WO2021114593A1 - 一种水性环保自动化施工的高耐候防护材料及其制备方法 - Google Patents
一种水性环保自动化施工的高耐候防护材料及其制备方法 Download PDFInfo
- Publication number
- WO2021114593A1 WO2021114593A1 PCT/CN2020/095642 CN2020095642W WO2021114593A1 WO 2021114593 A1 WO2021114593 A1 WO 2021114593A1 CN 2020095642 W CN2020095642 W CN 2020095642W WO 2021114593 A1 WO2021114593 A1 WO 2021114593A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- acrylic emulsion
- water
- nano
- protective material
- weather resistance
- Prior art date
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 85
- 239000000463 material Substances 0.000 title claims abstract description 47
- 230000001681 protective effect Effects 0.000 title claims abstract description 44
- 238000010276 construction Methods 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims description 5
- 239000000839 emulsion Substances 0.000 claims abstract description 87
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 58
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 58
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 58
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 56
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 53
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 52
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 29
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims abstract description 29
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 29
- 239000002270 dispersing agent Substances 0.000 claims abstract description 29
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 29
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 29
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims abstract description 28
- 239000004094 surface-active agent Substances 0.000 claims abstract description 28
- 239000002562 thickening agent Substances 0.000 claims abstract description 28
- 239000011787 zinc oxide Substances 0.000 claims abstract description 28
- 230000007613 environmental effect Effects 0.000 claims abstract description 27
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims abstract description 24
- 229910000165 zinc phosphate Inorganic materials 0.000 claims abstract description 24
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 23
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 21
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 21
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 19
- 239000011575 calcium Substances 0.000 claims abstract description 19
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002518 antifoaming agent Substances 0.000 claims abstract 2
- 239000013530 defoamer Substances 0.000 claims description 27
- 239000008367 deionised water Substances 0.000 claims description 22
- 229910021641 deionized water Inorganic materials 0.000 claims description 22
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000010408 film Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 2
- 239000013543 active substance Substances 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 17
- 239000003513 alkali Substances 0.000 abstract description 8
- 230000002265 prevention Effects 0.000 abstract description 8
- 238000005536 corrosion prevention Methods 0.000 abstract 1
- 230000002045 lasting effect Effects 0.000 abstract 1
- 239000000454 talc Substances 0.000 description 21
- 229910052623 talc Inorganic materials 0.000 description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
- 150000001669 calcium Chemical class 0.000 description 10
- 238000005260 corrosion Methods 0.000 description 7
- 230000005923 long-lasting effect Effects 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 6
- OXHXATNDTXVKAU-UHFFFAOYSA-N phosphoric acid zinc Chemical compound [Zn].OP(O)(O)=O OXHXATNDTXVKAU-UHFFFAOYSA-N 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- 230000005587 bubbling Effects 0.000 description 4
- 238000002791 soaking Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- MOVRNJGDXREIBM-UHFFFAOYSA-N aid-1 Chemical compound O=C1NC(=O)C(C)=CN1C1OC(COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)CO)C(O)C1 MOVRNJGDXREIBM-UHFFFAOYSA-N 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/328—Phosphates of heavy metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Definitions
- the invention relates to the field of materials, in particular to a high weather resistance protective material for water-based environmental protection and automatic construction and a preparation method thereof.
- metal anticorrosive materials are mainly oil-based paints. Since a large amount of organic solvents volatilize during the coating process of oil-based paints, it not only pollutes the environment, but also poses a major threat to human health. In recent years, water-based metal anti-corrosion materials that are pollution-free, energy-saving and cost-effective have become more and more popular, especially water-based protective materials that have the advantages of high weather resistance, long-lasting rust prevention, corrosion protection, environmental protection, water resistance, alkali resistance, and automatic construction. People's needs and requirements for protective materials.
- the purpose of the present invention is to provide a highly weather-resistant protective material for water-based environmental protection and automated construction to meet the requirements of environmental protection and conservation.
