WO2020090145A1 - 炭酸リチウムの製造装置 - Google Patents
炭酸リチウムの製造装置 Download PDFInfo
- Publication number
- WO2020090145A1 WO2020090145A1 PCT/JP2019/022920 JP2019022920W WO2020090145A1 WO 2020090145 A1 WO2020090145 A1 WO 2020090145A1 JP 2019022920 W JP2019022920 W JP 2019022920W WO 2020090145 A1 WO2020090145 A1 WO 2020090145A1
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- WIPO (PCT)
- Prior art keywords
- lithium hydroxide
- reaction tank
- aqueous solution
- carbon dioxide
- hydroxide aqueous
- Prior art date
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2455—Stationary reactors without moving elements inside provoking a loop type movement of the reactants
- B01J19/2465—Stationary reactors without moving elements inside provoking a loop type movement of the reactants externally, i.e. the mixture leaving the vessel and subsequently re-entering it
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
- B01J10/002—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor carried out in foam, aerosol or bubbles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J4/00—Feed or outlet devices; Feed or outlet control devices
- B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
- B01J4/002—Nozzle-type elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/08—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D7/00—Carbonates of sodium, potassium or alkali metals in general
- C01D7/07—Preparation from the hydroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00177—Controlling or regulating processes controlling the pH
Definitions
- the present invention relates to a lithium carbonate production apparatus.
- a liquid to be treated in which lithium ions are dissolved in an aqueous solvent is stored in a reaction chamber, and carbon dioxide gas is blown into the liquid to be bubbled while the liquid after the bubbling on the liquid surface of the liquid to be treated is bubbled.
- An apparatus for producing lithium carbonate is known in which a gas-filled layer filled with carbon dioxide gas for reaction is formed, and the treatment liquid in the reaction chamber is pumped up and sprayed onto the gas-filled layer (see, for example, Patent Document 1). ..
- lithium ions contained in the liquid to be treated react with carbon dioxide gas to form lithium carbonate.
- the carbon dioxide gas that has not reacted with the lithium ions due to the bubbling forms a gas-filled layer on the liquid surface of the liquid to be treated, and sprays the treatment liquid pumped from the reaction chamber onto the gas-filled layer. By doing so, it reacts with lithium ions contained in the liquid to be treated to further form lithium carbonate.
- the manufacturing apparatus it is possible to efficiently manufacture lithium carbonate without wasting the carbon dioxide gas that has not reacted with the lithium ions due to the bubbling.
- the present invention eliminates such inconvenience, can supply carbon dioxide without requiring a large pressure, and has a simple structure and can efficiently produce lithium carbonate from the supplied carbon dioxide. It is an object of the present invention to provide an apparatus for producing lithium.
- the apparatus for producing lithium carbonate of the present invention comprises a sealed reaction tank for storing the lithium hydroxide aqueous solution, and a lithium hydroxide aqueous solution supply means for supplying the lithium hydroxide aqueous solution to the reaction tank.
- a carbon dioxide gas supplying means for supplying carbon dioxide gas to a space above the liquid surface of the aqueous lithium hydroxide solution in the reaction tank, and circulating the aqueous lithium hydroxide solution stored in the reaction tank through the reaction tank, The lithium hydroxide stored in the reaction tank by being dropped into the lithium hydroxide aqueous solution from above the liquid surface of the lithium hydroxide aqueous solution in the reaction tank and entraining carbon dioxide gas in the reaction tank into the flow.
- Lithium hydroxide aqueous solution circulation means for introducing into an aqueous solution and reacting with the lithium hydroxide aqueous solution to generate lithium carbonate, and a base end provided at the tip of the lithium hydroxide aqueous solution circulation means. Characterized in that it comprises a nozzle which is reduced in diameter gradually toward the tip side from.
- the lithium hydroxide aqueous solution supply means supplies a predetermined amount of lithium hydroxide aqueous solution to the reaction tank.
- carbon dioxide gas is supplied to the reaction tank by a carbon dioxide gas supply means for supplying carbon dioxide gas to the reaction tank.
- the carbon dioxide gas supply means supplies the carbon dioxide gas to the space above the liquid level of the lithium hydroxide aqueous solution in the reaction tank, the carbon dioxide gas is supplied and bubbled in the lithium hydroxide aqueous solution.
