WO2021114593A1 - 一种水性环保自动化施工的高耐候防护材料及其制备方法 - Google Patents

一种水性环保自动化施工的高耐候防护材料及其制备方法 Download PDF

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WO2021114593A1
WO2021114593A1 PCT/CN2020/095642 CN2020095642W WO2021114593A1 WO 2021114593 A1 WO2021114593 A1 WO 2021114593A1 CN 2020095642 W CN2020095642 W CN 2020095642W WO 2021114593 A1 WO2021114593 A1 WO 2021114593A1
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acrylic emulsion
water
nano
protective material
weather resistance
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PCT/CN2020/095642
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French (fr)
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梅天诚
周小安
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苏州振瑞昌材料科技有限公司
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/328Phosphates of heavy metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Definitions

  • the invention relates to the field of materials, in particular to a high weather resistance protective material for water-based environmental protection and automatic construction and a preparation method thereof.
  • metal anticorrosive materials are mainly oil-based paints. Since a large amount of organic solvents volatilize during the coating process of oil-based paints, it not only pollutes the environment, but also poses a major threat to human health. In recent years, water-based metal anti-corrosion materials that are pollution-free, energy-saving and cost-effective have become more and more popular, especially water-based protective materials that have the advantages of high weather resistance, long-lasting rust prevention, corrosion protection, environmental protection, water resistance, alkali resistance, and automatic construction. People's needs and requirements for protective materials.
  • the purpose of the present invention is to provide a highly weather-resistant protective material for water-based environmental protection and automated construction to meet the requirements of environmental protection and conservation.
  • the high weather resistance protective material consists of the following components by weight percentage: dispersant 0.5 to 1.2%, surfactant 0.1 to 0.2%, defoamer 0.4 to 0.8%, Polyethylene glycol 0.8 ⁇ 3.5%, n-butanol 0.1 ⁇ 1%, titanium dioxide 0.8 ⁇ 5.2%, active calcium 2 ⁇ 5%, nano calcium carbonate 1 ⁇ 3.5%, talc 2 ⁇ 5%, nano zinc oxide 0.5 ⁇ 2.5%, nano-silica 0.8 ⁇ 1.5%, barium sulfate 2 ⁇ 5%, aluminum phosphate 2 ⁇ 6%, zinc phosphate 4 ⁇ 8%, pure acrylic emulsion 10 ⁇ 20%, silicone acrylic emulsion 8 ⁇ 20%, benzene Acrylic emulsion is 10-25%, thickener is 0.8-1.5%, film-forming auxiliary agent is 1-2.5%, and the balance is water.
  • the weight percentage content of each component of the high weather resistance protective material is: 1 to 1.1% of dispersant, 0.12 to 0.15% of surfactant, 0.5 to 0.6% of defoamer, 1 to 3% of polyethylene glycol, N-butanol 0.2 ⁇ 0.5%, titanium dioxide 4.5 ⁇ 5%, active calcium 2.5 ⁇ 3.5%, nano calcium carbonate 1.1 ⁇ 1.5%, talc 2.5 ⁇ 3.5%, nano zinc oxide 2 ⁇ 2.2%, nano silicon oxide 1.2 ⁇ 1.4%, barium sulfate 3.2 ⁇ 3.5%, aluminum phosphate 5 ⁇ 5.5%, zinc phosphate 4.6 ⁇ 6%, pure acrylic emulsion 13-15%, silicone acrylic emulsion 12-18%, styrene acrylic emulsion 14-16%, thickening
  • the amount is 1.1-1.2%, the film-forming aid is 2-2.2%, and the balance is water.
  • the weight percentage of each component of the high weather resistance protective material is: 1.05% of dispersant, 0.13% of surfactant, 0.55% of defoamer, 1.5% of polyethylene glycol, 0.3% of n-butanol, titanium dioxide 4.8%, active calcium 3%, nano calcium carbonate 1.3%, talc 3.1%, nano zinc oxide 2.1%, nano silicon oxide 1.3%, barium sulfate 3.3%, aluminum phosphate 5.2%, zinc phosphate 5%, pure acrylic emulsion 14 %, 13% of silicone-acrylic emulsion, 15% of styrene-acrylic emulsion, 1.15% of thickener, 2.1% of film-forming aid, and the balance is water.