- the high weather resistance protective material consists of the following components by weight percentage: dispersant 0.5 to 1.2%, surfactant 0.1 to 0.2%, defoamer 0.4 to 0.8%, Polyethylene glycol 0.8 ⁇ 3.5%, n-butanol 0.1 ⁇ 1%, titanium dioxide 0.8 ⁇ 5.2%, active calcium 2 ⁇ 5%, nano calcium carbonate 1 ⁇ 3.5%, talc 2 ⁇ 5%, nano zinc oxide 0.5 ⁇ 2.5%, nano-silica 0.8 ⁇ 1.5%, barium sulfate 2 ⁇ 5%, aluminum phosphate 2 ⁇ 6%, zinc phosphate 4 ⁇ 8%, pure acrylic emulsion 10 ⁇ 20%, silicone acrylic emulsion 8 ⁇ 20%, benzene Acrylic emulsion is 10-25%, thickener is 0.8-1.5%, film-forming auxiliary agent is 1-2.5%, and the balance is water.
- the weight percentage content of each component of the high weather resistance protective material is: 1 to 1.1% of dispersant, 0.12 to 0.15% of surfactant, 0.5 to 0.6% of defoamer, 1 to 3% of polyethylene glycol, N-butanol 0.2 ⁇ 0.5%, titanium dioxide 4.5 ⁇ 5%, active calcium 2.5 ⁇ 3.5%, nano calcium carbonate 1.1 ⁇ 1.5%, talc 2.5 ⁇ 3.5%, nano zinc oxide 2 ⁇ 2.2%, nano silicon oxide 1.2 ⁇ 1.4%, barium sulfate 3.2 ⁇ 3.5%, aluminum phosphate 5 ⁇ 5.5%, zinc phosphate 4.6 ⁇ 6%, pure acrylic emulsion 13-15%, silicone acrylic emulsion 12-18%, styrene acrylic emulsion 14-16%, thickening
- the amount is 1.1-1.2%, the film-forming aid is 2-2.2%, and the balance is water.
- the weight percentage of each component of the high weather resistance protective material is: 1.05% of dispersant, 0.13% of surfactant, 0.55% of defoamer, 1.5% of polyethylene glycol, 0.3% of n-butanol, titanium dioxide 4.8%, active calcium 3%, nano calcium carbonate 1.3%, talc 3.1%, nano zinc oxide 2.1%, nano silicon oxide 1.3%, barium sulfate 3.3%, aluminum phosphate 5.2%, zinc phosphate 5%, pure acrylic emulsion 14 %, 13% of silicone-acrylic emulsion, 15% of styrene-acrylic emulsion, 1.15% of thickener, 2.1% of film-forming aid, and the balance is water.
- the water is deionized water.
- a method for preparing the above-mentioned water-based environmentally friendly automatic construction high weather resistance protective material including the following steps:
- Step 1 According to the order, add a certain weight ratio of dispersant, surfactant, defoamer, polyethylene glycol, n-butanol, titanium dioxide, active calcium, nano calcium carbonate, talc powder, nano zinc oxide, nano oxidation Put silicon, barium sulfate, aluminum phosphate, zinc phosphate, pure acrylic emulsion, silicon acrylic emulsion, styrene acrylic emulsion, thickener, and film forming aid into the water;
- Step 2 Dispersant, surfactant, defoamer, polyethylene glycol, n-butanol, titanium dioxide, active calcium, nano calcium carbonate, talc, nano zinc oxide, nano silicon oxide, barium sulfate, aluminum phosphate, Zinc phosphate, pure acrylic emulsion, silicone acrylic emulsion, styrene-acrylic emulsion, thickener, and film-forming aid are added to the water and stirred evenly in the order of step 1.
- the water is deionized water.
- the water-based environmental protection automatic construction high weather resistance protective material of the present invention has the advantages of high weather resistance, long lasting rust prevention, anticorrosion, environmental protection, water resistance and alkali resistance, and is convenient for automatic construction, and meets the requirements of environmental protection and saving.
- the preparation method of the highly weather-resistant protective material for water-based environmental protection and automated construction is simple and easy for mass production.
