WO2022016675A1 - 一种陶化剂、其制备方法及搅拌装置 - Google Patents

一种陶化剂、其制备方法及搅拌装置 Download PDF

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WO2022016675A1
WO2022016675A1 PCT/CN2020/113072 CN2020113072W WO2022016675A1 WO 2022016675 A1 WO2022016675 A1 WO 2022016675A1 CN 2020113072 W CN2020113072 W CN 2020113072W WO 2022016675 A1 WO2022016675 A1 WO 2022016675A1
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tank
stirring
main tank
pipe
main
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PCT/CN2020/113072
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English (en)
French (fr)
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毛金成
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苏州波菲特新材料科技有限公司
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
    • B01F27/92—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with helices or screws
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00—Other mixers; Mixing plants; Combinations of mixers
    • B01F33/40—Mixers using gas or liquid agitation, e.g. with air supply tubes
    • B01F33/406—Mixers using gas or liquid agitation, e.g. with air supply tubes in receptacles with gas supply only at the bottom
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/40—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates
    • C23C22/44—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates containing also fluorides or complex fluorides

Definitions

  • the invention relates to a potting agent, a preparation method thereof and a stirring device.
  • the ceramic process is sometimes called zirconium salt passivation process, nano-ceramic process, etc. It refers to the deposition of oxides of metals such as zirconium/titanium on the surface of materials to obtain a metal oxide coating similar to the surface of ceramics.
  • zirconium salt passivation process nano-ceramic process, etc. It refers to the deposition of oxides of metals such as zirconium/titanium on the surface of materials to obtain a metal oxide coating similar to the surface of ceramics.
  • this ceramizer is made up of following weight ratio composition:
  • the invention also discloses a preparation method of the potting agent
  • Step 1 deionized water is poured into each tank of stirring device, and each component is poured into each tank separately and mixes; Wherein, sodium molybdate and sodium gluconate are mixed in the same tank;
  • Step 2 after the main tank is stirred for 15-20 minutes, open the tank containing sodium fluoride, and inject the sodium fluoride solution into the main tank;
  • Step 3 the main tank is operated again for 10-15 minutes, the tank containing ammonium molybdate is opened, and the ammonium molybdate solution is injected into the main tank;
  • Step 4 the main tank is run for 10-15 minutes again, the tank containing citric acid is opened, and the citric acid solution is injected into the main tank;
  • Step 5 the main tank runs again for 10-15 minutes, open the tank containing sodium molybdate and sodium gluconate, and inject the sodium molybdate and sodium gluconate solutions into the main tank; the main tank continues to stir for 40-50 minutes to obtain a pottery.
  • the invention also discloses a pottery stirring device, comprising a main tank body, a sub-tank body, a water pump, a first stirring mechanism, a second stirring mechanism and a third stirring mechanism.
  • the first stirring mechanism, the second stirring mechanism for stirring is arranged in the sub-tank, the water pump and the third stirring mechanism are arranged on the main tank through pipelines, and are connected with the main tank.
  • the sub-tank body forms a circulation loop; the sub-tank body is connected between the water pump and the third stirring mechanism through a pipeline, the sub-tank body includes a main body and a sealing cover, and the upper end of the main body is provided with an air inlet and a feed The air inlet is connected to the air source, and the sealing cover is sealed and arranged on the feed port.
  • the first stirring mechanism includes a motor, a rotating shaft and a blade, the rotating shaft is rotatably arranged in the main tank, the blade is arranged around the circumference of the rotating shaft, and the motor is arranged on the On the top of the main tank, the motor is used to drive the rotating shaft to drive the blades to rotate.
  • the second stirring mechanism includes an air compressor and an air inlet pipe
  • the air inlet pipe is arranged at the bottom of the sub-tank and is connected with the air compressor
  • the air inlet pipe has several air holes, and uses all the air holes.
  • the air compressor feeds the gas into the air intake pipe, and discharges the gas from the air hole.
  • the third stirring mechanism includes a shell, an installation block and a mixing pipe, an installation cavity for installing the installation block is arranged in the casing, and a plurality of penetrating installation pipes are arranged on the installation block. It is arranged in the installation pipe, and the two ends of the casing are respectively provided with a liquid inlet and a liquid outlet.
  • the mixing pipe includes a pipe and several superimposed stirring units, the stirring units are in a spiral shape, and the lower end of one stirring unit and the upper end of the other stirring unit are perpendicular to each other.
  • a positioning block is arranged on the side wall of the mixing pipe, and a positioning groove is arranged on the inner wall of the installation pipe to cooperate with the positioning block.
  • liquid outlet end of the third stirring mechanism is connected to a three-way valve, one end of the three-way valve is connected to the main tank body, and the other end is a liquid discharge port.