  • the water is deionized water.
  • a method for preparing the above-mentioned water-based environmentally friendly automatic construction high weather resistance protective material including the following steps:
  • Step 1 According to the order, add a certain weight ratio of dispersant, surfactant, defoamer, polyethylene glycol, n-butanol, titanium dioxide, active calcium, nano calcium carbonate, talc powder, nano zinc oxide, nano oxidation Put silicon, barium sulfate, aluminum phosphate, zinc phosphate, pure acrylic emulsion, silicon acrylic emulsion, styrene acrylic emulsion, thickener, and film forming aid into the water;
  • Step 2 Dispersant, surfactant, defoamer, polyethylene glycol, n-butanol, titanium dioxide, active calcium, nano calcium carbonate, talc, nano zinc oxide, nano silicon oxide, barium sulfate, aluminum phosphate, Zinc phosphate, pure acrylic emulsion, silicone acrylic emulsion, styrene-acrylic emulsion, thickener, and film-forming aid are added to the water and stirred evenly in the order of step 1.
  • the water is deionized water.
  • the water-based environmental protection automatic construction high weather resistance protective material of the present invention has the advantages of high weather resistance, long lasting rust prevention, anticorrosion, environmental protection, water resistance and alkali resistance, and is convenient for automatic construction, and meets the requirements of environmental protection and saving.
  • the preparation method of the highly weather-resistant protective material for water-based environmental protection and automated construction is simple and easy for mass production.
  • the water-based environmental protection automatic construction high weather resistance protective material provided by the present invention is composed of the following components by weight percentage: dispersant 0.5-1.2%, surfactant 0.1-0.2%, defoamer 0.4-0.8 %, polyethylene glycol 0.8 ⁇ 3.5%, n-butanol 0.1 ⁇ 1%, titanium dioxide 0.8 ⁇ 5.2%, active calcium 2 ⁇ 5%, nano calcium carbonate 1 ⁇ 3.5%, talc 2 ⁇ 5%, nano oxidation Zinc 0.5 ⁇ 2.5%, nano-silica 0.8 ⁇ 1.5%, barium sulfate 2 ⁇ 5%, aluminum phosphate 2 ⁇ 6%, zinc phosphate 4 ⁇ 8%, pure acrylic emulsion 10-20%, silicon acrylic emulsion 8-20% , Styrene-acrylic emulsion 10-25%, thickener 0.8-1.5%, film-forming aid 1-2.5%, the balance is water, of which water is deionized water.
  • the preparation method of the water-based environmental protection automatic construction high weather resistance protective material of the present invention includes the following steps:
  • Step 1 According to the order, add a certain weight ratio of dispersant, surfactant, defoamer, polyethylene glycol, n-butanol, titanium dioxide, active calcium, nano calcium carbonate, talc powder, nano zinc oxide, nano oxidation Put silicon, barium sulfate, aluminum phosphate, zinc phosphate, pure acrylic emulsion, silicon acrylic emulsion, styrene acrylic emulsion, thickener, and film forming aid into deionized water;
  • Step 2 Dispersant, surfactant, defoamer, polyethylene glycol, n-butanol, titanium dioxide, active calcium, nano calcium carbonate, talc, nano zinc oxide, nano silicon oxide, barium sulfate, aluminum phosphate, Zinc phosphate, pure acrylic emulsion, silicone acrylic emulsion, styrene-acrylic emulsion, thickener, and film-forming aid are added in deionized water and stirred evenly in the order of step 1.
  • weight percentage 1.05% of dispersant, 0.13% of surfactant, 0.55% of defoamer, 1.5% of polyethylene glycol, 0.3% of n-butanol, 4.8% of titanium dioxide, 3% of active calcium, 1.3% of nano-calcium carbonate, Talc 3.1%, nano zinc oxide 2.1%, nano silicon oxide 1.3%, barium sulfate 3.3%, aluminum phosphate 5.2%, zinc phosphate 5%, pure acrylic emulsion 14%, silicone acrylic emulsion 13%, styrene acrylic emulsion 15%, Thickener 1.15%, film-forming aid 2.1%, the balance is deionized water, and raw materials are prepared.
