaccharide, honey and the like. In addition, sugar-based sweeteners contain rare sugars.
- Rare sugar refers to monosaccharides and their derivatives whose abundance is small in nature. For example, naturally occurring aldoses other than D-glucose, D-galactose, D-mannose, D-ribose, D-xylose and L-arabinose, naturally occurring ketose other than D-fractose, natural other than D-sorbitol.
- the sugar alcohols and the like present in the rare sugars are included in the rare sugars.
- Non-limiting examples of rare sugars include, for example, D-tagatose, D-sorbose, D-alloth (D-psicose), L-fractose, L-allulose (L-psicose), L-tagatose, L-sorbose, etc.
- Examples thereof include aldoses such as ketose, altrose and D-allose, and sugar alcohols such as xylitol, erythritol and D-talitol.
- Caloric sweeteners typically mean sweeteners with an energy of 4 kcal / g. Whether the energy of the sweet substance is known, the content is measured by HPLC etc. and calculated by multiplying by the energy conversion coefficient, or the physical combustion heat is measured by a calorimeter (for example, bomb calorimeter etc.). Can be determined by correcting the digestion and absorption rate, the amount of heat excreted, and the like.
- caloric sweeteners include, for example, sucrose, lactose, glucose, maltose, starch syrup, high fructose corn syrup, fructose, and the like.
- Non-caloric sweeteners typically refer to those that are difficult to digest in the body and result in less energy being taken in, less than 2 kcal / g, preferably less than 1 kcal / g, more preferably. It means a sweetening substance having an energy of less than 0.5 kcal / g.
- Non-caloric examples of non-caloric sweeteners include, for example, non-caloric hexoses such as allose (psicose) and allose, non-caloric pentoses such as xylose and arabinose, non-caloric tetrose such as erythrose and treose, erythritol and aritol.
- Non-caloric sugar alcohols such as, etc. may be mentioned.
- sweet substances can be classified by energy (calorie) level.
- sweet substances can be classified into sweet substances having an energy of 4 kcal / g or more and sweet substances having an energy of less than 4 kcal / g.
- Sweet substances with energy less than 4 kcal / g are further sweet substances with energy less than 3 kcal / g, sweet substances with energy less than 2.5 kcal / g, sweet substances with energy less than 2 kcal / g, 1.5 kcal / Sweet substance with energy less than g, sweet substance with energy less than 1 kcal / g, sweet substance with energy less than 0.5 kcal / g, sweet substance with energy more than 1 kcal / g and less than 4 kcal / g, 2 kcal / Sweet substance with energy of g or more and less than 4 kcal / g, sweet substance with energy of 3 kcal / g or more and less than 4 kcal / g, sweet substance with energy of 2 kcal /
- Sucrose, lactose, glucose, maltose, water candy, isomerized sugar, fructose, etc. are sweet substances having an energy of 4 kcal / g or more
- sorbitol is a sweet substance having an energy of 2 kcal / g or more and less than 4 kcal / g.
- Xylitol, D-xylose, D-ribose, D-tagatose, arabinose, etc. are sweet substances having an energy of 0 kcal / g or more and less than 2 kcal / g, such as D-allulose, erythritol, allose, erythrose, threose, and alitor. And so on.
- the low-sweetness sweetener means a compound having a sweetness similar to that of sucrose (for example, less than 5 times, 0.1 to 2 times, 0.5 to 1.5 times, etc. of sucrose).
- Non-limiting examples of low-sweetness sweeteners include sucrose, high fructose corn syrup, glucose, fructose, lactose, maltose, xylitol, lactulose, fructo-oligosaccharide, malto-oligosaccharide, isomaltooligosaccharide, galactooligosaccharide, and coupling sugar (R).
- low-sweetness sweeteners include rare sugars, caloric sweeteners, non-caloric sweeteners, sugar-based sweeteners, non-sugar-based sweeteners, natural sweeteners, and so on, as long as the sweetness is within the above range. Contains artificial sweeteners.
- the fruit juice beverage according to one aspect of the present invention contains a low-sweetness sweetener.
- the following fruit juice beverage (hereinafter, also referred to as the fruit juice beverage of aspect A) is provided.
- Xc and Xd are referred to as X4 and X6 in the first aspect, respectively.
- the fruit juice beverage according to one embodiment of the present invention does not contain any component other than (a) a high sweetness sweetener equivalent to the sweetness intensity Xa and (c) a low sweetness sweetener equivalent to the sweetness intensity Xc. ..
- the fruit-derived sweetener (fructose, etc.) contained in the fruit juice beverage is included in the sweetener of (c).
- the low sweetness sweetener comprises a sweetener selected from hexose, pentose, tetrose, polysaccharides having aldose or ketose terminal sugars, sugar alcohols and combinations thereof.
- the low sweetness sweetener is selected from glucose, sucrose, fructose, maltose, oligosaccharides, high fructose corn syrup, lactose, psicose, allose, tagatose, xylose, ribose and combinations thereof. including.
- the low sweetness sweetener comprises a sweetener selected from glucose, sucrose, fructose and combinations thereof.
- Xc of "sweetness intensity Xc" is 0 to 0.5, 0 to 1.0, 0 to 1.5, 0 to 2.0, 0 to 2.5, 0 to 3.0, 0 to 3.5, 0 to 4.0, 0 to 4.5, 0 to 5.0, 0 to 5.5, 0-6.0, 0-6.5, 0-7.0, 0-7.5, 0-8.0, 0-8.25, 0-8.5, 0-8.75, 0-9.0, 0-9.25, 0-9.5, 0-9.75, 0 to 10.0, 0.05 to 0.5, 0.05 to 1.0, 0.05 to 1.5, 0.05 to 2.0, 0.05 to 2.5, 0.05 to 3.0, 0.05 to 3.5, 0.05 to 4.0, 0.05 to 4.5, 0.05 to 5.0, 0.05 to 5.5, 0.05 to 6.0, 0.05-6.5, 0.05-7.0, 0.05-7.5, 0.05-8.0, 0.05-8.25, 0.05-8.5, 0.05-8.75, 0.05-9.0, 0.05-9.25
- Xc is also 0 to 10.5, 0 to 11.0, 0 to 11.5, 0 to 12.0, 0 to 12.5, 0 to 13.0, 0 to 13.5, 0 to 14.0, 0 to 14.5, 0 to 15.0, 0.05 to 10.5, 0.05 to 11.0, 0.05-11.5, 0.05-12.0, 0.05-12.5, 0.05-13.0, 0.05-13.5, 0.05-14.0, 0.05-14.5, 0.05-15.0, 0.1-10.5, 0.1-11.0, 0.1-11.5, 0.1-12.0, 0.1 to 12.5, 0.1 to 13.0, 0.1 to 13.5, 0.1 to 14.0, 0.1 to 14.5, 0.1 to 15.0, 0.5 to 10.5, 0.5 to 11.0, 0.5 to 11.5, 0.5 to 12.0, 0.5 to 12.5, 0.5 to 13.0, 0.5 to 13.5, 0.5-14.0, 0.5-14.5, 0.5-15.0, 1.0-10.5, 1.0-11.0, 1.0-11.5, 1.0-12.0, 1.0-12.5, 1.0-13.0, 1.0
- the amount equivalent to the sweetness intensity Xc of the low-sweetness sweetener is the amount (concentration) that exhibits the sweetness of the low-sweetness sweetener under the condition that the low-sweetness sweetener is dissolved in 20 ° C. water having the same volume as the fruit juice beverage of the present invention. To say.
- Xc is preferably 0.05 to 6.0, more preferably 0.05 to 5.0, and even more preferably 0.1 to 4.0.
- Xd is not particularly limited as long as it is larger than Xa + Xc, but 4.0 to 20, 4.0 to 15, 4.0 to 12.5, 4.0 to 10, 4.5 to 20, 4.5 to 15, 4.5 to 12.5, 4.5 to 10, 5.0.
- ⁇ 20 5.0 ⁇ 15, 5.0 ⁇ 12.5, 5.0 ⁇ 10, 5.5 ⁇ 20, 5.5 ⁇ 15, 5.5 ⁇ 12.5, 5.5 ⁇ 10, 6.0 ⁇ 20, 6.0 ⁇ 15, 6.0 ⁇ 12.5, 6.0 ⁇ 10, 6.5 ⁇ 20 , 6.5 ⁇ 15, 6.5 ⁇ 12.5, 6.5 ⁇ 10, 7.0 ⁇ 20, 7.0 ⁇ 15, 7.0 ⁇ 12.5, 7.0 ⁇ 10, 7.5 ⁇ 20, 7.5 ⁇ 15, 7.5 ⁇ 12.5, 7.5 ⁇ 10, 7.5 ⁇ 9, 7.5 ⁇ 8, 8.0 ⁇ 20, 8.0 ⁇ 20, 8.0 ⁇ 20, 8.0 ⁇ 15, 8.0 ⁇ 12, 8.0 ⁇ 15, 8.0 ⁇ 12.5, 8.0 ⁇ 10, 8.5 ⁇ 20, 8.5 ⁇ 15, 8.5 ⁇ 12.
- Xd is also 4.0-18, 4.0-16, 4.0-15.5, 4.0-14, 4.5-18, 4.5-16, 4.5-15.5, 4.5-14, 5.0-18, 5.0-16, 5.0-15.5, 5.0-14, 5.5-18, 5.5-16, 5.5-15.5, 5.5-14, 6.0-18, 6.0-16, 6.0-15.5, 6.0-14, 6.5-18, 6.5-16, 6.5-15.5, 6.5- 14, 7.0-18, 7.0-16, 7.0-15.5, 7.0-14, 7.5-18, 7.5-16, 7.5-15.5, 7.5-14, 7.5-9, 7.5-8, 8.0-18, 8.0-18, 8.0-16, 8.0-15.5, 8.0-14, 8.5-18, 8.5-16, 8.5-15.5, 8.5-14, 9.0-18, 9.0-16, 9.0-15.5, 9.0-14, 9.5-18, 9.5- It may be 16, 9.5 to 15.5, 9.5 to 14, 10.0 to 18, 10.0 to 16, 10.0 to 15.5, 10.5 to 18, 10.5 to 16 or 10.5 to 15.5.
- the fruit juice beverages of the first and A1 aspects of the present invention may contain a small amount of sodium.
- the sodium content is 0 mg / 100 ml or more and less than 5 mg / 100 ml, 0 to 4.5 mg / 100 ml, 0 to 4.0 mg / 100 ml, 0 to 3.5 mg / 100 ml, 0 to 3.0 mg / 100 ml, 0, depending on the embodiment.
- sodium is derived from fruit juice or unavoidably mixed, and is not added.
- the content of sodium in a beverage can be measured by atomic absorption spectroscopy.
- the fruit juice beverage of the present invention is an antioxidant (sodium erythorsorbate, etc.), an emulsifier (sucrose fatty acid ester, sorbitan fatty acid ester, polyglycerin fatty acid ester, etc.), and an acidulant (phosphoric acid) as long as the effects of the present invention are not impaired.
- an antioxidant sodium erythorsorbate, etc.
- an emulsifier sucrose fatty acid ester, sorbitan fatty acid ester, polyglycerin fatty acid ester, etc.
- an acidulant phosphoric acid
- Example of the fruit juice beverage according to the first aspect of the present invention contains (a) a high-intensity sweetener in an amount equivalent to the sweetness intensity Xa, and (b) an amino acid below the taste recognition threshold or a derivative thereof or a salt thereof.
- the components (a) and (b) exhibit sweetness with a sweetness intensity of Xb, and 0.1 ⁇ Xa ⁇ Xb.
- the high-sweetness sweetener is selected from a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- Xa is 0.5 to 5.5, preferably 1.0 to 5.5, more preferably 2.0 to 5.0.
- a fruit juice beverage is provided in which the amino acid or a derivative thereof or a salt thereof contains an amino acid selected from DL-alanine, L-serine, glycine, L-arginine, L-glutamic acid, L-valine and L-glutamine.
- the amount of high sweetness sweetener is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm or about 150 to about 350 ppm. May be.
- a high-intensity sweetener in an amount equivalent to the sweetness intensity Xa, and (b) an amino acid below the taste recognition threshold or a derivative thereof or a salt thereof.
- the components (a) and (b) exhibit sweetness with a sweetness intensity of Xb, and 0.1 ⁇ Xa ⁇ Xb.
- the high-sweetness sweetener is selected from a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- Xa is 0.5 to 10.0, preferably 1.5 to 9.0, more preferably 2.0 to 8.0
- a fruit juice beverage is provided in which the amino acid or a derivative thereof or a salt thereof contains an amino acid selected from DL-alanine, L-serine, glycine, L-arginine, L-glutamic acid, L-valine and L-glutamine.
- the amount of high sweetness sweetener is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm or about 150 to about 350 ppm. May be.
- a high-sweetness sweetener in an amount equivalent to a sweetness intensity Xa
- B Amino acid below the taste recognition threshold or a derivative thereof or a salt thereof
- a low-sweetness sweetener in an amount equivalent to the sweetness intensity Xc.
- the components (a) to (c) exhibit sweetness with a sweetness intensity of Xd, and 0.1 ⁇ Xa + Xc ⁇ Xd.
- the high-sweetness sweetener is selected from a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- Xa is 0.5 to 5.5, preferably 1.0 to 5.5, more preferably 2.0 to 5.0.
- Amino acids or derivatives thereof or salts thereof contain amino acids selected from DL-alanine, L-serine, glycine, L-arginine, L-glutamic acid, L-valine and L-glutamine.
- Low sweeteners include sweeteners selected from glucose, sucrose, fructose, maltose, oligosaccharides, high fructose corn syrup, lactose, psicose, allose, tagatose, xylose, ribose and combinations thereof.
- Juice beverages are provided in which the Xc is 0.05-6.0, preferably 0.05-5.0, more preferably 0.1-4.0.
- the amount of high sweetness sweetener is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm or about 150 to about 350 ppm. May be.
- a high-sweetness sweetener in an amount equivalent to a sweetness intensity Xa
- B Amino acid below the taste recognition threshold or a derivative thereof or a salt thereof
- a low-sweetness sweetener in an amount equivalent to the sweetness intensity Xc.
- the components (a) to (c) exhibit sweetness with a sweetness intensity of Xd, and 0.1 ⁇ Xa + Xc ⁇ Xd.
- the high-sweetness sweetener is selected from a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- Xa is 0.5 to 5.5, preferably 1.0 to 5.5, and more preferably 2.0 to 5.0.
- Amino acids or derivatives thereof or salts thereof contain amino acids selected from DL-alanine, L-serine, glycine, L-arginine, L-glutamic acid, L-valine and L-glutamine.
- Low sweeteners include sweeteners selected from glucose, sucrose, fructose, maltose, oligosaccharides, high fructose corn syrup, lactose, psicose, allose, tagatose, xylose, ribose and combinations thereof.
- the juice ratio is 1-100%, 4-95%, 5-80%, 5-50% or 5-30%.
- Juice beverages are provided in which the Xc is 0.05-6.0, preferably 0.05-5.0, more preferably 0.1-4.0.
- the amount of high sweetness sweetener is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm or about 150 to about 350 ppm. May be.
- a high-sweetness sweetener in an amount equivalent to a sweetness intensity Xa
- B Amino acid below the taste recognition threshold or a derivative thereof or a salt thereof
- a low-sweetness sweetener in an amount equivalent to the sweetness intensity Xc.
- the components (a) to (c) exhibit sweetness with a sweetness intensity of Xd, and 0.1 ⁇ Xa + Xc ⁇ Xd.
- the high-sweetness sweetener is selected from a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- Xa is 0.5 to 5.5, preferably 1.0 to 5.5, more preferably 2.0 to 5.0.
- Amino acids or derivatives thereof or salts thereof have DL-alanine less than 20 mM, L-serine less than 40 mM, glycine less than 50 mM, L-arginine less than 1 mM, L-glutamic acid less than 0.25 mM, L-valine less than 40 mM, Amino acids selected from less than 5 mM L-glutamine, less than 20 mM L-leucine, less than 40 mM L-threonine, less than 40 mM L-proline, less than 10 mM L-asparagin and less than 0.4 mM L-lysine hydrochloride Including, Low sweeteners include sweeteners selected from glucose, sucrose, fructose, maltose, oligosaccharides, high fructose corn syrup, lactose, psicose, allose, tagatose, xylose, ribose and combinations thereof.
- Juice beverages are provided in which the Xc is 0.05-6.0, preferably 0.05-5.0, more preferably 0.1-4.0.
- the amount of high sweetness sweetener is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm or about 150 to about 350 ppm. May be.
- a high-sweetness sweetener in an amount equivalent to a sweetness intensity Xa
- B Amino acid below the taste recognition threshold or a derivative thereof or a salt thereof
- a low-sweetness sweetener in an amount equivalent to the sweetness intensity Xc.
- the components (a) to (c) exhibit sweetness with a sweetness intensity of Xd, and 0.1 ⁇ Xa + Xc ⁇ Xd.
- the high-sweetness sweetener is selected from a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- Xa is 0.5 to 5.5, preferably 1.0 to 5.5, more preferably 2.0 to 5.0.
- Amino acids or derivatives thereof or salts thereof contain amino acids selected from arginine, lysine, histidine, phenylalanine, tyrosine, leucine, isoleucine, methionine, valine, alanine, glycine, proline, glutamic acid, serine, threonine, aspartic acid and tryptophan.
- Low sweetness sweeteners include sweeteners selected from glucose, sucrose, fructose and combinations thereof.
- the juice is one or more selected from oranges, oranges, lemons, grapefruits, limes and combinations thereof.
- the juice ratio is 1-100%, 4-95%, 5-80%, 5-50% or 5-30%.
- Juice beverages are provided in which the Xc is 0.05-6.0, preferably 0.05-5.0, more preferably 0.1-4.0.
- the amount of high sweetness sweetener is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm or about 150 to about 350 ppm. May be.
- a high-sweetness sweetener in an amount equivalent to a sweetness intensity Xa
- B Amino acid below the taste recognition threshold or a derivative thereof or a salt thereof
- a low-sweetness sweetener in an amount equivalent to the sweetness intensity Xc.
- the components (a) to (c) exhibit sweetness with a sweetness intensity of Xd, and 0.1 ⁇ Xa + Xc ⁇ Xd.
- the high-sweetness sweetener is selected from a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- Xa is 0.5 to 5.5, preferably 1.0 to 5.5, more preferably 2.0 to 5.0.
- Amino acids or derivatives thereof or salts thereof contain amino acids selected from arginine, valine, alanine, glycine, proline, glutamic acid, serine, threonine, aspartic acid and tryptophan.
- Low sweetness sweeteners include sweeteners selected from glucose, sucrose, fructose and combinations thereof.
- the juice is one or more selected from blueberries, cassis, cranberries, strawberries, raspberries and combinations thereof.
- the juice ratio is 1-100%, 4-95%, 5-80%, 5-50% or 5-30%.
- Juice beverages are provided in which the Xc is 0.05-6.0, preferably 0.05-5.0, more preferably 0.1-4.0.
- the amount of high sweetness sweetener is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm or about 150 to about 350 ppm. May be.
- High-sweetness sweetener in an amount equivalent to sweetness intensity Xa, It contains (b) one or more amino acids selected from alanine, serine and glycine, and (c) a low sweetness sweetener in an amount equivalent to the sweetness intensity Xc.
- the components (a) to (c) exhibit sweetness with a sweetness intensity of Xd, and 0.1 ⁇ Xa + Xc ⁇ Xd.
- the amount of high sweetness sweetener is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm or about 150 to about 350 ppm. May be.
- a high-sweetness sweetener in an amount equivalent to the sweetness intensity Xa
- B Amino acid below the taste recognition threshold or a derivative thereof or a salt thereof
- a low-sweetness sweetener in an amount equivalent to the sweetness intensity Xc.
- the components (a) to (c) exhibit sweetness with a sweetness intensity of Xd, and 0.1 ⁇ Xa + Xc ⁇ Xd.
- the high-sweetness sweetener is selected from a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- Xa is 1.0 to 11.0, preferably 1.5 to 10.0, or 1.5 to 6.0 or 4.0 to 10.0.
- Amino acids or derivatives thereof or salts thereof contain amino acids selected from arginine, valine, alanine, glycine, proline, glutamic acid, serine, threonine, aspartic acid and tryptophan.
- Low sweetness sweeteners include sweeteners selected from glucose, sucrose, fructose and combinations thereof. Juice beverages are provided in which the Xc is 0.5-9.0, preferably 1.0-8.0, or 1.0-5.0 or 2.5-9.0. In this embodiment, the amount of high sweetness sweetener is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm or about 200 to about 450 ppm. May be.
- the present invention provides the following fruit juice beverage (hereinafter, also referred to as “fruit juice beverage B of the present invention”) as the first aspect of B1.
- the component exhibiting sweetness is (a) a high-sweetness sweetener in an amount equivalent to the sweetness intensity X1, and the sweetness exhibited by the fruit juice beverage of the present invention is calculated. Should have a sweetness intensity of X1. However, since (b) an amino acid or a derivative thereof or a salt thereof and (c) less than 50 mg / 100 ml of sodium are present in the fruit juice beverage at a low concentration, (a) a sweetness intensity X1 is equivalent. The sweetness exhibited by the amount of high sweetness sweetener is increased to the sweetness intensity X2 (where 0.1 ⁇ X1 ⁇ X2).
- the present invention further comprises sweeteners, acidulants, flavors, vitamins, pigments, antioxidants, emulsifiers, preservatives, seasonings, extracts, etc. other than (a). It means that it may contain additional components such as pH regulators, quality stabilizers and the like. For example, depending on the type of fruit juice, fructose derived from fruits is contained as a sweetener other than (a).
- the fruit juice beverage according to one aspect of the present invention does not contain a sweetening substance other than the component (a) and fructose derived from the fruit as a sweetener.
- the effect of improving the taste quality is exhibited in addition to the increase in sweetness.
- total sweetness “total sweetness”, “reduction of aftertaste of sweetness”, “body, thickness”, “flavor strength”, “miscellaneous taste (bitter taste, astringent taste, etc.)”
- at least one of "reduction” and “salt taste” is improved.
- the combination of alanine, glycine or serine with sodium improves "body, thickness" and "flavor intensity”.
- the "fruit juice beverage” means a beverage containing fruit juice which is squeezed fruit.
- Specific “juice beverages” include “fruit beverages” defined in the “Fair Competition Code for Labeling of Fruit Beverages” enforced in 2018 and “labeling of fruit beverages” enforced in 2016. Examples include “fruit juice,””fruit mixed juice,””fruit juice containing fruit grains,””fruit / vegetable mixed juice,””beverage containing fruit juice,” and “jelly beverage containing fruit juice,” which are the definitions of the “Fair Competition Code Enforcement Regulations.” Beverages in which the percentage of fruit juice used, which is classified as “other beverages” in the above regulations, is less than 10% are also included in the "fruit juice beverage” in the present invention as long as the beverage contains fruit juice.
- the fruit juice beverage of the present invention is also referred to as a "juice-containing beverage”.
- the fruit juice contained in the fruit juice beverage of the present invention is not particularly limited, and is, for example, orange, citrus, lemon, grapefruit, lime, pineapple, strawberry, raspberry, blueberry, cassis, cranberry, blueberry, guava, banana, acerola, papaya. , Passion fruit, mango, apple, grape, peach, plum, pear, apricot, peach, melon, kiwi fruit, and one or more selected from blueberry.
- the fruit juice contained in the fruit juice beverage of the present invention can be used regardless of the production method, such as straight fruit juice or concentrated fruit juice.
- the concentrated fruit juice may be prepared by either a heat concentration method or a freezing concentration method.
- the juice ratio of the juice beverage of the present invention is 1 to 100%, 5 to 100%, 10 to 100%, 15 to 100%, 20 to 100%, 25 to 100%, 30 to 100%, 35, depending on the embodiment. ⁇ 100%, 40-100%, 45-100%, 50-100%, 55-100%, 60-100%, 65-100%, 70-100%, 1-95%, 4-95%, 5 ⁇ 95%, 10-95%, 15-95%, 20-95%, 25-95%, 30-95%, 35-95%, 40-95%, 45-95%, 50-95%, 55 ⁇ 95%, 60-95%, 65-95%, 70-95%, 1-90%, 5-90%, 10-90%, 15-90%, 20-90%, 25-90%, 30 ⁇ 90%, 35 ⁇ 90%, 40 ⁇ 90%, 45 ⁇ 90%, 50 ⁇ 90%, 55 ⁇ 90%, 60 ⁇ 90%, 65 ⁇ 90%, 70 ⁇ 90%, 1 ⁇ 85%, 5 ⁇ 85%, 10-85%, 15-85%, 20-85%, 25-85%, 30-85%, 35-85%, 40-85%,
- the "fruit juice ratio" is a relative concentration when the straight fruit juice obtained by squeezing the fruit is taken as 100%, and is the sugar shown in the JAS standard (Japanese Agricultural Standard for fruit beverages). Can be converted based on the refractometer reading standard (° Bx) or acidity standard (%).
- Typical fruit sugar refractive index reading standards include orange: 11, plum: 9, grapefruit: 9, pineapple: 11, cranberry: 7, blueberry, pear: 8, Banana: 23, papaya: 9, passion fruit: 14, mango: 13, apple: 10, grape: 11, peach: 8, Japanese pear: 8, pear: 11, apricot: 7, plum: 6, melon, kiwi Fruit: 10.
- the standard (unit:%) of the acidity of a typical fruit is lemon: 4.5, lime: 6, plum: 3.5, and kabosu: 3.5.
- [Juice ratio (%)] [Juice content (g)] x [Concentration ratio] / 100 mL x 100
- the JAS standard for orange juice is Bx11 °
- the fruit juice ratio is 30%.
- the refractometer reading for sugar such as saccharides and honey added to the fruit juice shall be excluded.
- the fruit juice beverage of the present invention may be an alcoholic beverage.
- Alcoholic beverages refer to beverages containing alcoholic raw materials. It may be a chu-hi beverage or a highball beverage.
- the alcohol raw material include brewed liquor, distilled liquor, and mixed liquor. Examples of brewed liquor include wine and beer. Examples of distilled liquor include spirits (for example, gin, wokka, lamb, tequila, new spirits, etc., and alcohol for raw materials), liqueurs, whiskeys (for example, whiskey, brandy, etc.), shochu, and the like.
- the alcohol raw material may be a fermented fruit juice contained in the fruit juice beverage of the present invention.
- the alcoholic beverage may contain alcohol in a detectable amount, and for example, it contains 1% by volume or more, 2% by volume or more, 3% by volume or more, 4% by volume or more, and 5% by volume or more of alcohol. ..
- the form of the fruit juice beverage of the present invention is not limited, and may be, for example, a beverage in which a concentrated fruit juice extract is dissolved, or may be a container-filled fruit juice beverage enclosed in a container such as a can or a PET bottle. good.
- sweetness intensity means the intensity of sweetness exhibited by a substance.
- sweetness degree 1 the sweetness degree of glucose is 0.6 to 0.7 (median value 0.65).
- the sweetness of general sweeteners is as shown in Table 1 which describes the first and first aspects of A1.
- the fruit juice beverage of the present invention contains a high-sweetness sweetener in an amount equivalent to the sweetness intensity X1, and exhibits sweetness of the sweetness intensity X2 by the components (a) to (c), and 0.1 ⁇ X1 ⁇ X2. be.
- "Sweetness intensity X1" X1 is more than 0.1 and 0.5 or less, more than 0.1 and 1.0 or less, more than 0.1 and 1.5 or less, more than 0.1 and 2.0 or less, more than 0.1 and 2.5 or less, more than 0.1 and 3.0 or less, more than 0.1 and 3.5 or less, More than 0.1 4.0 or less, more than 0.1 4.5 or less, more than 0.1 5.0 or less, more than 0.1 5.5 or less, 0.5-1.0, 0.5-1.5, 0.5-2.0, 0.5-2.5, 0.5-3.0, 0.5-3.5, 0.5-4.0, 0.5-4.5, 0.5-5.0, 0.5-5.5, 1.0-1.5, 1.0-2.0, 1.0-2.5, 1.0-3.0, 1.0-3.5, 1.0-4.0, 1.0-4.5, 1.0-5.0, 1.0- 5.5, 1.5-2.0, 1.5-2.5, 1.5-3.0, 1.5-3.5, 1.5-4.0, 1.5-4.5, 1.5-5.0, 1.5-5.5, 2.0-2.5, 2.0
- X1 is also more than 0.1 and 6.0 or less, 0.1 and 6.5 or less, 0.1 and 7.0 or less, 0.1 and 7.5 or less, 0.1 and 8.0 or less, 0.1 and 8.5 or less, 0.1 or 9.0 or less, 0.1 or more and 9.5.
- 0.1 to 10.0 or less 0.1 to 10.5 or less, 0.1 to 11.0 or less, 0.1 to 11.5 or less, 0.1 to 12.0 or less, 0.1 to 13.0 or less, 0.1 to 14.0 or less, 0.1 to 15.0 or less, More than 0.1 and 16.0 or less, more than 0.1 and 17.0 or less, more than 0.1 and 18.0 or less, 0.5 to 6.0, 0.5 to 6.5, 0.5 to 7.0, 0.5 to 7.5, 0.5 to 8.0, 0.5 to 8.5, 0.5 to 9.0, 0.5 to 9.5, 0.5-10.0, 0.5-10.5, 0.5-11.0, 0.5-11.5, 0.5-12.0, 0.5-13.0, 0.5-14.0, 0.5-15.0, 0.5-16.0, 0.5-17.0, 0.5-18.0, 1.0-6.0, 1.0- 6.5, 1.0-7.0, 1.0-7.5, 1.0-8.0, 1.0-8.5, 1.0-9.0, 1.0-9.5, 1.0-10.0, 1.0-10.5, 1.0-10.5,
- X1 is preferably 0.5 to 10.0, more preferably 1.5 to 9.0, and even more preferably 2.0 to 8.0. Further, in another aspect of the present invention, X1 is preferably 0.5 to 5.5, more preferably 1.0 to 5.5, and even more preferably 2.0 to 5.0.
- the amount equivalent to the sweetness intensity X1 of the high sweetness sweetener means the amount that exhibits the sweetness of the sweetness intensity X1 under the condition that the high sweetness sweetener is dissolved in 20 ° C water having the same volume as the fruit juice beverage of the present invention.
- the amount of the high-sweetness sweetener may be Pa ppm, where Pa ppm is an amount equivalent to the sweetness intensity X1.
- Pa is about 20 to about 800, about 25 to about 800, about 30 to about 800, about 35 to about 800, about 40 to about 800, about 45 to about 800, about 50 to about 800, about 55.
- Pa is also 1-1500, 1-1200, 5-1200, 1-1000, 5-1000, 10-1000, 1-900, 5-900, 10-900, 15-900, 20-900, 25- 900, 30-900, 35-900, 40-900, 45-900, 50-900, 55-900, 1-800, 5-800, 10-800, 15-800, 20-800, 25-800, 30-800, 35-800, 40-800, 45-800, 50-800, 55-800, 1-700, 5-700, 10-700, 15-700, 20-700, 25-700, 30- 700, 35-700, 40-700, 45-700, 50-700, 55-700, 1-600, 5-600, 10-600, 15-600, 20-600, 25-600, 30-600, 35-600, 40-600, 45-600, 50-600, 55-600, 1-550, 1-540, 1-530, 1-520, 1-510, 1-505, 1-500, 1- 495, 1-490, 5-550, 5-540, 5-530, 5-520, 5-510, 5-505, 5-500, 5-495
- Pa is also about 20-about 200, about 100-about 500, about 100-about 450, about 100-about 400, about 100-about 350, about 100-about 300, about 100-about 250, about 100-about. 200, about 150 to about 500, about 150 to about 450, about 150 to about 400, about 150 to about 350, about 150 to about 300, about 150 to about 250, about 150 to about 200, about 200 to about 500, It can take values of about 200 to about 450, about 200 to about 400, about 200 to about 350, about 200 to about 300, or about 200 to about 250.