- carbon dioxide gas can be supplied at a lower pressure.
- the lithium hydroxide aqueous solution circulating means circulates the lithium hydroxide aqueous solution stored in the reaction tank into the reaction tank, and the lithium hydroxide aqueous solution is stored in the reaction tank. It is dropped from above the liquid surface into the aqueous lithium hydroxide solution.
- the tip of the lithium hydroxide aqueous solution circulating means is provided with a nozzle whose diameter is gradually reduced from the base end side to the tip side, the hydroxide solution circulated by the lithium hydroxide aqueous solution circulating means is circulated.
- the aqueous lithium solution is vigorously discharged from the nozzle and falls into the aqueous lithium hydroxide solution stored in the reaction tank.
- the lithium hydroxide aqueous solution discharged from the nozzle is introduced into the lithium hydroxide aqueous solution stored in the reaction tank by entraining the carbon dioxide gas in the reaction tank by its force.
- carbon dioxide gas By reacting carbon dioxide gas with lithium hydroxide, lithium carbonate can be efficiently produced.
- the reaction tank is sealed, the supplied carbon dioxide gas is not wasted, and the lithium hydroxide aqueous solution discharged from the nozzle is stored in the reaction tank. Since the lithium hydroxide aqueous solution is stirred, a stirring device is not required, and lithium carbonate can be efficiently manufactured with a simple structure.
- the reaction tank includes pressure detection means for detecting the pressure of carbon dioxide gas stored in the reaction tank, and the carbon dioxide gas supply means detects carbon dioxide detected by the pressure detection means.
- An on-off valve that opens and closes according to the gas pressure is preferably provided.
- the reaction tank since the reaction tank is sealed, when the reaction tank is equipped with the pressure detection means and the carbon dioxide gas supply means is provided with the opening / closing valve, the carbon dioxide gas in the reaction tank is oxidized. When consumed by the reaction with lithium, the decrease in the pressure is detected by the pressure detecting means, and the on-off valve is opened / closed according to the detected pressure. Therefore, the pressure of carbon dioxide gas in the reaction tank can be maintained within a predetermined range, and lithium carbonate can be produced more efficiently.
- the opening / closing valve for example, an electromagnetic valve can be used.
- the reaction tank is equipped with a pH detection means for detecting the pH of the lithium hydroxide aqueous solution stored in the reaction tank.
- the lithium hydroxide aqueous solution is a strong alkali and has a high pH value, but the pH gradually decreases as lithium carbonate is produced. Therefore, the reaction tank is provided with the pH detecting means, and the pH of the lithium hydroxide aqueous solution is detected by the pH detecting means, whereby the end time of the reaction can be easily known.
- a lithium carbonate production apparatus 1 includes a sealed reaction tank 2 that stores a lithium hydroxide aqueous solution A, and lithium hydroxide that supplies the lithium hydroxide aqueous solution A to the reaction tank 2.
- An aqueous solution supply means 3 and a carbon dioxide gas supply means 4 for supplying carbon dioxide gas to the reaction tank 2 are provided.
- the lithium hydroxide aqueous solution supply means 3 is obtained by a dissolution tank 31 for dissolving lithium recovered from a used lithium ion secondary battery or the like in ion-exchanged water to prepare a lithium hydroxide aqueous solution A, and a dissolution tank 31. And a supply conduit 32 for supplying the lithium hydroxide aqueous solution A to the reaction tank 2.
- the dissolution tank 31 is equipped with a stirring blade 34 that is rotationally driven by a motor 33 to stir lithium and ion-exchanged water.
- a first pump 35, a filter press 36, a filtrate tank 37, a second pump 38, and a microfiltration device 39 are provided in the supply conduit 32 in this order from the dissolution tank 31 side.
- the carbon dioxide gas supply means 4 includes a carbon dioxide gas cylinder 41 as a carbon dioxide gas supply source, and a carbon dioxide gas conduit 42 for supplying carbon dioxide gas from the carbon dioxide gas cylinder 41 to the reaction tank 2.
- a regulator 43, a sulfuric acid tank 44, a pure water tank 45, and a solenoid valve 46 are provided in the middle of the carbon dioxide gas pipe 42 in this order from the carbon dioxide gas cylinder 41 side.
