WO2021260750A1 - Skincare cosmetic free of sodium hydroxide and potassium hydroxide - Google Patents

Skincare cosmetic free of sodium hydroxide and potassium hydroxide Download PDF

Info

Publication number
WO2021260750A1
WO2021260750A1 PCT/JP2020/024272 JP2020024272W WO2021260750A1 WO 2021260750 A1 WO2021260750 A1 WO 2021260750A1 JP 2020024272 W JP2020024272 W JP 2020024272W WO 2021260750 A1 WO2021260750 A1 WO 2021260750A1
Authority
WO
WIPO (PCT)
Prior art keywords
sodium hydroxide
cosmetic
potassium hydroxide
skin care
hydroxide
Prior art date
Application number
PCT/JP2020/024272
Other languages
French (fr)
Japanese (ja)
Inventor
一重 中島
Original Assignee
中島産業株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 中島産業株式会社 filed Critical 中島産業株式会社
Priority to JP2022531243A priority Critical patent/JP7430009B2/en
Priority to PCT/JP2020/024272 priority patent/WO2021260750A1/en
Publication of WO2021260750A1 publication Critical patent/WO2021260750A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin

Definitions

  • the present invention is a skin care cosmetic for the purpose of cleansing and conditioning the skin, such as soap, lotion, and milky lotion, and sodium hydroxide and water to be blended in the skin care cosmetic. It relates to a skin care cosmetic product in which the pH of the cosmetic product is adjusted with strong alkaline electrolyzed water instead of potassium oxide.
  • the present invention is a gel-like skin care makeup in which a carboxyvinyl polymer added for the purpose of thickening action by a neutralization reaction is neutralized with strong alkaline electrolyzed water without using sodium hydroxide or potassium hydroxide.
  • charges Regarding charges.
  • a cosmetic using a carboxyvinyl polymer as a gelling agent containing a basic amino acid and an alkali metal hydroxide has been proposed (see, for example, Patent Document 1). ).
  • a basic amino acid and an alkali metal hydroxide, such as potassium hydroxide are used in combination to neutralize the carboxyvinyl polymer so that appropriate viscosity can be obtained even under weakly acidic conditions. It has become.
  • II ethylenediamine-N, N, N', N'-copper tetraacetate
  • composition for fibers a copper compound such as ethylenediamine-N, N, N', N'-copper tetraacetate (II) disodium salt tetrahydrate is blended, and pollen disintegration is added to the composition for fibers. It is designed to give sex.
  • a copper compound such as ethylenediamine-N, N, N', N'-copper tetraacetate (II) disodium salt tetrahydrate is blended, and pollen disintegration is added to the composition for fibers. It is designed to give sex.
  • a hair cosmetic containing a Polygonaceae plant Rumex japonicus extract as an ingredient having an effective antidandruff effect has been proposed (see, for example, Patent Document 3).
  • this hair cosmetic instead of antibacterial agent and bactericidal agent, Polygonaceae plant Rumex japonicus extract is blended so that even if hair cosmetic is used every day, the delicate balance of indigenous skin bacteria will not be disturbed. ing.
  • Patent Document 4 a cosmetic for cleaning pets consisting of vegetable oil, purified water, herbal powder, aloe herbal enzyme, sodium hydroxide or potassium hydroxide.
  • the pH value of the cosmetic is raised to about 8-9 by using aloe herb enzyme, where the herb powder makes the cosmetic acidic, and the herb's cleaning and moisturizing properties It is designed not to irritate the hair and skin of pets without impairing the bactericidal properties.
  • Japanese Unexamined Patent Publication No. 62-161711 (Page 1, lower right column, line 4-2, page 2, upper left column, line 7) Japanese Unexamined Patent Publication No. 2020-12214 (paragraphs 0009, 0019, 0022) Japanese Unexamined Patent Publication No. 61-282309 (Page 1, Lower Right Column, Line 6-Page 1, Lower Right Column, Line 17) Japanese Unexamined Patent Publication No. 2017-14127 (paragraph 0005,0006)
  • the sodium hydroxide when sodium hydroxide is used to neutralize the carboxyvinyl polymer, the sodium hydroxide also exceeds 5% of the drug substance according to the Poisonous and Deleterious Substances Control Law. The product is designated as a deleterious substance.
  • the hair cosmetic according to Patent Document 3 is designated as a deleterious substance even though it does not use antibacterial agents or bactericidal agents that have a problem in safety to the human body in terms of skin irritation and the like.
  • the pH of the squeaky extract is adjusted using the sodium hydroxide solution.
  • an object of the present invention is to solve the above-mentioned problems and to provide a skin care cosmetic having an adjusted pH of the cosmetic without using sodium hydroxide or potassium hydroxide designated as deleterious substances. ..
  • the present invention provides a gel-like skin care cosmetic product in which a carboxyvinyl polymer added for the purpose of thickening action by a neutralization reaction is neutralized without using sodium hydroxide or potassium hydroxide. The purpose.
  • a known cosmetic composition in which sodium hydroxide or potassium hydroxide is formulated and designed as a pH adjusting agent is to be blended.
  • sodium and potassium hydroxide strong alkaline electrolyzed water was used to adjust the pH of the cosmetic composition, or more correctly, known cosmetic compositions excluding sodium hydroxide and potassium hydroxide.
  • the pH of the cosmetic composition is adjusted with strong alkaline electrolyzed water having a pH of 13.0 or more and a pH of 14 or less.
  • strong alkaline electrolyzed water is used to neutralize the carboxyvinyl polymer added to the known cosmetic composition.
  • the pH of a known cosmetic composition containing an antibacterial component and a bactericidal component is adjusted with strongly alkaline electrolyzed water.
  • the pH of the cosmetic composition is adjusted with strong alkaline electrolyzed water, so that the skin care cosmetics More correctly, it is possible to avoid the use of sodium hydroxide and potassium hydroxide in skin care cosmetics consisting of known cosmetic compositions.
  • sodium hydroxide and potassium hydroxide are designated as deleterious substances by the Toxic and Deleterious Substances Control Law, but sodium hydroxide and potassium hydroxide used in cosmetics are specified as deleterious substances.
  • the blending amount of sodium hydroxide is generally 1% or less, and since the strongly alkaline property of sodium hydroxide and potassium hydroxide is canceled by the neutralization reaction, it is considered that there is no problem in safety.
  • the skin care cosmetic can be safely used even for pets such as infants, dogs and cats whose weight is lighter than that of adults.
  • sodium hydroxide and potassium hydroxide designated as deleterious substances can be prevented from being used in skin care cosmetics
  • sodium hydroxide in the manufacturing process of cosmetics can be used. It is also possible to eliminate leakage accidents and exposure accidents caused by potassium hydroxide.
  • poisonous deleterious substances can be used in cosmetic manufacturing factories and the like. It is not necessary to have a person in charge of handling, and it is possible to reduce the labor of storage management and disposal of cosmetic raw materials.
  • the strong alkaline electrolyzed water is obtained by electrolyzing an aqueous solution of water mixed with potassium carbonate, and more correctly, the aqueous solution of water mixed with potassium carbonate is electrolyzed and ions are generated from the aqueous solution. It is generated by the movement of ions to pure water through the exchange membrane.
  • strong alkaline electrolyzed water is made from potassium carbonate, which is also designated as water and food additives, and the raw materials are only water and food additives, more correctly, only water and ions, so it is highly safe.
  • the environmental load is also small.
  • the pH of the cosmetic composition is adjusted with highly safe strong alkaline electrolyzed water, the safety of the skin care cosmetic can be further enhanced. It is.
  • the pH of the cosmetic composition is adjusted with strong alkaline electrolyzed water instead of sodium hydroxide or potassium hydroxide to be blended. Since it has been adjusted, known skin care cosmetics can be made into skin care cosmetics that do not use sodium hydroxide and potassium hydroxide. Therefore, according to the invention of claim 1, since the known skin care cosmetic can be made into a skin care cosmetic that does not use sodium hydroxide and potassium hydroxide, the known skin care cosmetic can be renewed with enhanced safety.
  • the pH of the cosmetic composition is adjusted with strong alkaline electrolyzed water having a pH of 13.0 or more and pH 14 or less, the strong alkali is used instead of sodium hydroxide or potassium hydroxide.
  • the pH of the cosmetic composition can be adjusted with electrolyzed water.
  • strong alkaline electrolyzed water is used to neutralize the carboxyvinyl polymer added to the known cosmetic composition, so that the known gel-like skin care cosmetic can be used as sodium hydroxide. And can be a gel-like skin care cosmetic that does not use potassium hydroxide.
  • a known medicated skin care cosmetic product for example, medicinal product