- X2 is not particularly limited as long as it is larger than X1, but 0.5 to 6.0, 0.5 to 6.5, 0.5 to 7.0, 0.5 to 7.5, 0.5 to 8.0, 0.5 to 8.5, 0.5 to 9.0, 0.5 to 9.5, 0.5 to 10.0, 0.5. ⁇ 10.5, 0.5 ⁇ 11.0, 0.5 ⁇ 11.5, 0.5 ⁇ 12.0, 0.5 ⁇ 13.0, 0.5 ⁇ 14.0, 0.5 ⁇ 15.0, 0.5 ⁇ 16.0, 0.5 ⁇ 17.0, 0.5 ⁇ 18.0, 1.0 ⁇ 6.0, 1.0 ⁇ 6.5, 1.0 ⁇ 7.0 , 1.0-7.5, 1.0-8.0, 1.0-8.5, 1.0-9.0, 1.
- X2 is also 4.0-18, 4.0-16, 4.0-15.5, 4.0-14, 4.5-18, 4.5-16, 4.5-15.5, 4.5-14, 5.0-18, 5.0-16, 5.0-15.5, 5.0- 14, 5.5-18, 5.5-16, 5.5-15.5, 5.5-14, 6.0-18, 6.0-16, 6.0-15.5, 6.0-14, 6.
- the fruit juice beverage according to one embodiment of the present invention exhibits sweetness with a sweetness intensity of X3 depending on the components (a) and (b), and 0.1 ⁇ X1 ⁇ X3 ⁇ X2. That is, a combination of the component (a) and the component (b) by adding the sodium of the component (c) to the high sweetness sweetener of the component (a) and the amino acid of the component (b) or a derivative thereof or a salt thereof. The sweetness is enhanced.
- X3 is larger than X1 and smaller than X2, but is not particularly limited, but 0.5 to 6.0, 0.5 to 6.5, 0.5 to 7.0, 0.5 to 7.5, 0.5 to 8.0, 0.5 to 8.5, 0.5 to 9.0, 0.5 to 9.5, 0.5-10.0, 0.5-10.5, 0.5-11.0, 0.5-11.5, 0.5-12.0, 0.5-13.0, 0.5-14.0, 0.5-15.0, 0.5-16.0, 0.5-17.0, 0.5-18.0, 1.0-6.0, 1.0- 6.5, 1.0-7.0, 1.0-7.5, 1.0-8.0, 1.0-8.5, 1.0-9.0, 1.0-9.5, 1.0-10.0, 1.0-10.5, 1.0-11.0, 1.0-11.5, 1.0-12.0, 1.0-13.0, 1.0 to 14.0, 1.0 to 15.0, 1.0 to 16.0, 1.0 to 17.0, 1.0 to 18.0, 1.5 to 6.0, 1.5 to 6.5, 1.5 to 7.0, 1.5 to 7.5, 1.5 to 8.0,
- X3 is also 3.0-17, 3.0-15, 3.0-14.5, 3.0-13, 3.5-17, 3.5-15, 3.5-14.5, 3.5-13, 4.0-17, 4.0-15, 4.0-14.5, 4.0- 13, 4.5-17, 4.5-15, 4.5-14.5, 4.5-13, 5.0-17, 5.0-15, 5.0-14.5, 5.0-13, 5.5-17, 5.5-15, 5.5-14.5, 5.5-13, 6.0-17, 6.0-15, 6.0-14.5, 6.0-13, 6.5-17, 6.5-15, 6.5-14.5, 6.5-13, 6.5-8, 6.5-7, 7.0-17, 7.0-16, 7.0- 15, 7.0-14.5, 7.0-13, 7.5-17, 7.5-15, 7.5-14.5, 7.5-13, 8.0-17, 8.0-15, 8.0-14.5, 8.0-13, 8.5-17, 8.5-15, It may be 8.5 to 14.5, 8.5 to 13, 9.0 to 17, 9.0 to 15, 90 to 14.5, 9.5 to 17, 9.5 to 15 or 9.5 to 14.5.
- the fruit juice beverage of the present invention exhibits an enhanced sweetness. Whether or not the sweetness of the fruit juice beverage of the present invention is enhanced can be evaluated by a panelist trained in sensuality. Further, the sweetness intensity of the fruit juice beverage of the present invention is such that the standard fruit juice beverage, which is the standard of sweetness, has a sweetness intensity of 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, The sweetness of the fruit juice beverage of the present invention can be measured by adjusting the sucrose concentration to 14 and 15 and comparing the sweetness of the fruit juice beverage of the present invention with the sweetness of the standard fruit juice beverage. can. In addition, the standard fruit juice beverage with sweetness intensity 1, 2, ... 15 has a sucrose content of 1 g / 100 g, 2 g / 100 g, ...
- the standard fruit juice beverage having less sweetness than the fruit juice beverage of the present invention in the above measurement the standard fruit juice beverage having the closest sweetness to the fruit juice beverage of the present invention is selected, and sucrose is added to the selected standard fruit juice beverage.
- the sweetness is adjusted to be the same as that of the fruit juice beverage of the present invention, and at that time, the sweetness intensity of the fruit juice beverage of the present invention is measured from the sucrose content contained in the adjusted reference fruit juice beverage. You can also.
- VAS method sweetness intensity evaluation
- the evaluator defines the intensity of sweetness as "not sweet at all" at the lower end and "I can't think of anything sweeter than this" at the upper end.
- the evaluation is made by expressing the sweetness intensity felt at that time by the position on the straight line using the paper on which the vertical line showing the intensity is drawn on the straight line.
- the sweetness intensity of the fruit juice beverage of the present invention is not particularly limited as long as it is acceptable as a fruit juice beverage, and for example, the sweetness degree is 4.0 to 20, 4.0 to 15, 4.0 to 12.5, 4.0 to 10, 4.5. ⁇ 20, 4.5 ⁇ 15, 4.5 ⁇ 12.5, 4.5 ⁇ 10, 5.0 ⁇ 20, 5.0 ⁇ 15, 5.0 ⁇ 12.5, 5.0 ⁇ 10, 5.5 ⁇ 20, 5.5 ⁇ 15, 5.5 ⁇ 12.5, 5.5 ⁇ 10, 6.0 ⁇ 20, 6.0 ⁇ 15, 6.0 ⁇ 12.5, 6.0 ⁇ 10, 6.5 ⁇ 20, 6.5 ⁇ 15, 6.5 ⁇ 12.5, 6.5 ⁇ 10, 7.0 ⁇ 20, 7.0 ⁇ 15, 7.0 ⁇ 12.5, 7.0 ⁇ 10, 7.5 ⁇ 20, 7.5 ⁇ 15, 7.5 ⁇ 12.5, 7.5 ⁇ 10, 7.5 ⁇ 9, 7.5 ⁇ 8, 8.0 ⁇ 20, 8.0 ⁇ 20, 8.0 ⁇ 20, 8.0 ⁇ 15, 8.0 ⁇ 12.5, 8.0 ⁇ 10, 8.5 ⁇ 20, 8.5 ⁇ 15
- the energy (total energy amount) of the fruit juice beverage of the present invention is 0 to 50 Kcal / 100 ml, 0 to 45 Kcal / 100 ml, 0 to 40 Kcal / 100 ml, 0 to 35 Kcal / 100 ml, 0 to 30 Kcal / 100 ml, 0 to 24 Kcal depending on the embodiment.
- the energy (total energy amount, TE) of the fruit juice beverage of the present invention is 0 ⁇ TE ⁇ 50 Kcal / 100 ml, 0 ⁇ TE ⁇ 45 Kcal / 100 ml, 0 depending on the embodiment (for example, an embodiment containing a caloric sweetener).
- the components (a) to (c) can be arbitrarily combined. As shown in Examples described later, by adding the component (b) and the component (c) to the component (a), it is possible to obtain a sweetness intensity X2 higher than the sweetness intensity X1 of the component (a) alone. That is, the sweetness of the component (a) can be enhanced by the components (b) and (c). Therefore, it is possible to produce a fruit juice beverage while maintaining the same sweetness as that of a fruit juice beverage containing sucrose, without using sucrose having a high calorie content, or while reducing the amount of sucrose used. Therefore, it is possible to design a new low-calorie fruit juice beverage.
- an additional sweetness is used as the component (a) using a high-intensity sweetener having particularly excellent taste such as rebaugioside D (hereinafter, rebaugioside may be abbreviated as Reb) or rebaugioside M.
- a high-intensity sweetener having particularly excellent taste
- rebaugioside D hereinafter, rebaugioside may be abbreviated as Reb
- rebaugioside M Use D-allulose, erythritol, etc. as substances, and improve sweetness with low-concentration amino acids and low-concentration sodium.
- you want to adjust the calories of food to low calories instead of zero you can also add calorie sweeteners such as sucrose, glucose, fructose, and sorbitol as additional sweeteners.
- High sweetness sweetener in the present specification, may be abbreviated as "sweetener (a)” or “ingredient (a)" means a compound having a stronger sweetness than sucrose, and is a naturally derived compound. , Synthetic compounds or combinations of naturally occurring compounds and synthetic compounds. High sweetness sweetener is 5 times or more, 10 times or more, 50 times or more, 100 times or more, 500 times or more, 1,000 times or more, 5,000 times or more, 10,000 times or more, 50,000 times in the same amount as sucrose. It has a sweetness of 100,000 times or more.
- high-sweetness sweeteners include peptide-based sweeteners such as aspartame, neotheme, and advanced, and sucrose derivatives such as sucralose, such as acesurfam K, saccharin, sodium saccharin, sodium cyclamate, zultin, and diglycyrrhizinate.
- Synthetic sweeteners such as sodium, trisodium glycyrrhizinate, neohesperidin dihydrochalcone (including naturally occurring but predominantly synthetic products such as neohesperidin dihydrocarcon), such as somatin and monerin.
- Thunberg Extracts Thaumataococcus daniellii Benth extract, Dioscoreophyllum volkensii extract, Curculigo latifolia extract, Richadella dulcifica extract, Richadella dulcifica extract, Pentadiplandra Masaikai extract, Lippia dulcis (sweet herb Mexican) extract, etc. and sweeteners in the extract, such as stevia extract and stevia derivative such as enzyme-treated stevia, which is obtained by enzymatically treating stevia and adding glucose.
- Glycyrrhiza glabra Plant-containing sweeteners eg, triterpene such as glycyrrhizin
- sugars obtained from plant extracts such as steviol sugar, mogloside obtained by processing Luo Han Guo and Luo Han Guo extract.
- Sugar steviol sugar
- mogloside obtained by processing Luo Han Guo and Luo Han Guo extract.
- Plant-containing sweet ingredients eg, diterpen sugars such as rubusoside
- Hydrorangea macrophylla var eg, diterpen sugars such as rubusoside
- Thaumataococcus daniellii Benth plant-containing sweet components eg, proteins such as somatin
- Dioscoreophyllum volkensii plant-containing sweet components eg, proteins such as monerin
- Curculigo latifolia plant-containing sweet components eg, proteins such as curculin
- Richadella dulcifica plant-containing sweet ingredients eg, proteins such as miraculin
- Pentadiplandra brazzeana plant-containing sweet ingredients eg, brazein, pentadin, etc.
- Capparis masaikai plant-containing sweet ingredients eg, mabinlin, etc.
- Lippia dulcis plant-containing Examples include sweetening components (eg, sesquitelpen such as hernanzultin, 4 ⁇ -hydroxyhernanzultin) and the like.
- Steviol glycosides include rebaugioside A, rebaugioside B, rebaugioside C, rebaugioside D, rebaugioside E, rebaugioside F, rebaugioside I, rebaugioside J, rebaugioside K, rebaugioside M, rebaugioside Q, rebaugioside O, and rebaugioside O.
- A, Zulcoside C, rubusoside, steviol, steviol monoside, steviolbioside, stevioside and the like can be mentioned.
- mogroside include mogroside IV and mogroside V.
- the licorice (licorice) extract is obtained from the roots or rhizomes of Glycyrrhiza uralensis, Glycyrrhiza chinensis or Glycyrrhiza vulgaris, and is mainly composed of glycyrrhizic acid.
- licorice extract include licorice extract, glycyrrhizin, and licorice extract.
- the sucrose derivative includes, for example, one obtained by substituting the OH group or H group of sucrose with another substituent, and examples thereof include a halogen derivative (sucralose) of sucrose and an oxathiadinone dioxide derivative. And so on.
- the high sweetness sweetener is selected from the good quality high sweetness sweeteners.
- the "good-quality, high-sweetness sweetener” has (1) less astringent taste, (2) less metallic taste, and (3) less sweetness aftertaste than Rebaugioside A (RebA).
- (4) Less bitterness means a high-sweetness sweetening substance having one or more taste characteristics selected from. Whether or not a certain sweet substance has the above-mentioned taste characteristics is known or can be determined based on a sensory evaluation or the like.
- Non-limiting examples of good-tasting, high-sweetness sweeteners include, for example, RebD, RebM, Luo Han Guo extract, mogroside (eg, mogroside V), thaumatin, brazzein or a combination thereof.
- the high sweetness sweetener may be naturally occurring in a plant or the like, or may be artificially produced (for example, bioconversion, chemical synthesis, etc.). However, it is preferably a naturally occurring sweetener.
- the term "naturally occurring" does not mean that the high-intensity sweetening substance contained in the fruit juice beverage of the present invention is a natural product, as long as the same substance is naturally present.
- the high-intensity sweetening substance contained in the fruit juice beverage of the present invention may be artificially produced (for example, by bioconversion) (non-natural product).
- Non-limiting examples of the sweetening agent (a) include, for example, rebaugioside A (RebA), rebaugioside D (RebD), rebaugioside M (RebM), neohesperidin dihydrocalcone, glycyrrhizin, thaumatin, monerin, mogloside, rubusoside, curculin, mabinlin. , Brazein, Pentazine, Philozlutin, Hernanzultin, Miraclen, Stevia rebaudiana Plant-containing sweetness ingredient, Siraitia grosvenorii Plant-containing sweetening ingredient, Glycyrrhiza glabra Plant-containing sweetening ingredient, Rubus suavissimus S.
- RebA rebaugioside A
- RebD rebaugioside D
- RebM rebaugioside M
- neohesperidin dihydrocalcone glycyrrhizin, thaumatin, mon
- the sweetener (a) comprises RebA, RebD, RebM, mogroside (eg, mogroside V) or a combination thereof.
- the sweetener (a) comprises RebA, RebD, RebM, mogroside (eg, mogroside V), thaumatin or a combination thereof.
- the high sweetness sweetener comprises at least one selected from the group consisting of RebA, RebD, RebM, mogroside V, Luo Han Guo extract and combinations thereof.
- the sweetener (a) is substantially composed of sweeteners other than the major components of stevia sweeteners such as RebA and stevioside.
- substantially from means that the sweetener used in the present invention may contain the main components of the stevia sweetener as long as the effects of the present invention are not impaired.
- the sweeteners (a) used in the present invention preferably 90% or more, more preferably 95% or more, still more preferably 98% or more consist of sweeteners other than RebA and stevioside.
- RebA, RebD and RebM may be extracted directly from Stevia, or may be obtained by adding glucose to a compound having another structure contained in the Stevia extract.
- Luo Han Guo extract as a sweetener is an extract of Luo Han Guo containing a sweetening substance derived from Luo Han Guo, and is approved as a food additive in various countries including Japan and is commercially available.
- sweetening substance derived from Luo Han Guo include mogroside V, mogroside IV, 11-oxo-mogroside V, and siamenoside I.
- Mogroside V is one of the major mogroside glycosides contained in Luo Han Guo, and it has been reported that it exhibits high-quality sweetness characteristics close to those of sucrose as compared with rebaugioside A.
- Mogroside V can be obtained by purifying from a Luo Han Guo extract (for example, an alcohol extract of Luo Han Guo) by chromatography or the like.
- mogroside V may be obtained by adding glucose to a compound having another structure contained in the Luo Han Guo extract.
- the Luo Han Guo extract preferably contains mogloside V, and the proportion thereof is not limited, but is 10% by weight or more, 15% by weight or more, 20% by weight or more, 25% by weight or more, 30 by weight of the total dry weight of the Luo Han Guo extract. By weight% or more, 35% by weight or more, 40% by weight or more, 45% by weight or more, 50% by weight or more, 55% by weight or more, 60% by weight or more, 65% by weight or more, 70% by weight or more or 75% by weight or more. It may be there.
- the content of mogroside V can be determined by known techniques such as liquid chromatography.
- the fruit of Rakan fruit (Siraitia grosvenorii) is used as an appropriate solvent (for example, an aqueous solvent such as water, an alcohol solvent such as ethanol and methanol, a mixed solvent of an aqueous solvent such as hydrous ethanol and hydrous methanol, and an alcohol solvent. Etc.), and then optionally subjected to treatments such as degreasing, purification, concentration, and drying.
- an appropriate solvent for example, an aqueous solvent such as water, an alcohol solvent such as ethanol and methanol, a mixed solvent of an aqueous solvent such as hydrous ethanol and hydrous methanol, and an alcohol solvent. Etc.
- Mogroside V may be of high purity, for example, purity of 80% or more, 85% or more, 90% or more, 91% or more, 92% or more, 93% or more, 94% or more, 95% or more, 96. It may be% or more, 97% or more, 98% or more, and the like. As a matter of course, the higher the purity of mogroside V obtained by purifying the Luo Han Guo extract, the smaller the amount of the Luo Han Guo extract component other than the mogroside V mixed.
- the mogroside V may be of lower purity, eg, 50% or more, 55% or more, 60% or more, 65% or more, 70% or more or 75% or more. It may be a mogroside.
- sweetness degree 1 the sweetness intensity exhibited by sucrose per unit concentration Brix 1
- the calculated value of the sweetness degree of MogV having a purity of about 65% is about 175.
- Luo Han Guo extract containing about 30% by weight of MogV may be used as a high-sweetness sweetener, and the sweetness intensity exhibited by sucrose per unit concentration Brix 1 is defined as sweetness 1. In this case, the calculated sweetness of this Luo Han Guo extract is about 100.
- the high sweetness sweetener is contained in an amount equivalent to the sweetness intensity X1 as described above.
- sweetness intensity of sucrose per unit concentration Brix 1 is defined as sweetness 1
- the sweetness of rebaugioside D is about 225
- the sweetness of rebaugioside M is about 230
- the sweetness of rebaugioside B is about 325
- the sweetness of rebaugioside A is about 325.
- the degree is 200-300 (median 250)
- the sweetness of rebaugioside N is 200-250 (center value 225)
- the sweetness of rebaugioside O is 200-250 (median 225)
- the sweetness of rebaugioside E is 70-80.
- Luo Han Guo extract (containing 40% MogV) has a sweetness of about 130
- Mogroside V has a sweetness of about 270
- Thaumatin has a sweetness of 2,000
- Brazzein has a sweetness of 500-2000 (Median 1250).
- the value obtained by multiplying these sweetnesses by the concentration of the high-sweetness sweetener in the fruit juice beverage (w / v% (in the case of a beverage, it can be equated with w / w%)) is the sweetness of the high-sweetness sweetener. It becomes strength.
- the above-mentioned sweetness degree center value for those shown in the numerical range
- the relative ratio of the sweetness of various sweeteners to the sweetness of sucrose 1 can be obtained from a known sugar sweetness conversion table (for example, Beverage Japan Co., Ltd. "Beverage Glossary", page 11). In the present specification, the median value is used for those whose sweetness is shown in the numerical range. However, for sweeteners whose sweetness values differ depending on the literature, the relative ratio of the sweetness of sucrose to the sweetness of 1 can be determined by a sensory test. As such a sensory test, for example, a sample in which sucrose is added to pure water from Brix 3.0 to 5.0 in 0.5 increments is prepared, and the sample is equivalent to an aqueous solution of a sweetener having a predetermined concentration. A method of selecting a sucrose-added sample having a sweetness intensity can be mentioned.
- the high sweetness sweetener is derived from steviol glycoside, Luo Han Guo extract, mogrol glycoside, Thaumataococcus daniellii Benth plant-containing sweetener, Pentadiplandra brazzeana plant-containing sweetener, artificial sweetener and combinations thereof.
- the high-intensity sweeteners are rebaugioside A, rebaugioside B, rebaugioside C, rebaugioside D, rebaugioside E, rebaugioside F, rebaugioside I, rebaugioside J, rebaugioside K, rebaugioside M, rebaugioside N, rebaugioside.
- Lebaugioside Q Lebaugioside Q, Levaugioside R, Zulcoside A, Zulcoside C, Lubusoside, Steviolmonoside, Steviolbioside, Stevioside, Luo Han Guo extract, Mogloside V, Thaumatin, Brazzein, Aspartame, Acesulfam K, Sclarose, Canzo extract, Saccharin, and its Includes at least one selected from the group consisting of combinations.
- the sweetener (a) comprises the following combinations: RebA and RebM, RebA and RebD, RebD and RebM, RebA and RebD and RebM, RebA and mogroside V, RebD and mogroside V, RebM and mogroside V. , RebA and RebM and mogroside V, RebA and RebD and mogroside V, RebD and RebM and mogroside V, RebA and neohesperidin dihydrocalcon, RebD and neohesperidin dihydrocalcon, RebM and neohesperidin dihydrocalcon, RebA and RebM and neohesperidin dihydro.
- the sweetener (a) comprises the following combinations: RebA and thaumatin, RebD and thaumatin, RebM and thaumatin, Mogloside V and thaumatin, RebA and RebM and thaumatin, RebA and RebD and thaumatin, RebD and RebM. Thaumatin, RebA and Mogroside V and Thaumatin, RebD and Mogroside V and Thaumatin, RebM and Mogroside V and Thaumatin, RebD and RebM and Mogloside V and Thaumatin.
- the sweetener (a) is a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably rebaugioside D, rebaugioside M. And one or more high sweetness sweeteners selected from the combination thereof may be contained.
- the amount of the sweetener (a) contained in the fruit juice beverage according to one aspect of the present invention is an amount obtained by combining all the sweet substances.
- the amount of sweetener (a) is Pa (ppm)
- Pa is, for example, about 20 to about 800, about 25 to about 800, about 30 to about 800, about 35 to about 800, about 40 to about 800, About 45 to about 800, about 50 to about 800, about 55 to about 800, about 20 to about 750, about 25 to about 750, about 30 to about 750, about 35 to about 750, about 40 to about 750, about 45 ⁇ 750 ⁇ 50 ⁇ 750, 55 ⁇ 750, about 20 ⁇ 700, about 25 ⁇ 700, about 30 ⁇ 700, about 35 ⁇ 700, about 40 ⁇ 700, about 45 ⁇ about 700, about 50 to about 700, about 55 to about 700, about 20 to about 650, about 25 to about 650, about 30 to about 650, about 35 to
- the amount of high-sweetness sweetener Pa ppm is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm, or about 150. It may be up to about 350 ppm.
- the fruit juice beverage of the present invention contains (b) an amino acid below the taste recognition threshold, a derivative thereof, or a salt thereof.
- the amino acid or amino acid salt used in the present invention is not particularly limited as long as it is an organic compound having both functional groups of an amino group and a carboxyl group or a salt thereof and which can obtain an effect of increasing sweetness.
- proline and hydroxyproline in which hydrogen of an amino group replaces a side chain portion in a molecule to form a cyclic structure are also included in amino acids herein.
- the amino acid derivative used in the present invention also includes a derivative having no carboxyl group such as taurine.
- amino acids mean free amino acids.
- the amino acid used in the present invention may be D-form, L-form, or racemic-form (also referred to as DL amino acid in the present specification) consisting of D-form and L-form.
- the amino acid can be selected from neutral amino acids, basic amino acids and acidic amino acids.
- the neutral amino acid include glycine having an alkyl group, alanine, valine, isoleucine, leucine, etc., serine having an OH group (hydroxy group), threonine, etc., tyrosine having an aromatic group (or aromatic ring), phenylalanine, tryptophan, etc.
- Metionine having a sulfur-containing group, cysteine and the like, proline having an imino group, hydroxyproline and the like, glutamine having an amide group, asparagine and the like can be preferably selected.
- As the basic amino acid arginine, lysine, histidine and the like can be preferably selected.
- the acidic amino acid can be preferably selected from glutamic acid, aspartic acid and the like.
- the amino acid is selected from neutral or basic amino acids.
- the amino acid comprises a basic amino acid and an amino acid selected from a combination of neutral amino acids having an alkyl group, an OH group or an amide group in the side chain.
- those having an alkyl group in the side chain include, for example, glycine, alanine, valine, isoleucine and leucine, and those having an OH group in the side chain include, for example, serine and threonine.
- examples of those having an amide group in the side chain include glutamine and asparagine.
- the amino acid contained in the fruit juice beverage in one aspect of the present invention is one or more of the 22 amino acids forming a protein. Specifically, alanine (Ala), arginine (Arg), asparagine (Asn), aspartic acid (Asp), cysteine (Cys), glutamine (Gln), glutamic acid (Glu), glycine (Gly), histidine (His).
- the amino acid contained in the fruit juice beverage according to one aspect of the present invention is one or more selected from amino acids having a molecular weight of 70 to 260.
- amino acids include alanine (molecular weight: 89), arginine (molecular weight: 174), asparagine (molecular weight: 132), aspartic acid (molecular weight: 133), cysteine (molecular weight: 121), glutamine (molecular weight: 146), Glutamic acid (molecular weight: 147), glycine (molecular weight: 75), histidine (molecular weight: 155), isoleucine (molecular weight: 131), leucine (molecular weight: 131), lysine (molecular weight: 146), methionine (molecular weight: 149), phenylalanine (Molecular weight: 165), Proline (Molecular weight: 115), Serine (Molecular weight: 105), Threonin (Molecular weight: 119), Tryptophan (
- the amino acid is one or more selected from amino acids having a molecular weight of 75 to 204, more preferably one or more selected from amino acids having a molecular weight of 75 to 174, and further preferably having a molecular weight. Is one or more selected from 75 to 146 amino acids.
- the amino acid or salt thereof is L-Asparagine, L-Aspartic acid, Monosodium L-Aspartate, DL-Alanine, L-Alanine, L-Alanine solution, L-Arginine, L-Arginine L-glutamate, L-glutamate (L) -Glutamine), L-Cystine, L-Cystein Monohydrochloride, L-Serine, L-Tyrosine, L-Glutamic Acid Acid), L-Ammonium L-Glutamate (Monoammonium L-Glutamate), Potassium L-Glutamate (Monopotassium L-Glutamate), Calcium L-Glutamic Acid (Monocalcium Di-L-Glutamate), Sodium L-Glutamic Acid (also known as sodium glutamate) (Monosodium L -Glutamate), L-Glutamic Acid (Monomagnesium Di-L-Glutamate), Glycine,
- amino acids include amino acids selected from glycine, alanine, valine, isoleucine, leucine, serine, threonine, glutamine, asparagine, arginine, lysine, histidine and combinations thereof.
- the amino acid or derivative thereof or salt thereof comprises an amino acid selected from DL-alanine, L-serine, glycine, L-arginine, L-glutamic acid, L-valine and L-glutamine. May be good.
- the amino acid or derivative thereof or a salt thereof is arginine, lysine, histidine, phenylalanine, tyrosine, leucine, isoleucine, methionine, valine, alanine, glycine, proline, glutamic acid, serine, threonine, aspartic acid and It may contain one or more amino acids selected from tryptophan.
- the amino acid or derivative thereof or salt thereof comprises one or more amino acids selected from arginine, valine, alanine, glycine, proline, glutamic acid, serine, threonine, aspartic acid and tryptophan. You may.
- the amino acid threshold means a detection threshold or a taste recognition threshold.
- the detection threshold means the minimum concentration that can clearly show the difference from water, but does not necessarily have to be able to recognize the type of taste (eg, bitterness, acidity, sweetness, etc.).
- the taste cognitive threshold means the minimum concentration at which taste can be recognized (for example, Eur J Clin Nutr (2004) 58, 629-636).
- Amino acid thresholds are summarized in Susan S. Schiffman et al., “Comparison of Taste Qualities and Thresholds of D-and L-Amino Acids”, Physiology & Behavior, Vol. 27, pp. 51-59 (1981). ing.
- the detection thresholds for each amino acid are: glycine (30.9mM), L-threonine (25.7mM), L-serine (20.9mM), L-alanine (16.2mM), L-proline (15.1mM). ), L-Glutamine (9.77mM), L-isoleucine (7.41mM), L-phenylalanine (6.61mM), L-leucine (6.45mM), L-valine (4.16mM), L-methionine (3.72mM), L-tryptophan (2.29mM), L-aspartin (1.62mM), L-histidine (1.23mM), L-arginine (1.20mM), L-lysine (0.708mM), L-aspartic acid (0.182mM), L -Glutamic acid (0.063mM), L-cysteine (0.063mM).
- the taste recognition threshold is about 1.5 to 2 times the detection threshold (Yuki Yamauchi et al., "Whole oral taste test (1st report) -basic study and main component analysis-”. , Japan Otolaryngology Society Bulletin Vol. 98 (1995) No. 1, p.119-129, and Reiko Omori, "Comparison of Taste Sensitivity Between Generations", Utsunomiya University Faculty of Education Bulletin, Part 1 (2013) Vol.63 p.201-210)).
- the taste recognition threshold value of an amino acid can be obtained by a sensory test in which an amino acid-containing aqueous solution is prepared at a plurality of concentration levels, tasted in order from the one with the lowest concentration to the one with the highest concentration, and whether or not the taste is felt.
- the concentration at which it is detected to be different from water is defined as the detection threshold
- the concentration at which taste is recognized is defined as the cognitive threshold.
- an amino acid that already has a theoretical value (literature value) can be determined by preparing an aqueous solution having a plurality of concentration levels near the concentration and testing by a plurality of persons trained in sensory.
- the detection threshold described in the literature is 16.2 mM
- the theoretical cognitive threshold calculated from the detection threshold is 32.4 mM, so that 5 mM, 10 mM, 15 mM, 20 mM, 25 mM, and 30 mM.
- the cognitive threshold can be measured by performing a sensory test with multiple levels of aqueous solution selected from 35 mM.
- the amino acid taste recognition threshold means the taste recognition threshold in pure water.
- the taste recognition threshold value in pure water means the minimum concentration at which the taste can be recognized when only amino acids are added to water without adding a sweetener or the like.
- the fruit juice beverage contains glycine, and the content of glycine is more than 0 mM and 80 mM or less, 75 mM or less, less than 75 mM, 70 mM or less, 65 mM or less, 60 mM or less, 55 mM or less, 50 mM or less, less than 50 mM, 45 mM. Below, it may be 40 mM or less, 35 mM or less, 30 mM or less, 25 mM or less, 20 mM or less, 15 mM or less, or 10 mM or less.
