WO2020000591A1 - Tunnel kiln firing system for foamed ceramic lightweight board - Google Patents

Tunnel kiln firing system for foamed ceramic lightweight board Download PDF

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Publication number
WO2020000591A1
WO2020000591A1 PCT/CN2018/100134 CN2018100134W WO2020000591A1 WO 2020000591 A1 WO2020000591 A1 WO 2020000591A1 CN 2018100134 W CN2018100134 W CN 2018100134W WO 2020000591 A1 WO2020000591 A1 WO 2020000591A1
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unit
foamed ceramic
laying
tunnel kiln
board
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PCT/CN2018/100134
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French (fr)
Chinese (zh)
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林�智
欧阳慧
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广东科达洁能股份有限公司
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Publication of WO2020000591A1 publication Critical patent/WO2020000591A1/en

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B9/00Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
    • F27B9/02Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity of multiple-track type; of multiple-chamber type; Combinations of furnaces
    • F27B9/021Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity of multiple-track type; of multiple-chamber type; Combinations of furnaces having two or more parallel tracks
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/1305Organic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/131Inorganic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1321Waste slurries, e.g. harbour sludge, industrial muds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1324Recycled material, e.g. tile dust, stone waste, spent refractory material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/02Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C04B38/063Preparing or treating the raw materials individually or as batches
    • C04B38/0635Compounding ingredients
    • C04B38/0645Burnable, meltable, sublimable materials
    • C04B38/067Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74Physical characteristics
    • C04B2235/77Density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9607Thermal properties, e.g. thermal expansion coefficient
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Definitions

  • the invention relates to the technical field of ceramic plates, in particular to a tunnel kiln firing system for foamed ceramic light plates.
  • the matrix material used in foamed ceramics comes from wastes from ceramics factories and industrial wastes (such as ceramic tile polishing residues or coal residues or stone waste residues). If these wastes are left untreated, the random accumulation or landfill will cause pollution to the environment. Wasted resources.
  • the foamed ceramic products gradually began to be used nationwide due to its advantages such as light weight, high strength, fire resistance, earthquake resistance, heat insulation, sound insulation, strong combination, easy handling, and wide application. And because its raw materials are solid waste such as coal slag, ceramic tile polishing slag, slag, etc., it has positive social significance in making full use of resources and environmental protection.
  • the existing formula system of foamed ceramics generally includes tile polishing waste residue and foaming agent, and the amount of tile polishing waste residue is relatively small, mostly about 50%.
  • the amount of foaming agent added is about 1.2%, the amount of foaming agent is large, and the cost is high. Because the existing foamed bricks are relatively thick, the formula system is relatively difficult to oxidize.
  • the formula system of foamed ceramics determines that they must be fired in a tunnel kiln.
  • the firing cycle of a tunnel kiln is generally 24-26 hours, and the firing cycle is long. Higher temperature.
  • the foamed ceramic plate produced in the prior art has multiple layers of air holes formed therein.
  • the lower air pores will be flattened, making the overall uniformity of the product poor.
  • the existing tunnel kiln burning in Chengdu is a single-layer stack burning, which is basically manual operation, requires a lot of manpower, has low efficiency and high cost.
  • the technical problem to be solved by the present invention is to provide a tunnel kiln firing system for foamed ceramic lightweight plates, which realizes multi-layer firing, has high degree of automation, high production efficiency, and saves cost and space.
  • the technical problem to be solved by the present invention is also to provide a tunnel kiln firing system for foamed ceramic lightweight plates to achieve fast firing at low temperature.
  • the foamed ceramic lightweight plates obtained by firing are on the same section, from top to bottom. There is no difference in lower stomata, and the uniformity of air bubbles is high.
  • the present invention provides a tunnel kiln firing system of foamed ceramic light board, including: a feeding line for distributing raw materials on a kiln car; a tunnel kiln for expanding foam The ceramic body is fired; the cutting line is used to unload the foamed ceramic light board;
  • the kiln car includes a bracket, and a box bowl is provided on the bracket.
  • the box bowl includes a cushion plate, a surrounding plate, and a high-temperature resistant paper.
  • the board is provided with the high temperature resistant paper;
  • the loading line includes:
  • a first laying unit for laying a heat-resistant paper on a mat
  • Conveying unit for conveying the kiln car after distribution to the tunnel kiln.
  • the blanking line includes:
  • a second unloading unit for unloading foamed ceramic lightweight panels for unloading foamed ceramic lightweight panels.
  • the first laying unit includes a bottom-laying paper machine
  • the surrounding board laying unit includes a robot
  • the second laying unit includes a side-laying paper machine
  • the first laying unit, the erection unit and the second laying unit are connected in sequence;
  • the surrounding board erection unit is provided corresponding to the first unloading unit, and the robot hand transfers the surrounding board unloaded by the first unloading unit to the surrounding board erection unit.
  • the first laying unit, the erection unit and the second laying unit are further provided with a finishing machine, the finishing machine includes a lifting robot arm and a snapping member, and the snapping member is opposite to the pad The boards and boards are aligned.
  • the cleaning unit is a cleaning machine
  • the cleaning machine includes a brush, a driving mechanism, and a vacuum cleaning system
  • the driving mechanism drives the brush to roll.
  • the pad is a mullite pad, a silicon carbide pad or a cordierite pad;
  • the enclosure is a mullite enclosure, a silicon carbide enclosure or a cordierite enclosure;
  • the high temperature resistant paper is aluminum silicate fiber paper.
  • the bracket is provided with at least three layers of box bowls, and the green body in the box bowl is multi-layered and fired in a tunnel kiln to form a foamed ceramic light board.
  • the foamed ceramic lightweight board is mainly made of the following weight percentages of raw materials:
  • Tile polishing residue is 70-96%, clay is 0-10%, feldspar is 0-20%, foaming agent is 0.01-0.6%, stabilizer is 0.1-4%.
  • the foamed ceramic lightweight board is mainly made of the following weight percentages of raw materials:
  • Tile polishing residue is 75-95%, clay is 0.1-10%, feldspar is 0.1-20%, foaming agent is 0.1-0.4%, and stabilizer is 0.1-3%.
  • the clay is one or more of black mud, kaolin, urban sludge, and sea mud;
  • the foaming agent is silicon carbide or a reclaimed polishing head.
  • the main components of the reclaimed polishing head include silicon carbide and a resin.
  • the tunnel kiln firing system of the foamed ceramic light board of the present invention comprises a feeding line, a tunnel kiln and a feeding line, wherein the feeding line is used for distributing raw materials on a kiln car to form a green body; The tunnel kiln is used for firing the green body to form a foamed ceramic light board; the cutting line is used for unloading the foamed ceramic light board. After the kiln car comes out of the kiln tail of the tunnel kiln, it enters the unloading line, first unloads the siding, then unloads the foamed ceramic light board, and the unloading line is finished.
  • the invention adopts the above production system, which can avoid single-layer stacking, realize multi-layer stacking, reduce manual labor, realize fully automated production, and greatly improve production efficiency.
  • the hoisting board erection unit of the loading line is set corresponding to the first unloading unit of the feeding line, and the robot moves the hoisting board unloaded by the first unloading unit to the hoisting plate erection unit to reduce the moving distance between loading and unloading. , Easy to operate, making the layout of the production line more reasonable, reducing production space.
  • the present invention adopts a tunnel kiln stacking method to achieve low-temperature fast firing, which greatly reduces the oxidation reaction stage time of the formula. Even if the firing cycle is shortened, the ceramic plate can be burned through, which increases the yield and reduces the unit product. Energy consumption.
  • the present invention adopts a multi-layer firing method, and the green body is not affected by multilayer superposition, and can also be burned through at low temperature and in a short time to ensure product quality, greatly improve production efficiency, and reduce the occupation of the tunnel kiln. Ground space.
  • the raw materials of the foamed ceramic light board include 70-96% of tile polishing waste, 0.01-0.6% of foaming agent, and 0.1-4% of stabilizer, which increases the amount of tile polishing waste added.
  • the maximum amount can be up to 96%, and the amount of foaming agent can be reduced to 0.01-0.6%.
  • the addition of 0.1-4% manganese dioxide stabilizer can improve the uniformity of air bubbles. Even in the same section, there is no difference in the pores from top to bottom, which makes the overall uniformity of the product good.
  • the foamed ceramic light board made by the above-mentioned fire-stacking system and fire-stacking method has excellent quality, compressive strength ⁇ 4.5Mpa, bulk density: 200-1100Kg / m 3 , thermal conductivity: ⁇ 0.15W / m °C, Burning level: A1 level, water absorption: ⁇ 2%, radioactivity index: I Ra ⁇ 1.0, I r ⁇ 1.0.
  • FIG. 1 is a cross-sectional view of a prior art foamed ceramic lightweight board
  • FIG. 2 is a schematic view of a tunnel kiln firing system of the foamed ceramic light board of the present invention
  • Figure 3 is a front view of a kiln car of the present invention.
  • Figure 4 is a left side view of the kiln car of the present invention.
  • Fig. 5 is a plan view of a kiln car according to the present invention.
  • the present invention provides a tunnel kiln firing system for a foamed ceramic light board, including: a feeding line 1 for distributing raw materials on a kiln car 4; a tunnel kiln 2 for foaming The ceramic body is fired; the cutting line 3 is used for unloading the foamed ceramic light board.
  • the kiln car 4 includes a bracket 41 provided with a box bowl 42 including a shim plate 43, a surrounding plate 44 and a high temperature resistant paper 45.
  • a box bowl 42 including a shim plate 43, a surrounding plate 44 and a high temperature resistant paper 45.
  • the high temperature resistant paper 45 is provided on the shim plate 43 and the surrounding plate 44.
  • the bracket 41 is provided with at least three layers of box bowls 42, and the green body in the box bowl 42 is multi-layered and fired in the tunnel kiln 2 to form a foamed ceramic light board.