  • Hand soaps, deodorant products, anti-foam hair care products, etc. can be made into medicated skin care cosmetics that do not use sodium hydroxide and potassium hydroxide.
  • nax201 an aqua-ax environmentally processed water generator
  • aqua-ax is registered by the applicant.
  • nax201 is characterized by being provided with an electrolytic ionized water generator capable of producing so-called strong alkaline electrolyzed water having a pH of 12.5 (measured at room temperature of 20 ° C., the same applies hereinafter).
  • the nax201 can prevent the water-soluble coolant from spoiling by diluting the water-soluble cutting oil with strong alkaline electrolyzed water.
  • nax201 can generate strong alkaline electrolyzed water, and diluted the water-soluble cutting oil with strong alkaline electrolyzed water, which is simpler than the conventional device.
  • alkaline aqueous solutions such as the development of a small water-soluble coolant manufacturing device, that can remove oil stains and reduce bacteria, "products that are friendly to the global environment and can clean stains” and " We have developed "products that can be sterilized only with” water "born from the earth.”
  • Oil Nax is a registered trademark of the applicant (Registration No. 5284719)).
  • Oil Nax has oil and fat decomposition performance, and in particular, the alkaline electrolytic type that electrolyzes water to maintain its alkalinity is used for cleaning commercial tableware and kitchen equipment, towels with oil, and so on.
  • An oil-and-fat decomposition detergent that is effective for cleaning work clothes. Therefore, Oil Nax is highly evaluated not only in the restaurant and manufacturing industries, but also in the linen supply industry, especially in aromatherapy specialty stores and esthetic salons that use essential oils.
  • the inventor's motto is not to be satisfied with the current situation and to aim for a better product, but from customers who use Oil Nax to wash towels, as a preventive measure against viral infections, towels are used. I heard a voice hoping for an anti-virus effect.
  • the inventor is a processed fiber (a textile product that meets the certification criteria among the processes that reduce the number of specific viruses on the fiber certified by the Textile Evaluation Technology Council) in order to meet the customer's request.
  • a processed fiber a textile product that meets the certification criteria among the processes that reduce the number of specific viruses on the fiber certified by the Textile Evaluation Technology Council
  • components used in also referred to as anti-virus processing certification
  • Patent Document 2 We have found a composition for fibers that has disintegration properties.
  • the inventor paid attention to the fact that the highly functional nax301 with an increased degree of alkalinity can produce the industry's highest level of strong alkaline electrolyzed water with a pH of 13.1.
  • about 10 years have passed since the inventor started manufacturing and selling strong alkaline electrolyzed water, and the strong alkaline electrolyzed water manufactured 10 years ago has continued to maintain a high pH, and the strong alkaline electrolyzed water manufactured in-house has been maintained. It was noted that water hardly changed over time.
  • the inventor can replace sodium hydroxide or potassium hydroxide with his own strong alkaline electrolyzed water, which has a strong alkalinity exceeding the industry's highest level of pH 13, and has a stable pH value that hardly changes over time. He discovered and created this invention.
  • the skin care cosmetic according to the embodiment is a known cosmetic composition formulated and designed to contain sodium hydroxide or potassium hydroxide as a pH adjuster, and is to be blended with sodium hydroxide or potassium hydroxide. Instead, it is obtained by adjusting the pH of a known cosmetic composition with strong alkaline electrolyzed water, or more correctly, a known cosmetic composition excluding sodium hydroxide and potassium hydroxide.
  • Skin care cosmetics are cosmetic products that aim to cleanse and condition the skin, such as soap, lotion, and milky lotion, and are also called basic cosmetics.
  • the dosage form of skin care cosmetics may be solid like bar soap, liquid like lotion, gel like moisturizing gel, or any dosage form. Here, the solution is a little. It is a gel-like solidified jelly with the elasticity and hardness of.
  • a combination of ingredients to be blended in skin care cosmetics has been found (also referred to as a formulation design), and here, sodium hydroxide or potassium hydroxide is used as a pH adjuster.
  • the formulation is prescription designed.
  • the addition of a carboxyvinyl polymer is formulated and designed for the purpose of thickening action by a neutralization reaction.
  • the strong alkaline electrolyzed water is an aqueous solution having a pH of 11 or more and obtained by electrolyzing water, and here, it is an aqueous solution having a pH of 13.0 or more and a pH of 14 or less. Strong alkaline electrolyzed water is produced by electrolyzing an aqueous solution of water mixed with potassium carbonate and transferring ions from the aqueous solution to pure water through an ion exchange membrane.
  • the known cosmetic composition will be described as a gel-like skin care cosmetic according to Patent Document 1, specifically, a weakly acidic gel-like face wash.
  • the known cosmetic compositions are as follows, and a formulation of potassium hydroxide as a pH adjuster is formulated and designed.
  • the carboxyvinyl polymer is neutralized with strong alkaline electrolyzed water to obtain appropriate viscosity, and a weakly acidic gel is obtained. You do not need to use potassium hydroxide for the skin wash.
  • a known cosmetic composition will be described as a hair cosmetic according to Patent Document 3, specifically, a hair tonic for preventing dandruff.
  • the extract containing the active ingredient is specifically exemplified to be alkaline-treated with an aqueous sodium hydroxide solution, but instead of the aqueous sodium hydroxide solution, a strong alkaline electrolyzed water is used. It is treated with alkali.
  • the extraction method of Rumex japonicus extract is performed by fragmenting 5.0 kg of Rumex japonicus root and immersing it in dichloromethane overnight.
  • This extract is concentrated and treated with a 5% aqueous sodium hydroxide solution to remove an acidic part, which is subjected to silica gel column chromatography to concentrate and recrystallize the chloroform eluent to obtain 0.53 g of yellowish crystals. It is specifically illustrated that it can be done. Therefore, in the skin care cosmetics according to the other embodiment, the concentrated extract of Gishigishi is alkaline-treated with strong alkaline electrolyzed water instead of the sodium hydroxide aqueous solution.
  • glycerin is added to 36.5 g of purified water to dissolve it by heating, and after cooling, 55 g of ethyl alcohol and 2 g of polyoxyethylene oleyl alcohol ether are added to the aqueous phase portion to which an appropriate amount of dye is added.
  • ethyl alcohol and 2 g of polyoxyethylene oleyl alcohol ether are added to the aqueous phase portion to which an appropriate amount of dye is added.
  • 1.5 g of extracted yellowish crystals of glycerin, an appropriate amount of fragrance are added, and an alcohol phase obtained by dissolving at room temperature is added to solubilize the hair tonic to obtain a hair tonic having an anti-blurring effect.
  • the extract containing the active ingredient is alkaline-treated with strong alkaline electrolyzed water to add sodium hydroxide to the hair tonic for preventing indulgence. You don't have to use it.
  • the known cosmetic composition is used as a pet cleaning cosmetic according to Patent Document 4, specifically, a soap for normal skin and a cut dog breed.
  • the known cosmetic compositions are as follows, and a formulation of sodium hydroxide as a pH adjuster is formulated and designed.
  • Purified water 147g Aloe herb enzyme 100g Herb powder 50-70g
  • the skin care cosmetics according to another other embodiment replace the sodium hydroxide to be blended, more correctly, instead of the water in which sodium hydroxide is mixed with purified water and dissolved, a strong alkali. Electrolyzed water is slowly poured into a mixed oil containing the above oil, and after the injection, the pH is adjusted by stirring (stirring), more correctly, saponification is performed.
  • the skin care cosmetics according to another other embodiment can be made into soap for dogs by adjusting the pH of the mixed oil with strongly alkaline electrolyzed water instead of the sodium hydroxide to be blended. You don't have to use sodium hydroxide.
  • the present invention is not limited to the above-described embodiments.
  • the skin care cosmetics according to the embodiment although it is described as a weakly acidic skin care cosmetic, it may be neutral or weakly alkaline as long as it is in a range that is gentle on the skin.
  • the antibacterial component and the bactericidal component are described as an extract of Polygonaceae plant Gishigishi instead of the antibacterial agent and the bactericidal agent. It can be a disinfectant, a disinfectant, or any ingredient.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