  • a liquid inlet pipe which includes a main pipe and a sub-pipe axially arranged in the main pipe; the liquid inlet of the liquid inlet pipe is connected to the three-way valve, and the liquid outlet is connected to the The main tank is connected, and the liquid inlet direction is tangent to the main tank.
  • the corrosion inhibition effect of sodium molybdate is added to avoid excessive reaction of the workpiece in acid to affect the size of the workpiece; at the same time, sodium gluconate is added to reduce the usage amount of sodium molybdate to reduce toxicity.
  • the third stirring mechanism is composed of forehead stirring units with a spiral structure, which cuts and mixes the solution to realize the stirring of the solution; the whole solution is in an active state, which further promotes the dissolution of the solution; the first stirring mechanism promotes the solution in the main tank clockwise. While rotating, the solution entering the main tank through the third stirring mechanism rotates counterclockwise, and the two solutions collide with each other, further promoting the solution solution.
  • Fig. 1 is the three-dimensional structure schematic diagram of a kind of stirring device of the present invention
  • Fig. 2 is the structural representation of sub-tank
  • FIG. 3 is a schematic diagram of the internal structure of the sub-tank
  • Fig. 4 is the structural representation of the first stirring mechanism
  • Fig. 5 is the structural representation of the second stirring mechanism
  • Fig. 6 is the structural representation of the third stirring mechanism
  • Fig. 7 is the internal structure schematic diagram of Fig. 6;
  • Fig. 8 is the structural representation of shell
  • Fig. 10 is the structural representation of the installation block
  • Fig. 11 is the structural representation of the mixing pipe
  • Fig. 12 is the structural representation of the liquid inlet pipe
  • Main tank 1. Main tank, 2. Sub-tank, 3. Water pump, 4. First stirring mechanism, 5. Air inlet pipe, 6. Third stirring mechanism, 7. Liquid inlet pipe, 21, Main body, 22, Sealing cover, 41, motor, 42, rotating shaft, 43, vane, 61, housing, 62, mounting block, 63, mixing pipe, 64, three-way valve, 71, main pipe, 72, sub-pipe, 611, mounting cavity, 612 , housing, 613, sealing strip, 614, outer cover, 615, sealing groove, 616, sealing flange, 621, installation pipe, 631, pipe body, 632, stirring unit, 633, positioning block, 211, air inlet, 212. Feed inlet.
  • a kind of preparation method of ceramizer is made up of following weight ratio components:
  • Step 1 pour deionized water into each tank of the stirring device, and pour each component into each tank separately for mixing; wherein, sodium molybdate and sodium gluconate are mixed in the same tank;
  • Step 2 when the main tank is stirred and operated for 15 minutes, open the tank containing sodium fluoride, and inject the sodium fluoride solution into the main tank;
  • Step 3 the main tank is operated again for 10 minutes, the tank containing ammonium molybdate is opened, and the ammonium molybdate solution is injected into the main tank;
  • Step 4 the main tank is run for 10 minutes again, the tank containing citric acid is opened, and the citric acid solution is injected into the main tank;
  • step 5 the main tank is operated for 10 minutes again, the tank containing sodium molybdate and sodium gluconate is opened, and the sodium molybdate and sodium gluconate solutions are injected into the main tank; the main tank continues to stir for 40 minutes to obtain Ceramics.
  • ceramizer this ceramizer is made up of the following components by weight:
  • Step 1 pour deionized water into each tank of the stirring device, and pour each component into each tank separately for mixing; wherein, sodium molybdate and sodium gluconate are mixed in the same tank;
  • Step 2 when the main tank is stirred and operated for 15 minutes, open the tank containing sodium fluoride, and inject the sodium fluoride solution into the main tank;
  • Step 3 the main tank is operated again for 10 minutes, the tank containing ammonium molybdate is opened, and the ammonium molybdate solution is injected into the main tank;
  • Step 4 the main tank is run for 10 minutes again, the tank containing citric acid is opened, and the citric acid solution is injected into the main tank;
  • Step 5 the main tank is operated again for 10 minutes, the tank containing sodium molybdate and sodium gluconate is opened, and the sodium molybdate and sodium gluconate solutions are injected into the main tank; the main tank continues to stir for 50 minutes to obtain Ceramics.
  • ceramizer this ceramizer is made up of the following components by weight:
  • Step 1 pour deionized water into each tank of the stirring device, and pour each component into each tank separately for mixing; wherein, sodium molybdate and sodium gluconate are mixed in the same tank;
  • Step 2 when the main tank is stirred and operated for 18 minutes, open the tank containing sodium fluoride, and inject the sodium fluoride solution into the main tank;
  • Step 3 the main tank is run for 18 minutes again, the tank containing ammonium molybdate is opened, and the ammonium molybdate solution is injected into the main tank;
  • Step 4 the main tank is operated again for 18 minutes, the tank containing citric acid is opened, and the citric acid solution is injected into the main tank;
  • step 5 the main tank was operated again for 18 minutes, the tank containing sodium molybdate and sodium gluconate was opened, and the sodium molybdate and sodium gluconate solutions were injected into the main tank; the main tank continued to stir for 45 minutes to obtain Ceramics.