- the fruit juice beverage contains alanine and the alanine content is more than 0 mM and less than 32.4 mM, less than 30 mM, less than 30 mM, 25 mM or less, 20 mM or less, less than 20 mM, less than 15 mM or less than 10 mM. good.
- Alanine may be L-form, D-form or racemic-form (DL-form), but is preferably L-form.
- the fruit juice beverage contains valine and the valine content is more than 0 mM and less than 50 mM, less than 50 mM, less than 45 mM, 40 mM or less, less than 40 mM, 35 mM or less, 30 mM or less, less than 30 mM, 25 mM or less, 20 mM.
- it may be 15 mM or less or 10 mM or less.
- the fruit juice beverage may contain isoleucine, and the content of isoleucine may be more than 0 mM and 25 mM or less, 20 mM or less, 15 mM or less, 10 mM or less or 5 mM or less. Alternatively, at 1-25mM, 5-25mM, 10-25mM, 15-25mM, 20-25mM, 1-20mM, 5-20mM, 10-20mM, 15-20mM, 1-15mM, 5-15mM or 10-15mM. There may be. Isoleucine may be L-form, D-form or racemic (DL-form), but is preferably L-form.
- the fruit juice beverage contains leucine, and the leucine content is more than 0 mM and 50 mM or less, 45 mM or less, 40 mM or less, 35 mM or less, 30 mM or less, less than 30 mM, 25 mM or less, 20 mM or less, less than 20 mM, 15 mM.
- it may be 13 mM or less, 12 mM or less, 11 mM or less, 10 mM or less, less than 10 mM, 9 mM or less, 8 mM or less, 7 mM or less, 6 mM or less, 5 mM or less, 4 mM or less, 3 mM or less, 2 mM or less or 1 mM or less.
- the fruit juice beverage contains serine, and the serin content is more than 0 mM and 130 mM or less, 100 mM or less, 80 mM or less, 50 mM or less, 50 mM or less, 45 mM or less, 40 mM or less, 40 mM or less, 35 mM or less, 30 mM.
- the serin content is more than 0 mM and 130 mM or less, 100 mM or less, 80 mM or less, 50 mM or less, 50 mM or less, 45 mM or less, 40 mM or less, 40 mM or less, 35 mM or less, 30 mM.
- it may be 25 mM or less, 20 mM or less, 15 mM or less, or 10 mM or less.
- 10 to 130mM 10 to 100mM, 10 to 80mM, 20 to 80mM, 30 to 80mM, 40 to 80mM, 50 to 80mM, 60 to 80mM, 70 to 80mM, 10 to 70mM, 20 to 70mM, 30 to 70mM, 40-70mM, 50-70mM, 60-70mM, 10-60mM, 20-60mM, 30-60mM, 40-60mM, 50-60mM, 10-50mM, 20-50mM, 30-50mM, 40-50mM, 10- 40mM, 20-40mM, 30-40mM, 10-30mM, 20-30mM, 5-45mM, 5-40mM, 5-35mM, 5-30mM, 5-25mM, 5-20mM, 5-15mM, 5-10mM, It may be 1 to 45 mM, 1 to 40 mM, 1 mM or more and less than 40 mM, 1 to 35 mM, 1 to 30 mM, 1 to 25 mM,
- the fruit juice beverage contains threonine, and the threonine content is more than 0 mM and 70 mM or less, 65 mM or less, 60 mM or less, 55 mM or less, 50 mM or less, 50 mM or less, 45 mM or less, 40 mM or less, 40 mM or less, 35 mM.
- it may be 30 mM or less, 25 mM or less, 20 mM or less, 15 mM or less, or 10 mM or less.
- the fruit juice beverage contains phenylalanine, and the content of phenylalanine is more than 0 mM and 15 mM or less, 13 mM or less, 12 mM or less, 11 mM or less, 10 mM or less, 9 mM or less, 8 mM or less, 7 mM or less, 6 mM or less, 5 mM.
- it may be 4 mM or less, 3 mM or less, 2 mM or less, or 1 mM or less.
- Phenylalanine may be L-form, D-form or racemic (DL-form), but is preferably L-form.
- the fruit juice beverage may contain tryptophan and the tryptophan content may be more than 0 mM and 5 mM or less, 4 mM or less, 3 mM or less, 2 mM or less or 1 mM or less. Alternatively, it may be 1 to 5 mM, 2 to 5 mM, 3 to 5 mM or 4 to 5 mM. Tryptophan may be L-form, D-form or racemic (DL-form), but is preferably L-form.
- the fruit juice beverage contains methionine and the methionine content is more than 0 mM and 10 mM or less, 9 mM or less, 8 mM or less, 7 mM or less, 6 mM or less, 5 mM or less, 4 mM or less, 3 mM or less, 2 mM or less or 1 mM. It may be as follows. Alternatively, it may be 1 to 10 mM, 2 to 10 mM, 3 to 10 mM, 4 to 10 mM, 5 to 10 mM, 6 to 10 mM, 7 to 10 mM, 8 to 10 mM or 9 to 10 mM.
- the methionine may be L-form, D-form or racemic (DL-form), but is preferably L-form.
- the fruit juice beverage contains proline
- the content of proline is more than 0 mM and 120 mM or less, 100 mM or less, 80 mM or less, 50 mM or less, 50 mM or less, 45 mM or less, 40 mM or less, 40 mM or less, 35 mM or less, 30 mM.
- it may be 25 mM or less, 20 mM or less, 15 mM or less, or 10 mM or less.
- 10 to 120mM 10 to 100mM, 10 to 80mM, 20 to 80mM, 30 to 80mM, 40 to 80mM, 50 to 80mM, 60 to 80mM, 70 to 80mM, 10 to 70mM, 20 to 70mM, 30 to 70mM, 40-70mM, 50-70mM, 60-70mM, 10-60mM, 20-60mM, 30-60mM, 40-60mM, 50-60mM, 10-50mM, 20-50mM, 30-50mM, 40-50mM, 1mM or more It may be less than 40 mM, 10-40 mM, 20-40 mM, 30-40 mM, 1-30 mM, 5-30 mM, 10-30 mM, 15-30 mM, 20-30 mM or 25-30 mM.
- Proline may be L-form, D-form or racemic (DL-form), but is preferably L-form.
- the fruit juice beverage contains glutamine, and the glutamine content is more than 0 mM and 20 mM or less, 19 mM or less, 18 mM or less, 17 mM or less, 16 mM or less, 15 mM or less, 14 mM or less, 13 mM or less, 12 mM or less, 11 mM.
- it may be 10 mM or less, less than 10 mM, 9 mM or less, 8 mM or less, 7 mM or less, 6 mM or less, 5 mM or less, less than 5 mM, 4 mM or less, 3 mM or less, 2 mM or less or 1 mM or less.
- the fruit juice beverage contains asparagine, and the content of asparagine is more than 0 mM and less than 20 mM, less than 20 mM, 19 mM or less, 18 mM or less, 17 mM or less, 16 mM or less, 15 mM or less, 14 mM or less, 13 mM or less, 12 mM. Below, it may be 11 mM or less, 10 mM or less, less than 10 mM, 9 mM or less, 8 mM or less, 7 mM or less, 6 mM or less, 5 mM or less, 4 mM or less, 5 mM or less, 2 mM or less or 1 mM or less.
- the fruit juice beverage contains arginine, and the content of arginine is more than 0 mM and less than 4.0 mM, 3.5 mM or less, 3.0 mM or less, 2.5 mM or less, less than 2.5 mM, 2.0 mM or less, 1.5 mM or less, It may be 1.0 mM or less, less than 1.0 mM or 0.5 mM or less.
- Arginine may be L-form, D-form or racemic (DL-form), but is preferably L-form.
- the fruit juice beverage may contain lysine and the lysine content may be greater than 0 mM and less than 3.0 mM, 2.5 mM or less, 2.0 mM or less, 1.5 mM or less, 1.0 mM or less or 0.5 mM or less. .. Alternatively, 0.1-3.0mM, 0.1-2.5mM, 0.1-2.0mM, 0.1-1.5mM, 0.1-1.0mM, 0.1-0.5mM, 0.5-3.0mM, 0.5-2.5mM, 0.5-2.0mM, 0.5-1.5 It may be mM or 0.5-1.0 mM. Lysine may be L-form, D-form or racemic (DL-form), but is preferably L-form.
- the fruit juice beverage contains lysine hydrochloride, and the content of lysine hydrochloride is more than 0 mM and 1.0 mM or less, 0.9 mM or less, 0.8 mM or less, 0.7 mM or less, 0.6 mM or less, 0.5 mM or less, It may be less than 0.5 mM, 0.4 mM or less, less than 0.4 mM, 0.3 mM or less, or 0.2 mM or less.
- the fruit juice beverage contains histidine, and the histidine content is more than 0 mM and 4.0 mM or less, 3.5 mM or less, 3.0 mM or less, 2.5 mM or less, 2.0 mM or less, 1.5 mM or less, 1.0 mM or less or. It may be 0.5 mM or less.
- the fruit juice beverage contains glutamate, and the content of glutamate is more than 0 mM and less than 0.50 mM, less than 0.50 mM, 0.40 mM or less, less than 0.40 mM, 0.35 mM or less, 0.30 mM or less, 0.25 mM or less, Less than 0.25mM, 0.20mM or less, 0.15mM or less, 0.14mM or less, 0.13mM or less, 0.12mM or less, 0.11mM or less, 0.10mM or less, 0.09mM or less, 0.08mM or less, 0.07mM or less, 0.06mM or less, 0.05mM Hereinafter, it may be 0.04 mM or less, 0.03 mM or less, 0.02 mM or less, or 0.01 mM or less.
- the fruit juice beverage contains aspartic acid, and the content of aspartic acid is more than 0 mM and 1.5 mM or less, 1.4 mM or less, 1.3 mM or less, 1.2 mM or less, 1.1 mM or less, 1.0 mM or less, 0.9 mM.
- it may be 0.8 mM or less, 0.7 mM or less, 0.6 mM or less, 0.5 mM or less, 0.4 mM or less, 0.3 mM or less, 0.2 mM or less, or 0.1 mM or less.
- Aspartic acid may be L-form, D-form or racemic (DL-form), but is preferably L
- the fruit juice beverage according to one aspect of the present invention does not contain sodium aspartate as an amino acid salt.
- the amino acid content can be measured by automatic amino acid analysis or high performance liquid chromatography. If the blending amount of the amino acid blended in the beverage is known, the value calculated from the blending amount may be used.
- the amino acid is also included in the amino acid in the fruit juice beverage of the present invention. Therefore, the amount of amino acids contained in the fruit juice beverage of the present invention is the total value of those derived from fruit juice and those added from the outside.
- the content of at least one kind of amino acid may be less than the taste recognition threshold value, and the content of some amino acids sets the taste recognition threshold value. It may be exceeded.
- the content of each amino acid may be less than the taste recognition threshold value.
- Yet another aspect of the fruit juice beverage of the present invention is DL-alanine ⁇ 20 mM, L-serine ⁇ 40 mM, glycine ⁇ 50 mM, L-arginine ⁇ 1 mM, L-glutamic acid ⁇ 0.25 mM, L ⁇ 40 mM.
- -Selected from valine, L-glutamine less than 5 mM, L-leucine less than 20 mM, L-threonine less than 40 mM, L-proline less than 40 mM, L-asparagin less than 10 mM and L-lysine hydrochloride less than 0.4 mM May contain one or more amino acids.
- Yet another aspect of the fruit juice beverage of the present invention is DL-alanine of 1 mM or more and less than 20 mM, L-serine of 1 mM or more and less than 40 mM, glycine of 1 mM or more and less than 50 mM, L-arginine of 0.1 mM or more and less than 1.0 mM, 0.10 mM.
- the fruit juice beverage of the present invention contains less than 50 mg / 100 ml of sodium, which means that the content of sodium atoms is less than 50 mg / 100 ml.
- the sodium content is 0.1 mg / 100 ml or more and less than 50 mg / 100 ml, 0.1 to 45 mg / 100 ml, 0.1 to 40 mg / 100 ml, 0.1 to 35 mg / 100 ml, 0.1 to 30 mg / 100 ml, 0.1 to 25 mg / depending on the embodiment.
- the sodium content is 0.1 to 22 mg / 100 ml, 0.1 to 21 mg / 100 ml, 1 to 22 mg / 100 ml, 1 to 21 mg / 100 ml, 4 to 40 mg / 100 ml, 4 to 35 mg / 100 ml, depending on the embodiment.
- the amount of sodium added to fruit juice beverages is 0.1 to 50 mg / 100 ml, 0.1 to 45 mg / 100 ml, 0.1 to 40 mg / 100 ml, 0.1 to 35 mg / 100 ml, 0.1 to 30 mg / 100 ml, 0.1 to 25 mg / 100 ml.
- the form of sodium is not particularly limited as long as it is contained in the fruit juice beverage of the present invention in an ingestible state, but for example, sodium chloride, sodium hydroxide, sodium malate, sodium sulfate, sodium citrate, etc.
- the fruit juice contains sodium
- the sodium derived from the fruit juice is also included in the sodium contained in the fruit juice beverage of the present invention.
- sodium derived from a sodium component used as a preservative for example, sodium benzoate, sodium sulfite, sodium hyposulfate, sodium dehydroacetate, sodium pyrosulfite, sodium propionate, etc.
- a sodium component used as a preservative for example, sodium benzoate, sodium sulfite, sodium hyposulfate, sodium dehydroacetate, sodium pyrosulfite, sodium propionate, etc.
- the content of sodium in the beverage can be measured by the atomic absorption method. If the blending amount of the sodium-containing compound blended in the beverage is known, the value calculated from the blending amount may be used.
- the amount of sodium contained in the fruit juice beverage may be specified by the amount of the sodium source.
- “Sodium source” means a compound capable of producing sodium ions when a fruit juice beverage is placed in the mouth.
- the amount of sodium source may be less than 20 mM.
- the amount of sodium source is about 19 mM or less, about 18 mM or less, about 17 mM or less, about 16 mM or less, about 15 mM or less, about 14 mM or less, about 13 mM or less, about 12 mM or less, about 11 mM or less, About 10mM or less, about 9.0mM or less, about 8.5mM or less, about 8.0mM or less, about 8.5mM or less, about 7.0mM or less, about 7.5mM or less, about 6.0mM or less, about 5.5mM or less, about 5.0mM or less, about 4.5mM or less, about 4.0mM or less, about 3.5mM or less, about 2.0mM or less, about 1.5mM or less, about 1.0mM or less or about 0.5mM or less.
- the amount of sodium source is about 0.1 to about 19 mM, about 0.5 to about 19 mM, about 1.0 to about 19 mM, about 1.5 to about 19 mM, about 2.0 to about 19 mM, about 2.5 to about 19 mM, about.
- the fruit juice beverage of the present invention may contain a sweetener in addition to the high sweetness sweetener of the component (a).
- sweetener means any substance or group of substances that causes a sweetening response.
- the sweeteners can be divided into sugar-based sweeteners and non-sugar-based sweeteners according to their structural characteristics, and low-sweetness sweeteners and high-sweetness sweeteners based on the degree of sweetness.
- sweeteners can be divided into caloric sweeteners and non-caloric sweeteners.
- it can be divided into natural sweeteners and artificial sweeteners based on the acquisition method. If the fruit juice contains a fruit-derived sweetener (fructose, etc.), the sweetener shall also be included in the sweeteners described here.
- Carbohydrate-based sweeteners are not limited to starch sugars such as sucrose, lactose, glucose, maltose, water candy, isomerized sugar, and fructose, and sugar alcohols such as erythritol, sorbitol, mannitol, martitol, xylitol, and palatinit. , Sucrose, palatinose, fructo-oligosaccharide, coupling sugar (R) , galactooligosaccharide, milk fruit oligosaccharide, raffinose, soybean oligosaccharide, honey and the like. In addition, sugar-based sweeteners contain rare sugars.
- Rare sugar refers to monosaccharides and their derivatives whose abundance is small in nature. For example, naturally occurring aldoses other than D-glucose, D-galactose, D-mannose, D-ribose, D-xylose and L-arabinose, naturally occurring ketose other than D-fractose, natural other than D-sorbitol.
- the sugar alcohols and the like present in the rare sugars are included in the rare sugars.
- Non-limiting examples of rare sugars include, for example, D-tagatose, D-sorbose, D-alloth (D-psicose), L-fractose, L-allulose (L-psicose), L-tagatose, L-sorbose, etc.
- Examples thereof include aldose such as ketose, altrose and D-allose, and sugar alcohols such as xylitol, erythritol and D-talitol.
- Caloric sweeteners typically mean sweeteners with an energy of 4 kcal / g. Whether the energy of the sweet substance is known, the content is measured by HPLC etc. and calculated by multiplying by the energy conversion coefficient, or the physical combustion heat is measured by a calorimeter (for example, bomb calorimeter etc.). Can be determined by correcting the digestion and absorption rate, the amount of heat excreted, and the like.
- caloric sweeteners include, for example, sucrose, lactose, glucose, maltose, starch syrup, high fructose corn syrup, fructose, and the like.
- Non-caloric sweeteners typically refer to those that are difficult to digest in the body and result in less energy being taken in, less than 2 kcal / g, preferably less than 1 kcal / g, more preferably. It means a sweetening substance having an energy of less than 0.5 kcal / g.
- Non-caloric examples of non-caloric sweeteners include, for example, non-caloric hexoses such as allose (psicose) and allose, non-caloric pentoses such as xylose and arabinose, non-caloric tetrose such as erythrose and treose, erythritol and aritol.
- Non-caloric sugar alcohols such as, etc. may be mentioned.
- sweet substances can be classified by energy (calorie) level.
- sweet substances can be classified into sweet substances having an energy of 4 kcal / g or more and sweet substances having an energy of less than 4 kcal / g.
- Sweet substances with energy less than 4 kcal / g are further sweet substances with energy less than 3 kcal / g, sweet substances with energy less than 2.5 kcal / g, sweet substances with energy less than 2 kcal / g, 1.5 kcal / Sweet substance with energy less than g, sweet substance with energy less than 1 kcal / g, sweet substance with energy less than 0.5 kcal / g, sweet substance with energy more than 1 kcal / g and less than 4 kcal / g, 2 kcal / Sweet substance with energy of g or more and less than 4 kcal / g, sweet substance with energy of 3 kcal / g or more and less than 4 kcal / g, sweet substance with energy of 2 kcal /
- Sucrose, lactose, glucose, maltose, water candy, isomerized sugar, fructose, etc. are sweet substances having an energy of 4 kcal / g or more
- sorbitol is a sweet substance having an energy of 2 kcal / g or more and less than 4 kcal / g.
- Xylitol, D-xylose, D-ribose, D-tagatose, arabinose, etc. are sweet substances having an energy of 0 kcal / g or more and less than 2 kcal / g, such as D-allulose, erythritol, allose, erythrose, threose, and alitor. And so on.
- the low-sweetness sweetener means a compound having a sweetness similar to that of sucrose (for example, less than 5 times, 0.1 to 2 times, 0.5 to 1.5 times, etc. of sucrose).
- Non-limiting examples of low-sweetness sweeteners include sucrose, high fructose corn syrup, glucose, fructose, lactose, maltose, xylitol, lactulose, fructo-oligosaccharide, malto-oligosaccharide, isomaltooligosaccharide, galactooligosaccharide, and coupling sugar (R).
- low-sweetness sweeteners include rare sugars, caloric sweeteners, non-caloric sweeteners, sugar-based sweeteners, non-sugar-based sweeteners, natural sweeteners, and so on, as long as the sweetness is within the above range. Contains artificial sweeteners.
- the fruit juice beverage according to one aspect of the present invention contains a low-sweetness sweetener.
- the following fruit juice beverage (hereinafter, also referred to as the fruit juice beverage of aspect A) is provided.
- D) Low-sweetness sweetener in an amount equivalent to sweetness intensity X4 may be abbreviated as "ingredient (d)" in the present specification).
- the fruit juice beverage according to one embodiment of the present invention does not contain any component other than (a) a high sweetness sweetener equivalent to an amount of sweetness intensity X1 and (d) a low sweetness sweetener equivalent to an amount of sweetness intensity X4. ..
- the fruit-derived sweetener (fructose, etc.) contained in the fruit juice beverage is included in the sweetener of (d).
- the low sweetness sweetener comprises a sweetener selected from hexose, pentose, tetrose, polysaccharides having aldose or ketose terminal sugars, sugar alcohols and combinations thereof.
- the low sweetness sweetener is selected from glucose, sucrose, fructose, maltose, oligosaccharides, high fructose corn syrup, lactose, psicose, allose, tagatose, xylose, ribose and combinations thereof. including.
- the low sweetness sweetener comprises a sweetener selected from glucose, sucrose, fructose and combinations thereof.
- X4 of "sweetness intensity X4" is 0 to 0.5, 0 to 1.0, 0 to 1.5, 0 to 2.0, 0 to 2.5, 0 to 3.0, 0 to 3.5, 0 to 4.0, 0 to 4.5, 0 to 5.0, 0 to 5.5, 0-6.0, 0-6.5, 0-7.0, 0-7.5, 0-8.0, 0-8.25, 0-8.5, 0-8.75, 0-9.0, 0-9.25, 0-9.5, 0-9.75, 0 to 10.0, 0.05 to 0.5, 0.05 to 1.0, 0.05 to 1.5, 0.05 to 2.0, 0.05 to 2.5, 0.05 to 3.0, 0.05 to 3.5, 0.05 to 4.0, 0.05 to 4.5, 0.05 to 5.0, 0.05 to 5.5, 0.05 to 6.0, 0.05-6.5, 0.05-7.0, 0.05-7.5, 0.05-8.0, 0.05-8.25, 0.05-8.5, 0.05-8.75, 0.05-9.0, 0.05-9.25,
- X4 is also 0 to 10.5, 0 to 11.0, 0 to 11.5, 0 to 12.0, 0 to 12.5, 0 to 13.0, 0 to 13.5, 0 to 14.0, 0 to 14.5, 0 to 15.0, 0.05 to 10.5, 0.05 to 11.0, 0.05-11.5, 0.05-12.0, 0.05-12.5, 0.05-13.0, 0.05-13.5, 0.05-14.0, 0.05-14.5, 0.05-15.0, 0.1-10.5, 0.1-11.0, 0.1-11.5, 0.1-12.0, 0.1 to 12.5, 0.1 to 13.0, 0.1 to 13.5, 0.1 to 14.0, 0.1 to 14.5, 0.1 to 15.0, 0.5 to 10.5, 0.5 to 11.0, 0.5 to 11.5, 0.5 to 12.0, 0.5 to 12.5, 0.5 to 13.0, 0.5 to 13.5, 0.5-14.0, 0.5-14.5, 0.5-15.0, 1.0-10.5, 1.0-11.0, 1.0-11.5, 1.0-12.0, 1.0-12.5, 1.0-13.0, 1.0
- the amount equivalent to the sweetness intensity X4 of the low sweetness sweetener is the amount (concentration) that exhibits the sweetness of the sweetness intensity X4 under the condition that the low sweetness sweetener is dissolved in 20 ° C water having the same volume as the fruit juice beverage of the present invention. To say.
- X4 is preferably 0.05 to 6.0, more preferably 0.05 to 5.0, and even more preferably 0.1 to 4.0.
- X5 is not particularly limited as long as it is larger than X1 + X4, but 4.0 to 20, 4.0 to 15, 4.0 to 12.5, 4.0 to 10, 4.5 to 20, 4.5 to 15, 4.5 to 12.5, 4.5 to 10, 5.0.
- ⁇ 20 5.0 ⁇ 15, 5.0 ⁇ 12.5, 5.0 ⁇ 10, 5.5 ⁇ 20, 5.5 ⁇ 15, 5.5 ⁇ 12.5, 5.5 ⁇ 10, 6.0 ⁇ 20, 6.0 ⁇ 15, 6.0 ⁇ 12.5, 6.0 ⁇ 10, 6.5 ⁇ 20 , 6.5 ⁇ 15, 6.5 ⁇ 12.5, 6.5 ⁇ 10, 7.0 ⁇ 20, 7.0 ⁇ 15, 7.0 ⁇ 12.5, 7.0 ⁇ 10, 7.5 ⁇ 20, 7.5 ⁇ 15, 7.5 ⁇ 12.5, 7.5 ⁇ 10, 7.5 ⁇ 9, 7.5 ⁇ 8, 8.0 ⁇ 20, 8.0 ⁇ 20, 8.0 ⁇ 20, 8.0 ⁇ 15, 8.0 ⁇ 12, 8.0 ⁇ 15, 8.0 ⁇ 12.5, 8.0 ⁇ 10, 8.5 ⁇ 20, 8.5 ⁇ 15, 8.5 ⁇ 12.5,
- X5 is also 4.0-18, 4.0-16, 4.0-15.5, 4.0-14, 4.5-18, 4.5-16, 4.5-15.5, 4.5-14, 5.0-18, 5.0-16, 5.0-15.5, 5.0-14, 5.5-18, 5.5-16, 5.5-15.5, 5.5-14, 6.0-18, 6.0-16, 6.0-15.5, 6.0-14, 6.5-18, 6.5-16, 6.5-15.5, 6.5- 14, 7.0-18, 7.0-16, 7.0-15.5, 7.0-14, 7.5-18, 7.5-16, 7.5-15.5, 7.5-14, 7.5-9, 7.5-8, 8.0-18, 8.0-18, 8.0-16, 8.0-15.5, 8.0-14, 8.5-18, 8.5-16, 8.5-15.5, 8.5-14, 9.0-18, 9.0-16, 9.0-15.5, 9.0-14, 9.5-18, 9.5- It may be 16, 9.5 to 15.5, 9.5 to 14, 10.0 to 18, 10.0 to 16, 10.0 to 15.5, 10.5 to 18, 10.5 to 16 or 10.5 to 15.5.
- the fruit juice beverage of the present invention is an antioxidant (sodium erythorsorbate, etc.), an emulsifier (sucrose fatty acid ester, sorbitan fatty acid ester, polyglycerin fatty acid ester, etc.), and an acidulant (phosphoric acid) as long as the effects of the present invention are not impaired.
- an antioxidant sodium erythorsorbate, etc.
- an emulsifier sucrose fatty acid ester, sorbitan fatty acid ester, polyglycerin fatty acid ester, etc.
- an acidulant phosphoric acid
- Example of the fruit juice beverage according to the first aspect of the present invention In one aspect of the invention (A) High-sweetness sweetener in an amount equivalent to sweetness intensity X1 (B) Amino acids below the taste recognition threshold or derivatives thereof or salts thereof, and (c) less than 50 mg / 100 ml, 0.1-40 mg / 100 ml, 1-30 mg / 100 ml or 5-25 mg / 100 ml sodium. The components (a) to (c) exhibit sweetness with a sweetness intensity of X2, and 0.1 ⁇ X1 ⁇ X2.
- the high-sweetness sweetener is selected from a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably rebaugioside D, rebaugioside M and combinations thereof.
- a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably rebaugioside D, rebaugioside M and combinations thereof.
- X1 is 0.5 to 5.5, preferably 1.0 to 5.5, and more preferably 2.0 to 5.0.
- a fruit juice beverage is provided in which the amino acid or a derivative thereof or a salt thereof contains an amino acid selected from DL-alanine, L-serine, glycine, L-arginine, L-glutamic acid, L-valine and L-glutamine.
- the amount of high sweetness sweetener is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm or about 150 to about 350 ppm. May be.
- A High-sweetness sweetener in an amount equivalent to sweetness intensity X1
- B Amino acids below the taste recognition threshold or derivatives thereof or salts thereof, and (c) less than 50 mg / 100 ml, 0.1-40 mg / 100 ml, 1-30 mg / 100 ml or 5-25 mg / 100 ml sodium.
- the components (a) to (c) exhibit sweetness with a sweetness intensity of X2, and 0.1 ⁇ X1 ⁇ X2.
- the high-sweetness sweetener is selected from a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably rebaugioside D, rebaugioside M and combinations thereof.
- a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably rebaugioside D, rebaugioside M and combinations thereof.
- X1 is 0.5 to 10.0, preferably 1.5 to 9.0, more preferably 2.0 to 8.0
- a fruit juice beverage is provided in which the amino acid or a derivative thereof or a salt thereof contains an amino acid selected from DL-alanine, L-serine, glycine, L-arginine, L-glutamic acid, L-valine and L-glutamine.
- the amount of high sweetness sweetener is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm or about 150 to about 350 ppm. May be.
- a high-sweetness sweetener in an amount equivalent to a sweetness intensity X1.
- B Amino acids below the taste recognition threshold or derivatives thereof or salts thereof,
- C Contains less than 50 mg / 100 ml, 0.1-40 mg / 100 ml, 1-30 mg / 100 ml or 5-25 mg / 100 ml sodium, and
- a low sweetness sweetener in an amount equivalent to sweetness intensity X4.
- the components (a) to (d) exhibit sweetness with a sweetness intensity of X5, and 0.1 ⁇ X1 + X4 ⁇ X5.
- the high-sweetness sweetener is selected from a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- X1 is 0.5 to 5.5, preferably 1.0 to 5.5, and more preferably 2.0 to 5.0.
- Amino acids or derivatives thereof or salts thereof contain amino acids selected from DL-alanine, L-serine, glycine, L-arginine, L-glutamic acid, L-valine and L-glutamine.
- Low sweeteners include sweeteners selected from glucose, sucrose, fructose, maltose, oligosaccharides, high fructose corn syrup, lactose, psicose, allose, tagatose, xylose, ribose and combinations thereof.
- Juice beverages are provided in which X4 is 0.05-6.0, preferably 0.05-5.0, more preferably 0.1-4.0.
- the amount of high sweetness sweetener is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm or about 150 to about 350 ppm. May be.
- a high-sweetness sweetener in an amount equivalent to a sweetness intensity X1.
- B Amino acids below the taste recognition threshold or derivatives thereof or salts thereof,
- C Contains less than 50 mg / 100 ml, 0.1-40 mg / 100 ml, 1-30 mg / 100 ml or 5-25 mg / 100 ml sodium, and
- a low sweetness sweetener in an amount equivalent to sweetness intensity X4.
- the components (a) to (d) exhibit sweetness with a sweetness intensity of X5, and 0.1 ⁇ X1 + X4 ⁇ X5.
- the high-sweetness sweetener is selected from a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- X1 is 0.5 to 5.5, preferably 1.0 to 5.5, and more preferably 2.0 to 5.0.
- Amino acids or derivatives thereof or salts thereof contain amino acids selected from DL-alanine, L-serine, glycine, L-arginine, L-glutamic acid, L-valine and L-glutamine.
- Low sweeteners include sweeteners selected from glucose, sucrose, fructose, maltose, oligosaccharides, high fructose corn syrup, lactose, psicose, allose, tagatose, xylose, ribose and combinations thereof.
- the juice ratio is 1-100%, 4-95%, 5-80%, 5-50% or 5-30%.
- Juice beverages are provided in which X4 is 0.05-6.0, preferably 0.05-5.0, more preferably 0.1-4.0.
- the amount of high sweetness sweetener is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm or about 150 to about 350 ppm. May be.
- a high-sweetness sweetener in an amount equivalent to a sweetness intensity X1.
- B Amino acids below the taste recognition threshold or derivatives thereof or salts thereof,
- C Contains less than 50 mg / 100 ml, 0.1-40 mg / 100 ml, 1-30 mg / 100 ml or 5-25 mg / 100 ml sodium, and
- a low sweetness sweetener in an amount equivalent to sweetness intensity X4.