[Problem] To provide a skincare cosmetic in which pH is adjusted without using sodium hydroxide or potassium hydroxide, which are specified as deleterious substances. [Solution] The present invention modifies a known cosmetic composition in which a pH adjusting agent such as sodium hydroxide and potassium hydroxide is blended for formulation, by using strong alkaline electrolysis water instead of sodium hydroxide and potassium hydroxide which are supposed to be blended, to adjust the pH of the cosmetic composition, converting a known skincare cosmetic into a skincare cosmetic free of sodium hydroxide and potassium hydroxide. The present invention also modifies a known gel-like skincare cosmetic containing a carboxy vinyl polymer as a gelling agent, by using strong alkaline electrolysis water instead of sodium hydroxide or potassium hydroxide which is to be blended, to neutralize the carboxy vinyl polymer, converting a known gel-like skincare cosmetic into a skincare cosmetic free of sodium hydroxide and potassium hydroxide.

Description

水酸化ナトリウムおよび水酸化カリウム不使用のスキンケア化粧料Sodium hydroxide and potassium hydroxide free skin care cosmetics
 この発明は、石鹸(せっけん)や化粧水、乳液などのように肌を清潔にし整えることを目的とするスキンケア化粧料であって、スキンケア化粧料に配合することになっている水酸化ナトリウムや水酸化カリウムの代わりに、強アルカリ電解水で化粧料のpHを調整したスキンケア化粧料に関する。特に、この発明は、中和反応による増粘作用を目的に添加されているカルボキシビニルポリマーを、水酸化ナトリウムや水酸化カリウムを使わずに、強アルカリ電解水で中和したゲル状のスキンケア化粧料に関する。 The present invention is a skin care cosmetic for the purpose of cleansing and conditioning the skin, such as soap, lotion, and milky lotion, and sodium hydroxide and water to be blended in the skin care cosmetic. It relates to a skin care cosmetic product in which the pH of the cosmetic product is adjusted with strong alkaline electrolyzed water instead of potassium oxide. In particular, the present invention is a gel-like skin care makeup in which a carboxyvinyl polymer added for the purpose of thickening action by a neutralization reaction is neutralized with strong alkaline electrolyzed water without using sodium hydroxide or potassium hydroxide. Regarding charges.
 ゲル状のスキンケア化粧料としては、ゲル化剤としてカルボキシビニルポリマーを用いた化粧料に、塩基性アミノ酸とアルカリ金属の水酸化物を含有させたものが提案されている(例えば、特許文献1参照)。このゲル状のスキンケア化粧料では、塩基性アミノ酸とアルカリ金属の水酸化物、例えば水酸化カリウムを併用してカルボキシビニルポリマーを中和することで、弱酸性の条件でも適度な粘性を得られるようになっている。 As a gel-like skin care cosmetic, a cosmetic using a carboxyvinyl polymer as a gelling agent containing a basic amino acid and an alkali metal hydroxide has been proposed (see, for example, Patent Document 1). ). In this gel-like skin care cosmetic, a basic amino acid and an alkali metal hydroxide, such as potassium hydroxide, are used in combination to neutralize the carboxyvinyl polymer so that appropriate viscosity can be obtained even under weakly acidic conditions. It has become.
 スキンケア化粧料ではないものの、アミノ酸銀、アミノ酸亜鉛、カルボキシビニルポリマー、およびエチレンジアミン-N,N,N’,N’-四酢酸銅(II)二ナトリウム塩四水和物、グルタミン酸銅、アミノ酸銅のうちの1種または2種以上を含むことを特徴とする繊維用組成物が提案されている(例えば、特許文献2参照)。この繊維用組成物では、アミノ酸銀とアミノ酸亜鉛を配合して、抗菌と抗ウイルス効果を確実に高められるようになっている。また、この繊維用組成物では、エチレンジアミン-N,N,N’,N’-四酢酸銅(II)二ナトリウム塩四水和物などの銅化合物を配合して、繊維用組成物に花粉崩壊性を付与するようになっている。 Although not a skin care cosmetic, amino acid silver, amino acid zinc, carboxyvinyl polymer, and ethylenediamine-N, N, N', N'-copper tetraacetate (II) disodium salt tetrahydrate, copper glutamate, copper amino acid A composition for fibers characterized by containing one or more of them has been proposed (see, for example, Patent Document 2). In this fiber composition, the amino acid silver and the amino acid zinc are blended to surely enhance the antibacterial and antiviral effects. Further, in this composition for fibers, a copper compound such as ethylenediamine-N, N, N', N'-copper tetraacetate (II) disodium salt tetrahydrate is blended, and pollen disintegration is added to the composition for fibers. It is designed to give sex.
 別のスキンケア化粧料としては、タデ科植物ギシギシ抽出物を、有効なふけ抑制作用を持つ成分として配合した頭髪化粧料が提案されている(例えば、特許文献3参照)。この頭髪化粧料では、抗菌剤や殺菌剤の代わりに、タデ科植物ギシギシ抽出物を配合することで、頭髪化粧料を毎日使用しても皮膚常在菌の微妙なバランスを崩さないようになっている。 As another skin care cosmetic, a hair cosmetic containing a Polygonaceae plant Rumex japonicus extract as an ingredient having an effective antidandruff effect has been proposed (see, for example, Patent Document 3). In this hair cosmetic, instead of antibacterial agent and bactericidal agent, Polygonaceae plant Rumex japonicus extract is blended so that even if hair cosmetic is used every day, the delicate balance of indigenous skin bacteria will not be disturbed. ing.
 ヒト用のスキンケア化粧料ではないものの、植物オイルと精製水、ハーブパウダー、アロエハーブ酵素、水酸化ナトリウムまたは水酸化カリウムとからなるペットの洗浄用化粧料が提案されている(例えば、特許文献4参照)。このペットの洗浄用化粧料では、ハーブパウダーを配合することで化粧料が酸性になるところを、アロエハーブ酵素によって化粧料のpH値を8~9程度に上げて、ハーブの洗浄性や保湿性、殺菌性を損なうことなく、ペットの毛や肌に刺激を与えないようになっている。 Although it is not a skin care cosmetic for humans, a cosmetic for cleaning pets consisting of vegetable oil, purified water, herbal powder, aloe herbal enzyme, sodium hydroxide or potassium hydroxide has been proposed (for example, Patent Document 4). reference). In this pet cleaning cosmetic, the pH value of the cosmetic is raised to about 8-9 by using aloe herb enzyme, where the herb powder makes the cosmetic acidic, and the herb's cleaning and moisturizing properties It is designed not to irritate the hair and skin of pets without impairing the bactericidal properties.
特開昭62-161711号公報(第1頁右下欄第4行-第2頁左上欄第7行)Japanese Unexamined Patent Publication No. 62-161711 (Page 1, lower right column, line 4-2, page 2, upper left column, line 7) 特開2020-12214号公報(段落0009,0019,0022)Japanese Unexamined Patent Publication No. 2020-12214 (paragraphs 0009, 0019, 0022) 特開昭61-282309号公報(第1頁右下欄第6行-第1頁右下欄第17行)Japanese Unexamined Patent Publication No. 61-282309 (Page 1, Lower Right Column, Line 6-Page 1, Lower Right Column, Line 17) 特開2017-14127号公報(段落0005,0006)Japanese Unexamined Patent Publication No. 2017-14127 (paragraph 0005,0006)
 しかしながら、前記特許文献1に係るゲル状のスキンケア化粧料では、アルカリ金属の水酸化物、例えば水酸化カリウムを、塩基性アミノ酸と併用してカルボキシビニルポリマーを中和しているところ、水酸化カリウムは、毒物及び劇物取締法で原体と5%を超える製剤が劇物に指定されている。 However, in the gel-like skin care cosmetics according to Patent Document 1, when an alkali metal hydroxide, for example, potassium hydroxide is used in combination with a basic amino acid to neutralize the carboxyvinyl polymer, potassium hydroxide is used. Is designated as a deleterious substance by the Toxic and Deleterious Substances Control Law, with the original substance and a formulation exceeding 5%.
 また、前記特許文献2に係る繊維用組成物では、水酸化ナトリウムを使ってカルボキシビニルポリマーを中和しているところ、水酸化ナトリウムも、毒物及び劇物取締法で原体と5%を超える製剤が劇物に指定されている。 Further, in the fiber composition according to Patent Document 2, when sodium hydroxide is used to neutralize the carboxyvinyl polymer, the sodium hydroxide also exceeds 5% of the drug substance according to the Poisonous and Deleterious Substances Control Law. The product is designated as a deleterious substance.
 さらに、前記特許文献3に係る頭髪化粧料では、皮膚刺激性などの点で、人体に対する安全性に問題のある抗菌剤や殺菌剤を使わないようにしているにもかかわらず、劇物に指定されている水酸化ナトリウム液を使ってギシギシ抽出液のpHを調整している。 Further, the hair cosmetic according to Patent Document 3 is designated as a deleterious substance even though it does not use antibacterial agents or bactericidal agents that have a problem in safety to the human body in terms of skin irritation and the like. The pH of the squeaky extract is adjusted using the sodium hydroxide solution.
 加えて、前記特許文献4に係るペットの洗浄用化粧料では、アロエハーブ酵素で化粧料のpHを調整するようにしているにもかかわらず、鹸化(けんか)には劇物に指定されている水酸化ナトリウムや水酸化カリウムが使われている。 In addition, in the pet cleaning cosmetics according to Patent Document 4, although the pH of the cosmetics is adjusted by the aloe herb enzyme, it is designated as a deleterious substance for saponification. Sodium hydroxide and potassium hydroxide are used.
 そこで、この発明では、前記した課題を解決し、劇物に指定されている水酸化ナトリウムや水酸化カリウムを使わずに、化粧料のpHを調整したスキンケア化粧料を提供することを目的とする。特に、この発明では、中和反応による増粘作用を目的に添加されているカルボキシビニルポリマーを、水酸化ナトリウムや水酸化カリウムを使わずに中和したゲル状のスキンケア化粧料を提供することを目的とする。 Therefore, an object of the present invention is to solve the above-mentioned problems and to provide a skin care cosmetic having an adjusted pH of the cosmetic without using sodium hydroxide or potassium hydroxide designated as deleterious substances. .. In particular, the present invention provides a gel-like skin care cosmetic product in which a carboxyvinyl polymer added for the purpose of thickening action by a neutralization reaction is neutralized without using sodium hydroxide or potassium hydroxide. The purpose.