  • ceramizer this ceramizer is made up of the following components by weight:
  • Step 1 pour deionized water into each tank of the stirring device, and pour each component into each tank separately for mixing; wherein, sodium molybdate and sodium gluconate are mixed in the same tank;
  • Step 2 when the main tank is stirred and operated for 18 minutes, open the tank containing sodium fluoride, and inject the sodium fluoride solution into the main tank;
  • Step 3 the main tank is run for 18 minutes again, the tank containing ammonium molybdate is opened, and the ammonium molybdate solution is injected into the main tank;
  • Step 4 the main tank is operated again for 18 minutes, the tank containing citric acid is opened, and the citric acid solution is injected into the main tank;
  • Step 5 the main tank is operated for 18 minutes again, the tank containing sodium molybdate and sodium gluconate is opened, and the sodium molybdate and sodium gluconate solutions are injected into the main tank; the main tank continues to stir for 50 minutes to obtain Ceramics.
  • ceramizer this ceramizer is made up of the following components by weight:
  • Step 1 pour deionized water into each tank of the stirring device, and pour each component into each tank separately for mixing; wherein, sodium molybdate and sodium gluconate are mixed in the same tank;
  • Step 2 when the main tank is stirred and operated for 20 minutes, open the tank containing sodium fluoride, and inject the sodium fluoride solution into the main tank;
  • Step 3 the main tank is run for 15 minutes again, the tank containing ammonium molybdate is opened, and the ammonium molybdate solution is injected into the main tank;
  • Step 4 the main tank is operated again for 15 minutes, the tank containing the citric acid is opened, and the citric acid solution is injected into the main tank;
  • Step 5 the main tank is operated again for 15 minutes, the tank containing sodium molybdate and sodium gluconate is opened, and the sodium molybdate and sodium gluconate solutions are injected into the main tank; the main tank continues to stir for 50 minutes to obtain Ceramics.
  • the invention also discloses a stirring device for producing the ceramic agent of the invention; as shown in Figures 1-3, specifically:
  • the stirring device includes a main tank 1, a sub-tank 2, a water pump 3, a first stirring mechanism 4, a second stirring mechanism and a third stirring mechanism 6.
  • the main tank 1 is provided with a first stirring mechanism 4 for stirring.
  • the tank body 2 is provided with a second stirring mechanism for stirring, and the main tank body 1 is provided with a liquid outlet and a liquid inlet. liquid port.
  • the liquid in the main tank body 1 is pumped out by the water pump 3 and stirred by the third stirring mechanism 6 and then returned to the main tank body 1 .
  • a liquid outlet is set on the sub-tank 2, and the liquid outlet is connected between the water pump 3 and the third stirring mechanism 6 through a pipeline; and a valve is set at the liquid outlet to control the opening or closing of the liquid outlet.
  • the sub-tank 2 includes a main body 21 and a sealing cover 22.
  • the top of the main body 21 is provided with an air inlet 211 and a feeding port 212.
  • the sealing cover 22 is sealed at the feeding port 212.
  • the air inlet 211 is connected to the air source.
  • the liquid outlet valve is opened, and the gas source sends the gas into the sub-tank 2 through the air inlet 211, and then the solution in the sub-tank 2 is discharged and mixed.
  • the solution in the circuit of the main tank 1 enters the third stirring mechanism 6 for mixing at the same time. It can adjust the discharge speed of the solution in the sub-tank 2 by controlling the air pressure in the sub-tank 2 .
  • the liquid outlet of the sub-tank 2 is also provided with a one-way valve (not shown);
  • the number of sub-tanks 2 is set according to actual needs, that is, in the preparation of the potting agent of the present invention, four sub-tanks 2 need to be arranged to dissolve each component respectively; of course, only one sub-tank 2 may be provided. , when one component is added, the other components are mixed in the same sub-tank 2.
  • the first stirring mechanism 4 includes a motor 41 , a rotating shaft 42 and a blade 43 , the rotating shaft 42 is rotatably arranged in the main tank 1 , and the blade 43 is arranged around the rotating shaft 42 in the circumferential direction.
  • the motor 41 is arranged on the top of the main tank 1, and the motor 1 is used to drive the rotating shaft 42 to drive the blades 43 to rotate. Furthermore, the solution in the main tank 1 is mixed.
  • the second stirring mechanism includes an air compressor and an air intake pipe 5
  • the air intake pipe 5 is arranged at the bottom of the sub-tank 2, and is connected with the air compressor, and the air intake pipe has several air holes, The air is fed into the intake pipe by the air compressor, and the air is discharged from the air hole. Air bubbles are generated in the solution, and the solution is stirred by the air bubbles.