  • the prepared water-based environmentally friendly and automated construction high weather resistance protective material the samples using the high weather resistance protective material were immersed in water for 530 hours and 530 hours in salt water, and the surface did not bubble, bubble, and rust;
  • the samples using the highly weather-resistant protective material were soaked in a 5% sulfuric acid solution by volume for 135 hours, and after soaked in a 5% sodium hydroxide solution by volume for 135 hours, the surface did not bubble, bubble, and did not rust.
  • the water-based environmental protection automatic construction high weather resistance protective material of the present invention has the advantages of long-lasting rust prevention, corrosion resistance, environmental protection, water resistance and alkali resistance.
  • weight percentage 0.5% of dispersant, 0.1% of surfactant, 0.4% of defoamer, 0.8% of polyethylene glycol, 1% of n-butanol, 5.2% of titanium dioxide, 5% of active calcium, 1% of nano-calcium carbonate, Talc 2%, nano zinc oxide 0.5%, nano silicon oxide 0.8%, barium sulfate 2%, aluminum phosphate 6%, zinc phosphate 4%, pure acrylic emulsion 20%, silicone acrylic emulsion 20%, styrene acrylic emulsion 10%, Thickener 1.5%, film-forming aid 2.5%, the balance is deionized water, and raw materials are prepared.
  • the prepared water-based environmentally friendly automatic construction high weather resistance protective material the samples using the high weather resistance protective material were soaked in water for 500 hours and 500 hours in salt water, and the surface did not bubble, bubbling, or rust;
  • the samples using the high weather resistance protective material were soaked in a 5% sulfuric acid solution by volume for 120 hours, and after soaking in a 5% sodium hydroxide solution by volume for 120 hours, the surface did not bubble, bubble, and did not rust.
  • the water-based environmental protection automatic construction high weather resistance protective material of the present invention has the advantages of long-lasting rust prevention, corrosion resistance, environmental protection, water resistance and alkali resistance.
  • the prepared water-based environmentally friendly and automated construction high weather resistance protective material the samples using the high weather resistance protective material were immersed in water for 510 hours and 510 hours in salt water, and the surface did not bubble, bubble, or rust;
  • the samples using the high weather resistance protective material were soaked in a 5% sulfuric acid solution by volume for 120 hours, and after soaking in a 5% sodium hydroxide solution by volume for 120 hours, the surface did not bubble, bubble, and did not rust.
  • the water-based environmental protection automatic construction high weather resistance protective material of the present invention has the advantages of long-lasting rust prevention, corrosion resistance, environmental protection, water resistance and alkali resistance.
  • weight percentage 1% dispersant, 0.12% surfactant, 0.6% defoamer, 3% polyethylene glycol, 0.2% n-butanol, 5% titanium dioxide, 2.5% active calcium, 1.1% nano-calcium carbonate, Talc 3.5%, Nano Zinc Oxide 2%, Nano Silica 1.2%, Barium Sulfate 3.5%, Aluminum Phosphate 5%, Zinc Phosphate 6%, Pure Acrylic Emulsion 13%, Silicone Acrylic Emulsion 18%, Styrene Acrylic Emulsion 16%, Thickener 1.2%, film-forming aid 2.2%, the balance is deionized water, and raw materials are prepared.
  • the prepared water-based environmentally friendly and automated construction high weather resistance protective material the samples using the high weather resistance protective material were immersed in water for 520 hours and immersed in salt water for 520 hours, and the surface did not bubbling, bubbling, and rusting;
  • the samples using the high weather resistance protective material were soaked in a 5% sulfuric acid solution by volume for 125 hours, and after a 5% sodium hydroxide solution by volume for 125 hours, the surface did not bubble, bubble, and did not rust.
  • the water-based environmental protection automatic construction high weather resistance protective material of the present invention has the advantages of long-lasting rust prevention, corrosion resistance, environmental protection, water resistance and alkali resistance.