 前記課題を解決するため、請求項1に係る発明では、pH調整剤として水酸化ナトリウムや水酸化カリウムの配合が処方設計された既知の化粧料組成物について、配合することになっている水酸化ナトリウムや水酸化カリウムの代わりに、強アルカリ電解水で化粧料組成物、より正しくは、水酸化ナトリウムや水酸化カリウムを除いた既知の化粧料組成物のpHを調整するようにした。 In order to solve the above-mentioned problems, in the invention according to claim 1, a known cosmetic composition in which sodium hydroxide or potassium hydroxide is formulated and designed as a pH adjusting agent is to be blended. Instead of sodium and potassium hydroxide, strong alkaline electrolyzed water was used to adjust the pH of the cosmetic composition, or more correctly, known cosmetic compositions excluding sodium hydroxide and potassium hydroxide.
 請求項2に係る発明では、pH13.0以上pH14以下の強アルカリ電解水で、化粧料組成物のpHを調整するようにした。 In the invention according to claim 2, the pH of the cosmetic composition is adjusted with strong alkaline electrolyzed water having a pH of 13.0 or more and a pH of 14 or less.
 請求項3に係る発明では、強アルカリ電解水で、既知の化粧料組成物に添加されているカルボキシビニルポリマーを中和するようにした。 In the invention according to claim 3, strong alkaline electrolyzed water is used to neutralize the carboxyvinyl polymer added to the known cosmetic composition.
 請求項4に係る発明では、強アルカリ電解水で、抗菌成分や殺菌成分が配合されている既知の化粧料組成物のpHを調整するようにした。 In the invention according to claim 4, the pH of a known cosmetic composition containing an antibacterial component and a bactericidal component is adjusted with strongly alkaline electrolyzed water.
 請求項1に係る発明によれば、配合することになっている水酸化ナトリウムや水酸化カリウムの代わりに、強アルカリ電解水で化粧料組成物のpHを調整するようにしたので、スキンケア化粧料に、より正しくは、既知の化粧料組成物からなるスキンケア化粧料に、水酸化ナトリウムと水酸化カリウムを使わないようにするできる。ここで、水酸化ナトリウムと水酸化カリウムは、毒物及び劇物取締法で原体と5%を超える製剤が劇物に指定されているところ、化粧料に使用される水酸化ナトリウムや水酸化カリウムの配合量は一般に1%以下であり、また、水酸化ナトリウムや水酸化カリウムは中和反応によって強アルカリ性の性質が打ち消されているため、安全性に問題はないものと考えられている。 According to the invention of claim 1, instead of sodium hydroxide and potassium hydroxide to be blended, the pH of the cosmetic composition is adjusted with strong alkaline electrolyzed water, so that the skin care cosmetics More correctly, it is possible to avoid the use of sodium hydroxide and potassium hydroxide in skin care cosmetics consisting of known cosmetic compositions. Here, sodium hydroxide and potassium hydroxide are designated as deleterious substances by the Toxic and Deleterious Substances Control Law, but sodium hydroxide and potassium hydroxide used in cosmetics are specified as deleterious substances. The blending amount of sodium hydroxide is generally 1% or less, and since the strongly alkaline property of sodium hydroxide and potassium hydroxide is canceled by the neutralization reaction, it is considered that there is no problem in safety.
 しかしながら、請求項1に係る発明によれば、スキンケア化粧料に、劇物に指定されている水酸化ナトリウムと水酸化カリウムを使わないようにできるので、スキンケア化粧料の安全性をより高めることができる。そこで、請求項1に係る発明によれば、スキンケア化粧料を、成人と比べて体重が軽い、例えば乳幼児、犬や猫などのペットにも、安心して使えるようにすることができる。 However, according to the invention of claim 1, since sodium hydroxide and potassium hydroxide designated as deleterious substances can be prevented from being used in the skin care cosmetics, the safety of the skin care cosmetics can be further enhanced. can. Therefore, according to the first aspect of the present invention, the skin care cosmetic can be safely used even for pets such as infants, dogs and cats whose weight is lighter than that of adults.
 また、請求項1に係る発明によれば、スキンケア化粧料に、劇物に指定されている水酸化ナトリウムと水酸化カリウムを使わないようにできるので、化粧料の製造過程での水酸化ナトリウムと水酸化カリウムによる漏出事故や暴露事故をなくすこともできる。加えて、請求項1に係る発明によれば、スキンケア化粧料に、劇物に指定されている水酸化ナトリウムと水酸化カリウムを使わないようにできるので、化粧料の製造工場などに毒物劇物取扱責任者を置かなくてすみ、化粧料原料の保管管理や廃棄の労力を軽減することもできる。 Further, according to the invention of claim 1, since sodium hydroxide and potassium hydroxide designated as deleterious substances can be prevented from being used in skin care cosmetics, sodium hydroxide in the manufacturing process of cosmetics can be used. It is also possible to eliminate leakage accidents and exposure accidents caused by potassium hydroxide. In addition, according to the invention of claim 1, since sodium hydroxide and potassium hydroxide designated as deleterious substances can be prevented from being used in skin care cosmetics, poisonous deleterious substances can be used in cosmetic manufacturing factories and the like. It is not necessary to have a person in charge of handling, and it is possible to reduce the labor of storage management and disposal of cosmetic raw materials.
 ここで、強アルカリ電解水は、水に炭酸カリウムを混ぜた水溶液を電気分解して得られるものであり、より正しくは、水に炭酸カリウムを混ぜた水溶液を電気分解して、その水溶液からイオン交換膜を通してイオンが純水に移動することで生成されるものである。このように、強アルカリ電解水は、水と食品添加物にも指定される炭酸カリウムを原料にしており、原料は水と食品添加物だけ、より正しくは、水とイオンだけなので安全性が高く、環境負荷も少ない。このように、請求項1に係る発明によれば、安全性の高い強アルカリ電解水で、化粧料組成物のpHを調整するようにしたので、スキンケア化粧料の安全性をより高めることができるのである。 Here, the strong alkaline electrolyzed water is obtained by electrolyzing an aqueous solution of water mixed with potassium carbonate, and more correctly, the aqueous solution of water mixed with potassium carbonate is electrolyzed and ions are generated from the aqueous solution. It is generated by the movement of ions to pure water through the exchange membrane. In this way, strong alkaline electrolyzed water is made from potassium carbonate, which is also designated as water and food additives, and the raw materials are only water and food additives, more correctly, only water and ions, so it is highly safe. , The environmental load is also small. As described above, according to the invention of claim 1, since the pH of the cosmetic composition is adjusted with highly safe strong alkaline electrolyzed water, the safety of the skin care cosmetic can be further enhanced. It is.
 さらに、請求項1に係る発明によれば、既知の化粧料組成物について、配合することになっている水酸化ナトリウムや水酸化カリウムの代わりに、強アルカリ電解水で化粧料組成物のpHを調整するようにしたので、既知のスキンケア化粧品を、水酸化ナトリウムと水酸化カリウム不使用のスキンケア化粧品にすることができる。そのため、請求項1に係る発明によれば、既知のスキンケア化粧品を水酸化ナトリウムと水酸化カリウム不使用のスキンケア化粧品にできるので、既知のスキンケア化粧品を、安全性を高めて刷新することもできる。 Further, according to the invention of claim 1, for a known cosmetic composition, the pH of the cosmetic composition is adjusted with strong alkaline electrolyzed water instead of sodium hydroxide or potassium hydroxide to be blended. Since it has been adjusted, known skin care cosmetics can be made into skin care cosmetics that do not use sodium hydroxide and potassium hydroxide. Therefore, according to the invention of claim 1, since the known skin care cosmetic can be made into a skin care cosmetic that does not use sodium hydroxide and potassium hydroxide, the known skin care cosmetic can be renewed with enhanced safety.
 請求項2に係る発明によれば、pH13.0以上pH14以下の強アルカリ電解水で、化粧料組成物のpHを調整するようにしたので、水酸化ナトリウムや水酸化カリウムの代わりに、強アルカリ電解水で化粧料組成物のpHを調整することができる。 According to the invention of claim 2, since the pH of the cosmetic composition is adjusted with strong alkaline electrolyzed water having a pH of 13.0 or more and pH 14 or less, the strong alkali is used instead of sodium hydroxide or potassium hydroxide. The pH of the cosmetic composition can be adjusted with electrolyzed water.
 請求項3に係る発明によれば、強アルカリ電解水で、既知の化粧料組成物に添加されているカルボキシビニルポリマーを中和するようにしたので、既知のゲル状スキンケア化粧品を、水酸化ナトリウムと水酸化カリウム不使用のゲル状スキンケア化粧品にすることができる。 According to the invention of claim 3, strong alkaline electrolyzed water is used to neutralize the carboxyvinyl polymer added to the known cosmetic composition, so that the known gel-like skin care cosmetic can be used as sodium hydroxide. And can be a gel-like skin care cosmetic that does not use potassium hydroxide.
 請求項4に係る発明によれば、強アルカリ電解水で、抗菌成分や殺菌成分が配合されている既知の化粧料組成物のpHを調整するようにしたので、既知の薬用スキンケア化粧品、例えば薬用ハンドソープや、デオドラント製品、ふけ防止用のヘアケア製品などを、水酸化ナトリウムと水酸化カリウム不使用の薬用スキンケア化粧品にすることができる。 According to the invention of claim 4, since the pH of a known cosmetic composition containing an antibacterial component and a bactericidal component is adjusted with strong alkaline electrolyzed water, a known medicated skin care cosmetic product, for example, medicinal product, is used. Hand soaps, deodorant products, anti-foam hair care products, etc. can be made into medicated skin care cosmetics that do not use sodium hydroxide and potassium hydroxide.
