WO2022012015A1 - 一种单组份防水高硬度水性地坪漆及其制备方法 - Google Patents

一种单组份防水高硬度水性地坪漆及其制备方法 Download PDF

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WO2022012015A1
WO2022012015A1 PCT/CN2021/072989 CN2021072989W WO2022012015A1 WO 2022012015 A1 WO2022012015 A1 WO 2022012015A1 CN 2021072989 W CN2021072989 W CN 2021072989W WO 2022012015 A1 WO2022012015 A1 WO 2022012015A1
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parts
disperse
speed
add
water
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房迎春
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上海保立佳新材料有限公司
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
    • C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045—Sulfates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00—Crosslinking

Definitions

  • the invention belongs to the technical field of floor paint, in particular to a one-component waterproof high-hardness water-based floor paint and a preparation method thereof.
  • the existing floor paints are mainly oil-based, and the oil-based paints are divided into epoxy, polyurethane and polyurea. These floor paints all contain harmful substances and do not meet the current environmental protection requirements. Poor weather resistance, not suitable for outdoor use. So the water-based floor paint was born, but the current water-based floor paint has the disadvantages of low hardness, poor wear resistance, poor weather resistance, easy to efflorescence, and water resistance. Compounding various additives can effectively solve the problems of poor water resistance, low hardness and poor wear resistance.
  • the purpose of the present invention is to solve the problems of poor water resistance, low hardness and poor wear resistance of the existing floor paint.
  • a one-component waterproof high-hardness water-based floor paint of the present invention comprises the following components:
  • modified pure acrylic emulsion 15-25 parts of modified silicone-acrylic emulsion, 0.7-1 part of film-forming aid, 20-30 parts of lithium water glass, 5-7 parts of calcined kaolin and 7-10 parts of precipitated barium sulfate share.
  • 0.1-0.3 part of lithium hydroxide, 1.5-2 part of polycarbodiimide, 0.1-0.2 part of wetting and dispersing agent and 0.1-0.2 part of rheology aid are also included.
  • it also includes 0.2-0.4 parts of defoamer, 0.2-0.4 parts of preservatives, 3-5 parts of nano-zinc oxide and 10-15 parts of nano-titanium dioxide.
  • 0.1-0.3 parts of water glass stabilizer, 1-1.5 parts of fumed silica and 1-1.5 parts of modified bentonite are also included.
  • a preparation method of one-component waterproof high-hardness water-based floor paint specifically comprising the following steps:
  • the rotating speed of the high-speed disperser is 600-800 r/min
  • the rotating speed of the high-speed dispersing machine is 1000-1200 r/min
  • the rotating speed of the high-speed disperser is 1200-1500r/min.
  • the preservative solution in the step S400 is formed by mixing preservatives and deionized water, the ratio of preservatives and deionized water is 1:1, and the preservatives are carson-type preservatives.
  • the preparation materials in the step S100 are: 10-25 parts of modified pure acrylic emulsion, 15-25 parts of modified silicone-acrylic emulsion, 0.7-1 part of film-forming assistant, 20-30 parts of lithium water glass, Calcined kaolin 5-7 parts, precipitated barium sulfate 7-10 parts, lithium hydroxide 0.1-0.3 parts, polycarbodiimide 1.5-2 parts, wetting and dispersing agent 0.1-0.2 parts, rheology aid 0.1-0.2 parts , 0.2-0.4 parts of defoamer, 0.2-0.4 parts of preservatives, 3-5 parts of nano-zinc oxide, 10-15 parts of nano-titanium dioxide, 0.1-0.3 parts of water glass stabilizer, 1-1.5 parts of fumed silica and modified Sexual bentonite 1-1.5 parts.
  • the modified bentonite needs to be pre-dissolved with deionized water before adding.
  • the invention discloses a one-component waterproof and high-hardness water-based floor paint and a preparation method thereof.
  • Using the combination of modified pure acrylic emulsion and modified silicone acrylic emulsion can not only improve the weather resistance, but also enhance a certain hardness, and also has a good waterproof effect.
  • polycarbodiimide is also introduced into this formula to effectively promote the emulsion cross-linking. It can speed up the drying rate, which is very helpful to improve the adhesion. It is again different from the sodium silicate or potassium silicate used in general floor paint. Possibly, the stability is better, and the most important thing is to improve the overall strength and wear resistance.
  • the present invention introduces the stability of water glass, which can effectively prevent the reaction of the water glass and the emulsion, achieve the effect of coexistence, and effectively solve the problem of the storage stability of the system.
  • FIG. 1 is a flow chart of the method of the present invention.
  • a one-component waterproof and high hardness water-based floor paint of the present embodiment includes the following components:
  • modified pure acrylic emulsion 15-25 parts of modified silicone-acrylic emulsion, 0.7-1 part of film-forming aid, 20-30 parts of lithium water glass, 5-7 parts of calcined kaolin and 7-10 parts of precipitated barium sulfate share.
  • It also includes 0.1-0.3 part of lithium hydroxide, 1.5-2 part of polycarbodiimide, 0.1-0.2 part of wetting and dispersing agent and 0.1-0.2 part of rheology aid.
