WO2020000590A1 - Rolling kiln firing method for foamed ceramic lightweight plate material - Google Patents

Rolling kiln firing method for foamed ceramic lightweight plate material Download PDF

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WO2020000590A1
WO2020000590A1 PCT/CN2018/100133 CN2018100133W WO2020000590A1 WO 2020000590 A1 WO2020000590 A1 WO 2020000590A1 CN 2018100133 W CN2018100133 W CN 2018100133W WO 2020000590 A1 WO2020000590 A1 WO 2020000590A1
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temperature
foamed ceramic
rate
roller kiln
maintained
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PCT/CN2018/100133
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French (fr)
Chinese (zh)
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林�智
欧阳慧
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广东科达洁能股份有限公司
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Definitions

  • the invention relates to the technical field of ceramic plates, in particular to a roller kiln firing method for foamed ceramic lightweight plates.
  • the matrix material used in foamed ceramics comes from wastes from ceramics factories and industrial wastes (such as ceramic tile polishing residues or coal residues or stone waste residues). If these wastes are left untreated, random accumulation or landfill will cause pollution to the environment. Wasted resources.
  • the foamed ceramic products gradually began to be used nationwide due to its advantages such as light weight, high strength, fire resistance, earthquake resistance, heat insulation, sound insulation, strong combination, easy handling, and wide application. And because its raw materials are solid waste such as coal slag, ceramic tile polishing slag, slag, etc., it has positive social significance in making full use of resources and environmental protection.
  • the existing formulation system of foamed ceramics generally includes tile polishing waste residue and foaming agent, and the amount of tile polishing waste residue is relatively small, mostly about 50%.
  • the amount of foaming agent added is about 1.2%, the amount of foaming agent is large, and the cost is high.
  • the formula system of foamed ceramics determines that they must be fired in a tunnel kiln.
  • the firing cycle of the tunnel kiln is about 24-26 hours, and the firing cycle is long Higher temperature.
  • the foamed ceramic plate produced in the prior art has multiple layers of air holes formed therein.
  • the lower air pores will be flattened, making the overall uniformity of the product poor.
  • the technical problem to be solved by the present invention is to provide a roller kiln firing method for foamed ceramic lightweight sheet material to achieve low-temperature fast firing.
  • the foamed ceramic lightweight sheet material obtained by firing is on the same cross section, from top to bottom. There is no difference in lower stomata, and the uniformity of air bubbles is high.
  • the present invention provides a roller kiln firing method for foamed ceramic light board, including:
  • T 1 The temperature is raised to T 1 , T 1 is 800-900 ° C., and the temperature is maintained at T 1 for 0-30 min. Among them, the temperature rising rate from 0 ° C. to 400 ° C. is 10-20 ° C./min, and from 400 ° C. to The heating rate of T 1 is 1-8 °C / min;
  • T 2 The temperature is raised to T 2 , T 2 is 1150-1220 ° C., and the temperature is maintained at the highest temperature for 0-60 min. Among them, the temperature rising rate from T 1 to T 2 is 1-8 ° C./min;
  • the firing method of the roller kiln includes:
  • T 1 The temperature is raised to T 1 , T 1 is 800-900 ° C., and the temperature is maintained at T 1 for 0-30 min. Among them, the heating rate from 0 ° C. to 400 ° C. is 13-17 ° C./min, and from 400 ° C. to The heating rate of T 1 is 4-6 °C / min;
  • T 2 The temperature is raised to T 2 , T 2 is 1150-1220 ° C., and the temperature is maintained at the highest temperature for 0-60 min. Among them, the temperature rising rate from T 1 to T 2 is 4-6 ° C./min;
  • the firing method of the roller kiln includes:
  • T 1 is 800-900 ° C.
  • the temperature is maintained at T 1 for 0-30 min.
  • the temperature increase rate from 0 ° C. to 400 ° C. is 15 ° C./min, and from 400 ° C. to T 1
  • the heating rate is 5 °C / min;
  • T 2 The temperature is increased to T 2 , T 2 is 1150-1220 ° C., and the temperature is maintained at the highest temperature for 0-60 min. Among them, the temperature rising rate from T 1 to T 2 is 5 ° C./min;
  • the foamed ceramic lightweight board is mainly made of the following weight percentages of raw materials:
  • the stabilizer is manganese dioxide.
  • the foamed ceramic lightweight board is mainly made of the following weight percentages of raw materials:
  • Tile polishing residue is 75-95%, clay is 0.1-10%, feldspar is 0.1-20%, foaming agent is 0.1-0.4%, and stabilizer is 0.1-3%.
  • the clay is one or more of black mud, kaolin, urban sludge, and sea mud.
  • the foaming agent is silicon carbide or a polishing head recycled material
  • the main components of the polishing head recycled material include silicon carbide and a resin
  • the roller kiln firing includes:
  • a box bowl is used on the roller kiln.
  • the box bowl is an integrated box bowl or a combined box bowl. It is manually or mechanically clothed and then fired at 1150-1220 ° C.
  • the assembled box bowl includes a support, a support plate, a surrounding plate and high-temperature paper, the supporting plate is laid on the support, the surrounding plate is erected around the supporting plate, and the supporting plate and the surrounding plate The boards are all provided with the high-temperature paper.
  • the stent is a SiC stent
  • the pad is a mullite pad, a silicon carbide pad or a cordierite pad;
  • the enclosure is a mullite enclosure, a silicon carbide enclosure or a cordierite enclosure;
  • the high-temperature paper is aluminum silicate fiber paper.
  • the invention designs a new roller kiln firing method for foamed ceramic light board, which realizes fast firing at low temperature, greatly reducing the oxidation reaction stage time of the formula, shortening the firing cycle, increasing the yield, and reducing the unit product. Energy consumption.
  • the foamed ceramic light board comprises 70-96% of tile polishing waste, 0.01-0.6% of foaming agent, and 0.1-4% of stabilizer, which increases the amount of tile polishing waste added, and the maximum amount of tile polishing waste added can be Up to 96%, while reducing the amount of foaming agent added to 0.01-0.6%.
  • the addition of 0.1-4% manganese dioxide stabilizer can improve the uniformity of air bubbles. Even in the same section, there is no difference in pores from top to bottom, which makes the overall uniformity of the product good.
  • the foamed ceramic lightweight board prepared by the invention has excellent quality, compressive strength ⁇ 5Mpa, bulk density: 200-1100Kg / m 3 , flexural strength:> 4Mpa, thermal conductivity: ⁇ 0.15W / m ° C, combustion level: A1 grade, water absorption: ⁇ 2%, radioactivity index: I Ra ⁇ 1.0, I r ⁇ 1.0.
  • FIG. 1 is a cross-sectional view of a roller kiln firing method of a prior art foamed ceramic light board
  • FIG. 2 is a flow chart of a roller kiln firing method of the foamed ceramic light board of the present invention
  • FIG. 3 is a flowchart of a method for preparing a foamed ceramic lightweight board according to the present invention.
  • the present invention provides a roller kiln firing method of a foamed ceramic light board, including:
  • T 1 Heating up to T 1 , T 1 is 800-900 ° C., and holding at T 1 for 0-30 min, wherein the heating rate from 0 ° C. to 400 ° C. is 10-20 ° C./min, and from 400 ° C. to T a heating rate of 1-8 °C / min;
  • T 2 is 1150-1220 ° C., and the temperature is maintained at the highest temperature for 0-60 min. Among them, the temperature rising rate from T 1 to T 2 is 1-8 ° C./min;
  • the roller kiln firing method includes:
  • T 1 Heating up to T 1 , T 1 is 800-900 ° C., and holding at T 1 for 0-30 min, wherein the heating rate from 0 ° C. to 400 ° C. is 13-17 ° C./min, and from 400 ° C. to T The heating rate of 1 is 4-6 °C / min;
  • T 2 is 1150-1220 ° C., and the temperature is maintained at the highest temperature for 0-60 min. Among them, the temperature rising rate from T 1 to T 2 is 4-6 ° C./min;
  • the firing method of the roller kiln includes:
  • T 1 is 800-900 deg.] C, and incubated 0-30min T 1, wherein, heated from 0 °C to 400 deg.] C heating rate of 15 °C / min, heating from 400 °C to T 1 of Heating rate is 5 °C / min;
  • T 2 is 1150-1220 ° C., and the temperature is maintained at the highest temperature for 0-60 min. Among them, the temperature rising rate from T 1 to T 2 is 5 ° C./min;
  • the firing process of the present invention can achieve rapid low-temperature firing, greatly reducing the oxidation reaction stage time of the formula, shortening the firing cycle, increasing the output, and reducing the energy consumption per unit product.