- the reaction tank 2 includes a circulation conduit 21 provided outside as a lithium hydroxide aqueous solution circulation means, and a circulation pump 22 provided in the middle of the circulation conduit 21.
- One end of the circulation conduit 21 is connected to the bottom of the reaction tank 2, while the other end is inserted from the top surface of the reaction tank 2 into the reaction tank 2 and stored in the reaction tank 2. It opens above the liquid surface of the lithium hydroxide aqueous solution A.
- the circulation conduit 21 is provided with a nozzle (not shown) at the end opening above the liquid surface of the lithium hydroxide aqueous solution A, and the diameter of the nozzle gradually decreases from the base end side to the tip end side.
- an end portion of the supply conduit 32 and an end portion of the carbon dioxide gas conduit 42 are inserted into the top surface of the reaction tank 2, and both of the lithium hydroxide aqueous solution A stored in the reaction tank 2 are stored in the reaction tank 2. It opens above the liquid surface.
- the reaction tank 2 has an atmosphere release valve (not shown) that releases the gas in the reaction tank 2 to the atmosphere, and a pressure as a pressure detection unit that detects the pressure of carbon dioxide gas stored in the reaction tank 2.
- a sensor (not shown) and a pH meter (not shown) as pH detecting means for detecting the pH of the lithium hydroxide aqueous solution A stored in the reaction tank 2 are provided.
- the lithium hydroxide aqueous solution A taken out from the dissolution tank 31 is supplied to the reaction tank 2 through the supply conduit 32. At this time, the lithium hydroxide aqueous solution A can be easily supplied by opening the atmosphere opening valve in the reaction tank 2.
- the carbon dioxide gas supplied from the carbon dioxide gas cylinder 41 is supplied to the space above the liquid level of the lithium hydroxide aqueous solution A in the reaction tank 2 through the carbon dioxide gas conduit 42.
- the atmosphere release valve the air stored in the space is replaced with carbon dioxide gas supplied from the carbon dioxide gas conduit 42, and the space is filled with carbon dioxide gas.
- the circulation pump 22 is operated to react the lithium hydroxide aqueous solution A stored in the reaction tank 2 with the circulation conduit 21. It is circulated in the tank 2 and dropped into the lithium hydroxide aqueous solution A from above the liquid surface of the lithium hydroxide aqueous solution A.
- a nozzle (not shown) is provided at the end of the circulation conduit 21 that opens above the liquid surface of the lithium hydroxide aqueous solution A, the lithium hydroxide aqueous solution A circulated by the circulation conduit 21 is discharged from the nozzle. It is discharged, becomes a rod-shaped flow, and vigorously falls into the lithium hydroxide aqueous solution A stored in the reaction tank 2.
- the carbon dioxide gas filled in the reaction tank 2 is entrained in the rod-shaped flow of the lithium hydroxide aqueous solution A and introduced into the lithium hydroxide aqueous solution A stored in the reaction tank 2 so as to be hydroxylated.
- lithium hydroxide aqueous solution A stored in the reaction tank 2 is agitated by the rod-shaped flow falling from above, it is possible to efficiently produce lithium carbonate without using a stirrer or the like.
- the electromagnetic valve 46 provided in the carbon dioxide gas conduit 42 is opened and closed according to the pressure of the carbon dioxide gas detected by the pressure sensor.
- the electromagnetic valve 46 is opened, and the carbon dioxide gas supplied from the carbon dioxide gas conduit 42 is used to set a predetermined value.
- the solenoid valve 46 is closed.
- the lithium hydroxide in the aqueous lithium hydroxide solution A stored in the reaction tank 2 is consumed as the lithium carbonate is produced.
- the lithium hydroxide aqueous solution A is a strong alkali and has a high pH value, but when lithium hydroxide is consumed as lithium carbonate is produced, the pH gradually decreases. Therefore, it is possible to easily know the end time of the reaction by detecting that the pH of the lithium hydroxide aqueous solution A has reached the predetermined lower limit value with the pH meter.