  • It also includes 0.2-0.4 parts of defoamer, 0.2-0.4 parts of preservatives, 3-5 parts of nano-zinc oxide and 10-15 parts of nano-titanium dioxide.
  • a preparation method of one-component waterproof high-hardness water-based floor paint specifically comprising the following steps:
  • the rotating speed of the high-speed disperser is 600-800 r/min
  • the rotating speed of the high-speed dispersing machine is 1000-1200 r/min
  • the steps S800 and S900 And in S1000, the rotating speed of the high-speed disperser is 1200-1500r/min.
  • the preservative solution in the step S400 is a mixture of preservative and deionized water, the ratio of preservative and deionized water is 1:1, and the preservative is a carson-type preservative.
  • the preparation materials in the step S100 are: 16 parts of modified pure acrylic emulsion, 25 parts of modified silicone acrylic emulsion, 0.8 parts of film-forming aids, 0.2 parts of lithium hydroxide, 1.5 parts of polycarbodiimide, wetting and dispersing 0.2 part of rheological agent, 0.2 part of rheology additive, 0.3 part of defoamer, 0.3 part of preservative, 3 parts of nano-zinc oxide, 15 parts of nano-titanium dioxide, 8 parts of precipitated barium sulfate, 7 parts of calcined kaolin, 20 parts of lithium water glass, 0.1 part of water glass stabilizer, 1.5 part of fumed silica and 1 part of modified bentonite. .
  • the modified bentonite needs to be pre-dissolved with deionized water before adding.
  • the rotating speed of the high-speed disperser is 600-800 r/min
  • the rotating speed of the high-speed dispersing machine is 1000-1200 r/min
  • the steps S800 and S900 And in S1000, the rotating speed of the high-speed disperser is 1200-1500r/min.
  • the preservative solution in the step S400 is a mixture of preservative and deionized water, the ratio of preservative and deionized water is 1:1, and the preservative is a carson-type preservative.
  • the preparation materials in the step S100 are: 18 parts of modified pure acrylic emulsion, 20 parts of modified silicone acrylic emulsion, 0.9 parts of film-forming aids, 0.3 parts of lithium hydroxide, 1.5 parts of polycarbodiimide, wetting and dispersing 0.3 part of rheological agent, 0.2 part of rheological additive, 0.3 part of defoamer, 0.3 part of preservative, 3 parts of nano-zinc oxide, 12 parts of nano-titanium dioxide, 10 parts of precipitated barium sulfate, 5 parts of calcined kaolin, 25 parts of lithium water glass, 0.2 part of water glass stabilizer, 1.5 part of fumed silica, and 1.5 part of modified bentonite.
  • the modified bentonite needs to be pre-dissolved with deionized water before adding.
  • the rotating speed of the high-speed disperser is 600-800 r/min
  • the rotating speed of the high-speed dispersing machine is 1000-1200 r/min
  • the steps S800 and S900 And in S1000, the rotating speed of the high-speed disperser is 1200-1500r/min.
  • the preservative solution in the step S400 is a mixture of preservative and deionized water, the ratio of preservative and deionized water is 1:1, and the preservative is a carson-type preservative.
  • the preparation materials in the step S100 are specifically: 13 parts of modified pure acrylic emulsion, 20 parts of modified silicone acrylic emulsion, 0.9 parts of film-forming aids, 0.3 parts of lithium hydroxide, 1.5 parts of polycarbodiimide, wetting and dispersing 0.3 part of rheological agent, 0.2 part of rheological additive, 0.3 part of defoamer, 0.3 part of preservative, 3 parts of nano-zinc oxide, 12 parts of nano-titanium dioxide, 10 parts of precipitated barium sulfate, 5 parts of calcined kaolin, 30 parts of lithium water glass, 0.2 part of water glass stabilizer, 1.5 part of fumed silica and 1.5 part of modified bentonite.
  • the modified bentonite needs to be pre-dissolved with deionized water before adding.
  • the rotating speed of the high-speed disperser is 600-800 r/min
  • the rotating speed of the high-speed dispersing machine is 1000-1200 r/min
  • the steps S800 and S900 And in S1000, the rotating speed of the high-speed disperser is 1200-1500r/min.
  • the preservative solution in the step S400 is a mixture of preservative and deionized water, the ratio of preservative and deionized water is 1:1, and the preservative is a carson-type preservative.
  • the preparation materials in the step S100 are: 12 parts of modified pure acrylic emulsion, 25 parts of modified silicone acrylic emulsion, 0.9 parts of film-forming aids, 0.3 parts of lithium hydroxide, 1.5 parts of polycarbodiimide, wetting and dispersing 0.3 parts of rheological additives, 0.2 parts of rheological additives, 0.3 parts of defoamer, 0.3 parts of preservatives, 5 parts of nano-zinc oxide, 15 parts of nano-titanium dioxide, 10 parts of precipitated barium sulfate, 6 parts of calcined kaolin, 20 parts of lithium water glass, 0.2 part of water glass stabilizer, 1.5 part of fumed silica and 1.5 part of modified bentonite.