- the water-based environmental protection automatic construction high weather resistance protective material provided by the present invention is composed of the following components by weight percentage: dispersant 0.5-1.2%, surfactant 0.1-0.2%, defoamer 0.4-0.8 %, polyethylene glycol 0.8 ⁇ 3.5%, n-butanol 0.1 ⁇ 1%, titanium dioxide 0.8 ⁇ 5.2%, active calcium 2 ⁇ 5%, nano calcium carbonate 1 ⁇ 3.5%, talc 2 ⁇ 5%, nano oxidation Zinc 0.5 ⁇ 2.5%, nano-silica 0.8 ⁇ 1.5%, barium sulfate 2 ⁇ 5%, aluminum phosphate 2 ⁇ 6%, zinc phosphate 4 ⁇ 8%, pure acrylic emulsion 10-20%, silicon acrylic emulsion 8-20% , Styrene-acrylic emulsion 10-25%, thickener 0.8-1.5%, film-forming aid 1-2.5%, the balance is water, of which water is deionized water.
- the preparation method of the water-based environmental protection automatic construction high weather resistance protective material of the present invention includes the following steps:
- Step 1 According to the order, add a certain weight ratio of dispersant, surfactant, defoamer, polyethylene glycol, n-butanol, titanium dioxide, active calcium, nano calcium carbonate, talc powder, nano zinc oxide, nano oxidation Put silicon, barium sulfate, aluminum phosphate, zinc phosphate, pure acrylic emulsion, silicon acrylic emulsion, styrene acrylic emulsion, thickener, and film forming aid into deionized water;
- Step 2 Dispersant, surfactant, defoamer, polyethylene glycol, n-butanol, titanium dioxide, active calcium, nano calcium carbonate, talc, nano zinc oxide, nano silicon oxide, barium sulfate, aluminum phosphate, Zinc phosphate, pure acrylic emulsion, silicone acrylic emulsion, styrene-acrylic emulsion, thickener, and film-forming aid are added in deionized water and stirred evenly in the order of step 1.
- weight percentage 1.05% of dispersant, 0.13% of surfactant, 0.55% of defoamer, 1.5% of polyethylene glycol, 0.3% of n-butanol, 4.8% of titanium dioxide, 3% of active calcium, 1.3% of nano-calcium carbonate, Talc 3.1%, nano zinc oxide 2.1%, nano silicon oxide 1.3%, barium sulfate 3.3%, aluminum phosphate 5.2%, zinc phosphate 5%, pure acrylic emulsion 14%, silicone acrylic emulsion 13%, styrene acrylic emulsion 15%, Thickener 1.15%, film-forming aid 2.1%, the balance is deionized water, and raw materials are prepared.
- the prepared water-based environmentally friendly and automated construction high weather resistance protective material the samples using the high weather resistance protective material were immersed in water for 530 hours and 530 hours in salt water, and the surface did not bubble, bubble, and rust;
- the samples using the highly weather-resistant protective material were soaked in a 5% sulfuric acid solution by volume for 135 hours, and after soaked in a 5% sodium hydroxide solution by volume for 135 hours, the surface did not bubble, bubble, and did not rust.
- the water-based environmental protection automatic construction high weather resistance protective material of the present invention has the advantages of long-lasting rust prevention, corrosion resistance, environmental protection, water resistance and alkali resistance.
- weight percentage 0.5% of dispersant, 0.1% of surfactant, 0.4% of defoamer, 0.8% of polyethylene glycol, 1% of n-butanol, 5.2% of titanium dioxide, 5% of active calcium, 1% of nano-calcium carbonate, Talc 2%, nano zinc oxide 0.5%, nano silicon oxide 0.8%, barium sulfate 2%, aluminum phosphate 6%, zinc phosphate 4%, pure acrylic emulsion 20%, silicone acrylic emulsion 20%, styrene acrylic emulsion 10%, Thickener 1.5%, film-forming aid 2.5%, the balance is deionized water, and raw materials are prepared.
- the prepared water-based environmentally friendly automatic construction high weather resistance protective material the samples using the high weather resistance protective material were soaked in water for 500 hours and 500 hours in salt water, and the surface did not bubble, bubbling, or rust;
- the samples using the high weather resistance protective material were soaked in a 5% sulfuric acid solution by volume for 120 hours, and after soaking in a 5% sodium hydroxide solution by volume for 120 hours, the surface did not bubble, bubble, and did not rust.
- the water-based environmental protection automatic construction high weather resistance protective material of the present invention has the advantages of long-lasting rust prevention, corrosion resistance, environmental protection, water resistance and alkali resistance.
