WO2021006081A1 - Structure de fibres et procédé de fabrication de structure de fibres - Google Patents

Structure de fibres et procédé de fabrication de structure de fibres Download PDF

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Publication number
WO2021006081A1
WO2021006081A1 PCT/JP2020/025424 JP2020025424W WO2021006081A1 WO 2021006081 A1 WO2021006081 A1 WO 2021006081A1 JP 2020025424 W JP2020025424 W JP 2020025424W WO 2021006081 A1 WO2021006081 A1 WO 2021006081A1
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Prior art keywords
yarn
warp
fiber structure
auxiliary
thread
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PCT/JP2020/025424
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English (en)
Japanese (ja)
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河原真梨
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株式会社豊田自動織機
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Publication of WO2021006081A1 publication Critical patent/WO2021006081A1/fr

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    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00—Woven fabrics designed to make specified articles
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D11/00—Double or multi-ply fabrics not otherwise provided for

Definitions

  • the present disclosure relates to a fiber structure and a method for manufacturing the fiber structure.
  • a fiber-reinforced composite material with a resin matrix in the fiber structure is used as a structural material for aircraft, automobiles, buildings, etc.
  • the fiber structure there is a fiber structure of a multilayer woven fabric in which a plurality of fiber layers are laminated.
  • the shape of the fiber structure may be a shape having a bent portion such as an L shape or a U shape. In this case, the fibrous structure formed in a flat plate shape is shaped to have a bent portion.
  • a thread made of reinforcing fibers may be used for the fiber structure.
  • Reinforcing fibers generally have very low elongation. Therefore, when a fiber structure in which a thread made of reinforcing fibers is used is shaped to have a bent portion, the threads arranged on the outside of the bent portion are difficult to stretch, and wrinkles are formed on the inside of the bent portion. May occur. Wrinkles on the inside of the bent portion are not preferable because the resin does not easily penetrate into the bent portion when the fiber structure is impregnated with the resin.
  • the flat surface portion on one side of the bent portion has a bent portion.
  • the path of the thread connected to the inside and the path of the thread connected to the inside of the bent portion at the flat surface portion on the other side of the bent portion intersect at the bent portion in the thickness direction of the fiber structure.
  • the present disclosure has been made to solve the above problems, and an object of the present disclosure is to provide a fiber structure capable of suppressing the occurrence of wrinkles on the inside of bending and a method for producing the fiber structure.
  • the fiber structure that solves the above problems is a flat plate-like fiber structure that is a multilayer woven fabric in which the first yarn and the second yarn made of reinforcing fibers are arranged in directions orthogonal to each other, and the yarn main shaft of the first yarn.
  • the direction in which the yarn extends is the first direction and the direction in which the yarn main shaft of the second yarn extends is the second direction
  • the one side in the laminating direction of the multilayer woven fabric is bent as the outer side and becomes the outer side.
  • the fiber structure for shaping that is bent along the first direction and the first yarn arranged on the outer surface is the outer yarn
  • the multilayer woven fabric is more than the outer yarn in the laminating direction.
  • the auxiliary yarn is provided so as to overlap the outer yarn in the stacking direction, and the auxiliary yarn has a property that the amount of decrease in thickness is larger than that of the first yarn and the second yarn. It is characterized by having.
  • the method for producing a fiber structure that solves the above problems is a method for producing a flat plate-shaped fiber structure that is a multilayer woven fabric in which the first yarn and the second yarn made of reinforcing fibers are arranged in directions orthogonal to each other.
  • the direction in which the yarn main shaft of the first yarn extends is the first direction and the direction in which the yarn main shaft of the second yarn extends is the second direction
  • one surface in the stacking direction of the multilayer woven fabric is bent as the outer surface.
  • It is a method of manufacturing a fiber structure for shaping that is bent along the first direction so as to be such that the first yarn is arranged on the outer surface as an outer yarn and auxiliary yarns are arranged in the stacking direction.
  • the path of the outer thread after shaping becomes shorter than that before shaping by the amount that the thickness of the auxiliary thread is reduced. Therefore, a surplus that does not contribute to the path is generated in the outer yarn.
  • the dimension in the first direction can be extended by the excess of the outer thread as compared with the fiber structure before shaping.
  • the dimensions of the first yarns arranged inside the bend in the first direction are less likely to be excessive, so that the occurrence of wrinkles inside the bend can be suppressed.
  • the auxiliary yarn is preferably a weft.
  • the warp opening operation by the heddle frame and the insertion of the weft thread into the warp opening formed by the opening operation are repeated. Since the opening operation of the warp is performed by moving the entire warp up and down, the man-hours related to the opening operation of the warp may increase as the number of warp used for weaving increases.
  • the fiber structure can be woven by adding an auxiliary yarn as a weft. Therefore, the increase in man-hours related to the addition of the auxiliary yarn can be reduced as compared with the case where the auxiliary yarn is added to the fiber structure as a warp.
  • the auxiliary yarn preferably has a lower melting point than the first yarn and the second yarn. According to the above configuration, if the fiber structure is heat-treated at a temperature lower than the melting points of the first yarn and the second yarn and at a temperature equal to or higher than the melting point of the auxiliary yarn, the auxiliary yarn melts and the thickness of the auxiliary yarn is increased. Becomes smaller. Then, the path of the outer thread can be shortened by the amount that the thickness of the auxiliary thread is reduced. Therefore, by generating a surplus that does not contribute to the path in the outer yarn, it is possible to suppress the occurrence of wrinkles inside the bending.
  • the auxiliary yarn preferably has a lower fiber density than the first yarn and the second yarn.
  • the amount of decrease in the thickness of the auxiliary yarn when pressed from the surroundings is the amount of decrease in the thickness of the first yarn and the second yarn. Will be larger than.
  • the auxiliary thread in the fiber structure after shaping is pressed by the surrounding threads during shaping, so that the thickness of the auxiliary thread in the fiber structure before shaping becomes smaller than that in the auxiliary thread in the fiber structure before shaping. Therefore, by generating a surplus that does not contribute to the path in the outer yarn, it is possible to suppress the occurrence of wrinkles inside the bending.
  • the auxiliary yarn which is in the inner layer of the outer yarn in the laminating direction and is arranged so as to overlap the outer yarn in the laminating direction is used as the first auxiliary yarn, and the outer yarn is used in the laminating direction.