- the components (a) to (d) exhibit sweetness with a sweetness intensity of X5, and 0.1 ⁇ X1 + X4 ⁇ X5.
- the high-sweetness sweetener is selected from a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- X1 is 0.5 to 5.5, preferably 1.0 to 5.5, and more preferably 2.0 to 5.0.
- Amino acids or derivatives thereof or salts thereof have DL-alanine less than 20 mM, L-serine less than 40 mM, glycine less than 50 mM, L-arginine less than 1 mM, L-glutamic acid less than 0.25 mM, L-valine less than 40 mM, Amino acids selected from less than 5 mM L-glutamine, less than 20 mM L-leucine, less than 40 mM L-threonine, less than 40 mM L-proline, less than 10 mM L-asparagin and less than 0.4 mM L-lysine hydrochloride Including, Low sweeteners include sweeteners selected from glucose, sucrose, fructose, maltose, oligosaccharides, high fructose corn syrup, lactose, psicose, allose, tagatose, xylose, ribose and combinations thereof.
- Juice beverages are provided in which X4 is 0.05-6.0, preferably 0.05-5.0, more preferably 0.1-4.0.
- the amount of high sweetness sweetener is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm or about 150 to about 350 ppm. May be.
- a high-sweetness sweetener in an amount equivalent to a sweetness intensity X1.
- B Amino acids below the taste recognition threshold or derivatives thereof or salts thereof
- C Contains less than 50 mg / 100 ml, 0.1-40 mg / 100 ml, 1-30 mg / 100 ml or 5-25 mg / 100 ml sodium, and
- a low sweetness sweetener in an amount equivalent to a sweetness intensity X4.
- the components (a) to (d) exhibit sweetness with a sweetness intensity of X5, and 0.1 ⁇ X1 + X4 ⁇ X5.
- the high-sweetness sweetener is selected from a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- X1 is 0.5 to 5.5, preferably 1.0 to 5.5, and more preferably 2.0 to 5.0.
- Amino acids or derivatives thereof or salts thereof contain amino acids selected from arginine, lysine, histidine, phenylalanine, tyrosine, leucine, isoleucine, methionine, valine, alanine, glycine, proline, glutamic acid, serine, threonine, aspartic acid and tryptophan.
- Low sweetness sweeteners include sweeteners selected from glucose, sucrose, fructose and combinations thereof.
- the juice is one or more selected from oranges, oranges, lemons, grapefruits, limes and combinations thereof.
- the juice ratio is 1-100%, 4-95%, 5-80%, 5-50% or 5-30%.
- Juice beverages are provided in which X4 is 0.05-6.0, preferably 0.05-5.0, more preferably 0.1-4.0.
- the amount of high sweetness sweetener is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm or about 150 to about 350 ppm. May be.
- a high-sweetness sweetener in an amount equivalent to a sweetness intensity X1.
- B Amino acids below the taste recognition threshold or derivatives thereof or salts thereof,
- C Contains less than 50 mg / 100 ml, 0.1-40 mg / 100 ml, 1-30 mg / 100 ml or 5-25 mg / 100 ml sodium, and
- a low sweetness sweetener in an amount equivalent to sweetness intensity X4.
- the components (a) to (d) exhibit sweetness with a sweetness intensity of X5, and 0.1 ⁇ X1 + X4 ⁇ X5.
- the high-sweetness sweetener is selected from a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- X1 is 0.5 to 5.5, preferably 1.0 to 5.5, and more preferably 2.0 to 5.0.
- Amino acids or derivatives thereof or salts thereof contain amino acids selected from arginine, valine, alanine, glycine, proline, glutamic acid, serine, threonine, aspartic acid and tryptophan.
- Low sweetness sweeteners include sweeteners selected from glucose, sucrose, fructose and combinations thereof.
- the juice is one or more selected from blueberries, cassis, cranberries, strawberries, raspberries and combinations thereof.
- the juice ratio is 1-100%, 4-95%, 5-80%, 5-50% or 5-30%.
- Juice beverages are provided in which X4 is 0.05-6.0, preferably 0.05-5.0, more preferably 0.1-4.0.
- the amount of high sweetness sweetener is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm or about 150 to about 350 ppm. May be.
- A High-sweetness sweetener in an amount equivalent to sweetness intensity X1
- B One or more amino acids selected from alanine, serine and glycine, It contains (c) 1 to 25 mg / 100 ml of sodium and (d) a low sweetness sweetener in an amount equivalent to a sweetness intensity X4.
- the components (a) to (d) exhibit sweetness with a sweetness intensity of X5, and 0.1 ⁇ X1 + X4 ⁇ X5.
- a fruit juice beverage having an energy of 50 Kcal / 100 ml or less and X1 + X4 of 6 or more is provided.
- the amount of high sweetness sweetener is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm or about 150 to about 350 ppm. May be.
- a high-sweetness sweetener in an amount equivalent to a sweetness intensity X1.
- B Amino acids below the taste recognition threshold or derivatives thereof or salts thereof,
- C Contains less than 50 mg / 100 ml, 0.1-40 mg / 100 ml, 1-30 mg / 100 ml or 5-25 mg / 100 ml sodium, and
- a low sweetness sweetener in an amount equivalent to sweetness intensity X4.
- the components (a) to (d) exhibit sweetness with a sweetness intensity of X5, and 0.1 ⁇ X1 + X4 ⁇ X5.
- the high-sweetness sweetener is selected from a high-sweetness sweetener selected from rebaugioside A, rebaugioside D, rebaugioside M, mogroside V, Luo Han Guo extract and combinations thereof, preferably from rebaugioside D, rebaugioside M and combinations thereof.
- X1 is 1.0 to 11.0, preferably 1.5 to 10.0, or 1.5 to 6.0 or 4.0 to 10.0.
- Amino acids or derivatives thereof or salts thereof contain amino acids selected from arginine, valine, alanine, glycine, proline, glutamic acid, serine, threonine, aspartic acid and tryptophan.
- Low sweetness sweeteners include sweeteners selected from glucose, sucrose, fructose and combinations thereof. Juice beverages are provided in which the X4 is 0.5-9.0, preferably 1.0-8.0, or 1.0-5.0 or 2.5-9.0. In this embodiment, the amount of high sweetness sweetener is about 20 to about 600 ppm, about 30 to about 550 ppm, about 55 to about 490 ppm, about 20 to about 200 ppm, about 100 to about 500 ppm or about 200 to about 450 ppm. May be.
- the present invention provides, as a second aspect, the following method for producing a fruit juice beverage having an increased sweetness (hereinafter, referred to as "the production method of the present invention").
- the production method of the present invention which comprises adding (a) a high-intensity sweetener in an amount of sweetness intensity X1 and (b) adding an amino acid or a derivative thereof or a salt thereof below the taste recognition threshold. ..
- X1 and X3 correspond to Xa and Xb of the second aspect (corresponding to Japanese Patent Application No. 202-147848 / 2020-185335), respectively.
- the present invention provides, as the second aspect of A2, the following method for producing a fruit juice beverage having an increased sweetness (hereinafter, also referred to as "the production method A of the present invention”).
- the production method A of the present invention For raw materials A method for producing a fruit juice beverage of the present invention, which comprises adding (a) a high-intensity sweetener in an amount of sweetness intensity Xa, and (b) adding an amino acid or a derivative thereof or a salt thereof below the taste recognition threshold. ..
- the fruit juice beverage produced by the method of the present invention is the fruit juice beverage A of the present invention described in the above item "1.
- Fruit juice beverage with increased sweetness exhibited by a high-sweetness sweetener may be each material necessary for producing a fruit juice beverage or a mixture thereof, and may further contain arbitrary components such as preservatives, flavors and carriers. .. Further, the "raw material” may be composed of a plurality of materials.
- any of the following (a) and (b) may be performed first.
- the two steps may be performed at the same time.
- (a) and (b) may be performed at the same time.
- step (a) an amount of high-sweetness sweetener equivalent to sweetness intensity Xa is added to the raw material, but it is not necessary to add an amount of high-sweetness sweetener equivalent to sweetness intensity Xa at a time. It may be added in divided doses.
- the amino acid or its derivative or its salt added to the raw material in the step (b) is selected from the amino acid or its derivative or its salt described in the first or A1 aspect of the above item "1. Fruit juice beverage with increased sweetness”. can do.
- addition not only means an operation of actually adding either of the components (a) and (b) to the raw material, but is finally produced through the production process of the fruit juice beverage A of the present invention. It also means an operation of adjusting the amounts of the components (a) and (b) in the fruit juice beverage to predetermined amounts.
- the first raw material contains fruit juice, grains, beans and their extracts, for which the raw material previously contains one or more of the ingredients (a) and (b) and is mixed with the first raw material.
- the second raw material for the purpose also contains the components (a) and (b), and when the fruit juice beverage A of the present invention can be produced by mixing the first and second raw materials, the components (a) and ( Although there is no operation to add b) individually to the raw materials, in the method of the present invention, the finally produced fruit juice beverage of the present invention is (a) a high sweetness sweetener in an amount equivalent to the sweetness intensity Xa. , And (b) as long as it contains an amino acid below the taste recognition threshold or a derivative thereof or a salt thereof, steps (a) and (b) are considered to have been performed.
- the production method of one aspect of the present invention further comprises (c) adding a low-sweetness sweetener in an amount equivalent to the sweetness intensity Xc.
- the fruit juice beverage of Aspect A can be produced.
- the steps (a) to (c) may be performed separately, or two or more steps may be performed at the same time. For example, (a) and (b), (a) and (c), (b) and (c), or (a) and (b) and (c) may be performed at the same time.
- the method for producing the beverage of the present invention includes a step of filling the container with the fruit juice beverage.
- a packaged beverage it is preferable to sterilize the fruit juice beverage before or after filling the container, because long-term storage is possible.
- a can can be filled with a predetermined amount of fruit juice beverage, and for example, retort sterilization can be performed at 120 to 125 ° C. for about 5 to 20 minutes to perform heat sterilization.
- UHT sterilization that is held at 130 to 145 ° C. for about 2 to 120 seconds is performed, and a predetermined amount is filled in a hot pack or aseptically at a low temperature. You can get a bottled beverage.
- fruit juice beverage sweetness intensity Xa
- high sweetness sweetener sweetness intensity Xb
- amino acid or derivative thereof or salt thereof amino acid or derivative thereof or salt thereof
- arbitrary component low sweetness degree
- Other ingredients energy are the same as the definitions described in the items in the first and A1 aspects of the fruit juice beverage, and the numerical values thereof are the same.
- the numerical values described in the items in the first and A1 aspects of the fruit juice beverage are directly applicable.
- the present invention provides, as a second aspect, a method for producing a fruit juice beverage having the following increased sweetness (hereinafter, also referred to as “the production method B of the present invention”).
- the production method B of the present invention For raw materials (A) Adding a high-intensity sweetener in an amount of sweetness intensity X1, (B) Add amino acids or derivatives thereof or salts thereof below the taste recognition threshold, and (c) Add sodium so that the sodium content in the beverage is less than 50 mg / 100 ml.
- the method for producing a fruit juice beverage according to the present invention for producing a fruit juice beverage according to the present invention.
- the fruit juice beverage produced by the method of the present invention is the fruit juice beverage B of the present invention described in the above item "1.
- Fruit juice beverage with increased sweetness exhibited by a high-sweetness sweetener may be each material necessary for producing a fruit juice beverage or a mixture thereof, and may further contain arbitrary components such as preservatives, flavors, and carriers. Further, the "raw material” may be composed of a plurality of materials.
- any of the following (a) to (c) may be performed first.
- (A) Add a high-intensity sweetener in an amount of sweetness intensity X1
- (b) Add an amino acid or a derivative thereof or a salt thereof below the taste recognition threshold
- (c) Sodium content in the beverage is 50 mg / 100 ml. Add sodium so that it is less than
- two or more steps may be performed at the same time. For example, (a) and (b), (a) and (c), (b) and (c) or (a) and (b) and (c) may be performed at the same time.
- step (a) an amount of high-sweetness sweetener equivalent to sweetness intensity X1 is added to the raw material, but it is not necessary to add an amount of high-sweetness sweetener equivalent to sweetness intensity X1 at a time. It may be added in divided doses.
- the amino acid or its derivative or its salt added to the raw material in the step (b) can be selected from the amino acid or its derivative or its salt described in the first aspect of B1 of the above item "1. Fruit juice beverage with increased sweetness”. can.
- the sodium (or sodium source) added to the raw material in the step (c) can be selected from the sodium (or sodium source) described in the first aspect of the above item "1. Fruit juice beverage with increased sweetness”.
- addition not only means an operation of actually adding any of the components (a), (b) and (c) to the raw material, but also finally through the manufacturing process of the fruit juice beverage of the present invention. It also means an operation of adjusting the amounts of the components (a), (b) and (c) in the produced fruit juice beverage to predetermined amounts.
- the first raw material contains fruit juice, grains, beans and extracts thereof, and therefore the raw material contains one or more of the components (a), (b) and (c) in advance, and the first When the second raw material for mixing with the raw material also contains the components (a), (b) and (c), and the fruit juice beverage of the present invention can be produced by mixing the first and second raw materials.
- Steps (a), (b) and (c) are not added to the raw materials individually, but in the method of the present invention, the finally produced fruit juice beverage of the present invention is (a) sweetened. Steps (a)-(c) are as long as they contain (b) an amino acid or derivative thereof or a salt thereof and (c) less than 50 mg / 100 ml of sodium, as long as it contains an amount of high-sweetness sweetener equivalent to intensity X1. It is considered to have been done.
- the production method of one aspect of the present invention further comprises (d) adding a low-sweetness sweetener in an amount equivalent to the sweetness intensity X4.
- the fruit juice beverage of Aspect A can be produced.
- the steps (a) to (d) may be performed separately, or two or more steps may be performed at the same time.
- (a) and (b), (a) and (c), (a) and (d), (b) and (c), (b) and (d), (c) and (d), (A) and (b) and (c), (a) and (b) and (d), (a) and (c) and (d), (b) and (c) and (d) or (a) ), (B), (c) and (d) may be performed at the same time.
- the method for producing the beverage of the present invention includes a step of filling the container with the fruit juice beverage.
- a packaged beverage it is preferable to sterilize the fruit juice beverage before or after filling the container, because long-term storage is possible.
- a can can be filled with a predetermined amount of fruit juice beverage, and for example, retort sterilization can be performed at 120 to 125 ° C. for about 5 to 20 minutes to perform heat sterilization.
- UHT sterilization that is held at 130 to 145 ° C. for about 2 to 120 seconds is performed, and a predetermined amount is filled in a hot pack or aseptically at a low temperature. You can get a bottled beverage.
- fruit juice beverage "sweetness intensity X1", “high sweetness sweetener”, “sweetness intensity X2”, amount of sodium, form of sodium in fruit juice beverage, "amino acid or derivative thereof or salt thereof”.
- sweetness intensity X3 "Arbitrary ingredient”, “Low sweetness sweetener”, “Sweetness intensity X4", “Sweetness intensity X5", "Other ingredients” and energy are the above-mentioned B1 aspects of the fruit juice beverage.
- the same as the definition described in the item of, and the numerical value is directly applied to the numerical value described in the item in the first aspect of the fruit juice beverage.
- the present invention provides, as a third aspect, a method for enhancing the sweetness intensity of a fruit juice beverage (hereinafter, referred to as "the method for enhancing the present invention").
- a fruit juice beverage is made to contain (a) a high-sweetness sweetener in an amount equivalent to a sweetness intensity X1 and (b) an amino acid below the taste recognition threshold or a derivative thereof or a salt thereof.
- a characteristic method for enhancing the sweetness intensity of a fruit juice beverage is provided.
- X1 corresponds to Xa of the third aspect (corresponding to Japanese Patent Application No. 202-147848 / 2020-185335).
- the present invention provides, as a third aspect, a method for enhancing the sweetness intensity of a fruit juice beverage (hereinafter, referred to as "enhancing method A of the present invention").
- a fruit juice beverage is made to contain (a) a high-sweetness sweetener in an amount equivalent to a sweetness intensity Xa, and (b) an amino acid below the taste recognition threshold or a derivative thereof or a salt thereof.
- a characteristic method for enhancing the sweetness intensity of a fruit juice beverage is provided.
- a fruit juice beverage that enhances the sweetness of the fruit juice beverage and that produces a sweetness that exceeds the sweetness intensity when the component (a) is simply added to the fruit juice beverage.
- amino acids are added simultaneously or separately to a fruit juice beverage containing a predetermined amount of a high-intensity sweetener so that the fruit juice beverage contains amino acids below the taste recognition threshold after the addition.
- the sweetness of the fruit juice beverage brings about a sweetness exceeding the sweetness intensity when only a high-sweetness sweetener is added.
- the type and amount of the amino acid or its derivative or its salt to be added are determined by the type and amount of the amino acid or its derivative or its salt in the fruit juice beverage described in the first or A1 aspect of the above item "1.
- Fruit juice beverage with increased sweetness Can be selected to be the type and content of.
- amino acids selected from glycine, alanine, valine, isoleucine, leucine, serine, threonine, glutamine, asparagine, arginine, lysine, histidine and combinations thereof are used in the above item "1.
- Fruit juice beverage with increased sweetness It may be added to the fruit juice beverage in the amount described in 1 or A1.
- a low-sweetness sweetener corresponding to the sweetness intensity Xc may be further contained.
- a fruit juice beverage that enhances the sweetness of the fruit juice beverage and simply produces a sweetness exceeding the sweetness intensity when the component (a) and the component (d) are added to the fruit juice beverage. ..
- an amino acid is added to a fruit juice beverage containing a predetermined amount of a high-sweetness sweetener and a low-sweetness sweetener so that the fruit juice beverage contains an amino acid below the taste recognition threshold after the addition. This brings about a sweetness exceeding the sweetness intensity when only the high-sweetness sweetener and the low-sweetness sweetener are added to the fruit juice beverage.
- the fruit juice beverage is provided with (b) an amino acid below the taste recognition threshold or a derivative thereof or a salt thereof, and (c) a low-sweetness sweetener in an amount equivalent to the sweetness intensity Xc.
- a method for enhancing the sweetness intensity of a fruit juice beverage which is characterized by inclusion. According to the enhancing method of this embodiment, it is possible to provide a fruit juice beverage that enhances the sweetness of the fruit juice beverage and simply produces a sweetness exceeding the sweetness intensity when the component (c) is added to the fruit juice beverage.
- an amino acid is added to a fruit juice beverage containing a predetermined amount of a low-sweetness sweetener so that the fruit juice beverage contains an amino acid below the taste recognition threshold after the addition.
- Low sweetness A sweetness that exceeds the sweetness intensity when only a sweetener is added is obtained.
- the type and amount of the amino acid or its derivative or a salt thereof to be added are the amino acids in the fruit juice beverage described in the first or A1 aspect of the above item "1.
- Fruit juice beverage with increased sweetness It can be selected according to the type and content of the derivative or its salt.
- amino acids selected from glycine, alanine, valine, isoleucine, leucine, serine, threonine, glutamine, asparagine, arginine, lysine, histidine and combinations thereof are used in the above item "1.
- Fruit juice beverage with increased sweetness It may be added to the fruit juice beverage in the amount described in 1 or A1.
- an amino acid below the taste recognition threshold is added to a fruit juice beverage containing a high sweetness sweetener in an amount equivalent to a sweetness intensity Xa and / or a low sweetness sweetener in an amount equivalent to a sweetness intensity Xc.
- the amount of amino acid added in the fruit juice beverage is 100 mM or less, 90 mM or less, 80 mM or less, 70 mM or less, 60 mM or less, 50 mM or less, 40 mM or less, 30 mM or less, 20 mM or less, 15mM or less, 14mM or less, 13mM or less, 12mM or less, 11mM or less, 10mM or less, 9.5mM or less, 9.0mM or less, 8.5mM or less, 8.0mM or less, 7.5mM or less, 7.0mM or less, 6.5mM or less, 6.0mM or less, 5.5mM or less, 5.0mM or less, 4.5mM or less, 4.0mM or less, 3.5mM or less, 3.0mM or less, 2.5mM or less, 2.0mM or less, 1.5mM or less, 1.0mM or less, 0.5mM or less, 0.5-100
- fruit juice beverage In the method for enhancing sweetness of the present invention, "fruit juice beverage”, “sweetness intensity Xa”, “high sweetness sweetener”, “sweetness intensity Xb”, “amino acid or derivative thereof or salt thereof”, “arbitrary component”, “low” “Sweetness sweetener”, “sweetness intensity Xc”, “sweetness intensity Xd”, “other ingredients” and energy are the same as the definitions described in the items in the first and first aspects of the fruit juice beverage, and the same thereof.
- the numerical values the numerical values described in the items in the first and A1 aspects of the fruit juice beverage are directly applied.
- the present invention provides, as a third aspect, a method for enhancing the sweetness intensity of a fruit juice beverage (hereinafter, also referred to as "enhancing method B of the present invention").
- enhancing method B of the present invention in a fruit juice beverage, (a) a high-sweetness sweetener in an amount equivalent to a sweetness intensity X1.
- a fruit juice beverage that enhances the sweetness of the fruit juice beverage and that produces a sweetness that exceeds the sweetness intensity when the component (a) is simply added to the fruit juice beverage.
- sodium (or sodium source) and amino acids are added simultaneously or separately to a fruit juice beverage containing a predetermined amount of a high-intensity sweetener, and after the addition, less than 50 mg / 100 ml of sodium and less than 50 mg / 100 ml of sodium in the fruit juice beverage.
- amino acids below the taste recognition threshold, the sweetness of the fruit juice beverage is brought about to be sweeter than the sweetness intensity when only the high-sweetness sweetener is added.
- the amount of sodium (or sodium source) to be added can be selected from the amount described in the first aspect of the above item "1.
- Fruit juice beverage with increased sweetness The type and amount of the amino acid or its derivative or its salt to be added are the amino acid or its derivative or its salt in the fruit juice beverage described in the first aspect of the above item "1.
- Fruit juice beverage with increased sweetness It can be selected according to the type and content. For example, amino acids selected from glycine, alanine, valine, isoleucine, leucine, serine, threonine, glutamine, asparagine, arginine, lysine, histidine and combinations thereof are used in the above item "1.
- Fruit juice beverage with increased sweetness It may be added to the fruit juice beverage in the amount described in the aspect of B1.
- a low-sweetness sweetener in an amount corresponding to the sweetness intensity X4 may be further contained.
- a fruit juice beverage that enhances the sweetness of the fruit juice beverage and simply produces a sweetness exceeding the sweetness intensity when the component (a) and the component (d) are added to the fruit juice beverage. ..
- sodium (or sodium source) and amino acids are added simultaneously or separately to a fruit juice beverage containing a predetermined amount of a high-sweetness sweetener and a low-sweetness sweetener, and after the addition, 50 mg is added to the fruit juice beverage.
- High sweetness sweeteners in the fruit juice beverage by including less than / 100 ml, 0.1-40 mg / 100 ml, 1-30 mg / 100 ml or 5-25 mg / 100 ml sodium and amino acids below the taste recognition threshold. And low sweetness brings about a sweetness that exceeds the sweetness intensity when only a sweetener is added.
- an amino acid below the taste recognition threshold or a derivative thereof or a salt thereof is added to the fruit juice beverage.
- a method for enhancing the sweetness intensity of a fruit juice beverage which comprises (c) sodium less than 50 mg / 100 ml, and (d) a low-sweetness sweetener in an amount equivalent to the sweetness intensity X4.
- sodium (or sodium source) and amino acids are added simultaneously or separately to a fruit juice beverage containing a predetermined amount of a low-sweetness sweetener, and after the addition, less than 50 mg / 100 ml, 0.
- a low-sweetness sweetener is added to the fruit juice beverage by containing 1 to 40 mg / 100 ml, 1 to 30 mg / 100 ml or 5 to 25 mg / 100 ml of sodium and amino acids below the taste recognition threshold. Brings sweetness that exceeds the sweetness intensity.
- the amount of sodium (or sodium source) to be added can be selected from the amount described in the first aspect of the above item "1. Fruit juice beverage with increased sweetness".
- the type and amount of the amino acid or its derivative or its salt to be added are the amino acid or its derivative or its salt in the fruit juice beverage described in the first aspect of the above item "1.
- Fruit juice beverage with increased sweetness It can be selected according to the type and content.
- amino acids selected from glycine, alanine, valine, isoleucine, leucine, serine, threonine, glutamine, asparagine, arginine, lysine, histidine and combinations thereof are used in the above item "1.
- Fruit juice beverage with increased sweetness It may be added to the fruit juice beverage in the amount described in the aspect of B1.
- a fruit juice beverage containing a high sweetness sweetener in an amount equivalent to a sweetness intensity X1 and / or a low sweetness sweetener in an amount equivalent to a sweetness intensity X4 contains less than 50 mg / 100 ml of sodium and less than the taste recognition threshold.
- the amount of sodium added is such that the amount of sodium in the fruit juice beverage is 0.1 to 40 mg / 100 ml, 1 to 30 mg / 100 ml, or 5 to 25 mg / 100 ml.
- the amount of sodium in the juice drink is 0.1 to 45 mg / 100 ml, 0.1 to 40 mg / 100 ml, 0.1 to 35 mg / 100 ml, 0.1 to 30 mg / 100 ml, 0.1 to 25 mg / 100 ml, 0.1 to 20 mg.
- 0.1-10mg / 100ml 1mg / 100ml or more and less than 50mg / 100ml, 1-45mg / 100ml, 1-40mg / 100ml, 1-35mg / 100ml, 1-30mg / 100ml, 1-25mg / 100 ml, 1-20 mg / 100 ml, 1-19 mg / 100 ml, 1-18 mg / 100 ml, 1-17 mg / 100 ml, 1-16 mg / 100 ml, 1-15 mg / 100 ml, 1-14 mg /
- the amount of amino acid added in the fruit juice beverage is 100 mM or less, 90 mM or less, 80 mM or less, 70 mM or less, 60 mM or less, 50 mM or less, 40 mM or less, 30 mM or less, 20 mM or less, 15mM or less, 14mM or less, 13mM or less, 12mM or less, 11mM or less, 10mM or less, 9.5mM or less, 9.0mM or less, 8.5mM or less, 8.0mM or less, 7.5mM or less, 7.0mM or less, 6.5mM or less, 6.0mM or less, 5.5mM or less, 5.0mM or less, 4.5mM or less, 4.0mM or less, 3.5mM or less, 3.0mM or less, 2.5mM or less, 2.0mM or less, 1.5mM or less, 1.0mM or less, 0.5mM or less, 0.5-100
- fruit juice beverage In the method for enhancing sweetness of the present invention, "fruit juice beverage”, “sweetness intensity X1”, “high sweetness sweetener”, “sweetness intensity X2”, amount of sodium, form of sodium in fruit juice beverage, "amino acid or derivative thereof or The salt, “sweetness intensity X3", “arbitrary ingredient”, “low sweetness sweetener”, “sweetness intensity X4", “sweetness intensity X5", “other ingredients” and energy are the B1 of the above fruit juice beverage.
- the numerical value is the same as the definition described in the item in the aspect of the above-mentioned fruit juice beverage, and the numerical value described in the item in the item B1 of the above-mentioned fruit juice beverage is directly applied.
- Concentrate for providing fruit juice beverage ⁇ 4th and 4th A4 embodiments provides, as a fourth aspect, a concentrate for providing the following fruit juice beverages (hereinafter referred to as "concentrate of the present invention"). It contains (a) a high-intensity sweetener in an amount equivalent to the sweetness intensity X1 and (b) an amino acid below the taste recognition threshold or a derivative thereof or a salt thereof. A fruit juice beverage having a sweetness intensity of X3 and 0.1 ⁇ X1 ⁇ X3 due to the components (a) and (b).
- X1 and X3 correspond to Xa and Xb of the aspect A4 described later (corresponding to Japanese Patent Application No. 202-147848 / 2020-185335), respectively.
- the present invention provides, as an aspect of A4, a concentrate for providing the following fruit juice beverage (hereinafter, also referred to as "concentrate A of the present invention”). It contains (a) a high-intensity sweetener in an amount equivalent to the sweetness intensity Xa, and (b) an amino acid below the taste recognition threshold or a derivative thereof or a salt thereof.
- a fruit juice beverage having a sweetness intensity of Xb and 0.1 ⁇ Xa ⁇ Xb due to the components (a) and (b).
- the concentrate for providing the above-mentioned fruit juice beverage containing (a) a high-sweetness sweetener in an amount equivalent to the sweetness intensity Xaa, and (b) an amino acid or a derivative thereof or a salt thereof having a taste recognition threshold of less than 10 times.
- the concentrate of the present invention is used to provide a fruit juice beverage by diluting it at an arbitrary ratio.
- the "fruit juice beverage” is the same as that described for the first or first aspect of "1. fruit juice beverage with increased sweetness".
- the concentrate of the present invention can be used in beverages as a syrup or undiluted solution. At that time, it can be diluted 2-fold, 3-fold, 4-fold, 5-fold, 6-fold, 7-fold, 8-fold, 9-fold or 10-fold before use. Further, since the concentrate of the present invention is concentrated, it is preferable in terms of storage stability and transportability.
- the concentrate of the present invention may be solid or liquid.
- the concentrate of the present invention is a 2- to 10-fold concentrate, preferably a 3- to 9-fold concentrate, more preferably a 4- to 8-fold concentrate, and even more preferably 5 times the fruit juice beverage of the present invention. It is a 7-fold concentrate.
- the concentrate according to one aspect of the present invention is a 5-fold concentrate of the fruit juice beverage of the present invention. It contains (a) a high-sweetness sweetener in an amount equivalent to the sweetness intensity Xaa, and (b) an amino acid or a derivative thereof or a salt thereof that is less than 5 times the taste recognition threshold.
- the components (a) and (b) exhibit sweetness with a sweetness intensity of Xba, 0.5 ⁇ Xaa ⁇ Xba, preferably 1.0 ⁇ Xaa ⁇ Xba, and more preferably 2.0 ⁇ Xaa ⁇ Xba.
- the concentrate according to another aspect of the present invention is a 10-fold concentrate of the fruit juice beverage of the present invention. It contains (a) a high-sweetness sweetener in an amount equivalent to the sweetness intensity Xab, and (b) an amino acid or a derivative thereof or a salt thereof that is less than 10 times the taste recognition threshold.
- the components (a) and (b) exhibit sweetness with a sweetness intensity of Xbb, 1.0 ⁇ Xab ⁇ Xbb, preferably 2.0 ⁇ Xab ⁇ Xbb, and more preferably 4.0 ⁇ Xab ⁇ Xbb.
- the concentrate according to one aspect of the present invention is a 5-fold concentrate of the fruit juice beverage of the present invention.
- A High sweetness sweetener in an amount equivalent to sweetness intensity Xaa, It contains (b) an amino acid less than 5 times the taste recognition threshold or a derivative thereof or a salt thereof, and (c) a low-sweetness sweetener in an amount equivalent to the sweetness intensity Xca.
- the components (a) to (c) exhibit sweetness with a sweetness intensity of Xda, 0.5 ⁇ Xaa + Xca ⁇ Xda, preferably 1.0 ⁇ Xaa + Xca ⁇ Xda, and more preferably 2.0 ⁇ Xaa + Xca ⁇ Xda.