  • the prepared water-based environmental protection and automated construction high weather resistance protective material the samples using the high weather resistance protective material were immersed in water for 525 hours and 525 hours in salt water, and the surface did not bubble, bubbling, and rust;
  • the samples using the high weather resistance protective material were soaked in a 5% sulfuric acid solution by volume for 130 hours, and after soaking in a 5% sodium hydroxide solution by volume for 130 hours, the surface did not bubble, bubble, and did not rust.
  • the water-based environmental protection automatic construction high weather resistance protective material of the present invention has the advantages of long-lasting rust prevention, corrosion resistance, environmental protection, water resistance and alkali resistance.

Abstract

提供一种水性环保自动化施工的高耐候防护材料,高耐候防护材料由以下重量百分含量的组分组成:分散剂0.5~1.2%,表面活性剂0.1~0.2%,消泡剂0.4~0.8%,聚乙二醇0.8~3.5%,正丁醇0.1~1%,钛白粉0.8~5.2%,活性钙2~5%,纳米碳酸钙1~3.5%,滑石粉2~5%,纳米氧化锌0.5~2.5%,纳米氧化硅0.8~1.5%,硫酸钡2~5%,磷酸铝2~6%,磷酸锌4~8%,纯丙乳液10~20%,硅丙乳液8~20%,苯丙乳液10~25%,增稠剂0.8~1.5%,成膜助剂1~2.5%,余量为水。所述的水性环保自动化施工的高耐候防护材料具有高耐候持久防锈、防腐、环保、耐水、耐碱,便于自动化施工的优点,满足环保节约的要求。

Description

一种水性环保自动化施工的高耐候防护材料及其制备方法 技术领域
本发明涉及材料领域,特别是涉及一种水性环保自动化施工的高耐候防护材料及其制备方法。
背景技术
目前金属防腐材料主要以油性涂料为主,由于油性涂料在涂装过程中大量有机溶剂挥发,不但污染环境,而且对人体健康产生重大威胁。近年来,无污染、能源节约和经济高效的水性金属防腐材料越来越受到欢迎,尤其是具备高耐候持久防锈、防腐、环保、耐水、耐碱、自动化施工优点的水性防护材料,能满足人们对防护材料的需求和要求。
发明内容
针对上述现有技术中存在的问题,本发明的目的在于提供一种水性环保自动化施工的高耐候防护材料,满足环保节约的要求。
为了实现上述发明目的,本发明采用的技术方案如下:
一种水性环保自动化施工的高耐候防护材料,高耐候防护材料由以下重量百分含量的组分组成:分散剂0.5~1.2%,表面活性剂0.1~0.2%,消泡剂0.4~0.8%,聚乙二醇0.8~3.5%,正丁醇0.1~1%,钛白粉0.8~5.2%,活性钙2~5%,纳米碳酸钙1~3.5%,滑石粉2~5%,纳米氧化锌0.5~2.5%,纳米氧化硅0.8~1.5%,硫酸钡2~5%,磷酸铝2~6%,磷酸锌4~8%,纯丙乳液10~20%,硅丙乳液8~20%,苯丙乳液10~25%,增稠剂0.8~1.5%,成膜助剂1~2.5%,余量为水。
优选地,高耐候防护材料的各组分的重量百分含量为:分散剂1~1.1%, 表面活性剂0.12~0.15%,消泡剂0.5~0.6%,聚乙二醇1~3%,正丁醇0.2~0.5%,钛白粉4.5~5%,活性钙2.5~3.5%,纳米碳酸钙1.1~1.5%,滑石粉2.5~3.5%,纳米氧化锌2~2.2%,纳米氧化硅1.2~1.4%,硫酸钡3.2~3.5%,磷酸铝5~5.5%,磷酸锌4.6~6%,纯丙乳液13~15%,硅丙乳液12~18%,苯丙乳液14~16%,增稠剂1.1~1.2%,成膜助剂2~2.2%,余量为水。
优选地,高耐候防护材料的各组分的重量百分含量为:分散剂1.05%,表面活性剂0.13%,消泡剂0.55%,聚乙二醇1.5%,正丁醇0.3%,钛白粉4.8%,活性钙3%,纳米碳酸钙1.3%,滑石粉3.1%,纳米氧化锌2.1%,纳米氧化硅1.3%,硫酸钡3.3%,磷酸铝5.2%,磷酸锌5%,纯丙乳液14%,硅丙乳液13%,苯丙乳液15%,增稠剂1.15%,成膜助剂2.1%,余量为水。
进一步地,水为去离子水。
一种制备上述水性环保自动化施工的高耐候防护材料的方法,包含以下步骤:
步骤一:按照顺序依次将一定重量比例的分散剂、表面活性剂、消泡剂、聚乙二醇、正丁醇、钛白粉、活性钙、纳米碳酸钙、滑石粉、纳米氧化锌、纳米氧化硅、硫酸钡、磷酸铝、磷酸锌、纯丙乳液、硅丙乳液、苯丙乳液、增稠剂、成膜助剂投入到水里;
步骤二:分散剂、表面活性剂、消泡剂、聚乙二醇、正丁醇、钛白粉、活性钙、纳米碳酸钙、滑石粉、纳米氧化锌、纳米氧化硅、硫酸钡、磷酸铝、磷酸锌、纯丙乳液、硅丙乳液、苯丙乳液、增稠剂、成膜助剂按照步骤一的顺序依次在水里边投料边搅拌均匀。
进一步地,水为去离子水。
本发明的水性环保自动化施工的高耐候防护材料具有高耐候持久防锈、防腐、环保、耐水、耐碱,便于自动化施工的优点,满足环保节约的要求。并且水性环保自动化施工的高耐候防护材料的制备方法简单,易于大规模生产。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白,下面结合实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅用以解释本发明,并不用于限定本发明。
本发明提供的水性环保自动化施工的高耐候防护材料,高耐候防护材料由以下重量百分含量的组分组成:分散剂0.5~1.2%,表面活性剂0.1~0.2%,消泡剂0.4~0.8%,聚乙二醇0.8~3.5%,正丁醇0.1~1%,钛白粉0.8~5.2%,活性钙2~5%,纳米碳酸钙1~3.5%,滑石粉2~5%,纳米氧化锌0.5~2.5%,纳米氧化硅0.8~1.5%,硫酸钡2~5%,磷酸铝2~6%,磷酸锌4~8%,纯丙乳液10~20%,硅丙乳液8~20%,苯丙乳液10~25%,增稠剂0.8~1.5%,成膜助剂1~2.5%,余量为水,其中水为去离子水。
本发明水性环保自动化施工的高耐候防护材料的制备方法,包含以下步骤:
步骤一:按照顺序依次将一定重量比例的分散剂、表面活性剂、消泡剂、聚乙二醇、正丁醇、钛白粉、活性钙、纳米碳酸钙、滑石粉、纳米氧化锌、纳米氧化硅、硫酸钡、磷酸铝、磷酸锌、纯丙乳液、硅丙乳液、苯丙乳液、增稠剂、成膜助剂投入到去离子水里;
步骤二:分散剂、表面活性剂、消泡剂、聚乙二醇、正丁醇、钛白粉、活性钙、纳米碳酸钙、滑石粉、纳米氧化锌、纳米氧化硅、硫酸钡、磷酸铝、磷酸锌、纯丙乳液、硅丙乳液、苯丙乳液、增稠剂、成膜助剂按照步骤一的顺序依次在去离子水里边投料边搅拌均匀。
实施例一
按照重量百分比:分散剂1.05%,表面活性剂0.13%,消泡剂0.55%,聚乙二醇1.5%,正丁醇0.3%,钛白粉4.8%,活性钙3%,纳米碳酸钙1.3%,滑石粉3.1%,纳米氧化锌2.1%,纳米氧化硅1.3%,硫酸钡3.3%,磷酸铝5.2%,磷酸锌5%,纯丙乳液14%,硅丙乳液13%,苯丙乳液15%,增稠剂1.15%,成膜助剂2.1%,余量为去离子水,准备原料。
首先,按照顺序依次将分散剂、表面活性剂、消泡剂、聚乙二醇、正丁醇、钛白粉、活性钙、纳米碳酸钙、滑石粉、纳米氧化锌、纳米氧化硅、硫酸钡、磷酸铝、磷酸锌、纯丙乳液、硅丙乳液、苯丙乳液、增稠剂、成膜助剂投入到去离子水里。
接着,分散剂、表面活性剂、消泡剂、聚乙二醇、正丁醇、钛白粉、活性钙、纳米碳酸钙、滑石粉、纳米氧化锌、纳米氧化硅、硫酸钡、磷酸铝、磷酸锌、纯丙乳液、硅丙乳液、苯丙乳液、增稠剂、成膜助剂按照上述顺序依次在去离子水里边投料边搅拌均匀。
制备的水性环保自动化施工的高耐候防护材料,使用该高耐候防护材料的样品各自在水里浸泡530小时后、在盐水里浸泡530小时后,表面不起泡、不鼓泡、不起锈;使用该高耐候防护材料的样品各自在体积比5%的硫酸溶液泡135小时后、在体积比5%的氢氧化钠溶液泡135小时后,表面不起泡、不鼓泡、不起锈。本发明的水性环保自动化施工的高耐候防护材料具有持久防锈、防腐、环保、耐水、耐碱的优点。
实施例二
按照重量百分比:分散剂0.5%,表面活性剂0.1%,消泡剂0.4%,聚乙二醇0.8%,正丁醇1%,钛白粉5.2%,活性钙5%,纳米碳酸钙1%,滑石粉2%,纳米氧化锌0.5%,纳米氧化硅0.8%,硫酸钡2%,磷酸铝6%,磷酸锌4%,纯丙乳液20%,硅丙乳液20%,苯丙乳液10%,增稠剂1.5%,成膜助剂2.5%,余量为去离子水,准备原料。
首先,按照顺序依次将分散剂、表面活性剂、消泡剂、聚乙二醇、正丁醇、钛白粉、活性钙、纳米碳酸钙、滑石粉、纳米氧化锌、纳米氧化硅、硫酸钡、磷酸铝、磷酸锌、纯丙乳液、硅丙乳液、苯丙乳液、增稠剂、成膜助剂投入到去离子水里。
接着,分散剂、表面活性剂、消泡剂、聚乙二醇、正丁醇、钛白粉、活性钙、纳米碳酸钙、滑石粉、纳米氧化锌、纳米氧化硅、硫酸钡、磷酸铝、磷酸锌、纯丙乳液、硅丙乳液、苯丙乳液、增稠剂、成膜助剂按照上 述顺序依次在去离子水里边投料边搅拌均匀。
制备的水性环保自动化施工的高耐候防护材料,使用该高耐候防护材料的样品各自在水里浸泡500小时后、在盐水里浸泡500小时后,表面不起泡、不鼓泡、不起锈;使用该高耐候防护材料的样品各自在体积比5%的硫酸溶液泡120小时后、在体积比5%的氢氧化钠溶液泡120小时后,表面不起泡、不鼓泡、不起锈。本发明的水性环保自动化施工的高耐候防护材料具有持久防锈、防腐、环保、耐水、耐碱的优点。
实施例三
按照重量百分比:分散剂1.2%,表面活性剂0.2%,消泡剂0.8%,聚乙二醇3.5%,正丁醇0.1%,钛白粉0.8%,活性钙2%,纳米碳酸钙3.5%,滑石粉5%,纳米氧化锌2.5%,纳米氧化硅1.5%,硫酸钡5%,磷酸铝2%,磷酸锌8%,纯丙乳液10%,硅丙乳液8%,苯丙乳液25%,增稠剂0.8%,成膜助剂1%,余量为去离子水,准备原料。