- Lithium carbonate production device 2 ... Reaction tank, 3 ... Lithium hydroxide aqueous solution supply means, 4 ... Carbon dioxide gas supply means, 21 ... Lithium hydroxide aqueous solution circulation means.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Treating Waste Gases (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
Description
Claims (3)
- 水酸化リチウム水溶液を貯留する密閉された反応槽と、
該反応槽に該水酸化リチウム水溶液を供給する水酸化リチウム水溶液供給手段と、
該反応槽の該水酸化リチウム水溶液の液面の上方空間に炭酸ガスを供給する炭酸ガス供給手段と、
該反応槽に貯留されている該水酸化リチウム水溶液を該反応槽に循環させ、該反応槽内で該水酸化リチウム水溶液の液面の上方から該水酸化リチウム水溶液中に落下させ、該反応槽内の炭酸ガスを流れに巻き込んで該反応槽に貯留されている該水酸化リチウム水溶液中に導入し、該水酸化リチウム水溶液と反応させ、炭酸リチウムを生成させる水酸化リチウム水溶液循環手段と、
該水酸化リチウム水溶液循環手段の先端に設けられ基端側から先端側に向かって次第に縮径されたノズルとを備えることを特徴とする炭酸リチウム製造装置。 - 請求項1記載の炭酸リチウム製造装置において、前記反応槽は該反応槽内に貯留されている炭酸ガスの圧力を検知する圧力検知手段を備え、前記炭酸ガス供給手段は該圧力検知手段により検知される炭酸ガスの圧力に応じて開閉する開閉弁を備えることを特徴とする炭酸リチウム製造装置。
- 請求項1又は請求項2記載の炭酸リチウム製造装置において、前記反応槽は該反応槽内に貯留されている水酸化リチウム水溶液のpHを検知するpH検知手段を備えることを特徴とする炭酸リチウム製造装置。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201980035399.8A CN112236396A (zh) | 2018-10-29 | 2019-06-10 | 碳酸锂的制造装置 |
KR1020207033621A KR102425500B1 (ko) | 2018-10-29 | 2019-06-10 | 탄산리튬의 제조 장치 |
EP19880408.0A EP3875432A4 (en) | 2018-10-29 | 2019-06-10 | DEVICE FOR PRODUCTION OF LITHIUM CARBONATE |
US17/057,851 US11117114B2 (en) | 2018-10-29 | 2019-06-10 | Lithium carbonate production device |
CA3101466A CA3101466C (en) | 2018-10-29 | 2019-06-10 | Lithium carbonate production device |
Applications Claiming Priority (2)
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JP2018-202823 | 2018-10-29 | ||
JP2018202823A JP6533859B1 (ja) | 2018-10-29 | 2018-10-29 | 炭酸リチウムの製造装置 |
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PCT/JP2019/022920 WO2020090145A1 (ja) | 2018-10-29 | 2019-06-10 | 炭酸リチウムの製造装置 |
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US (1) | US11117114B2 (ja) |
EP (1) | EP3875432A4 (ja) |
JP (1) | JP6533859B1 (ja) |
KR (1) | KR102425500B1 (ja) |
CN (1) | CN112236396A (ja) |
CA (1) | CA3101466C (ja) |
CL (1) | CL2020003029A1 (ja) |
WO (1) | WO2020090145A1 (ja) |
Families Citing this family (2)
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KR102302077B1 (ko) * | 2019-11-26 | 2021-09-13 | 주식회사 포스코 | 탄산리튬 제조 시스템 |
EP4178913A1 (en) * | 2021-04-01 | 2023-05-17 | Li-Technology Pty Ltd. | Lithium carbonate recovery process |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH08217438A (ja) * | 1995-02-13 | 1996-08-27 | Nippon Chem Ind Co Ltd | 炭酸リチウムの製造方法 |
JPH11310414A (ja) * | 1998-04-27 | 1999-11-09 | Mitsui Chem Inc | 高純度炭酸リチウムの製造法 |
JP4333234B2 (ja) | 2003-07-02 | 2009-09-16 | トヨタ自動車株式会社 | リチウム塩の製造方法および製造装置 |
JP2012091999A (ja) * | 2010-09-27 | 2012-05-17 | Jx Nippon Mining & Metals Corp | 炭酸リチウムの精製方法 |
JP2015515440A (ja) * | 2012-04-05 | 2015-05-28 | ポスコ | 水酸化リチウムの製造方法およびこれを用いた炭酸リチウムの製造方法 |
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CN1819868B (zh) * | 2003-02-13 | 2013-10-09 | 深川胜之 | 气体溶解量调整方法和其装置及其系统 |