  • the sub-tank 2 is a closed container, the gas introduced by the second stirring mechanism is always stored in the sub-tank 2, and the pressure in the sub-tank 2 increases continuously. The pressure in the tank body 2 discharges the solution; when the pressure in the sub-tank body 2 is insufficient, the pressure is supplemented through the air inlet 211 to ensure the normal discharge of the subsequent solution.
  • the third stirring mechanism 6 includes a casing 61 , a mounting block 62 and a mixing pipe 63 , and a mounting cavity 611 for mounting the mounting block 62 is arranged in the casing 61 .
  • the mounting block 62 A plurality of installation pipes 621 penetrating therethrough are arranged on the top, the mixing pipes 63 are arranged in the installation pipes 621, and the two ends of the casing 61 are respectively provided with a liquid inlet and a liquid outlet.
  • the solution is pumped into the mixing pipe 63 from the liquid inlet through the water pump 3, and the solution is mixed through the mixing pipe and then discharged from the liquid outlet, and is guided back into the main tank 1 through the pipeline.
  • the mixing pipe 63 includes a pipe body 631 and several superimposed stirring units 632 .
  • the stirring units 632 are helical, and the lower end of one stirring unit 632 and the upper end of the other stirring unit 632 are perpendicular to each other. It can be seen that a stirring unit 632 cuts and rotates the solution and then passes through the next shift unit 632 to cut again, thereby realizing mixing of the solution.
  • the housing 61 includes an outer casing 612, a sealing strip 613 and an outer cover 614.
  • the installation cavity 611 is recessed in the outer casing 612.
  • the upper surface of the outer casing 612 has a concave sealing groove 615 around the periphery of the installation cavity 611, and at the corresponding position of the outer cover 614.
  • the sealing flange 616 matched with the sealing groove 615, the sealing strip 613 is arranged in the sealing groove,
  • a positioning block 633 is provided on the side wall of the mixing pipe 63 , and a positioning groove matched with the positioning block 633 is provided on the inner wall of the installation pipe 621 . During installation, the positioning block 633 is placed in the positioning groove to prevent the mixing pipe 63 from rotating.
  • the liquid outlet end of the third stirring mechanism 6 is connected to a three-way valve 64, and one end of the three-way valve 64 is connected to the three-way valve 64.
  • the main tank body 1 is connected, and the other end is a liquid discharge port 65 .
  • the three-way valve 64 is connected to the third stirring mechanism 6 and the main tank 1; when discharging, the three-way valve 64 is connected to the third stirring mechanism 6 and the liquid discharge port 65, and the main tank 1 is pumped through the water pump 3.
  • the liquid extracted is discharged from the liquid discharge port 65 through the third stirring mechanism 6 .
  • a liquid inlet pipe 7 is also included, and the liquid inlet pipe 7 includes a main pipe 71 and a sub-pipe 72 axially arranged in the 71 ; the main pipe 71 is provided with a liquid inlet, and the sub-pipe 72 is provided with Liquid outlet.
  • the liquid inlet of the liquid inlet pipe 7 is connected to the three-way valve 64 , the liquid outlet is connected to the main tank 1 , and the liquid inlet direction is tangential to the main tank 1 .
  • the liquid in the main tank 1 is stirred clockwise by the first stirring mechanism 4, so that the solution flows clockwise, and the solution discharged from the liquid outlet flows counterclockwise along the inner wall of the main tank 1, and the two solutions collide with each other. Improve solution mixing efficiency.