  • the invention adopts the multi-layer firing method of the tunnel kiln to realize low-temperature fast firing, which greatly reduces the oxidation reaction stage time of the formula. Even if the firing cycle is shortened, the ceramic plate can be burned through, the yield is increased, and the energy per unit product is reduced Consuming.
  • the present invention adopts a multi-layer firing method, and the green body is not affected by multilayer superposition, and can also be burned through at low temperature and in a short time to ensure product quality, greatly improve production efficiency, and reduce the occupation of the tunnel kiln. Ground space.
  • the number of layers of the box bowl 42 of the kiln car can be set according to the actual situation, for example, 4, 5, 6, 7, 8, 9, and 10 layers, and its implementation is not limited to the invention. Give examples.
  • the backing plate 43 is preferably a mullite backing plate, a silicon carbide backing plate or a cordierite backing plate, and has the advantages of small thermal expansion coefficient, good thermal shock stability, not being easily deformed and cracked, and long service life.
  • the enclosure 44 is preferably a mullite enclosure, a silicon carbide enclosure or a cordierite enclosure, which has the advantages of small thermal expansion coefficient, good thermal shock stability, not being easily deformed and cracked, and long service life.
  • the high temperature resistant paper 45 refers to a paper that can withstand a high temperature of 1220 ° C, preferably an aluminum silicate fiber paper.
  • the aluminum silicate fiber paper is made of gold stone aluminum silicate ceramic fiber cotton as a main raw material by a wet forming process. It has ideal heat insulation, heat preservation, sealing, electrical insulation, sound absorption, and filtering performance in the environment. It has low thermal capacity, low thermal conductivity, excellent electrical insulation properties, excellent machining performance, high strength, tear resistance and high flexibility.
  • the feeding line 1 includes:
  • a first laying unit 12 for laying a heat-resistant paper on a mat
  • a shroud erection unit 13 for laying a shroud on the pad
  • a second laying unit 14 for laying a heat-resistant paper on the surrounding board
  • the conveying unit 16 for conveying the kiln car after the distribution to the tunnel kiln.
  • the blanking line 3 includes:
  • the cleaning unit 11 is a cleaning machine, which includes a brush, a driving mechanism, and a vacuum cleaning system, and the driving mechanism drives the brush to roll.
  • the invention cleans and collects the surface of the backing plate and the surrounding plate by using a rolling brush and a vacuum cleaning system.
  • the first laying unit 12 includes a bottom paper machine
  • the surrounding board erection unit 13 includes a manipulator 17
  • the second laying unit 14 includes a side paper machine
  • the first laying unit 12 and the surrounding board The erection unit 13 and the second laying unit 14 are sequentially connected, and the processing of laying high-temperature-resistant paper on the backing board, the upper surrounding board, and laying the high-temperature-resistant paper on the surrounding board are sequentially performed.
  • the shroud erection unit 13 is provided corresponding to the first unloading unit 31, and the manipulator 17 moves the shroud slab of the first unloading unit 31 to the corresponding layer of the shroud erection unit 13, reducing the interval between loading and unloading.
  • the moving distance and convenient operation make the layout of the production line more reasonable and reduce the production space.
  • the first laying unit 12, the shroud erection unit 13, and the second laying unit 14 are further provided with a finishing machine, which includes a lifting robot arm and a snapping component, and the snapping component is pressed against the pad and the surrounding plate.
  • a finishing machine which includes a lifting robot arm and a snapping component, and the snapping component is pressed against the pad and the surrounding plate.
  • Dimensioning cylinders are set around the external dimensions.
  • the cleaning machine selected by the cleaning unit 11 of the present invention a commercially available cleaning machine can be selected; and the system selected by the first laying unit 12 is a bottom paper machine and the side laying paper machine by the second laying unit 14 is selected here. , Choose a commercially available paper machine.
  • the covered kiln car is fired in the tunnel kiln 2 to obtain a foamed ceramic lightweight board finished product after firing.
  • the kiln car comes out of the kiln tail of the tunnel kiln 2 and enters the unloading line 3.
  • the first unloading unit 31 is used to unload the enclosure board, and then the second unloading unit 32 is used to unload the foamed ceramic light board. Operation is complete.
  • the foamed ceramic lightweight board is mainly made of the following weight percentages of raw materials: tile polishing residue 70-96%, clay 0-10%, feldspar 0-20%, foaming agent 0.01-0.6%, Stabilizer 0.1-4%.
  • the foamed ceramic light board is mainly made of the following weight percentages of raw materials: 75-95% of tile polishing waste, 0.1-10% of clay, 0.1-20% of feldspar, and 0.1-0.4% of foaming agent. Stabilizer 0.1-3%.
  • the invention increases the amount of tile polishing waste residue and reduces the amount of foaming agent.
  • the addition of 0.1-4% manganese dioxide stabilizer can improve the uniformity of air bubbles. Even in the same section, there is no difference in the pores from top to bottom, which makes the overall uniformity of the product good.
  • the pores in the entire cross section of the foamed ceramic light board are round holes, and the pore sizes from top to bottom are basically the same, and the uniformity of the pores after firing is good.
  • Manganese dioxide is an amphoteric oxide, which is a very stable black powdery solid at room temperature. It appears oxidizing when it encounters a reducing agent, and it appears reducing when it encounters a strong oxidant.
  • the prior art generally uses manganese dioxide as an oxidant or catalyst.
  • manganese dioxide is used as a bubble stabilizer. After reacting with the formula, manganese dioxide can make the walls of the stomata firm, and at the same time, make the formula more homogeneous, even in the same section, from top to bottom. There is no difference in the pores, which prevents the pores from being squashed, improves the uniformity of the bubbles, and the overall uniformity of the product is good.
  • the foaming agent is silicon carbide or a reclaimed polishing head.
  • the main components of the reclaimed polishing head include silicon carbide and a resin.
  • Silicon carbide is a foaming material.The presence of this material makes it not shrink like ordinary ceramics during firing, but expands, thereby making the lightweight and high-strength ceramic plate for construction smaller than traditional ceramics in size and thickness. Plates are easier to make large and thick.
  • the polishing grinder recycling material is added as the base material because the components of the polishing grinder are silicon carbide and resin, and silicon carbide is the foaming agent added in the formulation of the invention, so the invention can reduce the amount of foaming agent added. To 0.01-0.6%, reduce the amount of foaming agent and reduce costs.
  • the introduction of 70-96% of tile polishing residue in the formula is not only conducive to environmental protection recycling, but also makes the foamed ceramic light board sintered with a solid honeycomb-like hole structure, which is green, environmentally friendly, lightweight, Convenient construction, lightening building load, etc.
  • the added amount of ceramic tile polishing waste of the present invention is much larger than the existing foamed ceramic plate, which reduces the cost and strengthens the recycling of solid waste.
  • the clay is one or more of black mud, kaolin, urban sludge, and sea mud.
  • the silicon, aluminum, potassium, and sodium component ratios in the base formulation can be adjusted to make the foamed brick wall harder and stronger, and further recycle the waste solids.
  • the present invention adopts a tunnel kiln multi-layer firing method, wherein the firing method includes:
  • T 1 The temperature is raised to T 1 , T 1 is 800-900 ° C., and the temperature is maintained at T 1 for 0-30 min. Among them, the temperature rising rate from 0 ° C. to 400 ° C. is 10-20 ° C./min, and from 400 ° C. to The heating rate of T 1 is 1-8 °C / min;
  • T 2 The temperature is raised to T 2 , T 2 is 1150-1220 ° C., and the temperature is maintained at the highest temperature for 0-60 min. Among them, the temperature rising rate from T 1 to T 2 is 1-8 ° C./min;
  • the firing method includes:
  • the temperature is increased to 800-900 ° C, and the temperature is maintained at 800-900 ° C for 0-30min.
  • the temperature increase rate from 0 ° C to 400 ° C is 15 ° C / min
  • the temperature increase rate from 400 ° C to 800 ° C is 5 °C / min;
  • the temperature is raised to 1150-1220 ° C, and the temperature is maintained at the highest temperature for 0-60min. Among them, the temperature increase rate from 800 ° C to 1150 ° C is 5 ° C / min;
  • the invention on the basis of solving the pores in the foamed ceramic light board, the invention also ensures that it has good compressive strength, good thermal insulation effect, good flame retardancy, and low radioactivity index.
  • the raw materials are mixed according to the ratio and ball milled to obtain powder;
  • the firing method is as follows: (a) The temperature is raised to 800 ° C. , And maintained at 800 ° C for 20min, in which, the temperature increase rate from 0 ° C to 400 ° C is 10 ° C / min, and the temperature increase rate from 400 ° C to 800 ° C is 3 ° C / min; (b) the temperature is increased to 1150 ° C, The temperature is maintained at the highest temperature for 40 minutes. Among them, the temperature increase rate from 800 ° C to 1150 ° C is 3 ° C / min. (C) Slow temperature decrease, the temperature decrease rate from 1150 ° C to 600 ° C is 3 ° C / min, from 600 ° C. The rate of temperature decrease to 50 °C is 1 °C / min;
  • the raw materials are mixed according to the ratio and ball milled to obtain powder;
  • the powder is distributed on the kiln car through the feeding line, and then the kiln car is pushed into the tunnel kiln for three-layer firing to obtain a foamed ceramic light board.
  • the firing method is as follows: (a) The temperature is raised to 820 ° C. , And maintained at 820 ° C for 15 minutes, in which the temperature increase rate from 0 ° C to 400 ° C is 15 ° C / min, and the temperature increase rate from 400 ° C to 820 ° C is 5 ° C / min; (b) the temperature is increased to 1170 ° C, The temperature is maintained at the highest temperature for 30 minutes.