- the concentrate according to one aspect of the present invention is a 10-fold concentrate of the fruit juice beverage of the present invention.
- A High sweetness sweetener in an amount equivalent to sweetness intensity Xaa, It contains (b) an amino acid less than 10 times the taste recognition threshold or a derivative thereof or a salt thereof, and (c) a low-sweetness sweetener in an amount equivalent to the sweetness intensity Xca.
- the components (a) to (c) exhibit sweetness with a sweetness intensity of Xda, 1.0 ⁇ Xaa + Xca ⁇ Xda, preferably 2.0 ⁇ Xaa + Xca ⁇ Xda, and more preferably 4.0 ⁇ Xaa + Xca ⁇ Xda.
- the present invention provides, as an aspect of B4, a concentrate for providing the following fruit juice beverage (hereinafter, also referred to as "concentrate B of the present invention").
- Concentrate B of the present invention a concentrate for providing the following fruit juice beverage (hereinafter, also referred to as "concentrate B of the present invention”).
- A High-sweetness sweetener in an amount equivalent to sweetness intensity X1
- B Amino acids below the taste recognition threshold or derivatives thereof or salts thereof, and (c) less than 50 mg / 100 ml of sodium.
- a fruit juice beverage having a sweetness intensity of X2 and 0.1 ⁇ X1 ⁇ X2 due to the components (a) to (c).
- compositions for providing the above fruit juice beverages include (b) amino acids or derivatives thereof or salts thereof that are less than 10 times the taste recognition threshold, and (c) sodium less than 500 mg / 100 ml.
- the concentrate of the present invention is used to provide a fruit juice beverage by diluting it at an arbitrary ratio.
- the "fruit juice beverage” is the same as that described for the first aspect of "1.
- the concentrate of the present invention can be used in beverages as a syrup or undiluted solution. At that time, it can be diluted 2-fold, 3-fold, 4-fold, 5-fold, 6-fold, 7-fold, 8-fold, 9-fold or 10-fold before use. Further, since the concentrate of the present invention is concentrated, it is preferable in terms of storage stability and transportability.
- the concentrate of the present invention may be solid or liquid.
- the concentrate of the present invention is a 2- to 10-fold concentrate, preferably a 3- to 9-fold concentrate, more preferably a 4- to 8-fold concentrate, and even more preferably 5 times the fruit juice beverage of the present invention. It is a 7-fold concentrate.
- the concentrate according to one aspect of the present invention is a 5-fold concentrate of the fruit juice beverage of the present invention.
- A High-sweetness sweetener in an amount equivalent to sweetness intensity X1a, It contains (b) an amino acid less than 5 times the taste recognition threshold or a derivative thereof or a salt thereof, and (c) less than 250 mg / 100 ml of sodium.
- the components (a) to (c) exhibit sweetness with a sweetness intensity of X2a, 0.5 ⁇ X1a ⁇ X2a, preferably 1.0 ⁇ X1a ⁇ X2a, and more preferably 2.0 ⁇ X1a ⁇ X2a.
- the concentrate according to another aspect of the present invention is a 10-fold concentrate of the fruit juice beverage of the present invention.
- A High-sweetness sweetener in an amount equivalent to sweetness intensity X1b, It contains (b) an amino acid less than 10 times the taste recognition threshold or a derivative thereof or a salt thereof, and (c) less than 500 mg / 100 ml of sodium.
- the components (a) to (c) exhibit sweetness with a sweetness intensity of X2b, 1.0 ⁇ X1b ⁇ X2b, preferably 2.0 ⁇ X1b ⁇ X2b, and more preferably 4.0 ⁇ X1b ⁇ X2b.
- the concentrate according to one aspect of the present invention is a 5-fold concentrate of the fruit juice beverage of the present invention.
- A High-sweetness sweetener in an amount equivalent to sweetness intensity X1a
- B Amino acids or derivatives thereof or salts thereof, which are less than 5 times the taste recognition threshold. It contains (c) less than 250 mg / 100 ml of sodium and (d) a low sweetness sweetener in an amount equivalent to the sweetness intensity X4a.
- the components (a) to (d) exhibit sweetness with a sweetness intensity of X5a, 0.5 ⁇ X1a + X4a ⁇ X5a, preferably 1.0 ⁇ X1a + X4a ⁇ X5a, and more preferably 2.0 ⁇ X1a + X4a ⁇ X5a.
- the concentrate according to one aspect of the present invention is a 10-fold concentrate of the fruit juice beverage of the present invention.
- A High-sweetness sweetener in an amount equivalent to sweetness intensity X1a
- B Amino acids or derivatives thereof or salts thereof, which are less than 10 times the taste recognition threshold. It contains (c) less than 500 mg / 100 ml of sodium and (d) a low sweetness sweetener in an amount equivalent to the sweetness intensity X4a.
- the components (a) to (d) exhibit sweetness with a sweetness intensity of X5a, and 1.0 ⁇ X1a + X4a ⁇ X5a, preferably 2.0 ⁇ X1a + X4a ⁇ X5a, and more preferably 4.0 ⁇ X1a + X4a ⁇ X5a.
- the word “about” exists in the range of ⁇ 25%, ⁇ 10%, ⁇ 5%, ⁇ 3%, ⁇ 2% or ⁇ 1% of the numerical value following "about” by the subject. Means that. For example, “about 10” means the range of 7.5 to 12.5. As used herein, “mM” means molar concentration and means 1 ⁇ 10 -3 mol / L.
- amino acid measurement method For 17 amino acids such as arginine, lysine, histidine, phenylalanine, tyrosine, leucine, isoleucine, valine, alanine, glycine, proline, glutamic acid, serine, threonine, aspartic acid, cystine and methionine, a 10% sulfothalicylic acid solution was added to the sample. Add and extract, then add 3 mol / l sodium hydroxide solution to adjust pH to 2.2, then add sodium citrate buffer (pH 2.2) to constant volume, filter and then Dilute appropriately to prepare the test solution.
- sodium citrate buffer pH 2.2
- the test solution can be measured under the following two conditions depending on the dilution ratio and the type of amino acid to be measured.
- Condition 1 L-8900 high-speed amino acid analyzer (manufactured by Hitachi High-Technologies Corporation) Column: Hitachi custom ion exchange resin, ⁇ 4.6mm ⁇ 60mm (Made by Hitachi High-Technologies Corporation)
- Mobile phase Buffer solution for biofluid analysis method PF KANTO (PF-1 to PF-4) (Kanto Chemical Co., Inc.)
- Reaction solution Ninhydrin coloring solution kit for Hitachi (Fuji Film Wako Pure Chemical Industries, Ltd.)
- Flow rate mobile phase 0.35 ml / min, reaction solution 0.30 ml / min
- Measurement wavelength 570nm (16 types excluding proline), 440nm (proline)
- Condition 2 Model: JLC-500 / V2 (manufactured by JEOL Ltd.) Column: LCR-6, ⁇ 4mm ⁇ 120mm (manufacture
- the measurement conditions are as follows. Detector: Fluorescence spectrophotometer RF-20A XS (manufactured by Shimadzu Corporation) Column: CAPCELL PAK C18 AQ, ⁇ 4.6mm ⁇ 250mm (manufactured by Osaka Soda Co., Ltd.) Mobile phase: 20 mmol / l mixed solution of perchloric acid and methanol (80:20) Flow rate: 0.7 ml / min Fluorescence excitation wavelength: 285 nm Fluorescence measurement wavelength: 348nm Column temperature: 40 ° C
- Natural sugar ⁇ sucrose manufactured by Pacific Sugar Manufacturing Co., Ltd.
- glucose manufactured by Showa Sangyo Co., Ltd.
- RebD rebaugioside D
- sodium gluconate purity
- Examples A1 and B1 are control samples to which neither alanine nor sodium is added.
- the sodium content in the base beverage was measured by atomic absorption spectroscopy using SpectrAA240FS (manufactured by Agilent Technologies).
- SpectrAA240FS manufactured by Agilent Technologies.
- the above "0 mg / 100 ml” means that it is less than 1.0 mg / 100 g, which is the lower limit of quantification.
- Amino acids (arginine, lysine, histidine, phenylalanine, tyrosine, leucine, isoleucine, valine, alanine) contained in the cassis diluted fruit juice (fruit juice ratio: 6%) used as the base of the beverage and the orange diluted fruit juice (fruit juice ratio: 12%).
- Glycin, proline, glutamic acid, serine, threonine, aspartic acid, cystine, methionine and tryptophan The content of amino acids contained in the concentrated fruit juice before dilution is determined by an automatic amino acid analysis method using a known method (for tryptophan).
- the content of the above 18 kinds of amino acids contained in the diluted cassis juice was less than 1.0 mg / 100 g.
- the content of the above 18 kinds of amino acids contained in orange diluted fruit juice (fruit juice ratio: 12%) is about 9.0 mg / 100 g for arginine, about 1.7 mg / 100 g for alanine, about 15.7 mg / 100 g for proline, and glutamic acid. All were less than 1.0 mg / 100 g, except for about 2.4 mg / 100 g, serine about 2.9 mg / 100 g, and aspartic acid about 6.0 mg / 100 g.
- the sodium content in the beverage in Tables 6 and 7 was measured by the atomic absorption method using SpectrAA240FS (manufactured by Azilent Technology), and the alanine content was measured by the automatic amino acid analysis method under the above-mentioned conditions.
- the energy (kcal / 100 ml) was calculated with 0 (kcal / 100 ml) as the energy of the components derived from acidulant, vitamin C, pigment, RebD and sodium.
- Brix soluble solid content
- the sweetness intensities of the orange-diluted fruit juice and the cassis-diluted fruit juice used in the examples were scored on the VAS scale, and the sweetness intensities of each were calculated.
- the cassis diluted juice was compared with Brix 0.5, 1.0 and 1.5 sucrose solutions (0.5, 1.0 and 1.5 w / v%, respectively), and the orange diluted juice was Brix 1. It was compared with 5, 2.0 and 2.5 sucrose solutions (1.5, 2.0 and 2.5 w / v%, respectively).
- Those who were trained in sensuality (4 people) acted as panelists and conducted the evaluation. The results are shown in Table 8.
- the taste qualities that are sensory evaluation items are "total sweetness”, “reduction of sweetness aftertaste”, “body, thickness”, “flavor strength”, “reduction of miscellaneous taste (bitterness, astringency, etc.)” and “ Regarding "salty taste", those who were trained in sensory (4 people) acted as panelists and verified.
- sterilization was performed as appropriate prior to the sensory evaluation.
- the "sensory evaluation score" for each taste quality was calculated for each beverage sample based on the common taste quality judgment criteria prepared by each panelist through daily training.
- the “sensory evaluation score” is the control sample in the range of -3.0 to +3.0, with the degree of taste quality of Example A1 and Example B1 (control sample in each fruit juice beverage sample) as “0" (reference). It is a quantification of the difference in taste quality.
- the criteria for each item of the “sensory evaluation score” are as follows. (Sensory evaluation score) -"+3.0”: I feel that the target taste quality is very strong compared to the control sample. -"+2.0": I feel that the target taste quality is stronger than that of the control sample. -"+1.0”: I feel that the target taste quality is slightly stronger than that of the control sample. -"0": The target taste quality is the same as that of the control sample.
- Example 2 Evaluation of taste improvement effect by different amino acids or different amino acids and sodium Experimental method Similar to Example 1, natural sugar ⁇ sucrose (manufactured by Pacific Sugar Manufacturing Co., Ltd.), glucose (manufactured by Showa Sangyo Co., Ltd.) ⁇ , rebaugioside D (RebD) (purity 95) in the ratios shown in Tables 11 and 12 below.
- natural sugar ⁇ sucrose (manufactured by Pacific Sugar Manufacturing Co., Ltd.)
- glucose manufactured by Showa Sangyo Co., Ltd.
- RebD rebaugioside D
- the above "0 mg / 100 ml” means that it is less than 1.0 mg / 100 g, which is the lower limit of quantification.
- the sodium content in the beverage in Tables 11 and 12 was measured by the atomic absorption method using SpectrAA240FS (manufactured by Azilent Technology), and the contents of serine and glycine were measured by the automatic amino acid analysis method under the above-mentioned conditions.
- the energy (kcal / 100 ml) was calculated by setting the energy of the components derived from acidulant, vitamin C, pigment, RebD and sodium to 0 (kcal / 100 ml).
- Brix soluble solid content
- the taste improving effect of serine or glycine or serine or glycine and sodium was verified.
- the taste quality as a sensory evaluation item is "total sweetness”, “reduction of sweetness aftertaste”, “body, thickness”, “flavor strength”, and “miscellaneous taste (bitterness, astringency)”. Regarding “taste, etc.) reduction” and “salt taste”, those who were trained in sensory (4 people) acted as panelists and verified.
- sterilization was performed as appropriate.
- the "sensory evaluation score" for each taste quality was calculated for each beverage sample based on the common taste quality judgment criteria prepared by each panelist through daily training.
- Example 3 Evaluation of taste improvement effect at different fruit juice rates Experimental method Similar to Example 1, natural sugar ⁇ sucrose (manufactured by Pacific Sugar Manufacturing Co., Ltd.), glucose (manufactured by Showa Sangyo Co., Ltd.) ⁇ , rebaugioside D (RebD) (purity 95) at the ratios shown in Tables 15 and 16 below. % Or more), sodium gluconate (purity 98% or more) and DL-alanine (purity 98% or more) were dissolved in cassis diluted juice or orange diluted juice to prepare a beverage sample.
- natural sugar ⁇ sucrose (manufactured by Pacific Sugar Manufacturing Co., Ltd.), glucose (manufactured by Showa Sangyo Co., Ltd.) ⁇ , rebaugioside D (RebD) (purity 95) at the ratios shown in Tables 15 and 16 below. % Or more), sodium gluconate (purity 98% or more) and DL-alanine (purity 9
- cassis diluted fruit juice (fruit juice ratio: 30%, sodium content: 2.5 (mg / 100 ml), energy: 13.5 (kcal / 100 ml) and fruit juice ratio: 50%, sodium content: 3.9 (mg / 100 ml) ), Energy: 22.6 (kcal / 100ml)) was used.
- orange diluted fruit juice (juice ratio: 30%, sodium content: 0 (mg / 100 ml), energy: 16.0 (kcal / 100 ml) and fruit juice ratio: 50%, sodium content: 1.11 (mg / 100 ml), energy: 26.1 (kcal / 100ml)) was used.
- Acidulants, vitamin C and pigments were also added to the cassis diluted juice.
- Examples E1 and E4 and F1 and F4 are control samples to which neither alanine nor sodium is added.
- the sodium content in the base beverage was measured by atomic absorption spectroscopy using SpectrAA240FS (manufactured by Agilent Technologies).
- the above "0 mg / 100 ml” means that it is less than 1.0 mg / 100 g, which is the lower limit of quantification.
- Amino acids contained in the cassis diluted fruit juice (fruit juice ratio: 30% and 50%) used as the base of the beverage and the orange diluted fruit juice (fruit juice ratio: 30% and 50%).
- Isoleucine, valine, alanine, glycine, proline, glutamic acid, serine, threonine, aspartic acid, cystine, methionine and tryptophan It was measured by an analytical institution using an analytical method (high-speed liquid chromatography for tryptophan), and calculated based on the measured values.
- the content of the above 18 kinds of amino acids contained in the diluted cassis juice was less than 1.0 mg / 100 g.
- the contents of the above 18 kinds of amino acids contained in the diluted cassis juice were about 1.3 mg / 100 g for alanine, about 1.2 mg / 100 g for proline, and about 1.3 mg / 100 g for glutamic acid. Other than that, all were less than 1.0 mg / 100 g.
- the content of the above 18 kinds of amino acids contained in orange diluted fruit juice is about 22.7 mg / 100 g for arginine, about 1.0 mg / 100 g for lysine, about 1.0 mg / 100 g for phenylalanine, and about alanine.
- juice ratio 30%
- the content of the above 18 kinds of amino acids contained in orange diluted fruit juice is about 37.5 mg / 100 g for arginine, about 1.7 mg / 100 g for lysine, about 1.6 mg / 100 g for phenylalanine, and valine.
- the sodium content in the beverage in Tables 15 and 16 was measured by the atomic absorption method using SpectrAA240FS (manufactured by Azilent Technology), and the alanine content was analyzed by the automatic amino acid analysis method under the above-mentioned conditions.
- the energy (kcal / 100 ml) was measured by an institution, and the energy of the components derived from acidulant, vitamin C, pigment, RebD and sodium was calculated as 0 (kcal / 100 ml).
- Brix soluble solid content
- the taste quality as a sensory evaluation item is "total sweetness”, “reduction of sweetness aftertaste”, “body, thickness”, “flavor strength”, and “miscellaneous taste (bitterness, astringency)”. Regarding “taste, etc.) reduction” and “salt taste”, those who were trained in sensory (4 people) acted as panelists and verified. In addition, prior to the sensory evaluation, sterilization was performed as appropriate. First, the "sensory evaluation score" for each taste quality was calculated for each beverage sample based on the common taste quality judgment criteria prepared by each panelist through daily training.
- Example 4 Evaluation of taste improvement effect with various sweeteners Experimental method Similar to Example 1, natural sugar ⁇ sucrose (manufactured by Pacific Sugar Co., Ltd.), glucose (manufactured by Showa Sangyo Co., Ltd.) ⁇ , rebaugioside D (RebD) (purity 95) at the ratios shown in Tables 19 to 21 below.
- Rebaugioside A (purity 99% or more), Rebaugioside M (RebM) (purity 98%), Mogroside V (MogV) (purity 97.7%), Luo Han Guo extract (40% by weight mogroside V) Luo Han Guo fruit water extract), mogroside (purity 98% or more), and DL-alanine (purity 98% or more) were added to the same orange-diluted fruit juice as in Example 1 (fruit juice ratio: 12%, sodium content: 0). Beverage samples were prepared by dissolving in (mg / 100 ml), energy: 5.28 (kcal / 100 ml)).
- Examples G1, H1, I1, J1, K1 and L1 are control samples to which neither amino acids nor sodium have been added.
- the sodium content in the beverages in Tables 19 to 21 was calculated from the amount of sodium gluconate added.
- the free alanine content was calculated from the amount of alanine added. Since the free alanine content of the base fruit juice beverage was near the lower limit of measurement (1.0 mg / 100 g), the amount of free alanine contained in the base fruit juice beverage was calculated as zero in this example. ..
- the energy (kcal / 100 ml) was calculated assuming that the energy of the high-sweetness sweetener and the sodium-derived component was 0 (kcal / 100 ml).
- Brix soluble solid content
- the taste improving effect of alanine or alanine and sodium was verified.
- the taste quality as a sensory evaluation item is "total sweetness”, “reduction of sweetness aftertaste”, “body, thickness”, “flavor strength”, and “miscellaneous taste (bitterness, astringency)”. Regarding “taste, etc.) reduction” and “salt taste”, those who were trained in sensory (4 people) acted as panelists and verified.
- the "sensory evaluation score" for each taste quality was calculated for each beverage sample based on the common taste quality judgment criteria prepared by each panelist through daily training.
- Example 5 Effect in a beverage containing only a high-sweetness sweetener Experimental method Similar to Example 1, rebaugioside D (RebD) (purity 95% or higher), sodium gluconate (purity 98% or higher), and DL-alanine (purity 98% or higher) at the ratios shown in Table 25 below. ) was dissolved in the same orange diluted fruit juice as in Example 1 (fruit juice ratio: 12%, sodium content: 0 (mg / 100 ml), energy: 5.28 (kcal / 100 ml)) to prepare a beverage sample.
- Example M1 is a control sample to which neither amino acid nor sodium is added. The sodium content in the beverage in Table 25 was calculated from the amount of sodium gluconate added.
- the free alanine content was calculated from the amount of alanine added. Since the free alanine content of the base fruit juice beverage was near the lower limit of measurement (1.0 mg / 100 g), the amount of free alanine contained in the base fruit juice beverage was calculated as zero in this example. ..
- the energy (kcal / 100 ml) was calculated assuming that the energy of the high-sweetness sweetener and the sodium-derived component was 0 (kcal / 100 ml).
- Brix soluble solid content
- the taste improving effect of alanine or alanine and sodium was verified.
- the taste quality as a sensory evaluation item is "total sweetness”, “reduction of sweetness aftertaste”, “body, thickness”, “flavor strength”, and “miscellaneous taste (bitterness, astringency)”. Regarding “taste, etc.) reduction” and “salt taste”, those who were trained in sensory (4 people) acted as panelists and verified.
- the "sensory evaluation score" for each taste quality was calculated for each beverage sample based on the common taste quality judgment criteria prepared by each panelist through daily training.
- Example 6 Effect on beverages having different sweetness intensities Experimental method Similar to Example 1, natural sugar ⁇ sucrose (manufactured by Pacific Sugar Manufacturing Co., Ltd.), glucose (manufactured by Showa Sangyo Co., Ltd.) ⁇ , rebaugioside D (RebD) (purity 95% or more) in the ratio shown in Table 27 below. ), Sodium gluconate (purity 98% or more), and DL-alanine (purity 98% or more) in the same orange-diluted fruit juice as in Example 1 (juice ratio: 12%, sodium content: 0 (mg / 100 ml), Energy: 5.28 (kcal / 100 ml)) was dissolved to prepare a beverage sample.
- natural sugar ⁇ sucrose (manufactured by Pacific Sugar Manufacturing Co., Ltd.), glucose (manufactured by Showa Sangyo Co., Ltd.) ⁇ , rebaugioside D (RebD) (purity 95% or more) in the ratio shown in Table
- Examples N1 and O1 are control samples to which neither amino acids nor sodium have been added.
- the sodium content in the beverage in Table 27 was calculated from the amount of sodium gluconate added.
- the free alanine content was calculated from the amount of alanine added. Since the free alanine content of the base fruit juice beverage was near the lower limit of measurement (1.0 mg / 100 g), the amount of free alanine contained in the base fruit juice beverage was calculated as zero in this example. ..
- the energy (kcal / 100 ml) was calculated assuming that the energy of the high-sweetness sweetener and the sodium-derived component was 0 (kcal / 100 ml).
- Brix (soluble solid content) was calculated by determining the refractive index of the sample with a digital refractometer manufactured by Atago Co., Ltd. and converting it into the weight% of the sucrose solution corresponding to this value.
- the total sweetness intensity (X1 + X4) of the high-sweetness sweetener and the low-sweetness sweetener contained in the samples of Examples N1 to 3 (low sweetness intensity) is 5.608, and is used in the samples of Examples O1 to 3 (high sweetness intensity).
- the total sweetness intensity (X1 + X4) of the high-sweetness sweetener and the low-sweetness sweetener contained was 17.540.
- the taste improving effect of alanine or alanine and sodium was verified.
- the taste quality as a sensory evaluation item is "total sweetness”, “reduction of sweetness aftertaste”, “body, thickness”, “flavor strength”, and “miscellaneous taste (bitterness, astringency)”. Regarding “taste, etc.) reduction” and “salt taste”, those who were trained in sensory (4 people) acted as panelists and verified.
- the "sensory evaluation score" for each taste quality was calculated for each beverage sample based on the common taste quality judgment criteria prepared by each panelist through daily training.