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Abstract

一种陶化剂、其制备方法及搅拌装置，陶化剂由下列成份组成：六氟锆酸10-15％；氟化钠0.5-1％；钼酸铵3-5％；钼酸钠2-3％；葡萄糖酸钠5-10％；柠檬酸10-15％；去离子水余量。通过钼酸钠的缓蚀效果，避免工件在酸中过度反应从而影响工件尺寸；同时添加葡萄糖酸钠，减少钼酸钠的使用量，以减少毒性。添加钼酸铵加快反应速度。并且配套设置搅拌装置，通过各组分单独加入混料，保证了各组分充分溶解。

Description

一种陶化剂、其制备方法及搅拌装置 技术领域
本发明涉及一种陶化剂、其制备方法及搅拌装置。
背景技术
陶化工艺有时又称锆盐钝化工艺、纳米陶瓷工艺等，是指以锆/钛等金属的氧化物在材料表面沉积，以获得类似陶瓷表面的金属氧化物涂层。近年来，陶化工艺作为最有希望代替传统高污染磷化钝化及铬酸盐钝化的技术之一获得了快速发展，已开始在金属表面处理中广泛应用。
发明内容
针对以上现有技术存在的缺陷，本发明的主要目的在于克服现有技术的不足之处，公开了一种陶化剂，其特征在于，该陶化剂由下列重量比例成份组成：
Figure PCTCN2020113072-appb-000001
本发明还公开了一种陶化剂的制备方法，
步骤一，将去离子水倒入搅拌装置的各罐体中，并且将各组分单独倒 入各罐体中进行混合；其中，钼酸钠与葡萄糖酸钠在同一罐体中混合；
步骤二，当主罐体搅拌运行15-20分钟后，打开装有氟化钠的罐体，将氟化钠溶液注入主罐体中；
步骤三，主罐体再次运行10-15分钟，打开装有钼酸铵的罐体，将钼酸铵溶液注入主罐体中；
步骤四，主罐体再次运行10-15分钟，打开装有柠檬酸的罐体，将柠檬酸溶液注入主罐体中；
步骤五，主罐体再次运行10-15分钟，打开装有钼酸钠和葡萄糖酸钠的罐体，将钼酸钠和葡萄糖酸钠溶液注入主罐体中；主罐体继续搅拌40-50分钟，制得陶化剂。
本发明还公开了一种陶化剂的搅拌装置，包括主罐体、子罐体、水泵、第一搅拌机构、第二搅拌机构和第三搅拌机构，所述主罐体内设置用于搅拌的所述第一搅拌机构，所述子罐体内设置用于搅拌的第二搅拌机构，所述水泵和所述第三搅拌机构通过管路设置在所述主罐体上，并且与所述主罐体形成循环回路；所述子罐体通过管路连接在所述水泵和所述第三搅拌机构之间，所述子罐体包括本体和密封盖，所述本体上端设置进气孔和进料口，所述进气孔与气源连接，所述密封盖密封设置在所述进料口上。
进一步地，所述第一搅拌机构包括电机、旋转轴和叶片，所述旋转轴转动设置在所述主罐体内，所述叶片环绕设置在所述旋转轴周向，所述电机设置在所述主罐体的顶部，利用所述电机驱动所述旋转轴以带动所述叶片转动。
进一步地，所述第二搅拌机构包括空气压缩机和进气管，所述进气管设置在所述子罐体底部，并且与所述空气压缩机连接，所述进气管具有若干个气孔，利用所述空气压缩机将气体送入所述进气管，从气孔将气体排出。
进一步地，第三搅拌机构包括壳体、安装块和混料管，所述壳体内设置安装所述安装块的安装腔，所述安装块上设置若干个贯穿的安装管，所 述混料管设置在所述安装管内，所述壳体的两端分别设置进液口与出液口。
进一步地，混料管包括管和若干个叠加的搅拌单元，所述搅拌单元呈螺旋状，一所述搅拌单元的下端与另一所述搅拌单元的上端相互垂直。
进一步地，所述混料管侧壁上设置定位块，所述安装管内壁设置与所述定位块配合的定位槽。
进一步地，所述第三搅拌机构的出液端连接三通阀门，所述三通阀门的一端与所述主罐体连接，另一端为排液口。
进一步地，还包括进液管，所述进液管包括主管和轴向排列在所述主管的子管；所述进液管的进液口与所述三通阀门连接，出液口与所述主罐体连接，并且进液方向与所述主罐体相切。
本发明取得的有益效果：
本发明通过添加钼酸钠的缓蚀效果，避免工件在酸中过度反应从而影响工件尺寸；同时添加葡萄糖酸钠，减少钼酸钠的使用量，以减少毒性。添加钼酸铵为反映或话题，加快反应速度。通过各组分单独加入混料，保证了各组分充分溶解。搅拌装置通过第一搅拌装置和第三搅拌装置对主罐体内溶液不断搅拌，利用第二搅拌装置是子罐体内溶液搅拌，溶液间的相互搅拌更加容易混合。第三搅拌机构采用螺旋结构的额搅拌单元叠加组成，对溶液切开混合，实现对溶液的搅拌；整个溶液均处于活动状态，进一步促进溶液的溶解；第一搅拌机构促进主罐体内溶液顺时针转动，同时通过第三搅拌机构进入主罐体的溶液逆时针转动，两股溶液相互撞击，进一步促进溶液溶液。