  • the heating rate from 820 ° C to 1170 ° C is 4 ° C / min;
  • the cooling rate from 1170 ° C to 600 ° C is 4 ° C / min, from 600 ° C
  • the rate of cooling down to 50 °C is 2 °C / min;
  • the raw materials are mixed according to the ratio and ball milled to obtain powder;
  • the powder is distributed on the kiln car through the feeding line, and then the kiln car is pushed into the tunnel kiln for three-layer firing to obtain a foamed ceramic light board.
  • the firing method is as follows: (a) The temperature is raised to 830 ° C.
  • the temperature increase rate from 0 ° C to 400 ° C is 15 ° C / min, and the temperature increase rate from 400 ° C to 830 ° C is 5 ° C / min;
  • the temperature is increased to 1180 ° C, And the temperature is maintained at the highest temperature for 0-60min, among which, the temperature increase rate from 830 ° C to 1180 ° C is 5 ° C / min;
  • the cooling rate from 600 °C to 50 °C is 2 °C / min;
  • the powder is distributed on the kiln car through the feeding line, and then the kiln car is pushed into the tunnel kiln for three-layer firing to obtain a foamed ceramic light board.
  • the firing method is as follows: (a) The temperature is raised to 850 ° C.
  • the raw materials are mixed according to the ratio and ball milled to obtain powder;
  • the powder is distributed on the kiln car through the feeding line, and then the kiln car is pushed into the tunnel kiln for three-layer firing to obtain a foamed ceramic lightweight board.
  • the firing method is as follows: (a) The temperature is raised to 860 ° C. And keep it at 860 °C for 10min, among which, the temperature increasing rate from 0 °C to 400 °C is 17 °C / min, and the temperature increasing rate from 400 °C to 860 °C is 6 °C / min; (b) the temperature is increased to 1210 °C, The temperature is maintained at the highest temperature for 30 minutes.
  • the temperature rising rate from 860 ° C to 1210 ° C is 5 ° C / min;
  • the cooling rate from 1210 ° C to 600 ° C is 6 ° C / min, from 600 ° C.
  • the rate of cooling down to 50 °C is 2 °C / min;
  • the raw materials are mixed according to the ratio and ball milled to obtain powder;
  • the powder is distributed on the kiln car through the feeding line, and then the kiln car is pushed into the tunnel kiln for three-layer firing treatment to obtain a foamed ceramic lightweight plate.
  • the firing method is as follows: (a) The temperature is raised to 900 ° C.

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Abstract

Disclosed is a tunnel kiln firing system for a foamed ceramic lightweight board, comprising a kiln vehicle, a loading line, a tunnel kiln and an unloading line, wherein the kiln vehicle comprises a rack, and a sagger is arranged on the rack and comprises a subplate, an enclosure and high-temperature resistant paper, the enclosure being arranged at the periphery of the subplate, and the high-temperature resistant paper being respectively arranged on the subplate and the enclosure. The loading line comprises: a cleaning unit for cleaning the subplate and the enclosure, a first laying unit for laying the high-temperature-resistant paper on the subplate, an enclosure arrangement unit for arranging the enclosure on the subplate, a second laying unit for laying the high-temperature-resistant paper on the enclosure, a material distribution unit for distributing material on the sagger formed by the subplate, the enclosure and the high-temperature resistant paper, and a conveying unit for conveying the kiln vehicle after material distribution to the tunnel kiln.

Description

一种发泡陶瓷轻质板材的隧道窑烧成系统Tunnel kiln firing system of foamed ceramic light board 技术领域Technical field
本发明涉及陶瓷板技术领域,尤其涉及一种发泡陶瓷轻质板材的隧道窑烧成系统。The invention relates to the technical field of ceramic plates, in particular to a tunnel kiln firing system for foamed ceramic light plates.
背景技术Background technique
发泡陶瓷所使用的基体材料来自于陶瓷厂废料和工业废料等废弃物(瓷砖抛光废渣或煤渣或石材废渣等),这些废弃物如若不处理,随意堆积或者填埋将对环境造成污染,也浪费了资源。The matrix material used in foamed ceramics comes from wastes from ceramics factories and industrial wastes (such as ceramic tile polishing residues or coal residues or stone waste residues). If these wastes are left untreated, the random accumulation or landfill will cause pollution to the environment. Wasted resources.
该发泡陶瓷产品以其重量轻、强度高、防火、抗震、隔热、隔音、组合性强、易于搬运,适用面广等优点逐渐开始在全国范围内使用。又因其原料为煤渣、瓷砖抛光废渣、矿渣等固体废弃物,在资源充分利用和环境保护方面具有积极的社会意义。The foamed ceramic products gradually began to be used nationwide due to its advantages such as light weight, high strength, fire resistance, earthquake resistance, heat insulation, sound insulation, strong combination, easy handling, and wide application. And because its raw materials are solid waste such as coal slag, ceramic tile polishing slag, slag, etc., it has positive social significance in making full use of resources and environmental protection.
现有发泡陶瓷的配方体系一般包括瓷砖抛光废渣和发泡剂,瓷砖抛光废渣用量较少,大多为50%左右而已。发泡剂加入量在1.2%左右,加入量较多,成本较高。因为现有发泡砖整体砖块比较厚,配方体系比较难氧化,发泡陶瓷的配方体系决定其必须使用隧道窑烧成,隧道窑的烧成周期一般为24-26小时,烧成周期长,温度较高。The existing formula system of foamed ceramics generally includes tile polishing waste residue and foaming agent, and the amount of tile polishing waste residue is relatively small, mostly about 50%. The amount of foaming agent added is about 1.2%, the amount of foaming agent is large, and the cost is high. Because the existing foamed bricks are relatively thick, the formula system is relatively difficult to oxidize. The formula system of foamed ceramics determines that they must be fired in a tunnel kiln. The firing cycle of a tunnel kiln is generally 24-26 hours, and the firing cycle is long. Higher temperature.
而且,如图1所示,现有技术制得的发泡陶瓷板,其内部形成多层气孔。在发泡的过程中,由于发泡时间较长,且受到重力的影响,下层气孔会被压扁,使得产品的整体均匀性不好。Moreover, as shown in FIG. 1, the foamed ceramic plate produced in the prior art has multiple layers of air holes formed therein. During the foaming process, due to the longer foaming time and the influence of gravity, the lower air pores will be flattened, making the overall uniformity of the product poor.
此外,现有的隧道窑烧成都是单层堆烧,基本手动操作,需要大量的人力,效率低,成本高。In addition, the existing tunnel kiln burning in Chengdu is a single-layer stack burning, which is basically manual operation, requires a lot of manpower, has low efficiency and high cost.
发明内容Summary of the invention
本发明所要解决的技术问题在于,提供一种发泡陶瓷轻质板材的隧道窑烧成系统,实现多层叠烧,自动化程度高,生产效率高,节省成本和空间。The technical problem to be solved by the present invention is to provide a tunnel kiln firing system for foamed ceramic lightweight plates, which realizes multi-layer firing, has high degree of automation, high production efficiency, and saves cost and space.
本发明所要解决的技术问题还在于,提供一种发泡陶瓷轻质板材的隧道窑烧成系统,实现低温快烧,其烧成得到的发泡陶瓷轻质板材在同一断面上,从上到下气孔无差异,气泡均匀性高。The technical problem to be solved by the present invention is also to provide a tunnel kiln firing system for foamed ceramic lightweight plates to achieve fast firing at low temperature. The foamed ceramic lightweight plates obtained by firing are on the same section, from top to bottom. There is no difference in lower stomata, and the uniformity of air bubbles is high.
为了解决上述技术问题,本发明提供了一种发泡陶瓷轻质板材的隧道窑烧成系统,包括:上料线,用于将原料在窑车上进行布料;隧道窑,用于将发泡陶瓷坯体进行烧成;下料线,用于将发泡陶瓷轻质板材进行卸载;In order to solve the above technical problems, the present invention provides a tunnel kiln firing system of foamed ceramic light board, including: a feeding line for distributing raw materials on a kiln car; a tunnel kiln for expanding foam The ceramic body is fired; the cutting line is used to unload the foamed ceramic light board;
其中,所述窑车包括支架,所述支架上设有匣钵,所述匣钵包括垫板、围板和耐高温纸,所述围板搭设在垫板的四周,所述垫板和围板上均设有所述耐高温纸;Wherein, the kiln car includes a bracket, and a box bowl is provided on the bracket. The box bowl includes a cushion plate, a surrounding plate, and a high-temperature resistant paper. The board is provided with the high temperature resistant paper;
所述上料线包括:The loading line includes:
用于清理垫板、围板的清理单元;Cleaning unit for cleaning pads and enclosures;
用于在垫板上铺设耐高温纸的第一铺设单元;A first laying unit for laying a heat-resistant paper on a mat;
用于在垫板上搭设围板的围板搭设单元;A siding installation unit for siding a siding on a shim;
用于在围板上铺设耐高温纸的第二铺设单元;A second laying unit for laying heat-resistant paper on the surrounding board;
用于在垫板、围板和耐高温纸形成的匣钵上进行布料的布料单元;A cloth distribution unit for cloth distribution on a cushion board, a surrounding board and a box formed of high temperature resistant paper;
用于将布料后的窑车输送到隧道窑的输送单元。Conveying unit for conveying the kiln car after distribution to the tunnel kiln.
作为上述方案的改进,所述下料线包括:As an improvement to the above solution, the blanking line includes:
用于卸载围板的第一卸载单元;A first unloading unit for unloading the shroud;
用于卸载发泡陶瓷轻质板材的第二卸载单元。A second unloading unit for unloading foamed ceramic lightweight panels.