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Abstract
Description
しかしながら、低カロリー食品にするためには糖濃度を低く抑える必要があり、この点が低カロリーかつ良好な味覚を呈する食品を提供する際の障害となっている。
[1]
(a)甘味強度X1相当の量の高甘味度甘味料、および
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩
を含み、
前記成分(a)および(b)により甘味強度X3の甘味を呈し、0.1<X1<X3である、果汁飲料。
[2]
(a)甘味強度X1相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、および
(c)50mg/100ml未満のナトリウム
を含み、
前記成分(a)~(c)により甘味強度X2の甘味を呈し、0.1<X1<X2である、果汁飲料。
[3]
低甘味度甘味料をさらに含む、[1]または[2]に記載の果汁飲料。
[4]
前記アミノ酸が、塩基性アミノ酸および側鎖にアルキル基、OH基またはアミド基を有する中性アミノ酸ならびにその組合せから選択されるアミノ酸を含む、[1]~[3]のいずれかに記載の果汁飲料。
[5]
前記アミノ酸が、分子量70~260のアミノ酸から選択される1種以上である、[1]~[4]のいずれかに記載の果汁飲料。
[6]
前記アミノ酸が、グリシン、アラニン、バリン、イソロイシン、ロイシン、セリン、スレオニン、グルタミン、アスパラギン、アルギニン、リジン、ヒスチジンおよびその組合せから選択されるアミノ酸を含む、[1]~[5]のいずれかに記載の果汁飲料。
[7]
エネルギーが50Kcal/100ml以下である、[1]~[6]のいずれかに記載の果汁飲料。
[8]
前記低甘味度甘味料の甘味強度が0.1~5.9である、[3]~[7]のいずれかに記載の果汁飲料。
[9]
前記果汁飲料の果汁率が1~100%、4~95%、5~80%、5~50%または5~30%である、[1]~[8]のいずれかに記載の果汁飲料。
[10]
前記果汁飲料に含まれる果汁が、オレンジ、ミカン、レモン、グレープフルーツ、ライム、パイナップル、イチゴ、ラズベリー、ブルーベリー、カシス、クランベリー、ブルーベリー、グァバ、バナナ、アセロラ、パパイヤ、パッションフルーツ、マンゴー、リンゴ、ブドウ、桃、梅、梨、アンズ、スモモ、メロン、キウイフルーツ、花梨およびその組合せから選択される1種以上である、[1]~[9]のいずれかに記載の果汁飲料。
[11]
前記低甘味度甘味料が、グルコース、スクロース、フルクトース、マルトース、オリゴ糖、異性化糖、乳糖、プシコース、アロース、タガトースおよびその組合せからなる群より選択される少なくとも1つを含む、[1]~[10]のいずれかに記載の果汁飲料。
[12]
前記高甘味度甘味料が、ステビオール配糖体、羅漢果抽出物、モグロール配糖体、Thaumataococcus daniellii Benth植物含有甘味成分、Pentadiplandra brazzeana植物含有甘味成分、人工甘味料およびその組合せからなる群より選択される少なくとも1つを含む、[1]~[11]のいずれかに記載の果汁飲料。
[13]
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドB、レバウジオシドC、レバウジオシドD、レバウジオシドE、レバウジオシドF、レバウジオシドI、レバウジオシドJ、レバウジオシドK、レバウジオシドM、レバウジオシドN、レバウジオシドO、レバウジオシドQ、レバウジオシドR、ズルコシドA、ズルコシドC、ルブソシド、ステビオールモノシド、ステビオールビオシド、ステビオシド、羅漢果抽出物、モグロシドV、ソーマチン、ブラゼイン、カンゾウ抽出物、サッカリン、アスパルテーム、アセスルファムK、スクラロース、およびその組合せからなる群より選択される少なくとも1つを含む、[1]~[12]のいずれかに記載の果汁飲料。
[14]
アラニン、セリンおよびグリシンから選択される1つ以上のアミノ酸を含み、エネルギーが50Kcal/100ml以下、かつ前記高甘味度甘味料と前記低甘味度甘味料の甘味強度の合計が6以上である、[3]~[13」のいずれかに記載の果汁飲料。
[15]
容器詰めされている、[1]~[14]のいずれかに記載の果汁飲料。
[16]
原材料に対し、
(a)甘味強度X1の量の高甘味度甘味料を添加すること、および
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩を添加することを含む、[1]および[3]~[15]のいずれかに記載の果汁飲料を製造する方法。
[17]
原材料に対し、
(a)甘味強度X1の量の高甘味度甘味料を添加すること、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩を添加すること、
および
(c)飲料中のナトリウム含有量が50mg/100ml未満となるようにナトリウムを添加すること、
を含む、[2]~[16]のいずれかに記載の果汁飲料を製造する方法。
[18]
(a)甘味強度X1a相当の量の高甘味度甘味料、および
(b)味覚認知閾値の10倍未満のアミノ酸またはその誘導体もしくはその塩
を含む、[1]および[3]~[15]のいずれかに記載の果汁飲料を提供するための濃縮物。
[19]
(a)甘味強度X1a相当の量の高甘味度甘味料、
(b)味覚認知閾値の10倍未満のアミノ酸またはその誘導体もしくはその塩、および
(c)500mg/100ml未満のナトリウム
を含む、[2]~[18]のいずれかに記載の果汁飲料を提供するための濃縮物。
(a)甘味強度Xa相当の量の高甘味度甘味料、および
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩
を含み、
前記成分(a)および(b)により甘味強度Xbの甘味を呈し、0.1<Xa<Xbである、果汁飲料。
[A2]
低甘味度甘味料をさらに含む、[A1]に記載の果汁飲料。
[A3]
前記アミノ酸が、塩基性アミノ酸および側鎖にアルキル基、OH基またはアミド基を有する中性アミノ酸ならびにその組合せから選択されるアミノ酸を含む、[A1]または[A2]に記載の果汁飲料。
[A4]
前記アミノ酸が、分子量70~260のアミノ酸から選択される1種以上である、[A1]~[A3]のいずれかに記載の果汁飲料。
[A5]
前記アミノ酸が、グリシン、アラニン、バリン、イソロイシン、ロイシン、セリン、スレオニン、グルタミン、アスパラギン、アルギニン、リジン、ヒスチジンおよびその組合せから選択されるアミノ酸を含む、[A1]~[A4]のいずれかに記載の果汁飲料。
[A6]
エネルギーが50Kcal/100ml以下である、[A1]~[A5]のいずれかに記載の果汁飲料。
[A7]
前記低甘味度甘味料の甘味強度が0.1~5.9である、[A2]~[A6]のいずれかに記載の果汁飲料。
[A8]
前記果汁飲料の果汁率が1~100%、4~95%、5~80%、5~50%または5~30%である、[A1]~[A7]のいずれかに記載の果汁飲料。
[A9]
前記果汁飲料に含まれる果汁が、オレンジ、ミカン、レモン、グレープフルーツ、ライム、パイナップル、イチゴ、ラズベリー、ブルーベリー、カシス、クランベリー、ブルーベリー、グァバ、バナナ、アセロラ、パパイヤ、パッションフルーツ、マンゴー、リンゴ、ブドウ、桃、梅、梨、アンズ、スモモ、メロン、キウイフルーツ、花梨およびその組合せから選択される1種以上である、[A1]~[A8]のいずれかに記載の果汁飲料。
[A10]
前記低甘味度甘味料が、グルコース、スクロース、フルクトース、マルトース、オリゴ糖、異性化糖、乳糖、プシコース、アロース、タガトースおよびその組合せからなる群より選択される少なくとも1つを含む、[A1]~[A9]のいずれかに記載の果汁飲料。
[A11]
前記高甘味度甘味料が、ステビオール配糖体、羅漢果抽出物、モグロール配糖体、Thaumataococcus daniellii Benth植物含有甘味成分、Pentadiplandra brazzeana植物含有甘味成分、人工甘味料およびその組合せからなる群より選択される少なくとも1つを含む、[A1]~[A10]のいずれかに記載の果汁飲料。
[A12]
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドB、レバウジオシドC、レバウジオシドD、レバウジオシドE、レバウジオシドF、レバウジオシドI、レバウジオシドJ、レバウジオシドK、レバウジオシドM、レバウジオシドN、レバウジオシドO、レバウジオシドQ、レバウジオシドR、ズルコシドA、ズルコシドC、ルブソシド、ステビオールモノシド、ステビオールビオシド、ステビオシド、羅漢果抽出物、モグロシドV、ソーマチン、ブラゼイン、カンゾウ抽出物、サッカリン、アスパルテーム、アセスルファムK、スクラロース、およびその組合せからなる群より選択される少なくとも1つを含む、[A1]~[A11]のいずれかに記載の果汁飲料。
[A13]
アラニン、セリンおよびグリシンから選択される1つ以上のアミノ酸を含み、エネルギーが50Kcal/100ml以下、かつ前記高甘味度甘味料と前記低甘味度甘味料の甘味強度の合計が6以上である、[A2]~[A12]のいずれかに記載の果汁飲料。
[A14]
容器詰めされている、[A1]~[A13]のいずれかに記載の果汁飲料。
[A15]
原材料に対し、
(a)甘味強度Xaの量の高甘味度甘味料を添加すること、および
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩を添加することを含む、[A1]~[A14]のいずれかに記載の果汁飲料を製造する方法。
[A16]
(a)甘味強度Xaa相当の量の高甘味度甘味料、および
(b)味覚認知閾値の10倍未満のアミノ酸またはその誘導体もしくはその塩
を含む、[A1]~[A15]のいずれかに記載の果汁飲料を提供するための濃縮物。
[A17]
果汁飲料に
(a)甘味強度Xa相当の量の高甘味度甘味料、および
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩
を含有させことを特徴とする、果汁飲料の甘味強度を増強する方法。
[A18]
(a)甘味強度Xa相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、および
(c)甘味強度Xc相当の量の低甘味度甘味料
を含み、
前記成分(a)~(c)により甘味強度Xdの甘味を呈し、0.1<Xa+Xc<Xdである、果汁飲料。
[A19]
前記アミノ酸が、塩基性アミノ酸および側鎖にアルキル基、OH基またはアミド基を有する中性アミノ酸ならびにその組合せから選択されるアミノ酸を含む、[A18]に記載の果汁飲料。
[A20]
前記アミノ酸が、分子量70~260のアミノ酸から選択される1種以上である、[A18]または[A19]に記載の果汁飲料。
[A21]
前記アミノ酸が、グリシン、アラニン、バリン、イソロイシン、ロイシン、セリン、スレオニン、グルタミン、アスパラギン、アルギニン、リジン、ヒスチジンおよびその組合せから選択されるアミノ酸を含む、[A18]~[A20]のいずれかに記載の果汁飲料。
[A22]
エネルギーが50Kcal/100ml以下である、[A18]~[A21]のいずれかに記載の果汁飲料。
[A23]
Xcが0.1~5.9である、[A18]~[A22]のいずれかに記載の果汁飲料。
[A24]
前記果汁飲料の果汁率が1~100%、4~95%、5~80%、5~50%または5~30%である、[A18]~[A23]のいずれかに記載の果汁飲料。
[A25]
前記果汁飲料に含まれる果汁が、オレンジ、ミカン、レモン、グレープフルーツ、ライム、パイナップル、イチゴ、ラズベリー、ブルーベリー、カシス、クランベリー、ブルーベリー、グァバ、バナナ、アセロラ、パパイヤ、パッションフルーツ、マンゴー、リンゴ、ブドウ、桃、梅、梨、アンズ、スモモ、メロン、キウイフルーツ、花梨およびその組合せから選択される1種以上である、[A18]~[A24]のいずれかに記載の果汁飲料。
[A26]
前記低甘味度甘味料が、グルコース、スクロース、フルクトース、マルトース、オリゴ糖、異性化糖、乳糖、プシコース、アロース、タガトースおよびその組合せからなる群より選択される少なくとも1つを含む、[A18]~[A25]のいずれかに記載の果汁飲料。
[A27]
前記高甘味度甘味料が、ステビオール配糖体、羅漢果抽出物、モグロール配糖体、Thaumataococcus daniellii Benth植物含有甘味成分、Pentadiplandra brazzeana植物含有甘味成分、人工甘味料およびその組合せからなる群より選択される少なくとも1つを含む、[A18]~[A26]のいずれかに記載の果汁飲料。
[A28]
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドB、レバウジオシドC、レバウジオシドD、レバウジオシドE、レバウジオシドF、レバウジオシドI、レバウジオシドJ、レバウジオシドK、レバウジオシドM、レバウジオシドN、レバウジオシドO、レバウジオシドQ、レバウジオシドR、ズルコシドA、ズルコシドC、ルブソシド、ステビオールモノシド、ステビオールビオシド、ステビオシド、羅漢果抽出物、モグロシドV、ソーマチン、ブラゼイン、カンゾウ抽出物、サッカリン、アスパルテーム、アセスルファムK、スクラロース、およびその組合せからなる群より選択される少なくとも1つを含む、[A18]~[A27]のいずれかに記載の果汁飲料。
[A29]
アラニン、セリンおよびグリシンから選択される1つ以上のアミノ酸を含み、エネルギーが50Kcal/100ml以下、かつXa+Xcが6以上である、[A18]~[A28]のいずれかに記載の果汁飲料。
[A30]
容器詰めされている、[A18]~[A29]のいずれかに記載の果汁飲料。
[A31]
原材料に対し、
(a)甘味強度Xaの量の高甘味度甘味料を添加すること、および
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩を添加することを含む、[A18]~[A30]のいずれかに記載の果汁飲料を製造する方法。
[A32]
(a)甘味強度Xaa相当の量の高甘味度甘味料、および
(b)味覚認知閾値の10倍未満のアミノ酸またはその誘導体もしくはその塩
を含む、[A18]~[A31]のいずれかに記載の果汁飲料を提供するための濃縮物。
(a)甘味強度X1相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、および
(c)50mg/100ml未満のナトリウム
を含み、
前記成分(a)~(c)により甘味強度X2の甘味を呈し、0.1<X1<X2である、果汁飲料。
[B2]
前記成分(a)および(b)により甘味強度X3の甘味を呈し、0.1<X1<X3<X2である、[B1]に記載の果汁飲料。
[B3]
低甘味度甘味料をさらに含む、[B1]または[B2]に記載の果汁飲料。
[B4]
前記アミノ酸が、塩基性アミノ酸および側鎖にアルキル基、OH基またはアミド基を有する中性アミノ酸ならびにその組合せから選択されるアミノ酸を含む、[B1]~[B3]のいずれかに記載の果汁飲料。
[B5]
前記アミノ酸が、分子量70~260のアミノ酸から選択される1種以上である、[B1]~[B4]のいずれかに記載の果汁飲料。
[B6]
前記アミノ酸が、グリシン、アラニン、バリン、イソロイシン、ロイシン、セリン、スレオニン、グルタミン、アスパラギン、アルギニン、リジン、ヒスチジンおよびその組合せから選択されるアミノ酸を含む、[B1]~[B5]のいずれかに記載の果汁飲料。
[B7]
ナトリウムの含有量が1~25mg/100mlである、[B1]~[B6]のいずれかに記載の果汁飲料。
[B8]
エネルギーが50Kcal/100ml以下である、[B1]~[B7]のいずれかに記載の果汁飲料。
[B9]
前記低甘味度甘味料の甘味強度が0.1~5.9である、[B3]~[B8]のいずれかに記載の果汁飲料。
[B10]
前記果汁飲料の果汁率が1~100%、4~95%、5~80%、5~50%または5~30%である、[B1]~[B9]のいずれかに記載の果汁飲料。
[B11]
前記果汁飲料に含まれる果汁が、オレンジ、ミカン、レモン、グレープフルーツ、ライム、パイナップル、イチゴ、ラズベリー、ブルーベリー、カシス、クランベリー、ブルーベリー、グァバ、バナナ、アセロラ、パパイヤ、パッションフルーツ、マンゴー、リンゴ、ブドウ、桃、梅、梨、アンズ、スモモ、メロン、キウイフルーツ、花梨およびその組合せから選択される1種以上である、[B1]~[B10]のいずれかに記載の果汁飲料。
[B12]
前記低甘味度甘味料が、グルコース、スクロース、フルクトース、マルトース、オリゴ糖、異性化糖、乳糖、プシコース、アロース、タガトースおよびその組合せからなる群より選択される少なくとも1つを含む、[B1]~[B11]のいずれかに記載の果汁飲料。
[B13]
前記高甘味度甘味料が、ステビオール配糖体、羅漢果抽出物、モグロール配糖体、Thaumataococcus daniellii Benth植物含有甘味成分、Pentadiplandra brazzeana植物含有甘味成分、人工甘味料およびその組合せからなる群より選択される少なくとも1つを含む、[B1]~[B12]のいずれかに記載の果汁飲料。
[B14]
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドB、レバウジオシドC、レバウジオシドD、レバウジオシドE、レバウジオシドF、レバウジオシドI、レバウジオシドJ、レバウジオシドK、レバウジオシドM、レバウジオシドN、レバウジオシドO、レバウジオシドQ、レバウジオシドR、ズルコシドA、ズルコシドC、ルブソシド、ステビオールモノシド、ステビオールビオシド、ステビオシド、羅漢果抽出物、モグロシドV、ソーマチン、ブラゼイン、カンゾウ抽出物、サッカリン、アスパルテーム、アセスルファムK、スクラロース、およびその組合せからなる群より選択される少なくとも1つを含む、[B1]~[B13]のいずれかに記載の果汁飲料。
[B15]
前記ナトリウムが、塩化ナトリウム、水酸化ナトリウム、リンゴ酸ナトリウム、硫酸ナトリウム、クエン酸ナトリウム、リン酸ナトリウム、炭酸ナトリウム、二硫化ナトリウム、重炭酸ナトリウム、アルギン酸ナトリウム、アルギニン酸ナトリウム、グルコヘプタン酸ナトリウム、グルコン酸ナトリウム、グルタミン酸ナトリウム、酒石酸ナトリウム、アスパラギン酸ナトリウム、乳酸ナトリウム、カゼインナトリウム、アスコルビン酸ナトリウムおよびその混合物からなる群より選択される少なくとも1つの形態で含まれている、[B1]~[B14]のいずれかに記載の果汁飲料。
[B16]
アラニン、セリンおよびグリシンから選択される1つ以上のアミノ酸と、1~25mg/100mlのナトリウムを含み、エネルギーが50Kcal/100ml以下、かつ前記高甘味度甘味料と前記低甘味度甘味料の甘味強度の合計が6以上である、[B3]~[B15]のいずれかに記載の果汁飲料。
[B17]
容器詰めされている、[B1]~[B16]のいずれかに記載の果汁飲料。
[B18]
原材料に対し、
(a)甘味強度X1の量の高甘味度甘味料を添加すること、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩を添加すること、および
(c)飲料中のナトリウム含有量が50mg/100ml未満となるようにナトリウムを添加すること、
を含む、[B1]~[B17]のいずれかに記載の果汁飲料を製造する方法。
[B19]
(a)甘味強度X1a相当の量の高甘味度甘味料、
(b)味覚認知閾値の10倍未満のアミノ酸またはその誘導体もしくはその塩、および
(c)500mg/100ml未満のナトリウム
を含む、[B1]~[B18]のいずれかに記載の果汁飲料を提供するための濃縮物。
[B20]
果汁飲料に
(a)甘味強度X1相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、および
(c)50mg/100ml未満のナトリウム
を含有させることを特徴とする、果汁飲料の甘味強度を増強する方法。
[B21]
(a)甘味強度X1相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、
(c)50mg/100ml未満のナトリウム、および
(d)甘味強度X4相当の量の低甘味度甘味料
を含み、
前記成分(a)~(d)により甘味強度X5の甘味を呈し、0.1<X1+X4<X5である、果汁飲料。
[B22]
前記アミノ酸が、塩基性アミノ酸および側鎖にアルキル基、OH基またはアミド基を有する中性アミノ酸ならびにその組合せから選択されるアミノ酸を含む、[B21]に記載の果汁飲料。
[B23]
前記アミノ酸が、分子量70~260のアミノ酸から選択される1種以上である、[B21]または[B22]に記載の果汁飲料。
[B24]
前記アミノ酸が、グリシン、アラニン、バリン、イソロイシン、ロイシン、セリン、スレオニン、グルタミン、アスパラギン、アルギニン、リジン、ヒスチジンおよびその組合せから選択されるアミノ酸を含む、[B21]~[B23]のいずれかに記載の果汁飲料。
[B25]
ナトリウムの含有量が1~25mg/100mlである、[B21]~[B24]のいずれかに記載の果汁飲料。
[B26]
エネルギーが50Kcal/100ml以下である、[B21]~[B25]のいずれかに記載の果汁飲料。
[B27]
X4が0.1~5.9である、[B21]~[B26]のいずれかに記載の果汁飲料。
[B28]
前記果汁飲料の果汁率が1~100%、4~95%、5~80%、5~50%または5~30%である、[B21]~[B27]のいずれかに記載の果汁飲料。
[B29]
前記果汁飲料に含まれる果汁が、オレンジ、ミカン、レモン、グレープフルーツ、ライム、パイナップル、イチゴ、ラズベリー、ブルーベリー、カシス、クランベリー、ブルーベリー、グァバ、バナナ、アセロラ、パパイヤ、パッションフルーツ、マンゴー、リンゴ、ブドウ、桃、梅、梨、アンズ、スモモ、メロン、キウイフルーツ、花梨およびその組合せから選択される1種以上である、[B21]~[B28]のいずれかに記載の果汁飲料。
[B30]
前記低甘味度甘味料が、グルコース、スクロース、フルクトース、マルトース、オリゴ糖、異性化糖、乳糖、プシコース、アロース、タガトースおよびその組合せからなる群より選択される少なくとも1つを含む、[B21]~[B29]のいずれかに記載の果汁飲料。
[B31]
前記高甘味度甘味料が、ステビオール配糖体、羅漢果抽出物、モグロール配糖体、Thaumataococcus daniellii Benth植物含有甘味成分、Pentadiplandra brazzeana植物含有甘味成分、人工甘味料およびその組合せからなる群より選択される少なくとも1つを含む、[B21]~[B30]のいずれかに記載の果汁飲料。
[B32]
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドB、レバウジオシドC、レバウジオシドD、レバウジオシドE、レバウジオシドF、レバウジオシドI、レバウジオシドJ、レバウジオシドK、レバウジオシドM、レバウジオシドN、レバウジオシドO、レバウジオシドQ、レバウジオシドR、ズルコシドA、ズルコシドC、ルブソシド、ステビオールモノシド、ステビオールビオシド、ステビオシド、羅漢果抽出物、モグロシドV、ソーマチン、ブラゼイン、カンゾウ抽出物、サッカリン、アスパルテーム、アセスルファムK、スクラロース、およびその組合せからなる群より選択される少なくとも1つを含む、[B21]~[B31]のいずれかに記載の果汁飲料。
[B33]
前記ナトリウムが、塩化ナトリウム、水酸化ナトリウム、リンゴ酸ナトリウム、硫酸ナトリウム、クエン酸ナトリウム、リン酸ナトリウム、炭酸ナトリウム、二硫化ナトリウム、重炭酸ナトリウム、アルギン酸ナトリウム、アルギニン酸ナトリウム、グルコヘプタン酸ナトリウム、グルコン酸ナトリウム、グルタミン酸ナトリウム、酒石酸ナトリウム、アスパラギン酸ナトリウム、乳酸ナトリウム、カゼインナトリウム、アスコルビン酸ナトリウムおよびその混合物からなる群より選択される少なくとも1つの形態で含まれている、[B21]~[B32]のいずれかに記載の果汁飲料。
[B34]
アラニン、セリンおよびグリシンから選択される1つ以上のアミノ酸と、1~25mg/100mlのナトリウムを含み、エネルギーが50Kcal/100ml以下、かつX1+X4が6以上である、[B21]~[B33]のいずれかに記載の果汁飲料。
[B35]
容器詰めされている、[B21]~[B34]のいずれかに記載の果汁飲料。
[B36]
原材料に対し、
(a)甘味強度X1の量の高甘味度甘味料を添加すること、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩を添加すること、および
(c)飲料中のナトリウム含有量が50mg/100ml未満となるようにナトリウムを添加すること、
を含む、[B21]~[B35]のいずれかに記載の果汁飲料を製造する方法。
[B37]
(a)甘味強度X1a相当の量の高甘味度甘味料、
(b)味覚認知閾値の10倍未満のアミノ酸またはその誘導体もしくはその塩、および
(c)500mg/100ml未満のナトリウム
を含む、[B21]~[B36]のいずれかに記載の果汁飲料を提供するための濃縮物。
なお、本明細書において引用した全ての文献、および公開公報、特許公報その他の特許文献は、参照として本明細書に組み込むものとする。また、本明細書は、2020年9月2日に出願された本願優先権主張の基礎となる日本国特許出願(特願2020-147833号および特願2020-147848号)ならびに2020年11月5日に出願された本願優先権主張の基礎となる日本国特許出願(特願2020-185333号および特願2020-185335号)の明細書及び図面に記載の内容を包含する。
本明細書において、例えば、「A成分の含有量がXmg/100mlである」との記載は、「飲料100mlに対して、A成分がXmg含まれている」ことを意味する。飲料の比重は凡そ1であるため、飲料において、「mg/100g」は「mg/100ml」と同視し得る。また、例えば、「B成分の含有量がYppmである」との記載は、「飲料の全量(100質量%)に対して、B成分がYppm含まれている」ことを意味する。
《第1および第A1の態様》
本発明は、第1の態様として、以下の果汁飲料(以下、「本発明の果汁飲料」という)を提供する。
(a)甘味強度X1相当の量の高甘味度甘味料、および
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩
を含み、
前記成分(a)および(b)により甘味強度X3の甘味を呈し、0.1<X1<X3である、果汁飲料。本態様において、X1とX3はそれぞれ第A1の態様(特願2020-147848/2020-185335号に対応)のXaおよびXbに相当する。
(a)甘味強度Xa相当の量の高甘味度甘味料、および
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩
を含み、
前記成分(a)および(b)により甘味強度Xbの甘味を呈し、0.1<Xa<Xbである、果汁飲料。
本発明において「果汁飲料」とは、果実の搾汁である果汁を含む飲料を意味する。
具体的な「果汁飲料」としては、2018年に施行された「果実飲料等の表示に関する公正競争規約」の定義にある「果実飲料」や、2016年に施行された「果実飲料等の表示に関する公正競争規約施行規則」の定義である「果実ジュース」「果実ミックスジュース」「果粒入り果実ジュース」「果実・野菜ミックスジュース」「果汁入り飲料」「果汁入りゼリー飲料」が挙げられる。
なお、上記の規約では「その他の飲料」に分類される果汁の使用割合が10%未満の飲料についても、果汁を含む飲料であれば、本発明でいう「果汁飲料」に含まれる。本発明の果汁飲料は「果汁含有飲料」とも称される。
なお、濃縮果汁は、加熱濃縮法および冷凍濃縮法のいずれによって調製されたものであってもよい。
代表的な果実の糖用屈折計示度の基準(単位:°Bx)の値としては、オレンジ:11、ミカン:9、グレープフルーツ:9、パイナップル:11、クランベリー:7、ブルーベリー、グァバ:8、バナナ:23、パパイヤ:9、パッションフルーツ:14、マンゴー:13、リンゴ:10、ブドウ:11、桃:8、日本梨:8、西洋梨:11、アンズ:7、スモモ:6、メロン、キウイフルーツ:10である。
また、代表的な果実の酸度の基準(単位:%)としては、レモン:4.5、ライム:6、梅:3.5、カボス:3.5である。
[果汁率(%)]=[果汁配合量(g)]×[濃縮倍率]/100mL×100
例えば、オレンジ果汁は、JAS規格がBx11°であるから、Bx55°の濃縮オレンジ果汁を飲料中6.0重量%配合した場合、果汁率は30%となる。なお、果汁の果汁率をJAS規格の糖用屈折計示度に基づいて換算する際には、果汁に加えられた糖類、はちみつ等の糖用屈折計示度を除くものとする。
本明細書において、「甘味強度」は物質の呈する甘味の強さを意味する。例えば、単位濃度Brix1当たりのショ糖が呈する甘味強度を甘味度1と定めた場合、ブドウ糖の甘味度は0.6~0.7(中心値0.65)となる。この甘味度にブドウ糖の濃度Brix値を乗じて得られる数値がブドウ糖の甘味強度となる。したがって、ブドウ糖の濃度がBrix1.5の場合、ブドウ糖の甘味強度は0.65×1.5=0.975となる。
さらには、上記測定において本発明の果汁飲料よりも甘味が少ない基準果汁飲料のうち、本発明の果汁飲料と最も甘味の近い基準果汁飲料を選択し、当該選択された基準果汁飲料にショ糖を追加することによって本発明の果汁飲料と同じ甘味を呈するように調整し、その際に、調整後の基準果汁飲料に含まれるショ糖含有量から、本発明の果汁飲料について甘味強度を測定することもできる。
高甘味度甘味料(本明細書中、「甘味料(a)」または「成分(a)」と略すことがある)は、ショ糖に比べて強い甘味を有する化合物を意味し、天然由来化合物、合成化合物または天然由来化合物および合成化合物の組み合わせを包含する。高甘味度甘味料はショ糖と同量において、ショ糖より5倍以上、10倍以上、50倍以上、100倍以上、500倍以上、1,000倍以上、5,000倍以上、10,000倍以上、50,000倍以上または100,000倍以上の甘味を呈する。
カンゾウ(甘草)抽出物とは、ウラルカンゾウ、チョウカカンゾウまたはヨウカンゾウの根または根茎から得られた、グリチルリチン酸を主成分とするものをいう。カンゾウ抽出物の例としてはカンゾウエキス、グリチルリチン、リコリス抽出物が挙げられる。
ショ糖誘導体は、例えば、ショ糖のOH基またはH基を別の置換基で置換して得られるものを含み、その例としては、ショ糖のハロゲン誘導体(スクラロース)、オキサチアジノンジオキシド誘導体等が挙げられる。
本発明の果汁飲料は、(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩を含む。本発明に用いられるアミノ酸またはアミノ酸塩としては、アミノ基とカルボキシル基の両方の官能基を有する有機化合物またはその塩であって、甘味増大効果が得られるものであれば特に限定されない。また、アミノ基の水素が分子内の側鎖部分と置換して環状構造を形成しているプロリンやヒドロキシプロリンも本明細書においてアミノ酸に包含する。本発明に用いられるアミノ酸誘導体としては、タウリンのようにカルボキシル基を有さない誘導体も包含される。本発明の一態様において、アミノ酸は遊離アミノ酸を意味する。
(甘味料)
本発明の果汁飲料は、成分(a)の高甘味度甘味料以外にも甘味料を含み得る。本明細書において「甘味料」は甘味応答を引き起こす任意の物質または物質群を意味する。甘味料は、構造上の特徴から糖質系甘味料と非糖質系甘味料に、また、甘味度に基づき、低甘味度甘味料と高甘味度甘味料に分けることができる。また、エネルギー(カロリー)に基づき、甘味物質をカロリー性甘味料と非カロリー性甘味料に分けることもできる。さらに入手方法に基づき、天然甘味料と人工甘味料に分けることもできる。なお、果汁に果実由来の甘味料(果糖など)が含まれる場合、その甘味料もここに記載の甘味料に含めるものとする。
(a)甘味強度Xa相当の量の高甘味度甘味料
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、および
(c)甘味強度Xc相当の量の低甘味度甘味料(本明細書中、「成分(c)」と略すことがある。)
を含み、
前記成分(a)~(c)により甘味強度Xdの甘味を呈し、0.1<Xa+Xc<Xdである、果汁飲料。XcとXdはそれぞれ第1の態様においてはX4とX6と称する。本発明の一態様における果汁飲料は、(a)甘味強度Xa相当の量の高甘味度甘味料と(c)甘味強度Xc相当の量の低甘味度甘味料以外の成分を甘味料として含まない。なお、果汁飲料に含まれる果実由来の甘味料(果糖など)は(c)の甘味料に含まれる。
低甘味度甘味料の甘味強度Xc相当の量とは、本発明の果汁飲料と同等体積の20℃の水に低甘味度甘味料を溶かした条件で甘味強度Xcの甘味を呈する量(濃度)をいう。
本発明の第1および第A1の態様の果汁飲料は少量のナトリウムを含んでいてもよい。ナトリウムの含有量は、実施態様に応じて、0mg/100ml以上5mg/100ml未満、0~4.5mg/100ml、0~4.0mg/100ml、0~3.5mg/100ml、0~3.0mg/100ml、0~2.5mg/100ml、0~2.0mg/100ml、0~1.9mg/100ml、0~1.8mg/100ml、0~1.7mg/100ml、0~1.6mg/100ml、0~1.5mg/100ml、0~1.4mg/100ml、0~1.3mg/100ml、0~1.2mg/100ml、0~1.1mg/100ml、0~1.0mg/100ml、0.1mg/100ml以上5mg/100ml未満、0.1~4.5mg/100ml、0.1~4.0mg/100ml、0.1~3.5mg/100ml、0.1~3.0mg/100ml、0.1~2.5mg/100ml、0.1~2.0mg/100ml、0.1~1.9mg/100ml、0.1~1.8mg/100ml、0.1~1.7mg/100ml、0.1~1.6mg/100ml、0.1~1.5mg/100ml、0.1~1.4mg/100ml、0.1~1.3mg/100ml、0.1~1.2mg/100ml、0.1~1.1mg/100ml、0.1~1.0mg/100ml、0.5mg/100ml以上5mg/100ml未満、0.5~4.5mg/100ml、0.5~4.0mg/100ml、0.5~3.5mg/100ml、0.5~3.0mg/100ml、0.5~2.5mg/100ml、0.5~2.0mg/100ml、0.5~1.9mg/100ml、0.5~1.8mg/100ml、0.5~1.7mg/100ml、0.5~1.6mg/100ml、0.5~1.5mg/100ml、0.5~1.4mg/100ml、0.5~1.3mg/100ml、0.5~1.2mg/100ml、0.5~1.1mg/100ml、0.5~1.0mg/100ml、1.0mg/100ml以上5mg/100ml未満、1.0~4.5mg/100ml、1.0~4.0mg/100ml、1.0~3.5mg/100ml、1.0~3.0mg/100ml、1. 0~2.5mg/100ml、1.0~2.0mg/100ml、1.0~1.9mg/100ml、1.0~1.8mg/100ml、1.0~1.7mg/100ml、1.0~1.6mg/100ml、1.0~1.5mg/100ml、1.0~1.4mg/100ml、1.0~1.3mg/100ml、1.0~1.2mg/100mlまたは1.0~1.1mg/100mlの含有量にあってもよい。
本発明の果汁飲料は、本発明の効果を損なわない限りにおいて、酸化防止剤(エリソルビン酸ナトリウムなど)、乳化剤(ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、ポリグリセリン脂肪酸エステルなど)、酸味料(リン酸、クエン酸、リンゴ酸など)、香料等を適宜配合することができる。
本発明の一態様において、