 まず、この発明の創作の基礎となる事項について簡単に説明する。発明者は、アルカリ電解水で水溶性切削油剤を希釈して得る水溶性冷却液の製造装置(製品名をアクアナックス環境加工水生成装置といい、以下、nax201という。アクアナックスは出願人の登録商標(登録第5286308号))の製造、販売を行っている。ここで、nax201は、pH12.5(常温20℃にて測定、以下同様)という、いわゆる強アルカリ電解水を生成することができる電解イオン水生成機を備えていることを特徴としている。そして、nax201は、強アルカリ電解水で水溶性切削油剤を希釈することで、水溶性冷却液の腐敗を防止することができるものである。 First, I will briefly explain the matters that are the basis of the creation of this invention. The inventor is an apparatus for producing a water-soluble coolant obtained by diluting a water-soluble cutting oil with alkaline electrolyzed water (the product name is referred to as an aqua-ax environmentally processed water generator, hereinafter referred to as nax201, and aqua-ax is registered by the applicant. Manufactures and sells the trademark (Registration No. 5286308). Here, nax201 is characterized by being provided with an electrolytic ionized water generator capable of producing so-called strong alkaline electrolyzed water having a pH of 12.5 (measured at room temperature of 20 ° C., the same applies hereinafter). The nax201 can prevent the water-soluble coolant from spoiling by diluting the water-soluble cutting oil with strong alkaline electrolyzed water.
 発明者は、先の発明(特許第6097992号)では、nax201が強アルカリ電解水を生成できることを生かし、強アルカリ電解水で水溶性切削油剤を希釈するようにして、従来の装置よりも簡素で小型の水溶性冷却液の製造装置を開発するなど、アルカリ性の水溶液が有する油汚れを落としたり、菌を減少させたりできる効果を生かして、「地球環境にやさしく、汚れもきれいにできる製品」や「地球から生まれた「水」だけで除菌できる製品」を開発してきた。 In the previous invention (Patent No. 6097992), the inventor took advantage of the fact that nax201 can generate strong alkaline electrolyzed water, and diluted the water-soluble cutting oil with strong alkaline electrolyzed water, which is simpler than the conventional device. Taking advantage of the effects of alkaline aqueous solutions, such as the development of a small water-soluble coolant manufacturing device, that can remove oil stains and reduce bacteria, "products that are friendly to the global environment and can clean stains" and " We have developed "products that can be sterilized only with" water "born from the earth."
 発明者が開発した製品に、油脂分解洗剤(製品名をオイルナックスという。オイルナックスは出願人の登録商標(登録第5284719号))がある。ここで、オイルナックスは、油脂分解性能を持ち、特に、水を電気分解してアルカリ性を維持させたアルカリ電解タイプは、業務用食器や厨房(ちゅうぼう)設備の洗浄、油の付着したタオルや作業着の洗浄などに効果を発揮する油脂分解洗剤である。そのため、オイルナックスは、飲食業や製造業のほか、リネンサプライ業、中でもエッセンシャルオイルを使うアロマセラピー専門店やエステティックサロンなどで高い評価を得ている。 The product developed by the inventor includes an oil-decomposing detergent (the product name is called Oil Nax. Oil Nax is a registered trademark of the applicant (Registration No. 5284719)). Here, Oil Nax has oil and fat decomposition performance, and in particular, the alkaline electrolytic type that electrolyzes water to maintain its alkalinity is used for cleaning commercial tableware and kitchen equipment, towels with oil, and so on. An oil-and-fat decomposition detergent that is effective for cleaning work clothes. Therefore, Oil Nax is highly evaluated not only in the restaurant and manufacturing industries, but also in the linen supply industry, especially in aromatherapy specialty stores and esthetic salons that use essential oils.
 発明者は、現状に満足せず、より良い製品を目指していくことをモットーにしているところ、タオルの洗浄にオイルナックスをお使いいただいているお客様から、ウイルス感染症の予防対策として、タオルに抗ウイルスの効果を望む声を耳にした。 The inventor's motto is not to be satisfied with the current situation and to aim for a better product, but from customers who use Oil Nax to wash towels, as a preventive measure against viral infections, towels are used. I heard a voice hoping for an anti-virus effect.
 そこで、発明者は、お客様の要望に応えるべく、加工繊維(一般社団法人繊維評価技術協議会が認証する繊維上の特定ウイルスの数を減少させる加工のうち、認証基準を満たす繊維製品のこと。抗ウイルス加工の認証ともいう。)に使用された成分の中に、オイルナックスに抗菌と抗ウイルスの効果をプラスできる成分、具体的には、前記特許文献2に係る抗菌性、抗ウイルスおよび花粉崩壊性を有する繊維用組成物を見つけた。 Therefore, the inventor is a processed fiber (a textile product that meets the certification criteria among the processes that reduce the number of specific viruses on the fiber certified by the Textile Evaluation Technology Council) in order to meet the customer's request. Among the components used in (also referred to as anti-virus processing certification), components that can add antibacterial and anti-virus effects to oil nax, specifically, antibacterial, anti-virus and pollen according to Patent Document 2. We have found a composition for fibers that has disintegration properties.
 発明者は、前記特許文献2に係る繊維用組成物に使用されている成分と同じ成分をオイルナックスに使用することに取り組む中で、前記特許文献2に係る繊維用組成物にはpHを調整するために、劇物に指定されている水酸化ナトリウムが使われていることが気になった。 While the inventor is working on using the same components as those used in the fiber composition according to Patent Document 2 for oil caustic, the pH of the fiber composition according to Patent Document 2 is adjusted. I was worried that sodium hydroxide, which is designated as a deleterious substance, is used for this purpose.
 そして、発明者は、水酸化ナトリウムを使わずにカルボキシビニルポリマーを中和できると、安全性をより高められると考えるようになった。 Then, the inventor came to think that the safety could be further enhanced if the carboxyvinyl polymer could be neutralized without using sodium hydroxide.
 そこで、発明者は、アルカリ性の度合いを高めた高機能型のnax301が、業界最高水準のpH13.1の強アルカリ電解水を生成できることに着目した。また、発明者は、強アルカリ電解水の製造販売を始めてから10年ほど経過するところ、10年前に製造した強アルカリ電解水が高いpHを維持し続けており、自社で製造した強アルカリ電解水はほとんど経時変化しないことに注目した。そして、発明者は、業界最高水準のpH13を超える強アルカリ性を有し、ほとんど経時変化しないpH値が安定した、自社の強アルカリ電解水であれば、水酸化ナトリウムや水酸化カリウムの代わりにできることを見いだし、この発明を創作するに至ったものである。 Therefore, the inventor paid attention to the fact that the highly functional nax301 with an increased degree of alkalinity can produce the industry's highest level of strong alkaline electrolyzed water with a pH of 13.1. In addition, about 10 years have passed since the inventor started manufacturing and selling strong alkaline electrolyzed water, and the strong alkaline electrolyzed water manufactured 10 years ago has continued to maintain a high pH, and the strong alkaline electrolyzed water manufactured in-house has been maintained. It was noted that water hardly changed over time. The inventor can replace sodium hydroxide or potassium hydroxide with his own strong alkaline electrolyzed water, which has a strong alkalinity exceeding the industry's highest level of pH 13, and has a stable pH value that hardly changes over time. He discovered and created this invention.
 次に、この発明の実施形態について詳細に説明する。実施形態に係るスキンケア化粧料は、pH調整剤として水酸化ナトリウムや水酸化カリウムの配合が処方設計された既知の化粧料組成物について、配合することになっている水酸化ナトリウムや水酸化カリウムの代わりに、強アルカリ電解水で既知の化粧料組成物、より正しくは、水酸化ナトリウムや水酸化カリウムを除いた既知の化粧料組成物のpHを調整して得たものである。 Next, an embodiment of the present invention will be described in detail. The skin care cosmetic according to the embodiment is a known cosmetic composition formulated and designed to contain sodium hydroxide or potassium hydroxide as a pH adjuster, and is to be blended with sodium hydroxide or potassium hydroxide. Instead, it is obtained by adjusting the pH of a known cosmetic composition with strong alkaline electrolyzed water, or more correctly, a known cosmetic composition excluding sodium hydroxide and potassium hydroxide.
 スキンケア化粧料は、石鹸や化粧水、乳液などのように肌を清潔にし整えることを目的とする化粧用の品で、基礎化粧品ともいう。スキンケア化粧料の剤形は、固形石鹸のような固形状でも、化粧水のような液状でも、保湿ジェルのようなゲル状でも、どのような剤形でも構わないところ、ここでは、溶液が多少の弾性と固さをもってゼリー状に固化したゲル状である。 Skin care cosmetics are cosmetic products that aim to cleanse and condition the skin, such as soap, lotion, and milky lotion, and are also called basic cosmetics. The dosage form of skin care cosmetics may be solid like bar soap, liquid like lotion, gel like moisturizing gel, or any dosage form. Here, the solution is a little. It is a gel-like solidified jelly with the elasticity and hardness of.
 既知の化粧料組成物は、スキンケア化粧料に配合する成分の組み合わせが見いだされている(処方設計されているともいう。)もので、ここでは、pH調整剤として水酸化ナトリウムや水酸化カリウムの配合が処方設計されたものである。また、ここでは、中和反応による増粘作用を目的にカルボキシビニルポリマーの添加が処方設計されたものでもある。 In known cosmetic compositions, a combination of ingredients to be blended in skin care cosmetics has been found (also referred to as a formulation design), and here, sodium hydroxide or potassium hydroxide is used as a pH adjuster. The formulation is prescription designed. Further, here, the addition of a carboxyvinyl polymer is formulated and designed for the purpose of thickening action by a neutralization reaction.
 強アルカリ電解水は、水を電気分解することで得られるpH11以上の水溶液であり、ここでは、pH13.0以上pH14以下の水溶液である。強アルカリ電解水は、水に炭酸カリウムを混ぜた水溶液を電気分解して、その水溶液からイオン交換膜を通してイオンが純水に移動することで生成されるものである。 The strong alkaline electrolyzed water is an aqueous solution having a pH of 11 or more and obtained by electrolyzing water, and here, it is an aqueous solution having a pH of 13.0 or more and a pH of 14 or less. Strong alkaline electrolyzed water is produced by electrolyzing an aqueous solution of water mixed with potassium carbonate and transferring ions from the aqueous solution to pure water through an ion exchange membrane.