首先,按照顺序依次将分散剂、表面活性剂、消泡剂、聚乙二醇、正丁醇、钛白粉、活性钙、纳米碳酸钙、滑石粉、纳米氧化锌、纳米氧化硅、硫酸钡、磷酸铝、磷酸锌、纯丙乳液、硅丙乳液、苯丙乳液、增稠剂、成膜助剂投入到去离子水里。
接着,分散剂、表面活性剂、消泡剂、聚乙二醇、正丁醇、钛白粉、活性钙、纳米碳酸钙、滑石粉、纳米氧化锌、纳米氧化硅、硫酸钡、磷酸铝、磷酸锌、纯丙乳液、硅丙乳液、苯丙乳液、增稠剂、成膜助剂按照上述顺序依次在去离子水里边投料边搅拌均匀。
制备的水性环保自动化施工的高耐候防护材料,使用该高耐候防护材料的样品各自在水里浸泡510小时后、在盐水里浸泡510小时后,表面不起泡、不鼓泡、不起锈;使用该高耐候防护材料的样品各自在体积比5%的硫酸溶液泡120小时后、在体积比5%的氢氧化钠溶液泡120小时后,表面不起泡、不鼓泡、不起锈。本发明的水性环保自动化施工的高耐候防护材料具有持久防锈、防腐、环保、耐水、耐碱的优点。
实施例四
按照重量百分比:分散剂1%,表面活性剂0.12%,消泡剂0.6%,聚乙二醇3%,正丁醇0.2%,钛白粉5%,活性钙2.5%,纳米碳酸钙1.1%,滑石粉3.5%,纳米氧化锌2%,纳米氧化硅1.2%,硫酸钡3.5%,磷酸铝5%,磷酸锌6%,纯丙乳液13%,硅丙乳液18%,苯丙乳液16%,增稠剂1.2%,成膜助剂2.2%,余量为去离子水,准备原料。
首先,按照顺序依次将分散剂、表面活性剂、消泡剂、聚乙二醇、正丁醇、钛白粉、活性钙、纳米碳酸钙、滑石粉、纳米氧化锌、纳米氧化硅、硫酸钡、磷酸铝、磷酸锌、纯丙乳液、硅丙乳液、苯丙乳液、增稠剂、成膜助剂投入到去离子水里。
接着,分散剂、表面活性剂、消泡剂、聚乙二醇、正丁醇、钛白粉、活性钙、纳米碳酸钙、滑石粉、纳米氧化锌、纳米氧化硅、硫酸钡、磷酸铝、磷酸锌、纯丙乳液、硅丙乳液、苯丙乳液、增稠剂、成膜助剂按照上述顺序依次在去离子水里边投料边搅拌均匀。
制备的水性环保自动化施工的高耐候防护材料,使用该高耐候防护材料的样品各自在水里浸泡520小时后、在盐水里浸泡520小时后,表面不起泡、不鼓泡、不起锈;使用该高耐候防护材料的样品各自在体积比5%的硫酸溶液泡125小时后、在体积比5%的氢氧化钠溶液泡125小时后,表面不起泡、不鼓泡、不起锈。本发明的水性环保自动化施工的高耐候防护材料具有持久防锈、防腐、环保、耐水、耐碱的优点。
实施例五
按照重量百分比:分散剂1.1%,表面活性剂0.15%,消泡剂0.5%,聚乙二醇1%,正丁醇0.5%,钛白粉4.5%,活性钙3.5%,纳米碳酸钙1.5%,滑石粉2.5%,纳米氧化锌2.2%,纳米氧化硅1.4%,硫酸钡3.2%,磷酸铝5.5%,磷酸锌4.6%,纯丙乳液15%,硅丙乳液12%,苯丙乳液14%,增稠剂1.1%,成膜助剂2%,余量为去离子水,准备原料。
首先,按照顺序依次将分散剂、表面活性剂、消泡剂、聚乙二醇、正 丁醇、钛白粉、活性钙、纳米碳酸钙、滑石粉、纳米氧化锌、纳米氧化硅、硫酸钡、磷酸铝、磷酸锌、纯丙乳液、硅丙乳液、苯丙乳液、增稠剂、成膜助剂投入到去离子水里。
接着,分散剂、表面活性剂、消泡剂、聚乙二醇、正丁醇、钛白粉、活性钙、纳米碳酸钙、滑石粉、纳米氧化锌、纳米氧化硅、硫酸钡、磷酸铝、磷酸锌、纯丙乳液、硅丙乳液、苯丙乳液、增稠剂、成膜助剂按照上述顺序依次在去离子水里边投料边搅拌均匀。
制备的水性环保自动化施工的高耐候防护材料,使用该高耐候防护材料的样品各自在水里浸泡525小时后、在盐水里浸泡525小时后,表面不起泡、不鼓泡、不起锈;使用该高耐候防护材料的样品各自在体积比5%的硫酸溶液泡130小时后、在体积比5%的氢氧化钠溶液泡130小时后,表面不起泡、不鼓泡、不起锈。本发明的水性环保自动化施工的高耐候防护材料具有持久防锈、防腐、环保、耐水、耐碱的优点。