  • the multilayer fabric is in the inner layer of the inner layer yarn in the stacking direction and is arranged so as to overlap the inner layer yarn in the stacking direction.
  • the second auxiliary thread, which is the auxiliary thread is further provided, and the thickness of the second auxiliary thread is smaller than that of the first auxiliary thread.
  • the thickness of the auxiliary thread in the fiber structure before shaping becomes smaller as the inner layer in the stacking direction.
  • a surplus that does not contribute to the path is generated in both the outer thread and the inner layer thread by the amount that the thickness of the auxiliary thread is reduced.
  • the surplus increases as the amount of decrease in the thickness of the auxiliary yarn increases. Therefore, the surplus increases in the outer yarn as in the inner yarn. Therefore, since the amount of elongation of the outer yarn on the bending outer side can be made larger than that of the inner layer yarn, the above-mentioned elongation amount can be set according to the shape of the fiber structure after shaping.
  • the occurrence of wrinkles inside the bend can be suppressed.
  • the perspective view which shows the fiber-reinforced composite material in the 1st Embodiment The cross-sectional view which shows typically the fiber structure in 1st Embodiment.
  • the fiber structure 11 is impregnated with the matrix resin 12 to form the fiber reinforced composite material 10.
  • the matrix resin 12 for example, an epoxy resin which is a thermosetting resin is used.
  • the fiber structure 11 is made of a multilayer woven fabric 10a.
  • the three-dimensional fiber structure 11 is formed by shaping the flat fiber structure 11 into an L shape.
  • the fiber structure 11 has a three-dimensional plate shape in which the first flat surface portion 16, the second flat surface portion 17, and the bent portion 18 located between the first flat surface portion 16 and the second flat surface portion 17 are continuous. ..
  • the laminating direction of the multilayer woven fabric 10a is referred to as the laminating direction Y.
  • the fiber structure 11 of the present embodiment has a plurality of weft layers formed by arranging a plurality of wefts 14 in the first direction X1.
  • the plurality of weft layers are laminated in the stacking direction Y.
  • the yarn spindles of the plurality of weft yarns 14 extend in the second direction X2.
  • the first direction X1 and the second direction X2 are both directions orthogonal to the stacking direction Y and orthogonal to each other.
  • the first weft layer 41, the second weft layer 42, the third weft layer 43, the fourth weft layer 44, the fifth weft layer 45, and the sixth weft The weft layers are laminated in the order of the layer 46 and the seventh weft layer 47.
  • the weft layer other than the first weft layer 41 is composed of a second yarn 14a composed of a bundle of reinforcing fibers in which a plurality of reinforcing fibers are bundled.
  • the first weft layer 41 is composed of an auxiliary yarn 15.
  • the reinforcing fiber constituting the second yarn 14a of the present embodiment is a carbon fiber.
  • the fiber constituting the auxiliary thread 15 of the present embodiment is a nylon fiber.
  • the fiber structure 11 has a plurality of warp threads 13 arranged in the stacking direction Y.
  • the yarn spindles of the plurality of warp yarns 13 extend in the first direction X1.
  • the fiber structure 11 includes, as the warp 13, the first warp 21 and the second warp 22 arranged on both sides of the first weft layer 41, the second weft layer 42, and the third weft layer 43 in the stacking direction Y.
  • a third warp 23 and a fourth warp 24 arranged on both sides of the third weft layer 43 and the fourth weft layer 44 in the stacking direction Y.
  • the fiber structure 11 has, as the warp 13, the fifth warp 25 and the sixth warp 26 arranged on both sides of the fourth weft layer 44 and the fifth weft layer 45 in the stacking direction Y, the fifth weft layer 45, and the fifth weft layer 45. It has a seventh warp 27 and an eighth warp 28 arranged on both sides of the sixth weft layer 46 in the stacking direction Y.
  • the fiber structure 11 has the 9th warp 29 and the 10th warp 30 and the 7th weft layer 47 arranged on both sides of the 6th weft layer 46 and the 7th weft layer 47 in the stacking direction Y as the warp 13.
  • the eleventh warp 31 and the twelfth warp 32 are arranged on both sides in the stacking direction Y. All of these warp threads 13 are composed of a first thread 13a composed of a reinforcing fiber bundle in which a plurality of reinforcing fibers are bundled.
  • the reinforcing fiber constituting the first yarn 13a of the present embodiment is a carbon fiber.
  • a plurality of the warp threads 13 are arranged in the second direction X2.
  • the warp threads 13 arranged in the second direction X2 have a similar arrangement mode in the stacking direction Y.
  • the first warp 21 and the second warp 22 are alternately positioned in the first direction X1 on the outer surface 11a as one surface of the fiber structure 11 in the stacking direction Y.
  • auxiliary threads 15 constituting the first weft layer 41 are overlapped in the stacking direction Y in the inner layer in the stacking direction Y with respect to the first warp 21.
  • auxiliary threads 15 constituting the first weft layer 41 are overlapped in the stacking direction Y in the inner layer in the stacking direction Y with respect to the second warp 22.
  • first warp thread 21 and the second warp thread 22 are engaged with the auxiliary thread 15 forming the first weft thread layer 41 and the second thread 14a forming the third weft thread layer 43.
  • the auxiliary yarns 15 adjacent to each other in the first direction X1 are engaged with the first warp yarns 21 and the second warp yarns 22 adjacent to each other in the second direction X2.
  • the first warp 21 is engaged with one and the second warp 22 is engaged with the other.
  • the first warp 21 and the second warp 22 are not engaged with the second thread 14a forming the second weft layer 42.
  • the auxiliary yarn 15 forming the first weft layer 41, the second yarn 14a forming the second weft layer 42, and the second yarn 14a forming the third weft layer 43 are formed by the first warp 21 and the second warp 22. It is bonded in the stacking direction Y.
  • the first warp 21 and the second warp 22 correspond to the outer yarn.
  • the tenth warp 30 and the twelfth warp 32 and the ninth warp 29 and the eleventh warp 31 are in the first direction X1. Alternately located.
  • the fiber structure 11 will be described in an L-shaped shape.
  • the intermediate portion between the first plane portion 16 and the second plane portion 17 in the first direction X1 is bent along the first direction X1.
  • the bent portion 18 is formed.
  • the first flat surface portion 16, the bent portion 18, and the second flat surface portion 17 are continuous along the first direction X1 by the warp threads 13.
  • the outer surface 11a is the bent outer side and the inner side surface 11b is the bent inner side.