  • the modified bentonite needs to be pre-dissolved with deionized water before adding.
  • the rotating speed of the high-speed disperser is 600-800 r/min
  • the rotating speed of the high-speed dispersing machine is 1000-1200 r/min
  • the steps S800 and S900 And in S1000, the rotating speed of the high-speed disperser is 1200-1500r/min.
  • the preservative solution in the step S400 is a mixture of preservative and deionized water, the ratio of preservative and deionized water is 1:1, and the preservative is a carson-type preservative.
  • the preparation materials in the step S100 are specifically: 20 parts of modified pure acrylic emulsion, 15 parts of modified silicone acrylic emulsion, 0.9 parts of film-forming aids, 1.5 parts of polycarbodiimide, 0.3 parts of wetting and dispersing agent, rheology 0.2 parts of additives, 0.3 parts of defoamer, 0.3 parts of preservatives, 5 parts of nano-zinc oxide, 10 parts of nano-titanium dioxide, 7 parts of precipitated barium sulfate, 6 parts of calcined kaolin, 30 parts of lithium water glass, 0.2 parts of water glass stabilizer , 1.5 parts of fumed silica and 1.5 parts of modified bentonite.
  • the modified bentonite needs to be pre-dissolved with deionized water before adding.
  • the present invention introduces the stability of water glass, which can effectively prevent the reaction of the water glass and the emulsion, achieve the effect of coexistence, and effectively solve the problem of the storage stability of the system.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
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Abstract

一种单组份防水高硬度水性地坪漆及其制备方法，该地坪漆包括如下组分：改性纯丙乳液10-25份、改性硅丙乳液15-25份、成膜助剂0.7-1份、锂水玻璃20-30份、煅烧高岭土5-7份和沉淀硫酸钡7-10份。

Description

一种单组份防水高硬度水性地坪漆及其制备方法 技术领域
本发明属于地坪漆技术领域，具体来说是一种单组份防水高硬度水性地坪漆及其制备方法。
背景技术
现有的地坪漆主要以油性为主，油性里又分环氧类，聚氨酯类和聚脲类，这几款地坪漆都含有有害物质，达不到目前环保要求，其中环氧类的耐候性较差，不适合做室外。于是水性地坪漆就诞生了，但目前的水性地坪漆存在硬度低，耐磨性差，耐候性差，易泛碱，不耐水等缺点，本发明通过纯丙，硅丙和锂水玻璃体系，复配各种助剂，有效解决耐水差，硬度低，耐磨性差等问题。
发明内容
1.发明要解决的技术问题
本发明的目的在于解决现有的地坪漆存在耐水差，硬度低，耐磨性差的问题。
2.技术方案
为达到上述目的，本发明提供的技术方案为：
本发明的一种单组份防水高硬度水性地坪漆，包括如下组分：
改性纯丙乳液10-25份、改性硅丙乳液15-25份、成膜助剂0.7-1份、锂水玻璃20-30份、煅烧高岭土5-7份和沉淀硫酸钡7-10份。
优选的，还包括氢氧化锂0.1-0.3份、聚碳化二亚胺1.5-2份、润湿分散剂0.1-0.2份和流变助剂0.1-0.2份。