  • the roller kiln firing method of the foamed ceramic light board adopts the roller kiln firing process, which not only improves the output, but also saves energy, and reduces the energy consumption per unit product by 10-30%.
  • the foamed ceramic light board is mainly made of the following weight percentages of raw materials: tile polishing waste 70-96%, clay 0-10%, feldspar 0-20%, foaming agent 0.01-0.6%, stabilizer 0.1-4%.
  • the foamed ceramic light board is mainly made of the following weight percentages of raw materials: 75-95% of tile polishing waste, 0.1-10% of clay, 0.1-20% of feldspar, and 0.1-0.4% of foaming agent.
  • Stabilizer 0.1-3%.
  • the stabilizer is manganese dioxide
  • the foaming agent is silicon carbide or a polishing head recycled material.
  • the invention increases the amount of tile polishing waste residue and reduces the amount of foaming agent.
  • the addition of 0.1-3% manganese dioxide stabilizer can improve the uniformity of air bubbles. Even in the same section, there is no difference in the pores from top to bottom, which makes the overall uniformity of the product good.
  • the pores in the entire cross section are round holes, and the size of the pores from the top to the bottom is basically the same.
  • Manganese dioxide is an amphoteric oxide, which is a very stable black powdery solid at room temperature. It appears oxidizing when it encounters a reducing agent, and it appears reducing when it encounters a strong oxidant.
  • the prior art generally uses manganese dioxide as an oxidant or catalyst.
  • manganese dioxide is used as a bubble stabilizer. After reacting with the formula, manganese dioxide can make the walls of the stomata firm, and at the same time, make the formula more homogeneous. There is no difference in the pores, which prevents the pores from being squashed, improves the uniformity of the bubbles, and the overall uniformity of the product is good.
  • the foaming agent is silicon carbide or a reclaimed polishing head.
  • the main components of the reclaimed polishing head include silicon carbide and a resin.
  • Silicon carbide is a foaming material.The presence of this material makes it not shrink like ordinary ceramics during firing, but expands, thereby making the lightweight and high-strength ceramic plate for construction smaller than traditional ceramics in size and thickness. Plates are easier to make large and thick.
  • the polishing grinder recycling material is added as the base material because the main components of the polishing grinder itself are silicon carbide and resin, and silicon carbide is the foaming agent added in the formulation of the invention, so the invention can add the amount of foaming agent Reduce to 0.1-0.4%, reduce the amount of foaming agent and reduce costs.
  • the tile polishing waste is introduced into the formula, which is not only conducive to environmental protection recycling, but also can make the foamed ceramic light board roll kiln firing method have a solid honeycomb-like hole structure inside. It has the advantages of environmental protection, light weight, convenient construction, and lightened building load.
  • the added amount of ceramic tile polishing waste of the present invention is much larger than the existing foamed ceramic plate, which reduces the cost and strengthens the recycling of solid waste.
  • the raw materials are added with clay and feldspar, that is, the ceramic light board is mainly made of the following weight percentages of raw materials:
  • Tile polishing residue is 75-95%, clay is 0.1-10%, feldspar is 0.1-20%, foaming agent is 0.1-0.4%, and stabilizer is 0.1-3%.
  • Clay is one or more of black mud, kaolin, municipal sludge, and sea mud.
  • the silicon, aluminum, potassium, and sodium component ratios in the base formulation can be adjusted to make the foamed brick wall harder and stronger, thereby further strengthening the recycling of solid waste.
  • the present invention breaks through the limitation that the traditional foamed ceramic plate can only be fired through a tunnel kiln, and can realize ordinary firing through a tunnel kiln or fast firing through a roller kiln.
  • roller kiln firing includes:
  • a box bowl is used on the roller kiln.
  • the box bowl is an integrated box bowl or a combined box bowl. It is manually or mechanically clothed and then fired at 1150-1220 ° C.
  • the assembled box comprises a support, a support plate, a surrounding plate, and a high-temperature paper.
  • the supporting plate is laid on the support, the surrounding plate is laid around the supporting plate, and the supporting plate and the surrounding plate are provided with all Mentioned high temperature paper.
  • the support is a SiC support
  • the support plate is a mullite support plate, a silicon carbide support plate, or a cordierite support plate
  • the surrounding plate is a mullite support plate, a silicon carbide support plate, or a cordierite support.
  • Board the high-temperature paper is aluminum silicate fiber paper.
  • the invention can use a roller kiln to achieve rapid firing (the period is about 12 hours), but the prior art can only use the tunnel kiln for firing (the period is 24-26 hours).
  • the present invention provides a method for preparing a foamed ceramic lightweight board, including:
  • the raw materials are mixed according to the ratio and ball-milled.
  • the ball milling powder may be a wet method powder or a dry method powder.
  • the wet milling method includes: adding raw materials with 30-40% water, and putting them into a ball mill for ball milling treatment, ball milling to a 250-mesh sieve and less than 1%, and then powdering through a spray tower to obtain a water content of 5- 10% powder.
  • the green body is fired through a roller kiln or a tunnel kiln to obtain a semi-finished product.
  • the semi-product is cut and ground to obtain a finished product.
  • the upper and lower surfaces of the green body need to be ground and the edges are cut.
  • the invention on the basis of solving the internal pores of the foamed ceramic light board, the invention also guarantees that it has good compressive strength, good thermal insulation effect, good flame retardancy and low radioactivity index.
  • the above raw materials are mixed according to the ratio, and they are sent to a ball mill for ball milling treatment, and sieved to a 250 mesh sieve with a screen balance of less than 1%, and then pass through the slurry storage tank and the transfer tank to the spray tower for spray granulation. Pass the material of the cart to the roller kiln for firing.
  • the firing method is as follows:
  • the above raw materials are mixed according to the ratio, and they are sent to a ball mill for ball milling treatment, and sieved to a 250 mesh sieve with a screen balance of less than 1%, and then pass through the slurry storage tank and the transfer tank to the spray tower for spray granulation to obtain the powder. Pass the material of the cart to the roller kiln for firing.
  • the firing method is as follows:
  • the above raw materials are mixed according to the ratio, and they are sent to a ball mill for ball milling treatment, and sieved to a 250 mesh sieve with a screen balance of less than 1%, and then pass through the slurry storage tank and the transfer tank to the spray tower for spray granulation to obtain the powder. Pass the material of the cart to the roller kiln for firing.
  • the firing method is as follows:
  • the above raw materials are mixed according to the ratio, and they are sent to a ball mill for ball milling treatment, and sieved to a 250 mesh sieve with a screen balance of less than 1%, and then pass through the slurry storage tank and the transfer tank to the spray tower for spray granulation. Pass the material of the cart to the roller kiln for firing.
  • the firing method is as follows:
  • the above raw materials are mixed according to the ratio, and they are sent to a ball mill for ball milling treatment, and sieved to a 250 mesh sieve with a screen balance of less than 1%, and then pass through the slurry storage tank and the transfer tank to the spray tower for spray granulation to obtain the powder. Pass the material of the cart to the roller kiln for firing.
  • the firing method is as follows:
  • the above raw materials are mixed according to the ratio, and they are sent to a ball mill for ball milling treatment, and sieved to a 250 mesh sieve with a screen balance of less than 1%, and then pass through the slurry storage tank and the transfer tank to the spray tower for spray granulation to obtain the powder. Pass the material of the trolley to the tunnel kiln for firing.
  • the firing method is as follows:

Abstract

A rolling kiln firing method for a foamed ceramic lightweight plate material, comprising: (1) heating to T1, T1 being 800-900 °C, holding at T1 for 0-30 min, where the heating rate for heating from 0 °C to 400 °C is 10-20 °C/min, and the heating rate for heating from 400 °C to T1 is 1-8 °C/min; (2) heating to T2, T2 being 1150-1220 °C, and holding at highest temperature for 0-60 min, where the heating rate for heating from T1 to T2 is 1-8 °C/min; (3) cooling slowly, the cooling rate for cooling from T2 to 600 °C being 3-9 °C/min, and the cooling rate for cooling from 600 °C to 50 °C being 1-4 °C/min.

Description

一种发泡陶瓷轻质板材的辊道窑烧成方法Roller kiln firing method of foamed ceramic light board 技术领域Technical field
本发明涉及陶瓷板技术领域,尤其涉及一种发泡陶瓷轻质板材的辊道窑烧成方法。The invention relates to the technical field of ceramic plates, in particular to a roller kiln firing method for foamed ceramic lightweight plates.