  • each of the first plane portion 16 and the second plane portion 17 a plurality of weft threads 14 are arranged in the first direction X1, and a plurality of warp threads 13 are arranged in the second direction X2. They are lined up in.
  • Each weft 14 arranged in the first plane portion 16 and the second plane portion 17 extends in the second direction X2 in a wavy state in the stacking direction Y.
  • Each of the warp threads 13 arranged in the first plane portion 16 and the second plane portion 17 extends in the first direction X1 in a wavy state in the stacking direction Y.
  • a plurality of warp threads 13 and a plurality of weft threads 14 are arranged along the arc of the bent portion 18 in a wavy state in the stacking direction Y.
  • the extending directions of the arranged warp threads 13 are different between the first plane portion 16 and the second plane portion 17. That is, the first direction X1 which is the yarn main axis direction of the warp thread 13 is different between the first plane portion 16 and the second plane portion 17.
  • the thickness of the auxiliary thread 15 constituting the first weft layer 41 is smaller than that before shaping of the fiber structure 11. ..
  • the dimension L2 passing outside the bent portion 18 is larger than the dimension L1 passing inside the bent portion 18. Is also big.
  • the method for manufacturing the fiber structure 11 includes a weaving step of weaving a flat plate-shaped fiber structure 11, a heating step of heating the fiber structure 11, a shaping step of shaping the fiber structure 11, and a fiber structure. 11 is provided with an impregnation step of impregnating the resin.
  • the flat fiber structure 11 is woven using a multi-layer loom.
  • the multi-layer loom of the present embodiment includes a warp beam for supplying a plurality of warp threads 13 and a heddle frame for opening the plurality of warp threads 13 by moving them up and down.
  • the second yarn 14a and the auxiliary yarn 15 is inserted as the weft yarn 14 by the weft insertion mechanism into the opening of the warp yarn 13.
  • each of the first threads 13a constituting each warp thread 13 is opened.
  • openings are sequentially formed.
  • each weft 14 is wefted into the opening between the first warp 21 and the second warp 22.
  • each weft 14 is formed from the outer surface 11a side in the stacking direction Y, the auxiliary yarn 15 of the first weft layer 41, the second yarn 14a of the second weft layer 42, and the second yarn 14a of the third weft layer 43. It is wefted so that it is arranged in the order of. As a result, the first warp 21 and the second warp 22 engage with the auxiliary thread 15 of the first weft layer 41 and the second thread 14a of the third weft layer 43.
  • the auxiliary yarn 15 of the first weft layer 41, the second yarn 14a of the second weft layer 42, and the second yarn 14a of the third weft layer 43 are coupled in the stacking direction Y by the first warp 21 and the second warp 22. Will be done. Further, in the first direction X1 of the fiber structure 11, in the portion where the first warp 21 is located on the outer surface 11a, the auxiliary thread 15 becomes the first warp 21 in the inner layer in the stacking direction Y than the first warp 21. They are arranged so as to overlap in the stacking direction Y.
  • the auxiliary thread 15 is in the stacking direction with the second warp 22 in the inner layer in the stacking direction Y than the second warp 22. They are arranged overlapping with Y.
  • the fiber structure 11 after the weaving step has the arrangement mode of the warp threads 13 and the weft threads 14 shown in FIG. 2 over the entire first direction X1.
  • the flat fiber structure 11 is formed by repeating the formation of the opening of the warp thread 13 by the heddle frame and the insertion of the weft thread 14 into the opening.
  • the first warp 21 and the second warp 22 are arranged on the outer surface 11a, and all the warp 13 including the first warp 21 engage with the second warp 14a, respectively.
  • a heating process is performed.
  • the fiber structure 11 is placed in a heating furnace and heated to a predetermined temperature.
  • This predetermined temperature is lower than the melting point of the carbon fibers constituting the first yarn 13a and the second yarn 14a, and is higher than the melting point of the nylon fibers constituting the auxiliary yarn 15.
  • the auxiliary thread 15 in the fiber structure 11 is melted. Therefore, in the fiber structure 11 after the heating step, the thickness of the auxiliary thread 15 becomes smaller as shown by the alternate long and short dash line in FIG.
  • the first yarn 13a and the second yarn 14a do not melt in the heating step, the thicknesses of the first yarn 13a and the second yarn 14a do not change before and after the heating step. Therefore, it can be said that the auxiliary yarn 15 has a property that the amount of decrease in thickness is larger than that of the first yarn 13a and the second yarn 14a with the heating step.
  • the heating step corresponds to the reduction step.
  • the paths of the first warp threads 21 and the second warp threads 22 that engage with the auxiliary threads 15 are reduced by the amount that the thickness of the auxiliary threads 15 constituting the first weft layer 41 is reduced. Is shorter than before the heating process. Therefore, in the fiber structure 11, the first warp 21 and the second warp 22 become loose. A surplus that does not contribute to the path is generated in the first warp 21 and the second warp 22.
  • the flat fiber structure 11 after the heating step is fitted into the mold to shape the fiber structure 11 into an L shape shown in FIG.
  • the surplus of the first warp 21 and the second warp 22 generated after the heating step grows along the first direction X1.
  • the dimensions in the first direction X1 can be extended by the surplus of the first warp 21 and the second warp 22 as compared with the fiber structure 11 before shaping.
  • the dimension L2 passing outside the bent portion 18 becomes larger than the dimension L1 passing inside the bent portion 18.
  • an impregnation step is performed.
  • the fiber-reinforced composite material 10 is formed by impregnating the fiber structure 11 after shaping with the matrix resin 12. According to the above embodiment, the following effects can be obtained.
  • the auxiliary thread 15 has a smaller thickness of the auxiliary thread 15 after shaping the fiber structure 11 by making the thickness of the auxiliary thread 15 smaller than that before shaping the fiber structure 11.
  • the path of the first warp 21 and the second warp 22 after shaping becomes shorter than that before shaping. Therefore, a surplus that does not contribute to the path is generated in the first warp 21 and the second warp 22.
  • the dimensions in the first direction X1 can be extended by the surplus of the first warp 21 and the second warp 22 as compared with the fiber structure 11 before shaping.
  • the dimensions of the first yarn 13a arranged inside the bend in the first direction X1 are less likely to be excessive, so that the occurrence of wrinkles inside the bend of the fiber structure 11 can be suppressed.