优选的，还包括消泡剂0.2-0.4份、防腐剂0.2-0.4份、纳米氧化锌3-5份和纳米二氧化钛10-15份。
优选的，还包括水玻璃稳定剂0.1-0.3份、气相二氧化硅1-1.5份和改性膨润土1-1.5份。
一种单组份防水高硬度水性地坪漆的制备方法，具体包括如下步骤：
S100、备料，按照所需组分的质量分数进行备料；
S200、一次混料，向高速分散机内添加改性纯丙乳液和改性硅丙乳液后进行分散；
S300、二次混料，向高速分散机内添加成膜助剂和消泡剂，分散15min；
S400、三次分散，向高速分散机内缓慢添加防腐剂溶液，分散10min；
S500、四次分散，向高速分散机内添加滴加碳化二亚胺和氢氧化锂，滴加过程中持续分散15min；
S600、五次分散，向高速分散机内添加润湿分散剂和流变助剂，分散10min；
S700、六次分散，向高速分散机内添加纳米二氧化钛和纳米氧化锌，增加分散机转速并分散15min；
S800、七次分散，继续添加沉淀硫酸钡和煅烧高岭土，再次增加分散机转速并分散30min；
S900、八次分散，当高速分散机内溶液出现气泡时加入消泡剂，待无颗粒气泡，添加锂水玻璃和水玻璃稳定剂，继续分散15min；
S1000、九次分散，向高速分散机内添加气相二氧化硅和改性膨润土，分散20min，待无颗粒气泡后停止分散即得所述地坪漆。
优选的，所述步骤S200、S300、S400、S500和S600中，高速分散机的转速为600-800r/min，所述步骤S700中，高速分散机的转速为1000-1200r/min，所述步骤S800、S900和S1000中，高速分散机的转速为1200-1500r/min。
优选的，所述步骤S400中的防腐剂溶液为防腐剂和去离子水混合而成，防 腐剂和去离子水的比例为1:1，所述防腐剂为卡松类防腐剂。
优选的，所述步骤S100中的备料具体为：改性纯丙乳液10-25份、改性硅丙乳液15-25份、成膜助剂0.7-1份、锂水玻璃20-30份、煅烧高岭土5-7份、沉淀硫酸钡7-10份、氢氧化锂0.1-0.3份、聚碳化二亚胺1.5-2份、润湿分散剂0.1-0.2份、流变助剂0.1-0.2份、消泡剂0.2-0.4份、防腐剂0.2-0.4份、纳米氧化锌3-5份、纳米二氧化钛10-15份、水玻璃稳定剂0.1-0.3份、气相二氧化硅1-1.5份和改性膨润土1-1.5份。
优选的，所述步骤S1000中，改性膨润土在添加前需用去离子水进行预溶解。
3.有益效果
采用本发明提供的技术方案，与现有技术相比，具有如下有益效果：
本发明的一种单组份防水高硬度水性地坪漆及其制备方法。使用改性纯丙乳液和改性硅丙乳液的组合，既能提高耐候性同时又可以增强一定硬度，还有很好的防水效果，其次本配方还引入聚碳化二亚胺，有效促进乳液交联，加快干燥速率，对提高附着力帮助很大，再次区别于一般地坪漆所用的硅酸钠或硅酸钾，本发明采用的硅酸锂，模数选用3.5的，最大降低泛碱的可能，稳定性更佳，最重要的是提高整体的强度和耐磨性。最后为解决传统硅酸盐体系储存稳定性的问题，本发明引入了水玻璃稳定性，可以有效阻止水玻璃和乳液的反应，达到共存的效果，有效解决了该体系储存稳定性的问题。
附图说明
图1为本发明的方法流程图。
具体实施方式
为了便于理解本发明，下面将参照相关附图对本发明进行更全面的描述， 附图中给出了本发明的若干实施例，但是，本发明可以以许多不同的形式来实现，并不限于本文所描述的实施例，相反地，提供这些实施例的目的是使对本发明的公开内容更加透彻全面。
除非另有定义，本文所使用的所有的技术和科学术语与属于本发明的技术领域的技术人员通常理解的含义相同；本文中在本发明的说明书中所使用的术语只是为了描述具体的实施例的目的，不是旨在于限制本发明；本文所使用的术语“及/或”包括一个或多个相关的所列项目的任意的和所有的组合。
实施例1
参照附图1，本实施例的一种单组份防水高硬度水性地坪漆，包括如下组分：
改性纯丙乳液10-25份、改性硅丙乳液15-25份、成膜助剂0.7-1份、锂水玻璃20-30份、煅烧高岭土5-7份和沉淀硫酸钡7-10份。
还包括氢氧化锂0.1-0.3份、聚碳化二亚胺1.5-2份、润湿分散剂0.1-0.2份和流变助剂0.1-0.2份。
还包括消泡剂0.2-0.4份、防腐剂0.2-0.4份、纳米氧化锌3-5份和纳米二氧化钛10-15份。
还包括水玻璃稳定剂0.1-0.3份、气相二氧化硅1-1.5份和改性膨润土1-1.5份。
一种单组份防水高硬度水性地坪漆的制备方法，具体包括如下步骤：
S100、备料，按照所需组分的质量分数进行备料；
S200、一次混料，向高速分散机内添加改性纯丙乳液和改性硅丙乳液后进行分散；
S300、二次混料，向高速分散机内添加成膜助剂和消泡剂，分散15min；
S400、三次分散，向高速分散机内缓慢添加防腐剂溶液，分散10min；
S500、四次分散，向高速分散机内添加滴加碳化二亚胺和氢氧化锂，滴加过程中持续分散15min；
S600、五次分散，向高速分散机内添加润湿分散剂和流变助剂，分散10min；
S700、六次分散，向高速分散机内添加纳米二氧化钛和纳米氧化锌，增加分散机转速并分散15min；
S800、七次分散，继续添加沉淀硫酸钡和煅烧高岭土，再次增加分散机转速并分散30min；
S900、八次分散，当高速分散机内溶液出现气泡时加入消泡剂，待无颗粒气泡，添加锂水玻璃和水玻璃稳定剂，继续分散15min；