以上所述实施例仅表达了本发明的实施方式,其描述较为具体和详细,但并不能因此而理解为对本发明专利范围的限制。应当指出的是,对于本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进,这些都属于本发明的保护范围。

Claims (6)

  1. 一种水性环保自动化施工的高耐候防护材料,其特征在于,所述高耐候防护材料由以下重量百分含量的组分组成:分散剂0.5~1.2%,表面活性剂0.1~0.2%,消泡剂0.4~0.8%,聚乙二醇0.8~3.5%,正丁醇0.1~1%,钛白粉0.8~5.2%,活性钙2~5%,纳米碳酸钙1~3.5%,滑石粉2~5%,纳米氧化锌0.5~2.5%,纳米氧化硅0.8~1.5%,硫酸钡2~5%,磷酸铝2~6%,磷酸锌4~8%,纯丙乳液10~20%,硅丙乳液8~20%,苯丙乳液10~25%,增稠剂0.8~1.5%,成膜助剂1~2.5%,余量为水。
  2. 根据权利要求1所述的水性环保自动化施工的高耐候防护材料,其特征在于,所述高耐候防护材料的各组分的重量百分含量为:所述分散剂1~1.1%,所述表面活性剂0.12~0.15%,所述消泡剂0.5~0.6%,所述聚乙二醇1~3%,所述正丁醇0.2~0.5%,所述钛白粉4.5~5%,所述活性钙2.5~3.5%,所述纳米碳酸钙1.1~1.5%,所述滑石粉2.5~3.5%,所述纳米氧化锌2~2.2%,所述纳米氧化硅1.2~1.4%,所述硫酸钡3.2~3.5%,所述磷酸铝5~5.5%,所述磷酸锌4.6~6%,所述纯丙乳液13~15%,所述硅丙乳液12~18%,所述苯丙乳液14~16%,所述增稠剂1.1~1.2%,所述成膜助剂2~2.2%,余量为所述水。
  3. 根据权利要求2所述的水性环保自动化施工的高耐候防护材料,其特征在于,所述高耐候防护材料的各组分的重量百分含量为:所述分散剂1.05%,所述表面活性剂0.13%,所述消泡剂0.55%,所述聚乙二醇1.5%,所述正丁醇0.3%,所述钛白粉4.8%,所述活性钙3%,所述纳米碳酸钙1.3%,所述滑石粉3.1%,所述纳米氧化锌2.1%,所述纳米氧化硅1.3%,所述硫酸钡3.3%,所述磷酸铝5.2%,所述磷酸锌5%,所述纯丙乳液14%,所述硅丙乳液13%,所述苯丙乳液15%,所述增稠剂1.15%,所述成膜助剂2.1%,余量为所述水。
  4. 根据权利要求3所述的水性环保自动化施工的高耐候防护材料,其特征在于,所述水为去离子水。
  5. 一种制备如权利要求1-4所述的水性环保自动化施工的高耐候防护材料的方法,其特征在于,包含以下步骤:
    步骤一:按照顺序依次将一定重量比例的分散剂、表面活性剂、消泡剂、聚乙二醇、正丁醇、钛白粉、活性钙、纳米碳酸钙、滑石粉、纳米氧化锌、纳米氧化硅、硫酸钡、磷酸铝、磷酸锌、纯丙乳液、硅丙乳液、苯丙乳液、增稠剂、成膜助剂投入到水里;
    步骤二:所述分散剂、所述表面活性剂、所述消泡剂、所述聚乙二醇、所述正丁醇、所述钛白粉、所述活性钙、所述纳米碳酸钙、所述滑石粉、所述纳米氧化锌、所述纳米氧化硅、所述硫酸钡、所述磷酸铝、所述磷酸锌、所述纯丙乳液、所述硅丙乳液、所述苯丙乳液、所述增稠剂、所述成膜助剂按照所述步骤一的顺序依次在水里边投料边搅拌均匀。
  6. 根据权利要求5所述的制备方法,其特征在于,所述水为去离子水。
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