- the prepared water-based environmentally friendly and automated construction high weather resistance protective material the samples using the high weather resistance protective material were immersed in water for 510 hours and 510 hours in salt water, and the surface did not bubble, bubble, or rust;
- the samples using the high weather resistance protective material were soaked in a 5% sulfuric acid solution by volume for 120 hours, and after soaking in a 5% sodium hydroxide solution by volume for 120 hours, the surface did not bubble, bubble, and did not rust.
- the water-based environmental protection automatic construction high weather resistance protective material of the present invention has the advantages of long-lasting rust prevention, corrosion resistance, environmental protection, water resistance and alkali resistance.
- weight percentage 1% dispersant, 0.12% surfactant, 0.6% defoamer, 3% polyethylene glycol, 0.2% n-butanol, 5% titanium dioxide, 2.5% active calcium, 1.1% nano-calcium carbonate, Talc 3.5%, Nano Zinc Oxide 2%, Nano Silica 1.2%, Barium Sulfate 3.5%, Aluminum Phosphate 5%, Zinc Phosphate 6%, Pure Acrylic Emulsion 13%, Silicone Acrylic Emulsion 18%, Styrene Acrylic Emulsion 16%, Thickener 1.2%, film-forming aid 2.2%, the balance is deionized water, and raw materials are prepared.
- the prepared water-based environmentally friendly and automated construction high weather resistance protective material the samples using the high weather resistance protective material were immersed in water for 520 hours and immersed in salt water for 520 hours, and the surface did not bubbling, bubbling, and rusting;
- the samples using the high weather resistance protective material were soaked in a 5% sulfuric acid solution by volume for 125 hours, and after a 5% sodium hydroxide solution by volume for 125 hours, the surface did not bubble, bubble, and did not rust.
- the water-based environmental protection automatic construction high weather resistance protective material of the present invention has the advantages of long-lasting rust prevention, corrosion resistance, environmental protection, water resistance and alkali resistance.
- the prepared water-based environmental protection and automated construction high weather resistance protective material the samples using the high weather resistance protective material were immersed in water for 525 hours and 525 hours in salt water, and the surface did not bubble, bubbling, and rust;
- the samples using the high weather resistance protective material were soaked in a 5% sulfuric acid solution by volume for 130 hours, and after soaking in a 5% sodium hydroxide solution by volume for 130 hours, the surface did not bubble, bubble, and did not rust.