S1000、九次分散，向高速分散机内添加气相二氧化硅和改性膨润土，分散20min，待无颗粒气泡后停止分散即得所述地坪漆。
所述步骤S200、S300、S400、S500和S600中，高速分散机的转速为600-800r/min，所述步骤S700中，高速分散机的转速为1000-1200r/min，所述步骤S800、S900和S1000中，高速分散机的转速为1200-1500r/min。
所述步骤S400中的防腐剂溶液为防腐剂和去离子水混合而成，防腐剂和去离子水的比例为1:1，所述防腐剂为卡松类防腐剂。
所述步骤S100中的备料具体为：改性纯丙乳液16份、改性硅丙乳液25份、成膜助剂0.8份、氢氧化锂0.2份、聚碳化二亚胺1.5份、润湿分散剂0.2份、流变助剂0.2份、消泡剂0.3份、防腐剂0.3份、纳米氧化锌3份、纳米二氧化钛15份、沉淀硫酸钡8份、煅烧高岭土7份、锂水玻璃20份、水玻璃稳定剂0.1份、气相二氧化硅1.5份和改性膨润土1份。。
所述步骤S1000中，改性膨润土在添加前需用去离子水进行预溶解。
实施例2
本实施例的一种单组份防水高硬度水性地坪漆及其制备方法，具体包括如下步骤：
S100、备料，按照所需组分的质量分数进行备料；
S200、一次混料，向高速分散机内添加改性纯丙乳液和改性硅丙乳液后进行分散；
S300、二次混料，向高速分散机内添加成膜助剂和消泡剂，分散15min；
S400、三次分散，向高速分散机内缓慢添加防腐剂溶液，分散10min；
S500、四次分散，向高速分散机内添加滴加碳化二亚胺和氢氧化锂，滴加过程中持续分散15min；
S600、五次分散，向高速分散机内添加润湿分散剂和流变助剂，分散10min；
S700、六次分散，向高速分散机内添加纳米二氧化钛和纳米氧化锌，增加分散机转速并分散15min；
S800、七次分散，继续添加沉淀硫酸钡和煅烧高岭土，再次增加分散机转速并分散30min；
S900、八次分散，当高速分散机内溶液出现气泡时加入消泡剂，待无颗粒气泡，添加锂水玻璃和水玻璃稳定剂，继续分散15min；
S1000、九次分散，向高速分散机内添加气相二氧化硅和改性膨润土，分散20min，待无颗粒气泡后停止分散即得所述地坪漆。
所述步骤S200、S300、S400、S500和S600中，高速分散机的转速为600-800r/min，所述步骤S700中，高速分散机的转速为1000-1200r/min，所述步骤S800、S900和S1000中，高速分散机的转速为1200-1500r/min。
所述步骤S400中的防腐剂溶液为防腐剂和去离子水混合而成，防腐剂和去离子水的比例为1:1，所述防腐剂为卡松类防腐剂。
所述步骤S100中的备料具体为：改性纯丙乳液18份、改性硅丙乳液20份、成膜助剂0.9份、氢氧化锂0.3份、聚碳化二亚胺1.5份、润湿分散剂0.3份、流变助剂0.2份、消泡剂0.3份、防腐剂0.3份、纳米氧化锌3份、纳米二氧化钛12份、沉淀硫酸钡10份、煅烧高岭土5份、锂水玻璃25份、水玻璃稳定剂0.2份、气相二氧化硅1.5份、改性膨润土1.5份。
所述步骤S1000中，改性膨润土在添加前需用去离子水进行预溶解。
实施例3
本实施例的一种单组份防水高硬度水性地坪漆及其制备方法，具体包括如下步骤：
S100、备料，按照所需组分的质量分数进行备料；
S200、一次混料，向高速分散机内添加改性纯丙乳液和改性硅丙乳液后进行分散；
S300、二次混料，向高速分散机内添加成膜助剂和消泡剂，分散15min；
S400、三次分散，向高速分散机内缓慢添加防腐剂溶液，分散10min；
S500、四次分散，向高速分散机内添加滴加碳化二亚胺和氢氧化锂，滴加过程中持续分散15min；
S600、五次分散，向高速分散机内添加润湿分散剂和流变助剂，分散10min；
S700、六次分散，向高速分散机内添加纳米二氧化钛和纳米氧化锌，增加分散机转速并分散15min；
S800、七次分散，继续添加沉淀硫酸钡和煅烧高岭土，再次增加分散机转速并分散30min；
S900、八次分散，当高速分散机内溶液出现气泡时加入消泡剂，待无颗粒气泡，添加锂水玻璃和水玻璃稳定剂，继续分散15min；
S1000、九次分散，向高速分散机内添加气相二氧化硅和改性膨润土，分散20min，待无颗粒气泡后停止分散即得所述地坪漆。
所述步骤S200、S300、S400、S500和S600中，高速分散机的转速为600-800r/min，所述步骤S700中，高速分散机的转速为1000-1200r/min，所述步骤S800、S900和S1000中，高速分散机的转速为1200-1500r/min。
所述步骤S400中的防腐剂溶液为防腐剂和去离子水混合而成，防腐剂和去离子水的比例为1:1，所述防腐剂为卡松类防腐剂。
所述步骤S100中的备料具体为：改性纯丙乳液13份、改性硅丙乳液20份、成膜助剂0.9份、氢氧化锂0.3份、聚碳化二亚胺1.5份、润湿分散剂0.3份、流变助剂0.2份、消泡剂0.3份、防腐剂0.3份、纳米氧化锌3份、纳米二氧化钛12份、沉淀硫酸钡10份、煅烧高岭土5份、锂水玻璃30份、水玻璃稳定剂0.2份、气相二氧化硅1.5份和改性膨润土1.5份。
所述步骤S1000中，改性膨润土在添加前需用去离子水进行预溶解。