附图说明
图1为本发明一种搅拌装置的立体结构示意图；
图2为子罐体的结构示意图；
图3为子罐体的内部结构示意图；
图4为第一搅拌机构的结构示意图；
图5为第二搅拌机构的结构示意图；
图6为第三搅拌机构的结构示意图；
图7为图6的内部结构示意图；
图8为外壳的结构示意图；
图9为外盖的结构示意图；
图10为安装块的结构示意图；
图11为混料管的结构示意图；
图12为进液管的结构示意图；
附图标记如下：
1、主罐体，2、子罐体，3、水泵，4、第一搅拌机构，5、进气管，6、第三搅拌机构，7、进液管，21、本体，22、密封盖，41、电机，42、旋转轴，43、叶片，61、壳体，62、安装块，63、混料管，64、三通阀门，71、主管，72、子管，611、安装腔，612、外壳，613、密封条，614、外盖，615、密封槽，616、密封凸缘，621、安装管，631、管体，632、搅拌单元，633、定位块，211、进气口，212、进料口。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白，下面结合附图及实施例对本发明作进一步详细说明。应当理解，此处所描述的具体实施例仅用以解释本发明，并不用于限定本发明。
实施例1：
一种陶化剂的制备方法，由下列重量比例成份组成：
Figure PCTCN2020113072-appb-000002
Figure PCTCN2020113072-appb-000003
包括以下步骤：
步骤一，将去离子水倒入搅拌装置的各罐体中，并且将各组分单独倒入各罐体中进行混合；其中，钼酸钠与葡萄糖酸钠在同一罐体中混合；
步骤二，当主罐体搅拌运行15分钟后，打开装有氟化钠的罐体，将氟化钠溶液注入主罐体中；
步骤三，主罐体再次运行10分钟，打开装有钼酸铵的罐体，将钼酸铵溶液注入主罐体中；
步骤四，主罐体再次运行10分钟，打开装有柠檬酸的罐体，将柠檬酸溶液注入主罐体中；
步骤五，主罐体再次运行10分钟，打开装有钼酸钠和葡萄糖酸钠的罐体，将钼酸钠和葡萄糖酸钠溶液注入主罐体中；主罐体继续搅拌40分钟，制得陶化剂。
实施例2：
一种陶化剂，该陶化剂由下列重量比例成份组成：
Figure PCTCN2020113072-appb-000004
包括以下步骤：
步骤一，将去离子水倒入搅拌装置的各罐体中，并且将各组分单独倒入各罐体中进行混合；其中，钼酸钠与葡萄糖酸钠在同一罐体中混合；
步骤二，当主罐体搅拌运行15分钟后，打开装有氟化钠的罐体，将氟化钠溶液注入主罐体中；
步骤三，主罐体再次运行10分钟，打开装有钼酸铵的罐体，将钼酸铵溶液注入主罐体中；
步骤四，主罐体再次运行10分钟，打开装有柠檬酸的罐体，将柠檬酸溶液注入主罐体中；
步骤五，主罐体再次运行10分钟，打开装有钼酸钠和葡萄糖酸钠的罐体，将钼酸钠和葡萄糖酸钠溶液注入主罐体中；主罐体继续搅拌50分钟，制得陶化剂。
实施例3：
一种陶化剂，该陶化剂由下列重量比例成份组成：
Figure PCTCN2020113072-appb-000005
包括以下步骤：
步骤一，将去离子水倒入搅拌装置的各罐体中，并且将各组分单独倒入各罐体中进行混合；其中，钼酸钠与葡萄糖酸钠在同一罐体中混合；
步骤二，当主罐体搅拌运行18分钟后，打开装有氟化钠的罐体，将氟化钠溶液注入主罐体中；
步骤三，主罐体再次运行18分钟，打开装有钼酸铵的罐体，将钼酸铵溶液注入主罐体中；
步骤四，主罐体再次运行18分钟，打开装有柠檬酸的罐体，将柠檬酸溶液注入主罐体中；
步骤五，主罐体再次运行18分钟，打开装有钼酸钠和葡萄糖酸钠的罐体，将钼酸钠和葡萄糖酸钠溶液注入主罐体中；主罐体继续搅拌45分钟，制得陶化剂。
实施例4：
一种陶化剂，该陶化剂由下列重量比例成份组成：
Figure PCTCN2020113072-appb-000006
包括以下步骤：
步骤一，将去离子水倒入搅拌装置的各罐体中，并且将各组分单独倒入各罐体中进行混合；其中，钼酸钠与葡萄糖酸钠在同一罐体中混合；
步骤二，当主罐体搅拌运行18分钟后，打开装有氟化钠的罐体，将氟化钠溶液注入主罐体中；
步骤三，主罐体再次运行18分钟，打开装有钼酸铵的罐体，将钼酸铵溶液注入主罐体中；
步骤四，主罐体再次运行18分钟，打开装有柠檬酸的罐体，将柠檬酸溶液注入主罐体中；