JP4442129B2 (ja) * | 2003-07-02 | 2010-03-31 | トヨタ自動車株式会社 | リチウム電池、その製造方法ならびに処理方法 |
JP5457627B2 (ja) * | 2007-09-20 | 2014-04-02 | 株式会社クレハ環境 | 反応ノズル、気相加水分解処理装置および気相加水分解処理方法 |
US8741256B1 (en) * | 2009-04-24 | 2014-06-03 | Simbol Inc. | Preparation of lithium carbonate from lithium chloride containing brines |
ES2750527T3 (es) * | 2010-02-17 | 2020-03-26 | All American Lithium LLC | Procedimientos de preparación de carbonato de litio altamente puro y de otros compuestos que contienen litio altamente puro |
KR101395796B1 (ko) * | 2012-01-06 | 2014-05-19 | 주식회사 포스코 | 탄산화 장치 및 이를 이용한 탄산화 방법 |
JP5386002B2 (ja) * | 2012-04-02 | 2014-01-15 | パナソニック株式会社 | 気体溶解装置 |
CA2996154C (en) * | 2013-10-23 | 2023-02-07 | Nemaska Lithium Inc. | Process for preparing lithium hydroxide via two electrochemical cells |
KR101746038B1 (ko) * | 2015-12-17 | 2017-06-13 | 재단법인 포항산업과학연구원 | 탄산염 제조장치 |
CN106906359B (zh) * | 2015-12-22 | 2018-12-11 | 理查德.亨威克 | 从硅酸盐矿物收取锂 |
WO2017213273A1 (ko) * | 2016-06-07 | 2017-12-14 | 재단법인 포항산업과학연구원 | 탄산염 제조 방법 및 장치 |
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2018
- 2018-10-29 JP JP2018202823A patent/JP6533859B1/ja active Active
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2019
- 2019-06-10 CN CN201980035399.8A patent/CN112236396A/zh active Pending
- 2019-06-10 KR KR1020207033621A patent/KR102425500B1/ko active IP Right Grant
- 2019-06-10 WO PCT/JP2019/022920 patent/WO2020090145A1/ja unknown
- 2019-06-10 CA CA3101466A patent/CA3101466C/en active Active
- 2019-06-10 US US17/057,851 patent/US11117114B2/en active Active
- 2019-06-10 EP EP19880408.0A patent/EP3875432A4/en active Pending
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2020
- 2020-11-23 CL CL2020003029A patent/CL2020003029A1/es unknown
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JPH08217438A (ja) * | 1995-02-13 | 1996-08-27 | Nippon Chem Ind Co Ltd | 炭酸リチウムの製造方法 |
JPH11310414A (ja) * | 1998-04-27 | 1999-11-09 | Mitsui Chem Inc | 高純度炭酸リチウムの製造法 |
JP4333234B2 (ja) | 2003-07-02 | 2009-09-16 | トヨタ自動車株式会社 | リチウム塩の製造方法および製造装置 |
JP2012091999A (ja) * | 2010-09-27 | 2012-05-17 | Jx Nippon Mining & Metals Corp | 炭酸リチウムの精製方法 |
JP2015515440A (ja) * | 2012-04-05 | 2015-05-28 | ポスコ | 水酸化リチウムの製造方法およびこれを用いた炭酸リチウムの製造方法 |
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Title |
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See also references of EP3875432A4 |
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CA3101466C (en) | 2023-01-17 |
JP2020070198A (ja) | 2020-05-07 |
US11117114B2 (en) | 2021-09-14 |
CL2020003029A1 (es) | 2021-05-07 |
EP3875432A1 (en) | 2021-09-08 |
KR20210003203A (ko) | 2021-01-11 |
EP3875432A4 (en) | 2022-07-27 |
US20210197169A1 (en) | 2021-07-01 |
CN112236396A (zh) | 2021-01-15 |
KR102425500B1 (ko) | 2022-07-27 |
JP6533859B1 (ja) | 2019-06-19 |
CA3101466A1 (en) | 2020-05-07 |
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