实施例4
本实施例的一种单组份防水高硬度水性地坪漆及其制备方法，具体包括如下步骤：
S100、备料，按照所需组分的质量分数进行备料；
S200、一次混料，向高速分散机内添加改性纯丙乳液和改性硅丙乳液后进行分散；
S300、二次混料，向高速分散机内添加成膜助剂和消泡剂，分散15min；
S400、三次分散，向高速分散机内缓慢添加防腐剂溶液，分散10min；
S500、四次分散，向高速分散机内添加滴加碳化二亚胺和氢氧化锂，滴加过程中持续分散15min；
S600、五次分散，向高速分散机内添加润湿分散剂和流变助剂，分散10min；
S700、六次分散，向高速分散机内添加纳米二氧化钛和纳米氧化锌，增加分散机转速并分散15min；
S800、七次分散，继续添加沉淀硫酸钡和煅烧高岭土，再次增加分散机转速并分散30min；
S900、八次分散，当高速分散机内溶液出现气泡时加入消泡剂，待无颗粒气泡，添加锂水玻璃和水玻璃稳定剂，继续分散15min；
S1000、九次分散，向高速分散机内添加气相二氧化硅和改性膨润土，分散20min，待无颗粒气泡后停止分散即得所述地坪漆。
所述步骤S200、S300、S400、S500和S600中，高速分散机的转速为600-800r/min，所述步骤S700中，高速分散机的转速为1000-1200r/min，所述步骤S800、S900和S1000中，高速分散机的转速为1200-1500r/min。
所述步骤S400中的防腐剂溶液为防腐剂和去离子水混合而成，防腐剂和去离子水的比例为1:1，所述防腐剂为卡松类防腐剂。
所述步骤S100中的备料具体为：改性纯丙乳液12份、改性硅丙乳液25份、成膜助剂0.9份、氢氧化锂0.3份、聚碳化二亚胺1.5份、润湿分散剂0.3份、流变助剂0.2份、消泡剂0.3份、防腐剂0.3份、纳米氧化锌5份、纳米二氧化钛15份、沉淀硫酸钡10份、煅烧高岭土6份、锂水玻璃20份、水玻璃稳定剂0.2份、气相二氧化硅1.5份和改性膨润土1.5份。
所述步骤S1000中，改性膨润土在添加前需用去离子水进行预溶解。
实施例5
本实施例的一种单组份防水高硬度水性地坪漆及其制备方法，具体包括如下步骤：
S100、备料，按照所需组分的质量分数进行备料；
S200、一次混料，向高速分散机内添加改性纯丙乳液和改性硅丙乳液后进行分散；
S300、二次混料，向高速分散机内添加成膜助剂和消泡剂，分散15min；
S400、三次分散，向高速分散机内缓慢添加防腐剂溶液，分散10min；
S500、四次分散，向高速分散机内添加滴加碳化二亚胺和氢氧化锂，滴加过程中持续分散15min；
S600、五次分散，向高速分散机内添加润湿分散剂和流变助剂，分散10min；
S700、六次分散，向高速分散机内添加纳米二氧化钛和纳米氧化锌，增加分散机转速并分散15min；
S800、七次分散，继续添加沉淀硫酸钡和煅烧高岭土，再次增加分散机转速并分散30min；
S900、八次分散，当高速分散机内溶液出现气泡时加入消泡剂，待无颗粒气泡，添加锂水玻璃和水玻璃稳定剂，继续分散15min；
S1000、九次分散，向高速分散机内添加气相二氧化硅和改性膨润土，分散20min，待无颗粒气泡后停止分散即得所述地坪漆。
所述步骤S200、S300、S400、S500和S600中，高速分散机的转速为600-800r/min，所述步骤S700中，高速分散机的转速为1000-1200r/min，所述步骤S800、S900和S1000中，高速分散机的转速为1200-1500r/min。
所述步骤S400中的防腐剂溶液为防腐剂和去离子水混合而成，防腐剂和去离子水的比例为1:1，所述防腐剂为卡松类防腐剂。
所述步骤S100中的备料具体为：改性纯丙乳液20份、改性硅丙乳液15份、成膜助剂0.9份、聚碳化二亚胺1.5份、润湿分散剂0.3份、流变助剂0.2份、 消泡剂0.3份、防腐剂0.3份、纳米氧化锌5份、纳米二氧化钛10份、沉淀硫酸钡7份、煅烧高岭土6份、锂水玻璃30份、水玻璃稳定剂0.2份、气相二氧化硅1.5份和改性膨润土1.5份。
所述步骤S1000中，改性膨润土在添加前需用去离子水进行预溶解。
分别将实施例1-5制得的地坪漆进行相应的性能检测，检测情况如下表所示：
Figure PCTCN2021072989-appb-000001
由上表可知，本发明配方里引用改性纯丙乳液和改性硅丙乳液的组合，既能提高耐候性同时又可以增强一定硬度，还有很好的防水效果，其次本配方还引入聚碳化二亚胺，有效促进乳液交联，加快干燥速率，对提高附着力帮助很 大，再次区别于一般地坪漆所用的硅酸钠或硅酸钾，本发明采用的硅酸锂，模数选用3.5的，最大降低泛碱的可能，稳定性更佳，最重要的是提高整体的强度和耐磨性。最后为解决传统硅酸盐体系储存稳定性的问题，本发明引入了水玻璃稳定性，可以有效阻止水玻璃和乳液的反应，达到共存的效果，有效解决了该体系储存稳定性的问题。
以上所述实施例仅表达了本发明的某种实施方式，其描述较为具体和详细，但并不能因此而理解为对本发明专利范围的限制；应当指出的是，对于本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进，这些都属于本发明的保护范围；因此，本发明专利的保护范围应以所附权利要求为准。