步骤五，主罐体再次运行18分钟，打开装有钼酸钠和葡萄糖酸钠的罐体，将钼酸钠和葡萄糖酸钠溶液注入主罐体中；主罐体继续搅拌50分钟，制得陶化剂。
实施例5：
一种陶化剂，该陶化剂由下列重量比例成份组成：
Figure PCTCN2020113072-appb-000007
包括以下步骤：
步骤一，将去离子水倒入搅拌装置的各罐体中，并且将各组分单独倒入各罐体中进行混合；其中，钼酸钠与葡萄糖酸钠在同一罐体中混合；
步骤二，当主罐体搅拌运行20分钟后，打开装有氟化钠的罐体，将氟化钠溶液注入主罐体中；
步骤三，主罐体再次运行15分钟，打开装有钼酸铵的罐体，将钼酸铵溶液注入主罐体中；
步骤四，主罐体再次运行15分钟，打开装有柠檬酸的罐体，将柠檬酸溶液注入主罐体中；
步骤五，主罐体再次运行15分钟，打开装有钼酸钠和葡萄糖酸钠的罐体，将钼酸钠和葡萄糖酸钠溶液注入主罐体中；主罐体继续搅拌50分钟，制得陶化剂。
本发明还公开了一种搅拌装置，用于生产本发明的陶化剂；如图1-3 所示，具体的：
搅拌装置包括主罐体1、子罐体2、水泵3、第一搅拌机构4、第二搅拌机构和第三搅拌机构6，主罐体1内设置用于搅拌的第一搅拌机构4，子罐体2内设置用于搅拌的第二搅拌机构，主罐体1上设置出液口和进液口，其出液口通过管路一次连接水泵3和第三搅拌机构6，并且回流至进液口。通过水泵3将主罐体1内的液体抽出经过第三搅拌机构6搅拌后回入主罐体1内。子罐体2上设置出液口，该出液口通过管路连接在水泵3和第三搅拌机构6之间；并且在该出液口处设置阀门，以控制出液口的打开或者关闭。其中，子罐体2包括本体21和密封盖22，本体21顶部设置进气口211和进料口212，密封盖22密封设置在进料口212处；进气口211与气源连接。子罐体2内的液体通过第二搅拌机构搅拌完成后，打开出液口阀门，气源通过进气口211将气体送入子罐体2内，进而将子罐体2内的溶液排出与主罐体1回路内的溶液同时进入第三搅拌机构6混合。其能够通过控制子罐体2内的气压以调节子罐体2内溶液排出速度。优选的，子罐体2的出液口还设置单向阀(未示出)；以防止主罐体1回路内的溶液反灌入子罐体2内。其中，子罐体2的数量根据实际需求设置，即在本发明陶化剂的制备中，子罐体2需要设置四个子罐体2分别对各组分进行溶解；当然，也可以只设置一个，当一个组分添加后，在同一个子罐体2中进行其他组份的混合。
在一实施例中，如图4所示，第一搅拌机构4包括电机41、旋转轴42和叶片43，旋转轴42转动设置在主罐体1内，叶片43环绕设置在旋转轴42周向，电机41设置在主罐体1的顶部，利用电机1驱动旋转轴42以带动叶片43转动。进而对主罐体1内的溶液进行混料。
在一实施例中，如图5所示，第二搅拌机构包括空气压缩机和进气管5，进气管5设置在子罐体2底部，并且与空气压缩机连接，进气管具有若干个气孔，利用空气压缩机将气体送入进气管，从气孔将气体排出。在溶液中产生气泡，利用气泡对溶液进行搅拌。另外，由于子罐体2为密闭容器，由第二搅拌机构通入的气体始终储存于子罐体2内，子罐体2内的压力不 断增加，当出液口的阀门打开后，利用子罐体2内的压力将溶液排出；当子罐体2内压力不足时，通过进气孔211进行压力补充，以保证后续溶液正常排出。
在一实施例中，如图6-11所示，第三搅拌机构6包括壳体61、安装块62和混料管63，壳体61内设置安装安装块62的安装腔611，安装块62上设置若干个贯穿的安装管621，混料管63设置在安装管621内，壳体61的两端分别设置进液口与出液口。通过水泵3将溶液从进液口打入混料管63内，通过混料管对溶液混料后从出液口排出，经管路引导回入主罐体1内。其中，混料管63包括管体631和若干个叠加的搅拌单元632，搅拌单元632呈螺旋状，一搅拌单元632的下端与另一搅拌单元632的上端相互垂直。可见，一搅拌单元632将溶液分切旋转后通过下一个交班单元632再分切，进而实现对溶液的混料。壳体61包括外壳612、密封条613和外盖614，安装腔611凹设在所述外壳612内，外壳612上表面绕安装腔611周边凹设密封槽615，在并且在外盖614得对应位置与密封槽615配合的密封凸缘616，密封条613设置在密封槽内，
在上述实施例中，如图6-11所示，混料管63侧壁上设置定位块633，安装管621内壁设置与定位块633配合的定位槽。安装时，定位块633至于定位槽内，防止混料管63转动。