  • the opening operation of the warp thread 13 by the heddle frame and the insertion of the weft thread 14 into the opening of the warp thread 13 formed by the opening operation are repeated. .. Since the opening operation of the warp thread 13 is performed by moving the entire warp thread 13 up and down, as the number of warp threads 13 used for weaving increases, the man-hours related to the opening operation of the warp thread 13 may increase.
  • the auxiliary yarn 15 is added as the weft yarn 14 to weave the fiber structure 11. Therefore, as compared with the case where the auxiliary thread 15 is added to the fiber structure 11 as the warp thread 13, the increase in man-hours related to the addition of the auxiliary thread 15 can be reduced.
  • the auxiliary thread 15 has a lower melting point than the first thread 13a and the second thread 14a. Therefore, if the fiber structure 11 is heat-treated at a temperature lower than the melting points of the first yarn 13a and the second yarn 14a and at a temperature equal to or higher than the melting point of the auxiliary yarn 15 in the heating step, the auxiliary yarn 15 is heated in the heating step. Melts and the thickness of the auxiliary thread 15 becomes smaller. Then, the paths of the first warp thread 21 and the second warp thread 22 can be shortened by the amount that the thickness of the auxiliary thread 15 is reduced. Therefore, by generating a surplus that does not contribute to the path in the first warp 21 and the second warp 22, it is possible to suppress the occurrence of wrinkles inside the bending of the fiber structure 11.
  • FIGS. 1 and 3 a second embodiment embodying the fiber structure and the method for manufacturing the fiber structure will be described with reference to FIGS. 1 and 3. In the following, the differences from the first embodiment will be mainly described.
  • the first weft layer 41, the second weft layer 42, the third weft layer 43, and the third weft layer 43 are arranged from one side to the other in the stacking direction Y.
  • the weft layers are laminated in the order of the 4 weft layer 44, the 5th weft layer 45, the 6th weft layer 46, the 7th weft layer 47, and the 8th weft layer 48.
  • the weft layers other than the first weft layer 41 and the third weft layer 43 are composed of the second yarn 14a.
  • the first weft layer 41 and the third weft layer 43 are composed of auxiliary threads 15.
  • the auxiliary thread 15 constituting the first weft layer 41 is referred to as a first auxiliary thread 15a
  • the auxiliary thread 15 constituting the third weft layer 43 is referred to as a second auxiliary thread 15b.
  • the second auxiliary thread 15b is smaller in thickness than the first auxiliary thread 15a.
  • the fiber structure 111 is a warp 13, and the first warp 21 and the first warp 21 and the first warp layer 41 arranged on both sides of the first weft layer 41, the second weft layer 42, the third weft layer 43, and the fourth weft layer 44 in the stacking direction Y. It has two warp threads 22, a third warp thread 23 and a fourth warp thread 24 arranged on both sides of the third weft thread layer 43, the fourth weft layer 44, and the fifth weft layer 45 in the stacking direction Y.
  • the fiber structure 111 includes the fifth warp threads 25 and the sixth warp threads 26 arranged on both sides of the fifth weft thread layer 45 and the sixth weft layer 46 in the stacking direction Y, the sixth weft thread layer 46, and the warp threads 13. It has a seventh warp 27 and an eighth warp 28 arranged on both sides of the seventh weft layer 47 in the stacking direction Y.
  • the fiber structure 111 includes the 9th warp 29 and the 10th warp 30 and the 8th weft layer 48 arranged on both sides of the 7th weft layer 47 and the 8th weft layer 48 in the stacking direction Y as the warp 13.
  • the eleventh warp 31 and the twelfth warp 32 are arranged on both sides in the stacking direction Y. All of these warp threads 13 are composed of the first thread 13a.
  • the first auxiliary yarn 15a constituting the first weft yarn layer 41 is laminated on the inner layer in the stacking direction Y from the first warp yarn 21. It overlaps in the direction Y.
  • the first auxiliary yarn 15a constituting the first weft layer 41 is formed in the inner layer in the stacking direction Y from the second warp 22 in the stacking direction Y. It overlaps with.
  • the first warp 21 and the second warp 22 are engaged with the first auxiliary thread 15a constituting the first weft layer 41 and the second thread 14a forming the fourth weft layer 44.
  • the first auxiliary yarn 15a adjacent to each other in the first direction X1 is engaged with the first warp yarn 21 and the second warp yarn 22 adjacent to each other in the second direction X2.
  • the first warp thread 21 is engaged with one and the second warp thread 22 is engaged with the other.
  • the first warp 21 and the second warp 22 are not engaged with the second yarn 14a constituting the second weft layer 42 and the second auxiliary yarn 15b forming the third weft layer 43.
  • the first auxiliary yarn 15a constituting the first weft layer 41, the second yarn 14a forming the second weft layer 42, the second auxiliary yarn 15b forming the third weft layer 43, and the fourth weft layer 44 are formed.
  • the second yarn 14a is connected in the stacking direction Y by the first warp 21 and the second warp 22.
  • the first warp 21 and the second warp 22 correspond to the outer yarn.
  • the third warp 23 and the fourth warp 24 are alternately positioned in the first direction X1. That is, the third warp thread 23 located on the outer surface 11a side of the third weft thread layer 43 has a second auxiliary thread forming the third weft thread layer 43 in the inner layer in the stacking direction Y from the third warp thread 23. 15b overlaps in the stacking direction Y.
  • the fourth warp yarn 24 located on the outer surface 11a side of the third weft yarn layer 43 has a second auxiliary yarn 15b constituting the third weft yarn layer 43 in the inner layer in the stacking direction Y from the fourth warp yarn 24.
  • the third warp thread 23 and the fourth warp thread 24 are engaged with the second auxiliary thread 15b forming the third weft thread layer 43 and the second thread 14a forming the fifth weft thread layer 45.
  • the second auxiliary yarn 15b adjacent to each other in the first direction X1 is engaged with the third warp yarn 23 and the fourth warp yarn 24 adjacent to each other in the second direction X2.
  • the third warp thread 23 is engaged with one and the fourth warp thread 24 is engaged with the other.
  • the third warp 23 and the fourth warp 24 are not engaged with the second thread 14a constituting the fourth weft layer 44.
  • the second auxiliary yarn 15b constituting the third weft layer 43, the second yarn 14a constituting the fourth weft layer 44, and the second yarn 14a constituting the fifth weft layer 45 are the third warp 23 and the fourth warp. It is connected in the stacking direction Y by 24.