作为上述方案的改进,所述第一铺设单元包括铺底面纸机,所述围板搭设单元包括机械手,所述第二铺设单元包括铺侧面纸机;As an improvement to the foregoing solution, the first laying unit includes a bottom-laying paper machine, the surrounding board laying unit includes a robot, and the second laying unit includes a side-laying paper machine;
所述第一铺设单元、围板搭设单元和第二铺设单元依次连接;The first laying unit, the erection unit and the second laying unit are connected in sequence;
所述围板搭设单元与第一卸载单元对应设置,所述机械手将第一卸载单元卸载的围板移送到围板搭设单元。The surrounding board erection unit is provided corresponding to the first unloading unit, and the robot hand transfers the surrounding board unloaded by the first unloading unit to the surrounding board erection unit.
作为上述方案的改进,所述第一铺设单元、围板搭设单元和第二铺设单元还设有归整机,所述归整机包括升降机械臂和拍齐部件,所述拍齐部件对垫板和围板进行拍齐归整。As an improvement of the above scheme, the first laying unit, the erection unit and the second laying unit are further provided with a finishing machine, the finishing machine includes a lifting robot arm and a snapping member, and the snapping member is opposite to the pad The boards and boards are aligned.
作为上述方案的改进,所述清理单元为清理机,所述清理机包括毛刷、驱动机构和真空吸尘系统,所述驱动机构驱动毛刷滚动。As an improvement of the above solution, the cleaning unit is a cleaning machine, the cleaning machine includes a brush, a driving mechanism, and a vacuum cleaning system, and the driving mechanism drives the brush to roll.
作为上述方案的改进,所述垫板为莫来石垫板、碳化硅垫板或堇青石垫板;As an improvement of the above solution, the pad is a mullite pad, a silicon carbide pad or a cordierite pad;
所述围板为莫来石围板、碳化硅围板或堇青石围板;The enclosure is a mullite enclosure, a silicon carbide enclosure or a cordierite enclosure;
所述耐高温纸为硅酸铝纤维纸。The high temperature resistant paper is aluminum silicate fiber paper.
作为上述方案的改进,所述支架上设有至少三层匣钵,匣钵内的坯体在隧道窑内进行多层叠烧,以形成发泡陶瓷轻质板材。As an improvement of the above solution, the bracket is provided with at least three layers of box bowls, and the green body in the box bowl is multi-layered and fired in a tunnel kiln to form a foamed ceramic light board.
作为上述方案的改进,所述发泡陶瓷轻质板材主要由下述重量百分比的原料制成:As an improvement to the above scheme, the foamed ceramic lightweight board is mainly made of the following weight percentages of raw materials:
瓷砖抛光废渣70-96%、粘土0-10%、长石0-20%、发泡剂0.01-0.6%、稳定剂0.1-4%。Tile polishing residue is 70-96%, clay is 0-10%, feldspar is 0-20%, foaming agent is 0.01-0.6%, stabilizer is 0.1-4%.
作为上述方案的改进,所述发泡陶瓷轻质板材主要由下述重量百分比的原料制成:As an improvement to the above scheme, the foamed ceramic lightweight board is mainly made of the following weight percentages of raw materials:
瓷砖抛光废渣75-95%、粘土0.1-10%、长石0.1-20%、发泡剂0.1-0.4%、稳定剂0.1-3%。Tile polishing residue is 75-95%, clay is 0.1-10%, feldspar is 0.1-20%, foaming agent is 0.1-0.4%, and stabilizer is 0.1-3%.
作为上述方案的改进,所述粘土为黑泥、高岭土、城市污泥、海泥中的一种或多种;As an improvement of the above scheme, the clay is one or more of black mud, kaolin, urban sludge, and sea mud;
所述发泡剂为碳化硅或抛光磨头回收料,所述抛光磨头回收料的主要成分包括碳化硅和树脂。The foaming agent is silicon carbide or a reclaimed polishing head. The main components of the reclaimed polishing head include silicon carbide and a resin.
实施本发明,具有如下有益效果:The implementation of the present invention has the following beneficial effects:
一、本发明发泡陶瓷轻质板材的隧道窑烧成系统,包括上料线、隧道窑和下料线,其中,上料线用于将原料在窑车上进行布料,以形成坯体;隧道窑用于将坯体进行烧成,以形成发泡陶瓷轻质板材;下料线用于将发泡陶瓷轻质板材进行卸载。窑车从隧道窑的窑尾出来后,进入下料线,首先卸围板,然后卸发泡陶瓷轻质板材,下料线操作完毕。进入上料线,依次清理垫板围板、在垫板上铺设耐高温纸、上围板、在围板上铺设耐高温纸、布料,最后将铺满料的窑车传送至窑炉。本发明采用上述生产系统,可以避免单层堆烧,实现多层叠烧,减少手动劳动力,实现全自动化生产,大大提高生产效率。1. The tunnel kiln firing system of the foamed ceramic light board of the present invention comprises a feeding line, a tunnel kiln and a feeding line, wherein the feeding line is used for distributing raw materials on a kiln car to form a green body; The tunnel kiln is used for firing the green body to form a foamed ceramic light board; the cutting line is used for unloading the foamed ceramic light board. After the kiln car comes out of the kiln tail of the tunnel kiln, it enters the unloading line, first unloads the siding, then unloads the foamed ceramic light board, and the unloading line is finished. Enter the feeding line, clean the padding board in turn, lay high temperature resistant paper on the padding board, place the upper board, lay high temperature resistant paper and cloth on the board, and finally transfer the kiln car covered with material to the kiln. The invention adopts the above production system, which can avoid single-layer stacking, realize multi-layer stacking, reduce manual labor, realize fully automated production, and greatly improve production efficiency.
二、上料线的围板搭设单元与下料线的第一卸载单元对应设置,机械手将第一卸载单元卸载的围板移送到围板搭设单元,减少上料、下料之间的移动距离,方便操作,使得生产线的布局更为合理,减少生产占地空间。2. The hoisting board erection unit of the loading line is set corresponding to the first unloading unit of the feeding line, and the robot moves the hoisting board unloaded by the first unloading unit to the hoisting plate erection unit to reduce the moving distance between loading and unloading. , Easy to operate, making the layout of the production line more reasonable, reducing production space.
三、本发明采用隧道窑叠烧方法,实现低温快烧,大大减少了配方的氧化反应阶段时间,即使缩短了烧成周期,也可以把陶瓷板烧透,提高了产量,降低了单位产品的能耗。而且,本发明采用多层叠烧的方法,坯体不会受到多层叠加的影响,也可以在低温、短时间内烧透,保证产品质量,大大提高了生产效率,并可以减少隧道窑的占地空间。3. The present invention adopts a tunnel kiln stacking method to achieve low-temperature fast firing, which greatly reduces the oxidation reaction stage time of the formula. Even if the firing cycle is shortened, the ceramic plate can be burned through, which increases the yield and reduces the unit product. Energy consumption. In addition, the present invention adopts a multi-layer firing method, and the green body is not affected by multilayer superposition, and can also be burned through at low temperature and in a short time to ensure product quality, greatly improve production efficiency, and reduce the occupation of the tunnel kiln. Ground space.
四、所述发泡陶瓷轻质板材的原料包括瓷砖抛光废渣70-96%、发泡剂0.01-0.6%、稳定剂0.1-4%,其增加了瓷砖抛光废渣的加入量,瓷砖抛光废渣的加入量最高可达96%,同时将发泡剂的加入量减少至0.01-0.6%。在这基础上,加入0.1-4%的二氧化锰稳定剂,可以提高气泡的均匀性,即使在同一断面,从上到下的气孔无差异,使得产品的整体均匀性好。4. The raw materials of the foamed ceramic light board include 70-96% of tile polishing waste, 0.01-0.6% of foaming agent, and 0.1-4% of stabilizer, which increases the amount of tile polishing waste added. The maximum amount can be up to 96%, and the amount of foaming agent can be reduced to 0.01-0.6%. On this basis, the addition of 0.1-4% manganese dioxide stabilizer can improve the uniformity of air bubbles. Even in the same section, there is no difference in the pores from top to bottom, which makes the overall uniformity of the product good.
最后,通过上述叠烧系统和叠烧方法制得的发泡陶瓷轻质板材质量优异,抗压强度≥4.5Mpa,体积密度:200-1100Kg/m 3,导热系数:≤0.15W/m℃,燃烧等级:A1级,吸水率: <2%,放射性指标:I Ra≤1.0,I r≤1.0。 Finally, the foamed ceramic light board made by the above-mentioned fire-stacking system and fire-stacking method has excellent quality, compressive strength ≥4.5Mpa, bulk density: 200-1100Kg / m 3 , thermal conductivity: ≤0.15W / m ℃, Burning level: A1 level, water absorption: <2%, radioactivity index: I Ra ≤ 1.0, I r ≤ 1.0.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1是现有技术发泡陶瓷轻质板材的截面图;1 is a cross-sectional view of a prior art foamed ceramic lightweight board;
图2是本发明发泡陶瓷轻质板材的隧道窑烧成系统的示意图;2 is a schematic view of a tunnel kiln firing system of the foamed ceramic light board of the present invention;
图3是本发明窑车的主视图;Figure 3 is a front view of a kiln car of the present invention;
图4是本发明窑车的左视图;Figure 4 is a left side view of the kiln car of the present invention;
图5是本发明窑车的俯视图。Fig. 5 is a plan view of a kiln car according to the present invention.
具体实施方式detailed description
为使本发明的目的、技术方案和优点更加清楚,下面将结合附图对本发明作进一步地详细描述。To make the objectives, technical solutions, and advantages of the present invention clearer, the present invention will be described in further detail below with reference to the accompanying drawings.
参见图2,本发明提供一种发泡陶瓷轻质板材的隧道窑烧成系统,包括:上料线1,用于将原料在窑车4上进行布料;隧道窑2,用于将发泡陶瓷坯体进行烧成;下料线3,用于将发泡陶瓷轻质板材进行卸载。Referring to FIG. 2, the present invention provides a tunnel kiln firing system for a foamed ceramic light board, including: a feeding line 1 for distributing raw materials on a kiln car 4; a tunnel kiln 2 for foaming The ceramic body is fired; the cutting line 3 is used for unloading the foamed ceramic light board.