Claims (9)

  1. 一种单组份防水高硬度水性地坪漆，其特征在于，包括如下组分：
    改性纯丙乳液10-25份、改性硅丙乳液15-25份、成膜助剂0.7-1份、锂水玻璃20-30份、煅烧高岭土5-7份和沉淀硫酸钡7-10份。
  2. 根据权利要求1所述的一种单组份防水高硬度水性地坪漆，其特征在于：还包括氢氧化锂0.1-0.3份、聚碳化二亚胺1.5-2份、润湿分散剂0.1-0.2份和流变助剂0.1-0.2份。
  3. 根据权利要求1所述的一种单组份防水高硬度水性地坪漆，其特征在于：还包括消泡剂0.2-0.4份、防腐剂0.2-0.4份、纳米氧化锌3-5份和纳米二氧化钛10-15份。
  4. 根据权利要求1所述的一种单组份防水高硬度水性地坪漆，其特征在于：还包括水玻璃稳定剂0.1-0.3份、气相二氧化硅1-1.5份和改性膨润土1-1.5份。
  5. 一种单组份防水高硬度水性地坪漆的制备方法，其特征在于，具体包括如下步骤：
    S100、备料，按照所需组分的质量分数进行备料；
    S200、一次混料，向高速分散机内添加改性纯丙乳液和改性硅丙乳液后进行分散；
    S300、二次混料，向高速分散机内添加成膜助剂和消泡剂，分散15min；
    S400、三次分散，向高速分散机内缓慢添加防腐剂溶液，分散10min；
    S500、四次分散，向高速分散机内添加滴加碳化二亚胺和氢氧化锂，滴加过程中持续分散15min；
    S600、五次分散，向高速分散机内添加润湿分散剂和流变助剂，分散10min；
    S700、六次分散，向高速分散机内添加纳米二氧化钛和纳米氧化锌，增加分散机转速并分散15min；
    S800、七次分散，继续添加沉淀硫酸钡和煅烧高岭土，再次增加分散机转速并分散30min；
    S900、八次分散，当高速分散机内溶液出现气泡时加入消泡剂，待无颗粒气泡，添加锂水玻璃和水玻璃稳定剂，继续分散15min；
    S1000、九次分散，向高速分散机内添加气相二氧化硅和改性膨润土，分散20min，待无颗粒气泡后停止分散即得所述地坪漆。
  6. 根据权利要求5所述的一种单组份防水高硬度水性地坪漆的制备方法，其特征在于：所述步骤S200、S300、S400、S500和S600中，高速分散机的转速为600-800r/min，所述步骤S700中，高速分散机的转速为1000-1200r/min，所述步骤S800、S900和S1000中，高速分散机的转速为1200-1500r/min。
  7. 根据权利要求5所述的一种单组份防水高硬度水性地坪漆的制备方法，其特征在于：所述步骤S400中的防腐剂溶液为防腐剂和去离子水混合而成，防腐剂和去离子水的比例为1:1，所述防腐剂为卡松类防腐剂。
  8. 根据权利要求5所述的一种单组份防水高硬度水性地坪漆的制备方法，其特征在于，所述步骤S100中的备料具体为：改性纯丙乳液10-25份、改性硅丙乳液15-25份、成膜助剂0.7-1份、锂水玻璃20-30份、煅烧高岭土5-7份、沉淀硫酸钡7-10份、氢氧化锂0.1-0.3份、聚碳化二亚胺1.5-2份、润湿分散剂0.1-0.2份、流变助剂0.1-0.2份、消泡剂0.2-0.4份、防腐剂0.2-0.4份、纳米氧化锌3-5份、纳米二氧化钛10-15份、水玻璃稳定剂0.1-0.3份、气相二氧化硅1-1.5份和改性膨润土1-1.5份。
  9. 根据权利要求5所述的一种单组份防水高硬度水性地坪漆的制备方法，其特征在于，所述步骤S1000中，改性膨润土在添加前需用去离子水进行预溶解。
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114736565A (zh) * 2022-03-29 2022-07-12 上海保立佳新材料有限公司 一种硬化剂及其原料组合物、制备方法和应用
CN115651487A (zh) * 2022-11-16 2023-01-31 株洲市九华新材料涂装实业有限公司 一种水性环氧底漆及其制备方法与应用

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111647329A (zh) * 2020-07-14 2020-09-11 上海保立佳新材料有限公司 一种单组份防水高硬度水性地坪漆及其制备方法
CN112898842B (zh) * 2021-01-25 2022-03-29 上海保立佳新材料有限公司 一种单组份高硬度耐水型水性罩面漆及其制备方法
CN116694172B (zh) * 2023-07-04 2023-11-24 佛山市顺德区荷叶化工有限公司 一种单组分罩面光油及其制备方法与应用
CN117511308B (zh) * 2023-11-07 2024-04-05 广东电安新材料科技有限公司 一种耐腐蚀高导电率涂层及其制备方法和应用

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102533082A (zh) * 2011-12-31 2012-07-04 武汉菲凡士建材有限公司 一种水性环保耐老化地坪涂料及其制备方法