  • the third warp 23 and the fourth warp 24 correspond to the inner layer yarn.
  • the fiber structure 111 after shaping in the present embodiment has an L-shaped three-dimensional shape as in the first embodiment. Then, in the fiber structure 111 after shaping, the first auxiliary thread 15a and the second auxiliary thread 15b are missing from the fiber structure 111. As a result, as shown in FIG. 1, among the dimensions along the first direction X1 of the fiber structure 111 after shaping, the dimension L2 passing through the outside of the bent portion 18 passes through the inside of the bent portion 18. It is larger than L1.
  • the method for producing the fiber structure 11 includes a weaving step, a shaping step, and an impregnation step, and also includes a sampling step of extracting the auxiliary thread 15.
  • the manufacturing method in the first embodiment is different from the manufacturing method in that a sampling step is performed instead of the heating step.
  • the flat fiber structure 111 is woven using a multi-layer loom. Then, in the multilayer loom, any one of the second yarn 14a, the first auxiliary yarn 15a, and the second auxiliary yarn 15b is inserted as the weft yarn 14 by the weft insertion mechanism into the opening of the warp yarn 13.
  • each weft 14 is wefted into the openings between the first warp 21 and the second warp 22. ..
  • each weft 14 is a second auxiliary thread 15a of the first weft layer 41, a second thread 14a of the second weft layer 42, and a second auxiliary thread of the third weft layer 43 from the outer surface 11a side in the stacking direction Y.
  • the yarn 15b and the second yarn 14a of the fourth weft layer 44 are wefted so as to be arranged in this order.
  • the first warp yarn 21 and the second warp yarn 22 engage with the first auxiliary yarn 15a of the first weft yarn layer 41 and the second yarn 14a of the fourth weft yarn layer 44.
  • the first auxiliary thread 15a of the first weft layer 41, the second thread 14a of the second weft layer 42, the second auxiliary thread 15b of the third weft layer 43, and the fourth The second yarn 14a of the weft layer 44 is joined in the stacking direction Y.
  • the first auxiliary thread 15a is the first warp in the inner layer in the stacking direction Y than the first warp 21. It is arranged so as to overlap with 21 in the stacking direction Y.
  • the first auxiliary thread 15a and the second warp 22 are formed in the inner layer in the stacking direction Y than the second warp 22. They are arranged so as to overlap in the stacking direction Y.
  • each weft 14 is wefted into the openings between the third warp 23 and the fourth warp 24.
  • each weft 14 is formed from the outer surface 11a side in the stacking direction Y, the second auxiliary yarn 15b of the third weft layer 43, the second yarn 14a of the fourth weft layer 44, and the second yarn layer 45 of the fifth weft layer 45. Wefting is performed so that the threads 14a are arranged in this order.
  • the third warp thread 23 and the fourth warp thread 24 are engaged with the second auxiliary thread 15b of the third weft thread layer 43 and the second thread 14a of the fifth weft thread layer 45.
  • the second auxiliary yarn 15b of the third weft layer 43, the second yarn 14a of the fourth weft layer 44, and the second yarn 14a of the fifth weft layer 45 are laminated in the stacking direction Y. Will be combined with.
  • the second auxiliary thread 15b is the third in the inner layer in the stacking direction Y than the third warp 23.
  • the warp threads 23 and the warp threads 23 are arranged so as to overlap each other in the stacking direction Y.
  • the second auxiliary thread 15b is the fourth warp 24 in the inner layer in the stacking direction Y than the fourth warp 24. And are arranged so as to overlap in the stacking direction Y.
  • the weft 14 is inserted into the openings of the first warp 21 and the second warp 22 and the weft 14 is inserted into the openings of the third warp 23 and the fourth warp 24 in the same manner as described above.
  • the insertion is done.
  • the fiber structure 111 after the weaving step has the arrangement mode of the warp threads 13 and the weft threads 14 shown in FIG. 3 over the entire first direction X1.
  • the thickness of the second auxiliary thread 15b is smaller than that of the first auxiliary thread 15a. That is, in the woven flat fiber structure 111, the thickness of the auxiliary thread 15 is smaller in the inner layer in the stacking direction Y than in the outer surface 11a. Therefore, at the stage of the flat fiber structure 11, the paths of the third warp threads 23 and the fourth warp threads 24 that engage with the second auxiliary thread 15b are the first warp threads 21 and the first warp threads that engage with the first auxiliary thread 15a. It is shorter than the path of the two warp threads 22.
  • a sampling process is performed.
  • the first auxiliary thread 15a and the second auxiliary thread 15b are extracted from the fiber structure 111. Since the first auxiliary thread 15a and the second auxiliary thread 15b are removed from the fiber structure 111 by the extraction step, it can be said that the thickness of the first auxiliary thread 15a and the second auxiliary thread 15b is reduced by the extraction step. On the other hand, the thicknesses of the first thread 13a and the second thread 14a do not change before and after the extraction process. Therefore, it can be said that the first auxiliary thread 15a and the second auxiliary thread 15b have a property that the amount of decrease in thickness is larger than that of the first thread 13a and the second thread 14a with the extraction step.
  • the sampling process corresponds to the reduction process.
  • the 22 paths are shorter than before the sampling process. Therefore, in the fiber structure 111, the first warp 21 and the second warp 22 become loose. A surplus that does not contribute to the path is generated in the first warp 21 and the second warp 22.
  • the third warp threads 23 and the third warp threads 23 and the second auxiliary threads that are engaged with the second auxiliary threads 15b are extracted by the amount that the second auxiliary threads 15b constituting the third weft layer 43 are extracted.
  • the path of the 4 warp threads 24 is also shorter than that before the extraction process. Therefore, in the fiber structure 111, the third warp 23 and the fourth warp 24 become loose, and a surplus that does not contribute to the path is generated in the third warp 23 and the fourth warp 24.
  • the path of the third warp thread 23 and the fourth warp thread 24 was the first. It was shorter than the path of the 1st warp 21 and the 2nd warp 22. That is, the amount of decrease in the paths of the third warp 23 and the fourth warp 24 due to the extraction of the second auxiliary thread 15b is the amount of decrease in the paths of the first warp 21 and the second warp 22 due to the extraction of the first auxiliary thread 15a. Is smaller than Therefore, in the fiber structure 111 after the extraction step, the excess amount of the third warp 23 and the fourth warp 24 is smaller than that of the first warp 21 and the second warp 22.