背景技术Background technique
发泡陶瓷所使用的基体材料来自于陶瓷厂废料和工业废料等废弃物(瓷砖抛光废渣或煤渣或石材废渣等),这些废弃物如若不处理,随意堆积或者填埋将对环境造成污染,也浪费了资源。The matrix material used in foamed ceramics comes from wastes from ceramics factories and industrial wastes (such as ceramic tile polishing residues or coal residues or stone waste residues). If these wastes are left untreated, random accumulation or landfill will cause pollution to the environment. Wasted resources.
该发泡陶瓷产品以其重量轻、强度高、防火、抗震、隔热、隔音、组合性强、易于搬运,适用面广等优点逐渐开始在全国范围内使用。又因其原料为煤渣、瓷砖抛光废渣、矿渣等固体废弃物,在资源充分利用和环境保护方面具有积极的社会意义。The foamed ceramic products gradually began to be used nationwide due to its advantages such as light weight, high strength, fire resistance, earthquake resistance, heat insulation, sound insulation, strong combination, easy handling, and wide application. And because its raw materials are solid waste such as coal slag, ceramic tile polishing slag, slag, etc., it has positive social significance in making full use of resources and environmental protection.
现有发泡陶瓷的配方体系一般包括瓷砖抛光废渣和发泡剂,瓷砖抛光废渣用量较少,大多为50%左右。发泡剂加入量在1.2%左右,加入量较多,成本较高。因为现有发泡砖整体砖块比较厚,配方体系比较难氧化,发泡陶瓷的配方体系决定其必须使用隧道窑烧成,隧道窑的烧成周期大概为24-26小时,烧成周期长,温度较高。The existing formulation system of foamed ceramics generally includes tile polishing waste residue and foaming agent, and the amount of tile polishing waste residue is relatively small, mostly about 50%. The amount of foaming agent added is about 1.2%, the amount of foaming agent is large, and the cost is high. Because the existing foamed bricks are relatively thick and the formula system is relatively difficult to oxidize, the formula system of foamed ceramics determines that they must be fired in a tunnel kiln. The firing cycle of the tunnel kiln is about 24-26 hours, and the firing cycle is long Higher temperature.
而且,如图1所示,现有技术制得的发泡陶瓷板,其内部形成多层气孔。在发泡的过程中,由于发泡时间较长,且受到重力的影响,下层气孔会被压扁,使得产品的整体均匀性不好。Moreover, as shown in FIG. 1, the foamed ceramic plate produced in the prior art has multiple layers of air holes formed therein. During the foaming process, due to the longer foaming time and the influence of gravity, the lower air pores will be flattened, making the overall uniformity of the product poor.
发明内容Summary of the invention
本发明所要解决的技术问题在于,提供一种发泡陶瓷轻质板材的辊道窑烧成方法,实现低温快烧,其烧成得到的发泡陶瓷轻质板材在同一断面上,从上到下气孔无差异,气泡均匀性高。The technical problem to be solved by the present invention is to provide a roller kiln firing method for foamed ceramic lightweight sheet material to achieve low-temperature fast firing. The foamed ceramic lightweight sheet material obtained by firing is on the same cross section, from top to bottom. There is no difference in lower stomata, and the uniformity of air bubbles is high.
为了解决上述技术问题,本发明提供了一种发泡陶瓷轻质板材的辊道窑烧成方法,包括:In order to solve the above technical problems, the present invention provides a roller kiln firing method for foamed ceramic light board, including:
(1)升温至T 1,T 1为800-900℃,并在T 1保温0-30min,其中,由0℃升温至400℃的升温速率为10-20℃/min,由400℃升温至T 1的升温速率为1-8℃/min; (1) The temperature is raised to T 1 , T 1 is 800-900 ° C., and the temperature is maintained at T 1 for 0-30 min. Among them, the temperature rising rate from 0 ° C. to 400 ° C. is 10-20 ° C./min, and from 400 ° C. to The heating rate of T 1 is 1-8 ℃ / min;
(2)升温至T 2,T 2为1150-1220℃,并在最高温保温0-60min,其中,由T 1升温至T 2的升温 速率为1-8℃/min; (2) The temperature is raised to T 2 , T 2 is 1150-1220 ° C., and the temperature is maintained at the highest temperature for 0-60 min. Among them, the temperature rising rate from T 1 to T 2 is 1-8 ° C./min;
(3)缓慢降温,由T 2降温至600℃的降温速率为3-9℃/min,由600℃降温至50℃的降温速率为1-4℃/min。 (3) Slow cooling, the cooling rate from T 2 to 600 ° C is 3-9 ° C / min, and the cooling rate from 600 ° C to 50 ° C is 1-4 ° C / min.
作为上述方案的改进,辊道窑烧成方法包括:As an improvement to the above scheme, the firing method of the roller kiln includes:
(1)升温至T 1,T 1为800-900℃,并在T 1保温0-30min,其中,由0℃升温至400℃的升温速率为13-17℃/min,由400℃升温至T 1的升温速率为4-6℃/min; (1) The temperature is raised to T 1 , T 1 is 800-900 ° C., and the temperature is maintained at T 1 for 0-30 min. Among them, the heating rate from 0 ° C. to 400 ° C. is 13-17 ° C./min, and from 400 ° C. to The heating rate of T 1 is 4-6 ℃ / min;
(2)升温至T 2,T 2为1150-1220℃,并在最高温保温0-60min,其中,由T 1升温至T 2的升温速率为4-6℃/min; (2) The temperature is raised to T 2 , T 2 is 1150-1220 ° C., and the temperature is maintained at the highest temperature for 0-60 min. Among them, the temperature rising rate from T 1 to T 2 is 4-6 ° C./min;
(3)缓慢降温,由T 2降温至600℃的降温速率为5-7℃/min,由600℃降温至50℃的降温速率为1-3℃/min。 (3) Slow cooling, the cooling rate from T 2 to 600 ° C is 5-7 ° C / min, and the cooling rate from 600 ° C to 50 ° C is 1-3 ° C / min.
作为上述方案的改进,辊道窑烧成方法包括:As an improvement of the above scheme, the firing method of the roller kiln includes:
(1)升温至T 1,T 1为800-900℃,并在T 1保温0-30min,其中,由0℃升温至400℃的升温速率为15℃/min,由400℃升温至T 1的升温速率为5℃/min; (1) The temperature is increased to T 1 , T 1 is 800-900 ° C., and the temperature is maintained at T 1 for 0-30 min. Among them, the temperature increase rate from 0 ° C. to 400 ° C. is 15 ° C./min, and from 400 ° C. to T 1 The heating rate is 5 ℃ / min;
(2)升温至T 2,T 2为1150-1220℃,并在最高温保温0-60min,其中,由T 1升温至T 2的升温速率为5℃/min; (2) The temperature is increased to T 2 , T 2 is 1150-1220 ° C., and the temperature is maintained at the highest temperature for 0-60 min. Among them, the temperature rising rate from T 1 to T 2 is 5 ° C./min;
(3)缓慢降温,由T 2降温至600℃的降温速率为6℃/min,由600℃降温至50℃的降温速率为2℃/min。 (3) Slow cooling, the cooling rate from T 2 to 600 ° C is 6 ° C / min, and the cooling rate from 600 ° C to 50 ° C is 2 ° C / min.
作为上述方案的改进,所述发泡陶瓷轻质板材主要由下述重量百分比的原料制成:As an improvement to the above scheme, the foamed ceramic lightweight board is mainly made of the following weight percentages of raw materials:
瓷砖抛光废渣70-96%、粘土0-10%、长石0-20%、发泡剂0.01-0.6%、稳定剂0.1-4%;Tile polishing residue 70-96%, clay 0-10%, feldspar 0-20%, foaming agent 0.01-0.6%, stabilizer 0.1-4%;
所述稳定剂为二氧化锰。The stabilizer is manganese dioxide.
作为上述方案的改进,所述发泡陶瓷轻质板材主要由下述重量百分比的原料制成:As an improvement to the above scheme, the foamed ceramic lightweight board is mainly made of the following weight percentages of raw materials:
瓷砖抛光废渣75-95%、粘土0.1-10%、长石0.1-20%、发泡剂0.1-0.4%、稳定剂0.1-3%。Tile polishing residue is 75-95%, clay is 0.1-10%, feldspar is 0.1-20%, foaming agent is 0.1-0.4%, and stabilizer is 0.1-3%.