- the water-based environmental protection automatic construction high weather resistance protective material of the present invention has the advantages of long-lasting rust prevention, corrosion resistance, environmental protection, water resistance and alkali resistance.
Abstract
Description
Claims (6)
- 一种水性环保自动化施工的高耐候防护材料,其特征在于,所述高耐候防护材料由以下重量百分含量的组分组成:分散剂0.5~1.2%,表面活性剂0.1~0.2%,消泡剂0.4~0.8%,聚乙二醇0.8~3.5%,正丁醇0.1~1%,钛白粉0.8~5.2%,活性钙2~5%,纳米碳酸钙1~3.5%,滑石粉2~5%,纳米氧化锌0.5~2.5%,纳米氧化硅0.8~1.5%,硫酸钡2~5%,磷酸铝2~6%,磷酸锌4~8%,纯丙乳液10~20%,硅丙乳液8~20%,苯丙乳液10~25%,增稠剂0.8~1.5%,成膜助剂1~2.5%,余量为水。
- 根据权利要求1所述的水性环保自动化施工的高耐候防护材料,其特征在于,所述高耐候防护材料的各组分的重量百分含量为:所述分散剂1~1.1%,所述表面活性剂0.12~0.15%,所述消泡剂0.5~0.6%,所述聚乙二醇1~3%,所述正丁醇0.2~0.5%,所述钛白粉4.5~5%,所述活性钙2.5~3.5%,所述纳米碳酸钙1.1~1.5%,所述滑石粉2.5~3.5%,所述纳米氧化锌2~2.2%,所述纳米氧化硅1.2~1.4%,所述硫酸钡3.2~3.5%,所述磷酸铝5~5.5%,所述磷酸锌4.6~6%,所述纯丙乳液13~15%,所述硅丙乳液12~18%,所述苯丙乳液14~16%,所述增稠剂1.1~1.2%,所述成膜助剂2~2.2%,余量为所述水。
- 根据权利要求2所述的水性环保自动化施工的高耐候防护材料,其特征在于,所述高耐候防护材料的各组分的重量百分含量为:所述分散剂1.05%,所述表面活性剂0.13%,所述消泡剂0.55%,所述聚乙二醇1.5%,所述正丁醇0.3%,所述钛白粉4.8%,所述活性钙3%,所述纳米碳酸钙1.3%,所述滑石粉3.1%,所述纳米氧化锌2.1%,所述纳米氧化硅1.3%,所述硫酸钡3.3%,所述磷酸铝5.2%,所述磷酸锌5%,所述纯丙乳液14%,所述硅丙乳液13%,所述苯丙乳液15%,所述增稠剂1.15%,所述成膜助剂2.1%,余量为所述水。
- 根据权利要求3所述的水性环保自动化施工的高耐候防护材料,其特征在于,所述水为去离子水。
- 一种制备如权利要求1-4所述的水性环保自动化施工的高耐候防护材料的方法,其特征在于,包含以下步骤:步骤一:按照顺序依次将一定重量比例的分散剂、表面活性剂、消泡剂、聚乙二醇、正丁醇、钛白粉、活性钙、纳米碳酸钙、滑石粉、纳米氧化锌、纳米氧化硅、硫酸钡、磷酸铝、磷酸锌、纯丙乳液、硅丙乳液、苯丙乳液、增稠剂、成膜助剂投入到水里;步骤二:所述分散剂、所述表面活性剂、所述消泡剂、所述聚乙二醇、所述正丁醇、所述钛白粉、所述活性钙、所述纳米碳酸钙、所述滑石粉、所述纳米氧化锌、所述纳米氧化硅、所述硫酸钡、所述磷酸铝、所述磷酸锌、所述纯丙乳液、所述硅丙乳液、所述苯丙乳液、所述增稠剂、所述成膜助剂按照所述步骤一的顺序依次在水里边投料边搅拌均匀。
- 根据权利要求5所述的制备方法,其特征在于,所述水为去离子水。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201911271491.2A CN111303699A (zh) | 2019-12-12 | 2019-12-12 | 一种水性环保自动化施工的高耐候防护材料及其制备方法 |
CN201911271491.2 | 2019-12-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2021114593A1 true WO2021114593A1 (zh) | 2021-06-17 |
Family
ID=71145257
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2020/095642 WO2021114593A1 (zh) | 2019-12-12 | 2020-06-11 | 一种水性环保自动化施工的高耐候防护材料及其制备方法 |
Country Status (2)
Country | Link |
---|---|
CN (1) | CN111303699A (zh) |
WO (1) | WO2021114593A1 (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114213927B (zh) * | 2021-12-31 | 2023-05-12 | 圣戈班汇杰(杭州)新材料有限公司 | 一种水性可剥离涂料、制备方法及应用 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000129164A (ja) * | 1998-10-27 | 2000-05-09 | Mitsubishi Kagaku Sanshi Corp | 水性エマルジョン系防水塗料組成物 |
CN1427044A (zh) * | 2001-11-07 | 2003-07-02 | 日本油漆株式会社 | 抗菌无铅阳离子电沉积涂层组合物 |
CN106118295A (zh) * | 2016-07-01 | 2016-11-16 | 洛阳双瑞防腐工程技术有限公司 | 一种水性底面合一带锈防腐涂料及其制备方法 |
CN106479246A (zh) * | 2016-08-18 | 2017-03-08 | 徐英豪 | 活性钙和钛白粉组合物在涂料上的应用 |
CN107236373A (zh) * | 2017-06-02 | 2017-10-10 | 西北师范大学 | 一种水性金属防腐涂膜及其制备方法 |
CN109796825A (zh) * | 2018-12-20 | 2019-05-24 | 科顺防水科技股份有限公司 | 一种防闪锈丙烯酸屋面防水涂料及其制备方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101921516B (zh) * | 2009-10-28 | 2012-07-04 | 北京航空航天大学 | 一种适用于钢铁表面的水性防腐透明涂料及其制备方法 |