 次いで、実施形態に係るスキンケア化粧料について、既知の化粧料組成物を前記特許文献1に係るゲル状のスキンケア化粧料、具体的には弱酸性ゲル状洗顔料として説明する。実施形態に係るスキンケア化粧料では、既知の化粧料組成物は以下のとおりであり、pH調整剤として水酸化カリウムの配合が処方設計されている。
      成分                 配合量(重量%)
水溶性カルボキシビニルポリマー            1.0
ソルビトール                     3.0
ヤシ油脂肪酸アミドプロピルジメチルアミノ酢酸ベタイン 0.5
メツキンスM                     0.3
メツキンスP                     0.2
1,3-ブチレングリコール              4.0
ポリオキシエチレングリセリルモノステアレート     5.0
ポリオキシエチレン硬化ヒマシ油            4.0
香料                         0.6
水酸化カリウム                    0.4
精製水                        残部
Next, regarding the skin care cosmetic according to the embodiment, the known cosmetic composition will be described as a gel-like skin care cosmetic according to Patent Document 1, specifically, a weakly acidic gel-like face wash. In the skin care cosmetics according to the embodiment, the known cosmetic compositions are as follows, and a formulation of potassium hydroxide as a pH adjuster is formulated and designed.
Ingredient content (% by weight)
Water-soluble carboxyvinyl polymer 1.0
Sorbitol 3.0
Coconut oil fatty acid amide propyldimethylaminoacetic acid betaine 0.5
Metskins M 0.3
Metskins P 0.2
1,3-butylene glycol 4.0
Polyoxyethylene glyceryl monostearate 5.0
Polyoxyethylene hydrogenated castor oil 4.0
Fragrance 0.6
Potassium hydroxide 0.4
Purified water balance
 実施形態に係るスキンケア化粧料は、配合することになっている水酸化カリウムの代わりに、上記成分を溶かした溶液に強アルカリ電解水を加えてpH6.0に調整して、弱酸性ゲル状洗顔料を調製するものである。 In the skin care cosmetic according to the embodiment, instead of potassium hydroxide to be blended, strong alkaline electrolyzed water is added to a solution in which the above components are dissolved to adjust the pH to 6.0, and a weakly acidic gel-like face wash is performed. It prepares the fee.
 このように、実施形態に係るスキンケア化粧料は、配合することになっている水酸化カリウムの代わりに、強アルカリ電解水でカルボキシビニルポリマーを中和して適度な粘性を得て、弱酸性ゲル状洗顔料に水酸化カリウムを使わないですむ。 As described above, in the skin care cosmetics according to the embodiment, instead of potassium hydroxide to be blended, the carboxyvinyl polymer is neutralized with strong alkaline electrolyzed water to obtain appropriate viscosity, and a weakly acidic gel is obtained. You do not need to use potassium hydroxide for the skin wash.
 続いて、他の実施形態に係るスキンケア化粧料について、既知の化粧料組成物を前記特許文献3に係る頭髪化粧料、具体的にはふけ防止用ヘアトニックとして説明する。他の実施形態に係るスキンケア化粧料では、有効成分を含む抽出液を水酸化ナトリウム水溶液でアルカリ処理するよう具体的に例示されているところを、水酸化ナトリウム水溶液の代わりに、強アルカリ電解水でアルカリ処理するものである。 Subsequently, regarding the skin care cosmetics according to other embodiments, a known cosmetic composition will be described as a hair cosmetic according to Patent Document 3, specifically, a hair tonic for preventing dandruff. In the skin care cosmetics according to the other embodiments, the extract containing the active ingredient is specifically exemplified to be alkaline-treated with an aqueous sodium hydroxide solution, but instead of the aqueous sodium hydroxide solution, a strong alkaline electrolyzed water is used. It is treated with alkali.
 ここで、前記特許文献3に係る頭髪化粧料では、ギシギシ抽出物の抽出法を、ギシギシの根5.0kgを細片化し、ジクロロメタンで一夜冷浸する。この抽出液を濃縮し、5%水酸化ナトリウム水溶液で処理して酸性部をとり、これをシリカゲルカラムクロマトグラフィに付しクロロホルム溶離部を濃縮、再結晶して、0.53gの黄色状結晶を得ることができると具体的に例示している。そこで、他の実施形態に係るスキンケア化粧料では、ギシギシの抽出液を濃縮したものを、水酸化ナトリウム水溶液の代わりに、強アルカリ電解水でアルカリ処理するものである。 Here, in the hair cosmetic according to Patent Document 3, the extraction method of Rumex japonicus extract is performed by fragmenting 5.0 kg of Rumex japonicus root and immersing it in dichloromethane overnight. This extract is concentrated and treated with a 5% aqueous sodium hydroxide solution to remove an acidic part, which is subjected to silica gel column chromatography to concentrate and recrystallize the chloroform eluent to obtain 0.53 g of yellowish crystals. It is specifically illustrated that it can be done. Therefore, in the skin care cosmetics according to the other embodiment, the concentrated extract of Gishigishi is alkaline-treated with strong alkaline electrolyzed water instead of the sodium hydroxide aqueous solution.
 そして、他の実施形態に係るスキンケア化粧料では、精製水36.5gにグリセリン5gを加え加熱溶解させ、冷却後に色素適量を加えた水相部に、エチルアルコール55gにポリオキシエチレンオレイルアルコールエーテル2g、ギシギシの抽出黄色状結晶1.5g、香料を適量加え、室温下に溶解させて得たアルコール相を加えて可溶化して、ふけ防止効果のあるヘアトニックを得るものである。 In the skin care cosmetics according to the other embodiment, 5 g of glycerin is added to 36.5 g of purified water to dissolve it by heating, and after cooling, 55 g of ethyl alcohol and 2 g of polyoxyethylene oleyl alcohol ether are added to the aqueous phase portion to which an appropriate amount of dye is added. , 1.5 g of extracted yellowish crystals of glycerin, an appropriate amount of fragrance are added, and an alcohol phase obtained by dissolving at room temperature is added to solubilize the hair tonic to obtain a hair tonic having an anti-blurring effect.
 このように、他の実施形態に係るスキンケア化粧料は、水酸化ナトリウム水溶液の代わりに、強アルカリ電解水で有効成分を含む抽出液をアルカリ処理して、ふけ防止用ヘアトニックに水酸化ナトリウムを使わないですむ。 As described above, in the skin care cosmetics according to the other embodiments, instead of the sodium hydroxide aqueous solution, the extract containing the active ingredient is alkaline-treated with strong alkaline electrolyzed water to add sodium hydroxide to the hair tonic for preventing indulgence. You don't have to use it.
 続いて、別の他の実施形態に係るスキンケア化粧料について、既知の化粧料組成物を前記特許文献4に係るペットの洗浄用化粧料、具体的には普通肌、カット犬種専用の石鹸として説明する。別の他の実施形態に係るスキンケア化粧料では、既知の化粧料組成物は以下のとおりであり、pH調整剤として水酸化ナトリウムの配合が処方設計されている。
ココナッツオイル   200g
パームオイル     200g
ヘンプシードオイル  100g
シアバター      100g
グレープシードオイル 150g
アボカドオイル     10g
    (オイル合計 760g)
水酸化ナトリウム   107g
精製水        147g
アロエハーブ酵素   100g
ハーブパウダー  50~70g
Subsequently, with respect to the skin care cosmetics according to another other embodiment, the known cosmetic composition is used as a pet cleaning cosmetic according to Patent Document 4, specifically, a soap for normal skin and a cut dog breed. explain. In the skin care cosmetics according to another other embodiment, the known cosmetic compositions are as follows, and a formulation of sodium hydroxide as a pH adjuster is formulated and designed.
Coconut oil 200g
Palm oil 200g
Hemp seed oil 100g
Shea butter 100g
Grape seed oil 150g
Avocado oil 10g
(Total oil 760g)
Sodium hydroxide 107g
Purified water 147g
Aloe herb enzyme 100g
Herb powder 50-70g
 別の他の実施形態に係るスキンケア化粧料は、配合することになっている水酸化ナトリウムの代わりに、より正しくは、水酸化ナトリウムを精製水に混合して溶かした水の代わりに、強アルカリ電解水を、上記オイルを調合した混合オイルに中にゆっくり注入し、注入後に撹拌(かくはん)してpHを調整する、より正しくは、鹸化させるものである。 The skin care cosmetics according to another other embodiment replace the sodium hydroxide to be blended, more correctly, instead of the water in which sodium hydroxide is mixed with purified water and dissolved, a strong alkali. Electrolyzed water is slowly poured into a mixed oil containing the above oil, and after the injection, the pH is adjusted by stirring (stirring), more correctly, saponification is performed.
 このように、別の他の実施形態に係るスキンケア化粧料は、配合することになっている水酸化ナトリウムの代わりに、強アルカリ電解水で混合オイルのpHを調整して、犬用の石鹸に水酸化ナトリウムを使わないですむ。 Thus, the skin care cosmetics according to another other embodiment can be made into soap for dogs by adjusting the pH of the mixed oil with strongly alkaline electrolyzed water instead of the sodium hydroxide to be blended. You don't have to use sodium hydroxide.
 以上、この発明の実施形態について説明したが、この発明は前記実施形態には限定されない。例えば、実施形態に係るスキンケア化粧料では、弱酸性のスキンケア化粧料と説明したところ、肌に優しい範囲であれば、中性でも、弱アルカリ性でも構わない。 Although the embodiments of the present invention have been described above, the present invention is not limited to the above-described embodiments. For example, in the skin care cosmetics according to the embodiment, although it is described as a weakly acidic skin care cosmetic, it may be neutral or weakly alkaline as long as it is in a range that is gentle on the skin.
 また、他の実施形態に係るスキンケア化粧料では、抗菌成分や殺菌成分を、抗菌剤や殺菌剤の代わりにタデ科植物ギシギシ抽出物と説明したところ、抗菌や殺菌の効果があれば、抗菌剤や殺菌剤でも、どのような成分でも構わない。 Further, in the skin care cosmetics according to other embodiments, the antibacterial component and the bactericidal component are described as an extract of Polygonaceae plant Gishigishi instead of the antibacterial agent and the bactericidal agent. It can be a disinfectant, a disinfectant, or any ingredient.