参见图3-5,所述窑车4包括支架41,所述支架41上设有匣钵42,所述匣钵42包括垫板43、围板44和耐高温纸45,所述围板44搭设在垫板43的四周,所述垫板43和围板44上均设有所述耐高温纸45。Referring to Figs. 3-5, the kiln car 4 includes a bracket 41 provided with a box bowl 42 including a shim plate 43, a surrounding plate 44 and a high temperature resistant paper 45. Laying on the periphery of the shim plate 43, the high temperature resistant paper 45 is provided on the shim plate 43 and the surrounding plate 44.
优选的,所述支架41上设有至少三层匣钵42,匣钵42内的坯体在隧道窑2内进行多层叠烧,以形成发泡陶瓷轻质板材。本发明采用隧道窑多层叠烧方法,实现低温快烧,大大减少了配方的氧化反应阶段时间,即使缩短了烧成周期,也可以把陶瓷板烧透,提高了产量,降低了单位产品的能耗。而且,本发明采用多层叠烧的方法,坯体不会受到多层叠加的影响,也可以在低温、短时间内烧透,保证产品质量,大大提高了生产效率,并可以减少隧道窑的占地空间。Preferably, the bracket 41 is provided with at least three layers of box bowls 42, and the green body in the box bowl 42 is multi-layered and fired in the tunnel kiln 2 to form a foamed ceramic light board. The invention adopts the multi-layer firing method of the tunnel kiln to realize low-temperature fast firing, which greatly reduces the oxidation reaction stage time of the formula. Even if the firing cycle is shortened, the ceramic plate can be burned through, the yield is increased, and the energy per unit product is reduced Consuming. In addition, the present invention adopts a multi-layer firing method, and the green body is not affected by multilayer superposition, and can also be burned through at low temperature and in a short time to ensure product quality, greatly improve production efficiency, and reduce the occupation of the tunnel kiln. Ground space.
需要说明的是,上述窑车的匣钵42的层数可以根据实际情况而进行设定,例如4、5、6、7、8、9、10层,其实施方式并不局限于本发明所举实施例。It should be noted that the number of layers of the box bowl 42 of the kiln car can be set according to the actual situation, for example, 4, 5, 6, 7, 8, 9, and 10 layers, and its implementation is not limited to the invention. Give examples.
所述垫板43优选为莫来石垫板、碳化硅垫板或堇青石垫板,具有热膨胀系数小,热震稳定性好,自身不易变形和开裂,使用寿命长等优点。The backing plate 43 is preferably a mullite backing plate, a silicon carbide backing plate or a cordierite backing plate, and has the advantages of small thermal expansion coefficient, good thermal shock stability, not being easily deformed and cracked, and long service life.
所述围板44优选为莫来石围板、碳化硅围板或堇青石围板,具有热膨胀系数小,热震 稳定性好,自身不易变形和开裂,使用寿命长等优点。The enclosure 44 is preferably a mullite enclosure, a silicon carbide enclosure or a cordierite enclosure, which has the advantages of small thermal expansion coefficient, good thermal shock stability, not being easily deformed and cracked, and long service life.
所述耐高温纸45是指可以经受1220℃高温的纸,优选为硅酸铝纤维纸,硅酸铝纤维纸由金石硅酸铝陶瓷纤维棉为主要原料采用湿法成型工艺制成,在高温环境下具有理想的隔热、保温、密封、电绝缘、吸音、过滤性能。其热容量低、热导率低、电绝缘性能优良、机械加工性能优良、强度高、抗撕扯、柔韧性高。The high temperature resistant paper 45 refers to a paper that can withstand a high temperature of 1220 ° C, preferably an aluminum silicate fiber paper. The aluminum silicate fiber paper is made of gold stone aluminum silicate ceramic fiber cotton as a main raw material by a wet forming process. It has ideal heat insulation, heat preservation, sealing, electrical insulation, sound absorption, and filtering performance in the environment. It has low thermal capacity, low thermal conductivity, excellent electrical insulation properties, excellent machining performance, high strength, tear resistance and high flexibility.
所述上料线1包括:The feeding line 1 includes:
用于清理垫板、围板的清理单元11;A cleaning unit 11 for cleaning pads and enclosures;
用于在垫板上铺设耐高温纸的第一铺设单元12;A first laying unit 12 for laying a heat-resistant paper on a mat;
用于在垫板上搭设围板的围板搭设单元13;A shroud erection unit 13 for laying a shroud on the pad;
用于在围板上铺设耐高温纸的第二铺设单元14;A second laying unit 14 for laying a heat-resistant paper on the surrounding board;
用于在垫板、围板和耐高温纸形成的匣钵上进行布料的布料单元15;A cloth distribution unit 15 for cloth distribution on a cushion plate, a surrounding plate and a box formed of high-temperature paper;
用于将布料后的窑车输送到隧道窑的输送单元16。The conveying unit 16 for conveying the kiln car after the distribution to the tunnel kiln.
所述下料线3包括:The blanking line 3 includes:
用于卸载围板的第一卸载单元31;A first unloading unit 31 for unloading a fence;
用于卸载发泡陶瓷轻质板材的第二卸载单元32。A second unloading unit 32 for unloading the foamed ceramic lightweight board.
具体的,所述清理单元11为清理机,所述清理机包括毛刷、驱动机构和真空吸尘系统,所述驱动机构驱动毛刷滚动。本发明通过带动滚动的毛刷和真空吸尘系统对垫板、围板表面进行清理收集。Specifically, the cleaning unit 11 is a cleaning machine, which includes a brush, a driving mechanism, and a vacuum cleaning system, and the driving mechanism drives the brush to roll. The invention cleans and collects the surface of the backing plate and the surrounding plate by using a rolling brush and a vacuum cleaning system.
所述第一铺设单元12体例于此包括铺底面纸机,所述围板搭设单元13包括机械手17,所述第二铺设单元14包括铺侧面纸机,所述第一铺设单元12、围板搭设单元13和第二铺设单元14依次连接,依次进行在垫板上铺设耐高温纸、上围板、在围板上铺设耐高温纸的处理。Here, the first laying unit 12 includes a bottom paper machine, the surrounding board erection unit 13 includes a manipulator 17, the second laying unit 14 includes a side paper machine, and the first laying unit 12 and the surrounding board The erection unit 13 and the second laying unit 14 are sequentially connected, and the processing of laying high-temperature-resistant paper on the backing board, the upper surrounding board, and laying the high-temperature-resistant paper on the surrounding board are sequentially performed.
所述围板搭设单元13与第一卸载单元31对应设置,所述机械手17将第一卸载单元卸载31的围板移送到围板搭设单元13的对应层上,减少上料、下料之间的移动距离,方便操作,使得生产线的布局更为合理,减少生产占地空间。The shroud erection unit 13 is provided corresponding to the first unloading unit 31, and the manipulator 17 moves the shroud slab of the first unloading unit 31 to the corresponding layer of the shroud erection unit 13, reducing the interval between loading and unloading. The moving distance and convenient operation make the layout of the production line more reasonable and reduce the production space.
所述第一铺设单元12、围板搭设单元13和第二铺设单元14还设有归整机,所述归整机包括升降机械臂和拍齐部件,拍齐部件按垫板、围板的外形尺寸四周设定有拍齐气缸,窑车到拍齐工位后,升降机械臂带动拍齐部件下降到指定位置对硼板四周进行拍齐归整,拍齐完毕升降机带动拍齐部件升起,窑车行走转至下一工位。The first laying unit 12, the shroud erection unit 13, and the second laying unit 14 are further provided with a finishing machine, which includes a lifting robot arm and a snapping component, and the snapping component is pressed against the pad and the surrounding plate. Dimensioning cylinders are set around the external dimensions. After the kiln car reaches the aligning station, the lifting robotic arm drives the aligning components to descend to the specified position, and aligns all around the boron board. After the completion of the aligning, the elevator drives the aligning components to rise. The kiln car walked to the next station.
需要说明的是,本发明清理单元11选用的清理机,选择市售清理机即可;而第一铺设 单元12选用的体例于此铺底面纸机和第二铺设单元14选用的铺侧面纸机,选择市售的铺纸机即可。It should be noted that, for the cleaning machine selected by the cleaning unit 11 of the present invention, a commercially available cleaning machine can be selected; and the system selected by the first laying unit 12 is a bottom paper machine and the side laying paper machine by the second laying unit 14 is selected here. , Choose a commercially available paper machine.
结合图2,本发明的工作流程如下:With reference to Figure 2, the working process of the present invention is as follows:
首先,进入上料线1,依次通过清理单元11清理垫板围板、通过第一铺设单元12在垫板上铺设耐高温纸、通过围板搭设单元13进行上围板、通过第二铺设单元14在围板上铺设耐高温纸、通过布料单元15布料,最后将铺满料的窑车通过输送单元16传送至窑炉。First, enter the loading line 1, and then clean the padding board in sequence by the cleaning unit 11, lay high-temperature paper on the padding board in the first laying unit 12, and place the boarding board in the boarding unit 13 and the second laying unit. 14 Lay high-temperature-resistant paper on the surrounding board, distribute it through the distribution unit 15, and finally transfer the kiln car covered with material to the kiln through the conveying unit 16.
然后,铺满料的窑车在隧道窑2内进行烧成,烧成后得到发泡陶瓷轻质板材成品。Then, the covered kiln car is fired in the tunnel kiln 2 to obtain a foamed ceramic lightweight board finished product after firing.
最后,窑车从隧道窑2的窑尾出来后,进入下料线3,首先通过第一卸载单元31卸围板,然后通过第二卸载单元32卸发泡陶瓷轻质板材,下料线3操作完毕。Finally, the kiln car comes out of the kiln tail of the tunnel kiln 2 and enters the unloading line 3. First, the first unloading unit 31 is used to unload the enclosure board, and then the second unloading unit 32 is used to unload the foamed ceramic light board. Operation is complete.