(a)甘味強度Xa相当の量の高甘味度甘味料、および
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩
を含み、
前記成分(a)および(b)により甘味強度Xbの甘味を呈し、0.1<Xa<Xbであり、
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドD、レバウジオシドM、モグロシドV、羅漢果抽出物およびその組合せから選択される高甘味度甘味料、好ましくは、レバウジオシドD、レバウジオシドMおよびその組み合わせから選択される高甘味度甘味料、を含み、
Xaが、0.5~5.5、好ましくは1.0~5.5、より好ましくは2.0~5.0であり、
アミノ酸またはその誘導体もしくはその塩が、DL-アラニン、L-セリン、グリシン、L-アルギニン、L-グルタミン酸、L-バリンおよびL-グルタミンから選択されるアミノ酸を含む、果汁飲料が提供される。本態様において、高甘味度甘味料の量は、約20~約600ppm、約30~約550ppm、約55~約490ppm、約20~約200ppm、約100~約500ppmまたは約150~約350ppmであってもよい。
(a)甘味強度Xa相当の量の高甘味度甘味料、および
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩
を含み、
前記成分(a)および(b)により甘味強度Xbの甘味を呈し、0.1<Xa<Xbであり、
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドD、レバウジオシドM、モグロシドV、羅漢果抽出物およびその組合せから選択される高甘味度甘味料、好ましくは、レバウジオシドD、レバウジオシドMおよびその組み合わせから選択される高甘味度甘味料、を含み、
Xaが、0.5~10.0、好ましくは1.5~9.0、より好ましくは2.0~8.0であり、
アミノ酸またはその誘導体もしくはその塩が、DL-アラニン、L-セリン、グリシン、L-アルギニン、L-グルタミン酸、L-バリンおよびL-グルタミンから選択されるアミノ酸を含む、果汁飲料が提供される。本態様において、高甘味度甘味料の量は、約20~約600ppm、約30~約550ppm、約55~約490ppm、約20~約200ppm、約100~約500ppmまたは約150~約350ppmであってもよい。
(a)甘味強度Xa相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、および
(c)甘味強度Xc相当の量の低甘味度甘味料
を含み、
前記成分(a)~(c)により甘味強度Xdの甘味を呈し、0.1<Xa+Xc<Xdであり、
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドD、レバウジオシドM、モグロシドV、羅漢果抽出物およびその組合せから選択される高甘味度甘味料、好ましくは、レバウジオシドD、レバウジオシドMおよびその組み合わせから選択される高甘味度甘味料、を含み、
Xaが、0.5~5.5、好ましくは1.0~5.5、より好ましくは2.0~5.0であり、
アミノ酸またはその誘導体もしくはその塩が、DL-アラニン、L-セリン、グリシン、L-アルギニン、L-グルタミン酸、L-バリンおよびL-グルタミンから選択されるアミノ酸を含み、
低甘味度甘味料が、グルコース、スクロース、フルクトース、マルトース、オリゴ糖、異性化糖、乳糖、プシコース、アロース、タガトース、キシロース、リボースおよびその組合せから選択される甘味料を含み、
Xcが、0.05~6.0、好ましくは0.05~5.0、より好ましくは0.1~4.0である、果汁飲料が提供される。本態様において、高甘味度甘味料の量は、約20~約600ppm、約30~約550ppm、約55~約490ppm、約20~約200ppm、約100~約500ppmまたは約150~約350ppmであってもよい。
(a)甘味強度Xa相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、および
(c)甘味強度Xc相当の量の低甘味度甘味料
を含み、
前記成分(a)~(c)により甘味強度Xdの甘味を呈し、0.1<Xa+Xc<Xdであり、
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドD、レバウジオシドM、モグロシドV、羅漢果抽出物およびその組合せから選択される高甘味度甘味料、好ましくは、レバウジオシドD、レバウジオシドMおよびその組み合わせから選択される高甘味度甘味料、を含み、
Xaが、0.5~5.5、好ましくは1.0~5.5、より好ましくは2.0~5.0であり、
アミノ酸またはその誘導体もしくはその塩が、DL-アラニン、L-セリン、グリシン、L-アルギニン、L-グルタミン酸、L-バリンおよびL-グルタミンから選択されるアミノ酸を含み、
低甘味度甘味料が、グルコース、スクロース、フルクトース、マルトース、オリゴ糖、異性化糖、乳糖、プシコース、アロース、タガトース、キシロース、リボースおよびその組合せから選択される甘味料を含み、
果汁率が1~100%、4~95%、5~80%、5~50%または5~30%であり、
Xcが、0.05~6.0、好ましくは0.05~5.0、より好ましくは0.1~4.0である、果汁飲料が提供される。本態様において、高甘味度甘味料の量は、約20~約600ppm、約30~約550ppm、約55~約490ppm、約20~約200ppm、約100~約500ppmまたは約150~約350ppmであってもよい。
(a)甘味強度Xa相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、および
(c)甘味強度Xc相当の量の低甘味度甘味料
を含み、
前記成分(a)~(c)により甘味強度Xdの甘味を呈し、0.1<Xa+Xc<Xdであり、
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドD、レバウジオシドM、モグロシドV、羅漢果抽出物およびその組合せから選択される高甘味度甘味料、好ましくは、レバウジオシドD、レバウジオシドMおよびその組み合わせから選択される高甘味度甘味料、を含み、
Xaが、0.5~5.5、好ましくは1.0~5.5、より好ましくは2.0~5.0であり、
アミノ酸またはその誘導体もしくはその塩が、20mM未満のDL-アラニン、40mM未満のL-セリン、50mM未満のグリシン、1mM未満のL-アルギニン、0.25mM未満のL-グルタミン酸、40mM未満のL-バリン、5mM未満のL-グルタミン、20mM未満のL-ロイシン、40mM未満のL-スレオニン、40mM未満のL-プロリン、10mM未満のL-アスパラギンおよび0.4mM未満のL-リジン塩酸塩から選択されるアミノ酸を含み、
低甘味度甘味料が、グルコース、スクロース、フルクトース、マルトース、オリゴ糖、異性化糖、乳糖、プシコース、アロース、タガトース、キシロース、リボースおよびその組合せから選択される甘味料を含み、
Xcが、0.05~6.0、好ましくは0.05~5.0、より好ましくは0.1~4.0である、果汁飲料が提供される。本態様において、高甘味度甘味料の量は、約20~約600ppm、約30~約550ppm、約55~約490ppm、約20~約200ppm、約100~約500ppmまたは約150~約350ppmであってもよい。
(a)甘味強度Xa相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、および
(c)甘味強度Xc相当の量の低甘味度甘味料
を含み、
前記成分(a)~(c)により甘味強度Xdの甘味を呈し、0.1<Xa+Xc<Xdであり、
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドD、レバウジオシドM、モグロシドV、羅漢果抽出物およびその組合せから選択される高甘味度甘味料、好ましくは、レバウジオシドD、レバウジオシドMおよびその組み合わせから選択される高甘味度甘味料、を含み、
Xaが、0.5~5.5、好ましくは1.0~5.5、より好ましくは2.0~5.0であり、
アミノ酸またはその誘導体もしくはその塩が、アルギニン、リジン、ヒスチジン、フェニルアラニン、チロシン、ロイシン、イソロイシン、メチオニン、バリン、アラニン、グリシン、プロリン、グルタミン酸、セリン、スレオニン、アスパラギン酸およびトリプトファンから選択されるアミノ酸を含み、
低甘味度甘味料が、グルコース、スクロース、フルクトースおよびその組合せから選択される甘味料を含み、
果汁が、オレンジ、ミカン、レモン、グレープフルーツ、ライムおよびその組合せから選択される1種以上であり、
果汁率が1~100%、4~95%、5~80%、5~50%または5~30%であり、
Xcが、0.05~6.0、好ましくは0.05~5.0、より好ましくは0.1~4.0である、果汁飲料が提供される。本態様において、高甘味度甘味料の量は、約20~約600ppm、約30~約550ppm、約55~約490ppm、約20~約200ppm、約100~約500ppmまたは約150~約350ppmであってもよい。
(a)甘味強度Xa相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、および
(c)甘味強度Xc相当の量の低甘味度甘味料
を含み、
前記成分(a)~(c)により甘味強度Xdの甘味を呈し、0.1<Xa+Xc<Xdであり、
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドD、レバウジオシドM、モグロシドV、羅漢果抽出物およびその組合せから選択される高甘味度甘味料、好ましくは、レバウジオシドD、レバウジオシドMおよびその組み合わせから選択される高甘味度甘味料、を含み、
Xaが、0.5~5.5、好ましくは1.0~5.5、より好ましくは2.0~5.0であり、
アミノ酸またはその誘導体もしくはその塩が、アルギニン、バリン、アラニン、グリシン、プロリン、グルタミン酸、セリン、スレオニン、アスパラギン酸およびトリプトファンから選択されるアミノ酸を含み、
低甘味度甘味料が、グルコース、スクロース、フルクトースおよびその組合せから選択される甘味料を含み、
果汁が、ブルーベリー、カシス、クランベリー、イチゴ、ラズベリーおよびその組合せから選択される1種以上であり、
果汁率が1~100%、4~95%、5~80%、5~50%または5~30%であり、
Xcが、0.05~6.0、好ましくは0.05~5.0、より好ましくは0.1~4.0である、果汁飲料が提供される。本態様において、高甘味度甘味料の量は、約20~約600ppm、約30~約550ppm、約55~約490ppm、約20~約200ppm、約100~約500ppmまたは約150~約350ppmであってもよい。
(a)甘味強度Xa相当の量の高甘味度甘味料、
(b)アラニン、セリンおよびグリシンから選択される1つ以上のアミノ酸、および
(c)甘味強度Xc相当の量の低甘味度甘味料
を含み、
前記成分(a)~(c)により甘味強度Xdの甘味を呈し、0.1<Xa+Xc<Xdであり、
エネルギーが50Kcal/100ml以下、かつXa+Xcが6以上である、果汁飲料が提供される。本態様において、高甘味度甘味料の量は、約20~約600ppm、約30~約550ppm、約55~約490ppm、約20~約200ppm、約100~約500ppmまたは約150~約350ppmであってもよい。
(a)甘味強度Xa相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、および
(c)甘味強度Xc相当の量の低甘味度甘味料
を含み、
前記成分(a)~(c)により甘味強度Xdの甘味を呈し、0.1<Xa+Xc<Xdであり、
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドD、レバウジオシドM、モグロシドV、羅漢果抽出物およびその組合せから選択される高甘味度甘味料、好ましくは、レバウジオシドD、レバウジオシドMおよびその組み合わせから選択される高甘味度甘味料、を含み、
Xaが、1.0~11.0、好ましくは1.5~10.0、あるいは1.5~6.0または4.0~10.0であり、
アミノ酸またはその誘導体もしくはその塩が、アルギニン、バリン、アラニン、グリシン、プロリン、グルタミン酸、セリン、スレオニン、アスパラギン酸およびトリプトファンから選択されるアミノ酸を含み、
低甘味度甘味料が、グルコース、スクロース、フルクトースおよびその組合せから選択される甘味料を含み、
Xcが、0.5~9.0、好ましくは1.0~8.0、あるいは1.0~5.0または2.5~9.0である、果汁飲料が提供される。本態様において、高甘味度甘味料の量は、約20~約600ppm、約30~約550ppm、約55~約490ppm、約20~約200ppm、約100~約500ppmまたは約200~約450ppmであってもよい。
本発明は、第B1の態様として、以下の果汁飲料(以下、「本発明の果汁飲料B」ともいう)を提供する。
(a)甘味強度X1相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、および
(c)50mg/100ml未満のナトリウム
を含み、
前記成分(a)~(c)により甘味強度X2の甘味を呈し、0.1<X1<X2である、果汁飲料。
本発明において「果汁飲料」とは、果実の搾汁である果汁を含む飲料を意味する。
具体的な「果汁飲料」としては、2018年に施行された「果実飲料等の表示に関する公正競争規約」の定義にある「果実飲料」や、2016年に施行された「果実飲料等の表示に関する公正競争規約施行規則」の定義である「果実ジュース」「果実ミックスジュース」「果粒入り果実ジュース」「果実・野菜ミックスジュース」「果汁入り飲料」「果汁入りゼリー飲料」が挙げられる。
なお、上記の規約では「その他の飲料」に分類される果汁の使用割合が10%未満の飲料についても、果汁を含む飲料であれば、本発明でいう「果汁飲料」に含まれる。本発明の果汁飲料は「果汁含有飲料」とも称される。
なお、濃縮果汁は、加熱濃縮法および冷凍濃縮法のいずれによって調製されたものであってもよい。
代表的な果実の糖用屈折計示度の基準(単位:°Bx)の値としては、オレンジ:11、ミカン:9、グレープフルーツ:9、パイナップル:11、クランベリー:7、ブルーベリー、グァバ:8、バナナ:23、パパイヤ:9、パッションフルーツ:14、マンゴー:13、リンゴ:10、ブドウ:11、桃:8、日本梨:8、西洋梨:11、アンズ:7、スモモ:6、メロン、キウイフルーツ:10である。
また、代表的な果実の酸度の基準(単位:%)としては、レモン:4.5、ライム:6、梅:3.5、カボス:3.5である。
[果汁率(%)]=[果汁配合量(g)]×[濃縮倍率]/100mL×100
例えば、オレンジ果汁は、JAS規格がBx11°であるから、Bx55°の濃縮オレンジ果汁を飲料中6.0重量%配合した場合、果汁率は30%となる。なお、果汁の果汁率をJAS規格の糖用屈折計示度に基づいて換算する際には、果汁に加えられた糖類、はちみつ等の糖用屈折計示度を除くものとする。
本明細書において、「甘味強度」は物質の呈する甘味の強さを意味する。例えば、単位濃度Brix1当たりのショ糖が呈する甘味強度を甘味度1と定めた場合、ブドウ糖の甘味度は0.6~0.7(中心値0.65)となる。この甘味度にブドウ糖の濃度Brix値を乗じて得られる数値がブドウ糖の甘味強度となる。したがって、ブドウ糖の濃度がBrix1.5の場合、ブドウ糖の甘味強度は0.65×1.5=0.975となる。一般的な甘味料の甘味度は、第1および第A1の態様について記載した表1に示されている通りである。
さらには、上記測定において本発明の果汁飲料よりも甘味が少ない基準果汁飲料のうち、本発明の果汁飲料と最も甘味の近い基準果汁飲料を選択し、当該選択された基準果汁飲料にショ糖を追加することによって本発明の果汁飲料と同じ甘味を呈するように調整し、その際に、調整後の基準果汁飲料に含まれるショ糖含有量から、本発明の果汁飲料について甘味強度を測定することもできる。
高甘味度甘味料(本明細書中、「甘味料(a)」または「成分(a)」と略すことがある)は、ショ糖に比べて強い甘味を有する化合物を意味し、天然由来化合物、合成化合物または天然由来化合物および合成化合物の組み合わせを包含する。高甘味度甘味料はショ糖と同量において、ショ糖より5倍以上、10倍以上、50倍以上、100倍以上、500倍以上、1,000倍以上、5,000倍以上、10,000倍以上、50,000倍以上または100,000倍以上の甘味を呈する。
カンゾウ(甘草)抽出物とは、ウラルカンゾウ、チョウカカンゾウまたはヨウカンゾウの根または根茎から得られた、グリチルリチン酸を主成分とするものをいう。カンゾウ抽出物の例としてはカンゾウエキス、グリチルリチン、リコリス抽出物が挙げられる。
ショ糖誘導体は、例えば、ショ糖のOH基またはH基を別の置換基で置換して得られるものを含み、その例としては、ショ糖のハロゲン誘導体(スクラロース)、オキサチアジノンジオキシド誘導体等が挙げられる。
本発明の果汁飲料は、(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩を含む。本発明に用いられるアミノ酸またはアミノ酸塩としては、アミノ基とカルボキシル基の両方の官能基を有する有機化合物またはその塩であって、甘味増大効果が得られるものであれば特に限定されない。また、アミノ基の水素が分子内の側鎖部分と置換して環状構造を形成しているプロリンやヒドロキシプロリンも本明細書においてアミノ酸に包含する。本発明に用いられるアミノ酸誘導体としては、タウリンのようにカルボキシル基を有さない誘導体も包含される。本発明の一態様において、アミノ酸は遊離アミノ酸を意味する。
本発明の果汁飲料は(c)50mg/100ml未満のナトリウムを含むが、これはナトリウム原子の含有量が50mg/100ml未満であることを意味する。ナトリウムの含有量は、実施態様に応じて、0.1mg/100ml以上50mg/100ml未満、0.1~45mg/100ml、0.1~40mg/100ml、0.1~35mg/100ml、0.1~30mg/100ml、0.1~25mg/100ml、0.1~20mg/100ml、0.1~19mg/100ml、0. 1~18mg/100ml、0.1~17mg/100ml、0.1~16mg/100ml、0.1~15mg/100ml、0.1~14mg/100ml、0.1~13mg/100ml、0.1~12mg/100ml、0.1~11mg/100ml、0.1~10mg/100ml、1mg/100ml以上50mg/100ml未満、1~45mg/100ml、1~40mg/100ml、1~35mg/100ml、1~30mg/100ml、1~25mg/100ml、1~20mg/100ml、1~19mg/100ml、1~18mg/100ml、1~17mg/100ml、1~16mg/100ml、1~15mg/100ml、1~14mg/100ml、1~13mg/100ml、1~12mg/100ml、1~11mg/100ml、1~10mg/100ml、5mg/100ml以上50mg/100ml未満、5~45mg/100ml、5~40mg/100ml、5~35mg/100ml、5~30mg/100ml、5~25mg/100ml、5~20mg/100ml、5~19mg/100ml、5~18mg/100ml、5~17mg/100ml、5~16mg/100ml、5~15mg/100ml、5~14mg/100ml、5~13mg/100ml、5~12mg/100ml、5~11mg/100ml、5~10mg/100ml、7mg/100ml以上50mg/100ml未満、7~45mg/100ml、7~40mg/100ml、7~35mg/100ml、7~30mg/100ml、7~25mg/100ml、7~20mg/100ml、7~19mg/100ml、7~18mg/100ml、7~17mg/100ml、7~16mg/100ml、7~15mg/100ml、10mg/100ml以上50mg/100ml未満、10~45mg/100ml、10~40mg/100ml、10~35mg/100ml、10~30mg/100ml、10~25mg/100ml、10~20mg/100ml、10~19mg/100ml、10~18mg/100ml、10~17mg/100ml、10~16mg/100ml、10~15mg/100ml、15mg/100ml以上50mg/100ml未満、15~45mg/100ml、15~40mg/100ml、15~35mg/100ml、15~30mg/100ml、15~25mg/100ml、15~20mg/100ml、20mg/100ml以上50mg/100ml未満、20~45mg/100ml、20~40mg/100ml、20~35mg/100ml、20~30mg/100ml、20~25mg/100ml、25mg/100ml以上50mg/100ml未満、25~45mg/100ml、25~40mg/100ml、25~35mg/100mlまたは25~30mg/100mlの含有量にあってもよい。
また、果汁にナトリウムが含まれる場合、その果汁由来のナトリウムも、本発明の果汁飲料に含まれるナトリウムに包含される。
本発明の一態様において、保存料として用いるナトリウム成分(例えば、安息香酸ナトリウム、亜硫酸ナトリウム、次亜硫酸ナトリウム、デヒドロ酢酸ナトリウム、ピロ亜硫酸ナトリウム、プロピオン酸ナトリウム等)由来のナトリウムは成分(c)に実質的に含まない。
(甘味料)
本発明の果汁飲料は、成分(a)の高甘味度甘味料以外にも甘味料を含み得る。本明細書において「甘味料」は甘味応答を引き起こす任意の物質または物質群を意味する。甘味料は、構造上の特徴から糖質系甘味料と非糖質系甘味料に、また、甘味度に基づき、低甘味度甘味料と高甘味度甘味料に分けることができる。また、エネルギー(カロリー)に基づき、甘味物質をカロリー性甘味料と非カロリー性甘味料に分けることもできる。さらに入手方法に基づき、天然甘味料と人工甘味料に分けることもできる。なお、果汁に果実由来の甘味料(果糖など)が含まれる場合、その甘味料もここに記載の甘味料に含めるものとする。
(a)甘味強度X1相当の量の高甘味度甘味料
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、
(c)50mg/100ml未満のナトリウム、および
(d)甘味強度X4相当の量の低甘味度甘味料(本明細書中、「成分(d)」と略すことがある。)
を含み、
前記成分(a)~(d)により甘味強度X5の甘味を呈し、0.1<X1+X4<X5である、果汁飲料。本発明の一態様における果汁飲料は、(a)甘味強度X1相当の量の高甘味度甘味料と(d)甘味強度X4相当の量の低甘味度甘味料以外の成分を甘味料として含まない。なお、果汁飲料に含まれる果実由来の甘味料(果糖など)は(d)の甘味料に含まれる。
低甘味度甘味料の甘味強度X4相当の量とは、本発明の果汁飲料と同等体積の20℃の水に低甘味度甘味料を溶かした条件で甘味強度X4の甘味を呈する量(濃度)をいう。
本発明の果汁飲料は、本発明の効果を損なわない限りにおいて、酸化防止剤(エリソルビン酸ナトリウムなど)、乳化剤(ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、ポリグリセリン脂肪酸エステルなど)、酸味料(リン酸、クエン酸、リンゴ酸など)、香料等を適宜配合することができる。
本発明の一態様において、
(a)甘味強度X1相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、および
(c)50mg/100ml未満、0.1~40mg/100ml、1~30mg/100mlまたは5~25mg/100mlのナトリウム
を含み、
前記成分(a)~(c)により甘味強度X2の甘味を呈し、0.1<X1<X2であり、
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドD、レバウジオシドM、モグロシドV、羅漢果抽出物およびその組合せから選択される高甘味度甘味料、好ましくは、レバウジオシドD、レバウジオシドMおよびその組み合わせから選択される高甘味度甘味料、を含み、
X1が、0.5~5.5、好ましくは1.0~5.5、より好ましくは2.0~5.0であり、
アミノ酸またはその誘導体もしくはその塩が、DL-アラニン、L-セリン、グリシン、L-アルギニン、L-グルタミン酸、L-バリンおよびL-グルタミンから選択されるアミノ酸を含む、果汁飲料が提供される。本態様において、高甘味度甘味料の量は、約20~約600ppm、約30~約550ppm、約55~約490ppm、約20~約200ppm、約100~約500ppmまたは約150~約350ppmであってもよい。
(a)甘味強度X1相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、および
(c)50mg/100ml未満、0.1~40mg/100ml、1~30mg/100mlまたは5~25mg/100mlのナトリウム
を含み、
前記成分(a)~(c)により甘味強度X2の甘味を呈し、0.1<X1<X2であり、
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドD、レバウジオシドM、モグロシドV、羅漢果抽出物およびその組合せから選択される高甘味度甘味料、好ましくは、レバウジオシドD、レバウジオシドMおよびその組み合わせから選択される高甘味度甘味料、を含み、
X1が、0.5~10.0、好ましくは1.5~9.0、より好ましくは2.0~8.0であり、
アミノ酸またはその誘導体もしくはその塩が、DL-アラニン、L-セリン、グリシン、L-アルギニン、L-グルタミン酸、L-バリンおよびL-グルタミンから選択されるアミノ酸を含む、果汁飲料が提供される。本態様において、高甘味度甘味料の量は、約20~約600ppm、約30~約550ppm、約55~約490ppm、約20~約200ppm、約100~約500ppmまたは約150~約350ppmであってもよい。
(a)甘味強度X1相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、
(c)50mg/100ml未満、0.1~40mg/100ml、1~30mg/100mlまたは5~25mg/100mlのナトリウム、および
(d)甘味強度X4相当の量の低甘味度甘味料
を含み、
前記成分(a)~(d)により甘味強度X5の甘味を呈し、0.1<X1+X4<X5であり、
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドD、レバウジオシドM、モグロシドV、羅漢果抽出物およびその組合せから選択される高甘味度甘味料、好ましくは、レバウジオシドD、レバウジオシドMおよびその組み合わせから選択される高甘味度甘味料、を含み、
X1が、0.5~5.5、好ましくは1.0~5.5、より好ましくは2.0~5.0であり、
アミノ酸またはその誘導体もしくはその塩が、DL-アラニン、L-セリン、グリシン、L-アルギニン、L-グルタミン酸、L-バリンおよびL-グルタミンから選択されるアミノ酸を含み、
低甘味度甘味料が、グルコース、スクロース、フルクトース、マルトース、オリゴ糖、異性化糖、乳糖、プシコース、アロース、タガトース、キシロース、リボースおよびその組合せから選択される甘味料を含み、
X4が、0.05~6.0、好ましくは0.05~5.0、より好ましくは0.1~4.0である、果汁飲料が提供される。本態様において、高甘味度甘味料の量は、約20~約600ppm、約30~約550ppm、約55~約490ppm、約20~約200ppm、約100~約500ppmまたは約150~約350ppmであってもよい。
(a)甘味強度X1相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、
(c)50mg/100ml未満、0.1~40mg/100ml、1~30mg/100mlまたは5~25mg/100mlのナトリウム、および
(d)甘味強度X4相当の量の低甘味度甘味料
を含み、
前記成分(a)~(d)により甘味強度X5の甘味を呈し、0.1<X1+X4<X5であり、
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドD、レバウジオシドM、モグロシドV、羅漢果抽出物およびその組合せから選択される高甘味度甘味料、好ましくは、レバウジオシドD、レバウジオシドMおよびその組み合わせから選択される高甘味度甘味料、を含み、
X1が、0.5~5.5、好ましくは1.0~5.5、より好ましくは2.0~5.0であり、
アミノ酸またはその誘導体もしくはその塩が、DL-アラニン、L-セリン、グリシン、L-アルギニン、L-グルタミン酸、L-バリンおよびL-グルタミンから選択されるアミノ酸を含み、
低甘味度甘味料が、グルコース、スクロース、フルクトース、マルトース、オリゴ糖、異性化糖、乳糖、プシコース、アロース、タガトース、キシロース、リボースおよびその組合せから選択される甘味料を含み、
果汁率が1~100%、4~95%、5~80%、5~50%または5~30%であり、
X4が、0.05~6.0、好ましくは0.05~5.0、より好ましくは0.1~4.0である、果汁飲料が提供される。本態様において、高甘味度甘味料の量は、約20~約600ppm、約30~約550ppm、約55~約490ppm、約20~約200ppm、約100~約500ppmまたは約150~約350ppmであってもよい。
(a)甘味強度X1相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、
(c)50mg/100ml未満、0.1~40mg/100ml、1~30mg/100mlまたは5~25mg/100mlのナトリウム、および
(d)甘味強度X4相当の量の低甘味度甘味料
を含み、
前記成分(a)~(d)により甘味強度X5の甘味を呈し、0.1<X1+X4<X5であり、
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドD、レバウジオシドM、モグロシドV、羅漢果抽出物およびその組合せから選択される高甘味度甘味料、好ましくは、レバウジオシドD、レバウジオシドMおよびその組み合わせから選択される高甘味度甘味料、を含み、
X1が、0.5~5.5、好ましくは1.0~5.5、より好ましくは2.0~5.0であり、
アミノ酸またはその誘導体もしくはその塩が、20mM未満のDL-アラニン、40mM未満のL-セリン、50mM未満のグリシン、1mM未満のL-アルギニン、0.25mM未満のL-グルタミン酸、40mM未満のL-バリン、5mM未満のL-グルタミン、20mM未満のL-ロイシン、40mM未満のL-スレオニン、40mM未満のL-プロリン、10mM未満のL-アスパラギンおよび0.4mM未満のL-リジン塩酸塩から選択されるアミノ酸を含み、
低甘味度甘味料が、グルコース、スクロース、フルクトース、マルトース、オリゴ糖、異性化糖、乳糖、プシコース、アロース、タガトース、キシロース、リボースおよびその組合せから選択される甘味料を含み、
X4が、0.05~6.0、好ましくは0.05~5.0、より好ましくは0.1~4.0である、果汁飲料が提供される。本態様において、高甘味度甘味料の量は、約20~約600ppm、約30~約550ppm、約55~約490ppm、約20~約200ppm、約100~約500ppmまたは約150~約350ppmであってもよい。
(a)甘味強度X1相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、
(c)50mg/100ml未満、0.1~40mg/100ml、1~30mg/100mlまたは5~25mg/100mlのナトリウム、および
(d)甘味強度X4相当の量の低甘味度甘味料
を含み、
前記成分(a)~(d)により甘味強度X5の甘味を呈し、0.1<X1+X4<X5であり、
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドD、レバウジオシドM、モグロシドV、羅漢果抽出物およびその組合せから選択される高甘味度甘味料、好ましくは、レバウジオシドD、レバウジオシドMおよびその組み合わせから選択される高甘味度甘味料、を含み、
X1が、0.5~5.5、好ましくは1.0~5.5、より好ましくは2.0~5.0であり、
アミノ酸またはその誘導体もしくはその塩が、アルギニン、リジン、ヒスチジン、フェニルアラニン、チロシン、ロイシン、イソロイシン、メチオニン、バリン、アラニン、グリシン、プロリン、グルタミン酸、セリン、スレオニン、アスパラギン酸およびトリプトファンから選択されるアミノ酸を含み、
低甘味度甘味料が、グルコース、スクロース、フルクトースおよびその組合せから選択される甘味料を含み、
果汁が、オレンジ、ミカン、レモン、グレープフルーツ、ライムおよびその組合せから選択される1種以上であり、
果汁率が1~100%、4~95%、5~80%、5~50%または5~30%であり、
X4が、0.05~6.0、好ましくは0.05~5.0、より好ましくは0.1~4.0である、果汁飲料が提供される。本態様において、高甘味度甘味料の量は、約20~約600ppm、約30~約550ppm、約55~約490ppm、約20~約200ppm、約100~約500ppmまたは約150~約350ppmであってもよい。
(a)甘味強度X1相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、
(c)50mg/100ml未満、0.1~40mg/100ml、1~30mg/100mlまたは5~25mg/100mlのナトリウム、および
(d)甘味強度X4相当の量の低甘味度甘味料
を含み、
前記成分(a)~(d)により甘味強度X5の甘味を呈し、0.1<X1+X4<X5であり、
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドD、レバウジオシドM、モグロシドV、羅漢果抽出物およびその組合せから選択される高甘味度甘味料、好ましくは、レバウジオシドD、レバウジオシドMおよびその組み合わせから選択される高甘味度甘味料、を含み、
X1が、0.5~5.5、好ましくは1.0~5.5、より好ましくは2.0~5.0であり、
アミノ酸またはその誘導体もしくはその塩が、アルギニン、バリン、アラニン、グリシン、プロリン、グルタミン酸、セリン、スレオニン、アスパラギン酸およびトリプトファンから選択されるアミノ酸を含み、
低甘味度甘味料が、グルコース、スクロース、フルクトースおよびその組合せから選択される甘味料を含み、
果汁が、ブルーベリー、カシス、クランベリー、イチゴ、ラズベリーおよびその組合せから選択される1種以上であり、
果汁率が1~100%、4~95%、5~80%、5~50%または5~30%であり、
X4が、0.05~6.0、好ましくは0.05~5.0、より好ましくは0.1~4.0である、果汁飲料が提供される。本態様において、高甘味度甘味料の量は、約20~約600ppm、約30~約550ppm、約55~約490ppm、約20~約200ppm、約100~約500ppmまたは約150~約350ppmであってもよい。
(a)甘味強度X1相当の量の高甘味度甘味料、
(b)アラニン、セリンおよびグリシンから選択される1つ以上のアミノ酸、
(c)1~25mg/100mlのナトリウムおよび
(d)甘味強度X4相当の量の低甘味度甘味料
を含み、
前記成分(a)~(d)により甘味強度X5の甘味を呈し、0.1<X1+X4<X5であり、
エネルギーが50Kcal/100ml以下、かつX1+X4が6以上である、果汁飲料が提供される。本態様において、高甘味度甘味料の量は、約20~約600ppm、約30~約550ppm、約55~約490ppm、約20~約200ppm、約100~約500ppmまたは約150~約350ppmであってもよい。
(a)甘味強度X1相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、
(c)50mg/100ml未満、0.1~40mg/100ml、1~30mg/100mlまたは5~25mg/100mlのナトリウム、および