Claims (4)

  1.  スキンケア化粧料であって、
     pH調整剤として水酸化ナトリウムまたは水酸化カリウムの配合が処方設計された既知の化粧料組成物について、
     配合することになっている水酸化ナトリウムまたは水酸化カリウムの代わりに、強アルカリ電解水で化粧料組成物のpHを調整することを特徴とする水酸化ナトリウムおよび水酸化カリウム不使用のスキンケア化粧料。
    It ’s a skin care cosmetic,
    For known cosmetic compositions formulated and designed to contain sodium hydroxide or potassium hydroxide as a pH regulator.
    Sodium hydroxide and potassium hydroxide free skin care cosmetics characterized by adjusting the pH of the cosmetic composition with strongly alkaline electrolyzed water instead of the sodium hydroxide or potassium hydroxide to be blended. ..
  2.  前記強アルカリ電解水が、pH13.0以上pH14以下であることを特徴とする請求項1に記載の水酸化ナトリウムおよび水酸化カリウム不使用のスキンケア化粧料。 The skin care cosmetic that does not use sodium hydroxide and potassium hydroxide according to claim 1, wherein the strong alkaline electrolyzed water has a pH of 13.0 or more and a pH of 14 or less.
  3.  前記既知の化粧料組成物が、カルボキシビニルポリマーを含有していることを特徴とする請求項1または請求項2に記載の水酸化ナトリウムおよび水酸化カリウム不使用のスキンケア化粧料。 The skin care cosmetic without sodium hydroxide and potassium hydroxide according to claim 1 or 2, wherein the known cosmetic composition contains a carboxyvinyl polymer.
  4.  前記既知の化粧料組成物が、抗菌成分または殺菌成分を含有していることを特徴とする請求項1から請求項3に記載の水酸化ナトリウムおよび水酸化カリウム不使用のスキンケア化粧料。 The skin care cosmetics without sodium hydroxide and potassium hydroxide according to claims 1 to 3, wherein the known cosmetic composition contains an antibacterial component or a bactericidal component.
PCT/JP2020/024272 2020-06-21 2020-06-21 Skincare cosmetic free of sodium hydroxide and potassium hydroxide WO2021260750A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2022531243A JP7430009B2 (en) 2020-06-21 2020-06-21 Skin care cosmetics without sodium hydroxide and potassium hydroxide
PCT/JP2020/024272 WO2021260750A1 (en) 2020-06-21 2020-06-21 Skincare cosmetic free of sodium hydroxide and potassium hydroxide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2020/024272 WO2021260750A1 (en) 2020-06-21 2020-06-21 Skincare cosmetic free of sodium hydroxide and potassium hydroxide