以此循环重复。Repeat this cycle.
进一步,所述发泡陶瓷轻质板材主要由下述重量百分比的原料制成:瓷砖抛光废渣70-96%、粘土0-10%、长石0-20%、发泡剂0.01-0.6%、稳定剂0.1-4%。Further, the foamed ceramic lightweight board is mainly made of the following weight percentages of raw materials: tile polishing residue 70-96%, clay 0-10%, feldspar 0-20%, foaming agent 0.01-0.6%, Stabilizer 0.1-4%.
优选的,所述发泡陶瓷轻质板材主要由下述重量百分比的原料制成:瓷砖抛光废渣75-95%、粘土0.1-10%、长石0.1-20%、发泡剂0.1-0.4%、稳定剂0.1-3%。Preferably, the foamed ceramic light board is mainly made of the following weight percentages of raw materials: 75-95% of tile polishing waste, 0.1-10% of clay, 0.1-20% of feldspar, and 0.1-0.4% of foaming agent. Stabilizer 0.1-3%.
本发明增加了瓷砖抛光废渣的加入量,同时降低发泡剂的加入量。在这基础上,加入0.1-4%的二氧化锰稳定剂,可以提高气泡的均匀性,即使在同一断面,从上到下的气孔无差异,使得产品的整体均匀性好。发泡陶瓷轻质板材整体断面的气孔均为圆孔,且从上到下的气孔尺寸基本一致,烧成的孔径均匀性好。The invention increases the amount of tile polishing waste residue and reduces the amount of foaming agent. On this basis, the addition of 0.1-4% manganese dioxide stabilizer can improve the uniformity of air bubbles. Even in the same section, there is no difference in the pores from top to bottom, which makes the overall uniformity of the product good. The pores in the entire cross section of the foamed ceramic light board are round holes, and the pore sizes from top to bottom are basically the same, and the uniformity of the pores after firing is good.
二氧化锰是两性氧化物,它是一种常温下非常稳定的黑色粉末状固体。遇还原剂时,表现为氧化性,遇强氧化剂时,表现为还原性。现有技术通常将二氧化锰作为氧化剂或催化剂使用。本发明将二氧化锰作为气泡稳定剂使用,二氧化锰可以通过与配方的反应后,使气孔的壁变得结实,同时使配方的均匀性更好,即使在同一断面,从上到下的孔也无差异,避免气孔被压扁,提高气泡的均匀性,产品的整体均匀性好。Manganese dioxide is an amphoteric oxide, which is a very stable black powdery solid at room temperature. It appears oxidizing when it encounters a reducing agent, and it appears reducing when it encounters a strong oxidant. The prior art generally uses manganese dioxide as an oxidant or catalyst. In the present invention, manganese dioxide is used as a bubble stabilizer. After reacting with the formula, manganese dioxide can make the walls of the stomata firm, and at the same time, make the formula more homogeneous, even in the same section, from top to bottom. There is no difference in the pores, which prevents the pores from being squashed, improves the uniformity of the bubbles, and the overall uniformity of the product is good.
所述发泡剂为碳化硅或抛光磨头回收料,所述抛光磨头回收料的主要成分包括碳化硅和树脂。碳化硅是一种发泡材料,该材料的存在,使其在烧制过程中不像普通陶瓷一样收缩,反而是膨胀的,从而使建筑用轻质高强陶瓷板在尺寸和厚度上比传统陶瓷板更加容易做到大而厚。抛光磨头回收料作为基底原料添加,是因为抛光磨头本身成分就是碳化硅和树脂,而碳化硅正是本发明配方中添加的发泡剂,所以本发明可以将发泡剂的加入量减少至0.01-0.6%,降低发泡剂的用量,降低成本。The foaming agent is silicon carbide or a reclaimed polishing head. The main components of the reclaimed polishing head include silicon carbide and a resin. Silicon carbide is a foaming material.The presence of this material makes it not shrink like ordinary ceramics during firing, but expands, thereby making the lightweight and high-strength ceramic plate for construction smaller than traditional ceramics in size and thickness. Plates are easier to make large and thick. The polishing grinder recycling material is added as the base material because the components of the polishing grinder are silicon carbide and resin, and silicon carbide is the foaming agent added in the formulation of the invention, so the invention can reduce the amount of foaming agent added. To 0.01-0.6%, reduce the amount of foaming agent and reduce costs.
同时,配方中引入70-96%的瓷砖抛光废渣,既有利于环保循环利用,也可以使得发泡陶瓷轻质板材烧结后内部具有坚固的类似蜂窝状的孔洞结构,具有绿色环保、质轻、方便施工、减轻建筑负载等优点。本发明瓷砖抛光废渣的加入量远远大于现有的发泡陶瓷板,降低成本,加强对固废物的回收利用。At the same time, the introduction of 70-96% of tile polishing residue in the formula is not only conducive to environmental protection recycling, but also makes the foamed ceramic light board sintered with a solid honeycomb-like hole structure, which is green, environmentally friendly, lightweight, Convenient construction, lightening building load, etc. The added amount of ceramic tile polishing waste of the present invention is much larger than the existing foamed ceramic plate, which reduces the cost and strengthens the recycling of solid waste.
所述粘土为黑泥、高岭土、城市污泥、海泥中的一种或多种。本发明原料加入粘土和长石,可以调整基底配方中的硅、铝、钾、钠成分比,使发泡砖壁更硬,强度更高,并进一步对废固物进行回收利用。The clay is one or more of black mud, kaolin, urban sludge, and sea mud. By adding clay and feldspar to the raw materials of the present invention, the silicon, aluminum, potassium, and sodium component ratios in the base formulation can be adjusted to make the foamed brick wall harder and stronger, and further recycle the waste solids.
本发明采用隧道窑多层叠烧方法,其中,所述烧成方法包括:The present invention adopts a tunnel kiln multi-layer firing method, wherein the firing method includes:
(1)升温至T 1,T 1为800-900℃,并在T 1保温0-30min,其中,由0℃升温至400℃的升温速率为10-20℃/min,由400℃升温至T 1的升温速率为1-8℃/min; (1) The temperature is raised to T 1 , T 1 is 800-900 ° C., and the temperature is maintained at T 1 for 0-30 min. Among them, the temperature rising rate from 0 ° C. to 400 ° C. is 10-20 ° C./min, and from 400 ° C. to The heating rate of T 1 is 1-8 ℃ / min;
(2)升温至T 2,T 2为1150-1220℃,并在最高温保温0-60min,其中,由T 1升温至T 2的升温速率为1-8℃/min; (2) The temperature is raised to T 2 , T 2 is 1150-1220 ° C., and the temperature is maintained at the highest temperature for 0-60 min. Among them, the temperature rising rate from T 1 to T 2 is 1-8 ° C./min;
(3)缓慢降温,由T 2降温至600℃的降温速率为3-9℃/min,由600℃降温至50℃的降温速率为1-4℃/min。 (3) Slow cooling, the cooling rate from T 2 to 600 ° C is 3-9 ° C / min, and the cooling rate from 600 ° C to 50 ° C is 1-4 ° C / min.
优选的,所述烧成方法包括:Preferably, the firing method includes:
(1)升温至800-900℃,并在800-900℃保温0-30min,其中,由0℃升温至400℃的升温速率为15℃/min,由400℃升温至800℃的升温速率为5℃/min;(1) The temperature is increased to 800-900 ° C, and the temperature is maintained at 800-900 ° C for 0-30min. Among them, the temperature increase rate from 0 ° C to 400 ° C is 15 ° C / min, and the temperature increase rate from 400 ° C to 800 ° C is 5 ℃ / min;
(2)升温至1150-1220℃,并在最高温保温0-60min,其中,由800℃升温至1150℃的升温速率为5℃/min;(2) The temperature is raised to 1150-1220 ° C, and the temperature is maintained at the highest temperature for 0-60min. Among them, the temperature increase rate from 800 ° C to 1150 ° C is 5 ° C / min;
(3)缓慢降温,由1150℃降温至600℃的降温速率为6℃/min,由600℃降温至50℃的降温速率为2℃/min。(3) Slow cooling, the cooling rate from 1150 ° C to 600 ° C is 6 ° C / min, and the cooling rate from 600 ° C to 50 ° C is 2 ° C / min.
将本发明所得的发泡陶瓷轻质板材做技术检测,结果如下:The technical inspection of the foamed ceramic light board obtained by the present invention has the following results:
项目project 本发明this invention
抗压强度Compressive strength ≥4.5Mpa≥4.5Mpa
体积密度Bulk Density 200-1100Kg/m 3 200-1100Kg / m 3
导热系数Thermal Conductivity ≤0.15W/m℃≤0.15W / m ℃
燃烧等级Burning level A1级A1 level
吸水率Water absorption <2%<2%
放射性指标Radioactive index I Ra≤1.0,I r≤1.0 I Ra ≤1.0, I r ≤1.0
因此,本发明在解决发泡陶瓷轻质板材内部气孔的基础上,还保证了其具有良好的抗压强度,且保温效果好,阻燃性好,放射性指标低。Therefore, on the basis of solving the pores in the foamed ceramic light board, the invention also ensures that it has good compressive strength, good thermal insulation effect, good flame retardancy, and low radioactivity index.
下面以具体实施例进一步阐述本发明The present invention is further explained in the following specific examples.
实施例1Example 1
(1)配方:瓷砖抛光废渣95.5%、发泡剂0.5%、二氧化锰稳定剂4%。(1) Formula: 95.5% ceramic tile polishing residue, 0.5% foaming agent, 4% manganese dioxide stabilizer.