作为上述方案的改进,所述粘土为黑泥、高岭土、城市污泥、海泥中的一种或多种。As an improvement of the above scheme, the clay is one or more of black mud, kaolin, urban sludge, and sea mud.
作为上述方案的改进,所述发泡剂为碳化硅或抛光磨头回收料,所述抛光磨头回收料的主要成分包括碳化硅和树脂。As an improvement of the foregoing solution, the foaming agent is silicon carbide or a polishing head recycled material, and the main components of the polishing head recycled material include silicon carbide and a resin.
作为上述方案的改进,所述辊道窑烧成包括:As an improvement to the above solution, the roller kiln firing includes:
辊道窑上使用匣钵,匣钵为一体式匣钵或拼装式匣钵,利用人工或机器布料,然后在1150-1220℃的条件下进行烧成。A box bowl is used on the roller kiln. The box bowl is an integrated box bowl or a combined box bowl. It is manually or mechanically clothed and then fired at 1150-1220 ° C.
作为上述方案的改进,所述拼装式匣钵包括支架、垫板、围板和高温纸,所述垫板铺 设在支架上,所述围板搭设在垫板的四周,所述垫板和围板上均设有所述高温纸。As an improvement to the above solution, the assembled box bowl includes a support, a support plate, a surrounding plate and high-temperature paper, the supporting plate is laid on the support, the surrounding plate is erected around the supporting plate, and the supporting plate and the surrounding plate The boards are all provided with the high-temperature paper.
作为上述方案的改进,所述支架为SiC支架;As an improvement of the foregoing solution, the stent is a SiC stent;
所述垫板为莫来石垫板、碳化硅垫板或堇青石垫板;The pad is a mullite pad, a silicon carbide pad or a cordierite pad;
所述围板为莫来石围板、碳化硅围板或堇青石围板;The enclosure is a mullite enclosure, a silicon carbide enclosure or a cordierite enclosure;
所述高温纸为硅酸铝纤维纸。The high-temperature paper is aluminum silicate fiber paper.
实施本发明,具有如下有益效果:The implementation of the present invention has the following beneficial effects:
本发明设计了一个全新的发泡陶瓷轻质板材的辊道窑烧成方法,实现低温快烧,大大减少了配方的氧化反应阶段时间,缩短了烧成周期,提高了产量,降低了单位产品的能耗。The invention designs a new roller kiln firing method for foamed ceramic light board, which realizes fast firing at low temperature, greatly reducing the oxidation reaction stage time of the formula, shortening the firing cycle, increasing the yield, and reducing the unit product. Energy consumption.
所述发泡陶瓷轻质板材包括瓷砖抛光废渣70-96%、发泡剂0.01-0.6%、稳定剂0.1-4%,其增加了瓷砖抛光废渣的加入量,瓷砖抛光废渣的加入量最高可达96%,同时将发泡剂的加入量减少至0.01-0.6%。在这基础上,加入0.1-4%的二氧化锰稳定剂,可以提高气泡的均匀性,即使在同一断面,从上到下的气孔无差异,使得产品的整体均匀性好。The foamed ceramic light board comprises 70-96% of tile polishing waste, 0.01-0.6% of foaming agent, and 0.1-4% of stabilizer, which increases the amount of tile polishing waste added, and the maximum amount of tile polishing waste added can be Up to 96%, while reducing the amount of foaming agent added to 0.01-0.6%. On this basis, the addition of 0.1-4% manganese dioxide stabilizer can improve the uniformity of air bubbles. Even in the same section, there is no difference in pores from top to bottom, which makes the overall uniformity of the product good.
本发明制得的发泡陶瓷轻质板材质量优异,抗压强度≥5Mpa,体积密度:200-1100Kg/m 3,抗折强度:>4Mpa,导热系数:≤0.15W/m℃,燃烧等级:A1级,吸水率:<2%,放射性指标:I Ra≤1.0,I r≤1.0。 The foamed ceramic lightweight board prepared by the invention has excellent quality, compressive strength ≥5Mpa, bulk density: 200-1100Kg / m 3 , flexural strength:> 4Mpa, thermal conductivity: ≤0.15W / m ° C, combustion level: A1 grade, water absorption: <2%, radioactivity index: I Ra ≤ 1.0, I r ≤ 1.0.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1是现有技术发泡陶瓷轻质板材的辊道窑烧成方法的截面图;1 is a cross-sectional view of a roller kiln firing method of a prior art foamed ceramic light board;
图2是本发明发泡陶瓷轻质板材的辊道窑烧成方法的流程图;2 is a flow chart of a roller kiln firing method of the foamed ceramic light board of the present invention;
图3是本发明发泡陶瓷轻质板材的制备方法的流程图。FIG. 3 is a flowchart of a method for preparing a foamed ceramic lightweight board according to the present invention.
具体实施方式detailed description
为使本发明的目的、技术方案和优点更加清楚,下面将结合附图对本发明作进一步地详细描述。To make the objectives, technical solutions, and advantages of the present invention clearer, the present invention will be described in further detail below with reference to the accompanying drawings.
如图2所示,本发明提供一种发泡陶瓷轻质板材的辊道窑烧成方法,包括:As shown in FIG. 2, the present invention provides a roller kiln firing method of a foamed ceramic light board, including:
S201、升温至T 1,T 1为800-900℃,并在T 1保温0-30min,其中,由0℃升温至400℃的升温速率为10-20℃/min,由400℃升温至T 1的升温速率为1-8℃/min; S201. Heating up to T 1 , T 1 is 800-900 ° C., and holding at T 1 for 0-30 min, wherein the heating rate from 0 ° C. to 400 ° C. is 10-20 ° C./min, and from 400 ° C. to T a heating rate of 1-8 ℃ / min;
S202、升温至T 2,T 2为1150-1220℃,并在最高温保温0-60min,其中,由T 1升温至T 2的升温速率为1-8℃/min; S202. The temperature is raised to T 2 , T 2 is 1150-1220 ° C., and the temperature is maintained at the highest temperature for 0-60 min. Among them, the temperature rising rate from T 1 to T 2 is 1-8 ° C./min;
S203、缓慢降温,由T 2降温至600℃的降温速率为3-9℃/min,由600℃降温至50℃的降温速率为1-4℃/min。 S203. Slowly cool down, the cooling rate from T 2 to 600 ° C is 3-9 ° C / min, and the cooling rate from 600 ° C to 50 ° C is 1-4 ° C / min.
优选的,辊道窑烧成方法包括:Preferably, the roller kiln firing method includes:
S201、升温至T 1,T 1为800-900℃,并在T 1保温0-30min,其中,由0℃升温至400℃的升温速率为13-17℃/min,由400℃升温至T 1的升温速率为4-6℃/min; S201. Heating up to T 1 , T 1 is 800-900 ° C., and holding at T 1 for 0-30 min, wherein the heating rate from 0 ° C. to 400 ° C. is 13-17 ° C./min, and from 400 ° C. to T The heating rate of 1 is 4-6 ℃ / min;
S202、升温至T 2,T 2为1150-1220℃,并在最高温保温0-60min,其中,由T 1升温至T 2的升温速率为4-6℃/min; S202. The temperature is raised to T 2 , T 2 is 1150-1220 ° C., and the temperature is maintained at the highest temperature for 0-60 min. Among them, the temperature rising rate from T 1 to T 2 is 4-6 ° C./min;
S203、缓慢降温,由T 2降温至600℃的降温速率为5-7℃/min,由600℃降温至50℃的降温速率为1-3℃/min。 S203. Slowly cool down, the cooling rate from T 2 to 600 ° C is 5-7 ° C / min, and the cooling rate from 600 ° C to 50 ° C is 1-3 ° C / min.
更佳的,辊道窑烧成方法包括:More preferably, the firing method of the roller kiln includes:
S201、升温至T 1,T 1为800-900℃,并在T 1保温0-30min,其中,由0℃升温至400℃的升温速率为15℃/min,由400℃升温至T 1的升温速率为5℃/min; S201, warmed to T 1, T 1 is 800-900 deg.] C, and incubated 0-30min T 1, wherein, heated from 0 ℃ to 400 deg.] C heating rate of 15 ℃ / min, heating from 400 ℃ to T 1 of Heating rate is 5 ℃ / min;
S202、升温至T 2,T 2为1150-1220℃,并在最高温保温0-60min,其中,由T 1升温至T 2的升温速率为5℃/min; S202. The temperature is raised to T 2 , T 2 is 1150-1220 ° C., and the temperature is maintained at the highest temperature for 0-60 min. Among them, the temperature rising rate from T 1 to T 2 is 5 ° C./min;
S203、缓慢降温,由T 2降温至600℃的降温速率为6℃/min,由600℃降温至50℃的降温速率为2℃/min。 S203. Slowly cool down, the cooling rate from T 2 to 600 ° C is 6 ° C / min, and the cooling rate from 600 ° C to 50 ° C is 2 ° C / min.