Publications (1)

Publication Number Publication Date
WO2021260750A1 true WO2021260750A1 (en) 2021-12-30

Family

ID=79282182

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2020/024272 WO2021260750A1 (en) 2020-06-21 2020-06-21 Skincare cosmetic free of sodium hydroxide and potassium hydroxide

Country Status (2)

Country Link
JP (1) JP7430009B2 (en)
WO (1) WO2021260750A1 (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004238302A (en) * 2003-02-04 2004-08-26 Yukitoshi Kubota Silicone compound-containing alkali ion cosmetic
JP2010037220A (en) * 2008-07-31 2010-02-18 Toyo Shinyaku Co Ltd Cosmetic
JP2012092022A (en) * 2010-10-25 2012-05-17 Tokuhon Corp External skin patch
JP2016159121A (en) * 2015-03-05 2016-09-05 株式会社ist・イスト Wet towel for wiping body
JP2018165266A (en) * 2017-03-28 2018-10-25 喜雅 井上 Peeling gel using basic aqueous solution
CN109077940A (en) * 2018-08-23 2018-12-25 山西纳安生物科技有限公司 A kind of beauty mask and preparation method thereof of electrolysis water preparation

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6085625B2 (en) 2014-11-27 2017-02-22 株式会社バイオレドックス研究所 Cosmetic liquid and method for producing the same

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004238302A (en) * 2003-02-04 2004-08-26 Yukitoshi Kubota Silicone compound-containing alkali ion cosmetic
JP2010037220A (en) * 2008-07-31 2010-02-18 Toyo Shinyaku Co Ltd Cosmetic
JP2012092022A (en) * 2010-10-25 2012-05-17 Tokuhon Corp External skin patch
JP2016159121A (en) * 2015-03-05 2016-09-05 株式会社ist・イスト Wet towel for wiping body
JP2018165266A (en) * 2017-03-28 2018-10-25 喜雅 井上 Peeling gel using basic aqueous solution
CN109077940A (en) * 2018-08-23 2018-12-25 山西纳安生物科技有限公司 A kind of beauty mask and preparation method thereof of electrolysis water preparation

Also Published As

Publication number Publication date
JP7430009B2 (en) 2024-02-09
JPWO2021260750A1 (en) 2021-12-30

Similar Documents

Publication Publication Date Title
CA2833030C (en) Sodium hypochlorite-based body wash compositions
US20080254150A1 (en) Management of dermatitic symptoms of mammalian integument with emollient disinfectant formulations
CN107929104A (en) A kind of three-in-one wash and maintenance liquid of biology enzyme and preparation method thereof
CN107982135A (en) A kind of shampoo and preparation method thereof
WO2008121355A1 (en) Management of dermatitic symptoms of mammalian integument with emollient disinfectant formulations
CN107854329B (en) A kind of antibacterial moisturizing foam hand cleanser of easy wash type and preparation method thereof
KR101769519B1 (en) Method for Purification of Saponin from Soapberry and Cleanser Composition Containing Saponin
CN108531319A (en) A kind of antibacterial cleaning products and preparation method thereof
JP6482808B2 (en) Cleaning composition
WO2021260750A1 (en) Skincare cosmetic free of sodium hydroxide and potassium hydroxide
JP2005089402A (en) External anti-pruritic agent
RU2716155C1 (en) Composition for washing children's hair and bathing babies
JP7121400B2 (en) Cosmetic cleanser products and their uses
JP2001302495A (en) Skin-cleansing agent and skin-cleansing supplies
US20120177751A1 (en) Pediculosis Treatment and Prophylaxis
JPH11140497A (en) Catechin-containing soap
US10363203B1 (en) Method of use, and composition of, first responder wet wipes
JP2005089403A (en) External anti-pruritic agent
JP2006298891A (en) Hair detergent composition for preventing dandruff and itch
KR20230022466A (en) Natural shampoo-bar and manufacturing method thereof
GB2608609A (en) Skin and hair wash gels
CN113476328A (en) Bath cream containing naringin and application
CA3117437A1 (en) An antimicrobial composition
Tai et al. Application of personal care detergent formulations
KR20220090292A (en) Composition comprising phosphate for removal biofilm

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 20941835

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2022531243

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 20941835

Country of ref document: EP

Kind code of ref document: A1