(d)甘味強度X4相当の量の低甘味度甘味料
を含み、
前記成分(a)~(d)により甘味強度X5の甘味を呈し、0.1<X1+X4<X5であり、
前記高甘味度甘味料が、レバウジオシドA、レバウジオシドD、レバウジオシドM、モグロシドV、羅漢果抽出物およびその組合せから選択される高甘味度甘味料、好ましくは、レバウジオシドD、レバウジオシドMおよびその組み合わせから選択される高甘味度甘味料、を含み、
X1が、1.0~11.0、好ましくは1.5~10.0、あるいは1.5~6.0または4.0~10.0であり、
アミノ酸またはその誘導体もしくはその塩が、アルギニン、バリン、アラニン、グリシン、プロリン、グルタミン酸、セリン、スレオニン、アスパラギン酸およびトリプトファンから選択されるアミノ酸を含み、
低甘味度甘味料が、グルコース、スクロース、フルクトースおよびその組合せから選択される甘味料を含み、
X4が、0.5~9.0、好ましくは1.0~8.0、あるいは1.0~5.0または2.5~9.0である、果汁飲料が提供される。本態様において、高甘味度甘味料の量は、約20~約600ppm、約30~約550ppm、約55~約490ppm、約20~約200ppm、約100~約500ppmまたは約200~約450ppmであってもよい。
《第2および第A2の態様》
本発明は、第2の態様として、以下の甘味が増大された果汁飲料の製造方法(以下、「本発明の製造方法」という)を提供する。
原材料に対し、
(a)甘味強度X1の量の高甘味度甘味料を添加すること、および
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩を添加することを含む、本発明の果汁飲料の製造方法。本態様において、X1とX3はそれぞれ第A2の態様(特願2020-147848/2020-185335に対応)のXaおよびXbに相当する。
原材料に対し、
(a)甘味強度Xaの量の高甘味度甘味料を添加すること、および
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩を添加することを含む、本発明の果汁飲料の製造方法。
(a)甘味強度Xaの量の高甘味度甘味料を添加すること
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩を添加すること
また、2つの工程が同時に行われてもよい。例えば、(a)と(b)が同時に行われてもよい。
例えば、第1の原材料に果汁、穀類、豆類やその抽出物が含まれ、そのために原材料に予め成分(a)および(b)のいずれか1つ以上が含まれ、第1の原材料と混合するための第2の原材料においても成分(a)および(b)が含まれ、第1および第2の原材料を混合することにより本発明の果汁飲料Aが製造できた場合、成分(a)および(b)を個別に原材料に追加する操作は存在していないが、本発明の方法では、最終的に製造される本発明の果汁飲料が(a)甘味強度Xa相当の量の高甘味度甘味料、および(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩を含む限り、工程(a)および(b)は行われたものとみなす。
本発明は、第B2の態様として、以下の甘味が増大された果汁飲料の製造方法(以下、「本発明の製造方法B」ともいう)を提供する。
原材料に対し、
(a)甘味強度X1の量の高甘味度甘味料を添加すること、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩を添加すること、および
(c)飲料中のナトリウム含有量が50mg/100ml未満となるようにナトリウムを添加すること、
を含む、本発明の果汁飲料の製造方法。
(a)甘味強度X1の量の高甘味度甘味料を添加すること
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩を添加すること
(c)飲料中のナトリウム含有量が50mg/100ml未満となるようにナトリウムを添加すること、
また、2つ以上の工程が同時に行われてもよい。例えば、(a)と(b)、(a)と(c)、(b)と(c)または(a)と(b)と(c)が同時に行われてもよい。
例えば、第1の原材料に果汁、穀類、豆類やその抽出物が含まれ、そのために原材料に予め成分(a)、(b)および(c)のいずれか1つ以上が含まれ、第1の原材料と混合するための第2の原材料においても成分(a)、(b)および(c)が含まれ、第1および第2の原材料を混合することにより本発明の果汁飲料が製造できた場合、成分(a)、(b)および(c)を個別に原材料に追加する操作は存在していないが、本発明の方法では、最終的に製造される本発明の果汁飲料が(a)甘味強度X1相当の量の高甘味度甘味料、(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩および(c)50mg/100ml未満のナトリウムを含む限り、工程(a)~(c)は行われたものとみなす。
《第3および第A3の態様》
本発明は、第3の態様として、果汁飲料の甘味強度を増強する方法(以下、「本発明の増強方法」という)を提供する。
本発明の増強方法の一態様において、果汁飲料に
(a)甘味強度X1相当の量の高甘味度甘味料、および
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩
を含有させことを特徴とする、果汁飲料の甘味強度を増強する方法、が提供される。本態様において、X1は第A3の態様(特願2020-147848/2020-185335に対応)のXaに相当する。
本発明の増強方法の一態様において、果汁飲料に
(a)甘味強度Xa相当の量の高甘味度甘味料、および
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩
を含有させことを特徴とする、果汁飲料の甘味強度を増強する方法、が提供される。
本態様の増強方法によれば、果汁飲料の甘味を増強し、単に果汁飲料に成分(a)および成分(d)を添加したときの甘味強度を超える甘味を奏する果汁飲料を提供することができる。具体的には、所定量の高甘味度甘味料および低甘味度甘味料を含む果汁飲料に、アミノ酸を添加して、添加後に当該果汁飲料中に味覚認知閾値未満のアミノ酸が含まれるようにすることで、当該果汁飲料に高甘味度甘味料および低甘味度甘味料のみを添加した場合の甘味強度を超える甘味をもたらす。
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、および
(c)甘味強度Xc相当の量の低甘味度甘味料
を含有させることを特徴とする、果汁飲料の甘味強度を増強する方法が提供される。
本態様の増強方法によれば、果汁飲料の甘味を増強し、単に果汁飲料に成分(c)を添加したときの甘味強度を超える甘味を奏する果汁飲料を提供することができる。具体的には、所定量の低甘味度甘味料を含む果汁飲料にアミノ酸を添加して、添加後に当該果汁飲料中に味覚認知閾値未満のアミノ酸が含まれるようにすることで、当該果汁飲料に低甘味度甘味料のみを添加した場合の甘味強度を超える甘味をもたらす。この態様においても、添加するアミノ酸またはその誘導体もしくはその塩の種類および量は、上記項目「1.甘味が増大された果汁飲料」の第1または第A1の態様で述べた果汁飲料中のアミノ酸またはその誘導体もしくはその塩の種類および含有量となるように選択することができる。例えば、グリシン、アラニン、バリン、イソロイシン、ロイシン、セリン、スレオニン、グルタミン、アスパラギン、アルギニン、リジン、ヒスチジンおよびその組合せから選択されるアミノ酸を、上記項目「1.甘味が増大された果汁飲料」の第1または第A1の態様に記載された量となるように果汁飲料に添加してもよい。
本発明は、第B3の態様として、果汁飲料の甘味強度を増強する方法(以下、「本発明の増強方法B」ともいう)を提供する。
本発明の増強方法の一態様において、果汁飲料に
(a)甘味強度X1相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、および
(c)50mg/100ml未満のナトリウム
を含有させることを特徴とする、果汁飲料の甘味強度を増強する方法、が提供される。
本態様の増強方法によれば、果汁飲料の甘味を増強し、単に果汁飲料に成分(a)および成分(d)を添加したときの甘味強度を超える甘味を奏する果汁飲料を提供することができる。具体的には、所定量の高甘味度甘味料および低甘味度甘味料を含む果汁飲料に、ナトリウム(またはナトリウム源)とアミノ酸を同時または別々に添加して、添加後に当該果汁飲料中に50mg/100ml未満、0.1~40mg/100ml、1~30mg/100mlまたは5~25mg/100mlのナトリウムおよび味覚認知閾値未満のアミノ酸が含まれるようにすることで、当該果汁飲料に高甘味度甘味料および低甘味度甘味料のみを添加した場合の甘味強度を超える甘味をもたらす。
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、
(c)50mg/100ml未満のナトリウム、および
(d)甘味強度X4相当の量の低甘味度甘味料
を含有させることを特徴とする、果汁飲料の甘味強度を増強する方法が提供される。
本態様の増強方法によれば、果汁飲料の甘味を増強し、単に果汁飲料に成分(d)を添加したときの甘味強度を超える甘味を奏する果汁飲料を提供することができる。具体的には、所定量の低甘味度甘味料を含む果汁飲料に、ナトリウム(またはナトリウム源)とアミノ酸を同時または別々に添加して、添加後に当該果汁飲料中に50mg/100ml未満、0.1~40mg/100ml、1~30mg/100mlまたは5~25mg/100mlのナトリウムおよび味覚認知閾値未満のアミノ酸が含まれるようにすることで、当該果汁飲料に低甘味度甘味料のみを添加した場合の甘味強度を超える甘味をもたらす。この態様においても、添加するナトリウム(またはナトリウム源)の量は、上記項目「1.甘味が増大された果汁飲料」の第B1の態様で述べた量から選択することができる。また、添加するアミノ酸またはその誘導体もしくはその塩の種類および量は、上記項目「1.甘味が増大された果汁飲料」の第B1の態様で述べた果汁飲料中のアミノ酸またはその誘導体もしくはその塩の種類および含有量となるように選択することができる。例えば、グリシン、アラニン、バリン、イソロイシン、ロイシン、セリン、スレオニン、グルタミン、アスパラギン、アルギニン、リジン、ヒスチジンおよびその組合せから選択されるアミノ酸を、上記項目「1.甘味が増大された果汁飲料」の第B1の態様に記載された量となるように果汁飲料に添加してもよい。
《第4および第A4の態様》
本発明は、第4の態様として、以下の果汁飲料を提供するための濃縮物(以下、「本発明の濃縮物」という)を提供する。
(a)甘味強度X1相当の量の高甘味度甘味料、および
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩
を含み、
前記成分(a)および(b)により甘味強度X3の甘味を呈し、0.1<X1<X3である、果汁飲料。本態様において、X1とX3はそれぞれ後述の第A4の態様(特願2020-147848/2020-185335に対応)のXaおよびXbに相当する。
(a)甘味強度Xa相当の量の高甘味度甘味料、および
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩
を含み、
前記成分(a)および(b)により甘味強度Xbの甘味を呈し、0.1<Xa<Xbである、果汁飲料。
(a)甘味強度Xaa相当の量の高甘味度甘味料、および
(b)味覚認知閾値の10倍未満のアミノ酸またはその誘導体もしくはその塩
を含む、上記の果汁飲料を提供するための濃縮物が提供される。
(a)甘味強度Xaa相当の量の高甘味度甘味料、および
(b)味覚認知閾値の5倍未満のアミノ酸またはその誘導体もしくはその塩
を含み、
前記成分(a)および(b)により甘味強度Xbaの甘味を呈し、0.5<Xaa<Xba、好ましく1. 0<Xaa<Xba、より好ましくは2.0<Xaa<Xbaである。
(a)甘味強度Xab相当の量の高甘味度甘味料、および
(b)味覚認知閾値の10倍未満のアミノ酸またはその誘導体もしくはその塩
を含み、
前記成分(a)および(b)により甘味強度Xbbの甘味を呈し、1.0<Xab<Xbb、好ましく2. 0<Xab<Xbb、より好ましくは4.0<Xab<Xbbである。
(a)甘味強度Xaa相当の量の高甘味度甘味料、
(b)味覚認知閾値の5倍未満のアミノ酸またはその誘導体もしくはその塩、および
(c)甘味強度Xca相当の量の低甘味度甘味料
を含み、
前記成分(a)~(c)により甘味強度Xdaの甘味を呈し、0.5<Xaa+Xca<Xda、好ましく1.0<Xaa+Xca<Xda、より好ましくは2.0<Xaa+Xca<Xdaである。
(a)甘味強度Xaa相当の量の高甘味度甘味料、
(b)味覚認知閾値の10倍未満のアミノ酸またはその誘導体もしくはその塩、および
(c)甘味強度Xca相当の量の低甘味度甘味料
を含み、
前記成分(a)~(c)により甘味強度Xdaの甘味を呈し、1.0<Xaa+Xca<Xda、好ましく2.0<Xaa+Xca<Xda、より好ましくは4.0<Xaa+Xca<Xdaである。
本発明は、第B4の態様として、以下の果汁飲料を提供するための濃縮物(以下、「本発明の濃縮物B」ともいう)を提供する。
(a)甘味強度X1相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、および
(c)50mg/100ml未満のナトリウム
を含み、
前記成分(a)~(c)により甘味強度X2の甘味を呈し、0.1<X1<X2である、果汁飲料。
(a)甘味強度X1a相当の量の高甘味度甘味料、
(b)味覚認知閾値の10倍未満のアミノ酸またはその誘導体もしくはその塩、および
(c)500mg/100ml未満のナトリウム
を含む、上記の果汁飲料を提供するための濃縮物が提供される。
(a)甘味強度X1a相当の量の高甘味度甘味料、
(b)味覚認知閾値の5倍未満のアミノ酸またはその誘導体もしくはその塩、および
(c)250mg/100ml未満のナトリウム
を含み、
前記成分(a)~(c)により甘味強度X2aの甘味を呈し、0.5<X1a<X2a、好ましくは1.0<X1a<X2a、より好ましくは2.0<X1a<X2aである。
(a)甘味強度X1b相当の量の高甘味度甘味料、
(b)味覚認知閾値の10倍未満のアミノ酸またはその誘導体もしくはその塩、および
(c)500mg/100ml未満のナトリウム
を含み、
前記成分(a)~(c)により甘味強度X2bの甘味を呈し、1.0<X1b<X2b、好ましくは2.0<X1b<X2b、より好ましくは4.0<X1b<X2bである。
(a)甘味強度X1a相当の量の高甘味度甘味料、
(b)味覚認知閾値の5倍未満のアミノ酸またはその誘導体もしくはその塩、
(c)250mg/100ml未満のナトリウム、および
(d)甘味強度X4a相当の量の低甘味度甘味料
を含み、
前記成分(a)~(d)により甘味強度X5aの甘味を呈し、0.5<X1a+X4a<X5a、好ましくは1.0<X1a+X4a<X5a、より好ましくは2.0<X1a+X4a<X5aである。
(a)甘味強度X1a相当の量の高甘味度甘味料、
(b)味覚認知閾値の10倍未満のアミノ酸またはその誘導体もしくはその塩、
(c)500mg/100ml未満のナトリウム、および
(d)甘味強度X4a相当の量の低甘味度甘味料
を含み、
前記成分(a)~(d)により甘味強度X5aの甘味を呈し、1.0<X1a+X4a<X5a、好ましくは2.0<X1a+X4a<X5a、より好ましくは4.0<X1a+X4a<X5aである。
DL-アラニン(純度98%以上)、L-セリン(純度98.5%以上)、グリシン(純度98. 5%以上)、L-アルギニン(純度98.5%以上)、L-グルタミン酸(純度99%以上)、L-バリン(純度98%以上)およびL-グルタミン(純度98%以上)について、純水を用いて下記表2の濃度の水溶液を調製した。各サンプルは水とアミノ酸のみを含んでいた。これらのサンプルを、官能に関して訓練を受けた者(5~6名)がパネラーとなって下記の基準で評価した。
評価基準
◎:水以外の味を感じない
○:水とは異なるが味を特定できない
△:味を感じる
×:非常に強い味を感じる
複数のアミノ酸またはその塩について、参考例1と同じ方法で、味覚認知閾値の実測を行った。L-ロイシン(純度98.0%以上)、L-スレオニン(純度98.0%以上)、L-プロリン(純度98.0%以上)、L-アスパラギン(純度99.0%以上)およびL-リジン塩酸塩(純度98.0%以上)について、純水を用いて下記表4の濃度の水溶液を調製した。各サンプルは水とアミノ酸またはその塩のみを含んでいた。これらのサンプルを、官能に関して訓練を受けた者(6~7名)がパネラーとなって下記の基準で評価した。
評価基準
◎:水以外の味を感じない
○:水とは異なるが味を特定できない
△:味を感じる
×:非常に強い味を感じる
まず、アミノ酸の測定方法を示す。
アルギニン、リジン、ヒスチジン、フェニルアラニン、チロシン、ロイシン、イソロイシン、バリン、アラニン、グリシン、プロリン、グルタミン酸、セリン、スレオニン、アスパラギン酸、シスチンおよびメチオニンの17種のアミノ酸については、サンプルに10%スルホサリチル酸溶液を添加して抽出を行い、次いで、3mol/l水酸化ナトリウム溶液を添加してpHを2.2に調整し、次いでクエン酸ナトリウム緩衝液(pH2.2)を添加して定容し、ろ過した後、適宜希釈を行い、試験溶液を調整する。試験溶液は、希釈倍率や測定するアミノ酸の種類に応じて、下記の2つの条件で測定することができる。
条件1
機種:L-8900形高速アミノ酸分析計(株式会社日立ハイテクノロジーズ製)
カラム:日立カスタムイオン交換樹脂、Φ4.6mm×60mm
(株式会社日立ハイテクノロジーズ製)
移動相:生体液分析法用緩衝液 PF KANTO(PF-1~PF-4)(関東化学株式会社)
反応液:日立用ニンヒドリン発色溶液キット(富士フイルム和光純薬株式会社)
流量:移動相0.35ml/min、反応液0.30ml/min
測定波長:570nm(プロリンを除く16種)、440nm(プロリン)
条件2
機種:JLC-500/V2(日本電子株式会社製)
カラム:LCR-6、Φ4mm×120mm(日本電子株式会社製)
移動相:クエン酸ナトリウム緩衝液(H-01~H-04) (日本電子株式会社)
反応液:日本電子用ニンヒドリン発色溶液キット-II
(富士フイルム和光純薬株式会社)
流量:移動相0.42ml/min、反応液0.22ml/min
測定波長:570nm(プロリンを除く16種)、440nm(プロリン)
トリプトファンについては、上記17種と同様にして試験溶液を調整し、3mol/l水酸化ナトリウム水溶液で微アルカリに調整し、定容した後、高速液体クロマトグラフィー(LC-20AD、株式会社島津製作所製)で測定する。測定条件は、以下の通りである。
検出器:蛍光分光光度計RF-20AXS(株式会社島津製作所製)
カラム:CAPCELL PAK C18 AQ、Φ4.6mm×250mm(株式会社大阪ソーダ製)
移動相:20mmol/l過塩素酸及びメタノールの混液(80:20)
流量:0.7ml/min
蛍光励起波長:285nm
蛍光測定波長:348nm
カラム温度:40℃
実験方法
飲料のベースに用いたカシス希釈果汁(果汁率:6%)と、オレンジ希釈果汁(果汁率:12%)に含まれるアミノ酸(アルギニン、リジン、ヒスチジン、フェニルアラニン、チロシン、ロイシン、イソロイシン、バリン、アラニン、グリシン、プロリン、グルタミン酸、セリン、スレオニン、アスパラギン酸、シスチン、メチオニンおよびトリプトファンの18種)の含有量は、希釈前の濃縮果汁に含まれるアミノ酸を公知の方法によりアミノ酸自動分析法(トリプトファンについては高速液体クロマトグラフィー)を用いて分析機関にて測定し、その測定値を基に算出した。カシス希釈果汁(果汁率:6%)に含まれる上記の18種のアミノ酸の含有量は、いずれも1.0mg/100g未満であった。オレンジ希釈果汁(果汁率:12%)に含まれる上記の18種のアミノ酸の含有量は、アルギニンが約9.0mg/100g、アラニンが約1.7mg/100g、プロリンが約15.7mg/100g、グルタミン酸が約2.4mg/100g、セリンが約2.9mg/100g、アスパラギン酸が約6.0mg/100gであった以外は、いずれも1.0mg/100g未満であった。
なお、表6および7における飲料中のナトリウム含有量はSpectrAA240FS(アジレント・テクノロジー社製)を用いた原子吸光法により測定し、アラニン含有量は上述した条件の下アミノ酸自動分析法を用いて分析機関にて測定し、エネルギー(kcal/100ml)は、酸味料、ビタミンC、色素、RebDおよびナトリウム由来の成分のエネルギーを0(kcal/100ml)として算出した。Brix(可溶性固形分量)は株式会社アタゴ社製のデジタル屈折計により試料の屈折率を求め、この値に相当するショ糖液の重量%に換算して算出した。
まず、各パネラーが日頃の訓練により備えている共通の味質判断基準に基づき、各飲料サンプルについて、味質ごとの「官能評価スコア」を算出した。
「官能評価スコア」は、例A1および例B1(それぞれの果汁飲料サンプルにおける対照サンプル)の味質の程度を「0」(基準)として、-3.0~+3.0の範囲で対照サンプルとの味質の違いを数値化したものである。「官能評価スコア」の各項目の基準としては以下のとおりである。
(官能評価スコア)
・「+3.0」:対照サンプルと比べて、対象となる味質が非常に強いと感じる。
・「+2.0」:対照サンプルと比べて、対象となる味質が強いと感じる。
・「+1.0」:対照サンプルと比べて、対象となる味質がやや強いと感じる。
・「0」 :対象となる味質が、対照サンプルと同じである。
・「-1.0」:対照サンプルと比べて、対象となる味質がやや弱いと感じる。
・「-2.0」:対照サンプルと比べて、対象となる味質が弱いと感じる。
・「-3.0」:対照サンプルと比べて、対象となる味質が非常に弱いと感じる。
実験方法
実施例1と同様に、下記の表11および12に示した比率で天然糖{スクロース(太平洋製糖株式会社製)、グルコース(昭和産業株式会社製)}、レバウジオシドD(RebD)(純度95%以上)、グルコン酸ナトリウム(純度98%以上)、L-セリン(純度98.5%以上)およびグリシン(純度98.5%以上)をカシス希釈果汁(果汁率:6%、ナトリウム含有量:0(mg/100ml)、エネルギー:2.0(kcal/100ml))またはオレンジ希釈果汁(果汁率:12%、ナトリウム含有量:0(mg/100ml)、エネルギー:5.28(kcal/100ml))に溶解して飲料サンプルを調製した。カシス希釈果汁には酸味料、ビタミンCおよび色素も添加した。また、例C1とD1はアミノ酸もナトリウムも添加していない対照サンプルである。上記の「0mg/100ml」は定量下限である1.0mg/100g未満であることを意味する。
なお、表11および12における飲料中のナトリウム含有量はSpectrAA240FS(アジレント・テクノロジー社製)を用いた原子吸光法により測定し、セリンおよびグリシンの含有量は上述した条件の下アミノ酸自動分析法を用いて分析機関にて測定し、エネルギー(kcal/100ml)は、酸味料、ビタミンC、色素、RebDおよびナトリウム由来の成分のエネルギーを0(kcal/100ml)として算出した。Brix(可溶性固形分量)は株式会社アタゴ社製のデジタル屈折計により試料の屈折率を求め、この値に相当するショ糖液の重量%に換算して算出した。
まず、各パネラーが日頃の訓練により備えている共通の味質判断基準に基づき、各飲料サンプルについて、味質ごとの「官能評価スコア」を算出した。
実験方法
実施例1と同様に、下記の表15および16に示した比率で天然糖{スクロース(太平洋製糖株式会社製)、グルコース(昭和産業株式会社製)}、レバウジオシドD(RebD)(純度95%以上)、グルコン酸ナトリウム(純度98%以上)およびDL-アラニン(純度98%以上)をカシス希釈果汁またはオレンジ希釈果汁に溶解して、飲料サンプルを調製した。本実施例では、カシス希釈果汁(果汁率:30%、ナトリウム含有量:2.5(mg/100ml)、エネルギー:13.5(kcal/100ml)と果汁率:50%、ナトリウム含有量:3.9(mg/100ml)、エネルギー:22.6(kcal/100ml))を使用した。またはオレンジ希釈果汁(果汁率:30%、ナトリウム含有量:0(mg/100ml)、エネルギー:16.0(kcal/100ml)と果汁率:50%、ナトリウム含有量:1.11(mg/100ml)、エネルギー:26.1(kcal/100ml))を使用した。カシス希釈果汁には酸味料、ビタミンCおよび色素も添加した。また、例E1とE4およびF1とF4はアラニンもナトリウムも添加していない対照サンプルである。ベースとなる飲料に含まれるナトリウム含有量は、SpectrAA240FS(アジレント・テクノロジー社製)を用いた原子吸光法により測定した。上記の「0mg/100ml」は定量下限である1.0mg/100g未満であることを意味する。
まず、各パネラーが日頃の訓練により備えている共通の味質判断基準に基づき、各飲料サンプルについて、味質ごとの「官能評価スコア」を算出した。
実験方法
実施例1と同様に、下記の表19~21に示した比率で天然糖{スクロース(太平洋製糖株式会社製)、グルコース(昭和産業株式会社製)}、レバウジオシドD(RebD)(純度95%以上)、レバウジオシドA(RebA)(純度99%以上)、レバウジオシドM(RebM)(純度98%)、モグロシドV(MogV)(純度97.7%)、羅漢果抽出物(40重量%モグロシドVを含有する羅漢果果実の水抽出物)、グルコン酸ナトリウム(純度98%以上)、およびDL-アラニン(純度98%以上)を実施例1と同様のオレンジ希釈果汁(果汁率:12%、ナトリウム含有量:0(mg/100ml)、エネルギー:5.28(kcal/100ml))に溶解して、飲料サンプルを調製した。例G1、H1、I1、J1、K1およびL1はアミノ酸もナトリウムも添加していない対照サンプルである。
なお、表19~21における飲料中のナトリウム含有量は、グルコン酸ナトリウムの添加量から算出した。また、遊離アラニン含有量は、アラニン添加量から算出した。なお、ベースの果汁飲料の遊離アラニン含有量は測定下限値(1.0mg/100g)付近であったため、本実施例ではベースの果汁飲料に含まれる遊離アラニン量は、本実施例ではゼロとして計算した。エネルギー(kcal/100ml)は、高甘味度甘味料およびナトリウム由来の成分のエネルギーを0(kcal/100ml)として算出した。Brix(可溶性固形分量)は株式会社アタゴ社製のデジタル屈折計により試料の屈折率を求め、この値に相当するショ糖液の重量%に換算して算出した。
まず、各パネラーが日頃の訓練により備えている共通の味質判断基準に基づき、各飲料サンプルについて、味質ごとの「官能評価スコア」を算出した。
実験方法
実施例1と同様に、下記の表25に示した比率で、レバウジオシドD(RebD)(純度95%以上)、グルコン酸ナトリウム(純度98%以上)、およびDL-アラニン(純度98%以上)を実施例1と同様のオレンジ希釈果汁(果汁率:12%、ナトリウム含有量:0(mg/100ml)、エネルギー:5.28(kcal/100ml))に溶解して、飲料サンプルを調製した。例M1はアミノ酸もナトリウムも添加していない対照サンプルである。
なお、表25における飲料中のナトリウム含有量は、グルコン酸ナトリウムの添加量から算出した。また、遊離アラニン含有量は、アラニン添加量から算出した。なお、ベースの果汁飲料の遊離アラニン含有量は測定下限値(1.0mg/100g)付近であったため、本実施例ではベースの果汁飲料に含まれる遊離アラニン量は、本実施例ではゼロとして計算した。エネルギー(kcal/100ml)は、高甘味度甘味料およびナトリウム由来の成分のエネルギーを0(kcal/100ml)として算出した。Brix(可溶性固形分量)は株式会社アタゴ社製のデジタル屈折計により試料の屈折率を求め、この値に相当するショ糖液の重量%に換算して算出した。
まず、各パネラーが日頃の訓練により備えている共通の味質判断基準に基づき、各飲料サンプルについて、味質ごとの「官能評価スコア」を算出した。
実験方法
実施例1と同様に、下記の表27に示した比率で天然糖{スクロース(太平洋製糖株式会社製)、グルコース(昭和産業株式会社製)}、レバウジオシドD(RebD)(純度95%以上)、グルコン酸ナトリウム(純度98%以上)、およびDL-アラニン(純度98%以上)を実施例1と同様のオレンジ希釈果汁(果汁率:12%、ナトリウム含有量:0(mg/100ml)、エネルギー:5.28(kcal/100ml))に溶解して、飲料サンプルを調製した。例N1およびO1はアミノ酸もナトリウムも添加していない対照サンプルである。
なお、表27における飲料中のナトリウム含有量は、グルコン酸ナトリウムの添加量から算出した。また、遊離アラニン含有量は、アラニン添加量から算出した。なお、ベースの果汁飲料の遊離アラニン含有量は測定下限値(1.0mg/100g)付近であったため、本実施例ではベースの果汁飲料に含まれる遊離アラニン量は、本実施例ではゼロとして計算した。エネルギー(kcal/100ml)は、高甘味度甘味料およびナトリウム由来の成分のエネルギーを0(kcal/100ml)として算出した。Brix(可溶性固形分量)は株式会社アタゴ社製のデジタル屈折計により試料の屈折率を求め、この値に相当するショ糖液の重量%に換算して算出した。例N1~3のサンプル(低甘味強度)に含まれる高甘味度甘味料と低甘味度甘味料の甘味強度の合計(X1+X4)は5.608であり、例O1~3のサンプル(高甘味強度)に含まれる高甘味度甘味料と低甘味度甘味料の甘味強度の合計(X1+X4)は17.540であった。
まず、各パネラーが日頃の訓練により備えている共通の味質判断基準に基づき、各飲料サンプルについて、味質ごとの「官能評価スコア」を算出した。
Claims (19)
- (a)甘味強度X1相当の量の高甘味度甘味料、および
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩
を含み、
前記成分(a)および(b)により甘味強度X3の甘味を呈し、0.1<X1<X3である、果汁飲料。 - (a)甘味強度X1相当の量の高甘味度甘味料、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩、および
(c)50mg/100ml未満のナトリウム
を含み、
前記成分(a)~(c)により甘味強度X2の甘味を呈し、0.1<X1<X2である、果汁飲料。 - 低甘味度甘味料をさらに含む、請求項1または2に記載の果汁飲料。
- 前記アミノ酸が、塩基性アミノ酸および側鎖にアルキル基、OH基またはアミド基を有する中性アミノ酸ならびにその組合せから選択されるアミノ酸を含む、請求項1~3のいずれか一項に記載の果汁飲料。
- 前記アミノ酸が、分子量70~260のアミノ酸から選択される1種以上である、請求項1~4のいずれか一項に記載の果汁飲料。
- 前記アミノ酸が、グリシン、アラニン、バリン、イソロイシン、ロイシン、セリン、スレオニン、グルタミン、アスパラギン、アルギニン、リジン、ヒスチジンおよびその組合せから選択されるアミノ酸を含む、請求項1~5のいずれか一項に記載の果汁飲料。
- エネルギーが50Kcal/100ml以下である、請求項1~6のいずれか一項に記載の果汁飲料。
- 前記低甘味度甘味料の甘味強度が0.1~5.9である、請求項3~7のいずれか一項に記載の果汁飲料。
- 前記果汁飲料の果汁率が1~100%、4~95%、5~80%、5~50%または5~30%である、請求項1~8のいずれか一項に記載の果汁飲料。
- 前記果汁飲料に含まれる果汁が、オレンジ、ミカン、レモン、グレープフルーツ、ライム、パイナップル、イチゴ、ラズベリー、ブルーベリー、カシス、クランベリー、ブルーベリー、グァバ、バナナ、アセロラ、パパイヤ、パッションフルーツ、マンゴー、リンゴ、ブドウ、桃、梅、梨、アンズ、スモモ、メロン、キウイフルーツ、花梨およびその組合せから選択される1種以上である、請求項1~9のいずれか一項に記載の果汁飲料。
- 前記低甘味度甘味料が、グルコース、スクロース、フルクトース、マルトース、オリゴ糖、異性化糖、乳糖、プシコース、アロース、タガトースおよびその組合せからなる群より選択される少なくとも1つを含む、請求項1~10のいずれか一項に記載の果汁飲料。
- 前記高甘味度甘味料が、ステビオール配糖体、羅漢果抽出物、モグロール配糖体、Thaumataococcus daniellii Benth植物含有甘味成分、Pentadiplandra brazzeana植物含有甘味成分、人工甘味料およびその組合せからなる群より選択される少なくとも1つを含む、請求項1~11のいずれか一項に記載の果汁飲料。
- 前記高甘味度甘味料が、レバウジオシドA、レバウジオシドB、レバウジオシドC、レバウジオシドD、レバウジオシドE、レバウジオシドF、レバウジオシドI、レバウジオシドJ、レバウジオシドK、レバウジオシドM、レバウジオシドN、レバウジオシドO、レバウジオシドQ、レバウジオシドR、ズルコシドA、ズルコシドC、ルブソシド、ステビオールモノシド、ステビオールビオシド、ステビオシド、羅漢果抽出物、モグロシドV、ソーマチン、ブラゼイン、カンゾウ抽出物、サッカリン、アスパルテーム、アセスルファムK、スクラロース、およびその組合せからなる群より選択される少なくとも1つを含む、請求項1~12のいずれか一項に記載の果汁飲料。
- アラニン、セリンおよびグリシンから選択される1つ以上のアミノ酸を含み、エネルギーが50Kcal/100ml以下、かつ前記高甘味度甘味料と前記低甘味度甘味料の甘味強度の合計が6以上である、請求項3~13のいずれか一項に記載の果汁飲料。
- 容器詰めされている、請求項1~14のいずれか一項に記載の果汁飲料。
- 原材料に対し、
(a)甘味強度X1の量の高甘味度甘味料を添加すること、および
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩を添加することを含む、請求項1および3~15のいずれか一項に記載の果汁飲料を製造する方法。 - 原材料に対し、
(a)甘味強度X1の量の高甘味度甘味料を添加すること、
(b)味覚認知閾値未満のアミノ酸またはその誘導体もしくはその塩を添加すること、
および
(c)飲料中のナトリウム含有量が50mg/100ml未満となるようにナトリウムを添加すること、
を含む、請求項2~16のいずれか一項に記載の果汁飲料を製造する方法。 - (a)甘味強度X1a相当の量の高甘味度甘味料、および
(b)味覚認知閾値の10倍未満のアミノ酸またはその誘導体もしくはその塩
を含む、請求項1および3~15のいずれか一項に記載の果汁飲料を提供するための濃縮物。 - (a)甘味強度X1a相当の量の高甘味度甘味料、
(b)味覚認知閾値の10倍未満のアミノ酸またはその誘導体もしくはその塩、および
(c)500mg/100ml未満のナトリウム
を含む、請求項2~18のいずれか一項に記載の果汁飲料を提供するための濃縮物。
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- 2021-09-01 EP EP21864383.1A patent/EP4209131A4/en active Pending
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CN116157022A (zh) | 2023-05-23 |
EP4209131A4 (en) | 2024-09-25 |
EP4209131A1 (en) | 2023-07-12 |
US20230389577A1 (en) | 2023-12-07 |
AU2021338038A1 (en) | 2023-04-20 |
JPWO2022050326A1 (ja) | 2022-03-10 |
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