Background technology
Present stage, light filler commonly used in the dry-mixed mortar has pearlstone, expanded vermiculite, haydite and granular polystyrene; Using the widest pearlstone is with high-quality material from acidic volcanic glass matter rock, supplies fragmentation, oven dry, drops into the high-temperature roasting stove, 1000-1300 ℃ of heating down; Make its instantaneous expansion 4-30 a kind of lightweight heat-insulating material doubly; Expanded perlite granule is irregular, surface irregularity and corner angle are arranged, and inside has the hole that is interconnected; Its ultimate compression strength is low; In whipping process, be prone to fragmentation and make it lose surperficial protection, and water-intake rate is very high, thereby be prone to lose effects such as insulation, sound-absorbing, sound insulation and the thermal conductivity that should have are low; To be vermiculite deposit sharply be heated under 900-950 ℃ of high temperature after selected, oven dry expanded vermiculite, the interlayer free water gasifies rapidly; Make and produce a large amount of steam between the scale layer of vermiculite and force it to produce a kind of light heat-insulating material that expands and form along direction perpendicular to cleavage surface; Expanded vermiculite belongs to not acid-proof substances, and electrical insulation capability is bad, crushing resistance is poor; Haydite is to be main raw material by clay, argillaceous rock, industrial waste etc.; Through processing, fuse the particulate state ceramic thing that forms, the haydite shell is hard and have one deck water proof to protect the red glaze layer parcel of grain of gas, inner porous; Haydite surface irregularity and thermal conductivity are high, and the volume water absorption rate is also higher; Granular polystyrene is to pulverize a kind of light filler that forms by useless styrenic foams, though the granular polystyrene thermal conductivity is low, and uvioresistant performance difference and inflammable.Since more than various light fillers all have defective more or less, thereby need to seek the preferable light filler of a kind of over-all properties and replace.
Ceramic tile bond is the cement based matrix material of bonding ceramic tile; Also claim glue for tile; It is one of kind main in the dry-mixed mortar; Along with the appearance of polymer modification glue for tile, inlay ceramic tile technology is also changed by traditional thick-layer normal direction thin-layer method in recent years, and has driven the revision of ceramic tile adhesive industry standard (JC/T547-2005) and perfect.According to the requirement among the new revised standard JC/T547-2005; The performance index that the cement based glue for tile need satisfy after tensile bond strength, immersion back intensity, thermal ageing intensity behind intensity, the freeze-thaw cycle, after the open hour the intensity, also to satisfy performance index such as anti-downslide, transverse deformation.Interior of building has long history with the outside ceramic tile that uses, and along with the expansion of ceramic tile application scenario and the development of ceramic tile manufacturing technology, the quality of ceramic tile has had great improvement, the increasing many traditional ceramic tiles of hole that replaced of the ceramic tile that structure is closely knit.Though existing common glue for tile can satisfy the requirement of part tensile bond strength; But in special construction occasion, as when needing the open hour more than the 30min, the anti-downslide of common glue for tile and transverse deformation index just do not reach requirement far away; And in thin layer construction technology; The smearing thickness of glue for tile has only about 5mm, how to let so a spot of glue for tile have outstanding performance, is the problem that industry technician endeavours to study.
Summary of the invention
For solving the problem of above existence, the purpose of this invention is to provide a kind of granulated glass sphere with bee-hole, this granulated glass sphere can use as light filler in dry-mixed mortar.
Another object of the present invention provides a kind of glue for tile that contains above-mentioned bee-hole granulated glass sphere.
For realizing above first purpose; Granulated glass sphere with bee-hole of the present invention; Be that the pure glasswork that industrial or civilian recovery obtain is ground into the glass powder below 400 orders; Mix with whipping agent and sticker, fusion under 800-820 ℃ hot conditions, expansion, cooling and screening make then again; This granulated glass sphere is that apparent coarse regular spherical particle, inside have the honeycomb reticulated structure, particle diameter is that 0.1-5mm, tap density are 310-460kg/m
3, cylindrical compress strength 2.6-2.8Mpa.
The addition of above-mentioned whipping agent is the 4.5-5.5% of glass powder weight.
The addition of above-mentioned sticker rises sticker for the per kilogram glass powder adds 0.18-0.19.
The preferred Paris white of above-mentioned whipping agent.
Above-mentioned sticker is water glass stoste or water glass diluent.
To be water glass and water form with the mixed of 4-5 ︰ 1 above-mentioned water glass diluent.
Granulated glass sphere with bee-hole of the present invention; Outward appearance is the regular spherical particle, joins in the mortar and can form cylinder effect, and resistance is little when making construction; Smear out easily; And its cylindrical compress strength is tens times of pearlstone, the volume stability of the fine maintenance material of ability in whipping process, and the volume output capacity is high; In addition, granulated glass sphere of the present invention, inside has special honeycomb reticulated structure; The small holes of this structure much is separate, even these independently little cavity suctions can all not be filled yet; Therefore water-intake rate is low, and then also has low thermal conductivity and stable anti-ultraviolet property.Granulated glass sphere with bee-hole of the present invention is that the industrial glass that utilize to reclaim or domestic glass are as raw material; Not only draw materials easily; And have the environmental protection and energy saving effect of utilization of waste material, be the ideal material that a kind of alternative pearlstone uses as light filler in dry-mixed mortar.