  • the shaping step the flat fiber structure 111 after the extraction step is fitted into the mold in the same manner as in the first embodiment to shape the fiber structure 111 into an L shape shown in FIG.
  • the surplus of the first warp 21 and the second warp 22 and the surplus of the third warp 23 and the fourth warp 24 generated after the extraction step are extended along the first direction X1.
  • the size in the first direction X1 can be extended by the above surplus as compared with the fiber structure 111 before shaping.
  • the portion of the outer surface 11a of the fiber structure 111 where the first warp 21 and the second warp 22 are located is the portion where the third warp 23 and the fourth warp 24 are located, and is larger than the outer surface 11a. It extends more along the first direction X1 than the portion of the inner layer in the stacking direction Y.
  • the dimension L2 passing outside the bent portion 18 becomes larger than the dimension L1 passing inside the bent portion 18. Then, the fiber-reinforced composite material 10 is formed by performing an impregnation step after the shaping step.
  • the following effects can be obtained in addition to the effects of the first embodiment.
  • the surplus in the first warp 21 and the second warp 22 is larger than the surplus in the third warp 23 and the fourth warp 24. Therefore, the amount of elongation of the first warp 21 and the second warp 22 on the bending outer side of the third warp 23 and the fourth warp 24 can be increased, so that the above-mentioned elongation can be adjusted according to the shape of the fiber structure 11 after shaping. You can set the amount.
  • the first weft layer 41 and the second weft layer are formed from one side to the other in the stacking direction Y, as in the first embodiment.
  • the weft layers are laminated in the order of 42, the third weft layer 43, the fourth weft layer 44, the fifth weft layer 45, the sixth weft layer 46, and the seventh weft layer 47.
  • the weft layer other than the first weft layer 41 is composed of the second thread 14a
  • the first weft layer 41 is composed of the auxiliary thread 15.
  • the auxiliary yarn 15 constituting the first weft layer 41 is referred to as a weft auxiliary yarn 115a.
  • both the first warp 121 and the second warp 122 and the third warp 123 and the fourth warp 124 are the first weft layer 41, the second weft layer 42, and the second warp.
  • the three weft layers 43 are arranged on both sides in the stacking direction Y.
  • the fiber structure 161 includes the fifth warp 125 and the sixth warp 126 arranged on both sides of the third weft layer 43 and the fourth weft layer 44 in the stacking direction Y, and the fourth weft layer 44 as the warp 13. It has a seventh warp 127 and an eighth warp 128 arranged on both sides of the fifth weft layer 45 in the stacking direction Y.
  • the fiber structure 161 includes the 9th warp 129 and the 10th warp 130 and the 6th weft layer 46 arranged on both sides of the 5th weft layer 45 and the 6th weft layer 46 in the stacking direction Y as the warp 13. And the eleventh warp 131 and the twelfth warp 132 arranged on both sides of the seventh weft layer 47 in the stacking direction Y.
  • the fiber structure 161 has the 13th warp 133 and the 14th warp 134 arranged on both sides of the 7th weft layer 47 in the stacking direction Y as the warp 13.
  • the warp threads 13 other than the third warp thread 123 and the fourth warp thread 124 are composed of the first thread 13a.
  • the third warp 123 and the fourth warp 124 are composed of an auxiliary thread 15.
  • the auxiliary thread 15 constituting the third warp thread 123 and the fourth warp thread 124 will be referred to as a warp auxiliary thread 115b.
  • the warp auxiliary threads 115b constituting the third warp thread 123 are overlapped in the stacking direction Y in the inner layer in the stacking direction Y with respect to the outer surface 11a.
  • the warp auxiliary yarn 115b constituting the fourth warp yarn 124 overlaps in the stacking direction Y in the inner layer in the stacking direction Y with respect to the outer surface 11a.
  • the warp auxiliary thread 115b overlaps the first warp thread 121 and the second warp thread 122 over the entire first direction X1 of the fiber structure 161.
  • the first warp threads 121 and the second warp threads 122 are alternately located along the first direction X1.
  • the weft auxiliary thread 115a constituting the first weft thread layer 41 is provided with the warp auxiliary thread 115b in the stacking direction Y in the inner layer in the stacking direction Y than the first warp thread 121. Overlapping through.
  • the weft auxiliary yarn 115a constituting the first weft yarn layer 41 is formed in the inner layer in the stacking direction Y from the second warp yarn 122 in the stacking direction Y. It overlaps with the warp auxiliary thread 115b. Further, the weft auxiliary yarn 115a forming the first weft layer 41 and the second yarn 14a forming the third weft layer 43 include the first warp 121, the second warp 122, the third warp 123, and the fourth warp 124. Are engaged.
  • the weft auxiliary threads 115a adjacent to each other in the first direction X1 are engaged with the first warp 121, the second warp 122, the third warp 123, and the fourth warp 124 adjacent to each other in the second direction X2. doing.
  • the first warp 121 and the third warp 123 are engaged with one
  • the second warp 122 and the fourth warp 124 are engaged with the other. Engaged.
  • first warp 121, the second warp 122, the third warp 123, and the fourth warp 124 are not engaged with the second thread 14a constituting the second weft layer 42.
  • the weft auxiliary yarn 115a forming the first weft layer 41, the second yarn 14a forming the second weft layer 42, and the second yarn 14a forming the third weft layer 43 are the first warp 121 and the second warp 122.
  • the third warp 123, and the fourth warp 124 are connected in the stacking direction Y.
  • the first warp 121 and the second warp 122 correspond to the outer yarn.
  • the fiber structure 161 after shaping in the present embodiment has an L-shaped three-dimensional shape as in the first embodiment. Then, in the fiber structure 161 after shaping, the weft auxiliary thread 115a and the warp auxiliary thread 115b are eliminated from the fiber structure 161. As a result, as shown in FIG. 1, among the dimensions along the first direction X1 of the fiber structure 161 after shaping, the dimension L2 passing through the outside of the bent portion 18 passes through the inside of the bent portion 18. It is larger than L1.
  • the method for producing the fiber structure 161 in the present embodiment includes a weaving step, a shaping step, and an impregnation step, and also includes a sampling step of extracting the auxiliary thread 15.
  • the manufacturing method in the first embodiment is different from the manufacturing method in that a sampling step is performed instead of the heating step.
  • the warp beam supplies the second auxiliary thread 15b in addition to the first thread 13a as the warp thread 13, and the heddle frame is the first thread 13a and the warp auxiliary thread 115b.