与现有技术相比,本发明的烧成工艺可以实现低温快速烧成,将配方的氧化反应阶段时间大大降低,烧成周期缩短,产量提高,单位产品的能耗降低。该发泡陶瓷轻质板材的辊道窑烧成方法采用辊道窑烧成工艺不仅提高了产量,还节约了能源,单位产品能耗降低10-30%。Compared with the prior art, the firing process of the present invention can achieve rapid low-temperature firing, greatly reducing the oxidation reaction stage time of the formula, shortening the firing cycle, increasing the output, and reducing the energy consumption per unit product. The roller kiln firing method of the foamed ceramic light board adopts the roller kiln firing process, which not only improves the output, but also saves energy, and reduces the energy consumption per unit product by 10-30%.
所述发泡陶瓷轻质板材主要由下述重量百分比的原料制成:瓷砖抛光废渣70-96%、粘土0-10%、长石0-20%、发泡剂0.01-0.6%、稳定剂0.1-4%。优选的,所述发泡陶瓷轻质板材主要由下述重量百分比的原料制成:瓷砖抛光废渣75-95%、粘土0.1-10%、长石0.1-20%、发泡剂0.1-0.4%、稳定剂0.1-3%。其中,所述稳定剂为二氧化锰,所述发泡剂为碳化硅或抛光磨头回收料。The foamed ceramic light board is mainly made of the following weight percentages of raw materials: tile polishing waste 70-96%, clay 0-10%, feldspar 0-20%, foaming agent 0.01-0.6%, stabilizer 0.1-4%. Preferably, the foamed ceramic light board is mainly made of the following weight percentages of raw materials: 75-95% of tile polishing waste, 0.1-10% of clay, 0.1-20% of feldspar, and 0.1-0.4% of foaming agent. Stabilizer 0.1-3%. Wherein, the stabilizer is manganese dioxide, and the foaming agent is silicon carbide or a polishing head recycled material.
本发明增加了瓷砖抛光废渣的加入量,同时降低发泡剂的加入量。在这基础上,加入0.1-3%的二氧化锰稳定剂,可以提高气泡的均匀性,即使在同一断面,从上到下的气孔无差异,使得产品的整体均匀性好。发泡陶瓷轻质板材的辊道窑烧成方法整体断面的气孔均为圆孔,且从上到下的气孔尺寸基本一致,烧成的孔径均匀性好。The invention increases the amount of tile polishing waste residue and reduces the amount of foaming agent. On this basis, the addition of 0.1-3% manganese dioxide stabilizer can improve the uniformity of air bubbles. Even in the same section, there is no difference in the pores from top to bottom, which makes the overall uniformity of the product good. In the roller kiln firing method of foamed ceramic light board, the pores in the entire cross section are round holes, and the size of the pores from the top to the bottom is basically the same.
二氧化锰是两性氧化物,它是一种常温下非常稳定的黑色粉末状固体。遇还原剂时,表现为氧化性,遇强氧化剂时,表现为还原性。现有技术通常将二氧化锰作为氧化剂或催化剂使用。本发明将二氧化锰作为气泡稳定剂使用,二氧化锰可以通过与配方的反应后,使气孔的壁变得结实,同时使配方的均匀性更好,即使在同一断面,从上到下的孔也无差异,避免气孔被压扁,提高气泡的均匀性,产品的整体均匀性好。Manganese dioxide is an amphoteric oxide, which is a very stable black powdery solid at room temperature. It appears oxidizing when it encounters a reducing agent, and it appears reducing when it encounters a strong oxidant. The prior art generally uses manganese dioxide as an oxidant or catalyst. In the present invention, manganese dioxide is used as a bubble stabilizer. After reacting with the formula, manganese dioxide can make the walls of the stomata firm, and at the same time, make the formula more homogeneous. There is no difference in the pores, which prevents the pores from being squashed, improves the uniformity of the bubbles, and the overall uniformity of the product is good.
所述发泡剂为碳化硅或抛光磨头回收料,所述抛光磨头回收料的主要成分包括碳化硅和树脂。碳化硅是一种发泡材料,该材料的存在,使其在烧制过程中不像普通陶瓷一样收缩,反而是膨胀的,从而使建筑用轻质高强陶瓷板在尺寸和厚度上比传统陶瓷板更加容易做到大而厚。抛光磨头回收料作为基底原料添加,是因为抛光磨头本身主要成分就是碳化硅和树脂,而碳化硅正是本发明配方中添加的发泡剂,所以本发明可以将发泡剂的加入量减少至0.1-0.4%,降低发泡剂的用量,降低成本。The foaming agent is silicon carbide or a reclaimed polishing head. The main components of the reclaimed polishing head include silicon carbide and a resin. Silicon carbide is a foaming material.The presence of this material makes it not shrink like ordinary ceramics during firing, but expands, thereby making the lightweight and high-strength ceramic plate for construction smaller than traditional ceramics in size and thickness. Plates are easier to make large and thick. The polishing grinder recycling material is added as the base material because the main components of the polishing grinder itself are silicon carbide and resin, and silicon carbide is the foaming agent added in the formulation of the invention, so the invention can add the amount of foaming agent Reduce to 0.1-0.4%, reduce the amount of foaming agent and reduce costs.
同时,配方中引入75-95%的瓷砖抛光废渣,既有利于环保循环利用,也可以使得发泡陶瓷轻质板材的辊道窑烧成方法烧结后内部具有坚固的类似蜂窝状的孔洞结构,具有绿色环保、质轻、方便施工、减轻建筑负载等优点。本发明瓷砖抛光废渣的加入量远远大于现有的发泡陶瓷板,降低成本,加强对固废物的回收利用。At the same time, 75-95% of the tile polishing waste is introduced into the formula, which is not only conducive to environmental protection recycling, but also can make the foamed ceramic light board roll kiln firing method have a solid honeycomb-like hole structure inside. It has the advantages of environmental protection, light weight, convenient construction, and lightened building load. The added amount of ceramic tile polishing waste of the present invention is much larger than the existing foamed ceramic plate, which reduces the cost and strengthens the recycling of solid waste.
作为本发明更佳的实施方式,其原料加入粘土和长石,即所述陶瓷轻质板材主要由下述重量百分比的原料制成:As a better embodiment of the present invention, the raw materials are added with clay and feldspar, that is, the ceramic light board is mainly made of the following weight percentages of raw materials:
瓷砖抛光废渣75-95%、粘土0.1-10%、长石0.1-20%、发泡剂0.1-0.4%、稳定剂0.1-3%。粘土为黑泥、高岭土、城市污泥、海泥中的一种或多种。Tile polishing residue is 75-95%, clay is 0.1-10%, feldspar is 0.1-20%, foaming agent is 0.1-0.4%, and stabilizer is 0.1-3%. Clay is one or more of black mud, kaolin, municipal sludge, and sea mud.
本发明原料加入粘土和长石,可以调整基底配方中的硅、铝、钾、钠成分比,使发泡砖壁更硬,强度更高,从而进一步加强对固废物的回收利用。By adding clay and feldspar to the raw materials of the present invention, the silicon, aluminum, potassium, and sodium component ratios in the base formulation can be adjusted to make the foamed brick wall harder and stronger, thereby further strengthening the recycling of solid waste.
由于采用了全新的配方体系,本发明突破了传统发泡陶瓷板只能通过隧道窑烧成的局限,既可以通过隧道窑实现普通烧成,也可以通过辊道窑实现快速烧成。Because of adopting a new formula system, the present invention breaks through the limitation that the traditional foamed ceramic plate can only be fired through a tunnel kiln, and can realize ordinary firing through a tunnel kiln or fast firing through a roller kiln.