(2)制备方法:(2) Preparation method:
将原料按配比混料,并经球磨,得到粉料;The raw materials are mixed according to the ratio and ball milled to obtain powder;
将粉料通过上料线在窑车上进行布料,然后将窑车推入隧道窑进行三层叠烧处理,得到发泡陶瓷轻质板材,其中,烧成方法如下:(a)升温至800℃,并在800℃保温20min,其中,由0℃升温至400℃的升温速率为10℃/min,由400℃升温至800℃的升温速率为3℃/min;(b)升温至1150℃,并在最高温保温40min,其中,由800℃升温至1150℃的升温速率为3℃/min;(c)缓慢降温,由1150℃降温至600℃的降温速率为3℃/min,由600℃降温至50℃的降温速率为1℃/min;The powder is distributed on the kiln car through the feeding line, and then the kiln car is pushed into the tunnel kiln for three-layer firing to obtain a foamed ceramic lightweight plate. The firing method is as follows: (a) The temperature is raised to 800 ° C. , And maintained at 800 ° C for 20min, in which, the temperature increase rate from 0 ° C to 400 ° C is 10 ° C / min, and the temperature increase rate from 400 ° C to 800 ° C is 3 ° C / min; (b) the temperature is increased to 1150 ° C, The temperature is maintained at the highest temperature for 40 minutes. Among them, the temperature increase rate from 800 ° C to 1150 ° C is 3 ° C / min. (C) Slow temperature decrease, the temperature decrease rate from 1150 ° C to 600 ° C is 3 ° C / min, from 600 ° C. The rate of temperature decrease to 50 ℃ is 1 ℃ / min;
最后通过下料线将发泡陶瓷轻质板材进行卸载。Finally, the foamed ceramic light board is unloaded through a cutting line.
实施例2Example 2
(1)配方:瓷砖抛光废渣90%、粘土1%、长石8.8%、发泡剂0.1%、稳定剂0.1%。(1) Formula: 90% ceramic tile polishing residue, 1% clay, feldspar 8.8%, foaming agent 0.1%, stabilizer 0.1%.
(2)制备方法:(2) Preparation method:
将原料按配比混料,并经球磨,得到粉料;The raw materials are mixed according to the ratio and ball milled to obtain powder;
将粉料通过上料线在窑车上进行布料,然后将窑车推入隧道窑进行三层叠烧处理,得到发泡陶瓷轻质板材,其中,烧成方法如下:(a)升温至820℃,并在820℃保温15min,其中,由0℃升温至400℃的升温速率为15℃/min,由400℃升温至820℃的升温速率为5℃/min;(b)升温至1170℃,并在最高温保温30min,其中,由820℃升温至1170℃的升温速率为4℃/min;(c)缓慢降温,由1170℃降温至600℃的降温速率为4℃/min,由600℃降温至50℃的降温速率为2℃/min;The powder is distributed on the kiln car through the feeding line, and then the kiln car is pushed into the tunnel kiln for three-layer firing to obtain a foamed ceramic light board. The firing method is as follows: (a) The temperature is raised to 820 ° C. , And maintained at 820 ° C for 15 minutes, in which the temperature increase rate from 0 ° C to 400 ° C is 15 ° C / min, and the temperature increase rate from 400 ° C to 820 ° C is 5 ° C / min; (b) the temperature is increased to 1170 ° C, The temperature is maintained at the highest temperature for 30 minutes. Among them, the heating rate from 820 ° C to 1170 ° C is 4 ° C / min; (c) Slow cooling, the cooling rate from 1170 ° C to 600 ° C is 4 ° C / min, from 600 ° C The rate of cooling down to 50 ℃ is 2 ℃ / min;
最后通过下料线将发泡陶瓷轻质板材进行卸载。Finally, the foamed ceramic light board is unloaded through a cutting line.
实施例3Example 3
(1)配方:瓷砖抛光废渣92%、粘土5%、长石2%、发泡剂0.2%、稳定剂0.8%。(1) Formula: 92% of tile polishing waste, 5% of clay, 2% of feldspar, 0.2% of foaming agent, 0.8% of stabilizer.
(2)制备方法:(2) Preparation method:
将原料按配比混料,并经球磨,得到粉料;The raw materials are mixed according to the ratio and ball milled to obtain powder;
将粉料通过上料线在窑车上进行布料,然后将窑车推入隧道窑进行三层叠烧处理,得到发泡陶瓷轻质板材,其中,烧成方法如下:(a)升温至830℃,并在830℃保温25min,其中,由0℃升温至400℃的升温速率为15℃/min,由400℃升温至830℃的升温速率为5℃/min;(b)升温至1180℃,并在最高温保温0-60min,其中,由830℃升温至1180℃的升温速率为5℃/min;(c)缓慢降温,由1180℃降温至600℃的降温速率为5℃/min,由600℃降温至50℃的降温速率为2℃/min;The powder is distributed on the kiln car through the feeding line, and then the kiln car is pushed into the tunnel kiln for three-layer firing to obtain a foamed ceramic light board. The firing method is as follows: (a) The temperature is raised to 830 ° C. , And maintained at 830 ° C for 25 minutes, in which, the temperature increase rate from 0 ° C to 400 ° C is 15 ° C / min, and the temperature increase rate from 400 ° C to 830 ° C is 5 ° C / min; (b) the temperature is increased to 1180 ° C, And the temperature is maintained at the highest temperature for 0-60min, among which, the temperature increase rate from 830 ° C to 1180 ° C is 5 ° C / min; (c) slowly cool down, the temperature decrease rate from 1180 ° C to 600 ° C is 5 ° C / min. The cooling rate from 600 ℃ to 50 ℃ is 2 ℃ / min;
最后通过下料线将发泡陶瓷轻质板材进行卸载。Finally, the foamed ceramic light board is unloaded through a cutting line.
实施例4Example 4
(1)配方:瓷砖抛光废渣88%、粘土2%、长石8%、发泡剂0.1%、稳定剂1.9%。(1) Formula: 88% of tile polishing waste, 2% of clay, 8% of feldspar, 0.1% of foaming agent, and 1.9% of stabilizer.
(2)制备方法:(2) Preparation method:
将粉料通过上料线在窑车上进行布料,然后将窑车推入隧道窑进行三层叠烧处理,得到发泡陶瓷轻质板材,其中,烧成方法如下:(a)升温至850℃,并在850℃保温30min,其中,由0℃升温至400℃的升温速率为16℃/min,由400℃升温至850℃的升温速率为5℃/min;(b)升温至1200℃,并在最高温保温50min,其中,由850℃升温至1200℃的升温速率为5℃/min;(c)缓慢降温,由1200℃降温至600℃的降温速率为6℃/min,由600℃降温至50℃的降温速率为2℃/min;The powder is distributed on the kiln car through the feeding line, and then the kiln car is pushed into the tunnel kiln for three-layer firing to obtain a foamed ceramic light board. The firing method is as follows: (a) The temperature is raised to 850 ° C. , And maintained at 850 ° C for 30 minutes, in which the temperature increase rate from 0 ° C to 400 ° C is 16 ° C / min, and the temperature increase rate from 400 ° C to 850 ° C is 5 ° C / min; (b) the temperature is increased to 1200 ° C, The temperature is maintained at the highest temperature for 50 minutes, among which, the heating rate from 850 ° C to 1200 ° C is 5 ° C / min; (c) Slow cooling, the cooling rate from 1200 ° C to 600 ° C is 6 ° C / min, from 600 ° C The rate of cooling down to 50 ℃ is 2 ℃ / min;
最后通过下料线将发泡陶瓷轻质板材进行卸载。Finally, the foamed ceramic light board is unloaded through a cutting line.
实施例5Example 5
(1)配方:瓷砖抛光废渣80%、粘土10%、长石7.7%、发泡剂0.3%、稳定剂2%。(1) Formula: 80% of tile polishing waste, 10% of clay, 7.7% of feldspar, 0.3% of foaming agent, and 2% of stabilizer.
(2)制备方法:(2) Preparation method:
将原料按配比混料,并经球磨,得到粉料;The raw materials are mixed according to the ratio and ball milled to obtain powder;
将粉料通过上料线在窑车上进行布料,然后将窑车推入隧道窑进行三层叠烧处理,得到发泡陶瓷轻质板材,其中,烧成方法如下:(a)升温至860℃,并在860℃保温10min,其中,由0℃升温至400℃的升温速率为17℃/min,由400℃升温至860℃的升温速率为6℃/min;(b)升温至1210℃,并在最高温保温30min,其中,由860℃升温至1210℃的升温速率为5℃/min;(c)缓慢降温,由1210℃降温至600℃的降温速率为6℃/min,由600℃降温至50℃的降温速率为2℃/min;The powder is distributed on the kiln car through the feeding line, and then the kiln car is pushed into the tunnel kiln for three-layer firing to obtain a foamed ceramic lightweight board. The firing method is as follows: (a) The temperature is raised to 860 ° C. And keep it at 860 ℃ for 10min, among which, the temperature increasing rate from 0 ℃ to 400 ℃ is 17 ℃ / min, and the temperature increasing rate from 400 ℃ to 860 ℃ is 6 ℃ / min; (b) the temperature is increased to 1210 ℃, The temperature is maintained at the highest temperature for 30 minutes. Among them, the temperature rising rate from 860 ° C to 1210 ° C is 5 ° C / min; (c) Slow cooling, the cooling rate from 1210 ° C to 600 ° C is 6 ° C / min, from 600 ° C. The rate of cooling down to 50 ℃ is 2 ℃ / min;
最后通过下料线将发泡陶瓷轻质板材进行卸载。Finally, the foamed ceramic light board is unloaded through a cutting line.
实施例6Example 6
(1)配方:瓷砖抛光废渣75%、粘土1.6%、长石20%、发泡剂0.4%、稳定剂3%。(1) Formula: 75% of tile polishing waste, 1.6% of clay, 20% of feldspar, 0.4% of foaming agent, and 3% of stabilizer.