  • Make an opening The opening operation of the first warp thread 121 and the second warp thread 122 by the heddle frame maintains a state in which the warp auxiliary thread 115b is overlapped with each warp thread 13 in the inner layer in the stacking direction Y than each warp thread 13. Do it while doing.
  • the set of the warp auxiliary thread 115b in the first warp 121 and the warp auxiliary thread 123 in the third warp 123, and the warp auxiliary thread 115b in the first thread 13a and the fourth warp 124 in the second warp 122 By alternately moving the sets up and down in the stacking direction Y, openings by the first warp set 151 and the second warp set 152 are sequentially formed.
  • the set of the first warp thread 13a in the first warp thread 121 and the warp auxiliary thread 115b in the third warp thread 123 is referred to as the first warp thread set 151.
  • the set of the first thread 13a in the second warp 122 and the warp auxiliary thread 115b in the fourth warp 124 is called the second warp set 152.
  • each weft 14 is wefted into the opening between the first warp assembly 151 and the second warp assembly 152.
  • each weft 14 is formed from the outer surface 11a side in the stacking direction Y, the weft auxiliary yarn 115a of the first weft layer 41, the second yarn 14a of the second weft layer 42, and the second yarn of the third weft layer 43. It is wefted so that it is arranged in the order of 14a.
  • first warp set 151 and the second warp set 152 are engaged with the weft auxiliary thread 115a of the first weft layer 41 and the second thread 14a of the third weft layer 43.
  • first warp set 151 and the second warp set 152 the weft auxiliary thread 115a of the first weft layer 41, the second thread 14a of the second weft layer 42, and the second thread 14a of the third weft layer 43 are laminated. It will be combined with Y.
  • the weft auxiliary thread 115a is the first warp 121 in the inner layer in the stacking direction Y than the first warp 121. And are arranged so as to overlap with each other via the warp auxiliary thread 115b in the stacking direction Y.
  • the weft auxiliary thread 115a is laminated with the second warp 122 in the inner layer in the stacking direction Y than the second warp 122. They are arranged so as to overlap with each other via the warp auxiliary thread 115b in the direction Y.
  • the fiber structure 161 after the weaving step in the present embodiment has the arrangement mode of the warp threads 13 and the weft threads 14 shown in FIG. 4 over the entire first direction X1.
  • the weft auxiliary thread 115a and the warp auxiliary thread 115b are extracted from the fiber structure 161. Since the weft auxiliary thread 115a and the warp auxiliary thread 115b are removed from the fiber structure 161 by the extraction step, it can be said that the thickness of the weft auxiliary thread 115a and the warp auxiliary thread 115b is reduced by the extraction step. On the other hand, the thicknesses of the first thread 13a and the second thread 14a do not change before and after the extraction process.
  • the weft auxiliary yarn 115a and the warp auxiliary yarn 115b have a property that the amount of decrease in thickness is larger than that of the first yarn 13a and the second yarn 14a with the extraction step.
  • the sampling process corresponds to the reduction process.
  • the first warp threads 121 and the second warp threads 122 that were engaged with the weft auxiliary threads 115a by the amount of the weft auxiliary threads 115a constituting the first weft thread layer 41 were extracted.
  • the route is shorter than before the sampling process.
  • the paths of 121 and the second warp 122 are shorter than before the extraction process. Therefore, in the fiber structure 161, the first warp 121 and the second warp 122 become loose, and a surplus that does not contribute to the path is generated in the first warp 121 and the second warp 122.
  • the flat fiber structure 161 after the extraction step is fitted into the mold in the same manner as in the first embodiment to shape the fiber structure 161 into the L shape shown in FIG.
  • the surplus portion of the first warp thread 121 and the second warp thread 122 generated after the extraction step is extended along the first direction X1.
  • the size in the first direction X1 can be extended by the above surplus as compared with the fiber structure 161 before shaping.
  • the dimension L2 passing outside the bent portion 18 becomes larger than the dimension L1 passing inside the bent portion 18.
  • the fiber-reinforced composite material 10 is formed by performing an impregnation step after the shaping step.
  • the following effects can be obtained in addition to the effects of the first embodiment.
  • (3-1) Auxiliary yarn 15 is added to both the warp yarn 13 and the weft yarn 14 to weave the fiber structure 161. Therefore, as compared with the case where the auxiliary thread 15 is added to only one of the warp thread 13 and the weft thread 14, the surplus portion that does not contribute to the path generated in the first warp thread 121 and the second warp thread 122 becomes longer. Therefore, when the fiber structure 161 is shaped, the outer surface 11a of the fiber structure 161 becomes more elongated along the first direction X1, so that the occurrence of wrinkles inside the bending of the fiber structure 161 can be further suppressed. ..
  • a thread composed of fibers other than carbon fibers may be adopted as the first thread 13a or the second thread 14a.
  • fibers other than carbon fibers include glass fibers.
  • the auxiliary yarn 15 in the first embodiment in which the heating step is performed is composed of synthetic fibers other than nylon fibers as long as it has a melting point lower than that of the first yarn 13a and the second yarn 14a. May be good.
  • the auxiliary thread 15 in the second embodiment and the third embodiment in which the extraction process is performed may be composed of synthetic fibers other than nylon fibers, or may be composed of fibers other than synthetic fibers. There may be. Since the auxiliary thread 15 does not remain in the fiber structures 111 and 161 after shaping, the material of the auxiliary thread 15 can be freely selected.
  • the auxiliary thread 15 may be melted by heating in the heating step so that the auxiliary thread 15 disappears in the fiber structure 11 after the heating step. Further, in the first embodiment, the sampling step in the second embodiment and the third embodiment may be performed instead of the heating step.
  • the heating step in the first embodiment may be performed instead of the sampling step.
  • the auxiliary thread 15 since the auxiliary thread 15 is melted by the heating step, the auxiliary thread 15 may be eliminated in the fiber structures 111 and 161 after the heating step, and the thickness of the auxiliary thread 15 is smaller than that before the heating step. It may be.
  • the auxiliary arranged in the fiber structures 11, 111, 161 other than these steps instead of the heating step in the first embodiment and the sampling step in the second embodiment and the third embodiment, the auxiliary arranged in the fiber structures 11, 111, 161 other than these steps.
  • a reduction step of reducing the thickness of the thread 15 may be adopted.