具体的,所述辊道窑烧成包括:Specifically, the roller kiln firing includes:
辊道窑上使用匣钵,匣钵为一体式匣钵或拼装式匣钵,利用人工或机器布料,然后在1150-1220℃的条件下进行烧成。所述拼装式匣钵包括支架、垫板、围板和高温纸,所述垫板铺设在支架上,所述围板搭设在垫板的四周,所述垫板和围板上均设有所述高温纸。优选的,所述支架为SiC支架;所述垫板为莫来石垫板、碳化硅垫板或堇青石垫板;所述围板为莫来石围板、碳化硅围板或堇青石围板;所述高温纸为硅酸铝纤维纸。A box bowl is used on the roller kiln. The box bowl is an integrated box bowl or a combined box bowl. It is manually or mechanically clothed and then fired at 1150-1220 ° C. The assembled box comprises a support, a support plate, a surrounding plate, and a high-temperature paper. The supporting plate is laid on the support, the surrounding plate is laid around the supporting plate, and the supporting plate and the surrounding plate are provided with all Mentioned high temperature paper. Preferably, the support is a SiC support; the support plate is a mullite support plate, a silicon carbide support plate, or a cordierite support plate; and the surrounding plate is a mullite support plate, a silicon carbide support plate, or a cordierite support. Board; the high-temperature paper is aluminum silicate fiber paper.
本发明能够使用辊道窑实现快速烧成(周期为12小时左右),而现有技术都只能使用隧道窑烧成(周期为24—26小时)。The invention can use a roller kiln to achieve rapid firing (the period is about 12 hours), but the prior art can only use the tunnel kiln for firing (the period is 24-26 hours).
相应的,如图3所示,本发明提供一种发泡陶瓷轻质板材的制备方法,包括:Accordingly, as shown in FIG. 3, the present invention provides a method for preparing a foamed ceramic lightweight board, including:
S101、将原料按配比混料,并球磨制粉;S101. The raw materials are mixed according to the ratio and ball-milled.
所述球磨制粉可以是湿法制粉,也可以是干法制粉。所述湿法制粉包括:将原料加30-40%的水,放入球磨机中进行球磨处理,球磨至250目筛筛余小于1%,再经过喷雾塔制粉,得到含水率为5-10%的粉料。The ball milling powder may be a wet method powder or a dry method powder. The wet milling method includes: adding raw materials with 30-40% water, and putting them into a ball mill for ball milling treatment, ball milling to a 250-mesh sieve and less than 1%, and then powdering through a spray tower to obtain a water content of 5- 10% powder.
S102、将粉料进行布料,得到坯体;S102: distribute the powder to obtain a green body;
S103、将坯体通过辊道窑或隧道窑进行烧成,得到半成品;S103. The green body is fired through a roller kiln or a tunnel kiln to obtain a semi-finished product.
S104、将半产品经过切割磨削,得到成品。S104. The semi-product is cut and ground to obtain a finished product.
烧成后,还需要对坯体上下表面采用磨削处理,边缘采用切割处理。After firing, the upper and lower surfaces of the green body need to be ground and the edges are cut.
将本发明发泡陶瓷轻质板材做技术检测,结果如下:The technical inspection of the foamed ceramic lightweight board of the present invention has the following results:
项目project 本发明this invention
抗压强度Compressive strength ≥4.5Mpa≥4.5Mpa
体积密度Bulk Density 200-1100Kg/m 3 200-1100Kg / m 3
导热系数Thermal Conductivity ≤0.15W/m℃≤0.15W / m ℃
燃烧等级Burning level A1级A1 level
吸水率Water absorption <2%<2%
放射性指标Radioactive index I Ra≤1.0,I r≤1.0 I Ra ≤1.0, I r ≤1.0
因此,本发明在解决发泡陶瓷轻质板材的内部气孔的基础上,还保证了其具有良好的抗压强度,且保温效果好,阻燃性好,放射性指标低。Therefore, on the basis of solving the internal pores of the foamed ceramic light board, the invention also guarantees that it has good compressive strength, good thermal insulation effect, good flame retardancy and low radioactivity index.
下面以具体实施例进一步阐述本发明The present invention is further explained in the following specific examples.
实施例1Example 1
(1)配方:瓷砖抛光废渣95.5%、发泡剂0.5%、二氧化锰稳定剂4%。(1) Formula: 95.5% ceramic tile polishing residue, 0.5% foaming agent, 4% manganese dioxide stabilizer.
(2)制备方法:(2) Preparation method:
将上述原料按配比混料,将其输送至球磨机进行球磨处理,并筛分至250目筛筛余小于1%,然后通过储浆池、中转池到达喷雾塔进行喷雾造粒,得到的粉料通过料车布料,进入辊道窑烧成,烧成方法如下:The above raw materials are mixed according to the ratio, and they are sent to a ball mill for ball milling treatment, and sieved to a 250 mesh sieve with a screen balance of less than 1%, and then pass through the slurry storage tank and the transfer tank to the spray tower for spray granulation. Pass the material of the cart to the roller kiln for firing. The firing method is as follows:
(a)升温至800℃,并在800℃保温20min,其中,由0℃升温至400℃的升温速率为10℃ /min,由400℃升温至800℃的升温速率为3℃/min;(a) The temperature is increased to 800 ° C, and the temperature is maintained at 800 ° C for 20 minutes, wherein the temperature increase rate from 0 ° C to 400 ° C is 10 ° C / min, and the temperature increase rate from 400 ° C to 800 ° C is 3 ° C / min;
(b)升温至1150℃,并在最高温保温40min,其中,由800℃升温至1150℃的升温速率为3℃/min;(b) The temperature is increased to 1150 ° C, and the temperature is maintained at the highest temperature for 40 minutes, wherein the temperature increase rate from 800 ° C to 1150 ° C is 3 ° C / min;
(c)缓慢降温,由1150℃降温至600℃的降温速率为3℃/min,由600℃降温至50℃的降温速率为1℃/min。(c) Slow cooling, the cooling rate from 1150 ° C to 600 ° C is 3 ° C / min, and the cooling rate from 600 ° C to 50 ° C is 1 ° C / min.
最后经过切割磨削,得到成品。Finally, after cutting and grinding, the finished product is obtained.
实施例2Example 2
(1)配方:瓷砖抛光废渣90%、粘土1%、长石8.8%、发泡剂0.1%、二氧化锰稳定剂0.1%。(1) Formula: 90% of tile polishing residue, 1% of clay, 8.8% of feldspar, 0.1% of foaming agent, 0.1% of manganese dioxide stabilizer.
(2)制备方法:(2) Preparation method:
将上述原料按配比混料,将其输送至球磨机进行球磨处理,并筛分至250目筛筛余小于1%,然后通过储浆池、中转池到达喷雾塔进行喷雾造粒,得到的粉料通过料车布料,进入辊道窑烧成,烧成方法如下:The above raw materials are mixed according to the ratio, and they are sent to a ball mill for ball milling treatment, and sieved to a 250 mesh sieve with a screen balance of less than 1%, and then pass through the slurry storage tank and the transfer tank to the spray tower for spray granulation to obtain the powder. Pass the material of the cart to the roller kiln for firing. The firing method is as follows:
(a)升温至820℃,并在820℃保温15min,其中,由0℃升温至400℃的升温速率为15℃/min,由400℃升温至820℃的升温速率为5℃/min;(a) The temperature is increased to 820 ° C, and the temperature is maintained at 820 ° C for 15 minutes, wherein the temperature increase rate from 0 ° C to 400 ° C is 15 ° C / min, and the temperature increase rate from 400 ° C to 820 ° C is 5 ° C / min;
(b)升温至1170,并在最高温保温30min,其中,由820℃升温至1170℃的升温速率为4℃/min;(b) The temperature is increased to 1170, and the temperature is maintained at the highest temperature for 30 minutes, wherein the temperature increase rate from 820 ° C to 1170 ° C is 4 ° C / min;
(c)缓慢降温,由1170℃降温至600℃的降温速率为4℃/min,由600℃降温至50℃的降温速率为2℃/min。(c) Slow cooling, the cooling rate from 1170 ° C to 600 ° C is 4 ° C / min, and the cooling rate from 600 ° C to 50 ° C is 2 ° C / min.
最后经过切割磨削,得到成品。Finally, after cutting and grinding, the finished product is obtained.
实施例3Example 3
(1)配方:瓷砖抛光废渣92%、粘土5%、长石2%、发泡剂0.2%、二氧化锰稳定剂0.8%。(1) Formula: 92% of ceramic tile polishing residue, 5% of clay, 2% of feldspar, 0.2% of foaming agent, 0.8% of manganese dioxide stabilizer.