CN103305075A (zh) * | 2013-06-26 | 2013-09-18 | 关锦池 | 一种水性防腐涂料及其制备方法 |
CN103819988B (zh) * | 2014-02-24 | 2017-01-04 | 浙江大学 | 一种底面合一水性防腐涂料及其制备方法 |
-
2019
- 2019-12-12 CN CN201911271491.2A patent/CN111303699A/zh active Pending
-
2020
- 2020-06-11 WO PCT/CN2020/095642 patent/WO2021114593A1/zh active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000129164A (ja) * | 1998-10-27 | 2000-05-09 | Mitsubishi Kagaku Sanshi Corp | 水性エマルジョン系防水塗料組成物 |
CN1427044A (zh) * | 2001-11-07 | 2003-07-02 | 日本油漆株式会社 | 抗菌无铅阳离子电沉积涂层组合物 |
CN106118295A (zh) * | 2016-07-01 | 2016-11-16 | 洛阳双瑞防腐工程技术有限公司 | 一种水性底面合一带锈防腐涂料及其制备方法 |
CN106479246A (zh) * | 2016-08-18 | 2017-03-08 | 徐英豪 | 活性钙和钛白粉组合物在涂料上的应用 |
CN107236373A (zh) * | 2017-06-02 | 2017-10-10 | 西北师范大学 | 一种水性金属防腐涂膜及其制备方法 |
CN109796825A (zh) * | 2018-12-20 | 2019-05-24 | 科顺防水科技股份有限公司 | 一种防闪锈丙烯酸屋面防水涂料及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN111303699A (zh) | 2020-06-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102731052A (zh) | 水性有机-无机复合涂料及其制备方法 | |
CN104449154A (zh) | 一种用于镀锌钢板的水性无铬耐指纹涂料 | |
CN105131772A (zh) | 一种自清洁防污内墙涂料 | |
CN105647362A (zh) | 一种持久高效纳米抗菌水性木器涂料及其制备方法 | |
CN104725969B (zh) | 一种水性防腐漂浮型银粉漆及其制备方法 | |
CN104059441B (zh) | 一种建筑内墙涂料及其制备方法 | |
CN108129966B (zh) | 一种氯醚乳液水性防腐涂料 | |
CN105238169B (zh) | 高耐候低voc水性氟碳金属漆及其制备方法 | |
CN102898906A (zh) | 环保水性金属装饰效果涂料及其制备方法 | |
CN104130687A (zh) | 食品级水性金属烤漆及其制备方法 | |
CN103865348A (zh) | 一种水性硅丙云铁防腐涂料 | |
CN106634424A (zh) | 一种水性环氧防腐底漆 | |
CN103666130A (zh) | 一种全水性氟碳抗酸质感涂料的制备 | |
CN102051095A (zh) | 一种低碳节能乳胶漆及其制备方法 | |
CN102676009B (zh) | 一种负离子生态幻彩漆及其制备方法 | |
WO2021114593A1 (zh) | 一种水性环保自动化施工的高耐候防护材料及其制备方法 | |
CN103173101A (zh) | 一种耐盐雾的防腐涂料 | |
CN107254225A (zh) | 一种水性金属防腐漆及其制备方法 | |
CN105400318A (zh) | 一种铝单板用水性pvdf氟碳金属烤漆 | |
CN102604537B (zh) | 一种水性金属防腐涂料及其制备方法 | |
CN104559591A (zh) | 一种用于铝型材生产的环保水性涂料及其制备方法 | |
CN109575657B (zh) | 一种高附着力高柔韧性防闪锈水性无机富锌涂料及其制备方法 | |
CN107141914A (zh) | 一种集装箱用水性金属重防腐丙烯酸面漆及其制备方法 | |
CN108610668A (zh) | 一种田螺壳粉水性涂料 | |
CN106905733A (zh) | 一种水性金属涂料 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 20899034 Country of ref document: EP Kind code of ref document: A1 |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 20899034 Country of ref document: EP Kind code of ref document: A1 |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 20899034 Country of ref document: EP Kind code of ref document: A1 |
|
32PN | Ep: public notification in the ep bulletin as address of the adressee cannot be established |
Free format text: NOTING OF LOSS OF RIGHTS PURSUANT TO RULE 112(1) EPC (EPO FORM 1205A DATED 13/01/2023) |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 20899034 Country of ref document: EP Kind code of ref document: A1 |