  • the fiber structures 11, 111, 161 after the weaving step are put in a container filled with a chemical solution having a property of dissolving the auxiliary thread 15 by causing a chemical reaction with the auxiliary thread 15.
  • the thread 15 may be melted.
  • the auxiliary yarn 15 is arranged in the inner layer in the stacking direction Y from these weft layers.
  • the weft layer may be provided as one layer or two or more layers.
  • the auxiliary yarn 15 constituting the first weft layer 41 becomes the first auxiliary yarn 15a
  • the auxiliary yarn 15 constituting the weft layer other than the first weft layer 41 becomes the second auxiliary yarn 15b.
  • the thickness of each of the second auxiliary threads 15b may be set to be smaller in the stacking direction Y toward the inner layer than the outer surface 11a.
  • the first weft layer 41 may be changed to one composed of the second thread 14a.
  • the auxiliary threads 15 are not arranged as the weft threads 14, but are arranged only as the warp threads 13.
  • auxiliary thread 15 bulky fibers having a lower fiber density than the first thread 13a and the second thread 14a may be adopted.
  • an auxiliary yarn 15 having a thickness similar to that of the first yarn 13a and the second yarn 14a and having a fiber density lower than that of the first yarn 13a and the second yarn 14a is adopted.
  • the thickness of the auxiliary thread 15 having a low fiber density is high. The amount of decrease is larger than that of the first thread 13a and the second thread 14a.
  • the first warp thread 21 and the second warp thread 22 have a surplus that does not contribute to the path by the amount that the thickness of the auxiliary thread 15 is reduced. Therefore, as in each of the above embodiments, the occurrence of wrinkles inside the bending of the fiber structures 11, 111, 161 can be suppressed.
  • the first direction X1 may be the direction in which the yarn spindle of the weft 14 extends
  • the second direction X2 may be the direction in which the yarn spindle of the warp 13 extends.
  • the first plane portion 16, the bent portion 18, and the second plane portion 17 are continuous along the direction in which the yarn spindle of the weft 14 extends.
  • the arrangement of the auxiliary threads 15 may be performed only in a partial range of the fiber structures 11, 111, 161 in the first direction X1.
  • the auxiliary threads 15 may be arranged in a range including a portion to be a bent portion 18, or a range excluding the bent portion 18.
  • the auxiliary thread 15 may be arranged in a range including one or both of the first flat surface portion 16 and the second flat surface portion 17.
  • the shape of the fiber structures 11, 111, 161 after shaping is not limited to the L shape.
  • the shaping of the fiber structures 11, 111, 161 may be performed so that the radius of curvature of the bent portion 18 is larger than that shown in FIG. 1, or the radius of curvature of the bent portion 18 is larger than that shown in FIG. May be reduced.
  • X1 1st direction X2 2nd direction Y Laminating direction 10a Multilayer woven fabric 11,111,161 Fiber structure 11a Outer side surface 13 Warp thread 13a 1st thread 14 Weft thread 14a 2nd thread 15 Auxiliary thread 15a 1st auxiliary thread 15b 2nd auxiliary thread 16 1st flat part 17 2nd flat part 18 Bending part 21,121 1st warp 22,122 2nd warp 23,123 3rd warp 24,124 4th warp 115a Weft auxiliary thread 115b Warp auxiliary thread

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Woven Fabrics (AREA)

Abstract

L'invention concerne une structure de fibres (11) comprenant des premiers fils (13a) constitués de fibres de renforcement en tant que fils de chaîne (13) et comprenant également des seconds fils (14a) constitués de fibres de renforcement en tant que fils de trame (14). Des premiers fils de chaîne (21) et des seconds fils de chaîne (22) sont disposés sur une surface externe (11a) sur le côté externe à courbure de la structure de fibres (11). Les premiers fils de chaîne (21) et les seconds fils de chaîne (22) sont en prise avec les seconds fils (14a). La structure de fibres (11) comprend des fils auxiliaires (15) qui sont situés dans une couche interne par rapport aux premiers fils de chaîne (21) et aux seconds fils de chaîne (22) dans une direction de stratification Y et qui sont agencés de façon à chevaucher les premiers fils de chaîne (21) et les seconds fils de chaîne (22) dans la direction de stratification Y. Les fils auxiliaires (15) ont la propriété selon laquelle la quantité de réduction d'épaisseur est plus grande que celle des premiers fils (13a) et des seconds fils (14a).
PCT/JP2020/025424 2019-07-11 2020-06-29 Structure de fibres et procédé de fabrication de structure de fibres WO2021006081A1 (fr)

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JPH02191742A (ja) * 1989-01-18 1990-07-27 Toyota Autom Loom Works Ltd 三次元織物及びその製造方法
JP2007291582A (ja) * 2006-03-31 2007-11-08 Toyota Industries Corp 三次元繊維構造体及び複合材並びに三次元繊維構造体の製造方法
JP2007297753A (ja) * 2006-04-03 2007-11-15 Toyota Industries Corp 三次元繊維構造体の製造方法
JP2013133555A (ja) * 2011-12-26 2013-07-08 Toyota Industries Corp 織物基材及び繊維強化複合材料
JP2015501890A (ja) * 2011-12-14 2015-01-19 スネクマ ３ｄ製織繊維構造、そのような繊維構造から得られた繊維プリフォーム、およびそのようなプリフォームを含む複合材料部品
JP2018178299A (ja) * 2017-04-11 2018-11-15 株式会社豊田自動織機 繊維構造体、及び繊維強化複合材の製造方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02191742A (ja) * 1989-01-18 1990-07-27 Toyota Autom Loom Works Ltd 三次元織物及びその製造方法
JP2007291582A (ja) * 2006-03-31 2007-11-08 Toyota Industries Corp 三次元繊維構造体及び複合材並びに三次元繊維構造体の製造方法
JP2007297753A (ja) * 2006-04-03 2007-11-15 Toyota Industries Corp 三次元繊維構造体の製造方法
JP2015501890A (ja) * 2011-12-14 2015-01-19 スネクマ ３ｄ製織繊維構造、そのような繊維構造から得られた繊維プリフォーム、およびそのようなプリフォームを含む複合材料部品
JP2013133555A (ja) * 2011-12-26 2013-07-08 Toyota Industries Corp 織物基材及び繊維強化複合材料
JP2018178299A (ja) * 2017-04-11 2018-11-15 株式会社豊田自動織機 繊維構造体、及び繊維強化複合材の製造方法

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