(2)制备方法:(2) Preparation method:
将上述原料按配比混料,将其输送至球磨机进行球磨处理,并筛分至250目筛筛余小于1%,然后通过储浆池、中转池到达喷雾塔进行喷雾造粒,得到的粉料通过料车布料,进入辊道窑烧成,烧成方法如下:The above raw materials are mixed according to the ratio, and they are sent to a ball mill for ball milling treatment, and sieved to a 250 mesh sieve with a screen balance of less than 1%, and then pass through the slurry storage tank and the transfer tank to the spray tower for spray granulation to obtain the powder. Pass the material of the cart to the roller kiln for firing. The firing method is as follows:
(a)升温至830℃,并在830℃保温25min,其中,由0℃升温至400℃的升温速率为15℃/min,由400℃升温至830℃的升温速率为5℃/min;(a) The temperature is increased to 830 ° C, and the temperature is maintained at 830 ° C for 25 minutes, wherein the temperature increase rate from 0 ° C to 400 ° C is 15 ° C / min, and the temperature increase rate from 400 ° C to 830 ° C is 5 ° C / min;
(b)升温至1180℃,并在最高温保温0-60min,其中,由830℃升温至1180℃的升温速率 为5℃/min;(b) The temperature is raised to 1180 ° C, and the temperature is maintained at the highest temperature for 0-60min, wherein the temperature increase rate from 830 ° C to 1180 ° C is 5 ° C / min;
(c)缓慢降温,由1180℃降温至600℃的降温速率为5℃/min,由600℃降温至50℃的降温速率为2℃/min。(c) Slow cooling, the cooling rate from 1180 ° C to 600 ° C is 5 ° C / min, and the cooling rate from 600 ° C to 50 ° C is 2 ° C / min.
最后经过切割磨削,得到成品。Finally, after cutting and grinding, the finished product is obtained.
实施例4Example 4
(1)配方:瓷砖抛光废渣88%、粘土2%、长石8%、发泡剂0.1%、二氧化锰稳定剂1.9%。(1) Formula: 88% of tile polishing waste, 2% of clay, 8% of feldspar, 0.1% of foaming agent, and 1.9% of manganese dioxide stabilizer.
(2)制备方法:(2) Preparation method:
将上述原料按配比混料,将其输送至球磨机进行球磨处理,并筛分至250目筛筛余小于1%,然后通过储浆池、中转池到达喷雾塔进行喷雾造粒,得到的粉料通过料车布料,进入辊道窑烧成,烧成方法如下:The above raw materials are mixed according to the ratio, and they are sent to a ball mill for ball milling treatment, and sieved to a 250 mesh sieve with a screen balance of less than 1%, and then pass through the slurry storage tank and the transfer tank to the spray tower for spray granulation. Pass the material of the cart to the roller kiln for firing. The firing method is as follows:
(a)升温至850℃,并在850℃保温30min,其中,由0℃升温至400℃的升温速率为16℃/min,由400℃升温至850℃的升温速率为5℃/min;(a) The temperature is increased to 850 ° C, and the temperature is maintained at 850 ° C for 30 minutes, wherein the temperature increase rate from 0 ° C to 400 ° C is 16 ° C / min, and the temperature increase rate from 400 ° C to 850 ° C is 5 ° C / min;
(b)升温至1200℃,并在最高温保温50min,其中,由850℃升温至1200℃的升温速率为5℃/min;(b) The temperature is increased to 1200 ° C, and the temperature is maintained at the highest temperature for 50 minutes, wherein the temperature increase rate from 850 ° C to 1200 ° C is 5 ° C / min;
(c)缓慢降温,由1200℃降温至600℃的降温速率为6℃/min,由600℃降温至50℃的降温速率为2℃/min。(c) Slow cooling, the cooling rate from 1200 ° C to 600 ° C is 6 ° C / min, and the cooling rate from 600 ° C to 50 ° C is 2 ° C / min.
最后经过切割磨削,得到成品。Finally, after cutting and grinding, the finished product is obtained.
实施例5Example 5
(1)配方:瓷砖抛光废渣80%、粘土10%、长石7.7%、发泡剂0.3%、二氧化锰稳定剂2%。(1) Formula: 80% of tile polishing waste, 10% of clay, 7.7% of feldspar, 0.3% of foaming agent, and 2% of manganese dioxide stabilizer.
(2)制备方法:(2) Preparation method:
将上述原料按配比混料,将其输送至球磨机进行球磨处理,并筛分至250目筛筛余小于1%,然后通过储浆池、中转池到达喷雾塔进行喷雾造粒,得到的粉料通过料车布料,进入辊道窑烧成,烧成方法如下:The above raw materials are mixed according to the ratio, and they are sent to a ball mill for ball milling treatment, and sieved to a 250 mesh sieve with a screen balance of less than 1%, and then pass through the slurry storage tank and the transfer tank to the spray tower for spray granulation to obtain the powder. Pass the material of the cart to the roller kiln for firing. The firing method is as follows:
(a)升温至860℃,并在860℃保温10min,其中,由0℃升温至400℃的升温速率为17℃/min,由400℃升温至860℃的升温速率为6℃/min;(a) The temperature is increased to 860 ° C, and the temperature is maintained at 860 ° C for 10 minutes, wherein the temperature increase rate from 0 ° C to 400 ° C is 17 ° C / min, and the temperature increase rate from 400 ° C to 860 ° C is 6 ° C / min;
(b)升温至1210℃,并在最高温保温30min,其中,由860℃升温至1210℃的升温速率为5℃/min;(b) The temperature is increased to 1210 ° C, and the temperature is maintained at the highest temperature for 30 minutes, wherein the temperature increase rate from 860 ° C to 1210 ° C is 5 ° C / min;
(c)缓慢降温,由1210℃降温至600℃的降温速率为6℃/min,由600℃降温至50℃的 降温速率为2℃/min。(c) Slow cooling, the cooling rate from 1210 ° C to 600 ° C is 6 ° C / min, and the cooling rate from 600 ° C to 50 ° C is 2 ° C / min.
最后经过切割磨削,得到成品。Finally, after cutting and grinding, the finished product is obtained.
实施例6Example 6
(1)配方:瓷砖抛光废渣75%、粘土1.6%、长石20%、发泡剂0.4%、稳定剂3%。(1) Formula: 75% of tile polishing waste, 1.6% of clay, 20% of feldspar, 0.4% of foaming agent, and 3% of stabilizer.
(2)制备方法:(2) Preparation method:
将上述原料按配比混料,将其输送至球磨机进行球磨处理,并筛分至250目筛筛余小于1%,然后通过储浆池、中转池到达喷雾塔进行喷雾造粒,得到的粉料通过料车布料,进入隧道窑烧成,烧成方法如下:The above raw materials are mixed according to the ratio, and they are sent to a ball mill for ball milling treatment, and sieved to a 250 mesh sieve with a screen balance of less than 1%, and then pass through the slurry storage tank and the transfer tank to the spray tower for spray granulation to obtain the powder. Pass the material of the trolley to the tunnel kiln for firing. The firing method is as follows:
(a)升温至900℃,并在900℃保温30min,其中,由0℃升温至400℃的升温速率为20℃/min,由400℃升温至900℃的升温速率为8℃/min;(a) The temperature is increased to 900 ° C, and the temperature is maintained at 900 ° C for 30 minutes, wherein the temperature increase rate from 0 ° C to 400 ° C is 20 ° C / min, and the temperature increase rate from 400 ° C to 900 ° C is 8 ° C / min;
(b)升温至1220℃,并在最高温保温60min,其中,由900℃升温至1220℃的升温速率为8℃/min;(b) The temperature is raised to 1220 ° C, and the temperature is maintained at the highest temperature for 60 minutes, wherein the temperature increase rate from 900 ° C to 1220 ° C is 8 ° C / min;
(c)缓慢降温,由1220℃降温至600℃的降温速率为9℃/min,由600℃降温至50℃的降温速率为4℃/min。(c) Slow cooling, the cooling rate from 1220 ° C to 600 ° C is 9 ° C / min, and the cooling rate from 600 ° C to 50 ° C is 4 ° C / min.
最后经过切割磨削,得到成品。Finally, after cutting and grinding, the finished product is obtained.
将实施例1-6所得的发泡陶瓷轻质板材做技术检测,结果如下:The technical inspection of the foamed ceramic lightweight plate obtained in Examples 1-6 is as follows:
Figure PCTCN2018100133-appb-000001
Figure PCTCN2018100133-appb-000001
Figure PCTCN2018100133-appb-000002
Figure PCTCN2018100133-appb-000002
最后所应当说明的是,以上实施例仅用以说明本发明的技术方案而非对本发明保护范围的限制,尽管参照较佳实施例对本发明作了详细说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的实质和范围。Finally, it should be explained that the above embodiments are only used to illustrate the technical solution of the present invention and not to limit the protection scope of the present invention. Although the present invention has been described in detail with reference to the preferred embodiments, those skilled in the art should understand that Modifications or equivalent substitutions may be made to the technical solution of the present invention without departing from the spirit and scope of the technical solution of the present invention.