在一实施例中，如图6-11所示，为了方便将主罐体1内搅拌完毕的液体排出，第三搅拌机构6的出液端连接三通阀门64，三通阀门64的一端与主罐体1连接，另一端为排液口65。当搅拌时，三通阀门64连接第三搅拌机构6和主罐体1；当排料时，三通阀门64连接第三搅拌机构6和排液口65，通过水泵3将主罐体1内的液体抽出通过第三搅拌机构6从排液口65排出。
在一实施例中，如图12所示，还包括进液管7，进液管7包括主管71和轴向排列在71的子管72；主管71上设置进液口，子管72上设置出液口。进液管7的进液口与三通阀门64连接，出液口与主罐体1连接，并且进液方向与主罐体1相切。主罐体1内的液体通过第一搅拌机构4进行顺时针 搅拌，使得溶液顺时针流动，而从出液口排出的溶液顺着主罐体1的内壁逆时针流动，两股溶液相互撞击，提高溶液混料效率。
以上仅为本发明的较佳实施例，并非用来限定本发明的实施范围；如果不脱离本发明的精神和范围，对本发明进行修改或者等同替换，均应涵盖在本发明权利要求的保护范围当中。

Claims (10)

  1. 一种陶化剂，其特征在于，该陶化剂由下列重量比例成份组成：
    Figure PCTCN2020113072-appb-100001
  2. 一种陶化剂的制备方法，其特征在于，
    步骤一，将去离子水倒入搅拌装置的各罐体中，并且将各组分单独倒入各罐体中进行混合；其中，钼酸钠与葡萄糖酸钠在同一罐体中混合；
    步骤二，当主罐体搅拌运行15-20分钟后，打开装有氟化钠的罐体，将氟化钠溶液注入主罐体中；
    步骤三，主罐体再次运行10-15分钟，打开装有钼酸铵的罐体，将钼酸铵溶液注入主罐体中；
    步骤四，主罐体再次运行10-15分钟，打开装有柠檬酸的罐体，将柠檬酸溶液注入主罐体中；
    步骤五，主罐体再次运行10-15分钟，打开装有钼酸钠和葡萄糖酸钠的罐体，将钼酸钠和葡萄糖酸钠溶液注入主罐体中；主罐体继续搅拌40-50分钟，制得陶化剂。
  3. 一种陶化剂的搅拌装置，其特征在于，包括主罐体、子罐体、水泵、第一搅拌机构、第二搅拌机构和第三搅拌机构，所述主罐体内设置用于搅拌的所述第一搅拌机构，所述子罐体内设置用于搅拌的第二搅拌机构，所述水泵和所述第三搅拌机构通过管路设置在所述主罐体上，并且与所述主罐体形 成循环回路；所述子罐体通过管路连接在所述水泵和所述第三搅拌机构之间，所述子罐体包括本体和密封盖，所述本体上端设置进气孔和进料口，所述进气孔与气源连接，所述密封盖密封设置在所述进料口上。
  4. 根据权利要求3所述的一种陶化剂的搅拌装置，其特征在于，所述第一搅拌机构包括电机、旋转轴和叶片，所述旋转轴转动设置在所述主罐体内，所述叶片环绕设置在所述旋转轴周向，所述电机设置在所述主罐体的顶部，利用所述电机驱动所述旋转轴以带动所述叶片转动。
  5. 根据权利要求3所述的一种陶化剂的搅拌装置，其特征在于，所述第二搅拌机构包括空气压缩机和进气管，所述进气管设置在所述子罐体底部，并且与所述空气压缩机连接，所述进气管具有若干个气孔，利用所述空气压缩机将气体送入所述进气管，从气孔将气体排出。
  6. 根据权利要求3所述的一种陶化剂的搅拌装置，其特征在于，所述第三搅拌机构包括壳体、安装块和混料管，所述壳体内设置安装所述安装块的安装腔，所述安装块上设置若干个贯穿的安装管，所述混料管设置在所述安装管内，所述壳体的两端分别设置进液口与出液口。
  7. 根据权利要求6所述的一种陶化剂的搅拌装置，其特征在于，所述混料管包括管和若干个叠加的搅拌单元，所述搅拌单元呈螺旋状，一所述搅拌单元的下端与另一所述搅拌单元的上端相互垂直。
  8. 根据权利要求6所述的一种陶化剂的搅拌装置，其特征在于，所述混料管侧壁上设置定位块，所述安装管内壁设置与所述定位块配合的定位槽。
  9. 根据权利要求3所述的一种陶化剂的搅拌装置，其特征在于，所述第三搅拌机构的出液端连接三通阀门，所述三通阀门的一端与所述主罐体连接，另一端为排液口。
  10. 根据权利要求9所述的一种陶化剂的搅拌装置，其特征在于，还包括进液管，所述进液管包括主管和轴向排列在所述主管的子管；所述进液管的进液口与所述三通阀门连接，出液口与所述主罐体连接，并且进液方向与所述主罐体相切。
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