(2)制备方法:(2) Preparation method:
将原料按配比混料,并经球磨,得到粉料;The raw materials are mixed according to the ratio and ball milled to obtain powder;
将粉料通过上料线在窑车上进行布料,然后将窑车推入隧道窑进行三层叠烧处理,得到发泡陶瓷轻质板材,其中,烧成方法如下:(a)升温至900℃,并在900℃保温30min,其中,由0℃升温至400℃的升温速率为20℃/min,由400℃升温至900℃的升温速率为8℃/min;(b)升温至1220℃,并在最高温保温60min,其中,由900℃升温至1220℃的升温速率为8℃/min;(c)缓慢降温,由1220℃降温至600℃的降温速率为9℃/min,由600℃降温至50℃的降温速率为4℃/min;The powder is distributed on the kiln car through the feeding line, and then the kiln car is pushed into the tunnel kiln for three-layer firing treatment to obtain a foamed ceramic lightweight plate. The firing method is as follows: (a) The temperature is raised to 900 ° C. , And maintained at 900 ° C for 30 minutes, wherein the temperature increase rate from 0 ° C to 400 ° C is 20 ° C / min, and the temperature increase rate from 400 ° C to 900 ° C is 8 ° C / min; (b) the temperature is increased to 1220 ° C, The temperature is maintained at the highest temperature for 60 minutes, among which, the heating rate from 900 ° C to 1220 ° C is 8 ° C / min; (c) Slow cooling, the cooling rate from 1220 ° C to 600 ° C is 9 ° C / min, from 600 ° C The rate of temperature decrease to 50 ℃ is 4 ℃ / min;
最后通过下料线将发泡陶瓷轻质板材进行卸载。Finally, the foamed ceramic light board is unloaded through a cutting line.
将实施例1-6所得的发泡陶瓷轻质板材做技术检测,结果如下:The technical inspection of the foamed ceramic lightweight plate obtained in Examples 1-6 is as follows:
Figure PCTCN2018100134-appb-000001
Figure PCTCN2018100134-appb-000001
Figure PCTCN2018100134-appb-000002
Figure PCTCN2018100134-appb-000002
最后所应当说明的是,以上实施例仅用以说明本发明的技术方案而非对本发明保护范围的限制,尽管参照较佳实施例对本发明作了详细说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的实质和范围。Finally, it should be explained that the above embodiments are only used to illustrate the technical solution of the present invention and not to limit the protection scope of the present invention. Although the present invention has been described in detail with reference to the preferred embodiments, those skilled in the art should understand that Modifications or equivalent substitutions may be made to the technical solution of the present invention without departing from the spirit and scope of the technical solution of the present invention.

Claims (10)

  1. 一种发泡陶瓷轻质板材的隧道窑烧成系统,其特征在于,包括:上料线,用于将原料在窑车上进行布料;隧道窑,用于将发泡陶瓷轻质板材坯体进行烧成;以及下料线,用于将发泡陶瓷轻质板材进行卸载;A tunnel kiln firing system for a foamed ceramic lightweight plate, which is characterized by comprising: a feeding line for distributing raw materials on a kiln car; and a tunnel kiln for transforming a foamed ceramic lightweight plate blank Firing; and a cutting line for unloading the foamed ceramic light board;
    其中,所述窑车包括支架,所述支架上设有匣钵,所述匣钵包括垫板、围板和耐高温纸,所述围板搭设在垫板的四周,所述垫板和围板上均设有所述耐高温纸;Wherein, the kiln car includes a bracket, and a box bowl is provided on the bracket. The box bowl includes a cushion plate, a surrounding plate, and a high-temperature resistant paper. The board is provided with the high temperature resistant paper;
    所述上料线包括:The loading line includes:
    用于清理垫板、围板的清理单元;Cleaning unit for cleaning pads and enclosures;
    用于在垫板上铺设耐高温纸的第一铺设单元;A first laying unit for laying a heat-resistant paper on a mat;
    用于在垫板上搭设围板的围板搭设单元;A siding installation unit for siding a siding on a shim;
    用于在围板上铺设耐高温纸的第二铺设单元;A second laying unit for laying heat-resistant paper on the surrounding board;
    用于在垫板、围板和耐高温纸形成的匣钵上进行布料的布料单元;A cloth distribution unit for cloth distribution on a cushion board, a surrounding board and a box formed of high temperature resistant paper;
    用于将布料后的窑车输送到隧道窑的输送单元。Conveying unit for conveying the kiln car after distribution to the tunnel kiln.
  2. 如权利要求1所述的发泡陶瓷轻质板材的隧道窑烧成系统,其特征在于,所述下料线包括:The tunnel kiln firing system for a foamed ceramic light board according to claim 1, wherein the cutting line comprises:
    用于卸载围板的第一卸载单元;A first unloading unit for unloading the shroud;
    用于卸载发泡陶瓷轻质板材的第二卸载单元。A second unloading unit for unloading foamed ceramic lightweight panels.
  3. 如权利要求1所述的发泡陶瓷轻质板材的隧道窑烧成系统,其特征在于,所述第一铺设单元包括铺底面纸机,所述围板搭设单元包括机械手,所述第二铺设单元包括铺侧面纸机;The tunnel kiln firing system for a foamed ceramic lightweight board according to claim 1, wherein the first laying unit includes a bottom-laying paper machine, the surrounding board laying unit includes a robot, and the second laying unit The unit includes a side-laying paper machine;
    所述第一铺设单元、围板搭设单元和第二铺设单元依次连接;The first laying unit, the erection unit and the second laying unit are connected in sequence;
    所述围板搭设单元与第一卸载单元对应设置,所述机械手将第一卸载单元卸载的围板移送到围板搭设单元。The surrounding board erection unit is provided corresponding to the first unloading unit, and the robot hand transfers the surrounding board unloaded by the first unloading unit to the surrounding board erection unit.
  4. 如权利要求3所述的发泡陶瓷轻质板材的隧道窑烧成系统,其特征在于,所述第一铺设单元、围板搭设单元和第二铺设单元还设有归整机,所述归整机包括升降机械臂和拍齐部件,所述拍齐部件对垫板和围板进行拍齐归整。The tunnel kiln firing system for a foamed ceramic light board according to claim 3, wherein the first laying unit, the cladding unit and the second laying unit are further provided with a finishing machine, wherein The whole machine includes a lifting robot arm and a aligning component, which aligns and aligns the pad and the surrounding plate.
  5. 如权利要求1所述的发泡陶瓷轻质板材的隧道窑烧成系统,其特征在于,所述清理单元为清理机,所述清理机包括毛刷、驱动机构和真空吸尘系统,所述驱动机构驱动毛刷滚动。The kiln firing system for a foamed ceramic light board according to claim 1, wherein the cleaning unit is a cleaning machine, the cleaning machine comprising a brush, a driving mechanism, and a vacuum cleaning system, wherein The driving mechanism drives the brush to roll.
  6. 如权利要求1-5任一项所述的发泡陶瓷轻质板材的隧道窑烧成系统,其特征在于, 所述垫板为莫来石垫板、碳化硅垫板或堇青石垫板;The tunnel kiln firing system for a foamed ceramic light board according to any one of claims 1 to 5, wherein the pad is a mullite pad, a silicon carbide pad or a cordierite pad;
    所述围板为莫来石围板、碳化硅围板或堇青石围板;The enclosure is a mullite enclosure, a silicon carbide enclosure or a cordierite enclosure;
    所述耐高温纸为硅酸铝纤维纸。The high temperature resistant paper is aluminum silicate fiber paper.
  7. 如权利要求1-5任一项所述的发泡陶瓷轻质板材的隧道窑烧成系统,其特征在于,所述支架上设有至少三层匣钵,匣钵内的坯体在隧道窑内进行多层叠烧,以形成发泡陶瓷轻质板材。The tunnel kiln firing system for a foamed ceramic light board according to any one of claims 1 to 5, wherein the bracket is provided with at least three layers of box bowls, and the blank in the box bowl is in the tunnel kiln. Multi-layer firing is performed inside to form a foamed ceramic lightweight board.
  8. 如权利要求7所述的发泡陶瓷轻质板材的隧道窑烧成系统,其特征在于,所述发泡陶瓷轻质板材主要由下述重量百分比的原料制成:The tunnel kiln firing system for a foamed ceramic light board according to claim 7, wherein the foamed ceramic light board is mainly made of the following weight percentages of raw materials:
    瓷砖抛光废渣70-96%、粘土0-10%、长石0-20%、发泡剂0.01-0.6%、稳定剂0.1-4%。Tile polishing residue is 70-96%, clay is 0-10%, feldspar is 0-20%, foaming agent is 0.01-0.6%, stabilizer is 0.1-4%.
  9. 如权利要求8所述的发泡陶瓷轻质板材的隧道窑烧成系统,其特征在于,所述发泡陶瓷轻质板材主要由下述重量百分比的原料制成:The tunnel kiln firing system for a foamed ceramic light board according to claim 8, wherein the foamed ceramic light board is mainly made of the following weight percentages of raw materials:
    瓷砖抛光废渣75-95%、粘土0.1-10%、长石0.1-20%、发泡剂0.1-0.4%、稳定剂0.1-3%。Tile polishing residue is 75-95%, clay is 0.1-10%, feldspar is 0.1-20%, foaming agent is 0.1-0.4%, and stabilizer is 0.1-3%.
  10. 如权利要求8所述的发泡陶瓷轻质板材的隧道窑烧成系统,其特征在于,所述粘土为黑泥、高岭土、城市污泥、海泥中的一种或多种;The tunnel kiln firing system for a foamed ceramic light board according to claim 8, wherein the clay is one or more of black mud, kaolin, urban sludge, and sea mud;
    所述发泡剂为碳化硅或抛光磨头回收料,所述抛光磨头回收料的主要成分包括碳化硅和树脂。The foaming agent is silicon carbide or a reclaimed polishing head. The main components of the reclaimed polishing head include silicon carbide and a resin.
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