Claims (10)

  1. 一种发泡陶瓷轻质板材的辊道窑烧成方法,其特征在于,包括:A roller kiln firing method for a foamed ceramic light board is characterized in that it includes:
    (1)升温至T 1,T 1为800-900℃,并在T 1保温0-30min,其中,由0℃升温至400℃的升温速率为10-20℃/min,由400℃升温至T 1的升温速率为1-8℃/min; (1) The temperature is raised to T 1 , T 1 is 800-900 ° C., and the temperature is maintained at T 1 for 0-30 min. Among them, the temperature rising rate from 0 ° C. to 400 ° C. is 10-20 ° C./min, and from 400 ° C. to The heating rate of T 1 is 1-8 ℃ / min;
    (2)升温至T 2,T 2为1150-1220℃,并在最高温保温0-60min,其中,由T 1升温至T 2的升温速率为1-8℃/min; (2) The temperature is raised to T 2 , T 2 is 1150-1220 ° C., and the temperature is maintained at the highest temperature for 0-60 min. Among them, the temperature rising rate from T 1 to T 2 is 1-8 ° C./min;
    (3)缓慢降温,由T 2降温至600℃的降温速率为3-9℃/min,由600℃降温至50℃的降温速率为1-4℃/min。 (3) Slow cooling, the cooling rate from T 2 to 600 ° C is 3-9 ° C / min, and the cooling rate from 600 ° C to 50 ° C is 1-4 ° C / min.
  2. 如权利要求1所述的发泡陶瓷轻质板材的辊道窑烧成方法,其特征在于,包括:The roller kiln firing method for a foamed ceramic light board according to claim 1, comprising:
    (1)升温至T 1,T 1为800-900℃,并在T 1保温0-30min,其中,由0℃升温至400℃的升温速率为13-17℃/min,由400℃升温至T 1的升温速率为4-6℃/min; (1) The temperature is raised to T 1 , T 1 is 800-900 ° C., and the temperature is maintained at T 1 for 0-30 min. Among them, the heating rate from 0 ° C. to 400 ° C. is 13-17 ° C./min, and from 400 ° C. to The heating rate of T 1 is 4-6 ℃ / min;
    (2)升温至T 2,T 2为1150-1220℃,并在最高温保温0-60min,其中,由T 1升温至T 2的升温速率为4-6℃/min; (2) The temperature is raised to T 2 , T 2 is 1150-1220 ° C., and the temperature is maintained at the highest temperature for 0-60 min. Among them, the temperature rising rate from T 1 to T 2 is 4-6 ° C./min;
    (3)缓慢降温,由T 2降温至600℃的降温速率为5-7℃/min,由600℃降温至50℃的降温速率为1-3℃/min。 (3) Slow cooling, the cooling rate from T 2 to 600 ° C is 5-7 ° C / min, and the cooling rate from 600 ° C to 50 ° C is 1-3 ° C / min.
  3. 如权利要求2所述的发泡陶瓷轻质板材的辊道窑烧成方法,其特征在于,包括:The roller kiln firing method for a foamed ceramic lightweight board according to claim 2, further comprising:
    (1)升温至T 1,T 1为800-900℃,并在T 1保温0-30min,其中,由0℃升温至400℃的升温速率为15℃/min,由400℃升温至T 1的升温速率为5℃/min; (1) The temperature is increased to T 1 , T 1 is 800-900 ° C., and the temperature is maintained at T 1 for 0-30 min. Among them, the temperature increase rate from 0 ° C. to 400 ° C. is 15 ° C./min, and from 400 ° C. to T 1 The heating rate is 5 ℃ / min;
    (2)升温至T 2,T 2为1150-1220℃,并在最高温保温0-60min,其中,由T 1升温至T 2的升温速率为5℃/min; (2) The temperature is increased to T 2 , T 2 is 1150-1220 ° C., and the temperature is maintained at the highest temperature for 0-60 min. Among them, the temperature rising rate from T 1 to T 2 is 5 ° C./min;
    (3)缓慢降温,由T 2降温至600℃的降温速率为6℃/min,由600℃降温至50℃的降温速率为2℃/min。 (3) Slow cooling, the cooling rate from T 2 to 600 ° C is 6 ° C / min, and the cooling rate from 600 ° C to 50 ° C is 2 ° C / min.
  4. 如权利要求1所述的发泡陶瓷轻质板材的辊道窑烧成方法,其特征在于,所述发泡陶瓷轻质板材主要由下述重量百分比的原料制成:The roller kiln firing method for a foamed ceramic lightweight sheet according to claim 1, wherein the foamed ceramic lightweight sheet is mainly made of the following weight percentages of raw materials:
    瓷砖抛光废渣70-96%、粘土0-10%、长石0-20%、发泡剂0.01-0.6%、稳定剂0.1-4%;Tile polishing residue 70-96%, clay 0-10%, feldspar 0-20%, foaming agent 0.01-0.6%, stabilizer 0.1-4%;
    所述稳定剂为二氧化锰。The stabilizer is manganese dioxide.
  5. 如权利要求4所述的发泡陶瓷轻质板材的辊道窑烧成方法,其特征在于,所述发泡陶瓷轻质板材主要由下述重量百分比的原料制成:The roller kiln firing method for a foamed ceramic lightweight board according to claim 4, wherein the foamed ceramic lightweight board is mainly made of the following weight percentages of raw materials:
    瓷砖抛光废渣75-95%、粘土0.1-10%、长石0.1-20%、发泡剂0.1-0.4%、稳定剂0.1-3%。Tile polishing residue is 75-95%, clay is 0.1-10%, feldspar is 0.1-20%, foaming agent is 0.1-0.4%, and stabilizer is 0.1-3%.
  6. 如权利要求4或5所述的发泡陶瓷轻质板材的辊道窑烧成方法,其特征在于,所述粘 土为黑泥、高岭土、城市污泥、海泥中的一种或多种。The method for sintering a foamed ceramic light board according to claim 4 or 5, wherein the clay is one or more of black mud, kaolin, urban sludge, and sea mud.
  7. 如权利要求4或5所述的发泡陶瓷轻质板材的辊道窑烧成方法,其特征在于,所述发泡剂为碳化硅或抛光磨头回收料,所述抛光磨头回收料的主要成分包括碳化硅和树脂。The method according to claim 4 or 5, wherein the foaming agent is silicon carbide or a polishing head recycled material. The main ingredients include silicon carbide and resin.
  8. 如权利要求1所述的发泡陶瓷轻质板材的辊道窑烧成方法,其特征在于,所述辊道窑烧成包括:The method of sintering a roller kiln for a foamed ceramic lightweight board according to claim 1, wherein the sintering of the roller kiln comprises:
    辊道窑上使用匣钵,匣钵为一体式匣钵或拼装式匣钵,利用人工或机器布料,然后在1150-1220℃的条件下进行烧成。A box bowl is used on the roller kiln. The box bowl is an integrated box bowl or a combined box bowl. It is manually or mechanically clothed and then fired at 1150-1220 ° C.
  9. 如权利要求8所述的发泡陶瓷轻质板材的辊道窑烧成方法,其特征在于,所述拼装式匣钵包括支架、垫板、围板和高温纸,所述垫板铺设在支架上,所述围板搭设在垫板的四周,所述垫板和围板上均设有所述高温纸。The roller kiln firing method for a foamed ceramic light board according to claim 8, wherein the assembled box comprises a support, a support plate, a surrounding plate, and a high-temperature paper, and the support plate is laid on the support In the above, the surrounding board is erected around the supporting board, and both the supporting board and the supporting board are provided with the high-temperature paper.
  10. 如权利要求9所述的发泡陶瓷轻质板材的辊道窑烧成方法,其特征在于,所述支架为SiC支架;The method according to claim 9, wherein the support is a SiC support;
    所述垫板为莫来石垫板、碳化硅垫板或堇青石垫板;The pad is a mullite pad, a silicon carbide pad or a cordierite pad;
    所述围板为莫来石围板、碳化硅围板或堇青石围板;The enclosure is a mullite enclosure, a silicon carbide enclosure or a cordierite enclosure;
    所述高温纸为硅酸铝纤维纸。The high-temperature paper is aluminum silicate fiber paper.
PCT/CN2018/100133 2018-06-28 2018-08-11 Rolling kiln firing method for foamed ceramic lightweight plate material WO2020000590A1 (en)

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