The present invention also provides a kind of glue for tile that contains above-mentioned bee-hole granulated glass sphere, and this glue for tile comprises following each component and weight proportion:
Silicate cement 45-50%
Light filler 15-20%
Water-ground limestone 10-15%
Fine sand 10-15%
Additive 6-9%
The weight proportion sum of above-mentioned each component is 100%, and light filler wherein is that particle diameter is the above-mentioned granulated glass sphere with bee-hole of 0.1-0.5 mm.
Above-mentioned additive comprises redispersible type rubber powder, ether of cellulose, starch ethers, wood fibre, and wherein the weight percent of each component is redispersible type rubber powder 80-90%, ether of cellulose 6-10%, starch ethers 1-2%, wood fibre 3-5%.
Above-mentioned silicate cement preferred intensity grade is the silicate cement of 52.5Mpa, water-ground limestone preferred size 310-330 purpose water-ground limestone.
In order to guarantee that glue for tile has better application property, above-mentioned fine sand preferred size is 70-140 purpose washing river sand.
Glue for tile of the present invention utilizes the granulated glass sphere with bee-hole to replace the sand in the conventional formulation, makes it have following advantage:
1, because bee-hole granulated glass sphere light weight and ultimate compression strength is high; Can reduce the tap density of glue for tile after the adding, the glue for tile wet density after adding water and stirring is except that the volume output capacity improves, and wet density also decreases; Can not only reduce transportation cost; And spread upon on the buildings, anti-gliding ability is good, also can reduce the weight of final body of wall.
2, because the bee-hole granulated glass sphere has the spherical design of rule, glue for tile is smeared in the process in construction, played the roller bearing lubrication, improve the construction feel of glue for tile greatly, improve operating efficiency as filler.
3, because the bee-hole granulated glass sphere has coarse surface, and this surface energy obtains the fine infiltration of grout, thereby improve the tensile bond strength of glue for tile and base material, easily reach more than the 1.0MPa.
4, because bee-hole granulated glass sphere volume inside reticulated structure has the wet function of certain protection against the tide control, and therefore, glue for tile water retention capacity of the present invention is higher, the open hour can reach about 40min, have prolonged the construction operation time of material greatly.
5, owing to the adding of bee-hole granulated glass sphere, the Young's modulus of glue for tile reduces, and snappiness increases, and makes tack coat can bear the dilatation that produces because of temperature difference influence.
6, glue for tile of the present invention, each item index all meet correlated performance index request in JC/T547-2005 " ceramic wall and floor bricks tackiness agent " standard, and can reach the C2TES1 index request.
Embodiment
Embodiment 1 (preparation) with bee-hole granulated glass sphere:
At first, the pure glasswork that industrial or civilian recovery are obtained is ground into the glass powder about 380 orders, in glass powder, adds Paris white and water glass diluent (water glass and water are with the mixed of 4 ︰ 1); The add-on of Paris white is 5% of a glass powder weight; The add-on of water glass diluent is pressed the per kilogram glass powder and is added 0.18 liter amount adding, and the three mixes, and then compound is sent in the rotary kiln; Make its fusion under 810 ℃ hot conditions, expansion, cooling then; Obtain shaggy spheroidal particle, through 35 orders, 50 orders and the screening of 60 purposes sieve bucket, obtaining particle diameter is that 0.1-0.3mm, 0.25-0.5 mm inside have the cancellated granulated glass sphere of honeycomb with these particles; Like Fig. 1, shown in 2, the tap density that records this granulated glass sphere is 420kg/m
3, cylindrical compress strength is 2.7Mpa.
Embodiment 2 (preparation of glue for tile):
1, prescription
3, preparation and test
Above-mentioned each component of 1# prescription is mixed; Add pan feeding and weigh 49% water; Each component of 2# prescription mixes, and adds pan feeding and weighs 52% water, and whipping device and the stirring means according to regulation among the standard JC/T547-2005 " ceramic wall and floor bricks tackiness agent " stirs respectively; Test according to this standard then, each item performance is following:
Can find out that by last table glue for tile of the present invention can satisfy the performance index of C2TES1.In addition, the wet density of common glue for tile is many at 1500kg/m
3More than, and wet density 1200kg/m of the present invention
3About.Glue for tile of the present invention; Prescription rationally; And have the introducing of bee-hole granulated glass sphere, and not only make ceramic tile bond have high volume output capacity, superior application property, can also save transportation cost, engineering time; Material itself can also attach the effect of sound-insulating, is rare novel ceramic tile glue.