CN104804599A (zh) * 2015-04-08 2015-07-29 田福东 一种水性自固化无机涂料
CN105694550A (zh) * 2016-03-16 2016-06-22 陈威 一种单组份水性无机地坪涂料配方及制作技术
CN105907214A (zh) * 2016-05-10 2016-08-31 深圳市宝光工业有限公司 纳米复合环保水性地坪漆制备方法
CN106497273A (zh) * 2016-10-27 2017-03-15 苏州富通高新材料科技股份有限公司 一种防腐纳米丙烯酸地坪漆
CN106519764A (zh) * 2016-10-25 2017-03-22 苏州富通高新材料科技股份有限公司 一种防滑纳米丙烯酸地坪漆
CN108342140A (zh) * 2018-03-01 2018-07-31 合肥峰腾节能科技有限公司 一种环保隔热自洁耐候地坪涂料及其制备方法
CN109082145A (zh) * 2018-08-01 2018-12-25 淮北庆丰涂料有限公司 一种水性地坪漆及其制备方法和使用方法
CN109913099A (zh) * 2019-03-07 2019-06-21 河北晨阳工贸集团有限公司 一种水性单组份环氧漆及其制备方法
CN111363431A (zh) * 2020-04-08 2020-07-03 乔兴刚 一种多功能水性环保涂料
CN111647329A (zh) * 2020-07-14 2020-09-11 上海保立佳新材料有限公司 一种单组份防水高硬度水性地坪漆及其制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103588443B (zh) * 2013-11-13 2015-09-16 武汉卓亿科技发展有限公司 纳米水性陶瓷功能型复合涂料及其制备方法
CN109294382B (zh) * 2018-09-14 2020-12-22 湖南凯斯利新材料有限公司 一种超耐候耐酸雨耐沾污水性无机纳米陶瓷涂料及其制备方法
CN109705685B (zh) * 2018-12-06 2021-05-11 浙江工业大学 一种交联型宽温域水性阻尼涂料及其制备
CN109868015B (zh) * 2019-03-22 2021-06-08 福建百花化学股份有限公司 一种有机无机复合水性铝粉漆及其制备方法

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102533082A (zh) * 2011-12-31 2012-07-04 武汉菲凡士建材有限公司 一种水性环保耐老化地坪涂料及其制备方法
CN104804599A (zh) * 2015-04-08 2015-07-29 田福东 一种水性自固化无机涂料
CN105694550A (zh) * 2016-03-16 2016-06-22 陈威 一种单组份水性无机地坪涂料配方及制作技术
CN105907214A (zh) * 2016-05-10 2016-08-31 深圳市宝光工业有限公司 纳米复合环保水性地坪漆制备方法
CN106519764A (zh) * 2016-10-25 2017-03-22 苏州富通高新材料科技股份有限公司 一种防滑纳米丙烯酸地坪漆
CN106497273A (zh) * 2016-10-27 2017-03-15 苏州富通高新材料科技股份有限公司 一种防腐纳米丙烯酸地坪漆
CN108342140A (zh) * 2018-03-01 2018-07-31 合肥峰腾节能科技有限公司 一种环保隔热自洁耐候地坪涂料及其制备方法
CN109082145A (zh) * 2018-08-01 2018-12-25 淮北庆丰涂料有限公司 一种水性地坪漆及其制备方法和使用方法
CN109913099A (zh) * 2019-03-07 2019-06-21 河北晨阳工贸集团有限公司 一种水性单组份环氧漆及其制备方法
CN111363431A (zh) * 2020-04-08 2020-07-03 乔兴刚 一种多功能水性环保涂料
CN111647329A (zh) * 2020-07-14 2020-09-11 上海保立佳新材料有限公司 一种单组份防水高硬度水性地坪漆及其制备方法

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114736565A (zh) * 2022-03-29 2022-07-12 上海保立佳新材料有限公司 一种硬化剂及其原料组合物、制备方法和应用
CN114736565B (zh) * 2022-03-29 2023-11-28 上海保立佳新材料有限公司 一种硬化剂及其原料组合物、制备方法和应用
CN115651487A (zh) * 2022-11-16 2023-01-31 株洲市九华新材料涂装实业有限公司 一种水性环氧底漆及其制备方法与应用
CN115651487B (zh) * 2022-11-16 2024-01-26 株洲市九华新材料涂装实业有限公司 一种水性环氧底漆及其制备方法与应用

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